TY - JOUR A1 - Wallny, Thomas A. A1 - Brackmann, H. H. A1 - Gunia, Günter A1 - Wilbertz, P. A1 - Oldenburg, J. A1 - Kraft, Clayton. N. T1 - Successful pain treatment in arthropathic lower extremities by acupuncture in haemophilia patients JF - Haemophilia : the official journal of the World Federation of Haemophilia N2 - Acupuncture is successfully used in the treatment of degenerative osteoarthritis. The treatment of haemophilic arthropathies can require strong painkillers with severe side-effects. Therefore, a special yet simple acupuncture technique was evaluated in the treatment of these joint problems. Twelve patients with a factor VIII activity < 1% and at least one painful arthropathy in both lower extremities were included in this single-blinded study. The non-treated side served as a control. Treatment was assessed by a visual analogue scale (VAS) and an orthopaedic clinical examination. Only one needle was inserted at the rear fontanelle once per week and in 15 cycles. Ten of 12 patients showed an improvement of their pain perception. The average VAS could be reduced from 6.8 to 5.0. The side not receiving treatment showed a reduction from 4.1 to 4.0. No side-effects were observed. Even though interpretation of our data are limited due to the small patient numbers, significant improvement of the VAS after treatment suggests that acupuncture has a measurable positive effect in pain management for haemophilic arthropathy of the lower extremities. KW - acupuncture KW - arthropathies KW - haemophilia KW - pain Y1 - 2006 U6 - https://doi.org/10.1111/j.1365-2516.2006.01308.x SN - 1351-8216 VL - 12 IS - 5 SP - 500 EP - 502 PB - Wiley-Blackwell CY - Oxford ER - TY - JOUR A1 - Szatmari, Istvan A1 - Toth, Diana A1 - Koch, Andreas A1 - Heydenreich, Matthias A1 - Kleinpeter, Erich A1 - Fulop, Ferenc T1 - Study of the substituent-influenced anomeric effect in the ring-chain tautomerism of 1-alkyl-3-aryl-naphth[1,2- e][1,3]oxazines N2 - The stabilities of the trans (B) and cis (C) tautomeric ring forms that are experimentally observed in the ring- chain tautomeric interconversion of 1-alkyl-3-aryl-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazines has been investigated. Stability differences are explained by the analysis of the natural bond orbital results for the lone pairs of electrons that are on the heteroatoms in the oxazine ring system and by regression analysis of the calculated 13C NMR chemical shift values. Y1 - 2006 UR - http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200600563/pdf U6 - https://doi.org/10.1002/ejoc.200600563 ER - TY - JOUR A1 - Emmerling, Franziska A1 - Orgzall, Ingo A1 - Reck, Günter A1 - Schulz, Burkhard W. A1 - Stockhause, Sabine A1 - Schulz, Burkhard T1 - Structures of substituted di-aryl-1, 3,4-oxadiazole derivatives: 2,5-bis(pyridyl)- and 2,5-bis(aminophenyl)-substitution JF - Journal of molecular structure N2 - Crystal structures of four different di-aryl-1,3,4-oxadiazole compounds (aryl = 2-pyridyl-, 3-pyridyl-, 2-aminophenyl-, 3-aminophenyl-) are determined. Crystallization of di(2-pyridyl)-1,3,4-oxadiazole yielded monoclinic and triclinic polymorphs. The structures are characterized by the occurrence of pi-pi interactions. Additionally, in case of the aminophenyl compounds intra- as well as intermolecular hydrogen bonds are found that influence the packing motif as well. Since these molecules are often used as ligands in metal-organic complexes similarities and differences of the molecular conformation between the molecules in the pure crystals and that of the ligands in the complexes are discussed. (c) 2006 Elsevier B.V. All rights reserved. KW - crystal structure KW - 1,3,4-oxadiazole KW - molecular conformation KW - hydrogen bonds Y1 - 2006 U6 - https://doi.org/10.1016/j.molstruc.2006.03.076 SN - 0022-2860 VL - 800 IS - 1-3 SP - 74 EP - 84 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Kleinpeter, Erich A1 - Holzberger, Anja T1 - Structure, intramolecular flexibility, and complexation of aza crown ethers to anions H2PO4- and HSO4- in nonprotic solvents JF - Tetrahedron N2 - Both the structure and intramolecular flexibility of a series of aza crown ethers were studied by experimental NMR and theoretical molecular modeling. The stoichiometries of complexation to the anions H2PO4- and resulting complex stabilities were determined by experimental NMR (1H, 31P) titration and, in addition, the structure and mobility changes of the aza crown ethers upon complexation were also examined. Y1 - 2006 UR - https://www.sciencedirect.com/science/article/abs/pii/S0040402006012130 U6 - https://doi.org/10.1016/j.tet.2006.07.074 SN - 0040-4020 VL - 62 IS - 43 SP - 10237 EP - 10247 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Klinka, Karel D. A1 - Balentova, Eva A1 - Bernát, Juraj A1 - Imrich, Ján A1 - Vavrusová, Martina A1 - Pihlaja, Kalevi A1 - Koch, Andreas A1 - Kleinpeter, Erich A1 - Kelling, Alexandra A1 - Schilde, Uwe T1 - Structural revision of products resulting from the reaction of methylhydrazine with acridin-9-yl isothiocyanate due to unexpected acridinyl migration And further reactions N2 - The reaction of methyl acridin-9-ylthiosemicarbazide under basic conditions with methyl bromoacetate resulted in a 1,3-thiazolin-4-one structure as provided by X-ray crystallography. The structure forced a re-evaluation of the reactant methyl acridin-9-ylthiosemicarbazide, originally thought to be 2-methyl 4-acridin-9-ylthiosemicarbazide based on synthetic expectations, but which when examined by X-ray crystallography was found to be in fact the isomeric 2- methyl 1-acridin-9-ylthiosemicarbazide resulting from rearrangement via a spiro form which it is in equilibrium with in solution. The product resulting from reaction with methyl iodide was also studied and the previously reported semicarbazide produced by reaction with MNO was re-examined. In both cases, the 1,2 isomer rather than the 2,4 isomer was found to be present based on the sign of the 3JCH3,N11 coupling. Full characterization of the compounds was rendered by 1H, 13C, and 15N solution-state NMR, and in the solid state, by both 13C and 15N NMR. Y1 - 2006 UR - http://arkat-usa.org/home.aspx?VIEW=BROWSE&MENU=ARKIVOC SN - 1551-7004 ER - TY - JOUR A1 - Steuer, Ralf A1 - Gross, Thilo A1 - Selbig, Joachim A1 - Blasius, Bernd T1 - Structural kinetic modeling of metabolic networks JF - Proceedings of the National Academy of Sciences of the United States of America N2 - To develop and investigate detailed mathematical models of metabolic processes is one of the primary challenges in systems biology. However, despite considerable advance in the topological analysis of metabolic networks, kinetic modeling is still often severely hampered by inadequate knowledge of the enzyme-kinetic rate laws and their associated parameter values. Here we propose a method that aims to give a quantitative account of the dynamical capabilities of a metabolic system, without requiring any explicit information about the functional form of the rate equations. Our approach is based on constructing a local linear model at each point in parameter space, such that each element of the model is either directly experimentally accessible or amenable to a straightforward biochemical interpretation. This ensemble of local linear models, encompassing all possible explicit kinetic models, then allows for a statistical exploration of the comprehensive parameter space. The method is exemplified on two paradigmatic metabolic systems: the glycolytic pathway of yeast and a realistic-scale representation of the photosynthetic Calvin cycle. KW - systems biology KW - computational biochemistry KW - metabolomics KW - metabolic regulation KW - biological robustness Y1 - 2006 U6 - https://doi.org/10.1073/pnas.0600013103 SN - 0027-8424 SN - 1091-6490 VL - 103 IS - 32 SP - 11868 EP - 11873 PB - National Academy of Sciences CY - Washington ER - TY - JOUR A1 - Wilke, Max A1 - Schmidt, Christian A1 - Farges, Francois A1 - Malavergne, Valerie A1 - Gautron, Laurent A1 - Simionovici, Alexandre A1 - Hahn, Matthias A1 - Petit, Pierre-Emanuel T1 - Structural environment of iron in hydrous aluminosilicate glass and melt-evidence from X-ray absorption spectroscopy N2 - The iron speciation in hydrous haplotonalitic and haplogranitic silicate glasses was studied using XAFS spectroscopy and transmission electron microscopy (TEM). Spectral features occurring at the main crest of the XANES at the iron K-edge of hydrous glasses indicate contributions to the spectra by iron-moieties present in a more ordered structural environment than found in the dry glass. These differences are also suggested by analysis of the EXAFS. These effects are not completely suppressed even for those samples that were quenched with a higher cooling rate. Strongest differences to the dry glass are observed for a sample that was quenched slowly through the temperature of glass transformation. Crystals (60 to 1500 nm in size) of magnetite, maghemite and another unidentified phase were observed in this sample by TEM, whereas no crystals were found