TY - GEN A1 - Delikostidis, Ioannis A1 - Engel, Juri A1 - Retsios, Bas A1 - Elzakker, Corné P.J.M. van A1 - Kraak, Menno-Jan A1 - Döllner, Jürgen Roland Friedrich T1 - Increasing the usability of pedestrian navigation interfaces by means of landmark visibility analysis T2 - Postprints der Universität Potsdam : Mathematisch Naturwissenschaftliche Reihe N2 - Communicating location-specific information to pedestrians is a challenging task which can be aided by user-friendly digital technologies. In this paper, landmark visibility analysis, as a means for developing more usable pedestrian navigation systems, is discussed. Using an algorithmic framework for image-based 3D analysis, this method integrates a 3D city model with identified landmarks and produces raster visibility layers for each one. This output enables an Android phone prototype application to indicate the visibility of landmarks from the user's actual position. Tested in the field, the method achieves sufficient accuracy for the context of use and improves navigation efficiency and effectiveness. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 599 KW - pedestrian navigation KW - landmark visibility KW - user-centred design KW - usability testing Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-415500 SN - 1866-8372 IS - 599 SP - 523 EP - 537 ER - TY - GEN A1 - Kaminski, Roland A1 - Schaub, Torsten H. A1 - Siegel, Anne A1 - Videla, Santiago T1 - Minimal intervention strategies in logical signaling networks with ASP T2 - Postprints der Universität Potsdam : Mathematisch Naturwissenschaftliche Reihe N2 - Proposing relevant perturbations to biological signaling networks is central to many problems in biology and medicine because it allows for enabling or disabling certain biological outcomes. In contrast to quantitative methods that permit fine-grained (kinetic) analysis, qualitative approaches allow for addressing large-scale networks. This is accomplished by more abstract representations such as logical networks. We elaborate upon such a qualitative approach aiming at the computation of minimal interventions in logical signaling networks relying on Kleene's three-valued logic and fixpoint semantics. We address this problem within answer set programming and show that it greatly outperforms previous work using dedicated algorithms. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 596 KW - systems biology KW - transduction KW - circuits KW - models KW - sets Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-415704 SN - 1866-8372 IS - 4-5 SP - 675 EP - 690 ER - TY - GEN A1 - Jacob, Gunnar A1 - Fleischhauer, Elisabeth A1 - Clahsen, Harald T1 - Allomorphy and affixation in morphological processing BT - a cross-modal priming study with late bilinguals T2 - Postprints der Universität Potsdam : Humanwissenschaftliche Reihe N2 - This study presents results from a cross-modal priming experiment investigating inflected verb forms of German. A group of late learners of German with Russian as their native language (L1) was compared to a control group of German L1 speakers. The experiment showed different priming patterns for the two participant groups. The L1 German data yielded a stem-priming effect for inflected forms involving regular affixation and a partial priming effect for irregular forms irrespective of stem allomorphy. By contrast, the data from the late bilinguals showed reduced priming effects for both regular and irregular forms. We argue that late learners rely more on lexically stored inflected word forms during word recognition and less on morphological parsing than native speakers. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 532 KW - bilingual processing KW - morphological priming KW - second language KW - German morphology Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-415408 SN - 1866-8364 IS - 532 ER - TY - GEN A1 - Ott, Susan A1 - Höhle, Barbara T1 - Verb inflection in German-learning children with typical and atypical language acquisition BT - the impact of subsyllabic frequencies T2 - Journal of Child Language N2 - Previous research has shown that high phonotactic frequencies facilitate the production of regularly inflected verbs in English-learning children with specific language impairment (SLI) but not with typical development (TD). We asked whether this finding can be replicated for German, a language with a much more complex inflectional verb paradigm than English. Using an elicitation task, the production of inflected nonce verb forms (3 rd person singular with -t suffix) with either high- or low-frequency subsyllables was tested in sixteen German-learning children with SLI (ages 4;1–5 ;1), sixteen TD-children matched for chronological age (CA) and fourteen TD- children matched for verbal age (VA) (ages 3;0–3 ;11). The findings revealed that children with SLI, but not CA- or VA-children, showed differential performance between the two types of verbs, producing more inflectional errors when the verb forms resulted in low-frequency subsyllables than when they resulted in high-frequency subsyllables, replicating the results from English-learning children. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 530 KW - english past tense KW - phonotactic probability KW - sentence repetition KW - nonword repetition KW - speaking children KW - impairment KW - morphology KW - infants KW - speech KW - words Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-416475 SN - 1866-8364 IS - 530 ER - TY - GEN A1 - Banbara, Mutsunori A1 - Soh, Takehide A1 - Tamura, Naoyuki A1 - Inoue, Katsumi A1 - Schaub, Torsten H. T1 - Answer set programming as a modeling language for course timetabling T2 - Postprints der Universität Potsdam : Mathematisch Naturwissenschaftliche Reihe N2 - The course timetabling problem can be generally defined as the task of assigning a number of lectures to a limited set of timeslots and rooms, subject to a given set of hard and soft constraints. The modeling language for course timetabling is required to be expressive enough to specify a wide variety of soft constraints and objective functions. Furthermore, the resulting encoding is required to be extensible for capturing new constraints and for switching them between hard and soft, and to be flexible enough to deal with different formulations. In this paper, we propose to make effective use of ASP as a modeling language for course timetabling. We show that our ASP-based approach can naturally satisfy the above requirements, through an ASP encoding of the curriculum-based course timetabling problem proposed in the third track of the second international timetabling competition (ITC-2007). Our encoding is compact and human-readable, since each constraint is individually expressed by either one or two rules. Each hard constraint is expressed by using integrity constraints and aggregates of ASP. Each soft constraint S is expressed by rules in which the head is the form of penalty (S, V, C), and a violation V and its penalty cost C are detected and calculated respectively in the body. We carried out experiments on four different benchmark sets with five different formulations. We succeeded either in improving the bounds or producing the same bounds for many combinations of problem instances and formulations, compared with the previous best known bounds. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 594 KW - answer set programming KW - educational timetabling KW - course timetabling Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-415469 SN - 1866-8372 IS - 594 SP - 783 EP - 798 ER - TY - GEN A1 - Chechkin, Aleksei V. A1 - Zaid, Irwin M. A1 - Lomholt, Michael A. A1 - Sokolov, Igor M. A1 - Metzler, Ralf T1 - Bulk-mediated surface diffusion on a cylinder in the fast exchange limit T2 - Postprints der Universität Potsdam : Mathematisch Naturwissenschaftliche Reihe N2 - In various biological systems and small scale technological applications particles transiently bind to a cylindrical surface. Upon unbinding the particles diffuse in the vicinal bulk before rebinding to the surface. Such bulk-mediated excursions give rise to an effective surface translation, for which we here derive and discuss the dynamic equations, including additional surface diffusion. We discuss the time evolution of the number of surface-bound particles, the effective surface mean squared displacement, and the surface propagator. In particular, we observe sub- and superdiffusive regimes. A plateau of the surface mean-squared displacement reflects a stalling of the surface diffusion at longer times. Finally, the corresponding first passage problem for the cylindrical geometry is analysed. