TY - JOUR A1 - Dunst, Alexander T1 - After trauma time and affect in american culture beyond 9/11 JF - Parallax Y1 - 2012 U6 - https://doi.org/10.1080/13534645.2012.672244 SN - 1353-4645 VL - 18 IS - 2 SP - 56 EP - 71 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Draganova, Nadya A1 - Richter, Philipp A1 - Fechner, Cora T1 - High-resolution observations of two O VI absorbers at z approximate to 2 toward PKS 1448-232 JF - Astronomy and astrophysics : an international weekly journal N2 - To explore the ionization conditions in highly-ionized absorbers at high redshift, we study in detail two intervening O vi absorbers at z approximate to 2 toward the quasar PKS 1448-232, based on high (R approximate to 75 000) and intermediate (R approximate to 45 000) resolution optical VLT/UVES spectra. We find that both absorption systems are composed of several narrow subcomponents with typical Civ/O VI Doppler-parameters of b < 10 km s(-1). This implies that the gas temperatures are T < 10(5) K and that the absorbers are photoionized by the UV background. The system at z = 2.1098 represents a simple, isolated O VI absorber that has only two absorption components and is relatively metal-rich (Z similar to 0.6 solar). Ioinization modeling implies that the system is photoionized with O VI, C IV, and H I coexisting in the same gas phase. The second system at z = 2.1660 represents a complicated, multi-component absorption system with eight O VI components spanning almost 300 km s(-1) in radial velocity. The photoionization modeling implies that the metallicity is non-uniform and relatively low (<= 0.1 solar) and that the O VI absorption must arise in a gas phase that differs from that traced by C IV, C III, and H I. Our detailed study of the two O VI systems towards PKS 1448-232 shows that multi-phase, multi-component high-ion absorbers similar to the one at z = 2.1660 can be described by applying a detailed ionization modeling of the various subcomponents to obtain reliable measurements of the physical conditions and the metal abundances in the gas. KW - intergalactic medium KW - quasars: absorption lines KW - cosmology: observations Y1 - 2012 U6 - https://doi.org/10.1051/0004-6361/201116730 SN - 0004-6361 VL - 538 IS - 1 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Dornick, Sahra T1 - "Footnotes to the Family" Performativity to the trauma of the Holocaust in the German-Jewish Family novels "So are we" (Gila Lustiger) and "Family Life" (Viola Roggenkamp) JF - Zeitschrift für Religions- und Geistesgeschichte Y1 - 2012 SN - 0044-3441 VL - 64 IS - 2 SP - 138 EP - 151 PB - Brill CY - Leiden ER - TY - JOUR A1 - Dorenkamp, Marc A1 - Bonaventura, Klaus A1 - Sohns, Christian A1 - Becker, Christoph R. A1 - Leber, Alexander W. T1 - Direct costs and cost-effectiveness of dual-source computed tomography and invasive coronary angiography in patients with an intermediate pretest likelihood for coronary artery disease JF - Heart N2 - Aims The study aims to determine the direct costs and comparative cost-effectiveness of latest-generation dual-source computed tomography (DSCT) and invasive coronary angiography for diagnosing coronary artery disease (CAD) in patients suspected of having this disease. Methods The study was based on a previously elaborated cohort with an intermediate pretest likelihood for CAD and on complementary clinical data. Cost calculations were based on a detailed analysis of direct costs, and generally accepted accounting principles were applied. Based on Bayes' theorem, a mathematical model was used to compare the cost-effectiveness of both diagnostic approaches. Total costs included direct costs, induced costs and costs of complications. Effectiveness was defined as the ability of a diagnostic test to accurately identify a patient with CAD. Results Direct costs amounted to (sic)98.60 for DSCT and to (sic)317.75 for invasive coronary angiography. Analysis of model calculations indicated that cost-effectiveness grew hyperbolically with increasing prevalence of CAD. Given the prevalence of CAD in the study cohort (24%), DSCT was found to be more cost-effective than invasive coronary angiography ((sic)970 vs (sic)1354 for one patient correctly diagnosed as having CAD). At a disease prevalence of 49%, DSCT and invasive angiography were equally effective with costs of (sic)633. Above a threshold value of disease prevalence of 55%, proceeding directly to invasive coronary angiography was more cost-effective than DSCT. Conclusions With proper patient selection and consideration of disease prevalence, DSCT coronary angiography is cost-effective for diagnosing CAD in patients with an intermediate pretest likelihood for it. However, the range of eligible patients may be smaller than previously reported. Y1 - 2012 U6 - https://doi.org/10.1136/heartjnl-2011-300149 SN - 1355-6037 VL - 98 IS - 6 SP - 460 EP - 467 PB - BMJ Publ. Group CY - London ER - TY - JOUR A1 - Domahs, Ulrike A1 - Knaus, Johannes A1 - Orzechowska, Paula A1 - Wiese, Richard T1 - Stress "deafness" in a language with fixed word stress an ERR study on Polish JF - Frontiers in psychology N2 - The aim of the present contribution was to examine the factors influencing the prosodic processing in a language with predictable word stress. For Polish, a language with fixed penultimate stress but several well-defined exceptions, difficulties in the processing and representation of prosodic information have been reported (e.g., Peperkamp and Dupoux, 2002). The present study utilized event-related potentials (ERPs) to investigate the factors influencing prosodic processing in Polish. These factors are (i) the predictability of stress and (ii) the prosodic structure in terms of metrical feet. Polish native speakers were presented with correctly and incorrectly stressed Polish words and instructed to judge the correctness of the perceived stress patterns. For some stress violations, an early negativity was found which was interpreted as a reflection of an error-detection mechanism. In addition, exceptional stress patterns (=antepenultimate stress) and post-lexical (=initial) stress evoked a task-related positivity effect (P300) whose amplitude and latency is correlated with the degree of anomaly and deviation from an expectation. In contrast, violations involving the default (=penultimate stress) did not produce such an effect. This asymmetrical result is interpreted to reflect that Polish native speakers are less sensitive to the default pattern than to the exceptional or post-lexical patterns. Behavioral results are orthogonal to the electrophysiological results showing that Polish speakers had difficulties to reject any kind of stress violation. Thus, on a meta-linguistic level Polish speakers appeared to be stress-"deaf" for any kind of stress manipulation, whereas the neural reactions differentiate between the default and lexicalized patterns. KW - stress "deafness" KW - fixed stress system KW - prosodic representation KW - P300 KW - generalized error-detection mechanism Y1 - 2012 U6 - https://doi.org/10.3389/fpsyg.2012.00439 SN - 1664-1078 VL - 3 PB - Frontiers Research Foundation CY - Lausanne ER - TY - JOUR A1 - Dolgener, Nicola A1 - Schröder, Christiane A1 - Schneeweiss, N. A1 - Tiedemann, Ralph T1 - Genetic population structure of the Fire-bellied toad Bombina bombina in an area of high population density implications for conservation JF - Hydrobiologia : acta hydrobiologica, hydrographica, limnologica et protistologica N2 - In this study, we report the genetic population structure of the Fire-bellied toad Bombina bombina in Brandenburg (East Germany) in the context of conservation. We analysed 298 samples originating from 11 populations in Brandenburg using mitochondrial control region sequences and six polymorphic microsatellite loci. For comparison, we included one population each from Poland and Ukraine into our analysis. Within Brandenburg, we detected a moderate variability in the mitochondrial control region (19 different haplotypes) and at microsatellite loci (9-12 alleles per locus). These polymorphisms revealed a clear population structure among toads in Brandenburg, despite a relatively high overall population density and the moderate size of single populations (100-2000 individuals). The overall genetic population structure is consistent with a postglacial colonization from South East-Europe and a subsequent population expansion. Based on genetic connectivity, we infer Management Units (MUs) as targets for conservation. Our genetic survey identified MUs, within which human infrastructure is currently preventing any genetic exchange. We also detect an unintentional translocation from South East to North West Brandenburg, presumably in the course of fish stocking activities. Provided suitable conservation measures are taken, Brandenburg should continue to harbor large populations of this critically endangered species. KW - Conservation genetics KW - Fire-bellied toad KW - Fragmentation KW - Mitochondrial DNA KW - Microsatellites KW - Translocation Y1 - 2012 U6 - https://doi.org/10.1007/s10750-012-1016-1 SN - 0018-8158 VL - 689 IS - 1 SP - 111 EP - 120 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Dimitrova, Ilinka A1 - Koppitz, Jörg T1 - On the monoid of all partial order-preserving extensive transformations JF - Communications in algebra N2 - A partial transformation alpha on an n-element chain X-n is called order-preserving if x <= y implies x alpha <= y alpha for all x, y in the domain of alpha and it is called extensive if x <= x alpha for all x in the domain of alpha. The set of all partial order-preserving extensive transformations on X-n forms a semiband POEn. We determine the maximal subsemigroups as well as the maximal subsemibands of POEn. KW - Extensive transformation KW - Maximal subsemibands KW - Maximal subsemigroups KW - Rank KW - Transformation semigroup Y1 - 2012 U6 - https://doi.org/10.1080/00927872.2011.557813 SN - 0092-7872 VL - 40 IS - 5 SP - 1821 EP - 1826 PB - Taylor & Francis Group CY - Philadelphia ER - TY - JOUR A1 - Dimitrova, Ilinka A1 - Fernandes, Vitor H. A1 - Koppitz, Jörg T1 - The maximal subsemigroups of semigroups of transformations preserving or reversing the orientation on a finite chain JF - Publicationes mathematicae N2 - The study of the semigroups OPn, of all orientation-preserving transformations on an n-element chain, and ORn, of all orientation-preserving or orientation-reversing transformations on an n-element chain, has began in [17] and [5]. In order to bring more insight into the subsemigroup structure of OPn and ORn, we characterize their maximal subsemigroups. KW - finite transformation semigroup KW - orientation-preserving and orientation-reversing transformations KW - maximal subsemigroups Y1 - 2012 U6 - https://doi.org/10.5486/PMD.2012.4897 SN - 0033-3883 VL - 81 IS - 1-2 SP - 11 EP - 29 PB - Institutum Mathematicum Universitatis Debreceniensis, Debreceni Tudományegyetem Matematikai Intézete CY - Debrecen ER - TY - JOUR A1 - Dimigen, Olaf A1 - Kliegl, Reinhold A1 - Sommer, Werner T1 - Trans-saccadic parafoveal preview benefits in fluent reading: A study with fixation-related brain potentials JF - NeuroImage : a journal of brain function N2 - During natural reading, a parafoveal preview of the upcoming word facilitates its subsequent recognition (e.g., shorter fixation durations compared to masked preview) but nothing is known about the neural correlates of this so-called preview benefit. Furthermore, while the evidence is strong that readers preprocess orthographic features of upcoming words, it is controversial whether word meaning can also be accessed parafoveally. We investigated the timing, scope, and electrophysiological correlates of parafoveal information use in reading by simultaneously recording eye movements and fixation-related brain potentials (FRPs) while participants read word lists fluently from left to right. For one word the target (e.g., "blade") parafoveal information was manipulated by showing an identical ("blade"), semantically related ("knife"), or unrelated ("sugar") word as preview. In boundary trials, the preview was shown parafoveally but changed to the correct target word during the incoming saccade. Replicating classic findings, target words were fixated shorter after identical previews. In the EEG, this benefit was reflected in an occipitotemporal preview positivity between 200 and 280 ms. In contrast, there was no facilitation from related previews. In parafoveal-on-foveal trials, preview and target were embedded at neighboring list positions without a display change. Consecutive fixation of two related words produced N400 priming effects, but only shortly (160 ms) after the second word was directly fixated. Results demonstrate that neural responses to words are substantially altered by parafoveal preprocessing under normal reading conditions. We found no evidence that word meaning contributes to these effects. Saccade-contingent display manipulations can be combined with EEG recordings to study extrafoveal perception in vision. KW - EEG KW - Eye tracking KW - Active vision KW - Eye-fixation-related potentials (EFRP) KW - Parafoveal vision KW - Boundary technique Y1 - 2012 U6 - https://doi.org/10.1016/j.neuroimage.2012.04.006 SN - 1053-8119 SN - 1095-9572 VL - 62 IS - 1 SP - 381 EP - 393 PB - Elsevier CY - San Diego ER - TY - JOUR A1 - Di Lucia, Matteo A1 - Trecalli, A. A1 - Mutti, Maria A1 - Parente, Maria T1 - Bio-chemostratigraphy of the Barremian-Aptian shallow-water carbonates of the southern Apennines (Italy): pinpointing the OAE1a in a Tethyan carbonate platform JF - Solid earth N2 - Low biostratigraphic resolution and lack of chronostratigraphic calibration hinder precise correlations between platform carbonates and coeval deep-water successions. These are the main obstacle when studying the record of Mesozoic oceanic anoxic events in carbonate platforms. In this paper carbon and strontium isotope stratigraphy are used to produce the first chronostratigraphic calibration of the Barremian-Aptian biostratigraphy of the Apenninic carbonate platform of southern Italy. According to this calibration, the segment of decreasing delta C-13 values, leading to the negative peak that is generally taken as the onset of the Selli event, starts a few metres above the last occurrence of Palorbitolina lenticularis and Voloshinoides murgensis. The following rise of delta C-13 values, corresponding to the interval of enhanced accumulation of organic matter in deep-water sections, ends just below the first acme of Salpingoporella dinarica, which roughly corresponds to the segment of peak delta C-13 values. The whole carbon isotope excursion associated with the oceanic anoxic event 1a is bracketed in the Apenninic carbonate platform between the last occurrence of Voloshinoides murgensis and the "Orbitolina level", characterized by the association of Mesorbitolina parva and Mesorbitolina texana. Since these bioevents have been widely recognized beyond the Apenninic platform, the calibration presented in this paper can be used to pinpoint the interval corresponding to the Early Aptian oceanic anoxic event in other carbonate platforms of central and southern Tethys. This calibration will be particularly useful to interpret the record of the Selli event in carbonate platform sections for which a reliable carbon isotope stratigraphy is not available. Y1 - 2012 U6 - https://doi.org/10.5194/se-3-1-2012 SN - 1869-9510 VL - 3 IS - 1 SP - 1 EP - 28 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Di Giulio, Giuseppe A1 - Savvaidis, Alexandros A1 - Ohrnberger, Matthias A1 - Wathelet, Marc A1 - Cornou, Cecile A1 - Knapmeyer-Endrun, Brigitte A1 - Renalier, Florence A1 - Theodoulidis, Nikos A1 - Bard, Pierre-Yves T1 - Exploring the model space and ranking a best class of models in surface-wave dispersion inversion application at European strong-motion sites JF - Geophysics N2 - The inversion of surface-wave dispersion curve to derive shear-wave velocity profile is a very delicate process dealing with a nonunique problem, which is strongly dependent on the model space parameterization. When independent and reliable information is not available, the selection of most representative models within the ensemble produced. by the inversion is often difficult. We implemented a strategy in the inversion of dispersion curves able to investigate the influence of the parameterization of the model space and to select a "best" class of models. We analyzed surface-wave dispersion curves measured at 14 European strong..-motion sites within the NERIES EC-Project. We focused on the inversion task exploring the model space by means of four distinct pararneterization classes composed of layers progressively added over a half-space. The classes differ in the definition of the shear-wave velocity profile; we considered models with uniform velocity as well as models with increasing velocity with depth. At each site and for each model parameterization, we performed an extensive surface-wave inversion (200,100 models for five seeds) using the conditional neighborhood algorithm. We addressed the model evaluation following the corrected Akaike's information criterion (AlCc) that combines the concept of misfit to the number of degrees of freedom of the system. The misfit was computed as least-squares estimation between theoretical and observed dispersion curve. The model complexity was accounted in a penalty term by AlCc. By applying such inversion strategy on 14 strong-motion sites, we found that the best parameterization of the model space is mostly three to four layers over a half-space: where the shear-wave velocity of the uppermost layers can follow uniform or power-law dependence with depth. The shear-wave velocity profiles derived by inversion agree with shear-wave velocity profiles provided by borehole surveys at approximately 80% of the sites. Y1 - 2012 U6 - https://doi.org/10.1190/GEO2011-0116.1 SN - 0016-8033 VL - 77 IS - 3 SP - B147 EP - B166 PB - Society of Exploration Geophysicists CY - Tulsa ER - TY - JOUR A1 - Denz, Rebekka A1 - Jurewicz, Grażyna A1 - Salzer, Dorothea M. T1 - Einblicke in die "British Jewish Studies" Y1 - 2012 SN - 1614-6492 ER - TY - JOUR A1 - Denz, Rebekka A1 - Jurewicz, Grażyna A1 - Salzer, Dorothea M. T1 - Insight into "British Jewish Studies" Y1 - 2012 SN - 1614-6492 ER - TY - JOUR A1 - Delavaud, Elise A1 - Scherbaum, Frank A1 - Kühn, Nicolas A1 - Allen, Trevor T1 - Testing the global applicability of ground-motion prediction equations for active shallow crustal regions JF - Bulletin of the Seismological Society of America N2 - Large research initiatives such as the Global Earthquake Model (GEM) or the Seismic HAzard haRmonization in Europe (SHARE) projects concentrate a great collaborative effort on defining a global standard for seismic hazard estimations. In this context, there is an increasing need for identifying ground-motion prediction equations (GMPEs) that can be applied at both global and regional scale. With increasing amounts of strong-motion records that are now available worldwide, observational data can provide a valuable resource to tackle this question. Using the global dataset of Allen and Wald (2009), we evaluate the ability of 11 GMPEs to predict ground-motion in different active shallow crustal regions worldwide. Adopting the approach of Scherbaum et al. (2009), we rank these GMPEs according to their likelihood of having generated the data. In particular, we estimate how strongly data support or reject the models with respect to the state of noninformativeness defined by a uniform weighting. Such rankings derived from this particular global dataset enable us to explore the potential of GMPEs to predict ground motions in their host region and also in other regions depending on the magnitude and distance considered. In the ranking process, we particularly focus on the influence of the distribution of the testing dataset compared with the GMPE's native dataset. One of the results of this study is that some nonindigenous models present a high degree of consistency with the data from a target region. Two models in particular demonstrated a strong power of geographically wide applicability in different geographic regions with respect to the testing dataset: the models of Akkar and Bommer (2010) and Chiou et al. (2010). Y1 - 2012 U6 - https://doi.org/10.1785/0120110113 SN - 0037-1106 VL - 102 IS - 2 SP - 707 EP - 721 PB - Seismological Society of America CY - El Cerrito ER - TY - JOUR A1 - Delavaud, Elise A1 - Cotton, Fabrice A1 - Akkar, Sinan A1 - Scherbaum, Frank A1 - Danciu, Laurentiu A1 - Beauval, Celine A1 - Drouet, Stephane A1 - Douglas, John A1 - Basili, Roberto A1 - Sandikkaya, M. Abdullah A1 - Segou, Margaret A1 - Faccioli, Ezio A1 - Theodoulidis, Nikos T1 - Toward a ground-motion logic tree for probabilistic seismic hazard assessment in Europe JF - Journal of seismology N2 - The Seismic Hazard Harmonization in Europe (SHARE) project, which began in June 2009, aims at establishing new standards for probabilistic seismic hazard assessment in the Euro-Mediterranean region. In this context, a logic tree for ground-motion prediction in Europe has been constructed. Ground-motion prediction equations (GMPEs) and weights have been determined so that the logic tree captures epistemic uncertainty in ground-motion prediction for six different tectonic regimes in Europe. Here we present the strategy that we adopted to build such a logic tree. This strategy has the particularity of combining two complementary and independent approaches: expert judgment and data testing. A set of six experts was asked to weight pre-selected GMPEs while the ability of these GMPEs to