in samples quenched with regular or high cooling rates. In-situ XANES measurements up to 700 degrees C and 500 MPa were performed to reveal the origin (i.e., during synthesis or quench) of the structural differences for those hydrous glasses that do not display any detectable crystallization. The comparison of XANES spectra collected on Fe2+ in water-saturated haplogranitic melt at 700 degrees C and 500 MPa and on Fe2+ in dry melt at 1150 degrees C shows that the local structural environment of Fe2+ in both systems is similar. This indicates that there is no detectable and direct influence of water on the local structure around iron in this type of melt. Hence, the differences observed between hydrous and dry glasses can only be related to artefacts formed during the quench process. (c) 2006 Elsevier B.V. All rights reserved Y1 - 2006 U6 - https://doi.org/10.1016/j.chemgeo.2006.01.017 ER - TY - JOUR A1 - Rufer, CE A1 - Glatt, Hansruedi A1 - Kulling, Sabine E. T1 - Structural elucidation of hydroxylated metabolites of the isoflavan equol by gas chromatography-mass spectrometry and high-performance liquid chromatography-mass spectrometry N2 - Equol has, as have other isoflavonoids, recently gained considerable interest due to its possible health effects. However, detailed studies on the metabolism of equol are scarce. Therefore, we investigated the phase I metabolism of equol using liver microsomes from Aroclor-treated male Wistar rats as well as from a male human. The identification of the metabolites formed was elucidated using high performance liquid chromatography ( HPLC) with diode array detection, HPLC/atmospheric pressure ionization electrospray mass spectrometry, and gas chromatography-mass spectrometry, as well as reference compounds. ( +/-)-Equol was converted to 11 metabolites by the liver microsomes from Aroclorpretreated rats comprising three aromatic monohydroxylated and four aliphatic monohydroxylated as well as four dihydroxylated products. The main metabolite was identified as 3'-hydroxy-equol. Using human liver microsomes, equol was converted to six metabolites with 3'-hydroxy- and 6-hydroxy-equol as main products. Furthermore, the aliphatic hydroxylated metabolite 4-hydroxyequol, which was recently detected in human urine after soy consumption, was formed. On the basis of these findings, it is suggested that phase I metabolism of equol is part of a complex biotransformation of the soy isoflavone daidzein in humans in vivo Y1 - 2006 U6 - https://doi.org/10.1124/dmd.105.004929 ER - TY - JOUR A1 - Menendez, Orquidea A1 - Rawel, Harshadrai Manilal A1 - Schwarzenbolz, Uwe A1 - Henle, Thomas T1 - Structural changes of microbial transglutaminase during thermal and high-pressure treatment N2 - The activity of microbial transglutaminase (MTG) and the corresponding secondary structure, measured by circular dichroism (CID), was analyzed before and after treatment at different temperatures (40 and 80 degrees C) and pressures (0.1, 200, 400, 600 MPa). Irreversible enzyme inactivation was achieved after 2 min at 80 degrees C and 0.1 MPa. Enzyme inactivation at 0.1, 200, 400, and 600 MPa and 40 degrees C followed first-order kinetics. The enzyme showed residual activity of 50% after 12 min at 600 MPa and 40 degrees C. Mobility of aromatic side chains of the enzyme molecule was observed in all temperature- and/or pressure-treated samples; however, high-pressure treatment at 600 MPa induced a loss of tertiary structure and a significant decrease in the alpha-helix content. The relative content of beta- strand substructures was significantly increased after 30 min at 600 MPa and 40 degrees C or 2 min at 0.1 MPa and 80 degrees C. We conclude that the active center of MTG, which is located in an expanded 8-strand domain, is resistant to high hydrostatic pressure and pressure-induced inactivation is caused by destruction of cc-helix elements with a corresponding influence on the enzyme stability in solution Y1 - 2006 UR - http://pubs.acs.org/journal/jafcau U6 - https://doi.org/10.1021/Jf0522863 ER - TY - JOUR A1 - Note, Carine A1 - Koetz, Joachim A1 - Kosmella, Sabine T1 - Structural changes in poly(ethyleneimine) modified microemulsion JF - Journal of colloid and interface science N2 - The influence of branched poly(ethyleneimine) on the phase behavior of the system sodium dodecylsulfate/toluene-pentanol (1:1)/water has been studied. The isotropic microemulsions still exist when water is replaced with aqueous solutions of PEI (up to 30% in weight), but their stability is significantly influenced. From a polymer concentration of 20 wt%, the polymer enhances the solubilization of water in oil, changes the sign of the spontaneous curvature of the surfactant film, and induces an inversion of the microemulsion type from water-in-oil (L-2) to oil-in-water (L-1), by the formation of a bicontinuous channel. Further investigations show that the addition of polymer in the L-2 phase changes the droplet-droplet interactions as the conductivity drops and the percolation disappears. In the bicontinuous channel, higher viscosities can be detected, as well as a weak percolation followed by a steep increase of the conductivity, which can be related to evident structural changes in the system. DSC measurements allow then to follow the changes of the water properties in the system, from interfacial-water in the L-2 phase to free-water in the sponge-like phase. Finally, all the measurements performed permit to characterize the structural transitions in the system and to understand the role of the added polymer. KW - polyelectrolyte KW - microemulsion KW - bicontinuous phase Y1 - 2006 U6 - https://doi.org/10.1016/j.jcis.2006.06.071 SN - 0021-9797 VL - 302 SP - 662 EP - 668 PB - Elsevier CY - Amsterdam ER - TY - RPRT A1 - Blien, Uwe A1 - Sanner, Helge T1 - Structural change and regional employment dynamics N2 - A casual look at regional unemployment rates reveals that there are vast differences, which cannot be explained by different institutional settings. Our paper attempts to trace these differences in the labor market performance back to the regions' specialization in products that are more or less advanced in their product cycle. The model we develop shows how individual profit and utility maximization endogenously yields higher employment levels in the beginning. In later phases, however, employment decreases in the presence of process innovation. Our model suggests that the only way to escape from this vicious circle is to specialize in products that are at the beginning of their "economic life". The model is based on an interaction of demand and supply side forces. T3 - Volkswirtschaftliche Diskussionsbeiträge - 82 Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-14425 ER - TY - JOUR A1 - Franco, Olga A1 - Orgzall, Ingo A1 - Regenstein, Wolfgang A1 - Schulz, Burkhard T1 - Structural and spectroscopical study of a 2,5-diphenyl-1,3,4-oxadiazole polymorph under compression N2 - The x-ray pattern and the Raman and luminescence spectra of crystalline 2,5-diphenyl-1,3,4-oxadiazole in one of its polymorphic forms (DPO II) have been investigated under pressure up to 5 GPa. The behaviour of the lattice parameters under compression was determined and it was found that the Murnaghan equation of state provides a good description of the volume-pressure relationship of DPO II. The values for the bulk modulus and its pressure derivative are K-0 = 8.6 GPa and K-0' = 7.2. The analysis of the Raman spectrum under compression clearly shows the pressure- induced shift of the Raman modes to higher frequencies. The mode Gruneisen parameters for the lattice modes were determined. Additionally, it was found that the emission spectrum of DPO II moves to lower energies and that the luminescence intensity decreases when pressure is applied Y1 - 2006 UR - http://iopscience.iop.org/0953-8984 U6 - https://doi.org/10.1088/0953-8984/18/4/029 SN - 0953-8984 ER - TY - JOUR A1 - Gaedke, Ursula A1 - Kamjunke, Norbert T1 - Structural and functional properties of low- and high-diversity planktonic food webs N2 - To test the consequences of decreased diversity and exclusion of keystone species, we compared the planktonic food webs in two acidic (pH <= 3), species-poor mining lakes with those in two species-rich, neutral lakes. The ratio of heterotrophic to autotrophic biomass (HIA) was similar in acidic and neutral lakes with comparable productivity. However, food webs in both acidic lakes were largely restricted to two trophic levels in contrast to the four levels found in neutral lakes. This restriction in food chain length was attributed to the absence of efficient secondary consumers, rather than to productivity or lake size which resulted in unusually low predator-prey weight ratios, with small top predators hardly exceeding their pry in size. In contrast to the neutral lakes, plankton biomass size spectra of acidic lakes were discontinuous due to a lack of major functional groups. The unique size-dependence of feeding modes in pelagic food webs, with bacteria in the smallest size classes followed