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 593 KW - Bulk-mediated diffusion; KW - anomalous diffusion KW - Levy flights KW - stochastic processes Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-415480 SN - 1866-8372 IS - 593 SP - 114 EP - 126 ER - TY - GEN A1 - Fleischer, Julia A1 - Seyfried, Markus T1 - Drawing from the bargaining pool BT - determinants of ministerial selection in Germany T2 - Party politics N2 - This article expands our current knowledge about ministerial selection in coalition governments and analyses why ministerial candidates succeed in acquiring a cabinet position after general elections. It argues that political parties bargain over potential office-holders during government-formation processes, selecting future cabinet ministers from an emerging bargaining pool'. The article draws upon a new dataset comprising all ministrable candidates discussed by political parties during eight government-formation processes in Germany between 1983 and 2009. The conditional logit regression analysis reveals that temporal dynamics, such as the day she enters the pool, have a significant effect on her success in achieving a cabinet position. Other determinants of ministerial selection discussed in the existing literature, such as party and parliamentary expertise, are less relevant for achieving ministerial office. The article concludes that scholarship on ministerial selection requires a stronger emphasis for its endogenous nature in government-formation as well as the relevance of temporal dynamics in such processes. T3 - Zweitveröffentlichungen der Universität Potsdam : Wirtschafts- und Sozialwissenschaftliche Reihe - 87 KW - candidates KW - Germany KW - government-formation Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-404479 ER - TY - GEN A1 - Boll-Avetisyan, Natalie A1 - Kager, René T1 - OCP-PLACE in speech segmentation T2 - Postprints der Universität Potsdam : Humanwissenschaftliche Reihe N2 - OCP-Place, a cross-linguistically well-attested constraint against pairs of consonants with shared [place], is psychologically real. Studies have shown that the processing of words violating OCP-Place is inhibited. Functionalists assume that OCP arises as a consequence of low-level perception: a consonant following another with the same [place] cannot be faithfully perceived as an independent unit. If functionalist theories were correct, then lexical access would be inhibited if two homorganic consonants conjoin at word boundaries-a problem that can only be solved with lexical feedback. Here, we experimentally challenge the functional account by showing that OCP-Place can be used as a speech segmentation cue during pre-lexical processing without lexical feedback, and that the use relates to distributions in the input. In Experiment 1, native listeners of Dutch located word boundaries between two labials when segmenting an artificial language. This indicates a use of OCP-Labial as a segmentation cue, implying a full perception of both labials. Experiment 2 shows that segmentation performance cannot solely be explained by well-formedness intuitions. Experiment 3 shows that knowledge of OCP-Place depends on language-specific input: in Dutch, co-occurrences of labials are under-represented, but co-occurrences of coronals are not. Accordingly, Dutch listeners fail to use OCP-Coronal for segmentation. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 386 KW - artificial language learning KW - OCP-Place KW - phonotactics KW - speech segmentation KW - pre-lexical processing Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-404141 IS - 386 ER - TY - GEN A1 - Prot, Sara A1 - Gentile, Douglas A. A1 - Anderson, Craig A. A1 - Suzuki, Kanae A1 - Swing, Edward A1 - Lim, Kam Ming A1 - Horiuchi, Yukiko A1 - Jelic, Margareta A1 - Krahé, Barbara A1 - Liuqing, Wei A1 - Liau, Albert K. A1 - Khoo, Angeline A1 - Petrescu, Poesis Diana A1 - Sakamoto, Akira A1 - Tajima, Sachi A1 - Toma, Roxana Andreea A1 - Warburton, Wayne A1 - Zhang, Xuemin A1 - Lam, Ben Chun Pan T1 - Long-term relations among prosocial-media use, empathy, and prosocial behavior T2 - Postprints der Universität Potsdam : Humanwissenschaftliche Reihe N2 - Despite recent growth of research on the effects of prosocial media, processes underlying these effects are not well understood. Two studies explored theoretically relevant mediators and moderators of the effects of prosocial media on helping. Study 1 examined associations among prosocial- and violent-media use, empathy, and helping in samples from seven countries. Prosocial-media use was positively associated with helping. This effect was mediated by empathy and was similar across cultures. Study 2 explored longitudinal relations among prosocial-video-game use, violent-video-game use, empathy, and helping in a large sample of Singaporean children and adolescents measured three times across 2 years. Path analyses showed significant longitudinal effects of prosocial- and violent-video-game use on prosocial behavior through empathy. Latent-growth-curve modeling for the 2-year period revealed that change in video-game use significantly affected change in helping, and that this relationship was mediated by change in empathy. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 389 KW - mass media KW - cross-cultural differences KW - social behavior KW - prosocial media KW - violent media KW - prosocial behavior KW - empathy KW - helping KW - general learning model KW - prediction Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-404136 IS - 389 ER - TY - GEN A1 - Chmielewski, Anna K. A1 - Dumont, Hanna A1 - Trautwein, Ulrich T1 - Tracking effects depend on tracking type BT - an international comparison of students’ mathematics self-concept T2 - American educational research journal N2 - The aim of the present study was to examine how different types of tracking— between-school streaming, within-school streaming, and course-by-course tracking—shape students’ mathematics self-concept. This was done in an internationally comparative framework using data from the Programme for International Student Assessment (PISA). After controlling for individual and track mean achievement, results indicated that generally for students in course-by-course tracking, high-track students had higher mathematics self-concepts and low-track students had lower mathematics self-concepts. For students in between-school and within-school streaming, the reverse pattern was found. These findings suggest a solution to the ongoing debate about the effects of tracking on students’ academic self-concept and suggest that the reference groups to which students compare themselves differ according to the type of tracking. KW - academic self-concept KW - international comparison KW - reference groups KW - social comparison KW - tracking Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-404052 VL - 50 IS - 5 ER - TY - GEN A1 - Clahsen, Harald A1 - Balkhair, Loay A1 - Schutter, John-Sebastian A1 - Cunnings, Ian T1 - The time course of morphological processing in a second language T2 - Postprints der Universität Potsdam : Humanwissenschaftliche Reihe N2 - We report findings from psycholinguistic experiments investigating the detailed timing of processing morphologically complex words by proficient adult second (L2) language learners of English in comparison to adult native (L1) speakers of English. The first study employed the masked priming technique to investigate -ed forms with a group of advanced Arabic-speaking learners of English. The results replicate previously found L1/L2 differences in morphological priming, even though in the present experiment an extra temporal delay was offered after the presentation of the prime words. The second study examined the timing of constraints against inflected forms inside derived words in English using the eye-movement monitoring technique and an additional acceptability judgment task with highly advanced Dutch L2 learners of English in comparison to adult L1 English controls. Whilst offline the L2 learners performed native-like, the eye-movement data showed that their online processing was not affected by the morphological constraint against regular plurals inside derived words in the same way as in native speakers. Taken together, these findings indicate that L2 learners are not just slower than native speakers in processing morphologically complex words, but that the L2 comprehension system employs real-time grammatical analysis (in this case, morphological information) less than the L1 system. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 379 KW - compounds KW - derivational morphology KW - English as a seond language KW - inflectional morphology KW - late bilinguals KW - masked priming KW - morphology processing KW - past tense KW - shallow structure hypothesis Y1 - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-403684 IS - 379 ER - TY - GEN A1 - Wolff, Wanja A1 - Baumgarten, Franz A1 - Brand, Ralf T1 - Reduced self-control leads to disregard of an unfamiliar behavioral option BT - an experimental approach to the study of neuroenhancement N2 - Background: Neuroenhancement (NE), the use of psychoactive substances in order to enhance a healthy individual's cognitive functioning from a proficient to an even higher level, is prevalent in student populations. According to the strength model of self-control, people fail to self-regulate and fall back on their dominant behavioral response when finite self-control resources are depleted. An experiment was conducted to test the hypothesis that ego-depletion will prevent students who are unfamiliar with NE from trying it. Findings: 130 undergraduates, who denied having tried NE before (43% female, mean age = 22.76 +/- 4.15 years old), were randomly assigned to either an ego-depletion or a control condition. The dependent variable was taking an "energy-stick" (a legal nutritional supplement, containing low doses of caffeine, taurine and vitamin B), offered as a potential means of enhancing performance on the bogus concentration task that followed. Logistic regression analysis showed that ego-depleted participants were three times less likely to take the substance, OR = 0.37, p = .01. Conclusion: This experiment found that trying NE for the first time was more likely if an individual's cognitive capacities were not depleted. This means that mental exhaustion is not predictive for NE in students for whom NE is not the dominant response. Trying NE for the first time is therefore more likely to occur as a thoughtful attempt at self-regulation than as an automatic behavioral response in stressful situations. We therefore recommend targeting interventions at this inter-individual difference. Students without previous reinforcing NE experience should be provided with information about the possible negative health outcomes of NE. Reconfiguring structural aspects in the academic environment (e.g. lessening workloads) might help to deter current users. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 358 KW - Neuroenhancement KW - Self-control KW - Ego-depletion KW - Prevention Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401386 ER - TY - GEN A1 - Eccard, Jana A1 - Herde, Antje T1 - Seasonal variation in the behaviour of a short-lived rodent N2 - Background: Short lived, iteroparous animals in seasonal environments experience variable social and environmental conditions over their lifetime. Animals can be divided into those with a "young-of-the-year" life history (YY, reproducing and dying in the summer of birth) and an "overwinter" life history (OW, overwintering in a subadult state before reproducing next spring). We investigated how behavioural patterns across the population were affected by season and sex, and whether variation in behaviour reflects the variation in life history patterns of each season. Applications of pace-of-life (POL) theory would suggest that long-lived OW animals are shyer in order to increase survival, and YY are bolder in order to increase reproduction. Therefore, we expected that in winter and spring samples, when only OW can be sampled, the animals should be shyer than in summer and autumn, when both OW and YY animals can be sampled. We studied common vole (Microtus arvalis) populations, which express typical, intra-annual density fluctuation. We captured a total of 492 voles at different months over 3 years and examined boldness and activity level with two standardised behavioural experiments. Results: Behavioural variables of the two tests were correlated with each other. Boldness, measured as short latencies in both tests, was extremely high in spring compared to other seasons. Activity level was highest in spring and summer, and higher in males than in females. Conclusion: Being bold in laboratory tests may translate into higher risk-taking in nature by being more mobile while seeking out partners or valuable territories. Possible explanations include asset-protection, with OW animals being rather old with low residual reproductive value in spring. Therefore, OW may take higher risks during this season. Offspring born in spring encounter a lower population density and may have higher reproductive value than offspring of later cohorts. A constant connection between life history and animal personality, as suggested by the POL theory, however, was not found. Nevertheless, correlations of traits suggest the existence of animal personalities. In conclusion, complex patterns of population dynamics, seasonal variation in life histories, and variability of behaviour due to asset-protection may cause complex seasonal behavioural dynamics in a population. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 403 KW - animal personalities KW - boldness KW - life history KW - pace-of-life KW - POL KW - phenotypic plasticity KW - common vole Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401370 ER - TY - GEN A1 - Liesenjohann, Monique A1 - Liesenjohann, Thilo A1 - Palme, Rupert A1 - Eccard, Jana T1 - Differential behavioural and endocrine responses of common voles (Microtus arvalis) to nest predators and resource competitors N2 - Background: Adaptive behavioural strategies promoting co-occurrence of competing species are known to result from a sympatric evolutionary past. Strategies should be different for indirect resource competition (exploitation, e.g., foraging and avoidance behaviour) than for direct interspecific interference (e.g., aggression, vigilance, and nest guarding). We studied the effects of resource competition and nest predation in sympatric small mammal species using semi-fossorial voles and shrews, which prey on vole offspring during their sensitive nestling phase. Experiments were conducted in caged outdoor enclosures. Focus common vole mothers (Microtus arvalis) were either caged with a greater white-toothed shrew (Crocidura russula) as a potential nest predator, with an herbivorous field vole (Microtus agrestis) as a heterospecific resource competitor, or with a conspecific resource competitor. Results: We studied behavioural adaptations of vole mothers during pregnancy, parturition, and early lactation, specifically modifications of the burrow architecture and activity at burrow entrances. Further, we measured pre- and postpartum faecal corticosterone metabolites (FCMs) of mothers to test for elevated stress hormone levels. Only in the presence of the nest predator were prepartum FCMs elevated, but we found no loss of vole nestlings and no differences in nestling body weight in the presence of the nest predator or the heterospecific resource competitor. Although the presence of both the shrew and the field vole induced prepartum modifications to the burrow architecture, only nest predators caused an increase in vigilance time at burrow entrances during the sensitive nestling phase. Conclusion: Voles displayed an adequate behavioural response for both resource competitors and nest predators. They modified burrow architecture to improve nest guarding and increased their vigilance at burrow entrances to enhance offspring survival chances. Our study revealed differential behavioural adaptations to resource competitors and nest predators. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 402 KW - behavioural adaptations KW - small mammals KW - interspecific interactions KW - nest predation KW - stress response KW - faecal corticosterone metabolites KW - burrow system KW - shrews KW - voles Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401184 ER - TY - GEN A1 - Jeltsch, Florian A1 - Bonte, Dries A1 - Pe'er, Guy A1 - Reineking, Björn A1 - Leimgruber, Peter A1 - Balkenhol, Niko A1 - Schröder-Esselbach, Boris A1 - Buchmann, Carsten M. A1 - Müller, Thomas A1 - Blaum, Niels A1 - Zurell, Damaris A1 - Böhning-Gaese, Katrin A1 - Wiegand, Thorsten A1 - Eccard, Jana A1 - Hofer, Heribert A1 - Reeg, Jette A1 - Eggers, Ute A1 - Bauer, Silke T1 - Integrating movement ecology with biodiversity research BT - exploring new avenues to address spatiotemporal biodiversity dynamics N2 - Movement of organisms is one of the key mechanisms shaping biodiversity, e.g. the distribution of genes, individuals and species in space and time. Recent technological and conceptual advances have improved our ability to assess the causes and consequences of individual movement, and led to the emergence of the new field of ‘movement ecology’. Here, we outline how movement ecology can contribute to the broad field of biodiversity research, i.e. the study of processes and patterns of life among and across different scales, from genes to ecosystems, and we propose a conceptual framework linking these hitherto largely separated fields of research. Our framework builds on the concept of movement ecology for individuals, and demonstrates its importance for linking individual organismal movement with biodiversity. First, organismal movements can provide ‘mobile links’ between habitats or ecosystems, thereby connecting resources, genes, and processes among otherwise separate locations. Understanding these mobile links and their impact on biodiversity will be facilitated by movement ecology, because mobile links can be created by different modes of movement (i.e., foraging, dispersal, migration) that relate to different spatiotemporal scales and have differential effects on biodiversity. Second, organismal movements can also mediate coexistence in communities, through ‘equalizing’ and ‘stabilizing’ mechanisms. This novel integrated framework provides a conceptual starting point for a better understanding of biodiversity dynamics in light of individual movement and space-use behavior across spatiotemporal scales. By illustrating this framework with examples, we argue that the integration of movement ecology and biodiversity research will also enhance our ability to conserve diversity at the genetic, species, and ecosystem levels. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 401 KW - mobile links KW - species coexistence KW - community dynamics KW - biodiversity conservation KW - long distance movement KW - landscape genetics KW - individual based modeling Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401177 ER - TY - GEN A1 - Helfert, Susanne A1 - Warschburger, Petra T1 - The face of appearance-related social pressure BT - gender, age and body mass variations in peer and parental pressure during adolescence N2 - Background Appearance-related social pressure plays an important role in the development of a negative body image and self-esteem as well as severe mental disorders during adolescence (e.g. eating disorders, depression). Identifying who is particularly affected by social pressure can improve targeted prevention and intervention, but findings have either been lacking or controversial. Thus the aim of this study is to provide a detailed picture of gender, weight, and age-related variations in the perception of appearance-related social pressure by peers and parents. Methods 1112 German students between grades 7 and 9 (mean age: M = 13.38, SD = .81) filled in the Appearance-Related Social Pressure Questionnaire (German: FASD), which considers different sources (peers, parents) as well as various kinds of social pressure (e.g. teasing, modeling, encouragement). Results Girls were more affected by peer pressure, while gender differences in parental pressure seemed negligible. Main effects of grade-level suggested a particular increase in indirect peer pressure (e.g. appearance-related school and class norms) from early to middle adolescence. Boys and girls with higher BMI were particularly affected by peer teasing and exclusion as well as by parental encouragement to control weight and shape. Conclusion The results suggest that preventive efforts targeting body concerns and disordered eating should bring up the topic of appearance pressure in a school-based context and should strengthen those adolescents who are particularly at risk - in our study, girls and adolescents with higher weight status. Early adolescence and school transition appear to be crucial periods for these efforts. Moreover, the comprehensive assessment of appearance-related social pressure appears to be a fruitful way to further explore social risk-factors in the development of a negative body image. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 357 KW - peer pressure KW - parental pressure KW - adolescence KW - gender KW - age KW - BMI Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401155 ER - TY - GEN A1 - Wolff, Wanja A1 - Brand, Ralf T1 - Subjective stressors in school and their relation to neuroenhancement BT - a behavioral perspective on students' everyday life "doping" N2 - Background: The use of psychoactive substances to neuroenhance cognitive performance is prevalent. Neuroenhancement (NE) in everyday life and doping in sport might rest on similar attitudinal representations, and both behaviors can be theoretically modeled by comparable means-to-end relations (substance-performance). A behavioral (not substance-based) definition of NE is proposed, with assumed functionality as its core component. It is empirically tested whether different NE variants (lifestyle drug, prescription drug, and illicit substance) can be regressed to school stressors. Findings: Participants were 519 students (25.8 +/- 8.4 years old, 73.1% female). Logistic regressions indicate that a modified doping attitude scale can predict all three NE variants. Multiple NE substance abuse was frequent. Overwhelming demands in school were associated with lifestyle and prescription drug NE. Conclusions: Researchers should be sensitive for probable structural similarities between enhancement in everyday life and sport and systematically explore where findings from one domain can be adapted for the other. Policy makers should be aware that students might misperceive NE as an acceptable means of coping with stress in school, and help to form societal sensitivity for the topic of NE among our younger ones in general. T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - 356 KW - Neuroenhancement KW - stress KW - school KW - doping Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401131 ER - TY - GEN A1 - Schwarte, Sandra A1 - Brust, Henrike A1 - Steup, Martin A1 - Tiedemann, Ralph T1 - Intraspecific sequence variation and differential expression in starch synthase genes of Arabidopsis thaliana T2 - BMC Research Notes N2 - Background Natural accessions of Arabidopsis thaliana are a well-known system to measure levels of intraspecific genetic variation. Leaf starch content correlates negatively with biomass. Starch is synthesized by the coordinated action of many (iso)enzymes. Quantitatively dominant is the repetitive transfer of glucosyl residues to the non-reducing ends of α-glucans as mediated by starch synthases. In the genome of A. thaliana, there are five classes of starch synthases, designated as soluble starch synthases (SSI, SSII, SSIII, and SSIV) and granule-bound synthase (GBSS). Each class is represented by a single gene. The five genes are homologous in functional domains due to their common origin, but have evolved individual features as well. Here, we analyze the extent of genetic variation in these fundamental protein classes as well as possible functional implications on transcript and protein levels. Findings Intraspecific sequence variation of the five starch synthases was determined by sequencing the entire loci including promoter regions from 30 worldwide distributed accessions of A. thaliana. In all genes, a considerable number of nucleotide polymorphisms was observed, both in non-coding and coding regions, and several amino acid substitutions were identified in functional domains. Furthermore, promoters possess numerous polymorphisms in potentially regulatory cis-acting regions. By realtime experiments performed with selected accessions, we demonstrate that DNA sequence divergence correlates with significant differences in transcript levels. Conclusions Except for AtSSII, all starch synthase classes clustered into two or three groups of haplotypes, respectively. Significant difference in transcript levels among haplotype clusters in AtSSIV provides evidence for cis-regulation. By contrast, no such correlation was found for AtSSI, AtSSII, AtSSIII, and AtGBSS, suggesting trans-regulation. The expression data presented here point to a regulation by common trans-regulatory transcription factors which ensures a coordinated action of the products of these four genes during starch granule biosynthesis. The apparent cis-regulation of AtSSIV might be related to its role in the initiation of de novo biosynthesis of granules. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 400 KW - Arabidopsis thaliana KW - starch synthases KW - genetic variation KW - transcript level Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401128 ER - TY - GEN A1 - Pavesi, Laura A1 - Tiedemann, Ralph A1 - De Matthaeis, Elvira A1 - Ketmaier, Valerio T1 - Genetic connectivity between land and sea BT - the case of the beachflea Orchestia montagui (Crustacea, Amphipoda, Talitridae) in the Mediterranean Sea N2 - Introduction: We examined patterns of genetic divergence in 26 Mediterranean populations of the semi-terrestrial beachflea Orchestia montagui using mitochondrial (cytochrome oxidase subunit I), microsatellite (eight loci) and allozymic data. The species typically forms large populations within heaps of dead seagrass leaves stranded on beaches at the waterfront. We adopted a hierarchical geographic sampling to unravel population structure in a species living at the sea-land transition and, hence, likely subjected to dramatically contrasting forces. Results: Mitochondrial DNA showed historical phylogeographic breaks among Adriatic, Ionian and the remaining basins (Tyrrhenian, Western and Eastern Mediterranean Sea) likely caused by the geological and climatic changes of the Pleistocene. Microsatellites (and to a lesser extent allozymes) detected a further subdivision between and within the Western Mediterranean and the Tyrrhenian Sea due to present-day processes. A pattern of isolation by distance was not detected in any of the analyzed data set. Conclusions: We conclude that the population structure of O. montagui is the result of the interplay of two contrasting forces that act on the species population genetic structure. On one hand, the species semi-terrestrial life style would tend to determine the onset of local differences. On the other hand, these differences are partially counter-balanced by passive movements of migrants via rafting on heaps of dead seagrass leaves across sites by sea surface currents. Approximate Bayesian Computations support dispersal at sea as prevalent over terrestrial regionalism. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 399 KW - Orchestia montagui KW - Talitrids KW - Mediterranean Sea KW - Phylogeography KW - Mitochondrial DNA KW - Microsatellites KW - Allozymes KW - Approximate Bayesian Computation Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-401110 ER - TY - GEN A1 - Kroll, Alexander A1 - Vogel, Dominik T1 - The PSM-leadership fit BT - a model of performance information use T2 - Postprints der Universität Potsdam : Wirtschafts- und Sozialwissenschaftliche Reihe N2 - This article examines the use of performance information by public managers. It conceptualizes purposeful data use as a type of extra-role behaviour which requires additional effort on the part of the managers and which is not extrinsically rewarded. The article sheds light on one potential antecedent of performance information use – the motivation of the users. It argues that we can observe high levels of data use if managers driven by public service motivation (PSM) work under transformational leaders. Using a needs-supply perspective on supervisors and followers we suggest that there is a PSM-leadership fit which fosters the performance of this extra-role behaviour. The article is based on data from German local government and its findings contribute to the literatures on PSM as well as on performance management. T3 - Zweitveröffentlichungen der Universität Potsdam : Wirtschafts- und Sozialwissenschaftliche Reihe - 77 KW - Public Service Motivation KW - Performance Information Use KW - Leadership KW - Transformational Leadership KW - Person-Organization Fit Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-100853 SN - 1867-5808 IS - 77 ER - TY - GEN A1 - Inal, Sahika A1 - Kölsch, Jonas D. A1 - Chiappisi, Leonardo A1 - Janietz, Dietmar A1 - Gradzielski, Michael A1 - Laschewsky, André A1 - Neher, Dieter T1 - Structure-related differences in the temperature-regulated fluorescence response of LCST type polymers N2 - We demonstrate new fluorophore-labelled materials based on acrylamide and on oligo(ethylene glycol) (OEG) bearing thermoresponsive polymers for sensing purposes and investigate their thermally induced solubility transitions. It is found