TY - JOUR A1 - Komarov, Maxim A1 - Bazhenov, Maxim T1 - Linking dynamics of the inhibitory network to the input structure JF - Journal of computational neuroscience KW - Inhibitory neurons KW - Information coding KW - Neural network KW - Olfactory system KW - Spike sequences KW - Odor discrimination Y1 - 2016 U6 - https://doi.org/10.1007/s10827-016-0622-8 SN - 0929-5313 SN - 1573-6873 VL - 41 SP - 367 EP - 391 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Kopyshev, Alexey A1 - Galvin, Casey J. A1 - Genzer, Jan A1 - Lomadze, Nino A1 - Santer, Svetlana T1 - Polymer brushes modified by photosensitive azobenzene containing polyamines JF - Polymer : the international journal for the science and technology of polymers N2 - This paper describes a strategy for preparing photosensitive polymeric grafts on flat solid surfaces by loading diblock-copolymer or homopolymer brushes with cationic azobenzene-containing surfactants. In contrast to previous work, we utilize photosensitive surfactants that bear positively-charged polyamine head groups whose charge varies between 1(+) and 3(+). Poly(methylmethacrylate-b-methacrylic acid) (PMMA-b-PMAA) brushes were prepared by employing atom transfer radical polymerization, where the bottom poly(methyl methacrylate) block was grown first followed by the synthesis of t-butyl methacrylate block that after de-protection yielded poly(methacrylic acid). We used PMMA-b-PMAA brushes with constant grafting density and length of the PMMA block, and three different lengths of the PMAA block. The azobenzene-based surfactants attached only to the PMAA block. The degree of binding (i.e., the number of surfactant molecules per binding site on the brush backbone) of the surfactants to the brush depends strongly on the valence of the surfactant head-group; within the brushes the concentration of the surfactant carrying unit charge is larger than that of multivalent surfactants. We detect pronounced response of the brush topography on irradiation with UV interference pattern even at very low degree of binding (as small as 0.08) of multi-valence surfactant. Areas on the sample that receive the highest UV dose exhibit chain scission. By removing the ruptured chains from the substrate via good solvent, one uncovers a surface topographical relief grating, whose spatial arrangement follows the intensity distribution of the UV light on the sample during irradiation. Due to strong coupling of the multi-valence surfactants to the polymer brush, it was possible in some cases to completely remove the polyelectrolyte block from the PMMA layer. The application of multi-valence azobenzene surfactants for triggering brush photosensitive has important advantage over usage of surfactant with unit charge because relative to single-valence surfactants much lower concentrations of the multivalent surfactant are needed to achieve comparable response upon UV irradiation. (C) 2016 Elsevier Ltd. All rights reserved. KW - Photosensitive brushes KW - Photosensitive azobenzene containing polyamines Y1 - 2016 U6 - https://doi.org/10.1016/j.polymer.2016.03.050 SN - 0032-3861 SN - 1873-2291 VL - 98 SP - 421 EP - 428 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Kopyshev, Alexey A1 - Galvin, Casey J. A1 - Patil, Rohan R. A1 - Genzer, Jan A1 - Lomadze, Nino A1 - Feldmann, David A1 - Zakrevski, Juri A1 - Santer, Svetlana T1 - Light-Induced Reversible Change of Roughness and Thickness of Photosensitive Polymer Brushes JF - Applied physics : A, Materials science & processing N2 - We investigate light-induced changes in thickness and roughness of photosensitive polymer brushes containing azobenzene cationic surfactants by atomic force microscopy (AFM) in real time during light irradiation. Because the cis-state of azobenzene unit requires more free volume than its trans counterpart, the UV light-induced expansion of polymer thin films associated with the trans-to-cis isomerism of azobenzene groups is expected to occur. This phenomenon is well documented in physisorbed polymer films containing azobenzene groups. In contrast, photosensitive polymer brushes show a decrease in thickness under UV irradiation. We have found that the azobenzene surfactants in their trans-state form aggregates within the brush. Under irradiation, the surfactants undergo photoisomerization to the cis-state, which is more hydrophilic. As a consequence, the aggregates within the brush are disrupted, and the polymer brush contracts. When subsequently irradiated with blue light the polymer brush thickness returns back to its initial value. This behavior is related to isomerization of the surfactant to the more hydrophobic trans-state and subsequent formation of surfactant aggregates within the polymer brush. The photomechanical function of the dry polymer brush, i.e., contraction and expansion, was found to be reversible with repeated irradiation cycles and requires only a few seconds for switching. In addition to the thickness change, the roughness of the brush also changes reversibly between a few Angstroms (blue light) and several nanometers (UV light). Photosensitive polymer brushes represent smart films with light responsive thickness and roughness that could be used for generating dynamic fluctuating surfaces, the function of which can be turned on and off in a controllable manner on a nanometer length scale. KW - photosensitive brushes KW - azobenzene containing surfactants KW - light driven reversible change of surface topography and thickness KW - domain memory in polymer brushes KW - orientation of azobenzenes in polymer brushes Y1 - 2016 U6 - https://doi.org/10.1021/acsami.6b06881 SN - 1944-8244 VL - 8 SP - 19175 EP - 19184 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Kretschmer, Marlene A1 - Coumou, Dim A1 - Donges, Jonathan A1 - Runge, Jakob T1 - Using Causal Effect Networks to Analyze Different Arctic Drivers of Midlatitude Winter Circulation JF - Journal of climate N2 - In recent years, the Northern Hemisphere midlatitudes have suffered from severe winters like the extreme 2012/13 winter in the eastern United States. These cold spells were linked to a meandering upper-tropospheric jet stream pattern and a negative Arctic Oscillation index (AO). However, the nature of the drivers behind these circulation patterns remains controversial. Various studies have proposed different mechanisms related to changes in the Arctic, most of them related to a reduction in sea ice concentrations or increasing Eurasian snow cover. Here, a novel type of time series analysis, called causal effect networks (CEN), based on graphical models is introduced to assess causal relationships and their time delays between different processes. The effect of different Arctic actors on winter circulation on weekly to monthly time scales is studied, and robust network patterns are found. Barents and Kara sea ice concentrations are detected to be important external drivers of the midlatitude circulation, influencing winter AO via tropospheric mechanisms and through processes involving the stratosphere. Eurasia snow cover is also detected to have a causal effect on sea level pressure in Asia, but its exact role on AO remains unclear. The CEN approach presented in this study overcomes some difficulties in interpreting correlation analyses, complements model experiments for testing hypotheses involving teleconnections, and can be used to assess their validity. The findings confirm that sea ice concentrations in autumn in the Barents and Kara Seas are an important driver of winter circulation in the midlatitudes. Y1 - 2016 U6 - https://doi.org/10.1175/JCLI-D-15-0654.1 SN - 0894-8755 SN - 1520-0442 VL - 29 SP - 4069 EP - 4081 PB - American Meteorological Soc. CY - Boston ER - TY - JOUR A1 - Kroll, Thomas A1 - Kern, Jan A1 - Kubin, Markus A1 - Ratner, Daniel A1 - Gul, Sheraz A1 - Fuller, Franklin D. A1 - Löchel, Heike A1 - Krzywinski, Jacek A1 - Lutman, Alberto A1 - Ding, Yuantao A1 - Dakovski, Georgi L. A1 - Moeller, Stefan A1 - Turner, Joshua J. A1 - Alonso-Mori, Roberto A1 - Nordlund, Dennis L. A1 - Rehanek, Jens A1 - Weniger, Christian A1 - Firsov, Alexander A1 - Brzhezinskaya, Maria A1 - Chatterjee, Ruchira A1 - Lassalle-Kaiser, Benedikt A1 - Sierra, Raymond G. A1 - Laksmono, Hartawan A1 - Hill, Ethan A1 - Borovik, Andrew S. A1 - Erko, Alexei A1 - Föhlisch, Alexander A1 - Mitzner, Rolf A1 - Yachandra, Vittal K. A1 - Yano, Junko A1 - Wernet, Philippe A1 - Bergmann, Uwe T1 - X-ray absorption spectroscopy using a self-seeded soft X-ray free-electron laser JF - Optics express : the international electronic journal of optics N2 - X-ray free electron lasers (XFELs) enable unprecedented new ways to study the electronic structure and dynamics of transition metal systems. L-edge absorption spectroscopy is a powerful technique for such studies and the feasibility of this method at XFELs for solutions and solids has been demonstrated. However, the required x-ray bandwidth is an order of magnitude narrower than that of self-amplified spontaneous emission (SASE), and additional monochromatization is needed. Here we compare L-edge x-ray absorption spectroscopy (XAS) of a prototypical transition metal system based on monochromatizing the SASE radiation of the linac coherent light source (LCLS) with a new technique based on self-seeding of LCLS. We demonstrate how L-edge XAS can be performed using the self-seeding scheme without the need of an additional beam line monochromator. We show how the spectral shape and pulse energy depend on the undulator setup and how this affects the x-ray spectroscopy measurements. (C) 2016 Optical Society of America Y1 - 2016 U6 - https://doi.org/10.1364/OE.24.022469 SN - 1094-4087 VL - 24 SP - 22469 EP - 22480 PB - Optical Society of America CY - Washington ER - TY - JOUR A1 - Kronberg, Elena A. A1 - Rashev, M. V. A1 - Daly, P. W. A1 - Shprits, Yuri Y. A1 - Turner, D. L. A1 - Drozdov, Alexander A1 - Dobynde, M. A1 - Kellerman, Adam C. A1 - Fritz, T. A. A1 - Pierrard, V. A1 - Borremans, K. A1 - Klecker, B. A1 - Friedel, R. T1 - Contamination in electron observations of the silicon detector on board JF - Space Weather: The International Journal of Research and Applications N2 - Since more than 15 years, the Cluster mission passes through Earth's radiation belts at least once every 2 days for several hours, measuring the electron intensity at energies from 30 to 400 keV. These data have previously been considered not usable due to contamination caused by penetrating energetic particles (protons at >100 keV and electrons at >400 keV). In this study, we assess the level of distortion of energetic electron spectra from the Research with Adaptive Particle Imaging Detector (RAPID)/Imaging Electron Spectrometer (IES) detector, determining the efficiency of its shielding. We base our assessment on the analysis of experimental data and a radiation transport code (Geant4). In simulations, we use the incident particle energy distribution of the AE9/AP9 radiation belt models. We identify the Roederer L values, L⋆, and energy channels that should be used with caution: at 3≤L⋆≤4, all energy channels (40–400 keV) are contaminated by protons (≃230 to 630 keV and >600 MeV); at L⋆≃1 and 4–6, the energy channels at 95–400 keV are contaminated by high-energy electrons (>400 keV). Comparison of the data with electron and proton observations from RBSP/MagEIS indicates that the subtraction of proton fluxes at energies ≃ 230–630 keV from the IES electron data adequately removes the proton contamination. We demonstrate the usefulness of the corrected data for scientific applications. Y1 - 2016 U6 - https://doi.org/10.1002/2016SW001369 SN - 1542-7390 VL - 14 SP - 449 EP - 462 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Kruesemann, Henning A1 - Schwarzl, Richard A1 - Metzler, Ralf T1 - Ageing Scher-Montroll Transport JF - Transport in Porous Media N2 - We study the properties of ageing Scher-Montroll transport in terms of a biased subdiffusive continuous time random walk in which the waiting times between consecutive jumps of the charge carriers are distributed according to the power law probability with . As we show, the dynamical properties of the Scher-Montroll transport depend on the ageing time span between the initial preparation of the system and the start of the observation. The Scher-Montroll transport theory was originally shown to describe the photocurrent in amorphous solids in the presence of an external electric field, but it has since been used in many other fields of physical sciences, in particular also in the geophysical context for the description of the transport of tracer particles in subsurface aquifers. In the absence of ageing () the photocurrent of the classical Scher-Montroll model or the breakthrough curves in the groundwater context exhibit a crossover between two power law regimes in time with the scaling exponents and . In the presence of ageing a new power law regime and an initial plateau regime of the current emerge. We derive the different power law regimes and crossover times of the ageing Scher-Montroll transport and show excellent agreement with simulations of the process. Experimental data of ageing Scher-Montroll transport in polymeric semiconductors are shown to agree well with the predictions of our theory. KW - Anomalous diffusion KW - Ageing KW - Scher-Montroll transport Y1 - 2016 U6 - https://doi.org/10.1007/s11242-016-0686-y SN - 0169-3913 SN - 1573-1634 VL - 115 SP - 327 EP - 344 PB - Springer CY - New York ER - TY - THES A1 - Krüsemann, Henning T1 - First passage phenomena and single-file motion in ageing continuous time random walks and quenched energy landscapes N2 - In der Physik gibt es viele Prozesse, die auf Grund ihrer Komplexität nicht durch physikalische Gleichungen beschrieben werden können, beispielsweise die Bewegung eines Staubkorns in der Luft. Durch die vielen Stöße mit Luftmolekülen führt es eine Zufallsbewegung aus, die so genannte Diffusion. Auch Moleküle in biologischen Zellen diffundieren, jedoch befinden sich in einer solchen Zelle im selben Volumen viel mehr oder viel größere Moleküle. Das beobachtete Teilchen stößt dementsprechend öfter mit anderen zusammen und die Diffusion wird langsamer, sie wird subdiffusiv. Mit der Zeit kann sich die Charakteristik der Subdiffusion ändern; dies wird als (mikroskopisches) Altern bezeichnet. Ich untersuche in der vorliegenden Arbeit zwei mathematische Modelle für eindimensionale Subdiffusion, einmal den continuous time random walk (CTRW) und einmal die Zufallsbewegung in einer eingefrorenen Energielandschaft (QEL=quenched energy landscape). Beide sind Sprungprozesse, das heißt, sie sind Abfolgen von räumlichen Sprüngen, die durch zufallsverteilte Wartezeiten getrennt sind. Die Wartezeiten in der QEL sind räumlich korrelliert, während sie im CTRW unkorrelliert sind. Ich untersuche in der vorliegenden Arbeit verschiedene statistische Größen in beiden Modellen. Zunächst untersuche ich den Einfluss des Alters und den Einfluss der Korrellationen einer QEL auf die Verteilung der Zeiten, die das diffundierendes Teilchen benötigt, um eine (räumliche) Schwelle zu überqueren. Ausserdem bestimme ich den Effekt des Alters auf Ströme von (sub)diffundierenden Partikeln, die sich auf eine absorbierende Barriere zubewegen. Zuletzt beschäftige ich mich mit der Diffusion einer eindimensionalen Anordnung von Teilchen in einer QEL, in der diese als harte Kugeln miteinander wechselwirken. Dabei vergleiche ich die gemeinsame Bewegung in einer QEL und als individuelle CTRWs miteinander über die Standartabweichung von der Startposition, für die ich das Mittel über mehrere QELs untersuche. Meine Arbeit setzt sich zusammen aus theoretischen Überlegungen und Berechnungen sowie der Simulation der Zufallsprozesse. Die Ergebnisse der Simulation und, soweit vorhanden, experimentelle Daten werden mit der Theorie verglichen. N2 - In the first part of my work I have investigated the ageing properties of the first passage time distributions in a one-dimensional subdiffusive continuous time random walk with power law distributed waiting times of the form $\psi(\tau) \sim \tau^{-1-\alpha}$ with $0<\alpha<1$ and $1<\alpha<2$. The age or ageing time $t_a$ is the time span from the start of the stochastic process to the start of the observation of this process (at $t=0$). I have calculated the results for a single target and two targets, also including the biased case, where the walker is driven towards the boundary by a constant force. I have furthermore refined the previously derived results for the non-ageing case and investigated the changes that occur when the walk is performed in a discrete quenched energy landscape, where the waiting times are fixed for every site. The results include the exact Laplace space densities and infinite (converging) series as exact results in the time space. The main results are the dominating long time power law behavior regimes, which depend on the ageing time. For the case of unbiased subdiffusion ($\alpha < 1$) in the presence of one target, I find three different dominant terms for ranges of $t$ separated by $t_a$ and another crossover time $t^{\star}$, which depends on $t_a$ as well as on the anomalous exponent $\alpha$ and the anomalous diffusion coefficient $K_{\alpha}$. In all three regimes ($t \ll t_a$, $t_a \ll t \ll t^{\star}$, $t \gg t^{\star}$) one finds power law decay with exponents depending on $\alpha$. The middle regime only exists for $t_a \ll t^{\star}$. The dominant terms in the first two regimes (ageing regimes) come from the probability distribution of the forward waiting time, the time one has to wait for the stochastic process to make the first step during the observation. When the observation time is larger than the second crossover time $t^{\star}$, the first passage time density does not show ageing and the non-ageing first passage time dominates. The power law exponents in the respective regimes are $-\alpha$ for strong ageing, $-1-\alpha$ in the intermediate regime, and $-1-\alpha/2$ in the final non-ageing regime. A similar split into three regimes can be found for $1<\alpha<2$, only with a different second crossover time $t^*$. In this regime the diffusion is normal but also age-dependent. For the diffusion in quenched energy landscapes one cannot detect ageing. The first passage time density shows a quenched power law $^\sim t^{-(1+2\alpha)/(1+\alpha)}$. For diffusion between two target sites and the biased diffusion towards a target only two scaling regimes emerge, separated by the ageing time. In the ageing case $t \ll t_a$ the forward waiting time is again dominant with power law exponent $-\alpha$, while the non-ageing power law $-1-\alpha$ is found for all times $t \gg t_a$. An intermediate regime does not exist. The bias and the confinement have similar effects on the first passage time density. For quenched diffusion, the biased case is interesting, as the bias reduces correlations due to revisiting of the same waiting time. As a result, CTRW like behavior is observed, including ageing. Extensive computer simulations support my findings. The second part of my research was done on the subject of ageing Scher-Montroll transport, which is in parts closely related to the first passage densities. It explains the electrical current in an amorphous material. I have investigated the effect of the width of a given initial distribution of charge carriers on the transport coefficients as well as the ageing effect on the emerging power law regimes and a constant initial regime. While a spread out initial distribution has only little impact on the Scher-Montroll current, ageing alters the behavior drastically. Instead of the two classical power laws one finds four current regimes, up to three of which can appear in a single experiment. The dominant power laws differ for $t \ll t_a, t_c$, $t_a \ll t \ll t_c$, $t_c \ll t \ll t_a$, and $t \gg t_a,t_c$. Here, $t_c$ is the crossover time of the non-aged Scher-Montroll current. For strongly aged systems one can observe a constant current in the first regime while the others are dominated by decaying power laws with exponents $\alpha -1$, $-\alpha$, and $-1-\alpha$. The ageing regimes are the 1st and 3rd one, while the classical regimes are the 2nd and the 4th. I have verified the theory using numerical integration of the exact integrals and applied the new results to experimental data. In the third part I considered a single file of subdiffusing particles in an energy landscape. Every occupied site of the landscape acts as a boundary, from which a particle is immediately reflected to its previous site, if it tries to jump there. I have analysed the effects single-file diffusion a quenched landscape compared to an annealed landscape and I have related these results to the number of steps and related quantities. The diffusion changes from ultraslow logarithmic diffusion in the annealed or CTRW case to subdiffusion with an anomalous exponent $\alpha/(1+\alpha)$ in the quenched landscape. The behavior is caused by the forward waiting time, which changes drastically from the quenched to the annealed case. Single-file effects in the quenched landscape are even more complicated to consider in the ensemble average, since the diffusion in individual landscapes shows extremely diverse behavior. Extensive simulations support my theoretical arguments, which consider mainly the long time evolution of the mean square displacement of a bulk particle. KW - continuous time random walk KW - quenched energy landscape KW - first passage time KW - Scher-Montroll transport KW - single-file motion KW - Zufallsbewegung KW - Diffusion KW - eingefrorene Energielandschaft