by autotrophs, herbivores and carnivores, was maintained for bacteria but the other feeding modes strongly overlapped in size. Thus, their characteristic succession along the size gradient was roughly preserved under extreme conditions but the flow of energy along the size gradient was truncated in the acidic lakes. For most but not all attributes studied, differences were larger between acidic and neutral lakes than between neutral lakes of different trophic state Y1 - 2006 UR - http://plankt.oxfordjournals.org/ U6 - https://doi.org/10.1093/plankt/fb1003 SN - 0142-7873 ER - TY - JOUR A1 - Zemanova, Lucia A1 - Zhou, Changsong A1 - Kurths, Jürgen T1 - Structural and functional clusters of complex brain networks JF - Physica, D, Nonlinear phenomena N2 - Recent research using the complex network approach has revealed a rich and complicated network topology in the cortical connectivity of mammalian brains. It is of importance to understand the implications of such complex network structures in the functional organization of the brain activities. Here we study this problem from the viewpoint of dynamical complex networks. We investigate synchronization dynamics on the corticocortical network of the cat by modeling each node (cortical area) of the network with a sub-network of interacting excitable neurons. We find that the network displays clustered synchronization behavior, and the dynamical clusters coincide with the topological community structures observed in the anatomical network. Our results provide insights into the relationship between the global organization and the functional specialization of the brain cortex. KW - cortical network KW - anatomical connectivity KW - functional connectivity KW - topological community KW - dynamical cluster Y1 - 2006 U6 - https://doi.org/10.1016/j.physd.2006.09.008 SN - 0167-2789 SN - 1872-8022 VL - 224 IS - 1-2 SP - 202 EP - 212 PB - Elsevier CY - Amsterdam ER - TY - THES A1 - Kierfeld, Jan T1 - Strings and Filaments: From Vortices to Biopolymers Y1 - 2006 CY - Potsdam ER - TY - JOUR A1 - Reichard, Christoph T1 - Strengthening competitiveness of local public service providers in Germany JF - International review of administrative sciences : an international journal of comparative public administration N2 - This article discusses the challenges for providers of local public services to adapt to increasing marketization and competition in the public sector. Based on some empirical evidence from local government in Germany, the article describes different adaptive measures in the past and shows the legal restrictions to strengthening performance and particularly competitiveness. Furthermore, the article presents some findings from good practice cases of local service providers in Germany who have successfully exposed themselves to market mechanisms. Finally, the article discusses observed results of increased competitiveness in the local government sector, with special regard to quality, efficiency and public employment. The article concludes with describing necessary elements of a competitive regime for public services and with some general reflections about the role of competition in the public sector. KW - competition KW - competitiveness KW - contractor/provider split KW - ensuring state KW - marketization KW - service provider strategies Y1 - 2006 U6 - https://doi.org/10.1177/0020852306070079 SN - 0020-8523 VL - 72 IS - 4 SP - 473 EP - 492 PB - Sage CY - London ER - TY - BOOK A1 - Freude, Ulrike A1 - Kuznetsov, Sergey P. A1 - Pikovskij, Arkadij T1 - Strange nonchaotic attractors : dynamics between order and chaos in Quasiperiodically Forced Systems Y1 - 2006 SN - 981-256633-3 PB - World Scientific CY - Singapore ER - TY - JOUR A1 - Köchy, Martin T1 - Stochastic time series of daily precipitation for the interior of Israel N2 - This contribution describes a generator of stochastic time series of daily precipitation for the interior of Israel from c. 90 to 900 mm mean annual precipitation (MAP) as a tool for studies of daily rain variability. The probability of rainfall on a given day of the year is described by a regular Gaussian peak curve function. The amount of rain is drawn randomly from an exponential distribution whose mean is the daily mean rain amount (averaged across years for each day of the year) described by a flattened Gaussian peak curve. Parameters for the curves have been calculated from monthly aggregated, long-term rain records from seven meteorological stations. Parameters for arbitrary points on the MAP gradient are calculated from a regression equation with MAP as the only independent variable. The simple structure of the generator allows it to produce time series with daily rain patterns that are projected under climate change scenarios and simultaneously control MAP. Increasing within-year variability of daily precipitation amounts also increases among-year variability of MAP as predicted by global circulation models. Thus, the time series incorporate important characteristics for climate change research and represent a flexible tool for simulations of daily vegetation or surface hydrology dynamics. Y1 - 2006 UR - 1960 = dx.doi.org/10.1560/IJES_55_2_103 ER - TY - GEN A1 - Köchy, Martin T1 - Stochastic time series of daily precipitation for the interior of Israel N2 - This contribution describes a generator of stochastic time series of daily precipitation for the interior of Israel from c. 90 to 900 mm mean annual precipitation (MAP) as a tool for studies of daily rain variability. The probability of rainfall on a given day of the year is described by a regular Gaussian peak curve function. The amount of rain is drawn randomly from an exponential distribution whose mean is the daily mean rain amount (averaged across years for each day of the year) described by a flattened Gaussian peak curve. Parameters for the curves have been calculated from monthly aggregated, long-term rain records from seven meteorological stations. Parameters for arbitrary points on the MAP gradient are calculated from a regression equation with MAP as the only independent variable. The simple structure of the generator allows it to produce time series with daily rain patterns that are projected under climate change scenarios and simultaneously control MAP. Increasing within-year variability of daily precipitation amounts also increases among-year variability of MAP as predicted by global circulation models. Thus, the time series incorporate important characteristics for climate change research and represent a flexible tool for simulations of daily vegetation or surface hydrology dynamics. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 029 KW - stochastische Zeitreihen KW - täglicher Niederschlag KW - Israel KW - Klimawandel KW - stochastic time series KW - daily precipitation KW - Israel KW - climate change Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13155 ER - TY - JOUR A1 - Makuch, Martin A1 - Brilliantov, Nikolai V. A1 - Sremcevic, Miodrag A1 - Spahn, Frank A1 - Krivov, Alexander V. T1 - Stochastic circumplanetary dynamics of rotating non-spherical dust particles JF - Planetary and space science N2 - We develop a model of stochastic radiation pressure for rotating non-spherical particles and apply the model to circumplanetary dynamics of dust grains. The stochastic properties of the radiation pressure are related to the ensemble-averaged characteristics of the rotating particles, which are given in terms of the rotational time-correlation function of a grain. We investigate the model analytically and show that an ensemble of particle trajectories demonstrates a diffusion-like behaviour. The analytical results are compared with numerical simulations, performed for the motion of the dusty ejecta from Deimos in orbit around Mars. We find that the theoretical predictions are in a good agreement with the simulation results. The agreement however deteriorates at later time, when the impact of non-linear terms, neglected in the analytic approach, becomes significant. Our results indicate that the stochastic modulation of the radiation pressure can play an important role in the circumplanetary dynamics of dust and may in case of some dusty systems noticeably alter an optical depth. (c) 2006 Elsevier Ltd. All rights reserved. KW - Mars KW - Deimos KW - ejecta KW - stochastics KW - radiation pressure Y1 - 2006 U6 - https://doi.org/10.1016/j.pss.2006.05.006 SN - 0032-0633 VL - 54 IS - 9-10 SP - 855 EP - 870 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Schmidt, Bernd A1 - Nave, Stefan T1 - Stereoselective syntheses of enantiomerically pure 2,5-disubstituted dihydropyrans based on olefin metathesis JF - The journal of organic chemistry N2 - A short synthesis of 2,5-disubstituted dihydropyrans starting from D-mannitol as a chiral building block is described. Our synthetic approach combines ruthenium-catalyzed ring closing olefin metathesis and palladium-catalyzed nucleophilic substitution. Y1 - 2006 U6 - https://doi.org/10.1021/jo061190k SN - 0022-3263 VL - 71 IS - 19 SP - 7364 EP - 7369 