that the emission properties of the polarity-sensitive (solvatochromic) naphthalimide derivative attached to three different thermoresponsive polymers are highly specific to the exact chemical structure of the macromolecule. While the dye emits very weakly below the LCST when incorporated into poly(N-isopropylacrylamide) (pNIPAm) or into a polyacrylate backbone bearing only short OEG side chains, it is strongly emissive in polymethacrylates with longer OEG side chains. Heating of the aqueous solutions above their cloud point provokes an abrupt increase of the fluorescence intensity of the labelled pNIPAm, whereas the emission properties of the dye are rather unaffected as OEG-based polyacrylates and methacrylates undergo phase transition. Correlated with laser light scattering studies, these findings are ascribed to the different degrees of pre-aggregation of the chains at low temperatures and to the extent of dehydration that the phase transition evokes. It is concluded that although the temperature-triggered changes in the macroscopic absorption characteristics, related to large-scale alterations of the polymer chain conformation and aggregation, are well detectable and similar for these LCST-type polymers, the micro-environment provided to the dye within each polymer network differs substantially. Considering sensing applications, this finding is of great importance since the temperature-regulated fluorescence response of the polymer depends more on the macromolecular architecture than the type of reporter fluorophore. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 251 KW - anionic polymerizations KW - dilute aqueous-solutions KW - ether methacrylates KW - n-isopropylacrylamide KW - oligo(ethylene glycol) methacrylate KW - phase-transitions KW - protein interactions KW - solvatochromic fluorophore KW - thermoresponsive polymers KW - to-coil transition Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95379 SP - 6603 EP - 6612 ER - TY - GEN A1 - Li, Hongguang A1 - Babu, Sukumaran Santhosh A1 - Turner, Sarah T. A1 - Neher, Dieter A1 - Hollamby, Martin J. A1 - Seki, Tomohiro A1 - Yagai, Shiki A1 - Deguchi, Yonekazu A1 - Möhwald, Helmuth A1 - Nakanishi, Takashi T1 - Alkylated-C60 based soft materials BT - regulation of selfassembly and optoelectronic properties by chain branching N2 - Derivatization of fullerene (C60) with branched aliphatic chains softens C60-based materials and enables the formation of thermotropic liquid crystals and room temperature nonvolatile liquids. This work demonstrates that by carefully tuning parameters such as type, number and substituent position of the branched chains, liquid crystalline C60 materials with mesophase temperatures suited for photovoltaic cell fabrication and room temperature nonvolatile liquid fullerenes with tunable viscosity can be obtained. In particular, compound 1, with branched chains, exhibits a smectic liquid crystalline phase extending from 84 °C to room temperature. Analysis of bulk heterojunction (BHJ) organic solar cells with a ca. 100 nm active layer of compound 1 and poly(3-hexylthiophene) (P3HT) as an electron acceptor and an electron donor, respectively, reveals an improved performance (power conversion efficiency, PCE: 1.6 ± 0.1%) in comparison with another compound, 10 (PCE: 0.5 ± 0.1%). The latter, in contrast to 1, carries linear aliphatic chains and thus forms a highly ordered solid lamellar phase at room temperature. The solar cell performance of 1 blended with P3HT approaches that of PCBM/P3HT for the same active layer thickness. This indicates that C60 derivatives bearing branched tails are a promising class of electron acceptors in soft (flexible) photovoltaic devices. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 250 Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95358 SP - 1943 EP - 1951 ER - TY - GEN A1 - Inal, Sahika A1 - Kölsch, Jonas D. A1 - Sellrie, Frank A1 - Schenk, Jörg A. A1 - Wischerhoff, Erik A1 - Laschewsky, André A1 - Neher, Dieter T1 - A water soluble fluorescent polymer as a dual colour sensor for temperature and a specific protein N2 - We present two thermoresponsive water soluble copolymers prepared via free radical statistical copolymerization of N-isopropylacrylamide (NIPAm) and of oligo(ethylene glycol) methacrylates (OEGMAs), respectively, with a solvatochromic 7-(diethylamino)-3-carboxy-coumarin (DEAC)- functionalized monomer. In aqueous solutions, the NIPAm-based copolymer exhibits characteristic changes in its fluorescence profile in response to a change in solution temperature as well as to the presence of a specific protein, namely an anti-DEAC antibody. This polymer emits only weakly at low temperatures, but exhibits a marked fluorescence enhancement accompanied by a change in its emission colour when heated above its cloud point. Such drastic changes in the fluorescence and absorbance spectra are observed also upon injection of the anti-DEAC antibody, attributed to the specific binding of the antibody to DEAC moieties. Importantly, protein binding occurs exclusively when the polymer is in the well hydrated state below the cloud point, enabling a temperature control on the molecular recognition event. On the other hand, heating of the polymer–antibody complexes releases a fraction of the bound antibody. In the presence of the DEAC-functionalized monomer in this mixture, the released antibody competitively binds to the monomer and the antibody-free chains of the polymer undergo a more effective collapse and inter-aggregation. In contrast, the emission properties of the OEGMA-based analogous copolymer are rather insensitive to the thermally induced phase transition or to antibody binding. These opposite behaviours underline the need for a carefully tailored molecular design of responsive polymers aimed at specific applications, such as biosensing. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 249 KW - intramolecular charge-transfer KW - phase-transitions KW - responsive polymers KW - sensitivity KW - thermometer KW - dyes KW - modulation KW - assemblies KW - antibodies KW - binding Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95336 SP - 6373 EP - 6381 ER - TY - GEN A1 - Men, Yongjun A1 - Siebenbürger, Miriam A1 - Qiu, Xunlin A1 - Antonietti, Markus A1 - Yuan, Jiayin T1 - Low fractions of ionic liquid or poly(ionic liquid) can activate polysaccharide biomass into shaped, flexible and fire-retardant porous carbons N2 - Sugar-based molecules and polysaccharide biomass can be turned into porous functional carbonaceous products at comparably low temperatures of 400 °C under a nitrogen atmosphere in the presence of an ionic liquid (IL) or a poly(ionic liquid) (PIL). The IL and PIL act as “activation agents” with own structural contribution, and effectively promote the conversion and pore generation in the biomaterials even at a rather low doping ratio (7 wt%). In addition, this “induced carbonization” and pore forming phenomenon enables the preservation of the biotemplate shape to the highest extent and was employed to fabricate shaped porous carbonaceous materials from carbohydrate-based biotemplates, exemplified here with cellulose filter membranes, coffee filter paper and natural cotton. These carbonized hybrids exhibit comparably good mechanical properties, such as bendability of membranes or shape recovery of foams. Moreover, the nitrogen atoms incorporated in the final products from the IL/PIL precursors further improve the oxidation stability in the fire-retardant tests. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 248 Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95250 SP - 11887 EP - 11887 ER - TY - GEN A1 - Di Florio, Giuseppe A1 - Bründermann, Erik A1 - Yadavalli, Nataraja Sekhar A1 - Santer, Svetlana A1 - Havenith, Martina T1 - Polarized 3D Raman and nanoscale near-field optical microscopy of optically inscribed surface relief gratings BT - chromophore orientation in azo-doped polymer films N2 - We have used polarized confocal Raman microspectroscopy and scanning near-field optical microscopy with a resolution of 60 nm to characterize photoinscribed grating structures of azobenzene doped polymer films on a glass support. Polarized Raman microscopy allowed determining the reorientation of the chromophores as a function of the grating phase and penetration depth of the inscribing laser in three dimensions. We found periodic patterns, which are not restricted to the surface alone, but appear also well below the surface in the bulk of the material. Near-field optical microscopy with nanoscale resolution revealed lateral two-dimensional optical contrast, which is not observable by atomic force and Raman microscopy. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 247 KW - glass-transition temperature KW - holographic diffraction gratings KW - chain azobenzene polymers KW - molecular-reorientation KW - amorphous polymers KW - data-storage KW - thin-films KW - dye KW - photoisomerization KW - alignment Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95233 SP - 1544 EP - 1554 ER - TY - GEN A1 - McQuade, D. Tyler A1 - O'Brien, Alexander G. A1 - Dörr, Markus A1 - Rajaratnam, Rajathees A1 - Eisold, Ursula A1 - Monnanda, Bopanna A1 - Nobuta, Tomoya A1 - Löhmannsröben, Hans-Gerd A1 - Meggers, Eric A1 - Seeberger, Peter H. T1 - Continuous synthesis of pyridocarbazoles and initial photophysical and bioprobe characterization N2 - Pyridocarbazoles when ligated to transition metals yield high affinity kinase inhibitors. While batch photocyclizations enable the synthesis of these heterocycles, the non-oxidative Mallory reaction only provides modest yields and difficult to purify mixtures. We demonstrate here that a flow-based Mallory cyclization provides superior results and enables observation of a clear isobestic point. The flow method allowed us to rapidly synthesize ten pyridocarbazoles and for the first time to document their interesting photophysical attributes. Preliminary characterization reveals that these molecules might be a new class of fluorescent bioprobe. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 246 KW - protein-kinase inhibitors KW - continuous-flow KW - photochemical synthesis KW - light KW - efficient KW - phenanthrenes KW - complexes Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95214 SP - 4067 EP - 4070 ER - TY - GEN A1 - Thete, Aniket A1 - Rojas, Oscar A1 - Neumeyer, David A1 - Koetz, Joachim A1 - Dujardin, Erik T1 - Ionic liquid-assisted morphosynthesis of gold nanorods using polyethyleneimine-capped seeds N2 - Seed-mediated gold nanorods with tunable lengths are prepared using new polyethyleneimine-capped gold nanoparticles synthesized in ionic liquid. The effect of polyethyleneimine and ionic liquid during nanorod growth is investigated and shows a marked effect on their final aspect ratio. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 245 KW - aqueous-solution KW - aspect-ratio KW - cationic surfactants KW - chemical-synthesis KW - delivery KW - metal nanoparticles KW - mixtures KW - shape KW - silver nanowires KW - surface-plasmon resonance Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95196 SP - 14294 EP - 14298 ER - TY - GEN A1 - Junginger, Mathias A1 - Kübel, Christian A1 - Schacher, Felix H. A1 - Müller, Axel H. E. A1 - Taubert, Andreas T1 - Crystal structure and chemical composition of biomimetic calcium phosphate nanofibers N2 - Calcium phosphate nanofibers with a diameter of only a few nanometers and a cotton-ball-like aggregate morphology have been reported several times in the literature. Although fiber formation seems reproducible in a variety of conditions, the crystal structure and chemical composition of the fibers have been elusive. Using scanning transmission electron microscopy, low dose electron (nano)diffraction, energy-dispersive X-ray spectroscopy, and energy-filtered transmission electron microscopy, we have assigned crystal structures and chemical compositions to the fibers. Moreover, we demonstrate that the mineralization process yields true polymer/calcium phosphate hybrid materials where the block copolymer template is closely associated with the calcium phosphate. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 244 KW - air-water-interface KW - polycationic monolayer KW - mineralization beneath KW - block-copolymers KW - aqueous-solution KW - morphology KW - orthophosphates KW - biomaterials KW - nucleation KW - clusters Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95176 SP - 11301 EP - 11308 ER - TY - GEN A1 - Thiel, Kerstin A1 - Zehbe, Rolf A1 - Roeser, Jerômé A1 - Strauch, Peter A1 - Enthaler, Stephan A1 - Thomas, Arne T1 - A polymer analogous reaction for the formation of imidazolium and NHC based porous polymer networks N2 - A polymer analogous reaction was carried out to generate a porous polymeric network with N-heterocyclic carbenes (NHC) in the polymer backbone. Using a stepwise approach, first a polyimine network is formed by polymerization of the tetrafunctional amine tetrakis(4-aminophenyl)methane. This polyimine network is converted in the second step into polyimidazolium chloride and finally to a polyNHC network. Furthermore a porous Cu(II)-coordinated polyNHC network can be generated. Supercritical drying generates polymer networks with high permanent surface areas and porosities which can be applied for different catalytic reactions. The catalytic properties were demonstrated for example in the activation of CO2 or in the deoxygenation of sulfoxides to the corresponding sulfides. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 243 KW - covalent organic framework KW - n-heterocyclic carbenes KW - carbon-dioxide KW - intrinsic microporosity KW - heterogeneous catalysis KW - sulfoxides KW - reduction KW - complex KW - system KW - transformation Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95118 SP - 1848 EP - 1856 ER - TY - GEN A1 - Schmidt, Bernd A1 - Elizarov, Nelli A1 - Berger, René A1 - Hölter, Frank T1 - Scope and limitations of the Heck–Matsuda-coupling of phenol diazonium salts and styrenes BT - a protecting-group economic synthesis of phenolic stilbenes N2 - 4-Phenol diazonium salts undergo Pd-catalyzed Heck reactions with various styrenes to 4’-hydroxy stilbenes. In almost all cases higher yields and fewer side products were observed, compared to the analogous 4-methoxy benzene diazonium salts. In contrast, the reaction fails completely with 2- and 3-phenol diazonium salts. For these substitution patterns the methoxy-substituted derivatives are superior. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 242 KW - catalyzed cross metathesis KW - o bond formation KW - arenediazonium salts KW - stereoselective-synthesis KW - arylboronic acids KW - substituted stilbenes KW - aryldiazonium salts KW - palladium catalyst KW - trans-stilbenes KW - boronic acid Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95070 SP - 3674 EP - 3691 ER - TY - GEN A1 - Schmidt, Bernd A1 - Hauke, Sylvia T1 - Cross metathesis of allyl alcohols BT - how to suppress and how to promote double bond isomerization N2 - Under standard conditions the cross metathesis of allyl alcohols and methyl acrylate is accompanied by the formation of ketones, resulting from uncontrolled and undesired double bond isomerization. By conducting the CM in the presence of phenol, the catalyst loading and the reaction time required for quantiative conversion can be reduced, and isomerization can be suppressed. On the other hand, consecutive isomerization can be deliberately promoted by evaporating excess methyl acrylate after completing cross metathesis and by adding a base or silane as chemical triggers. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 241 KW - ring-closing metathesis KW - de-novo synthesis KW - catalyzed redox isomerization KW - carbohydrate-based oxepines KW - diels-alder reaction KW - olefin-metathesis KW - in-situ KW - ruthenium carbene KW - alkynol cycloisomerization KW - carbonyl-compounds Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95037 SP - 4194 EP - 4206 ER - TY - GEN A1 - Winter, Alette A1 - Thiel, Kerstin A1 - Zabel, André A1 - Klamroth, Tillmann A1 - Pöppl, Andreas A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Taubert, Andreas A1 - Strauch, Peter T1 - Tetrahalidocuprates(II) – structure and EPR spectroscopy BT - Part 2: tetrachloridocuprates(II) N2 - We present and discuss the results of crystallographic and electron paramagnetic resonance (EPR) spectroscopic analyses of five tetrachloridocuprate(II) complexes to supply a useful tool for the structural characterisation of the [CuCl4]2− moiety in the liquid state, for example in ionic liquids, or in solution. Bis(benzyltriethylammonium)-, bis(trimethylphenylammonium)-, bis(ethyltriphenylphosphonium)-, bis(benzyltriphenylphosphonium)-, and bis(tetraphenylarsonium)tetrachloridocuprate(II) were synthesised and characterised by elemental, IR, EPR and X-ray analyses. The results of the crystallographic analyses show distorted tetrahedral coordination geometry of all [CuCl4]2− anions in the five complexes and prove that all investigated complexes are stabilised by hydrogen bonds of different intensities. Despite the use of sterically demanding ammonium, phosphonium and arsonium cations to obtain the separation of the paramagnetic Cu(II) centres for EPR spectroscopy no hyperfine structure was observed in the EPR spectra but the principal values of the electron Zeeman tensor, g∥ and g⊥, could be determined. With these EPR data and the crystallographic parameters we were able to carry out a correlation study to anticipate the structural situation of tetrachloridocuprates in different physical states. This correlation is in good agreement with DFT calculations. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 240 KW - electron-spin resonance KW - liquid-crystal precursors KW - copper(II) halide salts KW - ionic liquid KW - square planar KW - tetrachlorocuprate(II) salts KW - molecular-structure KW - magnetic-properties KW - paramagnetic-resonance KW - temperature phase Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-95012 SP - 1019 EP - 1030 ER - TY - GEN A1 - Barbosa Pfannes, Eva Katharina A1 - Anielski, Alexander A1 - Gerhardt, Matthias A1 - Beta, Carsten T1 - Intracellular photoactivation of caged cGMP induces myosin II and actin responses in motile cells N2 - Cyclic GMP (cGMP) is a ubiquitous second messenger in eukaryotic cells. It is assumed to regulate the association of myosin II with the cytoskeleton of motile cells. When cells of the social amoeba Dictyostelium discoideum are exposed to chemoattractants or to increased osmotic stress, intracellular cGMP levels rise, preceding the accumulation of myosin II in the cell cortex. To directly investigate the impact of intracellular cGMP on cytoskeletal dynamics in a living cell, we released cGMP inside the cell by laser-induced photo-cleavage of a caged precursor. With this approach, we could directly show in a live cell experiment that an increase in intracellular cGMP indeed induces myosin II to accumulate in the cortex. Unexpectedly, we observed for the first time that also the amount of filamentous actin in the cell cortex increases upon a rise in the cGMP concentration, independently of cAMP receptor activation and signaling. We discuss our results in the light of recent work on the cGMP signaling pathway and suggest possible links between cGMP signaling and the actin system. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 239 KW - cyclic-gmp KW - dictyostelium-discoideum KW - ena/vasp proteins KW - osmotic-stress KW - chemotaxis KW - phosphorylation KW - amp KW - cytoskeleton KW - oscillations KW - chemoattractant Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94984 SP - 1456 EP - 1463 ER - TY - GEN A1 - Schönborn, Jan Boyke A1 - Hartke, Bernd T1 - Photochemical dynamics of E-methylfurylfulgide BT - kinematic effects on photorelaxation dynamics of furylfulgides N2 - With the present theoretical study of the photochemical switching of E-methylfurylfulgide we contribute an important step towards the understanding of the photochemical processes in furylfulgide-related molecules. We have carried out large-scale, full-dimensional direct semiempirical configuration-interaction surface-hopping dynamics of the photoinduced ring-closure reaction. Simulated static and dynamical UV/Vis-spectra show good agreement with experimental data of the same molecule. By a careful investigation of our dynamical data, we were able to identify marked differences to the dynamics of the previously studied E-isopropylfurylfulgide. With our simulations we can not only reproduce the experimentally observed quantum yield differences qualitatively but we can also pinpoint two reasons for them: kinematics and pre-orientation. With our analysis, we thus offer straightforward molecular explanations for the high sensitivity of the photodynamics towards seemingly minor changes in molecular constitution. Beyond the realm of furylfulgides, these insights provide additional guidance to the rational design of photochemically switchable molecules. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 237 KW - decay dynamics KW - fulgides KW - implementation KW - molecular-dynamics KW - photoinduced nonadiabatic dynamics KW - photoisomerization KW - ring-closure KW - semiempirical methods KW - spectroscopy KW - state Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94516 SP - 2483 EP - 2490 ER - TY - GEN A1 - Banerjee, Shiladitya A1 - Saalfrank, Peter T1 - Vibrationally resolved absorption, emission and resonance Raman spectra of diamondoids BT - a study based on time-dependent correlation functions N2 - The time-dependent approach to electronic spectroscopy, as popularized by Heller and coworkers in the 1980's, is applied here in conjunction with linear-response, time-dependent density functional theory to study vibronic absorption, emission and resonance Raman spectra of several diamondoids. Two-state models, the harmonic and the Condon approximations, are used for the calculations, making them easily applicable to larger molecules. The method is applied to nine pristine lower and higher diamondoids: adamantane, diamantane, triamantane, and three isomers each of tetramantane and pentamantane. We also consider a hybrid species “Dia = Dia” – a shorthand notation for a recently synthesized molecule comprising two diamantane units connected by a C[double bond, length as m-dash]C double bond. We resolve and interpret trends in optical and vibrational properties of these molecules as a function of their size, shape, and symmetry, as well as effects of “blending” with sp2-hybridized C-atoms. Time-dependent correlation functions facilitate the computations and shed light on the vibrational dynamics following electronic transitions. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 238 KW - adamantane KW - models KW - molecules KW - states KW - thermochemistry Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94542 SP - 144 EP - 158 ER - TY - GEN A1 - Cherstvy, Andrey G. A1 - Metzler, Ralf T1 - Population splitting, trapping, and non-ergodicity in heterogeneous diffusion processes N2 - We consider diffusion processes with a spatially varying diffusivity giving rise to anomalous diffusion. Such heterogeneous diffusion processes are analysed for the cases of exponential, power-law, and logarithmic dependencies of the diffusion coefficient on the particle position. Combining analytical approaches with stochastic simulations, we show that the functional form of the space-dependent diffusion coefficient and the initial conditions of the diffusing particles are vital for their statistical and ergodic properties. In all three cases a weak ergodicity breaking between the time and ensemble averaged mean squared displacements is observed. We also demonstrate a population splitting of the time averaged traces into fast and slow diffusers for the case of exponential variation of the diffusivity as well as a particle trapping in the case of the logarithmic diffusivity. Our analysis is complemented by the quantitative study of the space coverage, the diffusive spreading of the probability density, as well as the survival probability. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 236 KW - anomalous diffusion KW - disordered media KW - fractional dynamics KW - infection pathway KW - inhomogeneous-media KW - intracellular-transport KW - langevin equation KW - living cells KW - random-walks KW - single-particle tracking Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94468 SP - 20220 EP - 20235 ER - TY - GEN A1 - Mondal, Suvendu Sekhar A1 - Bhunia, Asamanjoy A1 - Demeshko, Serhiy A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Janiak, Christoph A1 - Holdt, Hans-Jürgen T1 - Synthesis of a Co(II)–imidazolate framework from an anionic linker precursor BT - gas-sorption and magnetic properties N2 - A Co(II)–imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N2, CO2, CH4 and H2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 235 KW - building-blocks KW - carbon-dioxide capture KW - exchange KW - ionic liquids KW - ionothermal synthesis KW - ligand KW - metal-organic frameworks KW - solvent KW - surface KW - zeolitic imidazolate frameworks Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94424 SP - 39 EP - 42 ER - TY - GEN A1 - Mondal, Suvendu Sekhar A1 - Dey, Subarna A1 - Baburin, Igor A. A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Seifert, Gotthard A1 - Janiak, Christoph A1 - Holdt, Hans-Jürgen T1 - Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal–organic frameworks with flexible ethoxy substituent N2 - A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 234 KW - adsorption KW - behavior KW - carbon-dioxide KW - crystals KW - gases KW - ligand KW - pressure KW - selectivity KW - temperature KW - zinc Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94360 SP - 9394 EP - 9399 ER - TY - GEN A1 - Mondal, Suvendu Sekhar A1 - Bhunia, Asamanjoy A1 - Baburin, Igor A. A1 - Jäger, Christian A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Seifert, Gotthard A1 - Janiak, Christoph A1 - Holdt, Hans-Jürgen T1 - Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity N2 - A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 233 KW - adsorption KW - capacity KW - carbon-dioxide capture KW - coordination polymer KW - flexibility KW - hydrogen storage KW - ligand KW - metal-organic frameworks KW - mixed-matrix membranes KW - separation Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94341 SP - 7599 EP - 7601 ER - TY - GEN A1 - Richter, Michael A1 - van Hout, Roeland T1 - Interpreting resultative sentences in German BT - stages in L1 acquisition T2 - Postprints der Universität Potsdam : Philosophische Reihe N2 - This article presents the results of a study on the interpretation and acceptance of adjectival resultatives of German children between 6 and 9 years of age and adults. These results brought to light significant differences, due to age, in the interpretation and acceptance of these resultatives, that is to say, sentences with an adjective in the final position. The youngest participants were prone to accept ungrammatical sentences by assigning a resultative meaning. The ungrammaticality of the sentences in question was not due to semantic inconsistencies but to violations of the selectional properties of verbs, as for instance in *die Kinder erschrecken die Katze ängstlich ‘the children frighten the cat scared’. In contrast, the adults rejected or amended those sentences. The conclusion is (a) that the children seemed to rely on the sentence structure as a primary cue to compute the meaning of an utterance and (b) that, in contrast with adults, the youngest children in particular had not yet learned the relevant semantic properties of verbs that determine the selectional restrictions and thus the syntactic options of verbs. This means that differences in interpretation and acceptance of sentences are due to differences in knowledge of semantic verb properties between adults and children. The relevant semantic knowledge increases in gradual stages during language acquisition. T3 - Zweitveröffentlichungen der Universität Potsdam : Philosophische Reihe - 111 KW - first language acquisition KW - frame compliance KW - grammatical judgments KW - verb classes KW - resultative sentences Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-93974 SN - 1866-8380 IS - 111 ER - TY - GEN A1 - Kranich, Svenja T1 - Functional layering and the English progressive T2 - Postprints der Universität Potsdam : Philosophische Reihe N2 - In this article, it will be argued that the concept of functional layering – an extension of Hopper’s (1991) concept of layering – can be fruitfully applied to understand the mechanisms behind the sometimes large and messy looking synchronic picture of diverse meanings which one and the same construction can fulfill at a particular point in