predict available data was evaluated with the method of Scherbaum et al. (Bull Seismol Soc Am 99:3234-3247, 2009). Results of both approaches were taken into account to commonly select the smallest set of GMPEs to capture the uncertainty in ground-motion prediction in Europe. For stable continental regions, two models, both from eastern North America, have been selected for shields, and three GMPEs from active shallow crustal regions have been added for continental crust. For subduction zones, four models, all non-European, have been chosen. Finally, for active shallow crustal regions, we selected four models, each of them from a different host region but only two of them were kept for long periods. In most cases, a common agreement has been also reached for the weights. In case of divergence, a sensitivity analysis of the weights on the seismic hazard has been conducted, showing that once the GMPEs have been selected, the associated set of weights has a smaller influence on the hazard. KW - Logic trees KW - Ground-motion prediction equations KW - Expert judgment KW - Model selection KW - Seismic hazard assessment Y1 - 2012 U6 - https://doi.org/10.1007/s10950-012-9281-z SN - 1383-4649 VL - 16 IS - 3 SP - 451 EP - 473 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Delahaye, Emilie A1 - Goebel, Ronald A1 - Loebbicke, Ruben A1 - Guillot, Regis A1 - Sieber, Christoph A1 - Taubert, Andreas T1 - Silica ionogels for proton transport JF - Journal of materials chemistry N2 - A number of ionogels - silica-ionic liquid (IL) hybrid materials - were synthesized and studied for their ionic conductivity. The materials are based on a sulfonated IL, 1-methyl-3-(3-sulfopropyl-)-imidazolium p-toluenesulfonate, [PmimSO(3)H][PTS], which contains a sulfonic acid/sulfonate group both in the IL anion and in the side chain of the IL cation. By way of the sulfonate-sulfonic acid proton transfer, the IL imparts the ionogel with a high ionic conductivity of ca. 10(-2) S cm(-1) in the as-synthesized state at 120 degrees C and 10(-3) S cm(-1) in the dry state at 120 degrees C. The ionogels are stable up to ca. 150 degrees C in dynamic thermogravimetric analysis. This suggests that these materials, which are relatively cheap and easily fabricated, could find application in fuel cells in intermediate temperature ranges where many other membrane materials are not suitable. Y1 - 2012 U6 - https://doi.org/10.1039/c2jm00037g SN - 0959-9428 VL - 22 IS - 33 SP - 17140 EP - 17146 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Debatin, Franziska A1 - Möllmer, Jens A1 - Mondal, Suvendu Sekhar A1 - Behrens, Karsten A1 - Möller, Andreas A1 - Staudt, Reiner A1 - Thomas, Arne A1 - Holdt, Hans-Jürgen T1 - Mixed gas adsorption of carbon dioxide and methane on a series of isoreticular microporous metal-organic frameworks based on 2-substituted imidazolate-4-amide-5-imidates JF - Journal of materials chemistry N2 - In this work the adsorption of CO2 and CH4 on a series of isoreticular microporous metal-organic frameworks based on 2-substituted imidazolate-4-amide-5-imidates, IFP-1-IFP-6 (IFP Imidazolate Framework Potsdam), is studied firstly by pure gas adsorption at 273 K. All experimental isotherms can be nicely described by using the Toth isotherm model and show the preferred adsorption of CO2 over CH4. At low pressures the Toth isotherm equation exhibits a Henry region, wherefore Henry's law constants for CO2 and CH4 uptake could be determined and ideal selectivity (alpha CO2/CH4) has been calculated. Secondly, selectivities were calculated from mixture data by using nearly equimolar binary mixtures of both gases by a volumetric-chromatographic method to examine the IFPs. Results showed the reliability of the selectivity calculation. Values of (alpha CO2/CH4) around 7.5 for IFP-5 indicate that this material shows much better selectivities than IFP-1, IFP-2, IFP-3, IFP-4 and IFP-6 with slightly lower selectivity (alpha CO2/CH4) = 4-6. The preferred adsorption of CO2 over CH4 especially of IFP-5 and IFP-4 makes these materials suitable for gas separation application. Y1 - 2012 U6 - https://doi.org/10.1039/c2jm15811f SN - 0959-9428 VL - 22 IS - 20 SP - 10221 EP - 10227 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Debatin, Franziska A1 - Behrens, Karsten A1 - Weber, Jens A1 - Baburin, Igor A. A1 - Thomas, Arne A1 - Schmidt, Johannes A1 - Senkovska, Irena A1 - Kaskel, Stefan A1 - Kelling, Alexandra A1 - Hedin, Niklas A1 - Bacsik, Zoltan A1 - Leoni, Stefano A1 - Seifert, Gotthard A1 - Jäger, Christian A1 - Günter, Christina A1 - Schilde, Uwe A1 - Friedrich, Alwin A1 - Holdt, Hans-Jürgen T1 - An isoreticular family of microporous metal-organic frameworks based on zinc and 2-substituted imidazolate-4-amide-5-imidate Syntheses, structures and properties JF - Chemistry - a European journal N2 - We report on a new series of isoreticular frameworks based on zinc and 2-substituted imidazolate-4-amide-5-imidate (IFP-14, IFP=imidazolate framework Potsdam) that form one-dimensional, microporous hexagonal channels. Varying R in the 2-substitued linker (R=Me (IFP-1), Cl (IFP-2), Br (IFP-3), Et (IFP-4)) allowed the channel diameter (4.01.7 angstrom), the polarisability and functionality of the channel walls to be tuned. Frameworks IFP-2, IFP-3 and IFP-4 are isostructural to previously reported IFP-1. The structures of IFP-2 and IFP-3 were solved by X-ray crystallographic analyses. The structure of IFP-4 was determined by a combination of PXRD and structure modelling and was confirmed by IR spectroscopy and 1H MAS and 13C CP-MAS NMR spectroscopy. All IFPs showed high thermal stability (345400?degrees C); IFP-1 and IFP-4 were stable in boiling water for 7 d. A detailed porosity analysis was performed on the basis of adsorption measurements by using various gases. The potential of the materials to undergo specific interactions with CO2 was investigated by measuring the isosteric heats of adsorption. The capacity to adsorb CH4 (at 298 K), CO2 (at 298 K) and H2 (at 77 K) at high pressure were also investigated. In situ IR spectroscopy showed that CO2 is physisorbed on IFP-14 under dry conditions and that both CO2 and H2O are physisorbed on IFP-1 under moist conditions. KW - adsorption KW - metal- organic frameworks KW - microporous materials KW - N KW - O ligands KW - zinc Y1 - 2012 U6 - https://doi.org/10.1002/chem.201200889 SN - 0947-6539 VL - 18 IS - 37 SP - 11630 EP - 11640 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - de Vera, Jean-Pierre Paul A1 - Böttger, Ute A1 - de la Torre Nötzel, Rosa A1 - Sanchez, Francisco J. A1 - Grunow, Dana A1 - Schmitz, Nicole A1 - Lange, Caroline A1 - Hübers, Heinz-Wilhelm A1 - Billi, Daniela A1 - Baque, Mickael A1 - Rettberg, Petra A1 - Rabbow, Elke A1 - Reitz, Günther A1 - Berger, Thomas A1 - Möller, Ralf A1 - Bohmeier, Maria A1 - Horneck, Gerda A1 - Westall, Frances A1 - Jänchen, Jochen A1 - Fritz, Jörg A1 - Meyer, Cornelia A1 - Onofri, Silvano A1 - Selbmann, Laura A1 - Zucconi, Laura A1 - Kozyrovska, Natalia A1 - Leya, Thomas A1 - Foing, Bernard A1 - Demets, Rene A1 - Cockell, Charles S. A1 - Bryce, Casey A1 - Wagner, Dirk A1 - Serrano, Paloma A1 - Edwards, Howell G. M. A1 - Joshi, Jasmin Radha A1 - Huwe, Björn A1 - Ehrenfreund, Pascale A1 - Elsaesser, Andreas A1 - Ott, Sieglinde A1 - Meessen, Joachim A1 - Feyh, Nina A1 - Szewzyk, Ulrich A1 - Jaumann, Ralf A1 - Spohn, Tilman T1 - Supporting Mars exploration BIOMEX in Low Earth Orbit and further astrobiological studies on the Moon using Raman and PanCam technology JF - Planetary and space science N2 - The Low Earth Orbit (LEO) experiment Biology and Mars Experiment (BIOMEX) is an interdisciplinary and international space research project selected by ESA. The experiment will be accommodated on the space exposure facility EXPOSE-R2 on the International Space Station (ISS) and is foreseen to be launched in 2013. The prime objective of BIOMEX is to measure to what extent biomolecules, such as pigments and cellular components, are resistant to and able to maintain their stability under space and Mars-like conditions. The results of BIOMEX will be relevant for space proven biosignature definition and for building a biosignature data base (e.g. the proposed creation of an international Raman library). The library will be highly relevant for future space missions such as the search for life on Mars. The secondary scientific objective is to analyze to what extent terrestrial extremophiles are able to survive in space and to determine which interactions between biological samples and selected minerals (including terrestrial, Moon- and Mars analogs) can be observed under space and Mars-like conditions. In this context, the Moon will be an additional platform for performing similar experiments with negligible magnetic shielding and higher solar and galactic irradiation compared to LEO. Using the Moon as an additional astrobiological exposure platform to complement ongoing astrobiological LEO investigations could thus enhance the chances of detecting organic traces of life on Mars. We present a lunar lander mission with two related objectives: a lunar lander equipped with Raman and PanCam instruments which can analyze the lunar surface and survey an astrobiological exposure platform. This dual use of testing mission technology together with geo- and astrobiological analyses will significantly increase the science return, and support the human preparation objectives. It will provide knowledge about the Moon's surface itself and, in addition, monitor the stability of life-markers, such as cells, cell components and pigments, in an extraterrestrial environment with much closer radiation properties to the surface of Mars. The combination of a Raman data base of these data together with data from LEO and space simulation experiments, will lead to further progress on the analysis and interpretation of data that we will obtain from future Moon and Mars exploration missions. KW - Moon KW - Mars KW - Low Earth Orbit KW - Astrobiology KW - Instrumentation KW - Spectroscopy KW - Biosignature Y1 - 2012 U6 - https://doi.org/10.1016/j.pss.2012.06.010 SN - 0032-0633 VL - 74 IS - 1 SP - 103 EP - 110 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - de Molina, Paula Malo A1 - Herfurth, Christoph A1 - Laschewsky, André A1 - Gradzielski, Michael T1 - Structure and dynamics of networks in mixtures of hydrophobically modified telechelic multiarm polymers and oil in water microemulsions JF - Langmuir N2 - The structural and dynamical properties of oil-in-water (O/W) microemulsions (MEs) modified with telechelic polymers of different functionality (e.g., number of hydrophobically modified arms, f) were studied by means of dynamic light scattering (DLS), small-angle neutron scattering (SANS), and high frequency rheology measurements as a function of the polymer architecture and the amount of added polymer. For this purpose, we employed tailor-made hydrophobically end-capped poly(N,N-dimethylacrylamide) star polymers of a variable number of endcaps, f, of different alkyl chain lengths, synthesized by the reversible addition-fragmentation chain transfer method. The addition of the different end-capped polymers to an uncharged ME of O/W droplets leads to a large enhancement of the viscosity of the systems. SANS experiments show that the O/W ME droplets are not changed upon the addition of the polymer, and its presence only changes the interdroplet interactions. The viscosity increases largely upon addition of a polymer, and this enhancement depends pronouncedly on the alkyl length of the hydrophobic sticker as it controls the residence time in a ME droplet. Similarly, the high frequency modulus G(0) depends on the amount of added polymer but not on the sticker length. G(0) was found to be directly proportional to f - 1. The onset of network formation is shifted to a lower number of stickers per ME droplet with increasing f, and the network formation becomes more effective. Thus, the dynamics of network formation are controlled by the polymer architecture. The effect on the dynamics seen by DLS is even more pronounced. Upon increasing the polymer concentration, slower relaxation modes appear that become especially pronounced with increasing number of arms. The relaxation dynamics are correlated to the rheological relaxation, and both are controlled by the polymer architecture. Y1 - 2012 U6 - https://doi.org/10.1021/la303673a SN - 0743-7463 VL - 28 IS - 45 SP - 15994 EP - 16006 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - De Frenne, Pieter A1 - Graae, Bente J. A1 - Brunet, Jörg A1 - Shevtsova, Anna A1 - De Schrijver, An A1 - Chabrerie, Olivier A1 - Cousins, Sara A. O. A1 - Decocq, Guillaume A1 - Diekmann, Martin A1 - Hermy, Martin A1 - Heinken, Thilo A1 - Kolb, Annette A1 - Nilsson, Christer A1 - Stanton, Sharon A1 - Verheyen, Kris T1 - The response of forest plant regeneration to temperature variation along a latitudinal gradient JF - Annals of botany N2 - The response of forest herb regeneration from seed to temperature variations across latitudes was experimentally assessed in order to forecast the likely response of understorey community dynamics to climate warming. Seeds of two characteristic forest plants (Anemone nemorosa and Milium effusum) were collected in natural populations along a latitudinal gradient from northern France to northern Sweden and exposed to three temperature regimes in growth chambers (first experiment). To test the importance of local adaptation, reciprocal transplants were also made of adult individuals that originated from the same populations in three common gardens located in southern, central and northern sites along the same gradient, and the resulting seeds were germinated (second experiment). Seedling establishment was quantified by measuring the timing and percentage of seedling emergence, and seedling biomass in both experiments. Spring warming increased emergence rates and seedling growth in the early-flowering forb A. nemorosa. Seedlings of the summer-flowering grass M. effusum originating from northern populations responded more strongly in terms of biomass growth to temperature than southern populations. The above-ground biomass of the seedlings of both species decreased with increasing latitude of origin, irrespective of whether seeds were collected from natural populations or from the common gardens. The emergence percentage decreased with increasing home-away distance in seeds from the transplant experiment, suggesting that the maternal plants were locally adapted. Decreasing seedling emergence and growth were found from the centre to the northern edge of the distribution range for both species. Stronger responses to temperature variation in seedling growth of the grass M. effusum in the north may offer a way to cope with environmental change. The results further suggest that climate warming might differentially affect seedling establishment of understorey plants across their distribution range and thus alter future understorey plant dynamics. KW - Anemone nemorosa KW - climate change KW - common garden KW - growth chambers KW - latitudinal gradient KW - local adaptation KW - Milium effusum KW - plant regeneration KW - range edges KW - recruitment KW - seedling establishment KW - temperature Y1 - 2012 U6 - https://doi.org/10.1093/aob/mcs015 SN - 0305-7364 VL - 109 IS - 5 SP - 1037 EP - 1046 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - De Biase, Cecilia A1 - Maier, Uli A1 - Baeder-Bederski, Oliver A1 - Bayer, Peter A1 - Oswald, Sascha A1 - Thullner, Martin T1 - Removal of volatile organic compounds in vertical flow filters - predictions from reactive transport modeling JF - Ground water monitoring & remediation N2 - Vertical flow filters are containers filled with porous medium that are recharged from top and drained at the bottom, and are operated at partly saturated conditions. They have recently been suggested as treatment technology for groundwater containing volatile organic compounds (VOCs). Numerical reactive transport simulations were performed to investigate the relevance of different filter operation modes on biodegradation and/or volatilization of the contaminants and to evaluate the potential limitation of such remediation mean due to volatile emissions. On the basis of the data from a pilot-scale vertical flow filter intermittently fed with domestic waste water, model predictions on the systems performance for the treatment of contaminated groundwater were derived. These simulations considered the transport and aerobic degradation of ammonium and two VOCs, benzene and methyl tertiary butyl ether (MTBE). In addition, the advective-diffusive gas-phase transport of volatile compounds as well as oxygen was simulated. Model predictions addressed the influence of depth and frequency of the intermittent groundwater injection, degradation rate kinetics, and the composition of the filter material. Simulation results show that for unfavorable operation conditions significant VOC emissions have to be considered and that operation modes limiting VOC emissions may limit aerobic biodegradation. However, a suitable combination of injection depth and composition of the filter material does facilitate high biodegradation rates while only little VOC emissions take place. Using such optimized operation modes would allow using vertical flow filter systems as remediation technology suitable for groundwater contaminated with volatile compounds. Y1 - 2012 U6 - https://doi.org/10.1111/j.1745-6592.2011.01374.x SN - 1069-3629 VL - 32 IS - 2 SP - 106 EP - 121 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Darcy, Isabelle A1 - Krüger, Franziska T1 - Vowel perception and production in Turkish children acquiring L2 German JF - Journal of phonetics N2 - First language (L1) phonological categories strongly influence late learners' perception and production of second language (L2) categories. For learners who start learning an L2 early in life ("early learners"), this L1 influence appears to be substantially reduced or at least more variable. In this paper, we examine the age at which L1 vowel categories influence the acquisition of L2 vowels. We tested a child population with a very narrow range of age of first exposure, controlling for the use of L1 vs. L2, and various naturally produced contrasts that are not allophonic in the L1 of the children. An oddity discrimination task provided evidence that children who are native speakers of Turkish and began learning German as an L2 in kindergarten categorized difficult German contrasts differently from age-matched native speakers. Their vowel productions of these same contrasts (un-cued object naming) were mostly target-like. Y1 - 2012 U6 - https://doi.org/10.1016/j.wocn.2012.05.001 SN - 0095-4470 VL - 40 IS - 4 SP - 568 EP - 581 PB - Elsevier CY - London ER - TY - JOUR A1 - Dambacher, Michael A1 - Dimigen, Olaf A1 - Braun, Mario A1 - Wille, Kristin A1 - Jacobs, Arthur M. A1 - Kliegl, Reinhold T1 - Stimulus onset asynchrony and the timeline of word recognition: Event-related potentials during sentence reading JF - Neuropsychologia : an international journal in behavioural and cognitive neuroscience N2 - Three ERP experiments examined the effect of word presentation rate (i.e., stimulus onset asynchrony, SOA) on the time course of word frequency and predictability effects in sentence reading. In Experiments 1 and 2, sentences were presented word-by-word in the screen center at an SOA of 700 and 490 ms, respectively. While these rates are typical for psycholinguistic ERP research, natural reading happens at a considerably faster pace. Accordingly. Experiment 3 employed a near-normal SOA of 280 ms, which approximated the rate of normal reading. Main results can be summarized as follows: (1) The onset latency of early frequency effects decreases gradually with increasing presentation rates. (2) An early interaction between top-down and bottom-up processing is observed only under a near-normal SOA. (3) N400 predictability effects occur later and are smaller at a near-normal (i.e., high) presentation rate than at the lower rates commonly used in ERP experiments. (4) ERP morphology is different at the shortest compared to longer SOAs. Together, the results point to a special role of a near-normal presentation rate for visual word recognition and therefore suggest that SOA should be taken into account in research of natural reading. KW - Word recognition KW - Sentence reading KW - Stimulus onset asynchrony (SOA) KW - Frequency KW - Predictability KW - Event-related potentials (ERPs) Y1 - 2012 U6 - https://doi.org/10.1016/j.neuropsychologia.2012.04.011 SN - 0028-3932 VL - 50 IS - 8 SP - 1852 EP - 1870 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Daig, Isolde A1 - Mahlberg, Richard A1 - Stethin, Julia A1 - Shroeder, Franziska A1 - Wrase, Jana A1 - Knoll, Nina A1 - Bschor, Tom A1 - Esser, Günter A1 - Heinz, Andreas A1 - Kienast, Thorsten T1 - Decreased verbal learning but not recognition performance in alcohol-dependent individuals during early abstinence Y1 - 2012 ER - TY - JOUR A1 - D'Aprile, Iwan-Michelangelo A1 - Zimmermann, Matthias A1 - Jäger, Sophie A1 - Horn-Conrad, Antje A1 - Eckardt, Barbara A1 - Voigt, Juliane A1 - Görlich, Petra T1 - Portal = Friedrich der Große: Zwischen Legende und Wirklichkeit BT - Das Potsdamer Universitätsmagazin N2 - Aus dem Inhalt: - Friedrich der Große: Zwischen Legende und Wirklichkeit - Inseln im Büchermeer - Wenn das Universum beschleunigt expandiert T3 - Portal: Das Potsdamer Universitätsmagazin - 01/2012 Y1 - 2012 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-440464 SN - 1618-6893 IS - 01/2012 ER - TY - JOUR A1 - D'Aprile, Iwan-Michelangelo T1 - Europe in the mirror