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Shainyan, Bagrat A. A1 - Ushakov, Igor A. A1 - Koch, Andreas A1 - Kleinpeter, Erich T1 - Stereodynamics of 1-(methylsulfonyl)-3,5-bis(trifluoromethylsulfonyl)-1,3,5-triazinane: Experimental and theoretical analysis N2 - Dynamic NMR of 1-(methylsulfonyl)-3,5-bis(trifluoromethylsulfonyl)-1,3,5-triazinane reveals the existence of three conformers and two dynamic processes: ring inversion and rotation about the N-S bond, both processes having Delta G(double dagger) = 13.5 kcal/mol. An unprecedented large reverse Perlin effect (J(CHax) > J(CHeq)) was found experimentally and calculated theoretically. Y1 - 2006 UR - http://pubs.acs.org/doi/full/10.1021/jo061112x U6 - https://doi.org/10.1021/Jo061112x ER - TY - JOUR A1 - Leupold, Dieter A1 - Teuchner, Klaus A1 - Ehlert, Jürgen A1 - Irrgang, Klaus-Dieter A1 - Renger, Gernot A1 - Lokstein, Heiko T1 - Stepwise two-photon excited fluorescence from higher excited states of chlorophylls in photosynthetic antenna complexes Y1 - 2006 UR - http://www.jbc.org/ U6 - https://doi.org/10.1074/jbc.M600080200 SN - 0021-9258 ER - TY - THES A1 - Ott, Christian David T1 - Stellar iron core collapse in {3+1} general relativity and the gravitational wave signature of core-collapse supernovae T1 - Stellarer Eisenkernkollaps in Allgemeiner Relativitätstheorie und die Gravitationswellensignatur von Kern-Kollaps-Supernovae N2 - I perform and analyse the first ever calculations of rotating stellar iron core collapse in {3+1} general relativity that start out with presupernova models from stellar evolutionary calculations and include a microphysical finite-temperature nuclear equation of state, an approximate scheme for electron capture during collapse and neutrino pressure effects. Based on the results of these calculations, I obtain the to-date most realistic estimates for the gravitational wave signal from collapse, bounce and the early postbounce phase of core collapse supernovae. I supplement my {3+1} GR hydrodynamic simulations with 2D Newtonian neutrino radiation-hydrodynamic supernova calculations focussing on (1) the late postbounce gravitational wave emission owing to convective overturn, anisotropic neutrino emission and protoneutron star pulsations, and (2) on the gravitational wave signature of accretion-induced collapse of white dwarfs to neutron stars. N2 - Ich präsentiere die ersten Computer-Simulationen des rotierenden Kollapses stellarer Eisenkerne, die in der {3+1}-Zerlegung der Allgemeinen Relativitätstheorie durchgeführt werden und Vorsupernova-Sternmodelle aus Sternentwicklungsrechnungen, eine heiße nukleare Zustandsgleichung und ein näherungsweises Verfahren zur Beschreibung des Elektroneneinfangs enthalten und Neutrinodruck-Effekte berücksichtigen. Basierend auf den Ergebnissen dieser Rechnungen erhalte ich die zur Zeit realistischsten Vorhersagen für das Gravitationswellensignal der Kollaps, Abprall, Abkling und frühen Nach-Abprallphase einer Kern-Kollaps-Supernova. Neben den {3+1} Simulationen diskutiere ich newtonsche axisymmetrische Kern-Kollaps-Supernova-Simulationen mit Schwerpunkten auf: (1) der Gravitationswellenabstrahlung in der späten Nach-Abprallphase durch Konvektionsströmungen, anisotropische Neutrinoemission und Proto-Neutronenstern Pulsationen und (2) der Gravitationswellensignatur des Kollapses weißer Zwergsterne zu Neutronensternen, der durch Akkretion eingeleitet wird. KW - Gravitationswellen KW - Kern-Kollaps-Supernovae KW - Allgemeine Relativitätstheorie KW - Gravitational Waves KW - Core-Collapse Supernovae KW - General Relativity Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-12986 ER - TY - BOOK A1 - Nosova, Olga A1 - Bartels, Knut T1 - Statistical analysis of the corporate governance system in the Ukraine: problems and development perspectives N2 - This paper investigates the formation of the ownership structure and the corporate governance system of the Ukraine as a country in transition. Numerous studies consider that privatization results in the establishment of a proprietors’ motivation mechanism. On the other hand it causes ownership concentration in the hands of a few shareholders and managers. The goal of economic reform in transition and, largely, its pace, is measured by the degree to which shareholders participate in short- and long-term corporate value creation. Shareholder access to such created value depends on the ability of corporate “insiders”, especially executives and management, to claim a disproportionate share of corporate value (the “insider effect”). An econometric analysis of the correlation between privatization and macroeconomic factors studies the degree of effectiveness of economic reforming in Ukrainian regions. T3 - Statistische Diskussionsbeiträge - 25 KW - corporate governance KW - shareholders KW - econometric modelling Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-12188 ER - TY - JOUR A1 - Fleschhut, Jens A1 - Kratzer, Frank A1 - Rechkemmer, Gerhard A1 - Kulling, Sabine E. T1 - Stability and biotransformation of various dietary anthocyanins in vitro N2 - Background Anthocyanins, which are found in high concentrations in fruit and vegetable, may play a beneficial role in retarding or reversing the course of chronic degenerative diseases. However, little is known about the biotransformation and the metabolism of anthocyanins so far. Aim of the study The aim of the study was to investigate possible transformation pathways of anthocyanins by human faecal microflora and by rat liver microsomes as a source of cytochrome P450 enzymes as well as of glucuronyltransferases. Methods Pure anthocyanins, an aqueous extract of red radish as well as the assumed degradation products were incubated with human faecal suspension. The incubation mixtures were purified by solid-phase extraction and analysed by HPLC/DAD/MS and GC/MS. Quantification was done by the external standard method. Furthermore the biotransformation of anthocyanins by incubation with rat liver microsomes in the presence of the cofactor NADPH (as a model for the phase I oxidation) and in the presence of activated glucuronic acid (as a model for the phase II glucuronidation) was investigated. Results Glycosylated and acylated anthocyanins were rapidly degraded by the intestinal microflora after anaerobic incubation with a human faecal suspension. The major stable products of anthocyanin degradation are the corresponding phenolic acids derived from the B-ring of the anthocyanin skeleton. Anthocyanins were not metabolised by cytochrome P450 enzymes, neither hydroxylated nor demethylated. However they were glucuronidated by rat liver microsomes to several products. Conclusions The gut microflora seem to play an important role in the biotransformation of anthocyanins. A rapid degradation could be one major reason for the poor bioavailability of anthocyanins in pharmacokinetic studies described so far in the literature. The formation of phenolic acids as the major stable degradation products gives an important hint to the fate of anthocyanins in vivo Y1 - 2006 UR - http://www.springerlink.com/content/103683 U6 - https://doi.org/10.1007/s00394-005-0557-8 SN - 1436-6207 ER - TY - JOUR A1 - Thiel, Marco A1 - Romano, Maria Carmen A1 - Kurths, Jürgen T1 - Spurious structures in recurrence plots induced by embedding N2 - In this paper we show that delay embedding produces spurious structures in a recurrence plot (RP) that are not present in the real attractor. We analyze typical sets of simulated data, such as white noise and data from the chaotic Rossler system to show the relevance of this effect. In the second part of the paper we show that the second order Renyi entropy and the correlation dimension are dynamical invariants that can be estimated from Recurrence Plots with arbitrary embedding dimension and delay Y1 - 2006 U6 - https://doi.org/10.1007/s11071-006-2010-9 ER - TY - JOUR A1 - Tirok, Katrin A1 - Gaedke, Ursula T1 - Spring weather determines the relative importance of ciliates, rotifers and crustaceans for the initiation of the clear-water phase in a large, deep lake N2 - Clear-water phase (CWP) is an important event in seasonal plankton succession. We examined the influence of all herbivorous zooplankton on its initiation under different weather and climatic conditions using up to 19 years of observations from the large, deep Lake Constance (Europe) and estimates of relative clearance rates. A CWP occurred regularly, even if daphnid biomass was still very low. CWP was attributed to strong grazing either by a daphnid- dominated zooplankton community or by a diverse assemblage consisting of micro- and meso-zooplankton. Both types of zooplankton communities occurred with approximately the same frequency. The timing of the CWP was unrelated to the North Atlantic Oscillation (NAO) but correlated with the wind-dependent intensity of deep vertical mixing 3 months earlier, during early spring. Less mixing enabled early growth of phytoplankton, ciliates and rotifers despite low temperatures, which prevented daphnid development at this time. This resulted in enhanced