KW - Scher-Montroll Transport KW - Wartezeitverteilung Y1 - 2016 ER - TY - JOUR A1 - Kuik, Friderike A1 - Lauer, Axel A1 - Churkina, Galina A1 - Van der Gon, Hugo A. C. Denier A1 - Fenner, Daniel A1 - Mar, Kathleen A. A1 - Butler, Tim M. T1 - Air quality modelling in the Berlin-Brandenburg region using WRF-Chem v3.7.1: sensitivity to resolution of model grid and input data JF - Geoscientific model development : an interactive open access journal of the European Geosciences Union N2 - Air pollution is the number one environmental cause of premature deaths in Europe. Despite extensive regulations, air pollution remains a challenge, especially in urban areas. For studying summertime air quality in the Berlin–Brandenburg region of Germany, the Weather Research and Forecasting Model with Chemistry (WRF-Chem) is set up and evaluated against meteorological and air quality observations from monitoring stations as well as from a field campaign conducted in 2014. The objective is to assess which resolution and level of detail in the input data is needed for simulating urban background air pollutant concentrations and their spatial distribution in the Berlin–Brandenburg area. The model setup includes three nested domains with horizontal resolutions of 15, 3 and 1 km and anthropogenic emissions from the TNO-MACC III inventory. We use RADM2 chemistry and the MADE/SORGAM aerosol scheme. Three sensitivity simulations are conducted updating input parameters to the single-layer urban canopy model based on structural data for Berlin, specifying land use classes on a sub-grid scale (mosaic option) and downscaling the original emissions to a resolution of ca. 1 km × 1 km for Berlin based on proxy data including traffic density and population density. The results show that the model simulates meteorology well, though urban 2 m temperature and urban wind speeds are biased high and nighttime mixing layer height is biased low in the base run with the settings described above. We show that the simulation of urban meteorology can be improved when specifying the input parameters to the urban model, and to a lesser extent when using the mosaic option. On average, ozone is simulated reasonably well, but maximum daily 8 h mean concentrations are underestimated, which is consistent with the results from previous modelling studies using the RADM2 chemical mechanism. Particulate matter is underestimated, which is partly due to an underestimation of secondary organic aerosols. NOx (NO + NO2) concentrations are simulated reasonably well on average, but nighttime concentrations are overestimated due to the model's underestimation of the mixing layer height, and urban daytime concentrations are underestimated. The daytime underestimation is improved when using downscaled, and thus locally higher emissions, suggesting that part of this bias is due to deficiencies in the emission input data and their resolution. The results further demonstrate that a horizontal resolution of 3 km improves the results and spatial representativeness of the model compared to a horizontal resolution of 15 km. With the input data (land use classes, emissions) at the level of detail of the base run of this study, we find that a horizontal resolution of 1 km does not improve the results compared to a resolution of 3 km. However, our results suggest that a 1 km horizontal model resolution could enable a detailed simulation of local pollution patterns in the Berlin–Brandenburg region if the urban land use classes, together with the respective input parameters to the urban canopy model, are specified with a higher level of detail and if urban emissions of higher spatial resolution are used. Y1 - 2016 U6 - https://doi.org/10.5194/gmd-9-4339-2016 SN - 1991-959X SN - 1991-9603 VL - 9 SP - 4339 EP - 4363 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Kumph, Muir A1 - Henkel, Carsten A1 - Rabl, Peter A1 - Brownnutt, Michael A1 - Blatt, Rainer T1 - Electric-field noise above a thin dielectric layer on metal electrodes JF - NEW JOURNAL OF PHYSICS N2 - The electric-field noise above a layered structure composed of a planar metal electrode covered by a thin dielectric is evaluated and it is found that the dielectric film considerably increases the noise level, in proportion to its thickness. Importantly, even a thin (mono) layer of a low-loss dielectric can enhance the noise level by several orders of magnitude compared to the noise above a bare metal. Close to this layered surface, the power spectral density of the electric field varies with the inverse fourth power of the distance to the surface, rather than with the inverse square, as it would above a bare metal surface. Furthermore, compared to a clean metal, where the noise spectrum does not vary with frequency (in the radio-wave and microwave bands), the dielectric layer can generate electricfield noise which scales in inverse proportion to the frequency. For various realistic scenarios, the noise levels predicted from this model are comparable to those observed in trapped-ion experiments. Thus, these findings are of particular importance for the understanding and mitigation of unwanted heating and decoherence in miniaturized ion traps. KW - ion trap KW - electric field noise KW - fluctuation dissipation Y1 - 2016 U6 - https://doi.org/10.1088/1367-2630/18/2/023020 SN - 1367-2630 VL - 18 SP - 1125 EP - 1136 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Kunnus, Kristjan A1 - Josefsson, Ida A1 - Rajkovic, Ivan A1 - Schreck, Simon A1 - Quevedo, Wilson A1 - Beye, Martin A1 - Grübel, Sebastian A1 - Scholz, Mirko A1 - Nordlund, Dennis A1 - Zhang, Wenkai A1 - Hartsock, Robert W. A1 - Gaffney, Kelly J. A1 - Schlotter, William F. A1 - Turner, Joshua J. A1 - Kennedy, Brian A1 - Hennies, Franz A1 - Techert, Simone A1 - Wernet, Philippe A1 - Odelius, Michael A1 - Föhlisch, Alexander T1 - Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics JF - NEW JOURNAL OF PHYSICS N2 - Ultrafast electronic and structural dynamics of matter govern rate and selectivity of chemical reactions, as well as phase transitions and efficient switching in functional materials. Since x-rays determine electronic and structural properties with elemental, chemical, orbital and magnetic selectivity, short pulse x-ray sources have become central enablers of ultrafast science. Despite of these strengths, ultrafast x-rays have been poor at picking up excited state moieties from the unexcited ones. With time-resolved anti-Stokes resonant x-ray Raman scattering (AS-RXRS) performed at the LCLS, and ab initio theory we establish background free excited state selectivity in addition to the elemental, chemical, orbital and magnetic selectivity of x-rays. This unparalleled selectivity extracts low concentration excited state species along the pathway of photo induced ligand exchange of Fe(CO)(5) in ethanol. Conceptually a full theoretical treatment of all accessible insights to excited state dynamics with AS-RXRS with transform-limited x-ray pulses is given-which will be covered experimentally by upcoming transform-limited x-ray sources. KW - ultrafast photochemistry KW - excited state selectivity KW - anti-Stokes resonant x-ray raman scattering KW - free electron lasers KW - resonant inelastic x-ray scattering Y1 - 2016 U6 - https://doi.org/10.1088/1367-2630/18/10/103011 SN - 1367-2630 VL - 18 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Kunnus, Kristjan A1 - Zhang, Wenkai A1 - Delcey, Mickael G. A1 - Pinjari, Rahul V. A1 - Miedema, Piter S. A1 - Schreck, Simon A1 - Quevedo, Wilson A1 - Schröder, Henning A1 - Föhlisch, Alexander A1 - Gaffney, Kelly J. A1 - Lundberg, Marcus A1 - Odelius, Michael A1 - Wernet, Philippe T1 - Viewing the Valence Electronic Structure of Ferric and Ferrous Hexacyanide in Solution from the Fe and Cyanide Perspectives JF - The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces & biophysical chemistry N2 - The valence-excited states of ferric and ferrous hexacyanide ions in aqueous solution were mapped by resonant inelastic X-ray scattering (RIXS) at the Fe L-2,L-3 and N K edges. Probing of both the central Fe and the ligand N atoms enabled identification of the metal-and ligand-centered excited states, as well as ligand-to-metal and metal-to-ligand charge-transfer excited states. Ab initio calculations utilizing the RASPT2 method were used to simulate the Fe L-2,L-3-edge RIXS spectra and enabled quantification of the covalencies of both occupied and empty orbitals of pi and sigma symmetry. We found that pi back-donation in the ferric complex is smaller than that in the ferrous complex. This is evidenced by the relative amounts of Fe 3d character in the nominally 2 pi CN- molecular orbital of 7% and 9% in ferric and ferrous hexacyanide, respectively. Utilizing the direct sensitivity of Fe L-3-edge RIXS to the Fe 3d character in the occupied molecular orbitals, we also found that the donation interactions are dominated by sigma bonding. The latter was found to be stronger in the ferric complex, with an Fe 3d contribution to the nominally 5 sigma CN- molecular orbitals of 29% compared to 20% in the ferrous complex. These results are consistent with the notion that a higher charge at the central metal atom increases donation and decreases back-donation. Y1 - 2016 U6 - https://doi.org/10.1021/acs.jpcb.6b04751 SN - 1520-6106 VL - 120 SP - 7182 EP - 7194 PB - American Chemical Society CY - Washington ER - TY - GEN A1 - Kurpiers, Jona A1 - Neher, Dieter T1 - Dispersive Non-Geminate Recombination in an Amorphous Polymer:Fullerene Blend N2 - Recombination of free charge is a key process limiting the performance of solar cells. For low mobility materials, such as organic semiconductors, the kinetics of non-geminate recombination (NGR) is strongly linked to the motion of charges. As these materials possess significant disorder, thermalization of photogenerated carriers in the inhomogeneously broadened density of state distribution is an unavoidable process. Despite its general importance, knowledge about the kinetics of NGR in complete organic solar cells is rather limited. We employ time delayed collection field (TDCF) experiments to study the recombination of photogenerated charge in the high-performance polymer:fullerene blend PCDTBT:PCBM. NGR in the bulk of this amorphous blend is shown to be highly dispersive, with a continuous reduction of the recombination coefficient throughout the entire time scale, until all charge carriers have either been extracted or recombined. Rapid, contact-mediated recombination is identified as an additional loss channel, which, if not properly taken into account, would erroneously suggest a pronounced field dependence of charge generation. These findings are in stark contrast to the results of TDCF experiments on photovoltaic devices made from ordered blends, such as P3HT:PCBM, where non-dispersive recombination was proven to dominate the charge carrier dynamics under application relevant conditions. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 228 Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-91541 ER - TY - JOUR A1 - Kurpiers, Jona A1 - Neher, Dieter T1 - Dispersive Non-Geminate Recombination in an Amorphous Polymer:Fullerene Blend JF - Scientific reports N2 - Recombination of free charge is a key process limiting the performance of solar cells. For low mobility materials, such as organic semiconductors, the kinetics of non-geminate recombination (NGR) is strongly linked to the motion of charges. As these materials possess significant disorder, thermalization of photogenerated carriers in the inhomogeneously broadened density of state distribution is an unavoidable process. Despite its general importance, knowledge about the kinetics of NGR in complete organic solar cells is rather limited. We employ time delayed collection field (TDCF) experiments to study the recombination of photogenerated charge in the high-performance polymer:fullerene blend PCDTBT:PCBM. NGR in the bulk of this amorphous blend is shown to be highly dispersive, with a continuous reduction of the recombination coefficient throughout the entire time scale, until all charge carriers have either been extracted or recombined. Rapid, contact-mediated recombination is identified as an additional loss channel, which, if not properly taken into account, would erroneously suggest a pronounced field dependence of charge generation. These findings are in stark contrast to the results of TDCF experiments on photovoltaic devices made from ordered blends, such as P3HT:PCBM, where non-dispersive recombination was proven to dominate the charge carrier dynamics under application relevant conditions. Y1 - 2016 U6 - https://doi.org/10.1038/srep26832 SN - 2045-2322 VL - 6 PB - Nature Publishing Group CY - London ER - TY - JOUR A1 - Kurpiers, Jona A1 - Neher, Dieter T1 - Dispersive Non-Geminate Recombination in an Amorphous Polymer: Fullerene Blend JF - Scientific reports N2 - Recombination of free charge is a key process limiting the performance of solar cells. For low mobility materials, such as organic semiconductors, the kinetics of non-geminate recombination (NGR) is strongly linked to the motion of charges. As these materials possess significant disorder, thermalization of photogenerated carriers in the inhomogeneously broadened density of state distribution is an unavoidable process. Despite its general importance, knowledge about the kinetics of NGR in complete organic solar cells is rather limited. We employ time delayed collection field (TDCF) experiments to study the recombination of photogenerated charge in the high-performance polymer: fullerene blend PCDTBT:PCBM. NGR in the bulk of this amorphous blend is shown to be highly dispersive, with a continuous reduction of the recombination coefficient throughout the entire time scale, until all charge carriers have either been extracted or recombined. Rapid, contact-mediated recombination is identified as an additional loss channel, which, if not properly taken into account, would erroneously suggest a pronounced field dependence of charge generation. These findings are in stark contrast to the results of TDCF experiments on photovoltaic devices made from ordered blends, such as P3HT:PCBM, where non-dispersive recombination was proven to dominate the charge carrier dynamics under application relevant conditions. Y1 - 2016 U6 - https://doi.org/10.1038/srep26832 SN - 2045-2322 VL - 6 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Kuznetsov, Alexander P. A1 - Turukina, Ludmila V. A1 - Chernyshov, Nikolai Yu A1 - Sedova, Yuliya V. T1 - Oscillations and Synchronization in a System of Three Reactively Coupled Oscillators JF - International journal of bifurcation and chaos : in applied sciences and engineering N2 - We consider a system of three interacting van der Pol oscillators with reactive coupling. Phase equations are derived, using proper order of expansion over the coupling parameter. The dynamics of the system is studied by means of the bifurcation analysis and with the method of Lyapunov exponent charts. Essential and physically meaningful features of the reactive coupling are discussed. KW - Synchronization KW - quasi-periodic oscillation KW - bifurcation KW - chaos Y1 - 2016 U6 - https://doi.org/10.1142/S0218127416500103 SN - 0218-1274 SN - 1793-6551 VL - 26 SP - 31 EP - 39 PB - World Scientific CY - Singapore ER - TY - JOUR A1 - Kuznetsov, Sergey P. T1 - Parametric chaos generator operating on a varactor diode with the instability limitation decay mechanism JF - Technical Physics N2 - Equations are derived for a parametric chaos generator containing three oscillatory circuits and a variable-capacitance diode (varactor) and are reduced to equations for slow amplitudes of parametrically interacting modes. With allowance for quadratic nonlinearity, the problem is reduced to a system of three first-order differential equations for Pikovsky-Rabinovich-Trakhtengerts real amplitudes with a Lorenz-type attractor. In a more accurate description of nonlinearity of the varactor, the equations for slow amplitudes are complex-valued, which leads to the loss of robustness of chaotic dynamics, which is typical of the Lorenz attractor. The results of numerical calculations (portraits of attractors and Lyapunov exponents) in models with different approximation levels are compared. Y1 - 2016 U6 - https://doi.org/10.1134/S1063784216030129 SN - 1063-7842 SN - 1090-6525 VL - 61 SP - 436 EP - 445 PB - Pleiades Publ. CY - New York ER - TY - JOUR A1 - Laepple, Thomas A1 - Hörhold, Maria A1 - Münch, Thomas A1 - Freitag, Johannes A1 - Wegner, Anna A1 - Kipfstuhl, Sepp T1 - Layering of surface snow and firn at Kohnen Station, Antarctica: Noise or seasonal signal? JF - Journal of geophysical research : Earth surface N2 - The density of firn is an important property for monitoring and modeling the ice sheets as well as to model the pore close-off and thus to interpret ice core-based greenhouse gas records. One feature, which is still in debate, is the potential existence of an annual cycle of firn density in low-accumulation regions. Several studies describe or assume seasonally successive density layers, horizontally evenly distributed, as seen in radar data. On the other hand, high-resolution density measurements on firn cores in Antarctica and Greenland show no clear seasonal cycle in the top few meters. A major caveat of most existing snow-pit and firn-core-based studies is that they represent one vertical profile from a laterally heterogeneous density field. To overcome this, we created an extensive data set of horizontal and vertical density data at Kohnen Station, Dronning Maud Land, on the East Antarctic Plateau. We drilled and analyzed three 90m long firn cores as well as 143 one-meter-long vertical profiles from two elongated snow trenches to obtain a two-dimensional view of the density variations. The analysis of the 45m wide and 1m deep density fields reveals a seasonal cycle in density. However, the seasonality is overprinted by strong stratigraphic noise, making it invisible when analyzing single firn cores. Our density data set extends the view from the local ice core perspective to a hundred meter scale and thus supports linking spatially integrating methods such as radar and seismic studies to ice and firn cores. Y1 - 2016 U6 - https://doi.org/10.1002/2016JF003919 SN - 2169-9003 SN - 2169-9011 VL - 121 SP - 1849 EP - 1860 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Lechleitner, Franziska A. A1 - Baldini, James U. L. A1 - Breitenbach, Sebastian Franz Martin A1 - Fohlmeister, Jens Bernd A1 - McIntyre, Cameron A1 - Goswami, Bedartha A1 - Jamieson, Robert A. A1 - van der Voort, Tessa S. A1 - Prufer, Keith A1 - Marwan, Norbert A1 - Culleton, Brendan J. A1 - Kennett, Douglas J. A1 - Asmerom, Yemane A1 - Polyak, Victor A1 - Eglinton, Timothy I. T1 - Hydrological and climatological controls on radiocarbon concentrations in a tropical stalagmite JF - Geochimica et cosmochimica acta : journal of the Geochemical Society and the Meteoritical Society N2 - Precisely-dated stalagmites are increasingly important archives for the reconstruction of terrestrial paleoclimate at very high temporal resolution. In-depth understanding of local conditions at the cave site and of the processes driving stalagmite deposition is of paramount importance for interpreting proxy signals incorporated in stalagmite carbonate. Here we present a sub-decadally resolved dead carbon fraction (DCF) record for a stalagmite from Yok Balum Cave (southern Belize). The record is coupled to parallel stable carbon isotope (delta C-13) and U/Ca measurements, as well as radiocarbon (C-14) measurements from soils overlying the cave system. Using a karst carbon cycle model we disentangle the importance of soil and karst processes on stalagmite DCF incorporation, revealing a dominant host rock dissolution control on total DCF. Covariation between DCF, delta C-13, and U/Ca indicates that karst processes are a common driver of all three parameters, suggesting possible use of delta C-13 and trace element ratios to independently quantify DCF variability. A statistically significant multi-decadal lag of variable length exists between DCF and reconstructed solar activity, suggesting that solar activity influenced regional precipitation in Mesoamerica over the past 1500 years, but that the relationship was non-static. Although the precise nature of the observed lag is unclear, solar-induced changes in North Atlantic oceanic and atmospheric dynamics may play a role. (C) 2016 Elsevier Ltd. All rights reserved. KW - Stalagmite KW - Tropics KW - Radiocarbon KW - Trace elements KW - Hydroclimate Y1 - 2016 U6 - https://doi.org/10.1016/j.gca.2016.08.039 SN - 0016-7037 SN - 1872-9533 VL - 194 SP - 233 EP - 252 PB - Elsevier CY - Oxford ER - TY - THES A1 - Lehmann, Jascha In-su T1 - Changes in extratropical storm track activity and their implications for extreme weather events Y1 - 2016 ER - TY - JOUR A1 - Lenske, Gerlinde A1 - Wagner, Wolfgang A1 - Wirth, Joachim A1 - Thillmann, Hubertina A1 - Cauet, Eva A1 - Liepertz, Sven A1 - Leutner, Detlev T1 - The importance of pedagogical knowledge for classroom management and for and for students’ achievement JF - Zeitschrift für Erziehungswissenschaft N2 - Im Rahmen der vorliegenden Studie wurde untersucht, ob das pädagogisch-psychologische Wissen von Lehrkräften die prozessuale Qualität des Physikunterrichts mit Blick auf die Klassenführung und den Lernzuwachs der Schülerinnen und Schüler beeinflusst. Das pädagogisch-psychologische Professionswissen, konzeptualisiert als ein fächerübergreifendes, handlungsleitendes Wissen über Strategien und Mittel zur Unterrichtsgestaltung, wurde über einen Paper-Pencil-Test, bestehend aus einer Skala zum deklarativen und einer Skala zum konditional-prozeduralen Wissen erhoben (Lenske et al. 2015). Als ein grundlegendes Merkmal prozessualer Unterrichtsqualität wurde die Klassenführung anhand von Videoratings zu zwei Messzeitpunkten (zwei Unterrichtsstunden) erfasst. Der Lernzuwachs der Schülerinnen und Schüler wurde über standardisierte Fachwissenstests im Prä-Post-Testdesign gemessen. Die Stichprobe umfasst 34 Gymnasiallehrkräfte und deren Schülerinnen und Schüler (N = 993). Auf Basis eines Complex-Bootstrap-Mediations-Modells zeigte sich, dass das pädagogisch-psychologische Professionswissen über die Klassenführung vermittelt den Lernzuwachs der Schüler und Schülerinnen positiv beeinflusst. In the present study it was investigated whether the pedagogical knowledge of teachers has an influence on the process quality of physics instruction and on the learning achievement of students as well. Pedagogical knowledge, conceptualized as knowledge about strategies in classroom instruction that is domain-general and relevant for teaching behaviors, was measured using a paper-and-pencil test with two scales: one scale on declarative knowledge, the other on conditional-procedural knowledge (Lenske et al. 2015). As a basic aspect of the process quality of classroom instruction, classroom management was assessed using video ratings of two lessons from each participating teacher. Students’ learning achievement was assessed using standardized domain-specific knowledge tests in a pretest-posttest design. The sample included 34 teachers from higher-track secondary schools and their students (N = 993). A complex bootstrapping mediation model shows that teachers’ pedagogical knowledge, mediated by their classroom management, has a positive effect on their students’ learning achievement. KW - Classroom management KW - Instructional quality KW - Mediation-model KW - Pedagogical professional knowledge KW - Professional knowledge Y1 - 2016 U6 - https://doi.org/10.1007/s11618-015-0659-x SN - 1434-663X SN - 1862-5215 VL - 19 SP - 211 EP - 233 PB - Springer CY - Wiesbaden ER - TY - JOUR A1 - Leonhardt, Helmar A1 - Gerhardt, Matthias A1 - Hoeppner, Nadine A1 - Krüger, Kirsten A1 - Tarantola, Marco A1 - Beta, Carsten T1 - Cell-substrate impedance fluctuations of single amoeboid cells encode cell-shape and adhesion dynamics JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We show systematic electrical impedance measurements of single motile cells on microelectrodes. Wild-type cells and mutant strains were studied that differ in their cell-substrate adhesion strength. We recorded the projected cell area by time-lapse microscopy and observed irregular oscillations of the cell shape. These oscillations were correlated with long-term variations in the impedance signal. Superposed to these long-term trends, we observed fluctuations in the impedance signal. Their magnitude clearly correlated with the adhesion strength, suggesting that strongly adherent cells display more dynamic cell-substrate interactions. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevE.93.012414 SN - 2470-0045 SN - 2470-0053 VL - 93 PB - American Physical Society CY - College Park ER - TY - GEN A1 - Levermann, Anders A1 - Petoukhov, Vladimir A1 - Schewe, Jacob A1 - Schellnhuber, Hans Joachim T1 - Abrupt monsoon transitions as seen in paleorecords can be explained by moisture-advection feedback T2 - Proceedings of the National Academy of Sciences of the United States of America Y1 - 2016 U6 - https://doi.org/10.1073/pnas.1603130113 SN - 0027-8424 VL - 113 SP - E2348 EP - E2349 PB - National Acad. of Sciences CY - Washington ER - TY - JOUR A1 - Levermann, Anders A1 - Winkelmann, Ricarda T1 - A simple equation for the melt elevation feedback of ice sheets JF - The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union N2 - In recent decades, the Greenland Ice Sheet has been losing mass and has thereby contributed to global sea-level rise. The rate of ice loss is highly relevant for coastal protection worldwide. The ice loss is likely to increase under future warming. Beyond a critical temperature threshold, a meltdown of the Greenland Ice Sheet is induced by the self-enforcing feedback between its lowering surface elevation and its increasing surface mass loss: the more ice that is lost, the lower the ice surface and the warmer the surface air temperature, which fosters further melting and ice loss. The computation of this rate so far relies on complex numerical models which are the appropriate tools for capturing the complexity of the problem. By contrast we aim here at gaining a conceptual understanding by deriving a purposefully simple equation for the self-enforcing feedback which is then used to estimate the melt time for different levels of warming using three observable characteristics of the ice sheet itself and its surroundings. The analysis is purely conceptual in nature. It is missing important processes like ice dynamics for it to be useful for applications to sea-level rise on centennial timescales, but if the volume loss is dominated by the feedback, the resulting logarithmic equation unifies existing numerical simulations and shows that the melt time depends strongly on the level of warming with a critical slow-down near the threshold: the median time to lose 10% of the present-day ice volume varies between about 3500 years for a temperature level of 0.5 degrees C above the threshold and 500 years for 5 degrees C. Unless future observations show a significantly higher melting sensitivity than currently observed, a complete meltdown is unlikely within the next 2000 years without significant ice-dynamical contributions. Y1 - 2016 U6 - https://doi.org/10.5194/tc-10-1799-2016 SN - 1994-0416 SN - 1994-0424 VL - 10 SP - 1799 EP - 1807 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Liebig, Ferenc A1 - Sarhan, Radwan Mohamed A1 - Prietzel, Claudia Christina A1 - Reinecke, Antje A1 - Koetz, Joachim T1 - "Green" gold nanotriangles: synthesis, purification by polyelectrolyte/micelle depletion flocculation and performance in surface-enhanced Raman scattering JF - RSC Advances N2 - The aim of this study was to develop a one-step synthesis of gold nanotriangles (NTs) in the presence of mixed phospholipid vesicles followed by a separation process to isolate purified NTs. Negatively charged vesicles containing AOT and phospholipids, in the absence and presence of additional reducing agents (polyampholytes, polyanions or low molecular weight compounds), were used as a template phase to form anisotropic gold nanoparticles. Upon addition of the gold chloride solution, the nucleation process is initiated and both types of particles, i.e., isotropic spherical and anisotropic gold nanotriangles, are formed simultaneously. As it was not possible to produce monodisperse nanotriangles with such a one-step procedure, the anisotropic nanoparticles needed to be separated from the spherical ones. Therefore, a new type of separation procedure using combined polyelectrolyte/micelle depletion flocculation was successfully applied. As a result of the different purification steps, a green colored aqueous dispersion was obtained containing highly purified, well-defined negatively charged flat nanocrystals with a platelet thickness of 10 nm and an edge length of about 175 nm. The NTs produce promising results in surface-enhanced Raman scattering. Y1 - 2016 U6 - https://doi.org/10.1039/c6ra04808k SN - 2046-2069 VL - 6 SP - 33561 EP - 33568 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Ligorio, G. A1 - Nardi, M. V. A1 - Steyrleuthner, Robert A1 - Ihiawakrim, D. A1 - Crespo-Monteiro, N. A1 - Brinkmann, Martin A1 - Neher, Dieter A1 - Koch, N. T1 - Metal nanoparticle mediated space charge and its optical control in an organic hole-only device JF - Applied physics letters N2 - We reveal the role of localized space charges in hole-only devices based on an organic semiconductor with embedded metal nanoparticles (MNPs). MNPs act as deep traps for holes and reduce the current density compared to a device without MNPs by a factor of 10(4) due to the build-up of localized space charge. Dynamic MNPs charged neutrality can be realized during operation by electron transfer from excitons created in the organic matrix, enabling light sensing independent of device bias. In contrast to the previous speculations, electrical bistability in such devices was not observed. (C) 2016 AIP Publishing LLC. Y1 - 2016 U6 - https://doi.org/10.1063/1.4945710 SN - 0003-6951 SN - 1077-3118 VL - 108 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Liu, Rui A1 - Kliem, Bernhard A1 - Titov, Viacheslav S. A1 - Chen, Jun A1 - Wang, Yuming A1 - Wang, Haimin A1 - Liu, Chang A1 - Xu, Yan A1 - Wiegelmann, Thomas T1 - STRUCTURE, STABILITY, AND EVOLUTION OF MAGNETIC FLUX ROPES FROM THE PERSPECTIVE OF MAGNETIC TWIST JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We investigate the evolution of NOAA Active Region (AR) 11817 during 2013 August 10–12, when it developed a complex field configuration and produced four confined, followed by two eruptive, flares. These C-and-above flares are all associated with a magnetic flux rope (MFR) located along the major polarity inversion line, where shearing and converging photospheric flows are present. Aided by the nonlinear force-free field modeling, we identify the MFR through mapping magnetic connectivities and computing the twist number ${{ \mathcal T }}_{w}$ for each individual field line. The MFR is moderately twisted ($| {{ \mathcal T }}_{w}| \lt 2$) and has a well-defined boundary of high squashing factor Q. We found that the field line with the extremum $| {{ \mathcal T }}_{w}| $ is a reliable proxy of the rope axis, and that the MFR's peak $| {{ \mathcal T }}_{w}| $ temporarily increases within half an hour before each flare while it decreases after the flare peak for both confined and eruptive flares. This pre-flare increase in $| {{ \mathcal T }}_{w}| $ has little effect on the AR's free magnetic energy or any other parameters derived for the whole region, due to its moderate amount and the MFR's relatively small volume, while its decrease after flares is clearly associated with the stepwise decrease in the whole region's free magnetic energy due to the flare. We suggest that ${{ \mathcal T }}_{w}$ may serve as a useful parameter in forewarning the onset of eruption, and therefore, the consequent space weather effects. The helical kink instability is identified as the prime candidate onset mechanism for the considered flares. KW - coronal mass ejections (CMEs) KW - Sun: corona KW - Sun: filaments, pominences KW - Sun: flares KW - Sun: magnetic fields Y1 - 2016 U6 - https://doi.org/10.3847/0004-637X/818/2/148 SN - 0004-637X SN - 1538-4357 VL - 818 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Liu, Xiaodong A1 - Sachse, Manuel A1 - Spahn, Frank A1 - Schmidt, Jurgen T1 - Dynamics and distribution of Jovian dust ejected from the Galilean satellites JF - Journal of geophysical research, Planets N2 - In this paper, the dynamical analysis of the Jovian dust originating from the four Galilean moons is presented. High-accuracy orbital integrations of dust particles are used to determine their dynamical evolution. A variety of forces are taken into account, including the Lorentz force, solar radiation pressure, Poynting-Robertson drag, solar gravity, the satellites' gravity, plasma drag, and gravitational effects due to nonsphericity of Jupiter. More than 20,000 dust particles from each source moon in the size range from 0.05 μm to 1 cm are simulated over 8000 (Earth) years until each dust grain hits a sink (moons, Jupiter, or escape from the system). Configurations of dust number density in the Jovicentric equatorial inertial frame are calculated and shown. In a Jovicentric frame rotating with the Sun the dust distributions are found to be asymmetric. For certain small particle sizes, the dust population is displaced towards the Sun, while for certain larger sizes, the dust population is displaced away from the Sun. The average lifetime as a function of particle size for ejecta from each source moon is derived, and two sharp jumps in the average lifetime are analyzed. Transport of dust between the Galilean moons and to Jupiter is investigated. Most of the orbits for dust particles from Galilean moons are prograde, while, surprisingly, a small fraction of orbits are found to become retrograde mainly due to solar radiation pressure and Lorentz force. The distribution of orbital elements is also analyzed. Y1 - 2016 U6 - https://doi.org/10.1002/2016JE004999 SN - 2169-9097 SN - 2169-9100 VL - 121 SP - 1141 EP - 1173 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Loebner, Sarah A1 - Jelken, Joachim A1 - Yadavalli, Nataraja Sekhar A1 - Sava, Elena A1 - Hurduc, Nicolae A1 - Santer, Svetlana T1 - Motion of Adsorbed Nano-Particles on Azobenzene Containing Polymer Films JF - Molecules N2 - We demonstrate in situ recorded motion of nano-objects adsorbed on a photosensitive polymer film. The motion is induced by a mass transport of the underlying photoresponsive polymer material occurring during irradiation with interference pattern. The polymer film contains azobenzene molecules that undergo reversible photoisomerization reaction from trans-to cis-conformation. Through a multi-scale chain of physico-chemical processes, this finally results in the macro-deformations of the film due to the changing elastic properties of polymer. The topographical deformation of the polymer surface is sensitive to a local distribution of the electrical field vector that allows for the generation of dynamic changes in the surface topography during irradiation with different light interference patterns. Polymer film deformation together with the motion of the adsorbed nano-particles are recorded using a homemade set-up combining an optical part for the generation of interference patterns and an atomic force microscope for acquiring the surface deformation. The particles undergo either translational or rotational motion. The direction of particle motion is towards the topography minima and opposite to the mass transport within the polymer film. The ability to relocate particles by photo-induced dynamic topography fluctuation offers a way for a non-contact simultaneous manipulation of a large number of adsorbed particles just in air at ambient conditions. KW - motion of adsorbed nano-particles KW - azobenzene containing polymer films KW - fluctuating surfaces Y1 - 2016 U6 - https://doi.org/10.3390/molecules21121663 SN - 1420-3049 VL - 21 SP - 397 EP - 411 PB - MDPI CY - Basel ER - TY - JOUR A1 - Love, John A. A1 - Chou, Shu-Hua A1 - Huang, Ye A1 - Bazan, Guillermo C. A1 - Thuc-Quyen Nguyen, T1 - Effects of solvent additive on "s-shaped" curves in solution-processed small molecule solar cells JF - Beilstein journal of organic chemistry N2 - A novel molecular chromophore, p-SIDT(FBTThCA8)(2), is introduced as an electron-donor material for bulk heterojunction (BHJ) solar cells with broad absorption and near ideal energy levels for the use in combination with common acceptor materials. It is found that films cast from chlorobenzene yield devices with strongly s-shaped current-voltage curves, drastically limiting performance. We find that addition of the common solvent additive diiodooctane, in addition to facilitating crystallization, leads to improved vertical phase separation. This yields much better performing devices, with improved curve shape, demonstrating the importance of morphology control in BHJ devices and improving the understanding of the role of solvent additives. KW - current voltage analysis KW - morphology KW - organic solar cells Y1 - 2016 U6 - https://doi.org/10.3762/bjoc.12.249 SN - 1860-5397 VL - 12 SP - 2543 EP - 2555 PB - Beilstein-Institut zur Förderung der Chemischen Wissenschaften CY - Frankfurt, Main ER - TY - JOUR A1 - Lu, Guanghao A1 - Di Pietro, Riccardo A1 - Kölln, Lisa Sophie A1 - Nasrallah, Iyad A1 - Zhou, Ling A1 - Mollinger, Sonya A1 - Himmelberger, Scott A1 - Koch, Norbert A1 - Salleo, Alberto A1 - Neher, Dieter T1 - Dual-Characteristic Transistors Based on Semiconducting Polymer Blends JF - Advanced electronic materials N2 - A dual-characteristic polymer field-effect transistor has markedly different characteristics in low and high voltage operations. In the low-voltage range (<5 V) it shows sharp subthreshold slopes (0.3–0.4 V dec−1), using which a low-voltage inverter with gain 8 is realized, while high-voltage (>5 V) induces symmetric current with regard to drain and gate voltages, leading to discrete differential (trans) conductances. KW - charge accumulation KW - crystalline ordering KW - field-effect-transistor KW - semiconducting polymers Y1 - 2016 U6 - https://doi.org/10.1002/aelm.201600267 SN - 2199-160X VL - 2 SP - 2344 EP - 2351 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Martin, Nicolas F. A1 - Jungbluth, Valentin A1 - Nidever, David L. A1 - Bell, Eric F. A1 - Besla, Gurtina A1 - Blum, Robert D. A1 - Cioni, Maria-Rosa L. A1 - Conn, Blair C. A1 - Kaleida, Catherine C. A1 - Gallart, Carme A1 - Jin, Shoko A1 - Majewski, Steven R. A1 - Martinez-Delgado, David A1 - Monachesi, Antonela A1 - Munoz, Ricardo R. A1 - Noel, Noelia E. D. A1 - Olsen, Knut A1 - Stringfellow, Guy S. A1 - van der Marel, Roeland P. A1 - Vivas, A. Katherina A1 - Walker, Alistair R. A1 - Zaritsky, Dennis T1 - SMASH 1: A VERY FAINT GLOBULAR CLUSTER DISRUPTING IN THE OUTER REACHES OF THE LMC? JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters KW - globular clusters: individual: (SMASH 1) KW - Local Group KW - Magellanic Clouds Y1 - 2016 U6 - https://doi.org/10.3847/2041-8205/830/1/L10 SN - 2041-8205 SN - 2041-8213 VL - 830 SP - 92 EP - 98 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Martinez Gonzalez, M. J. A1 - Pastor Yabar, A. A1 - Lagg, A. A1 - Asensio Ramos, A. A1 - Collados Vera, M. A1 - Solanki, S. K. A1 - Balthasar, H. A1 - Berkefeld, T. A1 - Denker, Carsten A1 - Doerr, H. P. A1 - Feller, A. A1 - Franz, M. A1 - González Manrique, Sergio Javier A1 - Hofmann, A. A1 - Kneer, F. A1 - Kuckein, Christoph A1 - Louis, R. A1 - von der Lühe, O. A1 - Nicklas, H. A1 - Orozco, D. A1 - Rezaei, R. A1 - Schlichenmaier, R. A1 - Schmidt, D. A1 - Schmidt, W. A1 - Sigwarth, M. A1 - Sobotka, M. A1 - Soltau, D. A1 - Staude, J. A1 - Strassmeier, Klaus G. A1 - Verma, Meetu A1 - Waldman, T. A1 - Volkmer, R. T1 - Inference of magnetic fields in the very quiet Sun JF - Journal of geophysical research : Earth surface N2 - Context. Over the past 20 yr, the quietest areas of the solar surface have revealed a weak but extremely dynamic magnetism occurring at small scales (<500 km), which may provide an important contribution to the dynamics and energetics of the outer layers of the atmosphere. Understanding this magnetism requires the inference of physical quantities from high-sensitivity spectro-polarimetric data with high spatio-temporal resolution. Aims. We present high-precision spectro-polarimetric data with high spatial resolution (0.4") of the very quiet Sun at 1.56 mu m obtained with the GREGOR telescope to shed some light on this complex magnetism. Methods. We used inversion techniques in two main approaches. First, we assumed that the observed profiles can be reproduced with a constant magnetic field atmosphere embedded in a field-free medium. Second, we assumed that the resolution element has a substructure with either two constant magnetic atmospheres or a single magnetic atmosphere with gradients of the physical quantities along the optical depth, both coexisting with a global stray-light component. Results. Half of our observed quiet-Sun region is better explained by magnetic substructure within the resolution element. However, we cannot distinguish whether this substructure comes from gradients of the physical parameters along the line of sight or from horizontal gradients (across the surface). In these pixels, a model with two magnetic components is preferred, and we find two distinct magnetic field populations. The population with the larger filling factor has very weak (similar to 150 G) horizontal fields similar to those obtained in previous works. We demonstrate that the field vector of this population is not constrained by the observations, given the spatial resolution and polarimetric accuracy of our data. The topology of the other component with the smaller filling factor is constrained by the observations for field strengths above 250 G: we infer hG fields with inclinations and azimuth values compatible with an isotropic distribution. The filling factors are typically below 30%. We also find that the flux of the two polarities is not balanced. From the other half of the observed quiet-Sun area similar to 50% are two-lobed Stokes V profiles, meaning that 23% of the field of view can be adequately explained with a single constant magnetic field embedded in a non-magnetic atmosphere. The magnetic field vector and filling factor are reliable inferred in only 50% based on the regular profiles. Therefore, 12% of the field of view harbour hG fields with filling factors typically below 30%. At our present spatial resolution, 70% of the pixels apparently are non-magnetised. KW - Sun: atmosphere KW - Sun: magnetic fields KW - techniques: polarimetric KW - methods: observational Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201628449 SN - 1432-0746 VL - 596 PB - EDP Sciences CY - Les Ulis ER - TY - THES A1 - Marx, Robert T1 - A quantitative model of spatial correlations in parametric down conversion