of the world global historie in the German enlightenment Y1 - 2012 SN - 978-83-7842-018-7 ER - TY - JOUR A1 - Cubitt, Toby S. A1 - Eisert, Jens A1 - Wolf, Michael M. T1 - The complexity of relating quantum channels to master equations JF - Communications in mathematical physics N2 - Completely positive, trace preserving (CPT) maps and Lindblad master equations are both widely used to describe the dynamics of open quantum systems. The connection between these two descriptions is a classic topic in mathematical physics. One direction was solved by the now famous result due to Lindblad, Kossakowski, Gorini and Sudarshan, who gave a complete characterisation of the master equations that generate completely positive semi-groups. However, the other direction has remained open: given a CPT map, is there a Lindblad master equation that generates it (and if so, can we find its form)? This is sometimes known as the Markovianity problem. Physically, it is asking how one can deduce underlying physical processes from experimental observations. We give a complexity theoretic answer to this problem: it is NP-hard. We also give an explicit algorithm that reduces the problem to integer semi-definite programming, a well-known NP problem. Together, these results imply that resolving the question of which CPT maps can be generated by master equations is tantamount to solving P = NP: any efficiently computable criterion for Markovianity would imply P = NP; whereas a proof that P = NP would imply that our algorithm already gives an efficiently computable criterion. Thus, unless P does equal NP, there cannot exist any simple criterion for determining when a CPT map has a master equation description. However, we also show that if the system dimension is fixed (relevant for current quantum process tomography experiments), then our algorithm scales efficiently in the required precision, allowing an underlying Lindblad master equation to be determined efficiently from even a single snapshot in this case. Our work also leads to similar complexity-theoretic answers to a related long-standing open problem in probability theory. Y1 - 2012 U6 - https://doi.org/10.1007/s00220-011-1402-y SN - 0010-3616 VL - 310 IS - 2 SP - 383 EP - 418 PB - Springer CY - New York ER - TY - JOUR A1 - Csütörtöki, Renata A1 - Szatmari, Istvan A1 - Koch, Andreas A1 - Heydenreich, Matthias A1 - Kleinpeter, Erich A1 - Fulop, Ferenc T1 - Syntheses and conformational analyses of new naphth[1,2-e][1,3]oxazino[3,2-c] quinazolin-13-ones JF - Tetrahedron N2 - The syntheses of naphth[1,2-e][1,3]oxazino[3,2-c]quinazolin-13-one derivatives (3a-f) were achieved by the solvent-free heating of benzyloxycarbonyl-protected intermediates (2a-f) with MeONa. For intermediates 2a-f, prepared by the reactions of substituted aminonaphthols with benzyl N-(2-formylphenyl)carbamate, not only the expected trans ring form B and chain form A(1), but also the rearranged chain form A(2) as a new tautomer were detected in DMSO at room temperature. The quantity of A(2) in the tautomeric mixture was changed with time. Conformational analyses of the target heterocycles 3a-f by NMR spectroscopy and accompanying theoretical calculations at the DFT level of theory revealed that the oxazine ring preferred a twisted chair conformation and the quinazolone ring was planar. Besides the conformations, both the configurations at C-7a and C-15 and the preferred rotamers of the 1-naphthyl substituent at C-15 were assigned, which allowed evaluation of the aryl substituent-dependent steric hindrance in this part of the molecules. Configurational assignments were corroborated by quantifying the ring current effect of 15-aryl in terms of spatial NICS. KW - Naphthoxazinoquinazolinones KW - Aminonaphthols KW - NMR spectroscopy KW - Conformational analysis KW - Theoretical calculations KW - Ring current effect Y1 - 2012 U6 - https://doi.org/10.1016/j.tet.2012.04.026 SN - 0040-4020 VL - 68 IS - 24 SP - 4600 EP - 4608 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Csuetoertoeki, Renata A1 - Szatmari, Istvan A1 - Heydenreich, Matthias A1 - Koch, Andreas A1 - Starke, Ines A1 - Fueloep, Ferenc A1 - Kleinpeter, Erich T1 - Novel piperidine-fused benzoxazino- and quinazolinonaphthoxazines-synthesis and conformational study JF - TETRAHEDRON N2 - The reactions of 1-(amino(2-hydroxyphenyl)methyl)-2-naphthol (3) and 1-(amino(2-aminophenyl) methyl)-2-naphthol (6) with glutardialdehyde resulted in the formation of piperidine-fused benzox-azinonaphthoxazine 4 and quinazolinonaphthoxazine 7, respectively, both in diastereopure form. The full conformational search protocols of 4 and 7 were successfully carried out by NMR spectroscopy and accompanying molecular modelling; the global minimum-energy conformers of all diastereomers were computed, and the assignments of the most stable stereoisomers, G(tct)(1) for 4 and G(tct)(1) for 7, were corroborated by spatial NOE information relating to the H-7a-H-10a-H-15b and H,H coupling patterns of the protons in the flexible part of the piperidine moiety. Additionally, mass spectrometric fragmentation was investigated in collision-induced dissociation experiments. The elemental compositions of the ions were determined by accurate mass measurements. (C) 2012 Elsevier Ltd. All rights reserved. KW - Quinazolines KW - Naphthoxazines KW - DFT structural study KW - Conformational analysis KW - NMR spectroscopy Y1 - 2012 U6 - https://doi.org/10.1016/j.tet.2012.05.048 SN - 0040-4020 VL - 68 IS - 31 SP - 6284 EP - 6288 PB - PERGAMON-ELSEVIER SCIENCE LTD CY - OXFORD ER - TY - JOUR A1 - Coy-Barrera, Ericsson D. A1 - Cuca-Suarez, Luis E. A1 - Sefkow, Michael A1 - Schilde, Uwe T1 - Cinerin C: a macrophyllin-type bicyclo[3.2.1]octane neolignan from Pleurothyrium cinereum (Lauraceae) JF - Acta crystallographica : Section C, Crystal structure communications N2 - The structure of naturally-occurring cinerin C [systematic name: (7S,8R,3'R,4'S,5'R)-Delta(8')-4'-hydroxy-5,5',3'-trimethoxy-3,4-methylenedioxy-2',3',4',5'-tetrahydro-2'-oxo-7.3',8.5'-neolignan], isolated from the ethanol extract of leaves of Pleurothyrium cinereum (Lauraceae), has previously been established by NMR and HRMS spectroscopy, and its absolute configuration established by circular dichroism measurements. For the first time, its crystal strucure has now been established by single-crystal X-ray analysis, as the monohydrate, C22H26O7 center dot H2O. The bicyclooctane moiety comprises fused cyclopentane and cyclohexenone rings which are almost coplanar. An intermolecular O-H center dot center dot center dot O hydrogen bond links the 4'-OH and 5'-OCH3 groups along the c axis. Y1 - 2012 U6 - https://doi.org/10.1107/S0108270112030946 SN - 0108-2701 VL - 68 IS - 2 SP - O320 EP - + PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Costa, Alexandre Cunha A1 - Bronstert, Axel A1 - Kneis, David T1 - Probabilistic flood forecasting for a mountainous headwater catchment using a nonparametric stochastic dynamic approach JF - Hydrological sciences journal = Journal des sciences hydrologiques N2 - Hydrological models are commonly used to perform real-time runoff forecasting for flood warning. Their application requires catchment characteristics and precipitation series that are not always available. An alternative approach is nonparametric modelling based only on runoff series. However, the following questions arise: Can nonparametric models show reliable forecasting? Can they perform as reliably as hydrological models? We performed probabilistic forecasting one, two and three hours ahead for a runoff series, with the aim of ascribing a probability density function to predicted discharge using time series analysis based on stochastic dynamics theory. The derived dynamic terms were compared to a hydrological model, LARSIM. Our procedure was able to forecast within 95% confidence interval 1-, 2- and 3-h ahead discharge probability functions with about 1.40 m(3)/s of range and relative errors (%) in the range [-30; 30]. The LARSIM model and the best nonparametric approaches gave similar results, but the range of relative errors was larger for the nonparametric approaches. KW - streamflow probabilistic forecasting KW - time series analysis KW - stochastic dynamical systems KW - parametric and nonparametric comparison Y1 - 2012 U6 - https://doi.org/10.1080/02626667.2011.637043 SN - 0262-6667 VL - 57 IS - 1 SP - 10 EP - 25 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Costa, A. C. A1 - Bronstert, Axel A1 - de Araujo, Jose Carlos T1 - A channel transmission losses model for different dryland rivers JF - Hydrology and earth system sciences : HESS N2 - Channel transmission losses in drylands take place normally in extensive alluvial channels or streambeds underlain by fractured rocks. They can play an important role in streamflow rates, groundwater recharge, freshwater supply and channel-associated ecosystems. We aim to develop a process-oriented, semi-distributed channel transmission losses model, using process formulations which are suitable for data-scarce dryland environments and applicable to both hydraulically disconnected losing streams and hydraulically connected losing(/gaining) streams. This approach should be able to cover a large variation in climate and hydro-geologic controls, which are typically found in dryland regions of the Earth. Our model was first evaluated for a losing/gaining, hydraulically connected 30 km reach of the Middle Jaguaribe River (MJR), Ceara, Brazil, which drains a catchment area of 20 000 km(2). Secondly, we applied it to a small losing, hydraulically disconnected 1.5 km channel reach in the Walnut Gulch Experimental Watershed (WGEW), Arizona, USA. The model was able to predict reliably the streamflow volume and peak for both case studies without using any parameter calibration procedure. We have shown that the evaluation of the hypotheses on the dominant hydrological processes was fundamental for reducing structural model uncertainties and improving the streamflow prediction. For instance, in the case of the large river reach (MJR), it was shown that both lateral stream-aquifer water fluxes and groundwater flow in the underlying alluvium parallel to the river course are necessary to predict streamflow volume and channel transmission losses, the former process being more relevant than the latter. Regarding model uncertainty, it was shown that the approaches, which were applied for the unsaturated zone processes (highly nonlinear with elaborate numerical solutions), are much more sensitive to parameter variability than those approaches which were used for the saturated zone (mathematically simple water budgeting in aquifer columns, including backwater effects). In case of the MJR-application, we have seen that structural uncertainties due to the limited knowledge of the subsurface saturated system interactions (i.e. groundwater coupling with channel water; possible groundwater flow parallel to the river) were more relevant than those related to the subsurface parameter variability. In case of the WEGW application we have seen that the non-linearity involved in the unsaturated flow processes in disconnected dryland river systems (controlled by the unsaturated zone) generally contain far more model uncertainties than do connected systems controlled by the saturated flow. Therefore, the degree of aridity of a dryland river may be an indicator of potential model uncertainty and subsequent attainable predictability of the system. Y1 - 2012 U6 - https://doi.org/10.5194/hess-16-1111-2012 SN - 1027-5606 VL - 16 IS - 4 SP - 1111 EP - 1135 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Cosentino, Domenico A1 - Schildgen, Taylor F. A1 - Cipollari, Paola A1 - Faranda, Costanza A1 - Gliozzi, Elsa A1 - Hudackova, Natalia A1 - Lucifora, Stella A1 - Strecker, Manfred T1 - Late Miocene surface uplift of the southern margin of the Central Anatolian Plateau, Central Taurides, Turkey JF - Geological Society of America bulletin N2 - The timing and pattern of surface uplift of Miocene marine sediments capping the southern margin of the Central Anatolian Plateau in southern Turkey provide a first-order constraint on possible mechanisms of regional uplift. Nannofossil, ostracod, and planktic foraminifera biostratigraphy of the Basyayla section (Mut-Ermenek Basin) within the Mut and Kfiselerli Formations suggests a Tortonian age for marine sediments unconformably capping basement rocks at 2 km elevation. The identification of biozone MMi 12a (7.81-8.35 Ma) from planktic foraminifera in the upper part of the section provides the tightest constraint on the age, which is further limited to 8.35-8.108 Ma as a result of the reverse polarity of the collected samples (chron 4r.1 r or 4r.2r). This provides a limiting age for the onset of surface uplift at the margin of one of the world's major orogenic plateaus, from which an average uplift rate of 0.24-0.25 mm/yr can be calculated. Subhorizontal beds of the uppermost marine sediments exposed throughout the Mut-Ermenek Basin suggest minimal localized deformation, with just minor faulting at the basin margin and broad antiformal deformation across the basin. This implies that the post-8 Ma uplift mechanism must be rooted deep within the crust or in the upper mantle. Published Pn-wave velocity data for the region are compatible with topography compensated by asthenosphere across the southern margin of the plateau, showing a close match to the highest topography when elevations are filtered with a 100-km-wide smoothing window. Uplift along the southern margin of the Central Anatolian Plateau is also reflected by the pattern of Miocene marine sediments capping the margin, which form an asymmetric drape fold over the topography. These observations, together with tomographic evidence for slab steepening and break-off beneath the Eastern Anatolian Plateau, suggest that at least some of the 2 km of post-8 Ma uplift of the southern Central Anatolian Plateau margin is compensated by low-density asthenospheric mantle that upwelled following slab break-off. Y1 - 2012 U6 - https://doi.org/10.1130/B30466.1 SN - 0016-7606 VL - 124 IS - 1-2 SP - 133 EP - 145 PB - American Institute of Physics CY - Boulder ER - TY - JOUR A1 - Collings, R. A1 - Lange, Dietrich A1 - Rietbrock, Andreas A1 - Tilmann, F. A1 - Natawidjaja, D. A1 - Suwargadi, B. A1 - Miller, M. A1 - Saul, Joschim T1 - Structure and seismogenic properties of the Mentawai segment of the Sumatra subduction zone revealed by local earthquake traveltime tomography JF - Journal of geophysical research : Solid earth N2 - On 12 September 2007, an M-w 8.4 earthquake occurred within the southern section of the Mentawai segment of the Sumatra subduction zone, where the subduction thrust had previously ruptured in 1833 and 1797. Traveltime data obtained from a temporary local seismic network, deployed between December 2007 and October 2008 to record the aftershocks of the 2007 event, was used to determine two-dimensional (2-D) and three-dimensional (3-D) velocity models of the Mentawai segment. The seismicity distribution reveals significant activity along the subduction interface and within two clusters in the overriding plate either side of the forearc basin. The downgoing slab is clearly distinguished by a dipping region of high Vp (8.0 km/s), which can be a traced to similar to 50 km depth, with an increased Vp/Vs ratio (1.75 to 1.90) beneath the islands and the western side of the forearc basin, suggesting hydrated oceanic crust. Above the slab, a shallow continental Moho of less than 30 km depth can be inferred, suggesting that the intersection of the continental mantle with the subducting slab is much shallower than the downdip limit of the seismogenic zone despite localized serpentinization being present at the toe of the mantle wedge. The outer arc islands are characterized by low Vp (4.5-5.8 km/s) and high Vp/Vs (greater than 2.0), suggesting that they consist of fluid saturated sediments. The very low rigidity of the outer forearc contributed to the slow rupture of the M-w 7.7 Mentawai tsunami earthquake on 25 October 2010. Y1 - 2012 U6 - https://doi.org/10.1029/2011JB008469 SN - 2169-9313 SN - 2169-9356 VL - 117 IS - 3 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Colas, Helene A1 - Ewen, Kerstin M. A1 - Hannemann, Frank A1 - Bistolas, Nikitas A1 - Wollenberger, Ursula A1 - Bernhardt, Rita A1 - de Oliveira, Pedro T1 - Direct and mediated electrochemical response of the cytochrome P450 106A2 from Bacillus megaterium ATCC 13368 JF - Bioelectrochemistry : an international journal devoted to electrochemical aspects of biology and biological aspects of electrochemistry ; official journal of the Bioelectrochemical Society N2 - CYP106A2 is one of only a few known steroid hydroxylases of bacterial origin, which might be interesting for biotechnological applications. Despite the enzyme having been studied for more than 30 years, its physiological function remains elusive. To date, there have been no reports of the redox potential of CYP106A2, which was supposed to be unusually low for a cytochrome P450. In this work we show that cyclic voltammetry is not only suitable to determine the redox potential of challenging proteins such as CYP106A2, measured at - 128 mV vs. NHE, but also to study molecular interactions of the enzyme with different interaction partners via the respective electrochemical responses. The effect of small ligands, such as carbon monoxide and cyanide, was observed on the cyclic voltammograms of CYP106A2. Furthermore, we found that Tween 80 caused a positive shift of the redox potential of immobilised CYP106A2 indicative for water expulsion from the haem environment. Moreover, electron transfer mediation phenomena with biological redox partners (e.g. ferredoxins) were studied. Finally, the influence of two different kinds of substrates on the electrochemical response of CYP106A2 was assessed, aligning observations from spectral and electrochemical studies. KW - Cytochrome P450 KW - Cyclic voltammetry KW - Modified electrode KW - Protein interaction KW - Substrate binding Y1 - 2012 U6 - https://doi.org/10.1016/j.bioelechem.2012.01.006 SN - 1567-5394 VL - 87 IS - 5 SP - 71 EP - 77 PB - Elsevier CY - Lausanne ER - TY - JOUR A1 - Coelho, Catarina A1 - Mahro, Martin A1 - Trincao, Jose A1 - Carvalho, Alexandra T. P. A1 - Ramos, Maria Joao A1 - Terao, Mineko A1 - Garattini, Enrico A1 - Leimkühler, Silke A1 - Romao, Maria Joao T1 - The first mammalian aldehyde oxidase crystal structure insights into substrate specificity JF - The journal of biological chemistry N2 - Aldehyde oxidases (AOXs) are homodimeric proteins belonging to the xanthine oxidase family of molybdenum-containing enzymes. Each 150-kDa monomer contains a FAD redox cofactor, two spectroscopically distinct [2Fe-2S] clusters, and a molybdenum cofactor located within the protein active site. AOXs are characterized by broad range substrate specificity, oxidizing different aldehydes and aromatic N-heterocycles. Despite increasing recognition of its role in the metabolism of drugs and xenobiotics, the physiological function of the protein is still largely unknown. We have crystallized and solved the crystal structure of mouse liver aldehyde oxidase 3 to 2.9 angstrom. This is the first mammalian AOX whose structure has been solved. The structure provides important insights into the protein active center and further evidence on the catalytic differences characterizing AOX and xanthine oxidoreductase. The mouse liver aldehyde oxidase 3 three-dimensional structure combined with kinetic, mutagenesis data, molecular docking, and molecular dynamics studies make a decisive contribution to understand the molecular basis of its rather broad substrate specificity. Y1 - 2012 U6 - https://doi.org/10.1074/jbc.M112.390419 SN - 0021-9258 VL - 287 IS - 48 SP - 40690 EP - 40702 PB - American Society for Biochemistry and Molecular Biology CY - Bethesda ER - TY - JOUR A1 - Cockell, Charles S. A1 - Voytek, Mary A. A1 - Gronstal, Aaron L. A1 - Finster, Kai A1 - Kirshtein, Julie D. A1 - Howard, Kieren A1 - Reitner, Joachim A1 - Gohn, Gregory S. A1 - Sanford, Ward E. A1 - Horton, J. Wright A1 - Kallmeyer, Jens A1 - Kelly, Laura A1 - Powars, David S. T1 - Impact disruption and recovery of the deep subsurface biosphere JF - Astrobiology N2 - Although a large fraction of the world's biomass resides in the subsurface, there has been no study of the effects of catastrophic disturbance on the deep biosphere and the rate of its subsequent recovery. We carried out an investigation of the microbiology of a 1.76 km drill core obtained from the similar to 35 million-year-old Chesapeake Bay impact structure, USA, with robust contamination control. Microbial enumerations displayed a logarithmic downward decline, but the different gradient, when compared to previously studied sites, and the scatter of the data are consistent with a rnicrobiota influenced by the geological disturbances caused by the impact. Microbial abundance is low in buried crater-fill, ocean-resurge, and avalanche deposits despite the presence of redox couples for growth. Coupled with the low hydraulic conductivity, the data suggest the microbial community has not yet recovered from the impact similar to 35 million years ago. Microbial enumerations, molecular analysis of microbial enrichment cultures, and geochemical analysis showed recolonization of a deep region of impact-fractured rock that was heated to above the upper temperature limit for life at the time of impact. These results show how, by fracturing subsurface rocks, impacts can extend the depth of the biosphere. This phenomenon would have provided deep refugia for life on the more heavily