grazing of ciliates and rotifers, which increased the importance of phytoplankton less edible for most ciliates, rotifers and daphnids. Ciliates clearly dominated the grazing pressure on phytoplankton throughout spring, maintaining high biomasses together with the phytoplankton for up to 2 months. A CWP was observed when herbivores grazing on larger phytoplankton developed in addition to ciliates Y1 - 2006 ER - TY - JOUR A1 - Kumke, Michael Uwe A1 - Dosche, Carsten A1 - Flehr, Roman A1 - Trowitzsch-Kienast, Wolfram A1 - Löhmannsröben, Hans-Gerd T1 - Spectroscopic characterization of the artificial siderophore pyridinochelin Y1 - 2006 UR - http://www.znaturforsch.com/c.htm SN - 0939-5075 ER - TY - CHAP A1 - Hainzl, Sebastian A1 - Scherbaum, Frank A1 - Zöller, Gert T1 - Spatiotemporal earthquake patterns N2 - Interdisziplinäres Zentrum für Musterdynamik und Angewandte Fernerkundung Workshop vom 9. - 10. Februar 2006 Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-7267 N1 - [Poster] ER - TY - THES A1 - Mungur, Rajsree T1 - Spatio-temporal analysis of florigenic signals in Arabidopsis thaliana, Sinapis alba and Brassica napus T1 - Zeitabhängige Analyse von blühinduzierenden Signalen in Arabidopsis thaliana, Sinapis alba und Brassica napus N2 - Daylength is one of several parameters controlling flowering time in many plant species. The day length is perceived in leaves, but how the floral signal is transduced to the shoot apex via the phloem to induce flowering remains to be elucidated. This study aimed at the identification of new candidates involved in the induction of flowering by employing three plant species, Arabidopsis thaliana, Sinapis alba and Brassica napus in combination with transcript profiling by Affymetrix chip hybridization, metabolite profiling by gas chromatography – mass spectrometry and targeted protein analysis using antibodies. All analyses were performed on tissue-specific samples and focused on phloem sap or phloem exudates. To find common transcript and metabolite candidates potentially associated with the floral transition, two independent induction systems in Arabidopsis were used: a photoextension system, whereby plants received fourteen additional hours of light, and a parallel dexamethasone-inducible system, which was centered on the induction of the known flowering gene CONSTANS (CO). Identification of signals preceding the CO cascade was possible using the light extension regime, while downstream events dependent on CO activation were compared in both systems. Altogether, a number of interesting transcript and metabolite candidates were identified in both systems with some degree of overlap. Sinapis alba was used to investigate the universality of the floral signals between species. Comparisons of metabolite data revealed a few common candidates that may prove interesting for further studies. In addition, a targeted approach was carried out to investigate the presence of the Flowering Locus T (FT) protein during different stages of flower development using an antibody. Interesting changes in the sizes of antigens from rape phloem were seen and appeared consistent in Arabidopsis and to a lesser extent in Sinapis. Overall, the broad surveying approaches for transcripts and metabolites used in this study revealed several new potential candidates involved in the induction and/or regulation of flowering. As far as the protein work, additional experiments will reveal the link between FT and floral induction as well as its role in maintaining the floral state using the abovementioned plant species. N2 - Die Tageslänge ist in vielen Pflanzenarten einer der Parameter, welche die Blütenbildung kontrollieren. Die Tageslänge wird in Blättern gemessen, aber wie das blühinduzierende Signal über das Phloem in den Apex übertragen wird ist bisher nicht aufgeklärt. Die vorliegende Arbeit hatte das Ziel neue Kandidaten zu identifizieren, die an der Blühinduktion beteiligt sind. Dazu wurden die drei Pflanzenarten Arabidopsis thaliana, Sinapis alba und Brassica napus auf der Ebene von Transkripten durch Affymetrix Chip Hybridisierungen, Metaboliten durch Gaschromatographie-Massenspektrometrie und ausgesuchten Proteinen durch Antikörper analysiert. Alle Untersuchungen wurden an gewebespezifischen Proben vorgenommen und waren auf Phloemsaft bzw. Phloemexsudate fokussiert. Um gemeinsame Transkript- und Metabolitkandidaten zu ermitteln, welche mit der Blühinduktion in Zusammenhang stehen, wurden zwei unabhängige Induktionssysteme in Arabidopsis verwendet: Ein Photoextensions-System, in dem die Pflanzen vierzehn zusätzlichen Stunden Licht ausgesetzt wurden und ein paralleles Dexamethason-induzierbares System, das die gezielte Aktivierung des bekannten blühinduzierenden Gens CONSTANS (CO) ermöglicht. Die Identifikation von CO-vorgelagerten Signalen war in dem Photoextensions-System möglich, während der CO-Aktivierung nachgelagerte Ereignisse in beiden Systemen verglichen werden konnten. Zusammengenommen konnten mit beiden Systemen eine Reihe von interessanten Transkript- und Metabolitkandidaten ermittelt werden, welche auch teilweise überlappten. Anschließend wurde Sinapis alba verwendet, um die Universalität der blühinduzierenden Signale in verschiedenen Pflanzenarten zu untersuchen. Vergleiche der Metabolitendaten ergaben ein paar gemeinsame Kandidaten, welche für weitergehende Untersuchungen interessant sein könnten. Zusätzlich wurden mittels Antikörpern gezielte Untersuchungen bezüglich der Präsenz des Flowering Locus T (FT) Proteins während verschiedener Stadien der Blütenentwicklung durchgeführt. Diese Untersuchungen zeigten interessante Änderungen der Größe des Antigens in Raps Phloemsaft, welche auch in Arabidopsis und in geringerem Maße in Sinapis sichtbar waren. Zusammengefasst resultierten die umfassenden Transkript- und Metabolitenmessungen, die in dieser Arbeit verwendet wurden, in einer Reihe von neuen möglichen Kandidaten, welche an der Induktion und/oder Regulation der Blütenbildung beteiligt sein könnten. Bezüglich des Proteins FT sind zusätzliche Experimente notwendig, um seine Rolle bei der Blühinduktion bzw. bei der Aufrechterhaltung des blühenden Zustandes aufzudecken. KW - Florigen KW - Florigen Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-9861 ER - TY - JOUR A1 - Vasconcelos, D. B. A1 - Lopes, S. R. A1 - Viana, R. L. A1 - Kurths, Jürgen T1 - Spatial recurrence plots N2 - We propose an extension of the recurrence plot concept to perform quantitative analyzes of roughness and disorder of spatial patterns at a fixed time. We introduce spatial recurrence plots (SRPs) as a graphical representation of the pointwise correlation matrix, in terms of a two-dimensional spatial return plot. This technique is applied to the study of complex patterns generated by coupled map lattices, which are characterized by measures of complexity based on SRPs. We show that the complexity measures we propose for SRPs provide a systematic way of investigating the distribution of spatially coherent structures, such as synchronization domains, in lattice profiles. This approach has potential for many more applications, e.g., in surface roughness analyzes Y1 - 2006 UR - http://pre.aps.org/pdf/PRE/v73/i5/e056207 U6 - https://doi.org/10.1103/Physreve.73.056207 ER - TY - GEN A1 - Neye, Gundula A1 - Wallschläger, Hans-Dieter A1 - Tiedemann, Ralph T1 - Song dialect boundaries in the Yellowhammer: Do they restrict gene flow? T2 - Journal of ornithology Y1 - 2006 SN - 0021-8375 VL - 147 IS - Supplement 1 SP - 219 EP - 219 PB - Blackwell CY - New York ER - TY - JOUR A1 - Zen, Achmad A1 - Bilge, Askin A1 - Galbrecht, Frank A1 - Alle, Ronald A1 - Meerholz, Klaus A1 - Grenzer, Jörg A1 - Neher, Dieter A1 - Scherf, Ullrich A1 - Farrell, Tony T1 - Solution processable organic field-effect transistors utilizing an alpha,alpha '-dihexylpentathiophene- based swivel cruciform Y1 - 2006 UR - http://pubs.acs.org/doi/full/10.1021/ja0573357 U6 - https://doi.org/10.1021/Ja0573357 ER - TY - JOUR A1 - Heinken, Thilo A1 - Schmidt, Marcus A1 - von Oheimb, Goddert A1 - Kriebitzsch, Wolf-Ulrich A1 - Ellenberg, Hermann T1 - Soil seed banks near rubbing trees indicate dispersal of plant species into forests by wild boar N2 - Current knowledge about processes that generate long-distance dispersal of plants is still limited despite its importance for persistence of populations and colonization of new potential habitats. Today wild Large mammals are presumed to be important vectors for long-distance transport of diaspores within and between European temperate forest patches, and in particular wild boars recently came into focus. Here we use a specific habit of wild boar, i.e. wallowing in mud and subsequent rubbing against trees, to evaluate epizoochorous dispersal of vascular plant diaspores. We present soil seed bank data from 27 rubbing trees versus 27 control trees from seven forest areas in Germany. The mean number of viable seeds and the plant species number were higher in soil samples near rubbing trees compared with control trees. Ten of the 20 most frequent species were