for investigating complementarity at a double slit Y1 - 2016 ER - TY - JOUR A1 - Mazurek, P. A1 - Yu, L. A1 - Gerhard, Reimund A1 - Wirges, Werner A1 - Skov, A. L. T1 - Glycerol as high-permittivity liquid filler in dielectric silicone elastomers JF - Journal of applied polymer science N2 - A recently reported novel class of elastomers was tested with respect to its dielectric properties. The new elastomer material is based on a commercially available poly(dimethylsiloxane) composition, which has been modified by embedding glycerol droplets into its matrix. The approach has two major advantages that make the material useful in a dielectric actuator. First, the glycerol droplets efficiently enhance the dielectric constant, which can reach astonishingly high values in the composite. Second, the liquid filler also acts as a softener that effectively decreases the elastic modulus of the composite. In combination with very low cost and easy preparation, the two property enhancements lead to an extremely attractive dielectric elastomer material. Experimental permittivity data are compared to various theoretical models that predict relative permittivity changes as a function of filler loading, and the applicability of the models is discussed. (c) 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 44153. KW - crosslinking KW - dielectric properties KW - elastomers KW - sensors and actuators Y1 - 2016 U6 - https://doi.org/10.1002/app.44153 SN - 0021-8995 SN - 1097-4628 VL - 133 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Mengel, Matthias A1 - Feldmann, Johannes A1 - Levermann, Anders T1 - Linear sea-level response to abrupt ocean warming of major West Antarctic ice basin JF - Nature climate change N2 - Antarctica’s contribution to global sea-level rise has recently been increasing1. Whether its ice discharge will become unstable and decouple from anthropogenic forcing2,3,4 or increase linearly with the warming of the surrounding ocean is of fundamental importance5. Under unabated greenhouse-gas emissions, ocean models indicate an abrupt intrusion of warm circumpolar deep water into the cavity below West Antarctica’s Filchner–Ronne ice shelf within the next two centuries6,7. The ice basin’s retrograde bed slope would allow for an unstable ice-sheet retreat8, but the buttressing of the large ice shelf and the narrow glacier troughs tend to inhibit such instability9,10,11. It is unclear whether future ice loss will be dominated by ice instability or anthropogenic forcing. Here we show in regional and continental-scale ice-sheet simulations, which are capable of resolving unstable grounding-line retreat, that the sea-level response of the Filchner–Ronne ice basin is not dominated by ice instability and follows the strength of the forcing quasi-linearly. We find that the ice loss reduces after each pulse of projected warm water intrusion. The long-term sea-level contribution is approximately proportional to the total shelf-ice melt. Although the local instabilities might dominate the ice loss for weak oceanic warming12, we find that the upper limit of ice discharge from the region is determined by the forcing and not by the marine ice-sheet instability. Y1 - 2016 U6 - https://doi.org/10.1038/NCLIMATE2808 SN - 1758-678X SN - 1758-6798 VL - 6 SP - 71 EP - + PB - Nature Publ. Group CY - London ER - TY - GEN A1 - Metzler, Ralf T1 - PROTEIN PHYSICS Forever ageing T2 - Nature physics N2 - Single-molecule techniques have long given us insight into the motion and interactions of individual molecules. But simulations now show that the dynamics inside single proteins is not as simple as we thought — and that proteins are forever changing. Y1 - 2016 U6 - https://doi.org/10.1038/nphys3585 SN - 1745-2473 SN - 1745-2481 VL - 12 SP - 113 EP - 114 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Metzler, Ralf A1 - Jeon, J. -H. A1 - Cherstvy, Andrey G. T1 - Non-Brownian diffusion in lipid membranes: Experiments and simulations JF - Biochimica et biophysica acta : Biomembranes N2 - The dynamics of constituents and the surface response of cellular membranes also in connection to the binding of various particles and macromolecules to the membrane are still a matter of controversy in the membrane biophysics community, particularly with respect to crowded membranes of living biological cells. We here put into perspective recent single particle tracking experiments in the plasma membranes of living cells and supercomputing studies of lipid bilayer model membranes with and without protein crowding. Special emphasis is put on the observation of anomalous, non-Brownian diffusion of both lipid molecules and proteins embedded in the lipid bilayer. While single component, pure lipid bilayers in simulations exhibit only transient anomalous diffusion of lipid molecules on nanosecond time scales, the persistence of anomalous diffusion becomes significantly longer ranged on the addition of disorder through the addition of cholesterol or proteins and on passing of the membrane lipids to the gel phase. Concurrently, experiments demonstrate the anomalous diffusion of membrane embedded proteins up to macroscopic time scales in the minute time range. Particular emphasis will be put on the physical character of the anomalous diffusion, in particular, the occurrence of ageing observed in the experiments the effective diffusivity of the measured particles is a decreasing function of time. Moreover, we present results for the time dependent local scaling exponent of the mean squared displacement of the monitored particles. Recent results finding deviations from the commonly assumed Gaussian diffusion patterns in protein crowded membranes are reported. The properties of the displacement autocorrelation function of the lipid molecules are discussed in the light of their appropriate physical anomalous diffusion models, both for non-crowded and crowded membranes. In the last part of this review we address the upcoming field of membrane distortion by elongated membrane-binding particles. We discuss how membrane compartmentalisation and the particle-membrane binding energy may impact the dynamics and response of lipid membranes. This article is part of a Special Issue entitled: Biosimulations edited by Ilpo Vattulainen and Tomasz Rog. (C) 2016 The Authors. Published by Elsevier B.V. KW - Lipid bilayer KW - Protein crowding KW - Anomalous diffusion KW - Simulations KW - Stochastic modelling KW - Non-Gaussian Y1 - 2016 U6 - https://doi.org/10.1016/j.bbamem.2016.01.022 SN - 0005-2736 SN - 0006-3002 VL - 1858 SP - 2451 EP - 2467 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Moradi, N. A1 - Zakrevskyy, Yuriy A1 - Javadi, A. A1 - Aksenenko, E. V. A1 - Fainerman, V. B. A1 - Lomadze, Nino A1 - Santer, Svetlana A1 - Miller, R. T1 - Surface tension and dilation rheology of DNA solutions in mixtures with azobenzene-containing cationic surfactant JF - Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects N2 - The surface tension and dilational surface visco-elasticity of the individual solutions of the biopolymer DNA and the azobenzene-containing cationic surfactant AzoTAB, as well as their mixtures were measured using the drop profile analysis tensiometry. The negatively charged DNA molecules form complexes with the cationic surfactant AzoTAB. Mixed DNA + AzoTAB solutions exhibit high surface activity and surface layer elasticity. Extremes in the dependence of these characteristics on the AzoTAB concentration exist within the concentration range of 3 x 10(-6)-5 x 10(-5) M. The surface tension of the mixture shows a minimum with a subsequent maximum. In the same concentration range the elasticity shows first a maximum and then a subsequent minimum. A recently developed thermodynamic model was modified to account for the dependence of the adsorption equilibrium constant of the adsorbed complex on the cationic surfactant concentration. This modified theory shows good agreement with the experimental data both for the surface tension and the elasticity values over the entire range of studied AzoTAB concentrations. (C) 2016 Elsevier B.V. All rights reserved. KW - Mixed adsorption layers KW - Polymer/surfactant interaction KW - Water/air interface KW - Thermodynamics of adsorption KW - Dilational rheology KW - Drop profile analysis tensiometry Y1 - 2016 U6 - https://doi.org/10.1016/j.colsurfa.2016.04.021 SN - 0927-7757 SN - 1873-4359 VL - 505 SP - 186 EP - 192 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Moretti, M. I. A1 - Clementini, Gisella A1 - Marconi, V. Ripepi M. A1 - Rubele, S. A1 - Cioni, Maria-Rosa L. A1 - Muraveva, T. A1 - Groenewegen, M. A. T. A1 - Cross, N. J. G. A1 - Ivanov, V. D. A1 - Piatti, A. E. A1 - de Grijs, Richard T1 - The VMC survey - XX. Identification of new Cepheids in the Small Magellanic Cloud JF - Monthly notices of the Royal Astronomical Society N2 - We present K-s-band light curves for 299 Cepheids in the Small Magellanic Cloud (SMC) of which 288 are new discoveries that we have identified using multi-epoch near-infrared photometry obtained by the VISTA survey of the Magellanic Clouds system (VMC). The new Cepheids have periods in the range from 0.34 to 9.1 d and cover the magnitude interval 12.9 <= currency sign < K-s > <= currency sign 17.6 mag. Our method was developed using variable stars previously identified by the optical microlensing survey OGLE. We focus on searching new Cepheids in external regions of the SMC for which complete VMC K-s-band observations are available and no comprehensive identification of different types of variable stars from other surveys exists yet. KW - methods: data analysis KW - surveys KW - stars: variables: Cepheids KW - Magellanic Clouds Y1 - 2016 U6 - https://doi.org/10.1093/mnras/stw716 SN - 0035-8711 SN - 1365-2966 VL - 459 SP - 1687 EP - 1697 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Mueller, Lars A1 - Nanova, Diana A1 - Glaser, Tobias A1 - Beck, Sebastian A1 - Pucci, Annemarie A1 - Kast, Anne K. A1 - Schroeder, Rasmus R. A1 - Mankel, Eric A1 - Pingel, Patrick A1 - Neher, Dieter A1 - Kowalsky, Wolfgang A1 - Lovrincic, Robert T1 - Charge-Transfer-Solvent Interaction Predefines Doping Efficiency in p-Doped P3HT Films JF - Chemistry of materials : a publication of the American Chemical Society N2 - Efficient electrical doping of organic semiconductors is a necessary prerequisite for the fabrication of high performance organic electronic devices. In this work, we study p-type doping of poly(3-hexylthiophene) (P3HT) with 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F(4)TCNQ) spin-cast from two different solvents. Using electron diffraction, we find strong dopant-induced pi-pi-stacking for films from the solvent chloroform, but not from chlorobenzene. This image is confirmed and expanded by the analysis of vibrational features of P3HT and polaron absorptions using optical spectroscopy. Here, a red-shifted polaron absorption is found in doped films from chloroform, caused by a higher conjugation length of the polymer backbone. These differences result in a higher conductivity of films from chloroform. We use optical spectroscopy on the corresponding blend solutions to shed light on the origin of this effect and propose a model to explain why solutions of doped P3HT reveal more aggregation of charged molecules in chlorobenzene, whereas more order is finally observed in dried films from chloroform. Our study emphasizes the importance of solvent parameters exceeding the bare solubility of pure dopant and host material for the preparation of highly conductive doped films. Y1 - 2016 U6 - https://doi.org/10.1021/acs.chemmater.6b01629 SN - 0897-4756 SN - 1520-5002 VL - 28 SP - 4432 EP - 4439 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Münch, Thomas A1 - Kipfstuhl, Sepp A1 - Freitag, Johannes A1 - Meyer, Hanno A1 - Laepple, Thomas T1 - Regional climate signal vs. local noise: a two-dimensional view of water isotopes in Antarctic firn at Kohnen Station, Dronning Maud Land JF - Climate of the past : an interactive open access journal of the European Geosciences Union N2 - In low-accumulation regions, the reliability of delta O-18-derived temperature signals from ice cores within the Holocene is unclear, primarily due to the small climate changes relative to the intrinsic noise of the isotopic signal. In order to learn about the representativity of single ice cores and to optimise future ice-core-based climate reconstructions, we studied the stable-water isotope composition of firn at Kohnen Station, Dronning Maud Land, Antarctica. Analysing delta O-18 in two 50m long snow trenches allowed us to create an unprecedented, two-dimensional image characterising the isotopic variations from the centimetre to the 100-metre scale. Our results show seasonal layering of the isotopic composition but also high horizontal isotopic variability caused by local stratigraphic noise. Based on the horizontal and vertical structure of the isotopic variations, we derive a statistical noise model which successfully explains the trench data. The model further allows one to determine an upper bound for the reliability of climate reconstructions conducted in our study region at seasonal to annual resolution, depending on the number and the spacing of the cores taken. Y1 - 2016 U6 - https://doi.org/10.5194/cp-12-1565-2016 SN - 1814-9324 SN - 1814-9332 VL - 12 SP - 1565 EP - 1581 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Nagornov, Roman A1 - Osipoy, Grigory A1 - Komarov, Maxim A1 - Pikovskij, Arkadij A1 - Shilnikov, Andrey T1 - Mixed-mode synchronization between two inhibitory neurons with post-inhibitory rebound JF - Communications in nonlinear science & numerical simulation N2 - We study an array of activity rhythms generated by a half-center oscillator (HCO), represented by a pair of reciprocally coupled neurons with post-inhibitory rebounds (PIR). Such coupling induced bursting possesses two time scales, one for fast spiking and another for slow quiescent periods, is shown to exhibit an array of synchronization properties. We discuss several HCO configurations constituted by two endogenous bursters, by tonic-spiking and quiescent neurons, as well as mixed-mode configurations composed of neurons of different type. We demonstrate that burst synchronization can be accompanied by complex, often chaotic, interactions of fast spikes within synchronized bursts. (C) 2015 Elsevier B.V. All rights reserved. KW - Synchronization KW - Hodgkin-Huxley model KW - Half-center oscillator KW - Post-inhibitory rebound Y1 - 2016 U6 - https://doi.org/10.1016/j.cnsns.2015.11.024 SN - 1007-5704 SN - 1878-7274 VL - 36 SP - 175 EP - 191 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Negrete, Jose A1 - Pumir, Alain A1 - Hsu, Hsin-Fang A1 - Westendorf, Christian A1 - Tarantola, Marco A1 - Beta, Carsten A1 - Bodenschatz, Eberhard T1 - Noisy Oscillations in the Actin Cytoskeleton of Chemotactic Amoeba JF - Physical review letters N2 - Biological systems with their complex biochemical networks are known to be intrinsically noisy. Here we investigate the dynamics of actin polymerization of amoeboid cells, which are close to the onset of oscillations. We show that the large phenotypic variability in the polymerization dynamics can be accurately captured by a generic nonlinear oscillator model in the presence of noise. We determine the relative role of the noise with a single dimensionless, experimentally accessible parameter, thus providing a quantitative description of the variability in a population of cells. Our approach, which rests on a generic description of a system close to a Hopf bifurcation and includes the effect of noise, can characterize the dynamics of a large class of noisy systems close to an oscillatory instability. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevLett.117.148102 SN - 0031-9007 SN - 1079-7114 VL - 117 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Neher, Dieter A1 - Kniepert, Juliane A1 - Elimelech, Arik A1 - Koster, L. Jan Anton T1 - A New Figure of Merit for Organic Solar Cells with Transport-limited Photocurrents JF - Scientific reports N2 - Compared to their inorganic counterparts, organic semiconductors suffer from relatively low charge carrier mobilities. Therefore, expressions derived for inorganic solar cells to correlate characteristic performance parameters to material properties are prone to fail when applied to organic devices. This is especially true for the classical Shockley-equation commonly used to describe current-voltage (JV)-curves, as it assumes a high electrical conductivity of the charge transporting material. Here, an analytical expression for the JV-curves of organic solar cells is derived based on a previously published analytical model. This expression, bearing a similar functional dependence as the Shockley-equation, delivers a new figure of merit a to express the balance between free charge recombination and extraction in low mobility photoactive materials. This figure of merit is shown to determine critical device parameters such as the apparent series resistance and the fill factor. Y1 - 2016 U6 - https://doi.org/10.1038/srep24861 SN - 2045-2322 VL - 6 SP - E2348 EP - E2349 PB - Nature Publ. Group CY - London ER - TY - GEN A1 - Neher, Dieter A1 - Kniepert, Juliane A1 - Elimelech, Arik A1 - Koster, L. Jan Anton T1 - A New Figure of Merit for Organic Solar Cells with Transport-limited Photocurrents N2 - Compared to their inorganic counterparts, organic semiconductors suffer from relatively low charge carrier mobilities. Therefore, expressions derived for inorganic solar cells to correlate characteristic performance parameters to material properties are prone to fail when applied to organic devices. This is especially true for the classical Shockley-equation commonly used to describe current-voltage (JV)-curves, as it assumes a high electrical conductivity of the charge transporting material. Here, an analytical expression for the JV-curves of organic solar cells is derived based on a previously published analytical model. This expression, bearing a similar functional dependence as the Shockley-equation, delivers a new figure of merit α to express the balance between free charge recombination and extraction in low mobility photoactive materials. This figure of merit is shown to determine critical device parameters such as the apparent series resistance and the fill factor. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 225 KW - Electronic and spintronic devices KW - Semiconductors Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-91414 ER - TY - JOUR A1 - Neher, Dieter A1 - Kniepert, Juliane A1 - Elimelech, Arik A1 - Koster, L. Jan Anton T1 - A New Figure of Merit for Organic Solar Cells with Transport-limited Photocurrents JF - Scientific reports N2 - Compared to their inorganic counterparts, organic semiconductors suffer from relatively low charge carrier mobilities. Therefore, expressions derived for inorganic solar cells to correlate characteristic performance parameters to material properties are prone to fail when applied to organic devices. This is especially true for the classical Shockley-equation commonly used to describe current-voltage (JV)-curves, as it assumes a high electrical conductivity of the charge transporting material. Here, an analytical expression for the JV-curves of organic solar cells is derived based on a previously published analytical model. This expression, bearing a similar functional dependence as the Shockley-equation, delivers a new figure of merit α to express the balance between free charge recombination and extraction in low mobility photoactive materials. This figure of merit is shown to determine critical device parameters such as the apparent series resistance and the fill factor. KW - Electronic and spintronic devices KW - Semiconductors Y1 - 2016 U6 - https://doi.org/10.1038/srep24861 SN - 2045-2322 VL - 6 PB - Nature Publishing Group CY - London ER - TY - JOUR A1 - Nishikawa, Ken-Ichi A1 - Frederiksen, J. T. A1 - Nordlund, A. A1 - Mizuno, Y. A1 - Hardee, P. E. A1 - Niemiec, J. A1 - Gomez, J. L. A1 - Dutan, I. A1 - Meli, A. A1 - Sol, H. A1 - Pohl, Martin A1 - Hartmann, D. H. T1 - EVOLUTION OF GLOBAL RELATIVISTIC JETS: COLLIMATIONS AND EXPANSION WITH kKHI AND THE WEIBEL INSTABILITY JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - In the study of relativistic jets one of the key open questions is their interaction with the environment. Here. we study the initial evolution of both electron-proton (e(-) - p(+)) and electron-positron (e(+/-)) relativistic jets, focusing on their lateral interaction with ambient plasma. We follow the evolution of toroidal magnetic fields generated by both the kinetic Kelvin-Helmholtz and Mushroom instabilities. For an e(-) - p(+) jet, the induced magnetic field collimates the jet and electrons are perpendicularly accelerated. As the instabilities saturate and subsequently weaken, the magnetic polarity switches from clockwise to counterclockwise in the middle of the jet. For an e(+/-) jet, we find strong mixing of electrons and positrons with the ambient plasma, resulting in the creation of a bow shock. The merging of current filaments generates density inhomogeneities that. initiate a forward shock. Strong jet-ambient plasma mixing prevents a full development of the jet (on the scale studied), revealing evidence for both jet collimation and particle acceleration in the forming bow shock. Differences in the magnetic field structure generated by e(-) - p(+) and e(+/-) jets may contribute to the polarization properties of the observed emission in AGN jets and gamma-ray bursts. KW - acceleration of