bombarded early Earth, and it shows that the deeply fractured regions of impact craters are promising targets to study the past and present habitability of Mars. KW - Asteroid KW - Impacts KW - Subsurface biosphere KW - Subterranean environment KW - Geobiology Y1 - 2012 U6 - https://doi.org/10.1089/ast.2011.0722 SN - 1531-1074 VL - 12 IS - 3 SP - 231 EP - 246 PB - Liebert CY - New Rochelle ER - TY - JOUR A1 - Clegg, Mark R. A1 - Gaedke, Ursula A1 - Böhrer, Bertram A1 - Spijkerman, Elly T1 - Complementary ecophysiological strategies combine to facilitate survival in the hostile conditions of a deep chlorophyll maximum JF - Oecologia N2 - In the deep, cooler layers of clear, nutrient-poor, stratified water bodies, phytoplankton often accumulate to form a thin band or "deep chlorophyll maximum" (DCM) of ecological importance. Under such conditions, these photosynthetic microorganisms may be close to their physiological compensation points and to the boundaries of their ecological tolerance. To grow and survive any resulting energy limitation, DCM species are thought to exhibit highly specialised or flexible acclimation strategies. In this study, we investigated several of the adaptable ecophysiological strategies potentially employed by one such species, Chlamydomonas acidophila: a motile, unicellular, phytoplanktonic flagellate that often dominates the DCM in stratified, acidic lakes. Physiological and behavioural responses were measured in laboratory experiments and were subsequently related to field observations. Results showed moderate light compensation points for photosynthesis and growth at 22A degrees C, relatively low maintenance costs, a behavioural preference for low to moderate light, and a decreased compensation point for photosynthesis at 8A degrees C. Even though this flagellated alga exhibited a physiologically mediated diel vertical migration in the field, migrating upwards slightly during the day, the ambient light reaching the DCM was below compensation points, and so calculations of daily net photosynthetic gain showed that survival by purely autotrophic means was not possible. Results suggested that strategies such as low-light acclimation, small-scale directed movements towards light, a capacity for mixotrophic growth, acclimation to low temperature, in situ exposure to low O-2, high CO2 and high P concentrations, and an avoidance of predation, could combine to help overcome this energetic dilemma and explain the occurrence of the DCM. Therefore, corroborating the deceptive ecophysiological complexity of this and similar organisms, only a suite of complementary strategies can facilitate the survival of C. acidophila in this DCM. KW - DCM KW - Photosynthesis KW - Growth KW - Behaviour KW - Phytoplankton Y1 - 2012 U6 - https://doi.org/10.1007/s00442-011-2225-4 SN - 0029-8549 VL - 169 IS - 3 SP - 609 EP - 622 PB - Springer CY - New York ER - TY - JOUR A1 - Clahsen, Harald A1 - Hansen, Detlef T1 - Profiling linguistic disability in German-speaking children JF - Assessing Grammar : the Languages of LARSP Y1 - 2012 SN - 978-1-8476-9639-7 U6 - https://doi.org/10.21832/9781847696397-007 SP - 77 EP - 91 PB - Multilingual Matters CY - Bristol ER - TY - JOUR A1 - Ciobanu, M. -C. A1 - Rabineau, M. A1 - Droz, L. A1 - Revillon, S. A1 - Ghiglione, J. -F. A1 - Dennielou, B. A1 - Jorry, S. -J. A1 - Kallmeyer, Jens A1 - Etoubleau, J. A1 - Pignet, P. A1 - Crassous, P. A1 - Vandenabeele-Trambouze, O. A1 - Laugier, J. A1 - Guegan, M. A1 - Godfroy, A. A1 - Alain, K. T1 - Sedimentological imprint on subseafloor microbial communities in Western Mediterranean Sea Quaternary sediments JF - Biogeosciences N2 - An interdisciplinary study was conducted to evaluate the relationship between geological and paleoenvironmental parameters and the bacterial and archaeal community structure of two contrasting subseafloor sites in the Western Mediterranean Sea (Ligurian Sea and Gulf of Lion). Both depositional environments in this area are well-documented from paleoclimatic and paleooceanographic point of views. Available data sets allowed us to calibrate the investigated cores with reference and dated cores previously collected in the same area, and notably correlated to Quaternary climate variations. DNA-based fingerprints showed that the archaeal diversity was composed by one group, Miscellaneous Crenarchaeotic Group (MCG), within the Gulf of Lion sediments and of nine different lineages (dominated by MCG, South African Gold Mine Euryarchaeotal Group (SAGMEG) and Halobacteria) within the Ligurian Sea sediments. Bacterial molecular diversity at both sites revealed mostly the presence of the classes Alphaproteobacteria, Betaproteobacteria and Gammaproteobacteria within Proteobacteria phylum, and also members of Bacteroidetes phylum. The second most abundant lineages were Actinobacteria and Firmicutes at the Gulf of Lion site and Chloroflexi at the Ligurian Sea site. Various substrates and cultivation conditions allowed us to isolate 75 strains belonging to four lineages: Alpha-, Gammaproteobacteria, Firmicutes and Actinobacteria. In molecular surveys, the Betaproteobacteria group was consistently detected in the Ligurian Sea sediments, characterized by a heterolithic facies with numerous turbidites from a deep-sea levee. Analysis of relative betaproteobacterial abundances and turbidite frequency suggested that the microbial diversity was a result of main climatic changes occurring during the last 20 ka. Statistical direct multivariate canonical correspondence analyses (CCA) showed that the availability of electron acceptors and the quality of electron donors (indicated by age) strongly influenced the community structure. In contrast, within the Gulf of Lion core, characterized by a homogeneous lithological structure of upper-slope environment, most detected groups were Bacteroidetes and, to a lesser extent, Betaproteobacteria. At both site, the detection of Betaproteobacteria coincided with increased terrestrial inputs, as confirmed by the geochemical measurements (Si, Sr, Ti and Ca). In the Gulf of Lion, geochemical parameters were also found to drive microbial community composition. Taken together, our data suggest that the palaeoenvironmental history of erosion and deposition recorded in the Western Mediterranean Sea sediments has left its imprint on the sedimentological context for microbial habitability, and then indirectly on structure and composition of the microbial communities during the late Quaternary. Y1 - 2012 U6 - https://doi.org/10.5194/bg-9-3491-2012 SN - 1726-4170 VL - 9 IS - 9 SP - 3491 EP - 3512 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Chupeerach, Chaowanee A1 - Tungtrongchitr, Anchalee A1 - Phonrat, Benjaluck A1 - Schweigert, Florian J. A1 - Tungtrongchitr, Rungsunn A1 - Preutthipan, Sangchai T1 - Association of Thr420Lys polymorphism in DBP gene with fat-soluble vitamins and low radial bone mineral density in postmenopausal Thai women JF - Biomarkers in medicine N2 - Aims: To investigate the genetic markers for osteoporosis bone mineral density by the genotyping of rs7041, rs4588 and rs1352845 in the DBP gene with either bone mineral density or serum 25-hydroxycholecalciferol, retinol and alpha-tocopherol, among 365 postmenopausal Thai women. Materials & methods: The DBP genotypes were analyzed by a PCR restriction fragment-length polymorphism method. Serum 25-hydroxycholecalciferol was assessed using a commercial chemiluminescent immunoassay. Serum retinol and alpha-tocopherol were measured by reverse-phase high-performance liquid chromatography. Results: After adjustment for age >50 years, elder Thai subjects with low BMI (<= 25 kg/m(2)) and carrying the rs4588 CC genotype had a higher risk of radial bone mineral density osteoporosis (odds ratio: 6.29; p = 0.048). The rs1352845 genotype also had a statistical association with total hip bone mineral density; however, it disappeared after adjustment for age and BMI. No association was found in fat-soluble vitamins with bone mineral density. Conclusion: DBP genotypes may influence the osteoporosis bone mineral density in postmenopausal Thai women. KW - bone mineral density KW - fat-soluble vitamin KW - osteoporosis KW - single nucleotide polymorphism KW - vitamin D binding protein Y1 - 2012 U6 - https://doi.org/10.2217/BMM.11.88 SN - 1752-0363 VL - 6 IS - 1 SP - 103 EP - 108 PB - Future Medicine CY - London ER - TY - JOUR A1 - Christian, Jan-Ole A1 - Braginets, Rostyslav A1 - Schulze, Waltraud X. A1 - Walther, Dirk T1 - Characterization and prediction of protein phosphorylation hotspots in Arabidopsis thaliana JF - Frontiers in plant science N2 - The regulation of protein function by modulating the surface charge status via sequence-locally enriched phosphorylation sites (P-sites) in so called phosphorylation "hotspots" has gained increased attention in recent years. We set out to identify P-hotspots in the model plant Arabidopsis thaliana. We analyzed the spacing of experimentally detected P-sites within peptide-covered regions along Arabidopsis protein sequences as available from the PhosPhAt database. Confirming earlier reports (Schweiger and Lanial, 2010), we found that, indeed, P-sites tend to cluster and that distributions between serine and threonine P-sites to their respected closest next P-site differ significantly from those for tyrosine P-sites. The ability to predict P-hotspots by applying available computational P-site prediction programs that focus on identifying single P-sites was observed to be severely compromised by the inevitable interference of nearby P-sites. We devised a new approach, named HotSPotter, for the prediction of phosphorylation hotspots. HotSPotter is based primarily on local amino acid compositional preferences rather than sequence position-specific motifs and uses support vector machines as the underlying classification engine. HotSPotter correctly identified experimentally determined phosphorylation hotspots in A. thaliana with high accuracy. Applied to the Arabidopsis proteome, HotSPotter-predicted 13,677 candidate P-hotspots in 9,599 proteins corresponding to 7,847 unique genes. Hotspot containing proteins are involved predominantly in signaling processes confirming the surmised modulating role of hotspots in signaling and interaction events. Our study provides new bioinformatics means to identify phosphorylation hotspots and lays the basis for further investigating novel candidate P-hotspots. All phosphorylation hotspot annotations and predictions have been made available as part of the PhosPhAt database at http://phosphat.mpimp-golm.mpg.de. KW - protein phosphorylation KW - hotspots KW - Arabidopsis thaliana KW - support vector machines KW - regulation Y1 - 2012 U6 - https://doi.org/10.3389/fpls.2012.00207 SN - 1664-462X VL - 3 PB - Frontiers Research Foundation CY - Lausanne ER - TY - JOUR A1 - Christ, Nicolas A1 - Immenhauser, Adrian A1 - Amour, Frederic A1 - Mutti, Maria A1 - Tomas, Sara A1 - Agar, Susan M. A1 - Alway, Robert A1 - Kabiri, Lahcen T1 - Characterization and interpretation of discontinuity surfaces in a Jurassic ramp setting (High Atlas, Morocco) JF - Sedimentology : the journal of the International Association of Sedimentologists N2 - Discontinuity surfaces are widely recognized but often poorly understood features of epeiric carbonate settings. In sedimentary systems, these features often represent hiatus surfaces below biostratigraphic resolution and may represent a considerable portion of the time contained in the sediment record. From an applied perspective, discontinuities may represent horizontal flow barriers and result in reservoir compartmentalization. Here, a total of 80 condensed surfaces (S1), firmgrounds (S2) and hardgrounds (S3) from a Jurassic (Middle and Upper Bajocian Assoul Formation) ramp setting of the High Atlas in Morocco are carefully documented with respect to their morphology, their secondary impregnation by Fe and Mn oxides and phosphates and their palaeoecological record. A statistical frequency distribution of two surfaces of the S1 type, 1.1 surfaces of the S2 type and 0.4 surfaces of the S3 type per 10 section metres is observed along a 220 m long carbonate succession. Based on two stratigraphically and spatially separated study windows and correlative sections, the stratigraphic frequency distribution, the lateral extent and the nature of facies change across discontinuities are documented in a quantitative manner. Specific features of the study site include the considerable stratigraphic thickness of the Assoul Formation and the conspicuous absence of subaerial-exposure-related features. Based on the data presented here, firmground and hardground surfaces are best interpreted as maximum-regression-related features. Relative sea-level lowstand results in a lowered wave base, and wave orbitals and currents result in sea floor omission and lithification. Care must be taken to avoid overly simplistic interpretations, as differences in bathymetry and carbonate facies result in marked changes in discontinuity characteristics in proximal-distal transects. The data shown here are of significance for those concerned with the interpretation of shoal water carbonate environments and are instrumental in the building of more realistic carbonate reservoir flow models. KW - Atlas Mountains KW - carbonate ramp KW - discontinuity surfaces KW - hardgrounds KW - hydrodynamic level KW - Jurassic KW - palaeoecology KW - relative sea-level Y1 - 2012 U6 - https://doi.org/10.1111/j.1365-3091.2011.01251.x SN - 0037-0746 VL - 59 IS - 1 SP - 249 EP - 290 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Christ, Nicolas A1 - Immenhauser, Adrian A1 - Amour, Frederic A1 - Mutti, Maria A1 - Preston, Rosalind A1 - Whitaker, Fiona F. A1 - Peterhänsel, Arndt A1 - Egenhoff, Sven O. A1 - Dunn, Paul A. A1 - Agar, Susan M. T1 - Triassic Latemar cycle tops - Subaerial exposure of platform carbonates under tropical arid climate JF - Sedimentary geology : international journal of applied and regional sedimentology N2 - The Triassic Latemar platform in the Dolomites, Italy, is the site of several ongoing controversies. Perhaps the most interesting debate focuses on apparent cyclic deposition within the Latemar platform, whose nature and duration are still open to debate. Further disagreement concerns the lack of meteoric diagenesis-related isotope shifts at cycle tops that bear circumstantial petrographic evidence for subaerial emergence. Here, an evaluation of the nature of Latemar cycle tops is presented combining evidence from previous work and new field, petrographic and geochemical data. Cycle tops are ranked according to increasing exposure duration and spatial extent: type I surfaces lacking unequivocal evidence of prolonged supratidal conditions; type II dolomite caps formed in warm, evaporitic, intertidal lagoonal waters followed by exposure of perhaps intermediate duration; type III clastic-rich, red calcareous horizons with some showing platform-wide extent, representing prolonged supratidal conditions, and type IV discontinuities in tepee belts, genetically related to type II and III surfaces, but likely representing shorter-lived exposure stages. Petrographic and geochemical criteria indicate that most diagenesis occurred in the shallow marine and burial domain whilst an extensive meteoric overprint of cycle tops is lacking. This is underlined by the scarcity of meteoric diagenetic fabrics such as gravitational cements that, where present, are here interpreted as marine-vadose in origin. The scarcity of carbon and oxygen isotope signatures commonly assigned to subaerial exposure stages is best explained in the context of mid-Triassic climate. The low latitude, tropical but arid setting of the Latemar, situated in the western extension of the Tethys ocean, its isolation from nearby continental areas and overall short-term emergence episodes are in agreement with a limited degree of meteoric alteration of most cycle tops. High amounts of aeolian clastic material beneath some cycle tops, along with high Fe and Mn elemental abundances argue for intermittent subaerial conditions. This study proposes an enhancement of the classical Allan and Matthews (1982) isotope model for subaerial exposure under strongly arid climates. As the subaerial exposure nature of Latemar cycle tops, and therefore eustasy as the cause for cyclicity, have been previously challenged due to the lack of meteoric-induced isotopic signatures, the outcome of this study is of significance for the ongoing Latemar stratigraphic controversy. KW - Triassic KW - Latemar KW - Subaerial exposure KW - Carbonate platforms KW - Carbon and oxygen stable isotopes KW - Diagenesis Y1 - 2012 U6 - https://doi.org/10.1016/j.sedgeo.2012.02.008 SN - 0037-0738 VL - 265 IS - 28 SP - 1 EP - 29 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Chowdhury, Mita Mullick A1 - Dosche, Carsten A1 - Loehmannsröben, Hans-Gerd A1 - Leimkühler, Silke T1 - Dual role of the molybdenum cofactor biosynthesis protein MOCS3 in tRNA thiolation and molybdenum cofactor biosynthesis in humans JF - The journal of biological chemistry N2 - We studied two pathways that involve the transfer of persulfide sulfur in humans, molybdenum cofactor biosynthesis and tRNA thiolation. Investigations using human cells showed that the two-domain protein MOCS3 is shared between both pathways. MOCS3 has an N-terminal adenylation domain and a C-terminal rhodanese-like domain. We showed that MOCS3 activates both MOCS2A and URM1 by adenylation and a subsequent sulfur transfer step for the formation of the thiocarboxylate group at the C terminus of each protein. MOCS2A and URM1 are beta-grasp fold proteins that contain a highly conserved C-terminal double glycine motif. The role of the terminal glycine of MOCS2A and URM1 was examined for the interaction and the cellular localization with MOCS3. Deletion of the C-terminal glycine of either MOCS2A or URM1 resulted in a loss of interaction with MOCS3. Enhanced cyan fluorescent protein and enhanced yellow fluorescent protein fusions of the proteins were constructed, and the fluorescence resonance energy transfer efficiency was determined by the decrease in the donor lifetime. The cellular localization results showed that extension of the C terminus with an additional glycine of MOCS2A and URM1 altered the localization of MOCS3 from the cytosol to the nucleus. Y1 - 2012 U6 - https://doi.org/10.1074/jbc.M112.351429 SN - 0021-9258 VL - 287 IS - 21 SP - 17297 EP - 17307 PB - American Society for Biochemistry and Molecular Biology CY - Bethesda ER - TY - JOUR A1 - Chiarcos, Christian A1 - Ritz, Julia A1 - Stede, Manfred T1 - By all these lovely tokens... Merging conflicting tokenizations JF - Language resources and evaluation N2 - Given the contemporary trend to modular NLP architectures and multiple annotation frameworks, the existence of concurrent tokenizations of the same text represents a pervasive problem in everyday's NLP practice and poses a non-trivial theoretical problem to the integration of linguistic annotations and their interpretability in general. This paper describes a solution for integrating different tokenizations using a standoff XML format, and discusses the consequences from a corpus-linguistic perspective. KW - Linguistic annotation KW - Multi-layer annotation KW - Conflicting tokenizations KW - Tokenization alignment KW - Corpus linguistics Y1 - 2012 U6 - https://doi.org/10.1007/s10579-011-9161-0 SN - 1574-020X VL - 46 IS - 1 SP - 53 EP - 74 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Cherstvy, Andrey G. A1 - Winkler, R. G. T1 - Polyelectrolyte adsorption onto oppositely charged interfaces image-charge repulsion and surface curvature JF - The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces & biophysical chemistry N2 - We analyze theoretically the influence of low-dielectric boundaries on the adsorption of flexible polyelectrolytes onto planar and spherical oppositely charged surfaces in electrolyte solutions. We rationalize to what extent polymer chains are depleted from adsorbing interfaces by repulsive image forces. We employ the WKB (Wentzel-Kramers-Brillouin) quantum mechanical method for the Green function of the Edwards equation to determine the adsorption equilibrium. Scaling relations are determined for the critical adsorption strength required to initiate polymer adsorption onto these low-dielectric supports. Image-force repulsion shifts the equilibrium toward the desorbed state, demanding larger surface charge densities and polyelectrolyte linear charge densities for the adsorption to take place. The effect is particularly pronounced for a planar interface in a low-salt regime, where a dramatic change in the scaling behavior for the adsorption-desorption transition is predicted. For the adsorbed state, polymers with higher charge densities are displaced further from the interface by image-charge repulsions. We discuss relevant experimental evidence and argue about possible biological applications of the results. Y1 - 2012 U6 - https://doi.org/10.1021/jp304980e SN - 1520-6106 VL - 116 IS - 32 SP - 9838 EP - 9845 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Cherstvy, Andrey G. T1 - Critical polyelectrolyte adsorption under confinement Planar slit, cylindrical pore, and spherical cavity JF - Biopolymers N2 - We explore the properties of adsorption of flexible polyelectrolyte chains in confined spaces between the oppositely charged surfaces in three basic geometries. A method of approximate uniformly valid solutions for the Green function equation for the eigenfunctions of polymer density distributions is developed to rationalize the critical adsorption conditions. The same approach was implemented