more frequent, and many species exclusively appeared in the soil samples near rubbing trees. The large number of plant species and seeds - more than 1000 per tree - in the soils near rubbing trees is difficult to explain unless the majority were dispersed by wild boar. Hooked and bristly diaspores, i.e. those adapted to epizoochory, were more frequent; however, many species with unspecialized diaspores occurred exclusively near rubbing trees. As opposed to plant species closely tied to forests species which occur both in forest and open vegetation and non-forest species were more frequent near rubbing trees compared with controls. These findings are consistent with previous studies on diaspore loads in the coats and hooves of shot wild boars. However, our method allows to identify the transport of diaspores from the open landscape into forest stands, where they might especially emerge after disturbance, and a clustered distribution of epizoochorically dispersed seeds. Moreover, accumulation of seeds of wetness indicators near rubbing trees demonstrates directed dispersal of plant species inhabiting wet places among remote wallows. Y1 - 2006 UR - http://www.sciencedirect.com/science/journal/14391791 U6 - https://doi.org/10.1016/j.baae.2005.04.006 SN - 1439-1791 ER - TY - GEN A1 - Heinken, Thilo A1 - Schmidt, Marcus A1 - von Oheimb, Goddert A1 - Kriebitzsch, Wolf-Ulrich A1 - Ellenberg, Hermann T1 - Soil seed banks near rubbing trees indicate dispersal of plant species into forests by wild boar N2 - Current knowledge about processes that generate long-distance dispersal of plants is still limited despite its importance for persistence of populations and colonization of new potential habitats. Today wild large mammals are presumed to be important vectors for long-distance transport of diaspores within and between European temperate forest patches, and in particular wild boars recently came into focus. Here we use a specific habit of wild boar, i.e. wallowing in mud and subsequent rubbing against trees, to evaluate epizoic dispersal of vascular plant diaspores. We present soil seed bank data from 27 rubbing trees versus 27 control trees from seven forest areas in Germany. The mean number of viable seeds and the plant species number were higher in soil samples near rubbing trees compared with control trees. Ten of the 20 most frequent species were more frequent, and many species exclusively appeared in the soil samples near rubbing trees. The large number of plant species and seeds – approximated > 1000 per tree – in the soils near rubbing trees is difficult to explain unless the majority were dispersed by wild boar. Hooked and bristly diaspores, i.e. those adapted to epizoochory, were more frequent, above that many species with unspecialised diaspores occurred exclusively near rubbing trees. Different to plant species closely tied to forest species which occur both in forest and open vegetation, and non-forest species were more frequent near rubbing trees compared with controls. These findings are consistent with previous studies on diaspore loads in the coats and hooves of shot wild boars. However, our method allows to identify the transport of diaspores from the open landscape into forest stands where they might especially emerge after disturbance, and a clustered distribution of epizoochorically dispersed seeds. Moreover, accumulation of seeds of wetness indicators near rubbing trees demonstrates directed dispersal of plant species inhabiting wet places between remote wallows. N2 - Das aktuelle Wissen über Prozesse, die zur Fernausbreitung von Pflanzen führen, ist trotz ihrer Bedeutung für das Überleben von Populationen und die Besiedlung neuer potenzieller Habitate noch immer sehr begrenzt. Wildlebende Großsäuger sind heutzutage vermutlich wichtige Vektoren für den Ferntransport von Diasporen innerhalb und zwischen den einzelnen Waldflächen in Mitteleuropa, und speziell das Wildschwein (Sus scrofa L.) spielt dabei offenbar eine herausragende Rolle. Wir nutzen hier ein spezifisches Verhalten des Wildschweins – Suhlen im Schlamm und nachfolgendes Scheuern an sogenannten Malbäumen – um die epizoochore Ausbreitung von Gefäßpflanzen-Diasporen einzuschätzen. Dargestellt werden die Ergebnisse von Samenbank-Untersuchungen von 27 Malbäumen im Vergleich zu 27 Kontrollbäumen aus sieben Waldgebieten in Deutschland. Sowohl die mittlere Zahl lebensfähiger Samen als auch die Artenzahl waren höher in Bodenproben neben Malbäumen. Zehn der 20 in der Samenbank verbreitetsten Pflanzenarten hatten hier ihren Schwerpunkt, und viele Arten kamen ausschließlich in den neben Malbäumen gewonnenen Proben vor. Die große Zahl von Pflanzenarten und Samen – zumindest > 1000 pro Baum – im Boden an Malbäumen lässt sich nur durch die Aktivität der Wildschweine erklären. Mit Haken oder Borsten ausgestattete, d.h. an Epizoochorie angepasste Diasporen waren häufiger, aber auch viele Arten mit unspezialisierten Diasporen kamen ausschließlich in der Samenbank bei Malbäumen vor. Anders als weitgehend an Wald gebundene Pflanzenarten waren solche, die sowohl im Wald und im Offenland vorkommen, sowie nicht im Wald vorkommende Arten häufiger neben Malbäumen als neben Kontrollbäumen. Diese Befunde stimmen mit denen früherer Untersuchungen von Diasporenladungen im Fell und in den Hufen geschossener Wildschweine überein. Unsere Methode erlaubt darüber hinaus aber die Identifizierung des Diasporentransports aus dem Offenland in die Waldbestände, wo sie insbesondere nach Störungen keimen dürften, sowie einer ungleichmäßigen Verteilung epizoochor ausgebreiteter Diasporen. Außerdem zeigt die Akkumulation von Samen von Nässezeigern neben den Malbäumen eine gezielte Ausbreitung nasse Standorte bewohnender Pflanzenarten zwischen entfernt gelegenen Suhlen. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 150 KW - Diaspore morphology KW - directed dispersal KW - epizoochory KW - long-distance dispersal KW - Sus scrofa Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-46476 ER - TY - JOUR A1 - Gronau, Norbert A1 - Fröming, Jane A1 - Schmid, Simone T1 - Skill Management Y1 - 2006 ER - TY - THES A1 - Brunnemann, Johannes T1 - Singularities of Classical Relativity within the Framework of Loop Quantum Gravity Y1 - 2006 CY - Potsdam ER - TY - JOUR A1 - Henneberg, Oliver A1 - Pietsch, Ullrich A1 - Panzner, Tobias A1 - Geue, Thomas A1 - Finkelstein, Kenneth D. T1 - Simultaneous X-ray and visible light diffraction for the investigation of surface relief and density grating formation in azobenzene containing polymer films N2 - The development of surface relief and density patterns in azobenzene polymer films was studied by diffraction at two different wavelengths. We used x-ray diffraction of synchrotron radiation at 0.124 nm in combination with visible light diffraction at a wavelength of 633 nm. In contrast to visible light scattering x-ray diffraction allows the separation of a surface relief and a density grating contribution due to the different functional dependence of the scattering power. Additionally, the x-ray probe is most sensitive for the onset of the surface grating formation Y1 - 2006 UR - http://www.informaworld.com/smpp/title~content=t713644168~db=all U6 - https://doi.org/10.1080/15421400500383345 SN - 1542-1406 ER - TY - JOUR A1 - Sommer, Michael A1 - Kaczorek, Danuta A1 - Kuzyakov, Yakov A1 - Breuer, Jörn T1 - Silicon pools and fluxes in soils and landscapes : a review N2 - Silicon (Si) is the second-most abundant element in the earth's crust. In the pedosphere, however, huge spans of Si contents occur mainly caused by Si redistribution in soil profiles and landscapes. Here, we summarize the current knowledge on the different pools and fluxes of Si in soils and terrestrial biogeosystems. Weathering and subsequent release of soluble Si may lead to (1) secondarily bound Si in newly formed Al silicates, (2) amorphous silica precipitation on surfaces of other minerals, (3) plant uptake, formation of phytogenic Si, and subsequent retranslocation to soils, (4) translocation within soil profiles and formation of new horizons, or (5) translocation out of soils (desilication). The research carried out hitherto focused on the participation of Si in weathering processes, especially in clay neoformation, buffering mechanisms for acids in soils or chemical denudation of landscapes. There are, however, only few investigations on the characteristics and controls of the low-crystalline, almost pure silica compounds formed during pedogenesis. Further, there is strong demand to improve the knowledge of (micro)biological and rhizosphere processes contributing to Si mobilization, plant uptake, and formation of phytogenic Si in plants, and release due to microbial decomposition. The contribution of the biogenic Si sources to Si redistribution within soil profiles and desilication remains unknown concerning the pools, rates, processes, and driving forces. Comprehensive studies considering soil hydrological, chemical, and biological processes as well as their interactions at the scale of pedons and landscapes are