particles KW - plasmas KW - radiation mechanisms: non-thermal KW - relativistic processes KW - stars: jets KW - Sun: magnetic fields Y1 - 2016 U6 - https://doi.org/10.3847/0004-637X/820/2/94 SN - 0004-637X SN - 1538-4357 VL - 820 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Nishikawa, Ken-Ichi A1 - Mizuno, Yosuke A1 - Niemiec, Jacek A1 - Kobzar, Oleh A1 - Pohl, Martin A1 - Gomez, Jose L. A1 - Dutan, Ioana A1 - Frederiksen, Jacob Trier A1 - Nordlund, Ake A1 - Meli, Athina A1 - Sol, Helene A1 - Hardee, Philip E. A1 - Hartmann, Dieter H. T1 - Microscopic Processes in Global Relativistic Jets Containing Helical Magnetic Fields JF - Galaxies : open access journal N2 - In the study of relativistic jets one of the key open questions is their interaction with the environment on the microscopic level. Here, we study the initial evolution of both electron-proton (e(-)-p(+)) and electron-positron (e(+/-)) relativistic jets containing helical magnetic fields, focusing on their interaction with an ambient plasma. We have performed simulations of "global" jets containing helical magnetic fields in order to examine how helical magnetic fields affect kinetic instabilities such as the Weibel instability, the kinetic Kelvin-Helmholtz instability (kKHI) and the Mushroom instability (MI). In our initial simulation study these kinetic instabilities are suppressed and new types of instabilities can grow. In the e(-)-p(+) jet simulation a recollimation-like instability occurs and jet electrons are strongly perturbed. In the e(+/-) jet simulation a recollimation-like instability occurs at early times followed by a kinetic instability and the general structure is similar to a simulation without helical magnetic field. Simulations using much larger systems are required in order to thoroughly follow the evolution of global jets containing helical magnetic fields. KW - relativistic jets KW - particle-in-cell simulations KW - global jets KW - helical magnetic fields KW - kinetic instabilities KW - kink instability Y1 - 2016 U6 - https://doi.org/10.3390/galaxies4040038 SN - 2075-4434 VL - 4 PB - MDPI CY - Basel ER - TY - GEN A1 - Nishikawa, Ken-Ichi A1 - Mizuno, Yosuke A1 - Niemiec, Jacek A1 - Kobzar, Oleh A1 - Pohl, Martin A1 - Gómez, Jose L. A1 - Duţan, Ioana A1 - Pe’er, Asaf A1 - Frederiksen, Jacob Trier A1 - Nordlund, Åke A1 - Meli, Athina A1 - Sol, Helene A1 - Hardee, Philip E. A1 - Hartmann, Dieter H. T1 - Microscopic processes in global relativistic jets containing helical magnetic fields T2 - Galaxies N2 - In the study of relativistic jets one of the key open questions is their interaction with the environment on the microscopic level. Here, we study the initial evolution of both electron-proton (e(-)-p(+)) and electron-positron (e(+/-)) relativistic jets containing helical magnetic fields, focusing on their interaction with an ambient plasma. We have performed simulations of "global" jets containing helical magnetic fields in order to examine how helical magnetic fields affect kinetic instabilities such as the Weibel instability, the kinetic Kelvin-Helmholtz instability (kKHI) and the Mushroom instability (MI). In our initial simulation study these kinetic instabilities are suppressed and new types of instabilities can grow. In the e(-)-p(+) jet simulation a recollimation-like instability occurs and jet electrons are strongly perturbed. In the e(+/-) jet simulation a recollimation-like instability occurs at early times followed by a kinetic instability and the general structure is similar to a simulation without helical magnetic field. Simulations using much larger systems are required in order to thoroughly follow the evolution of global jets containing helical magnetic fields. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 446 KW - relativistic jets KW - particle-in-cell simulations KW - global jets KW - helical magnetic fields KW - kinetic instabilities KW - kink instability Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-407604 ER - TY - GEN A1 - Niskanen, Johannes A1 - Kooser, Kuno A1 - Koskelo, Jaakko A1 - Käämbre, Tanel A1 - Kunnus, Kristjan A1 - Pietzsch, Annette A1 - Quevedo, Wilson A1 - Hakala, Mikko A1 - Föhlisch, Alexander A1 - Huotari, Simo A1 - Kukk, Edwin T1 - Density functional simulation of resonant inelastic X-ray scattering experiments in liquids: acetonitrile N2 - In this paper we report an experimental and computational study of liquid acetonitrile (H3C–C[triple bond, length as m-dash]N) by resonant inelastic X-ray scattering (RIXS) at the N K-edge. The experimental spectra exhibit clear signatures of the electronic structure of the valence states at the N site and incident-beam-polarization dependence is observed as well. Moreover, we find fine structure in the quasielastic line that is assigned to finite scattering duration and nuclear relaxation. We present a simple and light-to-evaluate model for the RIXS maps and analyze the experimental data using this model combined with ab initio molecular dynamics simulations. In addition to polarization-dependence and scattering-duration effects, we pinpoint the effects of different types of chemical bonding to the RIXS spectrum and conclude that the H2C–C[double bond, length as m-dash]NH isomer, suggested in the literature, does not exist in detectable quantities. We study solution effects on the scattering spectra with simulations in liquid and in vacuum. The presented model for RIXS proved to be light enough to allow phase-space-sampling and still accurate enough for identification of transition lines in physical chemistry research by RIXS. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 331 Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-395133 ER - TY - JOUR A1 - Oskinova, Lida T1 - X-ray diagnostics of massive star winds JF - Advances in space research N2 - Nearly all types of massive stars with radiatively driven stellar winds are X-ray sources that can be observed by the presently operating powerful X-ray telescopes. In this review I briefly address recent advances in our understanding of stellar winds obtained from X-ray observations. X-rays may strongly influence the dynamics of weak winds of main sequence B-type stars. X-ray pulsations were detected in a beta Cep type variable giving evidence of tight photosphere-wind connections. The winds of OB dwarfs with subtypes later than O9V may be predominantly in a hot phase, and X-ray observations offer the best window for their studies. The X-ray properties of OB super giants are largely determined by the effects of radiative transfer in their clumped stellar winds. The recently suggested method to directly measure mass-loss rates of O stars by fitting the shapes of X-ray emission lines is considered but its validity cannot be confirmed. To obtain robust quantitative information on stellar wind parameters from X-ray spectroscopy, a multiwavelength analysis by means of stellar atmosphere models is required. Independent groups are now performing such analyses with encouraging results. Joint analyses of optical, UV, and X-ray spectra of OB supergiants yield consistent mass-loss rates. Depending on the adopted clumping parameters, the empirically derived mass-loss rates are a factor of a few smaller or comparable to those predicted by standard recipes (Vink et al., 2001). All sufficiently studied O stars display variable X-ray emission that might be related to corotating interaction regions in their winds. In the latest stages of stellar evolution, single red supergiants (RSG) and luminous blue variable (LBV) stars do not emit observable amounts of X-rays. On the other hand, nearly all types of Wolf-Rayet (WR) stars are X-ray sources. X-ray spectroscopy allows a sensitive probe of WR wind abundances and opacities. (C) 2016 COSPAR. Published by Elsevier Ltd. All rights reserved. KW - Blue stars KW - Stellar winds KW - X-ray emission spectra Y1 - 2016 U6 - https://doi.org/10.1016/j.asr.2016.06.030 SN - 0273-1177 SN - 1879-1948 VL - 58 SP - 739 EP - 760 PB - Elsevier CY - Oxford ER - TY - GEN A1 - Oskinova, Lida T1 - Preface: X-ray emission from hot stars and their winds T2 - Advances in space research Y1 - 2016 U6 - https://doi.org/10.1016/j.asr.2016.06.031 SN - 0273-1177 SN - 1879-1948 VL - 58 SP - 679 EP - 679 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Oskinova, Lida A1 - Kubatova, Brankica A1 - Hamann, Wolf-Rainer T1 - Moving inhomogeneous envelopes of stars JF - Transport in Porous Media N2 - Massive stars are extremely luminous and drive strong winds, blowing a large part of their matter into the galactic environment before they finally explode as a supernova. Quantitative knowledge of massive star feedback is required to understand our Universe as we see it. Traditionally, massive stars have been studied under the assumption that their winds are homogeneous and stationary, largely relying on the Sobolev approximation. However, Observations with the newest instruments, together with progress in model calculations, ultimately dictate a cardinal change of this paradigm: stellar winds are highly inhomogeneous. Hence, we are now advancing to a new stage in our understanding of stellar winds. Using the foundations laid by V.V. Sobolev and his school, we now update and further develop the stellar spectral analysis techniques. New sophisticated 3-D models of radiation transfer in inhomogeneous expanding media elucidate the physics of stellar winds and improve classical empiric mass-loss rate diagnostics. Applications of these new techniques to multiwavelength observations of massive stars yield consistent and robust stellar wind parameters. (C) 2016 Elsevier Ltd. All rights reserved. KW - Stars: mass-loss KW - Stars: winds KW - Outflows KW - Stars: atmospheres early type Y1 - 2016 U6 - https://doi.org/10.1016/j.jqsrt.2016.06.017 SN - 0022-4073 SN - 1879-1352 VL - 183 SP - 100 EP - 112 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Otto, Katharina Alexandra A1 - Jaumann, R. A1 - Krohn, K. A1 - Spahn, Frank A1 - Raymond, C. A. A1 - Russell, C. T. T1 - The Coriolis effect on mass wasting during the Rheasilvia impact on asteroid Vesta JF - Geophysical research letters N2 - We investigate the influence of the Coriolis force on mass motion related to the Rheasilvia impact on asteroid Vesta. Observations by the NASA Dawn mission revealed a pattern of curved radial ridges, which are related to Coriolis-deflected mass-wasting during the initial modification stage of the crater. Utilizing the projected curvature of the mass-wasting trajectories, we developed a method that enabled investigation of the initial mass wasting of the Rheasilvia impact by observational means. We demonstrate that the Coriolis force can strongly affect the crater formation processes on rapidly rotating objects, and we derive the material's velocities (28.9 ± 22.5 m/s), viscosities (1.5–9.0 × 106 Pa s) and coefficients of friction (0.02–0.81) during the impact modification stage. The duration of the impact modification stage could be estimated to (1.1 ± 0.5) h. By analyzing the velocity distribution with respect to the topography, we deduce that the Rheasilvia impactor hit a heterogeneous target and that the initial crater walls were significantly steeper during the modification stage. Y1 - 2016 U6 - https://doi.org/10.1002/2016GL071539 SN - 0094-8276 SN - 1944-8007 VL - 43 SP - 12340 EP - 12347 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Palyulin, Vladimir V. A1 - Chechkin, Aleksei V. A1 - Klages, Rainer A1 - Metzler, Ralf T1 - Search reliability and search efficiency of combined Levy-Brownian motion: long relocations mingled with thorough local exploration JF - Journal of physics : A, Mathematical and theoretical N2 - A combined dynamics consisting of Brownian motion and Levy flights is exhibited by a variety of biological systems performing search processes. Assessing the search reliability of ever locating the target and the search efficiency of doing so economically of such dynamics thus poses an important problem. Here we model this dynamics by a one-dimensional fractional Fokker-Planck equation combining unbiased Brownian motion and Levy flights. By solving this equation both analytically and numerically we show that the superposition of recurrent Brownian motion and Levy flights with stable exponent alpha < 1, by itself implying zero probability of hitting a point on a line, leads to transient motion with finite probability of hitting any point on the line. We present results for the exact dependence of the values of both the search reliability and the search efficiency on the distance between the starting and target positions as well as the choice of the scaling exponent a of the Levy flight component. KW - random search process KW - first passage KW - first arrival KW - Levy flights KW - Brownian motion Y1 - 2016 U6 - https://doi.org/10.1088/1751-8113/49/39/394002 SN - 1751-8113 SN - 1751-8121 VL - 49 SP - 2189 EP - 2193 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Parezanovic, Vladimir A1 - Cordier, Laurent A1 - Spohn, Andreas A1 - Duriez, Thomas A1 - Noack, Bernd R. A1 - Bonnet, Jean-Paul A1 - Segond, Marc A1 - Abel, Markus A1 - Brunton, Steven L. T1 - Frequency selection by feedback control in a turbulent shear flow JF - Journal of fluid mechanics N2 - Many previous studies have shown that the turbulent mixing layer under periodic forcing tends to adopt a lock-on state, where the major portion of the fluctuations in the flow are synchronized at the forcing frequency. The goal of this experimental study is to apply closed-loop control in order to provoke the lock-on state, using information from the flow itself. We aim to determine the range of frequencies for which the closed-loop control can establish the lock-on, and what mechanisms are contributing to the selection of a feedback frequency. In order to expand the solution space for optimal closed-loop control laws, we use the genetic programming control (CPC) framework. The best closed-loop control laws obtained by CPC are analysed along with the associated physical mechanisms in the mixing layer flow. The resulting closed-loop control significantly outperforms open-loop forcing in terms of robustness to changes in the free-stream velocities. In addition, the selection of feedback frequencies is not locked to the most amplified local mode, but rather a range of frequencies around it. KW - free shear layers KW - instability control KW - turbulence control Y1 - 2016 U6 - https://doi.org/10.1017/jfm.2016.261 SN - 0022-1120 SN - 1469-7645 VL - 797 SP - 247 EP - 283 PB - Cambridge Univ. Press CY - New York ER - TY - JOUR A1 - Paulke, Andreas A1 - Stranks, Samuel D. A1 - Kniepert, Juliane A1 - Kurpiers, Jona A1 - Wolff, Christian Michael A1 - Schön, Natalie A1 - Snaith, Henry J. A1 - Brenner, Thomas J. K. A1 - Neher, Dieter T1 - Charge carrier recombination dynamics in perovskite and polymer solar cells JF - Applied physics letters N2 - Time-delayed collection field experiments are applied to planar organometal halide perovskite (CH3NH3PbI3) based solar cells to investigate charge carrier recombination in a fully working solar cell at the nanosecond to microsecond time scale. Recombination of mobile (extractable) charges is shown to follow second-order recombination dynamics for all fluences and time scales tested. Most importantly, the bimolecular recombination coefficient is found to be time-dependent, with an initial value of ca. 10(-9) cm(3)/s and a progressive reduction within the first tens of nanoseconds. Comparison to the prototypical organic bulk heterojunction device PTB7:PC71BM yields important differences with regard to the mechanism and time scale of free carrier recombination. (C) 2016 AIP Publishing LLC. Y1 - 2016 U6 - https://doi.org/10.1063/1.4944044 SN - 0003-6951 SN - 1077-3118 VL - 108 SP - 252 EP - 262 PB - American Institute of Physics CY - Melville ER - TY - THES A1 - Pavlenko, Elena T1 - Hybrid nanolayer architectures for ultrafast acousto-plasmonics in soft matter T1 - Hybride Nanolayer-Architekturen für ultraschnelle Akusto-Plasmonics in weicher Materie N2 - The goal of the presented work is to explore the interaction between gold nanorods (GNRs) and hyper-sound waves. For the generation of the hyper-sound I have used Azobenzene-containing polymer transducers. Multilayer polymer structures with well-defined thicknesses and smooth interfaces were built via layer-by-layer deposition. Anionic polyelectrolytes with Azobenzene side groups (PAzo) were alternated with cationic polymer PAH, for the creation of transducer films. PSS/PAH multilayer were built for spacer layers, which do not absorb in the visible light range. The properties of the PAzo/PAH film as a transducer are carefully characterized by static and transient optical spectroscopy. The optical and mechanical properties of the transducer are studied on the picosecond time scale. In particular the relative change of the refractive index of the photo-excited and expanded PAH/PAzo is Δn/n = - 2.6*10‐4. Calibration of the generated strain is performed by ultrafast X-ray diffraction calibrated the strain in a Mica substrate, into which the hyper-sound is transduced. By simulating the X-ray data with a linear-chain-model the strain in the transducer under the excitation is derived to be Δd/d ~ 5*10‐4. Additional to the investigation of the properties of the transducer itself, I have performed a series of experiments to study the penetration of the generated strain into various adjacent materials. By depositing the PAzo/PAH film onto a PAH/PSS structure with gold nanorods incorporated in it, I have shown that nanoscale impurities can be detected via the scattering of hyper-sound. Prior to the investigation of complex structures containing GNRs and the transducer, I have performed several sets of experiments on GNRs deposited on a small buffer of PSS/PAH. The static and transient response of GNRs is investigated for different fluence of the pump beam and for different dielectric environments (GNRs covered by PSS/PAH). A systematic analysis of sample architectures is performed in order to construct a sample with the desired effect of GNRs responding to the hyper-sound strain wave. The observed shift of a feature related to the longitudinal plasmon resonance in the transient reflection spectra is interpreted as the event of GNRs sensing the strain wave. We argue that the shift of the longitudinal plasmon resonance is caused by the viscoelastic deformation of the polymer around the nanoparticle. The deformation is induced by the out of plane difference in strain in the area directly under a particle and next to it. Simulations based on the linear chain model support this assumption. Experimentally this assumption is proven by investigating the same structure, with GNRs embedded in a PSS/PAH polymer layer. The response of GNRs to the hyper-sound wave is also observed for the sample structure with GNRs embedded in PAzo/PAH films. The response of GNRs in this case is explained to be driven by the change of the refractive index of PAzo during the strain propagation. N2 - Akustische Experimente auf ultraschnellen Zeitskalen ermöglichen die Bestimmung von Tiefeninformationen in Dünnschichtproben. Der Grundgedanke dieser Methode ist die Analyse von Schallwellen, die sich in dem zu untersuchenden Material ausbreiten. Die Schallpulse werden dabei üblicherweise mittels dünner Schichten erzeugt, die dafür auf die Probe aufgebracht werden. Diese Methode ist etabliert für die Untersuchung von harten, anorganischen Materialien, aber weniger entwickelt für weiche, organische Materialien. Die wenigen existierenden Untersuchungen von weichen Materialien mittels ultraschneller Akustik nutzen bisher die Ausdehnung dünner Metallfilme, beispielsweise aus Aluminium oder Titan, für den Umwandlungsprozess von kurzen Lichtpulsen zu Schallwellen. Die deutlich höheren Dichten der Metalle gegenüber der zu untersuchenden weichen Materie führen zu einer geringen Effizienz bei der Einkopplung der Schallpulse in das Material. Weiterhin ist es schwierig, die Metallfilme auf die zu untersuchenden Materialien chemisch aufzubringen. Eine Möglichkeit diese Probleme zu umgehen, ist die Verwendung von Licht-Schallwandlern aus chemisch ähnlicher, weicher Materialien. Hier präsentiere ich die Ergebnisse meiner Untersuchungen von Polymer Filmen, welche Azobenzen als aktiven Bestandteil für die photo-akustische Umwandlung enthalten. Dabei wurden die Filme mittels statischer, sowie auch zeitaufgelöster Spektroskopie untersucht. Mit zeitaufgelösten Brillouin-Streuungs-Experimenten habe ich die Schallgeschwindigkeit in den Polymeren und dem Azobenzen-Schallwandler zu 3.4±0.3 nm/ps bestimmt. Die relative transiente Änderung des Brechungsindex in dem Azobenzenfilm aus optischen Messungen beträgt Δn/n = - 2.6*10‐4. Die Untersuchung der Schallpropagation in verschiedenen Probengeometrien erlaubt es uns, Reflektionen der Schallwellen von verschiedenen Übergängen (Polymer/Quarz, Polymer/Luft) und die Ausbreitung der mechanischen Wellen in weiche (Polymere) und harte (Quarz) angrenzende Materialien zu studieren. Durch Untersuchungen an einer Probe mit Gold-Nano-Stäbchen innerhalb einer Polymerschicht habe ich die Möglichkeit aufgezeigt, die Tiefenposition der Nanopartikel zu bestimmen. Die Ausdehnung des photomechanischen Wandlers wurde mittels zeitaufgelöster Röntgenbeugung zu ε = Δd/d ̴ 5x10-4 bestimmt. Der zweite Teil der Doktorarbeit behandelt die Wechselwirkung von Schallwellen und Gold-Nano-Stäbchen (GNS). GNS werden oft in der Chemie und Biologie als plasmonische Marker eingesetzt. In den meisten Fällen werden die Teilchen dafür mit einer Hülle überzogen, um