in our recent study for the inverse problem of polyelectrolyte adsorption onto a planar surface, and on the outer surface of rod-like and spherical obstacles. For the three adsorption geometries investigated, the theory yields simple scaling relations for the minimal surface charge density that triggers the chain adsorption, as a function of the Debye screening length and surface curvature. The encapsulation of polyelectrolytes is governed by interplay of the electrostatic attraction energy toward the adsorbing surface and entropic repulsion of the chain squeezed into a thin slit or small cavities. Under the conditions of surface-mediated confinement, substantially larger polymer linear charge densities are required to adsorb a polyelectrolyte inside a charged spherical cavity, relative to a cylindrical pore and to a planar slit (at the same interfacial surface charge density). Possible biological implications are discussed briefly in the end. KW - polymers KW - adsorption KW - electrostatics KW - confinement Y1 - 2012 U6 - https://doi.org/10.1002/bip.22023 SN - 0006-3525 VL - 97 IS - 5 SP - 311 EP - 317 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Cheng, Yuan A1 - Lenkoshi, Alex T1 - Hierarchical gaussian graphical models beyond reversible jump JF - Electronic journal of statistics N2 - The Gaussian Graphical Model (GGM) is a popular tool for incorporating sparsity into joint multivariate distributions. The G-Wishart distribution, a conjugate prior for precision matrices satisfying general GGM constraints, has now been in existence for over a decade. However, due to the lack of a direct sampler, its use has been limited in hierarchical Bayesian contexts, relegating mixing over the class of GGMs mostly to situations involving standard Gaussian likelihoods. Recent work has developed methods that couple model and parameter moves, first through reversible jump methods and later by direct evaluation of conditional Bayes factors and subsequent resampling. Further, methods for avoiding prior normalizing constant calculations-a serious bottleneck and source of numerical instability-have been proposed. We review and clarify these developments and then propose a new methodology for GGM comparison that blends many recent themes. Theoretical developments and computational timing experiments reveal an algorithm that has limited computational demands and dramatically improves on computing times of existing methods. We conclude by developing a parsimonious multivariate stochastic volatility model that embeds GGM uncertainty in a larger hierarchical framework. The method is shown to be capable of adapting to swings in market volatility, offering improved calibration of predictive distributions. KW - Gaussian graphical models KW - G-Wishart distribution KW - conditional Bayes factors KW - exchange algorithms Y1 - 2012 U6 - https://doi.org/10.1214/12-EJS746 SN - 1935-7524 VL - 6 SP - 2309 EP - 2331 PB - Institute of Mathematical Statistics CY - Cleveland ER - TY - JOUR A1 - Chen, You-Peng A1 - Xiao, Xiao-Min A1 - Li, Jian A1 - Reichetzeder, Christoph A1 - Wang, Zi-Neng A1 - Hocher, Berthold T1 - Paternal body mass index (BMI) is associated with offspring intrauterine growth in a gender dependent manner JF - PLoS one N2 - Background: Environmental alternations leading to fetal programming of cardiovascular diseases in later life have been attributed to maternal factors. However, animal studies showed that paternal obesity may program cardio-metabolic diseases in the offspring. In the current study we tested the hypothesis that paternal BMI may be associated with fetal growth. Methods and Results: We analyzed the relationship between paternal body mass index (BMI) and birth weight, ultrasound parameters describing the newborn's body shape as well as parameters describing the newborns endocrine system such as cortisol, aldosterone, renin activity and fetal glycated serum protein in a birth cohort of 899 father/mother/child triplets. Since fetal programming is an offspring sex specific process, male and female offspring were analyzed separately. Multivariable regression analyses considering maternal BMI, paternal and maternal age, hypertension during pregnancy, maternal total glycated serum protein, parity and either gestational age (for birth weight) or time of ultrasound investigation (for ultrasound parameters) as confounding showed that paternal BMI is associated with growth of the male but not female offspring. Paternal BMI correlated with birth parameters of male offspring only: birth weight; biparietal diameter, head circumference; abdominal diameter, abdominal circumference; and pectoral diameter. Cortisol was likewise significantly correlated with paternal BMI in male newborns only. Conclusions: Paternal BMI affects growth of the male but not female offspring. Paternal BMI may thus represent a risk factor for cardiovascular diseases of male offspring in later life. It remains to be demonstrated whether this is linked to an offspring sex specific paternal programming of cortisol secretion. Y1 - 2012 U6 - https://doi.org/10.1371/journal.pone.0036329 SN - 1932-6203 VL - 7 IS - 5 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Chen, You-Peng A1 - Li, Jian A1 - Wang, Zi-Neng A1 - Reichetzeder, Christoph A1 - Xu, Hao A1 - Gong, Jian A1 - Chen, Guang-Ji A1 - Pfab, Thiemo A1 - Xiao, Xiao-Min A1 - Hocher, Berthold T1 - Renin angiotensin aldosterone system and glycemia in pregnancy JF - Clinical laboratory : the peer reviewed journal for clinical laboratories and laboratories related to blood transfusion N2 - Background: The renin-angiotensin-aldosterone system (RAAS) is involved in the pathogenesis of insulin resistance and type 2 diabetes in the general population. The RAAS is activated during pregnancy. However, it is unknown whether the RAAS contributes to glycemia in pregnant women. Methods: Plasma renin activity (PRA) and plasma aldosterone levels were quantified at delivery in 689 Chinese mothers. An oral glucose tolerance test in fasted women was performed in the second trimester of pregnancy. The diagnosis of gestational diabetes mellitus (GDM) and impaired glucose tolerance during pregnancy were made according to the guidelines of the Chinese Society of Obstetrics. Results: Plasma aldosterone was significantly higher in pregnant women with GDM as compared to those without impairment of glycemic control (normal pregnancies: 0.27 +/- 0.21 ng/mL, GDM: 0.36 +/- 0.30 ng/mL; p<0.05). Regression analyses revealed that PRA was negatively correlated with fasting blood glucose (FBG) (R-2 = 0.03, p = 0.007), whereas plasma aldosterone and aldosterone/PRA ratio were positively correlated with FBG (R-2 = 0.05, p<0.001 and R-2 = 0.03, p = 0.007, respectively). Multivariable regression analysis models considering relevant confounding factors confirmed these findings. Conclusions: This study demonstrated that fasting blood glucose in pregnant women is inversely correlated with the PRA, whereas plasma aldosterone showed a highly significant positive correlation with fasting blood glucose during pregnancy. Moreover, plasma aldosterone is significantly higher in pregnant women with GDM as compared to those women with normal glucose tolerance during pregnancy. Although causality cannot be proven in association studies, these data may indicate that the RAAS during pregnancy contributes to the pathogenesis of insulin resistance/new onset of diabetes during pregnancy. KW - Renin-angiotensin-aldosterone system KW - pregnancy KW - fasting blood glucose KW - glycemic control Y1 - 2012 SN - 1433-6510 VL - 58 IS - 5-6 SP - 527 EP - 533 PB - Clin Lab Publ., Verl. Klinisches Labor CY - Heidelberg ER - TY - JOUR A1 - Chechkin, Aleksei V. A1 - Zaid, Irwin M. A1 - Lomholt, Michael A. A1 - Sokolov, Igor M. A1 - Metzler, Ralf T1 - Bulk-mediated diffusion on a planar surface full solution JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We consider the effective surface motion of a particle that intermittently unbinds from a planar surface and performs bulk excursions. Based on a random-walk approach, we derive the diffusion equations for surface and bulk diffusion including the surface-bulk coupling. From these exact dynamic equations, we analytically obtain the propagator of the effective surface motion. This approach allows us to deduce a superdiffusive, Cauchy-type behavior on the surface, together with exact cutoffs limiting the Cauchy form. Moreover, we study the long-time dynamics for the surface motion. Y1 - 2012 U6 - https://doi.org/10.1103/PhysRevE.86.041101 SN - 1539-3755 VL - 86 IS - 4 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Chechkin, Aleksei V. A1 - Lenz, F. A1 - Klages, Rainer T1 - Normal and anomalous fluctuation relations for gaussian stochastic dynamics JF - Journal of statistical mechanics: theory and experiment N2 - We study transient work fluctuation relations (FRs) for Gaussian stochastic systems generating anomalous diffusion. For this purpose we use a Langevin approach by employing two different types of additive noise: (i) internal noise where the fluctuation dissipation relation of the second kind (FDR II) holds, and (ii) external noise without FDR II. For internal noise we demonstrate that the existence of FDR II implies the existence of the fluctuation dissipation relation of the first kind (FDR I), which in turn leads to conventional (normal) forms of transient work FRs. For systems driven by external noise we obtain violations of normal FRs, which we call anomalous FRs. We derive them in the long-time limit and demonstrate the existence of logarithmic factors in FRs for intermediate times. We also outline possible experimental verifications. KW - stochastic particle dynamics (theory) KW - fluctuations (theory) KW - stochastic processes (theory) KW - diffusion Y1 - 2012 U6 - https://doi.org/10.1088/1742-5468/2012/11/L11001 SN - 1742-5468 IS - 4 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Cassel, Michael A1 - Müller, Steffen A1 - Carlsohn, Anja A1 - Baur, Heiner A1 - Jerusel, N. A1 - Mayer, Frank T1 - Intra- and interrater variability of sonographic investigations of patella and achilles tendons JF - Sportverletzung, Sportschaden : Grundlagen, Prävention, Rehabilitation N2 - Background: Clinical examinations of tendon disorders routinely include ultrasound examinations, despite the fact that availability of data concerning validity criteria of these measurements are limited. The present study therefore aims to evaluate the reliability of measurements of Achilles- and Patella tendon diameter and in the detection of structural adaptations. Materials and Methods: In 14 healthy, recreationally active subjects both asymptomatic Achilles (AT) and patella tendons (PT) were measured twice by two examiners in a test-retest design. Besides the detection of anteroposterior (a.p.-) and mediolateral (m.l.-) diameters, areas of hypoechogenicity and neovascularisation were registered. Data were analysed descriptively with calculation of test-retest variability (TRV), intraclass-correlation coefficient (ICC) and Bland and Altman's plots with bias and 95% limits of agreement (LOA). Results: Intra- and interrater differences of AT- and PT-a.p.-diameter varied from 0.2 - 1.2 mm, those of AT- and PT-m.l-diameter from 0.7-5.1 mm. Areas of hypoechogenicity were visible in 24% of the tendons, while 15% showed neovascularisations. Intrarater AT-a.p.-diameters showed sparse deviations (TRV 4.5-7.4%; ICC 0.60-0.84; bias -0.05-0.07 mm; LOA-0.6-0.5 to -1.1 - 1.0 mm), while interrater AT- and PT-m.l.-diameters were highly variable (TRV 13.7-19.7%; ICC 0.11-0.20; bias -1.4-4.3 mm; LOA-5.5-2.7 to -10.5 - 1.9 mm). Conclusion: Our results suggest that the measurement of AT- and PT-a.p.-diameters is a reliable parameter. In contrast, reproducibility of AT- and PT-m.l.-diameters is questionable. The study corroborates the presence of hypoechogenicity and neovascularisation in asymptomatic tendons. KW - ultrasound KW - Achilles tendon KW - Patella tendon KW - intra- and inter-rater variability KW - tendon diameter Y1 - 2012 U6 - https://doi.org/10.1055/s-0031-1281839 SN - 0932-0555 VL - 26 IS - 1 SP - 21 EP - 26 PB - Thieme CY - Stuttgart ER - TY - JOUR A1 - Casse, Olivier A1 - Shkilnyy, Andriy A1 - Linders, Jürgen A1 - Mayer, Christian A1 - Häussinger, Daniel A1 - Völkel, Antje A1 - Thünemann, Andreas F. A1 - Dimova, Rumiana A1 - Cölfen, Helmut A1 - Meier, Wolfgang P. A1 - Schlaad, Helmut A1 - Taubert, Andreas T1 - Solution behavior of double-hydrophilic block copolymers in dilute aqueous solution JF - Macromolecules : a publication of the American Chemical Society N2 - The self-assembly of double-hydrophilic poly(ethylene oxide)-poly(2-methyl-2-oxazoline) diblock copolymers in water has been studied. Isothermal titration calorimetry, small-angle X-ray scattering, and analytical ultracentrifugation suggest that only single polymer chains are present in solution. In contrast, light scattering and transmission electron microscopy detect aggregates with radii of ca. 100 nm. Pulsed field gradient NMR spectroscopy confirms the presence of aggregates, although only 2% of the polymer chains undergo aggregation. Water uptake experiments indicate differences in the hydrophilicity of the two blocks, which is believed to be the origin of the unexpected aggregation behavior (in accordance with an earlier study by Ke et al. [Macromolecules 2009, 42, 5339-5344]). The data therefore suggest that even in double-hydrophilic block copolymers, differences in hydrophilicity are sufficient to drive polymer aggregation, a phenomenon that has largely been overlooked or ignored so far. Y1 - 2012 U6 - https://doi.org/10.1021/ma300621g SN - 0024-9297 VL - 45 IS - 11 SP - 4772 EP - 4777 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Carrapa, Barbara A1 - Bywater-Reyes, Sharon A1 - DeCelles, Peter G. A1 - Mortimer, Estelle A1 - Gehrels, George E. T1 - Late Eocene-Pliocene basin evolution in the Eastern Cordillera of northwestern Argentina (25 degrees-26 degrees S) regional implications for Andean orogenic wedge development JF - Basin research N2 - Important aspects of the Andean foreland basin in Argentina remain poorly constrained, such as the effect of deformation on deposition, in which foreland basin depozones Cenozoic sedimentary units were deposited, how sediment sources and drainages evolved in response to tectonics, and the thickness of sediment accumulation. Zircon U-Pb geochronological data from EocenePliocene sedimentary strata in the Eastern Cordillera of northwestern Argentina (PucaraAngastaco and La Vina areas) provide an Eocene (ca.similar to 38 similar to Ma) maximum depositional age for the Quebrada de los Colorados Formation. Sedimentological and provenance data reveal a basin history that is best explained within the context of an evolving foreland basin system affected by inherited palaeotopography. The Quebrada de los Colorados Formation represents deposition in the distal to proximal foredeep depozone. Development of an angular unconformity at ca.similar to 14 similar to Ma and the coarse-grained, proximal character of the overlying Angastaco Formation (lower to upper Miocene) suggest deposition in a wedge-top depozone. Axial drainage during deposition of the Palo Pintado Formation (upper Miocene) suggests a fluvial-lacustrine intramontane setting. By ca.similar to 4 similar to Ma, during deposition of the San Felipe Formation, the Angastaco area had become structurally isolated by the uplift of the Sierra de los Colorados Range to the east. Overall, the Eastern Cordillera sedimentary record is consistent with a continuous foreland basin system that migrated through the region from late Eocene through middle Miocene time. By middle Miocene time, the region lay within the topographically complex wedge-top depozone, influenced by thick-skinned deformation and re-activation of Cretaceous rift structures. The association of the Eocene Quebrada del los Colorados Formation with a foredeep depozone implies that more distal foreland deposits should be represented by pre-Eocene strata (Santa Barbara Subgroup) within the region. Y1 - 2012 U6 - https://doi.org/10.1111/j.1365-2117.2011.00519.x SN - 0950-091X VL - 24 IS - 3 SP - 249 EP - 268 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Carlsohn, Anja A1 - Scharhag-Rosenberger, Friederike A1 - Schapp, Lukas A1 - Fusch, Gerhard A1 - Mayer, Frank T1 - Validity of the determination of energy input from a dietary record in persons of normal weight - dependence on the level of energy input comparison between elite sportsmen with very high energy intake and a control group of persons of normal weight JF - Ernährungs-Umschau : Forschung & Praxis N2 - Dietary records are often biased, especially those of overweight individuals. The purpose of the study was to investigate underreporting among persons of normal weight with a very high energy intake (El). The total energy expenditure (TEE) of 16 elite athletes (BMI 24 +/- 2 kg/m(2)) and 17 controls (BMI 23 3 kg/m2) was measured using the doubly-labeled water technique (DLW, 14d). El was estimated using 2 x 3-day dietary records. Underreporters were identified by BLACK'S cut-off (El:TEE < 0.76). 44% of athletes (El: 3584 824 kcal/d; TEE: 4621 1460 kcal/d) and 29% of controls (El: 2552 680 kcal/d; TEE: 3151 822 kcal/d) were identified as underreporters. TEE explains 52% of underreporting. In summary, a high energy intake seems to strongly predict underreporting. Prevalence and magnitude of underreporting increase with increasing energy intake. KW - energy intake KW - dietary records KW - bias KW - underreporting KW - athletes Y1 - 2012 U6 - https://doi.org/10.4455/eu.2012.958 SN - 0174-0008 VL - 59 IS - 10 SP - 572 EP - 577 PB - Umschau-Zeitschriftenverl. CY - Frankfurt, Main ER - TY - JOUR A1 - Carlsohn, Anja A1 - Nippe, Susanne A1 - Heydenreich, Juliane A1 - Mayer, Frank T1 - Carbohydrate intake and food sources of junior triathletes during a moderate and an intensive training period JF - International journal of sport nutrition and exercise metabolism N2 - The study was conducted to investigate the quantity and the main food sources of carbohydrate (CHO) intake of junior elite triathletes during a short-term moderate (MOD; 12 km swimming, 100 km cycling, 30 km running per wk) and intensive training period (INT; 23 km swimming, 200 km cycling, 45 km running per wk). Self-reported dietary-intake data accompanied by training protocols of 7 male triathletes (18.1 +/- 2.4 yr, 20.9 +/- 1.4 kg/m(2)) were collected on 7 consecutive days during both training periods in the same competitive season. Total energy and CHO intake were calculated based on the German Food Database. A paired t test was applied to test for differences between the training phases (alpha = .05). CHO intake was slightly higher in INT than in MOD (9.0 +/- 1.6 g . kg(-1) . d(-1) vs. 7.8 +/- 1.6 g . kg(-1) . d(-1); p = .041). Additional CHO in INT was mainly ingested during breakfast (115 +/- 37 g in MOD vs. 175 +/- 23 g in INT; p = .002) and provided by beverages (280.5 +/- 97.3 g/d vs. 174.0 +/- 58.3 g/d CHO; p = .112). Altogether, main meals provided approximately two thirds of the total CHO intake. Pre- and postexercise snacks additionally supplied remarkable amounts of CHO (198.3 +/- 84.3 g/d in INT vs. 185.9 +/- 112 g/d CHO in MOD; p = .231). In conclusion, male German junior triathletes consume CHO in amounts currently recommended for endurance athletes during moderate to intensive training periods. Main meals provide the majority of CHO and should therefore not be skipped. CHO-containing beverages, as well as pre- and postexercise snacks, may provide a substantial amount of CHO intake in training periods with high CHO requirements. KW - carbohydrate sources KW - endurance athletes KW - meal schedule KW - beverages Y1 - 2012 SN - 1526-484X VL - 22 IS - 6 SP - 438 EP - 443 PB - Human Kinetics Publ. CY - Champaign ER - TY - JOUR A1 - Caravelli, Francesco A1 - Hamma, Alioscia A1 - Markopoulou, Fotini A1 - Riera, Arnau T1 - Trapped surfaces and emergent curved space in the Bose-Hubbard model JF - Physical review : D, Particles, fields, gravitation, and cosmology N2 - A Bose-Hubbard model on a dynamical lattice was introduced in previous work as a spin system analogue of emergent geometry and gravity. Graphs with regions of high connectivity in the lattice were identified as candidate analogues of spacetime geometries that contain trapped surfaces. We carry out a detailed study of these systems and show explicitly that the highly connected subgraphs trap matter. We do this by solving the model in the limit of no back-reaction of the matter on the lattice, and for states with certain symmetries that are natural for our problem. We find that in this case the problem reduces to a one-dimensional Hubbard model on a lattice with variable vertex degree and multiple edges between the same two vertices. In addition, we obtain a (discrete) differential equation for the evolution of the probability density of particles which is closed in the classical regime. This is a wave equation in which the vertex degree is related to the local speed of propagation of probability. This allows an interpretation of the probability density of particles similar to that in analogue gravity systems: matter inside this analogue system sees a curved spacetime. We verify our analytic results by numerical simulations. Finally, we analyze the dependence of localization on a gradual, rather than abrupt, falloff of the vertex degree on the boundary of the highly connected region and find that matter is localized in and around that region. Y1 - 2012 U6 - https://doi.org/10.1103/PhysRevD.85.044046 SN - 1550-7998 VL - 85 