necessary to make up and model the Si balance and to couple terrestrial processes with Si cycle of limnic, fluvial, or marine biogeosystems Y1 - 2006 ER - TY - JOUR A1 - Hausen, Harald A1 - Bleidorn, Christoph T1 - Significance of chaetal arrangement for maldanid systematics (Annelida : Maldanidae) JF - Scientia marina : international journal on marine sciences N2 - Maldanids are usually divided into several subfamilies: Euclymeninae, Lumbriclymeninae, Maldaninae, Nicomachinae, Rhodininae, Clymenurinae, Notoproctinae, and Boguinae. The taxonomy of maldanids and the delimination of these taxa are mainly based on head morphology, total number of segments, chaetal structure, shape of the pygidium, and position of the anus. The maldanid ingroup relationships, as well as the monophyly of the proposed subfamilies, have so far not been investigated. Pilgrim (1977) described a shift of the notopodial chaetal rows from a transverse direction in anterior chaetigers to a more longitudinal one in posterior chaetigers in Clymene torquata (Leidy, 1855) and Euclymene oerstedii (Claparede, 1863), both belonging to the Euclymeninae. We investigated several maldanid species to assess the usefulness of this character for maldanid systematics and used 3D-reconstruction techniques to reveal the complete geometry of the chaetal sacs. Our investigation shows that a shift is apparent in Euclymene, Axiothella, Johnstonia (all Euclymeninae) and Clymenura (Clymenurinae), but absent in species like Maldane sarsi (Malmgren, 1865), Metasychis disparidentata (Moore, 1904) (both Maldaninae) and Petaloproctus borealis Ardwisson, 1906 (Nicomachinae). The shift is not typical for sedentary polychaetes and is apomorphic within maldanid polychaetes. It thus argues for a close relationship between Euclymeninae and Clymenurinae. The investigation of further maldanid species of different subfamilies may shed additional light on maldanid systematics. KW - Annelida KW - Polychaeta KW - Maldanidae KW - systematics KW - chaetae KW - chaetal arrangement Y1 - 2006 SN - 0214-8358 VL - 70 SP - 75 EP - 79 PB - Institut de Ciències del Mar CY - Barcelona ER - TY - JOUR A1 - Lokstein, Heiko A1 - Hedke, Boris A1 - Mustroph, Angelika A1 - Kühn, Christina T1 - Signals, sensing, and plant primary metabolism Y1 - 2006 ER - TY - JOUR A1 - Zou, Yong A1 - Thiel, M. A1 - Romano, Maria Carmen A1 - Kurths, Jürgen A1 - Bi, Q. T1 - Shrimp structure and associated dynamics in parametrically excited oscillators JF - International journal of bifurcation and chaos : in applied sciences and engineering N2 - We investigate the bifurcation structures in a two-dimensional parameter space (PS) of a parametrically excited system with two degrees of freedom both analytically and numerically. By means of the Renyi entropy of second order K-2, which is estimated from recurrence plots, we uncover that regions of chaotic behavior are intermingled with many complex periodic windows, such as shrimp structures in the PS. A detailed numerical analysis shows that, the stable solutions lose stability either via period doubling, or via intermittency when the parameters leave these shrimps in different directions, indicating different bifurcation properties of the boundaries. The shrimps of different sizes offer promising ways to control the dynamics of such a complex system. KW - bifurcation analysis KW - recurrence plot KW - period doubling KW - intermittency Y1 - 2006 U6 - https://doi.org/10.1142/S0218127406016987 SN - 0218-1274 VL - 16 IS - 12 SP - 3567 EP - 3579 PB - World Scientific Publ. Co CY - Singapore ER - TY - GEN A1 - Rolfs, Martin A1 - Laubrock, Jochen A1 - Kliegl, Reinhold T1 - Shortening and Prolongation of Saccade Latencies Following Microsaccades N2 - When the eyes fixate at a point in a visual scene, small saccades rapidly shift the image on the retina. The effect of these microsaccades on the latency of subsequent large-scale saccades may be twofold. First, microsaccades are associated with an enhancement of visual perception. Their occurrence during saccade target perception should, thus, decrease saccade latencies. On the other hand, microsaccades likely indicate activity in fixation-related oculomotor neurons. These represent competitors to saccade-related cells in the interplay of gaze holding and shifting. Consequently, an increase in saccade latencies after microsaccades would be expected. Here, we present evidence for both aspects of microsaccadic impact on saccade latency. In a delayed response task, participants made saccades to visible or memorized targets. First, microsaccade occurrence up to 50 ms before target disappearance correlated with 18 ms (or 8%) faster saccades to memorized targets. Second, if microsaccades occurred shortly (i.e., < 150 ms) before a saccade was required, saccadic reaction times in visual and memory trials were increased by about 40 ms (or 16%). Hence, microsaccades can have opposite consequences for saccade latencies, pointing at a differential role of these fixational eye movements in preparation of motor programs. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - paper 242 KW - Fixational eye movements KW - Memory-guided saccades KW - Visually-guided saccades Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-57012 ER - TY - JOUR A1 - Rolfs, Martin A1 - Laubrock, Jochen A1 - Kliegl, Reinhold T1 - Shortening and prolongation of saccade latencies following microsaccades N2 - When the eyes fixate at a point in a visual scene, small saccades rapidly shift the image on the retina. The effect of these microsaccades on the latency of subsequent large-scale saccades may be twofold. First, microsaccades are associated with an enhancement of visual perception. Their occurrence during saccade target perception could, thus, decrease saccade latencies. Second, microsaccades are likely to indicate activity in fixation-related oculomotor neurons. These represent competitors to saccade-related cells in the interplay of gaze holding and shifting. Consequently, an increase in saccade latencies would be expected after microsaccades. Here, we present evidence for both aspects of microsaccadic impact on saccade latency. In a delayed response task, participants made saccades to visible or memorized targets. First, microsaccade occurrence up to 50 ms before target disappearance correlated with 18 ms (or 8%) faster saccades to memorized targets. Second, if microsaccades occurred shortly (i.e., < 150 ms) before a saccade was required, mean saccadic reaction time in visual and memory trials was increased by about 40 ms (or 16%). Hence, microsaccades can have opposite consequences for saccade latencies, pointing at a differential role of these fixational eye movements in the preparation of saccade motor programs Y1 - 2006 UR - http://www.springerlink.com/content/y67j226367352u28/fulltext.html U6 - https://doi.org/10.1007/s00221-005-0148-1 ER - TY - JOUR A1 - Medrano-T., R. O. A1 - Baptista, Murilo da Silva A1 - Caldas, Ibere Luiz T1 - Shilnikov homoclinic orbit bifurcations in the Chua’s circuit JF - Chaos : an interdisciplinary journal of nonlinear science N2 - We analytically describe the complex scenario of homoclinic bifurcations in the Chua’s circuit. We obtain a general scaling law that gives the ratio between bifurcation parameters of different nearby homoclinic orbits. As an application of this theoretical approach, we estimate the number of higher order subsidiary homoclinic orbits that appear between two consecutive lower order subsidiary orbits. Our analytical finds might be valid for a large class of dynamical systems and are numerically confirmed in the parameter space of the Chua’s circuit. Shilnikov homoclinic orbits are trajectories that depart from a fixed saddle-focus point, with specific eigenvalues, and return to it after an infinite amount of time (that is also true to time reversal evolution). That results in an orbit that is unstable and has an infinite period. These two main characteristics contribute in the hardness for its observation in a dynamical system as well as in nature. However, its presence reveals fundamental characteristics of the system involved, as the existence of unstable periodic orbits embedded in a chaotic set. Once the unstable periodic orbits give invariants quantities of this set,1 the Shilnikov homoclinic orbits are also related to the characteristics of the chaotic set. Their connection with the fundamental dynamical properties is verified in a wide variety of systems. A series of numerical and experimental investigations reveal how Shilnikov homoclinic orbits, in the vicinity of a chaotic attractor, determine its dynamical and topological properties.4 Thus, the Shilnikov orbits are related to the returning time of the trajectory of a CO2 laser,5 also to the topology of a glow-discharge system.6 Moreover, some class of spiking neurons are modeled by chaos governed by such orbits,7,8 and their presence are connected to the intermittence present in rabbit arteries.9 These orbits are shown to be behind the mechanism of noise-induced phenomena,10 and they