ihre Agglomeration zu unterdrücken oder um ihnen spezielle Sensoreigenschaften zu geben. Trotz ihrer häufigen Anwendung in teilweise sehr komplexen Geometrien sind die optischen und elastischen Eigenschaften der Hülle der Nanopartikel, sowie deren Wechselwirkung mit der Umgebung wenig erforscht. Um die Wechselwirkung zwischen GNS und Schallwellen zu untersuchen habe ich eine systematische Studie an verschiedenen Probenstrukturen unternommen. Dabei finden wir, dass die viskoelastische Verformung der Polymerhülle um die GNS von der unterschiedlichen Ausdehnung der Fläche unterhalb der Partikel und neben ihnen stammt. Diese Schlussfolgerung wird von einer Simulation ihrer Ausdehnungsdynamik unterstützt. Einen weiteren Beleg liefern Experimente bei denen die Verformung von Polymeren an der Oberfläche dadurch verringert wird, dass die Gold-Nano-Stäbchen mit einer zusätzlichen dünnen Polymerschicht bedeckt werden. KW - ultrafast dynamics KW - plasmonics KW - hypersound KW - azobenzene KW - ultrafast spectroscopy KW - ultraschnelle Dynamik KW - Pump-Probe Spektroskopie KW - Plasmonics KW - Gold-Nanopartikel KW - Azobenzene Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-99544 ER - TY - JOUR A1 - Pavlenko, Elena S. A1 - Sander, Mathias A1 - Cui, Q. A1 - Bargheer, Matias T1 - Gold Nanorods Sense the Ultrafast Viscoelastic Deformation of Polymers upon Molecular Strain Actuation JF - The journal of physical chemistry : C, Nanomaterials and interfaces N2 - On the basis of the layer-by-layer deposition of polyelectrolytes, we have designed hybrid nanolayer composites for integrated optoacoustic experiments. The femtosecond-laser-excitation of an Azo functionalized film launches nanoscale strain waves at GHz frequencies into a transparent polymer layer. Gold nanorods deposited on the surface sense the arrival of these hyper-sound-waves on the picosecond time scale via a modification of their longitudinal plasmon resonance. We simulated the strain waves using a simple linear masses-and-springs model, which yields good agreement with the observed time scales associated with the nanolayer thicknesses of the constituent materials. From systematic experiments with calibrated strain amplitudes we conclude that reversible viscoelastic deformations of the polyelectrolyte multilayers are triggered by ultrashort pressure transients of about 4 MPa. Our experiments show that strain-mediated interactions in nanoarchitectures composed of molecular photoswitches and plasmonic particles may be used to design new functionalities. The approach combines the highly flexible and cost-effective preparation of polyelectrolyte multilayers with ultrafast molecular strain actuation and plasmonic sensing. Although we use simple flat layered structures for demonstration, this new concept can be used for three-dimensional nanoassemblies with different functionalities. The ultrafast and reversible nature of the response is highly desirable, and the short wavelength associated with the high frequency of the hyper-sound-waves connecting photoactive molecules and nanoparticles inherently gives spectroscopic access to the nanoscale. High-frequency elastic moduli are derived from the ultrafast spectroscopy of the hypersonic response in polyelectrolyte multilayers. Y1 - 2016 U6 - https://doi.org/10.1021/acs.jpcc.6b06915 SN - 1932-7447 VL - 120 SP - 24957 EP - 24964 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Pavlenko, Elena S. A1 - Sander, Mathias A1 - Mitzscherling, S. A1 - Pudell, Jan-Etienne A1 - Zamponi, Flavio A1 - Roessle, M. A1 - Bojahr, Andre A1 - Bargheer, Matias T1 - Azobenzene - functionalized polyelectrolyte nanolayers as ultrafast optoacoustic transducers JF - Nanoscale N2 - We introduce azobenzene-functionalized polyelectrolyte multilayers as efficient, inexpensive optoacoustic transducers for hyper-sound strain waves in the GHz range. By picosecond transient reflectivity measurements we study the creation of nanoscale strain waves, their reflection from interfaces, damping by scattering from nanoparticles and propagation in soft and hard adjacent materials like polymer layers, quartz and mica. The amplitude of the generated strain epsilon similar to 5 x 10(-4) is calibrated by ultrafast X-ray diffraction. Y1 - 2016 U6 - https://doi.org/10.1039/c6nr01448h SN - 2040-3364 SN - 2040-3372 VL - 8 SP - 13297 EP - 13302 PB - Royal Society of Chemistry CY - Cambridge ER - TY - GEN A1 - Pavlenko, Elena S. A1 - Sander, Mathias A1 - Mitzscherling, Steffen A1 - Pudell, Jan-Etienne A1 - Zamponi, Flavio A1 - Rössle, Matthias A1 - Bojahr, Andre A1 - Bargheer, Matias T1 - Azobenzene – functionalized polyelectrolyte nanolayers as ultrafast optoacoustic transducers N2 - We introduce azobenzene-functionalized polyelectrolyte multilayers as efficient, inexpensive optoacoustic transducers for hyper-sound strain waves in the GHz range. By picosecond transient reflectivity measurements we study the creation of nanoscale strain waves, their reflection from interfaces, damping by scattering from nanoparticles and propagation in soft and hard adjacent materials like polymer layers, quartz and mica. The amplitude of the generated strain ε ∼ 5 × 10−4 is calibrated by ultrafast X-ray diffraction. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 297 Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-101996 VL - 8 SP - 13297 EP - 13302 ER - TY - JOUR A1 - Pedatella, Nick M. A1 - Fang, T. -W. A1 - Jin, Hao A1 - Sassi, F. A1 - Schmidt, H. A1 - Chau, Jorge Luis A1 - Siddiqui, Tarique Adnan A1 - Goncharenko, L. T1 - Multimodel comparison of the ionosphere variability during the 2009 sudden stratosphere warming JF - Journal of geophysical research : Space physics N2 - A comparison of different model simulations of the ionosphere variability during the 2009 sudden stratosphere warming (SSW) is presented. The focus is on the equatorial and low-latitude ionosphere simulated by the Ground-to-topside model of the Atmosphere and Ionosphere for Aeronomy (GAIA), Whole Atmosphere Model plus Global Ionosphere Plasmasphere (WAM+GIP), and Whole Atmosphere Community Climate Model eXtended version plus Thermosphere-Ionosphere-Mesosphere-Electrodynamics General Circulation Model (WACCMX+TIMEGCM). The simulations are compared with observations of the equatorial vertical plasma drift in the American and Indian longitude sectors, zonal mean Fregion peak density (NmF2) from the Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) satellites, and ground-based Global Positioning System (GPS) total electron content (TEC) at 75 degrees W. The model simulations all reproduce the observed morning enhancement and afternoon decrease in the vertical plasma drift, as well as the progression of the anomalies toward later local times over the course of several days. However, notable discrepancies among the simulations are seen in terms of the magnitude of the drift perturbations, and rate of the local time shift. Comparison of the electron densities further reveals that although many of the broad features of the ionosphere variability are captured by the simulations, there are significant differences among the different model simulations, as well as between the simulations and observations. Additional simulations are performed where the neutral atmospheres from four different whole atmosphere models (GAIA, HAMMONIA (Hamburg Model of the Neutral and Ionized Atmosphere), WAM, and WACCMX) provide the lower atmospheric forcing in the TIME-GCM. These simulations demonstrate that different neutral atmospheres, in particular, differences in the solar migrating semidiurnal tide, are partly responsible for the differences in the simulated ionosphere variability in GAIA, WAM+GIP, and WACCMX+TIMEGCM. KW - ionosphere KW - sudden stratosphere warming Y1 - 2016 U6 - https://doi.org/10.1002/2016JA022859 SN - 2169-9380 SN - 2169-9402 VL - 121 SP - 7204 EP - 7225 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Piatti, Andres E. A1 - Ivanov, Valentin D. A1 - Rubele, Stefano A1 - Marconi, Marcella A1 - Ripepi, Vincenzo A1 - Cioni, Maria-Rosa L. A1 - Oliveira, Joana M. A1 - Bekki, Kenji T1 - The VMC Survey - XXI. New star cluster candidates discovered from infrared photometry in the Small Magellanic Cloud JF - Monthly notices of the Royal Astronomical Society KW - techniques: photometric KW - galaxies: individual: SMC KW - Magellanic Clouds Y1 - 2016 U6 - https://doi.org/10.1093/mnras/stw1000 SN - 0035-8711 SN - 1365-2966 VL - 460 SP - 383 EP - 395 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Pikovskij, Arkadij T1 - Reconstruction of a neural network from a time series of firing rates JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - Randomly coupled neural fields demonstrate irregular variation of firing rates, if the coupling is strong enough, as has been shown by Sompolinsky et al. [Phys. Rev. Lett. 61, 259 (1988)]. We present a method for reconstruction of the coupling matrix from a time series of irregular firing rates. The approach is based on the particular property of the nonlinearity in the coupling, as the latter is determined by a sigmoidal gain function. We demonstrate that for a large enough data set and a small measurement noise, the method gives an accurate estimation of the coupling matrix and of other parameters of the system, including the gain function. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevE.93.062313 SN - 2470-0045 SN - 2470-0053 VL - 93 PB - American Physical Society CY - College Park ER - TY - GEN A1 - Pimenova, Anastasiya V. A1 - Goldobin, Denis S. A1 - Rosenblum, Michael A1 - Pikovskij, Arkadij T1 - Interplay of coupling and common noise at the transition to synchrony in oscillator populations N2 - There are two ways to synchronize oscillators: by coupling and by common forcing, which can be pure noise. By virtue of the Ott-Antonsen ansatz for sine-coupled phase oscillators, we obtain analytically tractable equations for the case where both coupling and common noise are present. While noise always tends to synchronize the phase oscillators, the repulsive coupling can act against synchrony, and we focus on this nontrivial situation. For identical oscillators, the fully synchronous state remains stable for small repulsive coupling; moreover it is an absorbing state which always wins over the asynchronous regime. For oscillators with a distribution of natural frequencies, we report on a counter-intuitive effect of dispersion (instead of usual convergence) of the oscillators frequencies at synchrony; the latter effect disappears if noise vanishes. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 310 Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-103471 ER - TY - JOUR A1 - Pimenova, Anastasiya V. A1 - Goldobin, Denis S. A1 - Rosenblum, Michael A1 - Pikovskij, Arkadij T1 - Interplay of coupling and common noise at the transition to synchrony in oscillator populations JF - Scientific reports N2 - There are two ways to synchronize oscillators: by coupling and by common forcing, which can be pure noise. By virtue of the Ott-Antonsen ansatz for sine-coupled phase oscillators, we obtain analytically tractable equations for the case where both coupling and common noise are present. While noise always tends to synchronize the phase oscillators, the repulsive coupling can act against synchrony, and we focus on this nontrivial situation. For identical oscillators, the fully synchronous state remains stable for small repulsive coupling; moreover it is an absorbing state which always wins over the asynchronous regime. For oscillators with a distribution of natural frequencies, we report on a counter-intuitive effect of dispersion (instead of usual convergence) of the oscillators frequencies at synchrony; the latter effect disappears if noise vanishes. Y1 - 2016 U6 - https://doi.org/10.1038/srep38518 SN - 2045-2322 VL - 6 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Pingel, Patrick A1 - Arvind, Malavika A1 - Kölln, Lisa A1 - Steyrleuthner, Robert A1 - Kraffert, Felix A1 - Behrends, Jan A1 - Janietz, Silvia A1 - Neher, Dieter T1 - p-Type Doping of Poly(3-hexylthiophene) with the Strong Lewis Acid Tris(pentafluorophenyl)borane JF - Advanced electronic materials N2 - State-of-the-art p-type doping of organic semiconductors is usually achieved by employing strong -electron acceptors, a prominent example being tetrafluorotetracyanoquinodimethane (F(4)TCNQ). Here, doping of the semiconducting model polymer poly(3-hexylthiophene), P3HT, using the strong Lewis acid tris(pentafluorophenyl)borane (BCF) as a dopant, is investigated by admittance, conductivity, and electron paramagnetic resonance measurements. The electrical characteristics of BCF- and F(4)TCNQ-doped P3HT layers are shown to be very similar in terms of the mobile hole density and the doping efficiency. Roughly 18% of the employed dopants create mobile holes in either F-4 TCNQ- or BCF-doped P3HT, while the majority of doping-induced holes remain strongly Coulomb-bound to the dopant anions. Despite similar hole densities, conductivity and hole mobility are higher in BCF-doped P3HT layers than in F(4)TCNQ-doped samples. This and the good solubility in many organic solvents render BCF very useful for p-type doping of organic semiconductors. KW - charge carrier transport KW - charge transfer KW - conductivity KW - molecular doping KW - organic semiconductors Y1 - 2016 U6 - https://doi.org/10.1002/aelm.201600204 SN - 2199-160X VL - 2 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Poeschke, Patrick A1 - Sokolov, Igor M. A1 - Nepomnyashchy, Alexander A. A1 - Zaks, Michael A. T1 - Anomalous transport in cellular flows: The role of initial conditions and aging JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We consider the diffusion-advection problem in two simple cellular flow models ( often invoked as examples of subdiffusive tracer motion) and concentrate on the intermediate time range, in which the tracer motion indeed may show subdiffusion. We perform extensive numerical simulations of the systems under different initial conditions and show that the pure intermediate-time subdiffusion regime is only evident when the particles start at the border between different cells, i.e., at the separatrix, and is less pronounced or absent for other initial conditions. The motion moreover shows quite peculiar aging properties, which are also mirrored in the behavior of the time-averaged mean squared displacement for single trajectories. This kind of behavior is due to the complex motion of tracers trapped inside the cell and is absent in classical models based on continuous-time random walks with no dynamics in the trapped state. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevE.94.032128 SN - 2470-0045 SN - 2470-0053 VL - 94 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Przybilla, Norbert A1 - Fossati, Luca A1 - Hubrig, Swetlana A1 - Nieva, M. -F. A1 - Jaervinen, S. P. A1 - Castro, Norberto A1 - Schoeller, M. A1 - Ilyin, Ilya A1 - Butler, Keith A1 - Schneider, F. R. N. A1 - Oskinova, Lida A1 - Morel, T. A1 - Langer, N. A1 - de Koter, A. T1 - B fields in OB stars (BOB): Detection of a magnetic field in the He-strong star CPD-57 degrees 3509 JF - Organic letters N2 - Methods. Spectropolarimetric observations with FORS2 and HARPSpol are analysed using two independent approaches to quantify the magnetic field strength. A high-S/N FLAMES/GIRAFFE spectrum is analysed using a hybrid non-LTE model atmosphere technique. Comparison with stellar evolution models constrains the fundamental parameters of the star. Results. We obtain a firm detection of a surface averaged longitudinal magnetic field with a maximum amplitude of about 1 kG. Assuming a dipolar configuration of the magnetic field, this implies a dipolar field strength larger than 3.3 kG. Moreover, the large amplitude and fast variation (within about 1 day) of the longitudinal magnetic field implies that CPD-57 degrees 3509 is spinning very fast despite its apparently slow projected rotational velocity. The star should be able to support a centrifugal magnetosphere, yet the spectrum shows no sign of magnetically confined material; in particular, emission in H alpha is not observed. Apparently, the wind is either not strong enough for enough material to accumulate in the magnetosphere to become observable or, alternatively, some leakage process leads to loss of material from the magnetosphere. The quantitative spectroscopic analysis of the star yields an effective temperature and a logarithmic surface gravity of 23 750 +/- 250 K and 4.05 +/- 0.10, respectively, and a surface helium fraction of 0.28 +/- 0.02 by number. The surface abundances of C, N, O, Ne, S, and Ar are compatible with the cosmic abundance standard, whereas Mg, Al, Si, and Fe are depleted by about a factor of 2. This abundance pattern can be understood as the consequence of a fractionated stellar wind. CPD-57 degrees 3509 is one of the most evolved He-strong stars known with an independent age constraint due to its cluster membership. KW - stars: abundances KW - stars: atmospheres KW - stars: evolution KW - stars: magnetic field KW - stars: individual: CPD-57 degrees 3509 KW - stars: massive Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201527646 SN - 1432-0746 VL - 587 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Puhlmann, Dirk A1 - Henkel, Carsten A1 - Heuer, Axel A1 - Pieplow, Gregor A1 - Menzel, Ralf T1 - Characterization of a remote optical element with bi-photons JF - Physica scripta : an international journal for experimental and theoretical physics N2 - We present a simple setup that exploits the interference of entangled photon pairs. 'Signal' photons are sent through a Mach–Zehnder-like interferometer, while 'idlers' are detected in a variable polarization state. Two-photon interference (in coincidence detection) is observed with very high contrast and for significant time delays between signal and idler detection events. This is explained by quantum erasure of the polarization tag and a delayed choice protocol involving a non-local virtual polarizer. The phase of the two-photon fringes is scanned by varying the path length in the signal beam or by rotating a birefringent crystal in the idler beam. We exploit this to characterize one beam splitter of the signal photon interferometer (reflection and transmission amplitudes including losses), using only information about coincidences and control parameters in the idler path. This is possible because our bi-photon state saturates the Greenberger–Yelin–Englert inequality between contrast and predictability. KW - quantum optics KW - quantum eraser KW - entanglement KW - bi-photons Y1 - 2016 U6 - https://doi.org/10.1088/0031-8949/91/2/023006 SN - 0031-8949 SN - 1402-4896 VL - 91 SP - 113 EP - 114 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Qiu, Xunlin T1 - Significant enhancement of the charging efficiency in the cavities of ferroelectrets through gas exchange during charging JF - Applied physics letters N2 - Ferroelectrets are non-polar polymer foams or polymer systems with internally charged cavities. They are charged through a series of dielectric barrier discharges (DBDs) that are caused by the electrical breakdown of the gas inside the cavities. Thus, the breakdown strength of the gas strongly influences the charging process of ferroelectrets. A gas with a lower breakdown strength has a lower threshold voltage, thus decreasing the onset voltage for DBD charging. However, a lower threshold voltage also leads to a lower value for the remanent polarization, as back discharges that are caused by the electric field of the internally deposited charges can take place already at lower charge levels. On this basis, a charging strategy is proposed where the DBDs start in a gas with a lower breakdown strength (in the present example, helium) and are completed at a higher breakdown strength (e.g., nitrogen or atmospheric air). Thus, the exchange of the gas in the cavities during charging can significantly enhance the charging efficiency, i.e., yield much higher piezoelectric coefficients in ferroelectrets at significantly lower charging voltages. Published by AIP Publishing. Y1 - 2016 U6 - https://doi.org/10.1063/1.4971259 SN - 0003-6951 SN - 1077-3118 VL - 109 SP - 2543 EP - 2555 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Qiu, Xunlin A1 - Wirges, Werner A1 - Gerhard, Reimund T1 - Thermal poling of ferroelectrets: How does the gas temperature influence dielectric barrier discharges in cavities? JF - Applied physics letters N2 - The influence of the temperature in the gas-filled cavities on the charging process of ferroelectret film systems has been studied in hysteresis measurements. The threshold voltage and the effective polarization of the ferroelectrets were determined as functions of the charging temperature TP. With increasing TP, the threshold voltage for triggering dielectric barrier discharges in ferroelectrets decreases. Thus, increasing the temperature facilitates the charging of ferroelectrets. However, a lower threshold voltage reduces the attainable remanent polarization because back discharges occur at lower charge levels, as soon as the charging voltage is turned off. The results are discussed in view of Paschen's law for electrical breakdown, taking into account the respective gas temperature and a simplified model for ferroelectrets. Our results indicate that the thermal poling scheme widely used for conventional ferroelectrics is also useful for electrically charging ferroelectrets. Ferroelectrets (sometimes also called piezoelectrets) are relatively new members of the family of piezo-, pyro-, and ferroelectric materials.1–5 As their name indicates, ferroelectrets are space-charge electrets that show ferroic behavior. They are non-uniform electret materials or materials systems with electrically charged internal cavities. As space-charge electrets, ferroelectrets usually do not contain any molecular dipoles. However, the cavities inside the material can be turned into macroscopic dipoles through a series of micro-plasma discharges at high electric fields, so-called dielectric barrier discharges (DBDs).6–8 The gas inside the cavities is ionized when the internal electric field exceeds the threshold for electrical breakdown, generating charges of both polarities.9 The positive and negative charges travel in opposite directions, and are eventually trapped at the internal top and bottom surfaces of the cavities, respectively. After charging, the cavities may be regarded as macroscopic dipoles that can be switched by reversing the applied voltage. An electric-polarization-vs.