IS - 4 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Campbell, Earl T. A1 - Eisert, Jens T1 - Gaussification and entanglement distillation of continuous-variable systems a unifying picture JF - Physical review letters N2 - Distillation of entanglement using only Gaussian operations is an important primitive in quantum communication, quantum repeater architectures, and distributed quantum computing. Existing distillation protocols for continuous degrees of freedom are only known to converge to a Gaussian state when measurements yield precisely the vacuum outcome. In sharp contrast, non-Gaussian states can be deterministically converted into Gaussian states while preserving their second moments, albeit by usually reducing their degree of entanglement. In this work-based on a novel instance of a noncommutative central limit theorem-we introduce a picture general enough to encompass the known protocols leading to Gaussian states, and new classes of protocols including multipartite distillation. This gives the experimental option of balancing the merits of success probability against entanglement produced. Y1 - 2012 U6 - https://doi.org/10.1103/PhysRevLett.108.020501 SN - 0031-9007 VL - 108 IS - 2 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Caliendo, Marco A1 - Fossen, Frank A1 - Kritikos, Alexander T1 - Trust, positive reciprocity, and negative reciprocity Do these traits impact entrepreneurial dynamics? JF - Journal of economic psychology : research in economic psychology and behavioral economics N2 - Experimental evidence reveals that there is a strong willingness to trust and to act in both positively and negatively reciprocal ways. So far it is rarely analyzed whether these variables of social cognition influence everyday decision making behavior. We focus on entrepreneurs who are permanently facing exchange processes in the interplay with investors, sellers, and buyers, as well as needing to trust others and reciprocate with their network. We base our analysis on the German Socio-Economic Panel with its recently introduced questions about trust, positive reciprocity, and negative reciprocity to examine the extent that these variables influence the entrepreneurial decision processes. More specifically, we analyze whether (i) the willingness to trust other people influences the probability of starting a business; (ii) trust, positive reciprocity, and negative reciprocity influence the exit probability of entrepreneurs; and (iii) willingness to trust and to act reciprocally influences the probability of being an entrepreneur versus an employee or a manager. Our findings reveal that, in particular, trust impacts entrepreneurial development. Interestingly, entrepreneurs are more trustful than employees, but much less trustful than managers. KW - Entrepreneurship KW - Trust KW - Reciprocity Y1 - 2012 U6 - https://doi.org/10.1016/j.joep.2011.01.005 SN - 0167-4870 VL - 33 IS - 2 SP - 394 EP - 409 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Caliendo, Marco A1 - Clement, Michel A1 - Papies, Dominik A1 - Scheel-Kopeinig, Sabine T1 - The cost impact of spam filters measuring the effect of information system technologies in organizations JF - Information systems research N2 - Dealing with spam is very costly, and many organizations have tried to reduce spam-related costs by installing spam filters. Relying on modern econometric methods to reduce the selection bias of installing a spam filter, we use a unique data setting implemented at a German university to measure the costs associated with spam and the costs savings of spam filters. Our methodological framework accounts for effect heterogeneity and can be easily used to estimate the effect of other IS technologies implemented in organizations. The majority of costs stem from the time that employees spend identifying and deleting spam, amounting to an average of approximately five minutes per employee per day. Our analysis, which accounts for selection bias, finds that the installation of a spam filter reduces these costs by roughly one third. Failing to account for the selection bias would lead to a result that suggests that installing a spam filter does not reduce working time losses. However, cost savings only occur when the spam burden is high, indicating that spam filters do not necessarily reduce costs and are therefore no universal remedy. The analysis further shows that spam filters alone are a countermeasure against spam that exhibits only limited effectiveness because they only reduce costs by one third. KW - spam KW - spam filter KW - selection bias KW - propensity score matching Y1 - 2012 U6 - https://doi.org/10.1287/isre.1110.0396 SN - 1047-7047 VL - 23 IS - 3 SP - 1068 EP - 1080 PB - INFORMS CY - Hannover ER - TY - JOUR A1 - Bütow, Sascha T1 - Vom König neu gestaltet - vom Magistrat treu verwaltet BT - Stadtumbau und Herrschaft in Beeskow wärend des 18. Jahrhunderts JF - König macht Stadt : Preußens und andere Einflüsse auf der historischen Stadtkerne in Land Brandenburg Y1 - 2012 SN - 978-3-00-039489-8 SP - 33 EP - 40 PB - Brandenburgische Universitätsdruckerei, Verlagsgesellschaft Potsdam mbH CY - Potsdam ER - TY - JOUR A1 - Bütow, Sascha T1 - Stadtbrand und Festungsschleifung BT - wie Peitz im 18. Jahrhundert neu entstand JF - König macht Stadt : Preußens und andere Einflüsse auf der historischen Stadtkerne in Land Brandenburg Y1 - 2012 SN - 978-3-00-039489-8 SP - 79 EP - 62 PB - Brandenburgische Universitätsdruckerei, Verlagsgesellschaft Potsdam mbH CY - Potsdam ER - TY - JOUR A1 - Böniger, Urs A1 - Tronicke, Jens T1 - Subsurface utility extraction and characterization combining GPR symmetry and polarization attributes JF - IEEE transactions on geoscience and remote sensing N2 - Polarization of the electromagnetic wavefield has significant implications for the acquisition and interpretation of ground-penetrating radar (GPR) data. Based on the geometrical and physical properties of the subsurface scatterer and the physical properties of its surrounding material, strong polarization phenomena might occur. Here, we develop an attribute-based analysis approach to extract and characterize buried utility pipes using two broadside antenna configurations. First, we enhance and extract the utilities by making use of their distinct symmetric nature through the application of a symmetry-enhancing image-processing algorithm known as phase symmetry. Second, we assess the polarization characteristics by calculating two attributes (polarization angle and linearity) using principal component analysis. Combination of attributes derived from these steps into a novel depolarization attribute allows one to efficiently detect and distinguish different utilities present within 3-D GPR data. The performance of our analysis approach is illustrated using synthetic examples and evaluated using field examples (including a dual-configuration 3-D data set) collected across a field site, where detailed ground-truth information is available. Our results demonstrate that the proposed approach allows for a more detailed extraction and combination of utility relevant information compared to approaches relying on single-component data and, thus, eases the interpretation of multicomponent GPR data sets. KW - Multicomponent ground-penetrating radar (GPR) data KW - phase symmetry KW - pipe detection KW - polarization analysis KW - principal component analysis (PCA) Y1 - 2012 U6 - https://doi.org/10.1109/TGRS.2011.2163413 SN - 0196-2892 SN - 1558-0644 VL - 50 IS - 3 SP - 736 EP - 746 PB - Inst. of Electr. and Electronics Engineers CY - Piscataway ER - TY - JOUR A1 - Bödecker, Geesche A1 - Henkel, Carsten T1 - Validity of the quantum regression theorem for resonance fluorescence in a photonic crystal JF - Annalen der Physik N2 - Correlation functions of a driven two-level system embedded in a photonic crystal are analyzed. The spectral density of the photonic bands near a gap makes this system non-Markovian. The equations of motion for two-time correlations are derived by two different methods, the quantum regression theorem and the fluctuation dissipation theorem, and found to be the same. KW - Resonance fluorescence KW - fluctuation dissipation theorem KW - quantum regression theorem KW - non-Markovian dynamics KW - open quantum system KW - photonic bandgap Y1 - 2012 U6 - https://doi.org/10.1002/andp.201200135 SN - 0003-3804 VL - 524 IS - 12 SP - 805 EP - 813 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Bäse, Frank A1 - Elsenbeer, Helmut A1 - Neill, Christopher A1 - Krusche, Alex V. T1 - Differences in throughfall and net precipitation between soybean and transitional tropical forest in the southern Amazon, Brazil JF - Agriculture, ecosystems & environment : an international journal for scientific research on the relationship of agriculture and food production to the biosphere N2 - The expansion of soybean cultivation into the Amazon in Brazil has potential hydrological effects at local to regional scales. To determine the impacts of soybean agriculture on hydrology, a comparison of net precipitation (throughfall, stemflow) in undisturbed tropical forest and soybean fields on the southern edge of the Amazon Basin in the state of Mato Grosso is needed. This study measured throughfall with troughs and stemflow with collar collectors during two rainy seasons. The results showed that in forest 91.6% of rainfall was collected as throughfall and 0.3% as stemflow, while in soybean fields with two-month old plants, 46.2% of rainfall was collected as throughfall and 9.0% as stemflow. Hence, interception of precipitation in soybean fields was far greater than in intact forests. Differences in throughfall, stemflow and net precipitation were found to be mainly associated with differences in plant structure and stem density in transitional forest and soybean cropland. Because rainfall interception in soybean fields is higher than previously believed and because both the area of cropland and the frequency of crop cycles (double cropping) are increasing rapidly, interception needs to be reconsidered in regional water balance models when consequences of land cover changes are analyzed in the Amazon soybean frontier region. Based on the continued expansion of soybean fields across the landscape and the finding that net precipitation is lower in soy agriculture, a reduction in water availability in the long term can be assumed. KW - Throughfall KW - Net precipitation KW - Stemflow KW - Soybean KW - Tropical forest Y1 - 2012 U6 - https://doi.org/10.1016/j.agee.2012.06.013 SN - 0167-8809 VL - 159 SP - 19 EP - 28 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Burnecki, Krzysztof A1 - Wylomanska, Agnieszka A1 - Beletskii, Aleksei A1 - Gonchar, Vsevolod A1 - Chechkin, Aleksei V. T1 - Recognition of stable distribution with levy index alpha close to 2 JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We address the problem of recognizing alpha-stable Levy distribution with Levy index close to 2 from experimental data. We are interested in the case when the sample size of available data is not large, thus the power law asymptotics of the distribution is not clearly detectable, and the shape of the empirical probability density function is close to a Gaussian. We propose a testing procedure combining a simple visual test based on empirical fourth moment with the Anderson-Darling and Jarque-Bera statistical tests and we check the efficiency of the method on simulated data. Furthermore, we apply our method to the analysis of turbulent plasma density and potential fluctuations measured in the stellarator-type fusion device and demonstrate that the phenomenon of the L-H transition from low confinement, L mode, to a high confinement, H mode, which occurs in this device is accompanied by the transition from Levy to Gaussian fluctuation statistics. Y1 - 2012 U6 - https://doi.org/10.1103/PhysRevE.85.056711 SN - 1539-3755 VL - 85 IS - 5 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Burkart-Waco, Diana A1 - Josefsson, Caroline A1 - Dilkes, Brian A1 - Kozloff, Nora A1 - Torjek, Otto A1 - Meyer, Rhonda C. A1 - Altmann, Thomas A1 - Comai, Luca T1 - Hybrid incompatibility in arabidopsis is determined by a Multiple-Locus genetic network JF - Plant physiology : an international journal devoted to physiology, biochemistry, cellular and molecular biology, biophysics and environmental biology of plants N2 - The cross between Arabidopsis thaliana and the closely related species Arabidopsis arenosa results in postzygotic hybrid incompatibility, manifested as seed death. Ecotypes of A. thaliana were tested for their ability to produce live seed when crossed to A. arenosa. The identified genetic variation was used to map quantitative trait loci (QTLs) encoded by the A. thaliana genome that affect the frequency of postzygotic lethality and the phenotypes of surviving seeds. Seven QTLs affecting the A. thaliana component of this hybrid incompatibility were identified by crossing a Columbia x C24 recombinant inbred line population to diploid A. arenosa pollen donors. Additional epistatic loci were identified based on their pairwise interaction with one or several of these QTLs. Epistatic interactions were detected for all seven QTLs. The two largest additive QTLs were subjected to fine-mapping, indicating the action of at least two genes in each. The topology of this network reveals a large set of minor-effect loci from the maternal genome controlling hybrid growth and viability at different developmental stages. Our study establishes a framework that will enable the identification and characterization of genes and pathways in A. thaliana responsible for hybrid lethality in the A. thaliana x A. arenosa interspecific cross. Y1 - 2012 U6 - https://doi.org/10.1104/pp.111.188706 SN - 0032-0889 VL - 158 IS - 2 SP - 801 EP - 812 PB - American Society of Plant Physiologists CY - Rockville ER - TY - JOUR A1 - Burchert, Linn T1 - Handlungspotential! BT - Für eine neue Lebenskunst JF - Perspektiven für morgen : Gedanken zur Zukunft von Politik, Wirtschaft und Gesellschaft N2 - Inhalt: - Es kommt auf den Einzelnen an - Konsum, Glück und Freiheit - Das Individuum als Lebenskünstler - Konsum, Ästhetik und Lebenskunst - Neues Handlungspotential KW - Nachhaltigkeit KW - Zukunft KW - Politik KW - Wirtschaft KW - Gesellschaft KW - sustainability KW - future KW - politics KW - economy KW - society Y1 - 2012 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-60578 SP - 50 EP - 59 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Burchert, Linn T1 - Vorwort : Perspektiven für morgen BT - ein studentischer Essayband JF - Perspektiven für morgen : Gedanken zur Zukunft von Politik, Wirtschaft und Gesellschaft KW - Nachhaltigkeit KW - Zukunft KW - Politik KW - Wirtschaft KW - Gesellschaft KW - sustainability KW - future KW - politics KW - economy KW - society Y1 - 2012 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-60526 SP - 4 EP - 7 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Bukovinszky, Tibor A1 - Verschoor, Antonie M. A1 - Helmsing, Nico R. A1 - Bezemer, T. Martijn A1 - Bakker, Elisabeth S. A1 - Vos, Matthijs A1 - Domis, Lisette Nicole de Senerpont T1 - The Good, the bad and the plenty Interactive effects of food quality and quantity on the growth of different daphnia species JF - PLoS one N2 - Effects of food quality and quantity on consumers are neither independent nor interchangeable. Although consumer growth and reproduction show strong variation in relation to both food quality and quantity, the effects of food quality or food quantity have usually been studied in isolation. In two experiments, we studied the growth and reproduction in three filter-feeding freshwater zooplankton species, i.e. Daphnia galeata x hyalina, D. pulicaria and D. magna, on their algal food (Scenedesmus obliquus), varying in carbon to phosphorus (C:P) ratios and quantities (concentrations). In the first experiment, we found a strong positive effect of the phosphorus content of food on growth of Daphnia, both in their early and late juvenile development. Variation in the relationship between the P-content of animals and their growth rate reflected interspecific differences in nutrient requirements. Although growth rates typically decreased as development neared maturation, this did not affect these species-specific couplings between growth rate and Daphnia P-content. In the second experiment, we examined the effects of food quality on Daphnia growth at different levels of food quantity. With the same decrease in P-content of food, species with higher estimated P-content at zero growth showed a larger increase in threshold food concentrations (i.e. food concentration sufficient to meet metabolic requirements but not growth). These results suggest that physiological processes such as maintenance and growth may in combination explain effects of food quality and quantity on consumers. Our study shows that differences in response to variation in food quality and quantity exist between species. As a consequence, species-specific effects of food quality on consumer growth will also determine how species deal with varying food levels, which has implications for resource-consumer interactions. Y1 - 2012 U6 - https://doi.org/10.1371/journal.pone.0042966 SN - 1932-6203 VL - 7 IS - 9 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Buchmann, Carsten M. A1 - Schurr, Frank Martin A1 - Nathan, Ran A1 - Jeltsch, Florian T1 - Movement upscaled - the importance of individual foraging movement for community response to habitat loss JF - Ecography : pattern and diversity in ecology ; research papers forum N2 - Habitat loss poses a severe threat to biodiversity. While many studies yield valuable information on how specific species cope with such environmental modification, the mechanistic understanding of how interacting species or whole communities are affected by habitat loss is still poor. Individual movement plays a crucial role for the space use characteristics of species, since it determines how individuals perceive and use their heterogeneous environment. At the community level, it is therefore essential to include individual movement and how it is influenced by resource sharing into the investigation of consequences of habitat loss. To elucidate the effects of foraging movement on communities in face of habitat loss, we here apply a recently published spatially-explicit and individual-based model of home range formation. This approach allows predicting the individual size distribution (ISD) of mammal communities in simulation landscapes that vary in the amount of suitable habitat. We apply three fundamentally different foraging movement approaches (central place forager (CPF), patrolling forager (PF) and body mass dependent nomadic forager (BNF)). Results show that the efficiency of the different foraging strategies depends on body mass, which again affects community structure in face of habitat loss. CPF is only efficient for small animals, and therefore yields steep ISD exponents on which habitat loss has little effect (due to a movement limitation of body mass). PF and particularly BNF are more efficient for larger animals, resulting in less steep ISDs with higher mass maxima, both showing a threshold behaviour with regard to loss of suitable habitat. These findings represent a new way of explaining observed extinction thresholds, and therefore indicate the importance of individual space use characterized by physiology and behaviour, i.e. foraging movement, for communities and their response to habitat loss. Findings also indicate the necessity to incorporate the crucial role of movement into future conservation efforts of terrestrial communities. Y1 - 2012 U6 - https://doi.org/10.1111/j.1600-0587.2011.06924.x SN - 0906-7590 VL - 35 IS - 5 SP - 436 EP - 445 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Brückner, Michael A1 - Kanzow, Christian A1 - Scheffer, Tobias T1 - Static prediction games for adversarial learning problems JF - Journal of machine learning research N2 - The standard assumption of identically distributed training and test data is violated when the test data are generated in response to the presence of a predictive model. This becomes apparent, for example, in the context of email spam filtering. Here, email service providers employ spam filters, and spam senders engineer campaign templates to achieve a high rate of successful deliveries despite the filters. We model the interaction between the learner and the data generator as a static game in which the cost functions of the learner and the data generator are not necessarily antagonistic. We identify conditions under which this prediction game has a unique Nash equilibrium and derive algorithms that find the equilibrial prediction model. We derive two instances, the Nash logistic regression and the Nash support vector machine, and empirically explore their properties in a case study on email spam filtering. KW - static prediction games KW - adversarial classification KW - Nash equilibrium Y1 - 2012 SN - 1532-4435 VL - 13 SP - 2617 EP - 2654 PB - Microtome Publishing CY - Cambridge, Mass. ER - TY - JOUR A1 - Bräuer, B. A1 - Asch, Günter A1 - Hofstetter, Rami A1 - Haberland, Christian A1 - Jaser, D. A1 - El-Kelani, R. A1 - Weber, Michael H. T1 - High-resolution local earthquake tomography of the southern Dead Sea area JF - Geophysical journal international N2 - Local earthquake data from a dense temporary seismological network in the southern Dead Sea area have been analysed within the project DESIRE (Dead Sea Integrated Research Project). Local earthquakes are used for the first precise image of the distribution of the P-wave velocity and the vP/vS ratios. 