are also responsible for the dynamics of an electrochemical oscillator.11 In this work, we contribute to the understanding of how Shilnikov homoclinic orbits appear on the parameter space of systems as the ones above mentioned, by showing that these orbits are not only distributed following an universal rule but also exist for large parameter variations. We then confirm our previsions in the Chua’s circuit system Y1 - 2006 U6 - https://doi.org/10.1063/1.2401060 SN - 1054-1500 VL - 16 IS - 4 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Carroll, Susanne E. T1 - Shallow processing : a consequence of bilingualism or second language learning? Y1 - 2006 UR - http://journals.cambridge.org/jid_APS U6 - https://doi.org/10.1017/S0142716406060061 SN - 0142-7164 ER - TY - JOUR A1 - Grobosch, Thomas A1 - Mickler, Wulfhard A1 - Feistel, Lothar A1 - Schilde, Uwe T1 - Separation of arsenic and other heavy metals with impregnated adsorber polymers : chapter 1: synthesis of the impregnation medium and separation of arsenic Y1 - 2006 UR - http://www3.interscience.wiley.com/cgi-bin/jhome/60500203/ U6 - https://doi.org/10.1002/cite.200500170 SN - 0009-286X ER - TY - JOUR A1 - Winterhalder, Matthias A1 - Schelter, B A1 - Kurths, Jürgen A1 - Schulze-Borthage, A A1 - Timmer, Jens T1 - Sensitivity and specificity of coherence and phase synchronization analysis N2 - In this Letter, we show that coherence and phase synchronization analysis are sensitive but not specific in detecting the correct class of underlying dynamics. We propose procedures to increase specificity and demonstrate the power of the approach by application to paradigmatic dynamic model systems. (c) 2006 Elsevier B.V. All rights reserved Y1 - 2006 UR - http://www.sciencedirect.com/science/article/pii/S0375960106004002 ( 11.07.2011] U6 - https://doi.org/10.1016/j.physleta.2006.03.018 ER - TY - THES A1 - Hohberger, Horst T1 - Semiclassical asymptotics for the scattering amplitude in the presence of focal points at infinity Y1 - 2006 CY - Potsdam ER - TY - THES A1 - Hohberger, Horst T1 - Semiclassical asymptotics for the scattering amplitude in the presence of focal points at infinity T1 - Semiklassische Asymptotik der Streuamplitude bei unendlich fernen Fokalpunkten N2 - We consider scattering in $\R^n$, $n\ge 2$, described by the Schr\"odinger operator $P(h)=-h^2\Delta+V$, where $V$ is a short-range potential. With the aid of Maslov theory, we give a geometrical formula for the semiclassical asymptotics as $h\to 0$ of the scattering amplitude $f(\omega_-,\omega_+;\lambda,h)$ $\omega_+\neq\omega_-$) which remains valid in the presence of focal points at infinity (caustics). Crucial for this analysis are precise estimates on the asymptotics of the classical phase trajectories and the relationship between caustics in euclidean phase space and caustics at infinity. N2 - Wir betrachten Streuung in $\R^n$, $n\ge 2$, beschrieben durch den Schr\"odinger operator $P(h)=-h^2\Delta+V$, wo $V$ ein kurzreichweitiges Potential ist. Mit Hilfe von Maslov Theorie erhalten wir eine geometrische Formel fuer die semiklassische Asymptotik ($h\to 0$) der Streuamplitude $f(\omega_-,\omega_+;\lambda,h)$ ($\omega_+\neq\omega_-$) welche auch bei Vorhandensein von Fokalpunkten bei Unendlich (Kaustiken) gueltig bleibt. KW - Mathematik KW - Physik KW - Streutheorie KW - Streuamplitude KW - Semiklassik KW - mathematics KW - physics KW - scattering theory KW - semiclassics KW - scattering amplitude Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-11574 ER - TY - JOUR A1 - Kofod, Guggi A1 - Paajanen, Mika A1 - Bauer, Siegfried T1 - Self-organized minimum-energy structures for dielectric elastomer actuators Y1 - 2006 UR - http://www.springerlink.com/content/100501 U6 - https://doi.org/10.1007/s00339-006-3680-3 SN - 0947-8396 ER - TY - JOUR A1 - Torjek, Otto A1 - Witucka-Wall, Hanna A1 - Meyer, Rhonda C. A1 - von Korff, Maria A1 - Kusterer, Barbara A1 - Rautengarten, Carsten A1 - Altmann, Thomas T1 - Segregation distortion in Arabidopsis C24/Col-0 and Col-0/C24 recombinant inbred line populations is due to reduced fertility caused by epistatic interaction of two loci JF - Theoretical and applied genetics N2 - A new large set of reciprocal recombinant inbred lines (RILs) was created between the Arabidopsis accessions Col-0 and C24 for quantitative trait mapping approaches, consisting of 209 Col-0 x C24 and 214 C24 x Col-0 F-7 RI lines. Genotyping was performed using 110 evenly distributed framework single nucleotide polymorphism markers, yielding a genetic map of 425.70 cM, with an average interval of 3.87 cM. Segregation distortion (SD) was observed in several genomic regions during the construction of the genetic map. Linkage disequilibrium analysis revealed an association between a distorted region at the bottom of chromosome V and a non-distorted region on chromosome IV. A detailed analysis of the RILs for these two regions showed that an SD occurred when homozygous Col-0 alleles on chromosome IV coincided with homozygous C24 alleles at the bottom of chromosome V. Using nearly isogenic lines segregating for the distorted region we confirmed that this genotypic composition leads to reduced fertility and fitness. Y1 - 2006 U6 - https://doi.org/10.1007/s00122-006-0402-3 SN - 0040-5752 VL - 113 SP - 1551 EP - 1561 PB - Springer CY - Berlin ER - TY - CHAP A1 - Lücking, Andy A1 - Rieser, Hannes A1 - Staudacher, Marc T1 - SDRT and multi-modal situated communication N2 - Classical SDRT (Asher and Lascarides, 2003) discussed essential features of dialogue like adjacency pairs or corrections and up-dating. Recent work in SDRT (Asher, 2002, 2005) aims at the description of natural dialogue. We use this work to model situated communication, i.e. dialogue, in which sub-sentential utterances and gestures (pointing and grasping) are used as conventional modes of communication. We show that in addition to cognitive modelling in SDRT, capturing mental states and speech-act related goals, special postulates are needed to extract meaning out of contexts. Gestural meaning anchors Discourse Referents in contextually given domains. Both sorts of meaning are fused with the meaning of fragments to get at fully developed dialogue moves. This task accomplished, the standard SDRT machinery, tagged SDRSs, rhetorical relations, the up-date mechanism, and the Maximize Discourse Coherence constraint generate coherent structures. In sum, meanings from different verbal and non-verbal sources are assembled using extended SDRT to form coherent wholes. Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-10348 ER - TY - CHAP A1 - DeVault, David A1 - Stone, Matthew T1 - Scorekeeping in an uncertain language game N2 - Received views of utterance context in pragmatic theory characterize the occurrent subjective states of interlocutors using notions like common knowledge or mutual belief. We argue that these views are not compatible with the uncertainty and robustness of context-dependence in humanhuman dialogue. We present an alternative characterization of utterance context as objective and normative. This view reconciles the need for uncertainty with received intuitions about coordination and meaning in context, and can directly inform computational approaches to dialogue. Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-10448 ER - TY - GEN A1 - Christmann, Olivia A1 - Warlouzet, Laurent T1 - Scenarios of "Europe-puissance" : the French foreign policy in Europe by 2020 N2 - Forum: EU-Diplomatie im Jahre 2020 KW - Europäische Verfassung KW - Supermacht KW - Politik KW - Wirtschaft KW - Regierungskooperation KW - European Constitution KW - superpower KW - politics KW - economy KW - intergovernmental cooperation Y1 - 2006 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-48399 ER - TY - CHAP A1 - Rossmanith, Eva A1 - Blaum, Niels A1 - Keil, Manfred A1 - Langerwisch, F. A1 - Meyer, Jork A1 - Popp, Alexander A1 - Schmidt, Michael A1 - Schultz, Christoph A1 - Schwager, Monika A1 - Vogel, Melanie A1 - Wasiolka, Bernd A1 - Jeltsch, Florian T1 - Scaling up local population dynamics to regional scales BT - an integrated approach N2 - In semi-arid savannas, unsustainable land use can lead to degradation of entire landscapes, e.g. in the form of shrub encroachment. This leads to habitat loss and is assumed to reduce species diversity. In BIOTA phase 1, we investigated the effects of land use on population dynamics on farm scale. In phase 2 we scale up to consider the whole regional landscape consisting of a diverse mosaic of farms with different historic and present land use intensities. This mosaic creates a heterogeneous, dynamic pattern of structural diversity at a large spatial scale. Understanding how the region-wide dynamic land use pattern affects the abundance of animal and plant species requires the integration of processes on large as well as on small spatial scales. In our multidisciplinary approach, we integrate information from remote sensing, genetic and ecological field studies as well as small scale process models in a dynamic region-wide simulation tool.