-electric-field (P(E)) hysteresis is considered as an essential criterion for ferroelectricity. P(E)-hysteresis curves are usually characterized by the spontaneous polarization, the coercive field, and the remanent polarization. Recently, we have demonstrated P(E)-hysteresis loops on two different types of ferroelectrets, namely, cellular polypropylene ferroelectrets and tubular-channel fluoroethylene-polypropylene copolymer ferroelectrets.10,11 The P(E)-hysteresis loops not only prove the ferroic behavior of ferroelectrets, but also allow us to determine such parameters as the coercive field and the remanent polarization. It is widely accepted that Paschen breakdown is the underlying mechanism for the inception of DBDs in ferroelectrets.12–14 On this basis, the charging behavior and the resulting piezoelectricity of ferroelectrets in different gases at various pressures have been studied.15–17 Paschen's law describes the conditions for electrical breakdown in a gas at a constant temperature (usually room temperature), and it needs to be modified for gas breakdown at other temperatures. The temperature stability of the piezoelectricity in ferroelectrets after charging at elevated temperatures was investigated by several researchers.18–21 Recently, a preliminary report about the effects of the charging temperature on the hysteresis loops in ferroelectrets has been presented.22 In this letter, the influence of the gas temperature on the charging of ferroelectret systems is investigated in more detail by means of quasi-ferroelectric hysteresis-loop measurements. Teflon™ fluoroethylenepropylene (FEP) copolymer samples with tubular channels were prepared via thermal lamination as described previously.23 To this end, two FEP films with a thickness of 50 μm each were laminated at 300 ° C around a 100 μm thick polytetrafluoroethylene (PTFE) template (total area 35 mm × 45 mm) that contains parallel rectangular openings (area 1.5 mm × 40 mm each). After lamination, the template was removed, which results in an FEP film system with open tubular channels. The samples were metallized on both surfaces with aluminum electrodes of 20 mm diameter. P(E)-hysteresis loops were obtained with a modified Sawyer–Tower (ST) circuit.10,11 A high-voltage (HV) capacitor C1 (3 nF) and a large standard capacitor Cm (1 μF) were connected in series with the sample. A bipolar sinusoidal voltage with a frequency of 10 mHz was applied from an HV power supply (FUG HCB 7-6500) controlled by an arbitrary-waveform generator (HP 33120a). The voltage Vout on Cm is measured by means of an electrometer (HP 3458a), and the charge flowing through the circuit is determined as Q(t)=CmVout(t) . The experiments were carried out at isothermal conditions in a Novocontrol® Quatro cryosystem. With the modified ST circuit, Q–V loops have been measured on a tubular-channel FEP ferroelectret system at different temperatures. The sample capacitance of about 34.5 pF is determined by a linear fit of the initial part of the Q–V curve recorded at 20 °C , where the voltage has been raised up from zero on a fresh sample. The hysteresis loops are obtained from the Q–V curves by subtracting the contribution that results from charging of the sample capacitance.10 Figure 1 shows the hysteresis loops of the sample at −100, 0, and +100 ° C, respectively. According to previous theoretical and experimental studies,24,25 the length of each of the horizontal sides of the parallelogram-like hysteresis loops is given by 2Vth where Vth is the threshold voltage. As the charging temperature decreases, the hysteresis loop becomes wider and less high, i.e., the threshold voltage increases, while the polarization at maximum voltage decreases. Y1 - 2016 U6 - https://doi.org/10.1063/1.4954263 SN - 0003-6951 SN - 1077-3118 VL - 108 SP - 1687 EP - 1697 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Quade, Markus A1 - Abel, Markus A1 - Shafi, Kamran A1 - Niven, Robert K. A1 - Noack, Bernd R. T1 - Prediction of dynamical systems by symbolic regression JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We study the modeling and prediction of dynamical systems based on conventional models derived from measurements. Such algorithms are highly desirable in situations where the underlying dynamics are hard to model from physical principles or simplified models need to be found. We focus on symbolic regression methods as a part of machine learning. These algorithms are capable of learning an analytically tractable model from data, a highly valuable property. Symbolic regression methods can be considered as generalized regression methods. We investigate two particular algorithms, the so-called fast function extraction which is a generalized linear regression algorithm, and genetic programming which is a very general method. Both are able to combine functions in a certain way such that a good model for the prediction of the temporal evolution of a dynamical system can be identified. We illustrate the algorithms by finding a prediction for the evolution of a harmonic oscillator based on measurements, by detecting an arriving front in an excitable system, and as a real-world application, the prediction of solar power production based on energy production observations at a given site together with the weather forecast. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevE.94.012214 SN - 2470-0045 SN - 2470-0053 VL - 94 PB - American Society for Pharmacology and Experimental Therapeutics CY - Bethesda ER - TY - JOUR A1 - Rauch, Thomas A1 - Quinet, P. A1 - Hoyer, D. A1 - Werner, K. A1 - Richter, Philipp A1 - Kruk, J. W. A1 - Demleitner, M. T1 - VII. New Kr IV - VII oscillator strengths and an improved spectral analysis of the hot, hydrogen-deficient DO-type white dwarf RE 0503-289 JF - Plant physiology : an international journal devoted to physiology, biochemistry, cellular and molecular biology, biophysics and environmental biology of plants N2 - Context. For the spectral analysis of high-resolution and high signal-to-noise (S/N) spectra of hot stars, state-of-the-art non-local thermodynamic equilibrium (NLTE) model atmospheres are mandatory. These are strongly dependent on the reliability of the atomic data that is used for their calculation. Aims. New Kr IV-VII oscillator strengths for a large number of lines enable us to construct more detailed model atoms for our NLTE model-atmosphere calculations. This enables us to search for additional Kr lines in observed spectra and to improve Kr abundance determinations. Methods. We calculated Kr IV-VII oscillator strengths to consider radiative and collisional bound-bound transitions in detail in our NLTE stellar-atmosphere models for the analysis of Kr lines that are exhibited in high-resolution and high S/N ultraviolet (UV) observations of the hot white dwarf RE 0503-289. Results. We reanalyzed the effective temperature and surface gravity and determined T-eff = 70 000 +/- 2000 K and log (g/cm s(-2)) = 7.5 +/- 0.1. We newly identified ten Kr V lines and one Kr vi line in the spectrum of RE 0503-289. We measured a Kr abundance of 3.3 +/- 0.3 (logarithmic mass fraction). We discovered that the interstellar absorption toward RE 0503-289 has a multi-velocity structure within a radial-velocity interval of -40 km s(-1) < upsilon(rad) < +18 km s(-1). Conclusions. Reliable measurements and calculations of atomic data are a prerequisite for state-of-the-art NLTE stellar-atmosphere modeling. Observed Kr V-VII line profiles in the UV spectrum of the white dwarf RE 0503-289 were simultaneously well reproduced with our newly calculated oscillator strengths. KW - atomic data KW - line: identification KW - stars: abundances KW - stars: individual: RE 0503-289 KW - virtual observatory tools KW - stars: individual: RE 0457-281 Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201628131 SN - 1432-0746 VL - 590 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Reindl, Nicole A1 - Rauch, Thomas A1 - Miller Bertolami, Marcelo Miguel A1 - Todt, Helge Tobias A1 - Werner, K. T1 - Breaking news from the HST BT - the central star of the Stingray Nebula is now returning towards the AGB JF - Monthly notices of the Royal Astronomical Society N2 - SAO 244567 is a rare example of a star that allows us to witness stellar evolution in real time. Between 1971 and 1990, it changed from a B-type star into the hot central star of the Stingray Nebula. This observed rapid heating has been a mystery for decades, since it is in strong contradiction with the low mass of the star and canonical post-asymptotic giant branch (AGB) evolution. We speculated that SAO 244567 might have suffered from a late thermal pulse (LTP) and obtained new observations with Hubble Space Telescope (HST)/COS to follow the evolution of the surface properties of SAO 244567 and to verify the LTP hypothesis. Our non-LTE spectral analysis reveals that the star cooled significantly since 2002 and that its envelope is now expanding. Therefore, we conclude that SAO 244567 is currently on its way back towards the AGB, which strongly supports the LTP hypothesis. A comparison with state-of-the-art LTP evolutionary calculations shows that these models cannot fully reproduce the evolution of all surface parameters simultaneously, pointing out possible shortcomings of stellar evolution models. Thereby, SAO 244567 keeps on challenging stellar evolution theory and we highly encourage further investigations. KW - stars: AGB and post-AGB KW - stars: atmospheres KW - stars: evolution Y1 - 2016 U6 - https://doi.org/10.1093/mnrasl/slw175 SN - 0035-8711 SN - 1365-2966 VL - 464 SP - L51 EP - L55 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Reinhardt, Matthias A1 - Koc, Azize A1 - Leitenberger, Wolfram A1 - Gaal, Peter A1 - Bargheer, Matias T1 - Optimized spatial overlap in optical pump-X-ray probe experiments with high repetition rate using laser-induced surface distortions JF - Journal of synchrotron radiation N2 - Ultrafast X-ray diffraction experiments require careful adjustment of the spatial overlap between the optical excitation and the X-ray probe pulse. This is especially challenging at high laser repetition rates. Sample distortions caused by the large heat load on the sample and the relatively low optical energy per pulse lead to only tiny signal changes. In consequence, this results in small footprints of the optical excitation on the sample, which turns the adjustment of the overlap difficult. Here a method for reliable overlap adjustment based on reciprocal space mapping of a laser excited thin film is presented. KW - ultrafast X-ray diffraction KW - nanostructures KW - surface deformation KW - heat diffusion KW - optical pump Y1 - 2016 U6 - https://doi.org/10.1107/S1600577515024443 SN - 1600-5775 VL - 23 SP - 474 EP - 479 PB - International Union of Crystallography CY - Chester ER - TY - JOUR A1 - Rettig, L. A1 - Dornes, C. A1 - Thielemann-Kuehn, Nele A1 - Pontius, N. A1 - Zabel, Hartmut A1 - Schlagel, D. L. A1 - Lograsso, T. A. A1 - Chollet, M. A1 - Robert, A. A1 - Sikorski, M. A1 - Song, S. A1 - Glownia, J. M. A1 - Schuessler-Langeheine, Christian A1 - Johnson, S. L. A1 - Staub, U. T1 - Itinerant and Localized Magnetization Dynamics in Antiferromagnetic Ho JF - Physical review letters N2 - Using femtosecond time-resolved resonant magnetic x-ray diffraction at the Ho L-3 absorption edge, we investigate the demagnetization dynamics in antiferromagnetically ordered metallic Ho after femtosecond optical excitation. Tuning the x-ray energy to the electric dipole (E1, 2p -> 5d) or quadrupole (E2, 2p -> 4f) transition allows us to selectively and independently study the spin dynamics of the itinerant 5d and localized 4f electronic subsystems via the suppression of the magnetic (2 1 3-tau) satellite peak. We find demagnetization time scales very similar to ferromagnetic 4f systems, suggesting that the loss of magnetic order occurs via a similar spin-flip process in both cases. The simultaneous demagnetization of both subsystems demonstrates strong intra-atomic 4f-5d exchange coupling. In addition, an ultrafast lattice contraction due to the release of magneto-striction leads to a transient shift of the magnetic satellite peak. Y1 - 2016 U6 - https://doi.org/10.1103/PhysRevLett.116.257202 SN - 0031-9007 SN - 1079-7114 VL - 116 SP - 6382 EP - 6389 PB - American Physical Society CY - College Park ER - TY - THES A1 - Rettig, Robert T1 - Über die Anisotropie der Kosmischen Strahlung Y1 - 2016 ER - TY - THES A1 - Rezanezhad, Vahid T1 - Inversion of the 2004 M6.0 Parkfield Earthquake Coseismic Offsets by Partition Model Y1 - 2016 ER - TY - JOUR A1 - Richardson, Noel D. A1 - Shenar, Tomer A1 - Roy-Loubier, Olivier A1 - Schaefer, Gail A1 - Moffat, Anthony F. J. A1 - St-Louis, Nicole A1 - Gies, Douglas R. A1 - Farrington, Chris A1 - Hill, Grant M. A1 - Williams, Peredur M. A1 - Gordon, Kathryn A1 - Pablo, Herbert A1 - Ramiaramanantsoa, Tahina T1 - The CHARA Array resolves the long-period Wolf-Rayet binaries WR 137 and WR 138 JF - Monthly notices of the Royal Astronomical Society N2 - We report on interferometric observations with the CHARAArray of two classical Wolf-Rayet (WR) stars in suspected binary systems, namely WR 137 and WR 138. In both cases, we resolve the component stars to be separated by a few milliarcseconds. The data were collected in the H band, and provide a measure of the fractional flux for both stars in each system. We find that the WR star is the dominant H-band light source in both systems (fWR, 137 = 0.59 +/- 0.04; fWR, 138 = 0.67 +/- 0.01), which is confirmed through both comparisons with estimated fundamental parameters for WR stars and O dwarfs, as well as through spectral modelling of each system. Our spectral modelling also provides fundamental parameters for the stars and winds in these systems. The results on WR 138 provide evidence that it is a binary system which may have gone through a previous mass-transfer episode to create the WR star. The separation and position of the stars in the WR 137 system together with previous results from the IOTA interferometer provides evidence that the binary is seen nearly edgeon. The possible edge-on orbit of WR 137 aligns well with the dust production site imaged by the Hubble Space Telescope during a previous periastron passage, showing that the dust production may be concentrated in the orbital plane. KW - binaries: visual KW - stars: individual: WR 137 KW - stars: individual: WR 138 KW - stars: mass-loss KW - stars: winds, outflows KW - stars: Wolf-Rayet Y1 - 2016 U6 - https://doi.org/10.1093/mnras/stw1585 SN - 0035-8711 SN - 1365-2966 VL - 461 SP - 4115 EP - 4124 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Richter, Philipp A1 - Wakker, Bart P. A1 - Fechner, Cora A1 - Herenz, Peter A1 - Tepper-Garcia, T. A1 - Fox, Andrew J. T1 - An HST/COS legacy survey of intervening Si III absorption in the extended gaseous halos of low-redshift galaxies JF - Climate : open access journal N2 - Aims. Doubly ionized silicon (Si III) is a powerful tracer of diffuse ionized gas inside and outside of galaxies. It can be observed in the local Universe in ultraviolet (UV) absorption against bright extragalactic background sources. We here present an extensive study of intervening Si III-selected absorbers and study the properties of the warm circumgalactic medium (CGM) around low-redshift (z <= 0.1) galaxies. Methods. We analyzed the UV absorption spectra of 303 extragalactic background sources, as obtained with the Cosmic Origins Spectrograph (COS) on-board the Hubble Space Telescope (HST). We developed a geometrical model for the absorption-cross section of the CGM around the local galaxy population and compared the observed Si III absorption statistics with predictions provided by the model. We also compared redshifts and positions of the absorbers with those of similar to 64 000 galaxies using archival galaxy-survey data to investigate the relation between intervening Si III absorbers and the CGM. Results. Along a total redshift path of Delta z approximate to 24, we identify 69 intervening Si III systems that all show associated absorption from other low and high ions (e.g., H I, Si II, Si IV, C II, C IV). We derive a bias-corrected number density of dN/dz(Si III) = 2.5 +/- 0.4 for absorbers with column densities log N(Si III) > 12.2, which is similar to 3 times the number density of strong Mg II systems at z = 0. This number density matches the expected cross section of a Si III absorbing CGM around the local galaxy population with a mean covering fraction of < f(c)> = 0.69. For the majority (similar to 60 percent) of the absorbers, we identify possible host galaxies within 300 km s(-1) of the absorbers and derive impact parameters rho < 200 kpc, demonstrating that the spatial distributions of Si III absorbers and galaxies are highly correlated. Conclusions. Our study indicates that the majority of Si III-selected absorbers in our sample trace the CGM of nearby galaxies within their virial radii at a typical covering fraction of similar to 70 percent. We estimate that diffuse gas in the CGM around galaxies, as traced by Si III, contains substantially more (more than twice as much) baryonic mass than their neutral interstellar medium. KW - galaxies: halos KW - galaxies: formation KW - intergalactic medium KW - quasars: absorption lines Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201527038 SN - 1432-0746 VL - 590 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Ripepi, Vincenzo A1 - Marconi, M. A1 - Moretti, M. I. A1 - Clementini, Gisella A1 - Cioni, Maria-Rosa L. A1 - de Grijs, Richard A1 - Emerson, J. P. A1 - Groenewegen, M. A. T. A1 - Ivanov, V. D. A1 - Piatti, A. E. T1 - THE VMC SURVEY. XIX. CLASSICAL CEPHEIDS IN THE SMALL MAGELLANIC CLOUD JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series N2 - The "VISTA near-infrared YJK(s) survey of the Magellanic Clouds System" (VMC) is collecting deep K-s-band time-series photometry of pulsating variable stars hosted by the two Magellanic Clouds and their connecting Bridge. In this paper, we present Y, J, K-s light curves for a sample of 4172 Small Magellanic Cloud (SMC) Classical Cepheids (CCs). These data, complemented with literature V values, allowed us to construct a variety of period-luminosity (PL), period-luminosity-color (PLC), and period-Wesenheit (PW) relationships, which are valid for Fundamental (F), First Overtone (FO), and Second Overtone (SO) pulsators. The relations involving the V, J, K-s bands are in agreement with their counterparts in the literature. As for the Y band, to our knowledge, we present the first CC PL, PW, and PLC relations ever derived using this filter. We also present the first near-infrared PL, PW, and PLC relations for SO pulsators to date. We used PW(V, K-s) to estimate the relative SMC-LMC distance and, in turn, the absolute distance to the SMC. For the former quantity, we find a value of Delta mu = 0.55. +/- 0.04 mag, which is in rather good agreement with other evaluations based on CCs, but significantly larger than the results obtained from older population II distance indicators. This discrepancy might be due to the different geometric distributions of young and old tracers in both Clouds. As for the absolute distance to the SMC, our best estimates are mu(SMC) = 19.01 +/- 0.05 mag and mu(SMC) = 19.04 +/- 0.06 mag, based on two distance measurements to the LMC which rely on accurate CC and eclipsing Cepheid binary data, respectively. KW - distance scale KW - Magellanic Clouds KW - stars: oscillations KW - stars: variables: Cepheids Y1 - 2016 U6 - https://doi.org/10.3847/0067-0049/224/2/21 SN - 0067-0049 SN - 1538-4365 VL - 224 SP - 199 EP - 229 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Ripoll, Jean-François A1 - Loridan, Vivien A1 - Cunningham, G. S. A1 - Reeves, Geoffrey D. A1 - Shprits, Yuri Y. T1 - On the time needed to reach an equilibrium structure of the radiation belts JF - Journal of geophysical research : Space physics N2 - In this study, we complement the notion of equilibrium states of the radiation belts with a discussion on the dynamics and time needed to reach equilibrium. We solve for the equilibrium states obtained using 1-D radial diffusion with recently developed hiss and chorus lifetimes at constant values of Kp = 1, 3, and 6. We find that the equilibrium states at moderately low Kp, when plotted versus L shell (L) and energy (E), display the same interesting S shape for the inner edge of the outer belt as recently observed by the Van Allen Probes. The S shape is also produced as the radiation belts dynamically evolve toward the equilibrium state when initialized to simulate the buildup after a massive dropout or to