65 stations registered 655 local events within 18 months of observation time. A subset of 530 well-locatable events with 26 730 P- and S-arrival times was used to calculate a tomographic model for the vP and vP/vS distribution. Since the study area is at first-order 2-D, a gradual approach was chosen, which compromised a 2-D inversion followed by a 3-D inversion. The sedimentary basin fill is clearly imaged through high vP/vS ratios and low vP. The basin fill shows an asymmetric structure with average depth of 7 km at the western boundary and depth between 10 and 14 km at the eastern boundary. This asymmetry is reflected by the vertical strike-slip eastern border fault, and the normal faulting at the western boundary, caused by the transtensional deformation within the last 5 Myr. Within the basin fill the Lisan salt diapir is imaged through low vP/vS ratios, reflecting its low fluid content. The extensions were determined to 12 km in EW and 17 km in NS direction while its depth is 56 km. The thickness of the pre-basin sediments below the basin fill cannot be derived from the tomography datait is estimated to less than 3 km from former investigations. Below the basin, down to 18 km depth very low P-wave velocities and low vP/vS ratios are observedmost likely caused by fluids from the surrounding crust or the upper mantle. KW - Seismic tomography KW - Continental margins: transform KW - Continental tectonics: strike-slip and transform Y1 - 2012 U6 - https://doi.org/10.1111/j.1365-246X.2012.05668.x SN - 0956-540X VL - 191 IS - 3 SP - 881 EP - 897 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Brzezicka, Aneta A1 - Krejtz, Izabela A1 - von Hecker, Ulrich A1 - Laubrock, Jochen T1 - Eye movement evidence for defocused attention in dysphoria - A perceptual span analysis JF - International journal of psychophysiology N2 - The defocused attention hypothesis (von Hecker and Meiser, 2005) assumes that negative mood broadens attention, whereas the analytical rumination hypothesis (Andrews and Thompson, 2009) suggests a narrowing of the attentional focus with depression. We tested these conflicting hypotheses by directly measuring the perceptual span in groups of dysphoric and control subjects, using eye tracking. In the moving window paradigm, information outside of a variable-width gaze-contingent window was masked during reading of sentences. In measures of sentence reading time and mean fixation duration, dysphoric subjects were more pronouncedly affected than controls by a reduced window size. This difference supports the defocused attention hypothesis and seems hard to reconcile with a narrowing of attentional focus. KW - Dysphoria KW - Defocused attention KW - Eye tracking KW - Moving window paradigm KW - Perceptual span Y1 - 2012 U6 - https://doi.org/10.1016/j.ijpsycho.2011.09.022 SN - 0167-8760 VL - 85 IS - 1 SP - 129 EP - 133 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Brunner, Jana A1 - Hoole, Phil T1 - Motor equivalent strategies in the production of german/integral/ under perturbation JF - Language and speech N2 - The German sibilant /integral/ is produced with a constriction in the postalveolar region and often with protruded lips. By covarying horizontal lip and tongue position speakers can keep a similar acoustic output even if the articulation varies. This study investigates whether during two weeks of adaptation to an artificial palate speakers covary these two articulatory parameters, whether tactile landmarks have an influence on the covariation and to what extent speakers can foresee the acoustic result of the covariation without auditory feedback. Six German speakers were recorded with EMA. Four of them showed a covariation of lip and tongue, which is consistent with the motor equivalence hypothesis. The acoustic output, however, does not stay entirely constant but varies with the tongue position. The role of tactile landmarks is negligible. To a certain extent, speakers are able to adapt even without auditory feedback. KW - fricative KW - motor equivalence KW - perturbation KW - sibilant Y1 - 2012 U6 - https://doi.org/10.1177/0023830911434098 SN - 0023-8309 VL - 55 IS - 7 SP - 457 EP - 476 PB - Sage Publ. CY - London ER - TY - JOUR A1 - Bruhn, Anja A1 - Huschka, Denis A1 - Wagner, Gert G. T1 - Naming and war in modern Germany JF - Names : a journal of onomastics N2 - This paper analyzes naming behavior in Germany in the context of rapid social change. It begins with an overview of general developments in naming in Germany over the last one hundred years, based on data from the German Socio-Economic Panel Study (SOEP), which supplies us with almost 45,000 datasets. The paper focuses on the periods of World War II and the Cold War since we conclude that general developments in naming were disrupted by these two phenomena. Wartime brings accelerated social change in its wake and people react to this social change - often on an apparently individual level. Here, our findings are in accordance with established sociological theories. KW - naming KW - World War II KW - Cold War KW - Germany KW - SOEP Y1 - 2012 U6 - https://doi.org/10.1179/0027773812Z.00000000011 SN - 0027-7738 VL - 60 IS - 2 SP - 74 EP - 89 PB - Routledge, Taylor & Francis Group CY - Leeds ER - TY - JOUR A1 - Bruchmüller, Wiebke A1 - Sjöstrom, Saana A1 - Schütz, Susann A1 - Swietza, Romy A1 - Zielina, Marie T1 - Wie kann zwischen Kindern mit einer ungestörten Zweitsprachentwicklung und zweisprachigen Kindern mit einer grammatikalischen sSES differenziert werden? Y1 - 2012 ER - TY - JOUR A1 - Brotman, Yariv A1 - Landau, Udi A1 - Pnini, Smadar A1 - Lisec, Jan A1 - Balazadeh, Salma A1 - Müller-Röber, Bernd A1 - Zilberstein, Aviah A1 - Willmitzer, Lothar A1 - Chet, Ilan A1 - Viterbo, Ada T1 - The LysM Receptor-Like Kinase LysM RLK1 is required to activate defense and abiotic-stress responses induced by overexpression of fungal chitinases in arabidopsis plants JF - Molecular plant N2 - Application of crab shell chitin or pentamer chitin oligosaccharide to Arabidopsis seedlings increased tolerance to salinity in wild-type but not in knockout mutants of the LysM Receptor-Like Kinase1 (CERK1/LysM RLK1) gene, known to play a critical role in signaling defense responses induced by exogenous chitin. Arabidopsis plants overexpressing the endochitinase chit36 and hexoaminidase excy1 genes from the fungus Trichoderma asperelleoides T203 showed increased tolerance to salinity, heavy-metal stresses, and Botrytis cinerea infection. Resistant lines, overexpressing fungal chitinases at different levels, were outcrossed to lysm rlk1 mutants. Independent homozygous hybrids lost resistance to biotic and abiotic stresses, despite enhanced chitinase activity. Expression analysis of 270 stress-related genes, including those induced by reactive oxygen species (ROS) and chitin, revealed constant up-regulation (at least twofold) of 10 genes in the chitinase-overexpressing line and an additional 76 salt-induced genes whose expression was not elevated in the lysm rlk1 knockout mutant or the hybrids harboring the mutation. These findings elucidate that chitin-induced signaling mediated by LysM RLK1 receptor is not limited to biotic stress response but also encompasses abiotic-stress signaling and can be conveyed by ectopic expression of chitinases in plants. KW - abiotic stress KW - chitin-induced signaling KW - chitinases KW - LysM receptor kinase KW - Trichoderma Y1 - 2012 U6 - https://doi.org/10.1093/mp/sss021 SN - 1674-2052 VL - 5 IS - 5 SP - 1113 EP - 1124 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Bronstert, Axel A1 - Creutzfeldt, Benjamin A1 - Gräff, Thomas A1 - Hajnsek, Irena A1 - Heistermann, Maik A1 - Itzerott, Sibylle A1 - Jagdhuber, Thomas A1 - Kneis, David A1 - Lueck, Erika A1 - Reusser, Dominik A1 - Zehe, Erwin T1 - Potentials and constraints of different types of soil moisture observations for flood simulations in headwater catchments JF - Natural hazards : journal of the International Society for the Prevention and Mitigation of Natural Hazards N2 - Flood generation in mountainous headwater catchments is governed by rainfall intensities, by the spatial distribution of rainfall and by the state of the catchment prior to the rainfall, e. g. by the spatial pattern of the soil moisture, groundwater conditions and possibly snow. The work presented here explores the limits and potentials of measuring soil moisture with different methods and in different scales and their potential use for flood simulation. These measurements were obtained in 2007 and 2008 within a comprehensive multi-scale experiment in the Weisseritz headwater catchment in the Ore-Mountains, Germany. The following technologies have been applied jointly thermogravimetric method, frequency domain reflectometry (FDR) sensors, spatial time domain reflectometry (STDR) cluster, ground-penetrating radar (GPR), airborne polarimetric synthetic aperture radar (polarimetric SAR) and advanced synthetic aperture radar (ASAR) based on the satellite Envisat. We present exemplary soil measurement results, with spatial scales ranging from point scale, via hillslope and field scale, to the catchment scale. Only the spatial TDR cluster was able to record continuous data. The other methods are limited to the date of over-flights (airplane and satellite) or measurement campaigns on the ground. For possible use in flood simulation, the observation of soil moisture at multiple scales has to be combined with suitable hydrological modelling, using the hydrological model WaSiM-ETH. Therefore, several simulation experiments have been conducted in order to test both the usability of the recorded soil moisture data and the suitability of a distributed hydrological model to make use of this information. The measurement results show that airborne-based and satellite-based systems in particular provide information on the near-surface spatial distribution. However, there are still a variety of limitations, such as the need for parallel ground measurements (Envisat ASAR), uncertainties in polarimetric decomposition techniques (polarimetric SAR), very limited information from remote sensing methods about vegetated surfaces and the non-availability of continuous measurements. The model experiments showed the importance of soil moisture as an initial condition for physically based flood modelling. However, the observed moisture data reflect the surface or near-surface soil moisture only. Hence, only saturated overland flow might be related to these data. Other flood generation processes influenced by catchment wetness in the subsurface such as subsurface storm flow or quick groundwater drainage cannot be assessed by these data. One has to acknowledge that, in spite of innovative measuring techniques on all spatial scales, soil moisture data for entire vegetated catchments are still today not operationally available. Therefore, observations of soil moisture should primarily be used to improve the quality of continuous, distributed hydrological catchment models that simulate the spatial distribution of moisture internally. Thus, when and where soil moisture data are available, they should be compared with their simulated equivalents in order to improve the parameter estimates and possibly the structure of the hydrological model. KW - Soil moisture KW - Remote sensing KW - Hydrological modelling KW - Flood forecasting KW - Soil moisture measurement comparison Y1 - 2012 U6 - https://doi.org/10.1007/s11069-011-9874-9 SN - 0921-030X SN - 1573-0840 VL - 60 IS - 3 SP - 879 EP - 914 PB - Springer CY - New York ER - TY - JOUR A1 - Bronner, C. A1 - Leyssner, F. A1 - Stremlau, S. A1 - Utecht, Manuel Martin A1 - Saalfrank, Peter A1 - Klamroth, Tillmann A1 - Tegeder, P. T1 - Electronic structure of a subnanometer wide bottom-up fabricated graphene nanoribbon: End states, band gap, and dispersion JF - Physical review : B, Condensed matter and materials physics N2 - Angle-resolved two-photon photoemission and high-resolution electron energy loss spectroscopy are employed to derive the electronic structure of a subnanometer atomically precise quasi-one-dimensional graphene nanoribbon (GNR) on Au(111). We resolved occupied and unoccupied electronic bands including their dispersion and determined the band gap, which possesses an unexpectedly large value of 5.1 eV. Supported by density functional theory calculations for the idealized infinite polymer and finite size oligomers, an unoccupied nondispersive electronic state with an energetic position in the middle of the band gap of the GNR could be identified. This state resides at both ends of the ribbon (end state) and is only found in the finite sized systems, i.e., the oligomers. Y1 - 2012 U6 - https://doi.org/10.1103/PhysRevB.86.085444 SN - 1098-0121 VL - 86 IS - 8 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Broeker, Patrick A1 - Luecke, Klaus A1 - Perpeet, Markus A1 - Gronewold, Thomas M. A. T1 - A nanostructured SAW chip-based biosensor detecting cancer cells JF - SENSORS AND ACTUATORS B-CHEMICAL N2 - A nanostructured chip surface was fabricated enabling binding via spaced antibodies specifically targeting surface proteins of cancer cells and detection of extremely low numbers of circulating tumor cells (CTC) without labeling using a sam (R) 5 biosensor. The antibody surfaces mostly were generated by self assembly of antibodies to gold nanospots on the sensitive SiO2-surface of a sam (R) 5 chip. Compared with a complete gold surface, only 40% of the amount of antibodies was bound to the nanospot surface, but structured such that 15-fold higher sensitivity to vital cancer cells was achieved. Human cancer cell lines JEG-3 (lmphoblastic leukemia) and MOLT-17 (placental choriocarcinoma) from cell cultures were successfully detected. The sensor showed significant responses on less than 10 cells injected in a single run. The extreme increase in sensitivity and its simple regeneration emphasizes the usefulness of its introduction in biomedical applications. (C) 2011 Elsevier B.V. All rights reserved. KW - Nanospots KW - Nanostructured surfaces KW - SAW sensor KW - Cell detection KW - Cancer cells KW - sam (R) 5 Y1 - 2012 U6 - https://doi.org/10.1016/j.snb.2011.11.022 SN - 0925-4005 VL - 165 IS - 1 SP - 1 EP - 6 PB - ELSEVIER SCIENCE SA CY - LAUSANNE ER - TY - JOUR A1 - Brietzke, Thomas Martin A1 - Mickler, Wulfhard A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Krüger, Hans-Joerg A1 - Holdt, Hans-Jürgen T1 - Mono- and dinuclear Ruthenium(II)-1,6,7,12-Tetraazaperylene complexes of N,N '-Dimethyl-2,11-diaza[3.3](2,6)-pyridinophane JF - European journal of inorganic chemistry : a journal of ChemPubSoc Europe N2 - Ruthenium(II) complexes [Ru(L-N4Me2)(dape)](PF6)2 {[1](PF6)2}, [Ru(L-N4Me2)(tape)](PF6)2 {[2](PF6)2}, and [{Ru(L-N4Me2)}2(mu-tape)](PF6)4 {[3](PF6)4} were synthesized in two reaction steps by first reacting [Ru(DMSO)4Cl2] with tetraazamacrocyclic ligand N,N'-dimethyl-2,11-diaza[3.3](2,6)-pyridinophane (L-N4Me2) in ethanol under microwave irradiation to the intermediate [Ru(L-N4Me2)Cl2], which was subsequently, without further isolation, reacted with 1,12-diazaperylene (dape) or 1,6,7,12-tetraazaperylene (tape). X-ray structures of [Ru(L-N4Me2)(dape)](PF6)2, [Ru(L-N4Me2)(tape)](PF6)2.acetone, and [{Ru(L-N4Me2)}2(mu-tape)](ClO4)4.MeCN were determined. The UV/Vis absorption spectra of [1](PF6)2, [2](PF6)2, and [3](PF6)4 in acetonitrile display intense low-energy dp(Ru)?p* (dape or tape) MLCT absorption bands centered at 579, 637, and 794 nm, respectively. Reversible metal oxidations for the bimetallic complex [{Ru(L-N4Me2)}2(mu-tape)]4+ ([3]4+) are detected at 1.69 and 1.28 V vs. SCE. The potential difference ?E = 410 mV and the intervalence-charge-transfer (IVCT) transition at 2472 nm indicate a high degree of electronic interaction between the two ruthenium ions mediated through the tape bridging ligand. All three complexes, [1]2+, [2]2+, and [3]4+, were characterized by UV/Vis spectroelectrochemistry. The monooxidized and monoreduced states, [1]3+, [2]3+, [3]5+, and [1]+, [2]+, [3]3+, are accessible by reversible one-electron oxidation and one-electron reduction processes, respectively, as documented by the observation of several stable isosbestic points in the spectral progressions. The second reduction in each complex and the second oxidation in [3]4+ prove to be irreversible in these spectroelectrochemical experiments. Monoreduced species [1]+, [2]+, and [3]3+ yield EPR signals indicating that the unpaired electron is mainly centered on the large surface ligands dape or tape. KW - Ruthenium KW - Macrocyclic li-gands KW - N ligands KW - Redox chemistry KW - Mixed-valent compounds Y1 - 2012 U6 - https://doi.org/10.1002/ejic.201200667 SN - 1434-1948 IS - 29 SP - 4632 EP - 4643 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Brietzke, Thomas Martin A1 - Mickler, Wulfhard A1 - Kelling, Alexandra A1 - Holdt, Hans-Jürgen T1 - Mono- and dinuclear ruthenium(II) 1,6,7,12-tetraazaperylene complexes JF - Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry N2 - We report the synthesis of free 1,6,7,12-tetraazaperylene (tape). Tape was obtained from 1,1'-bis-2,7-naphthyridine by potassium promoted cyclization followed by oxidation with air. Mono-and dinuclear ruthenium(II) 1,6,7,12-tetraazaperylene complexes of the general formulas [Ru(L-L)(2)(tape)](PF6)(2), [1] (PF6)(2)-[5](PF6)(2), and [{Ru(L-L)(2)}(2)(mu-tape)](PF6)(4), [6](PF6)(4)-[10](PF6)(4), with{L-L = phen, bpy, dmbpy (4,4'-dimethyl-2,2'-bipyridine), dtbbpy (4,4'-ditertbutyl-2,2'-bipyridine) and tmbpy (4,4' 5,5'-tetramethyl-2,2'- bipyridine)}, respectively, were synthesized. The X-ray structures of tape center dot 2CHCl(3) and the mononuclear complexes [Ru(bpy)(2)(tape)](PF6)(2)center dot 0.5CH(3)CN center dot 0.5toluene, [Ru(dmbpy)(2)(tape)] (PF6)(2)center dot 2toluene and [Ru(dtbbpy)(2)(tape)](PF6)(2) center dot 3acetone center dot 0.5H(2)O were solved. The UV-vis absorption spectra and the electrochemical behavior of the ruthenium(II) tape complexes were explored and compared with the data of the analogous dibenzoeilatin (dbneil), 2,2'-bipyrimidine (bpym) and tetrapyrido [3,2-a:2',3'-c:3 '',2''-h:2''',3'''-j] phenazin (tpphz) species. Y1 - 2012 U6 - https://doi.org/10.1039/c2dt11805j SN - 1477-9226 VL - 41 IS - 9 SP - 2788 EP - 2797 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Breuninger, Holger A1 - Lenhard, Michael T1 - Expression of the central growth regulator BIG BROTHER is regulated by multiple cis-elements JF - BMC PLANT BIOLOGY N2 - Background: Much of the organismal variation we observe in nature is due to differences in organ size. The observation that even closely related species can show large, stably inherited differences in organ size indicates a strong genetic component to the control of organ size. Despite recent progress in identifying factors controlling organ growth in plants, our overall understanding of this process remains limited, partly because the individual factors have not yet been connected into larger regulatory pathways or networks. To begin addressing this aim, we have studied the upstream regulation of expression of BIG BROTHER (BB), a central growth-control gene in Arabidopsis thaliana that prevents overgrowth of organs. Final organ size and BB expression levels are tightly correlated, implying the need for precise control of its expression. BB expression mirrors proliferative activity, yet the gene functions to limit proliferation, suggesting that it acts in an incoherent feedforward loop downstream of growth activators to prevent over-proliferation. Results: To investigate the upstream regulation of BB we combined a promoter deletion analysis with a phylogenetic footprinting approach. We were able to narrow down important, highly conserved, cis-regulatory elements within the BB promoter. Promoter sequences of other Brassicaceae species were able to partially complement the A. thaliana bb-1 mutant, suggesting that at least within the Brassicaceae family the regulatory pathways are conserved. Conclusions: This work underlines the complexity involved in precise quantitative control of gene expression and lays the foundation for identifying important upstream regulators that determine BB expression levels and thus final organ size. Y1 - 2012 U6 - https://doi.org/10.1186/1471-2229-12-41 SN - 1471-2229 VL - 12 PB - BIOMED CENTRAL LTD CY - LONDON ER - TY - JOUR A1 - Breitenbach, Sebastian Franz Martin A1 - Rehfeld, Kira A1 - Goswami, Bedartha A1 - Baldini, James U. L. A1 - Ridley, H. E. A1 - Kennett, D. J. A1 - Prufer, K. M. A1 - Aquino, Valorie V. A1 - Asmerom, Yemane A1 - Polyak, V. J. A1 - Cheng, Hai A1 - Kurths, Jürgen A1 - Marwan, Norbert T1 - Constructing Proxy Records from Age models (COPRA) JF - Climate of the past : an interactive open access journal of the European Geosciences Union N2 - Reliable age models are fundamental for any palaeoclimate reconstruction. Available interpolation procedures between age control points are often inadequately reported, and very few translate age uncertainties to proxy uncertainties. Most available modeling algorithms do not allow incorporation of layer counted intervals to improve the confidence limits of the age model in question. We present a framework that allows detection and interactive handling of age reversals and hiatuses, depth-age modeling, and proxy-record reconstruction. Monte Carlo simulation and a translation procedure are used to assign a precise time scale to climate proxies and to translate dating uncertainties to uncertainties in the proxy values. The presented framework allows integration of incremental relative dating information to improve the final age model. The free software package COPRA1.0 facilitates easy interactive usage. Y1 - 2012 U6 - https://doi.org/10.5194/cp-8-1765-2012 SN - 1814-9324 VL - 8 IS - 5 SP - 1765 EP - 1779 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Braun, W. A1 - Pikovskij, Arkadij A1 - Matias, M. A. A1 - Colet, P. T1 - Global dynamics of oscillator populations under common noise JF - epl : a letters journal exploring the frontiers of physics N2 - Common noise acting on a population of identical oscillators can synchronize them. We develop a description of this process which is not limited to the states close to synchrony, but provides a global picture of the evolution of the ensembles. The theory is based on the Watanabe-Strogatz transformation, allowing us to obtain closed stochastic equations for the global variables. We show that at the initial stage, the order parameter grows linearly in time, while at the later stages the convergence to synchrony is exponentially fast. Furthermore, we extend the theory to nonidentical ensembles with the Lorentzian distribution of natural frequencies and determine the stationary values of the order parameter in dependence on driving noise and mismatch. Y1 - 2012 U6 - https://doi.org/10.1209/0295-5075/99/20006 SN - 0295-5075 VL - 99 IS - 2 PB - EDP Sciences CY - Mulhouse ER - TY - JOUR A1 - Braun, Christina A1 - Mustafa, Osama A1 - Nordt, Anja A1 - Pfeiffer, Simone A1 - Peter, Hans-Ulrich T1 - Environmental monitoring and management proposals for the Fildes Region, King George Island, Antarctica JF - Polar research : a Norwegian journal of Polar research N2 - The Antarctic terrestrial environment is under increasing pressure from human activities. The Fildes Region is characterized by high biodiversity, but is also a major logistic centre for the northern Antarctic Peninsula. Different interests, from scientific research, nature conservation, protection of geological and historical values, station operations, transport logistics and tourism, regularly overlap in space and time. This has led to increasing conflict among the multiple uses of the region and breaches of the legal requirements for environmental protection that apply in the area. The aim of this study was to assess the impacts of human activities in the Fildes Region by monitoring the distribution of bird and seal breeding sites and recording human activities and their associated environmental impacts. Data from an initial monitoring period 2003-06 were compared with data from 2008-10. We observed similar or increased levels of air, land and ship traffic, but fewer violations of overflight limits near Antarctic Specially Protected Area No. 150 Ardley Island. Open waste dumping and oil contamination are still major environmental impacts. Scientific and outdoor leisure activities undertaken by station personnel are more frequent than tourist activities and are likely to have a commensurate level of environmental impact. Despite the initial success of some existing management measures, it is essential that scientific and environmental values continue to be safeguarded, otherwise environmental impacts will increase and the habitat will be further degraded. We argue that the Fildes Region should be considered for designation as an Antarctic Specially Managed Area, a measure that has proven effective for environmental management of vulnerable areas of the Antarctic. KW - human impact KW - Antarctic KW - Fildes Region KW - environmental management KW - Antarctic Specially Managed Area KW - protected area Y1 - 2012 U6 - https://doi.org/10.3402/polar.v31i0.18206 SN - 0800-0395 VL - 31 IS - 209 PB - Co-Action Publ. CY - Jarfalla ER - TY - JOUR A1 - Bramborg, Andrea A1 - Linker, Torsten T1 - Regioselective synthesis of alkylarenes by two-step ipso-substitution of aromatic dicarboxylic acids JF - European journal of organic chemistry N2 - A strategy for the regioselective alkylation of arenes was developed, starting from commercially available and inexpensive terephthalic acid or naphthalene-1,4-dicarboxylic acid. The method entails a formal ipso-substitution of the carboxylate groups by a sequence of reductive alkylation under Birch conditions and subsequent acid-mediated rearomatization with loss of carbon monoxide and carbon dioxide. More than 20 different arenes with various side-chains were synthesized. With naphthalene-1,4-dicarboxylic acid as starting material, we were able to control the degree of alkylation by choosing the appropriate electrophile in the Birch reduction. Thus, bisalkylated naphthalenes and naphthoic acids became available chemoselectively. All reactions afforded a single regioisomer exclusively in high yields. Overall, aromatic dicarboxylic acids are suitable substrates for a two-step ipso-substitution that allows the selective synthesis of alkylated benzenes and naphthalenes. KW - Synthetic methods KW - Alkylation KW - Birch reduction KW - Arenes KW - Regioselectivity Y1 - 2012 U6 - https://doi.org/10.1002/ejoc.201200823 SN - 1434-193X IS - 28 SP - 5552 EP - 5563 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Braeuer, B. A1 - Asch, Günter A1 - Hofstetter, Rami A1 - Haberland, Christian A1 - Jaser, Darweesh A1 - El-Kelani, Radwan J.. A1 - Weber, Michael H. T1 - Microseismicity distribution in the southern Dead Sea basin and its implications on the structure of the basin JF - Geophysical journal international N2 - While the Dead Sea basin has been studied for a long time, the available knowledge about the detailed seismicity distribution in the area, as well as the deeper structure of the basin, is limited. Therefore, within the framework of the international project DESIRE (DEad Sea Integrated REsearch project), a dense temporary local seismological network was operated in the southern Dead Sea area. We use 530 local earthquakes, having all together 26 730 P- and S-arrival times for a simultaneous inversion of 1-D velocity models, station corrections and precise earthquake locations. Jackknife tests suggest an accuracy of the derived hypocentre locations of about 1 km. Thus, the result is the first clear image of the absolute distribution of the microseismicity of the area, especially in depth. The seismicity is concentrated in the upper crust down to 20 km depth while the lower limit of the seismicity is reached at 31 km depth. The seismic events at the eastern boundary fault (EBF) in the southern part of the study area represent the northward transform motion of the Arabian Plate along the Dead Sea Transform. North of the Boqeq fault the seismic activity represents the transfer of the motion in the pull-apart basin from the eastern to the western boundary. We find that from the surface downward the seismic events are tracing the boundary faults of the basin. The western boundary is mapped down to 12 km depth while the EBF reaches about 17 km depth, forming an asymmetric basin. One fifth of the data set is related to a specific cluster in time and space, which occurred in 2007 February at the western border fault. This cluster is aligned vertically, that is, it is perpendicular to the direction of the dominating left-lateral strike-slip movement at the main transform fault. KW - Seismicity and tectonics KW - Continental tectonics: strike-slip and transform KW - Asia Y1 - 2012 U6 - https://doi.org/10.1111/j.1365-246X.2011.05318.x SN - 0956-540X VL - 188 IS - 3 SP - 873 EP - 878 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Bouakline, Foudhil A1 - Lüder, Franziska A1 - Martinazzo, Rocco A1 - Saalfrank, Peter T1 - Reduced and exact quantum dynamics of the vibrational relaxation of a molecular system interacting with a finite-dimensional bath JF - The journal of physical chemistry : A, Molecules, spectroscopy, kinetics, environment & general theory N2 - We investigate the vibrational relaxation of a Morse oscillator, nonlinearly coupled to a finite-dimensional bath of harmonic oscillators at zero temperature, using two different approaches: Reduced dynamics with the help of the Lindblad formalism of reduced density matrix theory in combination with Fermi's Golden Rule, and exact dynamics (within the chosen model). with the multiconfiguration time-dependent Hartree (MCTDH) method. Two different models have been constructed, the situation where the bath spectrum is exactly resonant with the anharmonic oscillator transition frequencies, and the case for which the subsystem is slightly off-resonant with the environment. At short times, reduced dynamics calculations describe the relaxation process qualitatively well but fail to reproduce recurrences observed with MCTDH for longer times. Lifetimes of all the vibrational levels of the Morse oscillator have been calculated, and both Lindblad and MCTDH. results show the same dependence of the lifetimes on the initial vibrational state quantum number. A prediction, which should be generic for adsorbate systems is a striking, sharp increase of lifetimes of the subsystem vibrational levels close to the dissociation This is contradictory with harmonic/linear extrapolation laws, which predict a monotonic decrease of the lifetime with initial vibrational quantum number. Y1 - 2012 U6 - https://doi.org/10.1021/jp304466u SN - 1089-5639 VL - 116 IS - 46 SP - 11118 EP - 11127 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Bordihn, Henning A1 - Kutrib, Martin A1 - Malcher, Andreas T1 - On the computational capacity of parallel communicating finite automata JF - International journal of foundations of computer science N2 - Systems of parallel finite automata communicating by states are investigated. We consider deterministic and nondeterministic devices and distinguish four working modes. It is known that systems in the most general mode are as powerful as one-way multi-head finite automata. Here we solve some open problems on the computational capacity of systems working in the remaining modes. In particular, it is shown that deterministic returning and non-returning devices are equivalent, and that there are languages which are accepted by deterministic returning and centralized systems but cannot be accepted by deterministic non-returning centralized systems. Furthermore, we show that nondeterministic systems are strictly more powerful than their deterministic variants in all the four working modes. Finally, incomparability with the classes of (deterministic) (linear) context-free languages as well as the Church-Rosser languages is derived. KW - Automata systems KW - cooperating systems KW - formal languages KW - theory of computation Y1 - 2012 U6 - https://doi.org/10.1142/S0129054112500062 SN - 0129-0541 VL - 23 IS - 3 SP - 713 EP - 732 PB - World Scientific CY - Singapore ER - TY - JOUR A1 - Borchardt, Sven A1 - Trauth, Martin H. T1 - Remotely-sensed evapotranspiration estimates for an improved hydrological modeling of the early holocene mega-lake Suguta, northern Kenya Rift JF - Palaeogeography, palaeoclimatology, palaeoecology : an international journal for the geo-sciences N2 - The actual evapotranspiration is an important, but difficult to determine, element in the water balance of lakes and their catchment areas. Reliable data on evapotranspiration are not available for most lake basins for which paleoclimate reconstructions and modeling have been performed, particularly those in remote parts of Africa. We have used thermal infrared multispectral data for 14 ASTER scenes from the TERRA satellite to estimate the actual evapotranspiration in the 12,800 km(2) catchment of the Suguta Valley, northern Kenya Rift Evidence from sediments and paleo-shorelines indicates that, during the African Humid Period (AHP, 14.8 to 5.5 kyrs BP), this valley contained a large lake, 280 m deep and covering similar to 2200 km(2), which has now virtually disappeared. Evapotranspiration estimates for the Suguta Basin were generated using the Surface Energy Balance Algorithm for Land (SEBAL). Climate data required for the model were extracted from a high-resolution gridded dataset obtained from the Climatic Research Unit (East Anglia, UK). Results suggest significant spatial variations in evapotranspiration within the catchment area (ranging from 450 mm/yr in the basin to the north to 2000 mm/yr in more elevated areas) and precipitation that was similar to 20% higher during the AHP than in recent times. These results are in agreement with other estimates of paleo-precipitation in East Africa. The extreme response of the lake system (similar to 280 m greater water depth than today, and a lake surface area of 2200 km(2)) to only moderately higher precipitation illustrates the possible sensitivity of this area to future climate change. KW - Actual evapotranspiration KW - Remote sensing KW - Water balance model KW - East African Rift KW - Kenya KW - SEBAL Y1 - 2021 U6 - https://doi.org/10.1016/j.palaeo.2012.07.009 SN - 0031-0182 VL - 361 IS - 22 SP - 14 EP - 20 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Bookhagen, Bodo A1 - Strecker, Manfred T1 - Spatiotemporal trends in erosion rates across a pronounced rainfall gradient: Examples from the southern Central Andes JF - Earth & planetary science letters N2 - The tectonic and climatic boundary conditions of the broken foreland and the orogen interior of the southern Central Andes of northwestern Argentina cause strong contrasts in elevation, rainfall, and surface-process regimes. The climatic gradient in this region ranges from the wet, windward eastern flanks (similar to 2 m/yr rainfall) to progressively drier western basins and ranges (similar to 0.1 m/yr) bordering the arid Altiplano-Puna Plateau. In this study, we analyze the impact of spatiotemporal climatic gradients on surface erosion: First, we present 41 new catchment-mean erosion rates derived from cosmogenic nuclide inventories to document spatial erosion patterns. Second, we re-evaluate paleoclimatic records from the Calchaquies basin (66 W, 26 S), a large intermontane basin bordered by high (> 4.5 km) mountain ranges, to demonstrate temporal variations in erosion rates associated with changing climatic boundary conditions during the late Pleistocene and Holocene. Three key observations in this region emphasize the importance of climatic parameters on the efficiency of surface processes in space and time: (1) First-order spatial patterns of erosion rates can be explained by a simple specific stream power (SSP) approach. We explicitly account for discharge by routing high-resolution, satellite derived rainfall. This is important as the steep climatic gradient results in a highly non-linear relation between drainage area and discharge. This relation indicates that erosion rates (ER) scale with ER similar to SSP1.4 on cosmogenic-nuclide time scales. (2) We identify an intrinsic channel-slope behavior in different climatic compartments. Channel slopes in dry areas (< 0.25 m/yr rainfall) are slightly steeper than in wet areas (> 0.75 m/yr) with equal drainage areas, thus compensating lower amounts of discharge with steeper slopes. (3) Erosion rates can vary by an order of magnitude between presently dry (similar to 0.05 mm/yr) and well-defined late Pleistocene humid (similar to 0.5 mm/yr) conditions within an intemontane basin. Overall, we document a strong climatic impact on erosion rates and channel slopes. We suggest that rainfall reaching areas with steeper channel slopes in the orogen interior during wetter climate periods results in intensified sediment mass transport, which is primarily responsible for maintaining the balance between surface uplift, erosion, sediment routing and transient storage in the orogen. KW - erosion KW - landscape evolution KW - specific stream power KW - cosmogenic radionuclides KW - paleoclimate KW - climate-tectonic feedback processes Y1 - 2012 U6 - https://doi.org/10.1016/j.epsl.2012.02.005 SN - 0012-821X VL - 327 IS - 8 SP - 97 EP - 110 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Bonaventura, Klaus A1 - Leber, Alexander W. A1 - Sohns, Christian A1 - Roser, Mattias A1 - Boldt, Leif-Hendrik A1 - Kleber, Franz X. A1 - Haverkamp, Wilhelm A1 - Dorenkamp, Marc T1 - Cost-effectiveness of paclitaxel-coated balloon angioplasty and paclitaxel-eluting stent implantation for treatment of coronary in-stent restenosis in patients with stable coronary artery disease JF - Clinical research in cardiology : official journal of the German Cardiac Society. N2 - Recent studies have demonstrated the safety and efficacy of drug-coated balloon (DCB) angioplasty for the treatment of coronary in-stent restenosis (ISR). The cost-effectiveness of this practice is unknown. A Markov state-transition decision analytic model accounting for varying procedural efficacy rates, complication rates, and cost estimates was developed to compare DCB angioplasty with drug-eluting stent (DES) placement in patients with bare-metal stent (BMS)-ISR. Data on procedural outcomes associated with both treatment strategies were derived from the literature, and the cost analysis was conducted from a health care payer perspective. Effectiveness was expressed as life-years gained. In the base-case analysis, initial procedure costs amounted to a,not sign3,604.14 for DCB angioplasty and to a,not sign3,309.66 for DES implantation. Over a 12-month time horizon, the DCB strategy was found to be less costly (a,not sign4,130.38 vs. a,not sign5,305.30) and slightly more effective in terms of life expectancy (0.983 vs. 0.976 years) than the DES strategy. Extensive sensitivity analyses indicated that, in comparison with DES implantation, the cost advantage of the DCB strategy was robust to clinically plausible variations in the values of key model input parameters. The variables with the greatest impact on base-case results were the duration of dual antiplatelet therapy with acetylsalicylic acid and clopidogrel after DCB angioplasty, the use of generic clopidogrel, and variations in the costs associated with the DCB device. DCB angioplasty is a cost-effective treatment option for coronary BMS-ISR. The higher initial costs of DCB are more than offset by later cost-savings, predominantly as a result of reduced medication costs. KW - Cost-effectiveness KW - Drug-coated balloon KW - Drug-eluting stent KW - Restenosis KW - Revascularization Y1 - 2012 U6 - https://doi.org/10.1007/s00392-012-0428-2 SN - 1861-0684 VL - 101 IS - 7 SP - 573 EP - 584 PB - Springer CY - Heidelberg ER - TY - JOUR A1 - Bomm, Jana A1 - Günter, Christina A1 - Stumpe, Joachim T1 - Synthesis and optical characterization of thermosensitive, luminescent gold nanodots JF - The journal of physical chemistry : C, Nanomaterials and interfaces N2 - A facile one-pot synthesis for preparing thermosensitive, luminescent gold nanodots with diameters of 1-2 nm is presented. The influence of the alkyl chain length of the surface ligands (alkyl thiols) on the optical properties of the gold nanodots was investigated. The synthesized gold nanodots show strong thermosensitive photoluminescence. A photoluminescence quantum yield of 16.6% was observed at room temperature, which could be improved to a value of 28.6% when cooling the gold nanodot solutions to -7 degrees C. The synthesized thermosensitive, luminescent gold nanodots are interesting candidates for optoelectronic devices, medical imaging, sensing, or security labels. Y1 - 2012 U6 - https://doi.org/10.1021/jp206260r SN - 1932-7447 VL - 116 IS - 1 SP - 81 EP - 85 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Bojahr, Andre A1 - Schick, Daniel A1 - Märten, Lena A1 - Herzog, Marc A1 - Vrejoiu, Ionela A1 - von Korff Schmising, Clemens A1 - Milne, Chris A1 - Johnson, Steven Lee A1 - Bargheer, Matias T1 - Comparing the oscillation phase in optical pump-probe spectra to ultrafast x-ray diffraction in the metal-dielectric SrRuO3/SrTiO3 superlattice JF - Physical review : B, Condensed matter and materials physics N2 - We measured the ultrafast optical response of metal-dielectric superlattices by broadband all-optical pump-probe spectroscopy. The observed phase of the superlattice mode depends on the probe wavelength, making assignments of the excitation mechanism difficult. Ultrafast x-ray diffraction data reveal the true oscillation phase of the lattice which changes as a function of the excitation fluence. This result is confirmed by the fluence dependence of optical transients. We set up a linear chain model of the lattice dynamics and successfully simulated the broadband optical reflection by unit-cell resolved calculation of the strain-dependent dielectric functions of the constituting materials. Y1 - 2012 U6 - https://doi.org/10.1103/PhysRevB.85.224302 SN - 1098-0121 VL - 85 IS - 22 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Bojahr, Andre A1 - Herzog, Marc A1 - Schick, Daniel A1 - Vrejoiu, Ionela A1 - Bargheer, Matias T1 - Calibrated real-time detection of nonlinearly propagating strain waves JF - Physical review : B, Condensed matter and materials physics N2 - Epitaxially grown metallic oxide transducers support the generation of ultrashort strain pulses in SrTiO3 (STO) with high amplitudes up to 0.5%. The strain amplitudes are calibrated by real-time measurements of the lattice deformation using ultrafast x-ray diffraction. We determine the speed at which the strain fronts propagate by broadband picosecond ultrasonics and conclude that, above a strain level of approx. 0.2%, the compressive and tensile strain components travel at considerably different sound velocities, indicating nonlinear wave behavior. Simulations based on an anharmonic linear-chain model are in excellent accord with the experimental findings and show how the spectrum of coherent phonon modes changes with time. Y1 - 2012 U6 - https://doi.org/10.1103/PhysRevB.86.144306 SN - 1098-0121 VL - 86 IS - 14 PB - American Physical Society CY - College Park ER -