simulate loss due to outward diffusion from a saturated state. Physically, this shape, intimately linked with the slot structure, is due to the dependence of electron loss rate (originating from wave-particle interactions) on both energy and L shell. Equilibrium electron flux profiles are governed by the Biot number (tau(Diffusion)/tau(loss)), with large Biot number corresponding to low fluxes and low Biot number to large fluxes. The time it takes for the flux at a specific (L, E) to reach the value associated with the equilibrium state, starting from these different initial states, is governed by the initial state of the belts, the property of the dynamics (diffusion coefficients), and the size of the domain of computation. Its structure shows a rather complex scissor form in the (L, E) plane. The equilibrium value (phase space density or flux) is practically reachable only for selected regions in (L, E) and geomagnetic activity. Convergence to equilibrium requires hundreds of days in the inner belt for E>300 keV and moderate Kp (<= 3). It takes less time to reach equilibrium during disturbed geomagnetic conditions (Kp = 3), when the system evolves faster. Restricting our interest to the slot region, below L = 4, we find that only small regions in (L, E) space can reach the equilibrium value: E similar to [200, 300] keV for L= [3.7, 4] at Kp= 1, E similar to[0.6, 1] MeV for L = [3, 4] at Kp = 3, and E similar to 300 keV for L = [3.5, 4] at Kp = 6 assuming no new incoming electrons. Y1 - 2016 U6 - https://doi.org/10.1002/2015JA022207 SN - 2169-9380 SN - 2169-9402 VL - 121 SP - 7684 EP - 7698 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Romita, Krista A1 - Lada, Elizabeth A1 - Cioni, Maria-Rosa L. T1 - EMBEDDED CLUSTERS IN THE LARGE MAGELLANIC CLOUD USING THE VISTA MAGELLANIC CLOUDS SURVEY JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We present initial results of the first large-scale survey of embedded star clusters in molecular clouds in the Large Magellanic Cloud (LMC) using near-infrared imaging from the Visible and Infrared Survey Telescope for Astronomy Magellanic Clouds Survey. We explored a ~1.65 deg2 area of the LMC, which contains the well-known star-forming region 30 Doradus as well as ~14% of the galaxy's CO clouds, and identified 67 embedded cluster candidates, 45 of which are newly discovered as clusters. We have determined the sizes, luminosities, and masses for these embedded clusters, examined the star formation rates (SFRs) of their corresponding molecular clouds, and made a comparison between the LMC and the Milky Way. Our preliminary results indicate that embedded clusters in the LMC are generally larger, more luminous, and more massive than those in the local Milky Way. We also find that the surface densities of both embedded clusters and molecular clouds is ~3 times higher than in our local environment, the embedded cluster mass surface density is ~40 times higher, the SFR is ~20 times higher, and the star formation efficiency is ~10 times higher. Despite these differences, the SFRs of the LMC molecular clouds are consistent with the SFR scaling law presented in Lada et al. This consistency indicates that while the conditions of embedded cluster formation may vary between environments, the overall process within molecular clouds may be universal. KW - galaxies: star clusters: general KW - Magellanic Clouds KW - stars: formation Y1 - 2016 U6 - https://doi.org/10.3847/0004-637X/821/1/51 SN - 0004-637X SN - 1538-4357 VL - 821 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Roshchupkin, Dmitry A1 - Ortega, Luc A1 - Plotitcyna, Olga A1 - Erko, Alexei A1 - Zizak, Ivo A1 - Vadilonga, Simone A1 - Irzhak, Dmitry A1 - Emelin, Evgenii A1 - Buzanov, Oleg A1 - Leitenberger, Wolfram T1 - Piezoelectric Ca3NbGa3Si2O14 crystal: crystal growth, piezoelectric and acoustic properties JF - Journal of geophysical research : Space physics N2 - Ca3NbGa3Si2O14 (CNGS), a five-component crystal of lanthanum-gallium silicate group, was grown by the Czochralski method. The parameters of the elementary unit cell of the crystal were measured by powder diffraction. The independent piezoelectric strain coefficients d(11) and d(14) were determined by the triple-axis X-ray diffraction in the Bragg and Laue geometries. Excitation and propagation of surface acoustic waves (SAW) were studied by high-resolution X-ray diffraction at BESSY II synchrotron radiation source. The velocity of SAW propagation and power flow angles in the Y-, X-and yxl/+36 degrees-cuts of the CNGS crystal were determined from the analysis of the diffraction spectra. The CNGS crystal was found practically isotropic by its acoustic properties. Y1 - 2016 U6 - https://doi.org/10.1007/s00339-016-0279-1 SN - 0947-8396 SN - 1432-0630 VL - 122 SP - 2803 EP - 2812 PB - Springer CY - New York ER - TY - THES A1 - Ruppert, Jan T1 - The Low-Mass Young Stellar Content in the Extended Environment of the Galactic Starburst Region NGC3603 Y1 - 2016 ER - TY - JOUR A1 - Ryabchun, Alexander A1 - Kollosche, Matthias A1 - Wegener, Michael A1 - Sakhno, Oksana T1 - Holographic Structuring of Elastomer Actuator: First True Monolithic Tunable Elastomer Optics JF - Advanced materials N2 - Volume diffraction gratings (VDGs) are inscribed selectively by diffusive introduction of benzophenone and subsequent UV-holographic structuring into an electroactive dielectric elastomer actuator (DEA), to afford a continuous voltage-controlled grating shift of 17%. The internal stress coupling of DEA and optical domain allows for a new generation of true monolithic tunable elastomer optics with voltage controlled properties. Y1 - 2016 U6 - https://doi.org/10.1002/adma.201602881 SN - 0935-9648 SN - 1521-4095 VL - 28 SP - 10217 EP - 10223 PB - Wiley-VCH CY - Weinheim ER - TY - GEN A1 - Rätzel, Dennis A1 - Wilkens, Martin A1 - Menzel, Ralf T1 - Gravitational properties of light BT - the gravitational field of a laser pulse N2 - The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 222 KW - electromagnetic radiation KW - general relativity KW - gravity KW - laser pulses KW - linearized gravity KW - pp-wave solutions Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-90553 ER - TY - JOUR A1 - Rätzel, Dennis A1 - Wilkens, Martin A1 - Menzel, Ralf T1 - Gravitational properties of light BT - the gravitational field of a laser pulse JF - New journal of physics : the open-access journal for physics N2 - The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources. KW - gravity KW - general relativity KW - laser pulses KW - electromagnetic radiation KW - linearized gravity KW - pp-wave solutions Y1 - 2016 U6 - https://doi.org/10.1088/1367-2630/18/2/023009 SN - 1367-2630 VL - 18 SP - 1 EP - 16 PB - IOP Science CY - London ER - TY - JOUR A1 - Rätzel, Dennis A1 - Wilkens, Martin A1 - Menzel, Ralf T1 - Gravitational properties of light-the gravitational field of a laser pulse JF - NEW JOURNAL OF PHYSICS N2 - The gravitational field of a laser pulse of finite lifetime, is investigated in the framework of linearized gravity. Although the effects are very small, they may be of fundamental physical interest. It is shown that the gravitational field of a linearly polarized light pulse is modulated as the norm of the corresponding electric field strength, while no modulations arise for circular polarization. In general, the gravitational field is independent of the polarization direction. It is shown that all physical effects are confined to spherical shells expanding with the speed of light, and that these shells are imprints of the spacetime events representing emission and absorption of the pulse. Nearby test particles at rest are attracted towards the pulse trajectory by the gravitational field due to the emission of the pulse, and they are repelled from the pulse trajectory by the gravitational field due to its absorption. Examples are given for the size of the attractive effect. It is recovered that massless test particles do not experience any physical effect if they are co-propagating with the pulse, and that the acceleration of massless test particles counter-propagating with respect to the pulse is four times stronger than for massive particles at rest. The similarities between the gravitational effect of a laser pulse and Newtonian gravity in two dimensions are pointed out. The spacetime curvature close to the pulse is compared to that induced by gravitational waves from astronomical sources. KW - gravity KW - general relativity KW - laser pulses KW - electromagnetic radiation KW - linearized gravity KW - pp-wave solutions Y1 - 2016 U6 - https://doi.org/10.1088/1367-2630/18/2/023009 SN - 1367-2630 VL - 18 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Rätzel, Dennis A1 - Wilkens, Martin A1 - Menzel, Ralf T1 - The effect of entanglement in gravitational photon-photon scattering JF - epl : a letters journal exploring the frontiers of physics N2 - The differential cross-section for gravitational photon-photon scattering calculated in perturbative quantum gravity is shown to depend on the degree of polarization entanglement of the two photons. The interaction between photons in the symmetric Bell state is stronger than between not entangled photons. In contrast, the interaction between photons in the anti-symmetric Bell state is weaker than between not entangled photons. The results are interpreted in terms of quantum interference, and it is shown how they fit into the idea of distance-dependent forces. Copyright (C) EPLA, 2016 Y1 - 2016 U6 - https://doi.org/10.1209/0295-5075/115/51002 SN - 0295-5075 SN - 1286-4854 VL - 115 SP - S12 EP - S13 PB - EDP Sciences CY - Mulhouse ER - TY - JOUR A1 - Sander, Mathias A1 - Koc, A. A1 - Kwamen, C. T. A1 - Michaels, H. A1 - von Reppert, Alexander A1 - Pudell, Jan-Etienne A1 - Zamponi, Flavio A1 - Bargheer, Matias A1 - Sellmann, J. A1 - Schwarzkopf, J. A1 - Gaal, P. T1 - Characterization of an ultrafast Bragg-Switch for shortening hard x-ray pulses JF - Journal of applied physics N2 - We present a nanostructured device that functions as photoacoustic hard x-ray switch. The device is triggered by femtosecond laser pulses and allows for temporal gating of hard x-rays on picosecond (ps) timescales. It may be used for pulse picking or even pulse shortening in 3rd generation synchrotron sources. Previous approaches mainly suffered from insufficient switching contrasts due to excitation-induced thermal distortions. We present a new approach where thermal distortions are spatially separated from the functional switching layers in the structure. Our measurements yield a switching contrast of 14, which is sufficient for efficient hard x-ray pulse shortening. The optimized structure also allows for utilizing the switch at high repetition rates of up to 208 kHz. Published by AIP Publishing. Y1 - 2016 U6 - https://doi.org/10.1063/1.4967835 SN - 0021-8979 SN - 1089-7550 VL - 120 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Sandev, Trifce A1 - Iomin, Alexander A1 - Kantz, Holger A1 - Metzler, Ralf A1 - Chechkin, Aleksei V. T1 - Comb Model with Slow and Ultraslow Diffusion JF - Mathematical modelling of natural phenomena N2 - We consider a generalized diffusion equation in two dimensions for modeling diffusion on a comb-like structures. We analyze the probability distribution functions and we derive the mean squared displacement in x and y directions. Different forms of the memory kernels (Dirac delta, power-law, and distributed order) are considered. It is shown that anomalous diffusion may occur along both x and y directions. Ultraslow diffusion and some more general diffusive processes are observed as well. We give the corresponding continuous time random walk model for the considered two dimensional diffusion-like equation on a comb, and we derive the probability distribution functions which subordinate the process governed by this equation to the Wiener process. KW - comb-like model KW - anomalous diffusion KW - mean squared displacement KW - probability density function Y1 - 2016 U6 - https://doi.org/10.1051/mmnp/201611302 SN - 0973-5348 SN - 1760-6101 VL - 11 SP - 18 EP - 33 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Sandin, C. A1 - Steffen, M. A1 - Schoenberner, D. A1 - Rühling, Ute T1 - Hot bubbles of planetary nebulae with hydrogen-deficient winds I. Heat conduction in a chemically stratified plasma JF - Frontiers in psychology N2 - Heat conduction has been found a plausible solution to explain discrepancies between expected and measured temperatures in hot bubbles of planetary nebulae (PNe). While the heat conduction process depends on the chemical composition, to date it has been exclusively studied for pure hydrogen plasmas in PNe. A smaller population of PNe show hydrogen-deficient and helium-and carbon-enriched surfaces surrounded by bubbles of the same composition; considerable differences are expected in physical properties of these objects in comparison to the pure hydrogen case. The aim of this study is to explore how a chemistry-dependent formulation of the heat conduction affects physical properties and how it affects the X-ray emission from PN bubbles of hydrogen-deficient stars. We extend the description of heat conduction in our radiation hydrodynamics code to work with any chemical composition. We then compare the bubble-formation process with a representative PN model using both the new and the old descriptions. We also compare differences in the resulting X-ray temperature and luminosity observables of the two descriptions. The improved equations show that the heat conduction in our representative model of a hydrogen-deficient PN is nearly as efficient with the chemistry-dependent description; a lower value on the diffusion coefficient is compensated by a slightly steeper temperature gradient. The bubble becomes somewhat hotter with the improved equations, but differences are otherwise minute. The observable properties of the bubble in terms of the X-ray temperature and luminosity are seemingly unaffected. KW - conduction KW - hydrodynamics KW - planetary nebulae: general KW - stars: AGB and post-AGB KW - stars: Wolf-Rayet KW - X-rays: stars Y1 - 2016 U6 - https://doi.org/10.1051/0004-6361/201527357 SN - 1432-0746 VL - 586 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Sandmann, Michael A1 - Garz, Andreas A1 - Menzel, Ralf T1 - Physiological response of two different Chlamydomonas reinhardtii strains to light-dark rhythms JF - Botany N2 - Cells of a cell-wall deficient line (cw15-type) of Chlamydomonas reinhardtii and of the corresponding wild type were grown during repetitive light-dark cycles. In a direct comparison, both lines showed approximately the same relative biomass increase during light phase but the cw-line produced significantly more, and smaller, daughter cells. Throughout the light period the average cellular starch content, the cellular chlorophyll content, the cellular rate of dark respiration, and the cellular rate of photosynthesis of the cw-line was lower. Despite this, several non-cell volume related parameters like the development of starch content per cell volume were clearly different over time between the strains. Additionally, the chlorophyll-based photosynthesis rates were 2-fold higher in the mutant than in the wild-type cells, and the ratio of chlorophyll a to chlorophyll b as well as the light-saturation index were also consistently higher in the mutant cells. Differences in the starch content were also confirmed by single cell analyses using a sensitive SHG-based microscopy approach. In summary, the cw15-type mutant deviates from its genetic background in the entire cell physiology. Both lines should be used in further studies in comparative systems biology with focus on the detailed relation between cell volume increase, photosynthesis, starch metabolism, and daughter cell productivity. KW - cell wall deficient mutant KW - diurnal rhythm KW - nonlinear microscopy KW - photosynthesis KW - single-cell analysis Y1 - 2016 U6 - https://doi.org/10.1139/cjb-2015-0144 SN - 1916-2790 SN - 1916-2804 VL - 94 SP - 53 EP - 64 PB - NRC Research Press CY - Ottawa ER - TY - JOUR A1 - Santos de Lima, Reinaldo A1 - Yan, Huirong A1 - de Gouveia Dal Pino, E. M. A1 - Lazarian, A. T1 - Limits on the ion temperature anisotropy in the turbulent intracluster medium JF - Monthly notices of the Royal Astronomical Society N2 - Turbulence in the weakly collisional intracluster medium (ICM) of galaxies is able to generate strong thermal velocity anisotropies in the ions (with respect to the local magnetic field direction), if the magnetic moment of the particles is conserved in the absence of Coulomb collisions. In this scenario, the anisotropic pressure magnetohydrodynamic (AMHD) turbulence shows a very different statistical behaviour from the standard MHD one and is unable to amplify seed magnetic fields. This is in contrast to previous cosmological MHD simulations that are successful in explaining the observed magnetic fields in the ICM. On the other hand, temperature anisotropies can also drive plasma instabilities that can relax the anisotropy. This work aims to compare the relaxation rate with the growth rate of the anisotropies driven by the turbulence. We employ quasi-linear theory to estimate the ion scattering rate resulting from the parallel firehose, mirror and ion-cyclotron instabilities, for a set of plasma parameters resulting from AMHD simulations of the turbulent ICM. We show that the ICM turbulence can sustain only anisotropy levels very close to the instability thresholds. We argue that the AMHD model that bounds the anisotropies at the marginal stability levels can describe the Alfv,nic turbulence cascade in the ICM. KW - MHD KW - plasmas KW - turbulence KW - galaxies: clusters: intracluster medium Y1 - 2016 U6 - https://doi.org/10.1093/mnras/stw1079 SN - 0035-8711 SN - 1365-2966 VL - 460 SP - 2492 EP - 2504 PB - Oxford Univ. Press CY - Oxford ER - TY - GEN A1 - Schick, Daniel A1 - Eckert, Sebastian A1 - Pontius, Niko A1 - Mitzner, Rolf A1 - Föhlisch, Alexander A1 - Holldack, Karsten A1 - Sorgenfrei, Nomi T1 - Versatile soft X-ray-optical cross-correlator for ultrafast applications T2 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - We present an X-ray-optical cross-correlator for the soft (> 150 eV) up to the hard X-ray regime based on a molybdenum-silicon superlattice. The cross-correlation is done by probing intensity and position changes of superlattice Bragg peaks caused by photoexcitation of coherent phonons. This approach is applicable for a wide range of X-ray photon energies as well as for a broad range of excitation wavelengths and requires no external fields or changes of temperature. Moreover, the cross-correlator can be employed on a 10 ps or 100 fs time scale featuring up to 50% total X-ray reflectivity and transient signal changes of more than 20%. (C) 2016 Author(s). T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 1331 Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-436962 SN - 1866-8372 IS - 1331 SP - 054304-1 EP - 054304-8 ER - TY - JOUR A1 - Schick, Daniel A1 - Eckert, Sebastian A1 - Pontius, Niko A1 - Mitzner, Rolf A1 - Föhlisch, Alexander A1 - Holldack, Karsten A1 - Sorgenfrei, Nomi T1 - Versatile soft X-ray-optical cross-correlator for ultrafast applications JF - Structural dynamics N2 - We present an X-ray-optical cross-correlator for the soft (> 150 eV) up to the hard X-ray regime based on a molybdenum-silicon superlattice. The cross-correlation is done by probing intensity and position changes of superlattice Bragg peaks caused by photoexcitation of coherent phonons. This approach is applicable for a wide range of X-ray photon energies as well as for a broad range of excitation wavelengths and requires no external fields or changes of temperature. Moreover, the cross-correlator can be employed on a 10 ps or 100 fs time scale featuring up to 50% total X-ray reflectivity and transient signal changes of more than 20%. (C) 2016 Author(s). Y1 - 2016 U6 - https://doi.org/10.1063/1.4964296 SN - 2329-7778 VL - 3 SP - 054304-1 EP - 054304-8 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Schick, Daniel A1 - Le Guyader, Loic A1 - Pontius, Niko A1 - Radu, Ilie A1 - Kachel, Torsten A1 - Mitzner, Rolf A1 - Zeschke, Thomas A1 - Schuessler-Langeheine, Christian A1 - Föhlisch, Alexander A1 - Holldack, Karsten T1 - Analysis of the halo background in femtosecond slicing experiments JF - Journal of synchrotron radiation N2 - The slicing facility FemtoSpeX at BESSY II offers unique opportunities to study photo-induced dynamics on femtosecond time scales by means of X-ray magnetic circular dichroism, resonant and non-resonant X-ray diffraction, and X-ray absorption spectroscopy experiments in the soft X-ray regime. Besides femtosecond X-ray pulses, slicing sources inherently also produce a so-called `halo' background with a different time structure, polarization and pointing. Here a detailed experimental characterization of the halo radiation is presented, and a method is demonstrated for its correct and unambiguous removal from femtosecond time-resolved data using a special laser triggering scheme as well as analytical models. Examples are given for time-resolved measurements with corresponding halo correction, and errors of the relevant physical quantities caused by either neglecting or by applying a simplified model to describe this background are estimated. KW - femtosecond slicing KW - halo KW - pump-probe KW - XMCD KW - X-ray scattering Y1 - 2016 U6 - https://doi.org/10.1107/S160057751600401X SN - 1600-5775 VL - 23 SP - 700 EP - 711 PB - International Union of Crystallography CY - Chester ER -