time. The concept will be used to account for the meaning spectrum of the present-day English progressive, which, it will be argued, no monosemic approach to date can account for. Taking a look at the diachrony of the construction will help to reveal that the various “exceptions” found in the use of the progressive can be understood as reflections of different stages in its development. Older, less grammaticalized or less well-defined usage patterns thus often survive in certain restricted niches next to the newer, more grammaticalized or more clear-cut functions, representing different diachronic layers. In addition to this diachronic motivation for synchronic meaning variety, the article will also address the crucial question of how a present-day hearer of a progressive form is able to decode the specific meaning intended by the speaker based on contextual clues. The article ends with some suggestions for further applications of the concept of functional layering. T3 - Zweitveröffentlichungen der Universität Potsdam : Philosophische Reihe - 110 KW - grammaticalization KW - subjectification KW - semantic change KW - the English progressive construction KW - polysemy Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-93961 SN - 1866-8380 IS - 110 ER - TY - GEN A1 - Wiemann, Dirk T1 - Cities of the Mind – Villages of the Mind BT - Imagining Urbanity in Contemporary India T2 - Postprints der Universität Potsdam : Philosophische Reihe N2 - Deep into the second half of the twentieth century the traditionalist definition of India as a country of villages remained dominant in official political rhetoric as well as cultural production. In the past two decades or so, this ruralist paradigm has been effectively superseded by a metropolitan imaginary in which the modern, globalised megacity increasingly functions as representative of India as a whole. Has the village, then, entirely vanished from the cultural imaginary in contemporary India? Addressing economic practices from upper-class consumerism to working-class family support strategies, this paper attempts to trace how ‘the village’ resurfaces or survives as a cultural reference point in the midst of the urban. T3 - Zweitveröffentlichungen der Universität Potsdam : Philosophische Reihe - 109 Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-93951 SN - 1866-8380 IS - 109 ER - TY - GEN A1 - Degen, Andreas T1 - Hans Ulrich Seeber, Literarische Faszination in England um 1900 / [rezensiert von] Andreas Degen N2 - Rezensiertes Werk: Hans Ulrich Seeber: Literarische Faszination in England um 1900. - Heidelberg: Winter, 2012. - (Anglistische Forschungen ; 426) T3 - Zweitveröffentlichungen der Universität Potsdam : Philosophische Reihe - 108 Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-93935 SP - 217 EP - 222 ER - TY - GEN A1 - Gatzhammer, Stefan T1 - Commento alla sentenza del Landgericht Köln del 7 maggio 2012 in tema di circoncisione e commento alla nuova normativa § 1631d del codice civile tedesco (BGB) N2 - Kommentar zu § 1631d BGB (Beschneidung aus religiösen Gründen, elterliches Sorgerecht), Kommentar zum Urteil des Landgerichts Köln vom 7. Mai 2012 (Strafrecht, Religionsfreiheit) N2 - In May 2012 a misleading decision of the Landgericht (Court of Appeal) Cologne declared that male circumcision in children amounts to be a criminal offence, even if performed lege artis and with the consent of the parents. The article pays attention to the new legislation of December 2012 introduced into the BGB as a legal framework of male circumcision with regard to the right of freedom of religion and the parental rights in education especially for Jewish and Muslims in Germany. T3 - Zweitveröffentlichungen der Universität Potsdam : Rechtswissenschaftliche Reihe - 2 KW - Beschneidung aus religiösen Motiven KW - Religionsrecht KW - BGB KW - elterliches Sorgerecht KW - Strafrecht KW - male circumcision KW - religious law KW - German civil code KW - legal custody KW - criminal law Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-72075 ER - TY - GEN A1 - Schwarz, Wolfgang T1 - Iran: Wandel durch Annäherung! N2 - Die Frage nach einer veränderten Strategie des Westens im Atomkonflikt mit dem Iran ist wieder virulent. Bereits auf seiner ersten Pressekonferenz hat der als gemäßigt geltende neue iranische Präsident Hassan Ruhani mehr Transparenz über das Atomprogramm seines Landes in Aussicht gestellt. Ob sich damit ein Fenster der Möglichkeiten öffnet, den Konflikt doch noch einvernehmlich und vor allem friedlich zu lösen, muss sich erweisen. KW - Iran KW - USA KW - Rohani KW - Atomwaffen Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-71175 ER - TY - GEN A1 - Roll, Stephan T1 - Der bezahlte Putsch : Golfspiele am Nil als Herausforderung für den Westen N2 - Die westliche Diplomatie wurde mit der Absetzung des gewählten Präsidenten Mohammed Mursi, der Verhaftung der Führungsriege der Muslimbruderschaft und der Aussetzung der Verfassung durch die ägyptische Militärführung vor vollendete Tatsachen gestellt. Damit sind die Bemühungen Deutschlands, der EU und der USA um eine politische Lösung, die alle Kräfte einbezieht, vorerst gescheitert. Gab es anfangs die Hoffnung, dass der Militärputsch in Kairo Auftakt für einen demokratischen Neustart sein könnte,so ist mittlerweile deutlich geworden, dass Ägypten in autoritäre Herrschaftsmechanismen der Mubarak-Ära zurückfällt. KW - Arabischer Frühling KW - Ägypten Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-71165 ER - TY - GEN A1 - Behrens, Benedikt T1 - Eine unvorhergesehene Revolte : Proteste in Brasilien N2 - Brasilien ist sowohl politisch als auch wirtschaftlich ein aufstrebendes Land. Seit Jahren regiert in Brasília eine linke Regierung.Trotz Fortschritten im sozialen Bereich gibt es zahlreiche Reformbaustellen. Die gesellschaftliche Spaltung ist tief. Darüber kann auch die anstehende Fußball-WM nicht hinwegtäuschen. Im Gegenteil! Die Brasilianer machten sich unerwartet Luft. Welche Konsequenzen wird Präsidentin Rousseff daraus ziehen und was bedeutet dies für die anderen Linksregierungen in Südamerika? KW - Süd- und Mittelamerika KW - Brasilien KW - soziale Bewegungen Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-71156 ER - TY - GEN T1 - Regionalmacht Südafrika N2 - Der „schwarze Kontinent“ emanzipiert sich vom Westen, auch außenpolitisch. Afrikanische Lösungen für afrikanische Probleme – dies wird gefordert. Dabei spielt Südafrika, das jüngste Mitglied der aufstrebenden BRICS-Gruppe, eine Hauptrolle. Trotz schwacher Wirtschaft und geringer militärischer Kapazitäten zeigt das Land Selbstbewusstsein sowohl in der konfliktreichen Region als auch auf der globalen Bühne. Im neuen Heft prüfen südafrikanische Stimmen die neue Außenpolitik des „Koloss am Kap“ auf Anspruch und Wirklichkeit. KW - Südafrika KW - Hegemonie KW - Afrika Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-71184 ER - TY - GEN A1 - Gatzhammer, Stefan T1 - O debate de direito eclesiástico : a circuncisão por motivos religiosos e anova lei do Código Civil da Alemanha N2 - Em Maio 2012 uma decisão equívoca do Tribunal de segunda instância de Colónia (Landgericht Köln) declarou crime a circuncisão de um menino por motivos religiosos, mesmo efectuada de acordo com as leges artis e com o consentimento dos pais. O artigo comenta a nova legislação introduzida em Dezembro de 2012 no Código Civil alemão (BGB) como quadro legal para a circuncisão do menino em relação com o direito à liberdade religiosa e com o direito dos pais à educação, especialmente para judeus e muçulmanos, na Alemanha. N2 - In May 2012 a misleading decision of the Landgericht (Court of Appeal) Cologne declared that male circumcision in children amounts to be a criminal offence, even if performed lege artis and with the consent of the parents. The article pays attention to the new legislation of December 2012 introduced into the BGB as a legal framework of male circumcision with regard to the right of freedom of religion and the parental rights in education especially for Jewish and Muslims in Germany. T3 - Zweitveröffentlichungen der Universität Potsdam : Philosophische Reihe - 88 KW - Beschneidung aus religiösen Gründen KW - Zirkumzision KW - Staatskirchenrecht KW - Religionsrecht KW - Strafrecht KW - Sorgerecht KW - Kindeswohl KW - BGB KW - Judentum Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-68652 ER - TY - GEN A1 - Christoffers, Ralf T1 - Brandenburg trifft Südafrika N2 - Südafrika hat eine rasante Entwicklung genommen. Das wird schnell sichtbar, wenn man im Land unterwegs ist – wozu ich gemeinsam mit einer brandenburgischen Wirt- schaftsdelegation in diesem Sommer Gelegenheit hatte. Inzwischen steht Südafrika vor großen Herausforderungen. Bis heute sind die Nachwirkungen der jahrelangen Apartheid im realen Leben spürbar. Umso größer ist mein Respekt vor allen, die sich den Herausforderungen stellen. KW - Südafrika KW - Brandenburg Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-69187 ER - TY - GEN A1 - Schwarz, Wolfgang T1 - Interventionismus und kein Ende? N2 - Spätestens die Geschichte in der zweiten Hälfte des 20. Jahrhunderts hat gezeigt, dass es historische Lektionen gibt, deren Verinnerlichung permanent, weil von jeder nachwachsenden politischen und militärischen Elite aufs Neue verweigert wird. Dazu zählt, dass militärische Gewalt in der Regel ein komplett untaugliches Mittel ist, anderen Staaten und Völkern den eigenen politischen Willen aufzuzwingen und regime change entweder zu verhindern oder herbeizuführen. KW - Interventionismus KW - Krieg KW - Afghanistan Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-69179 ER - TY - GEN A1 - Heisig, Johannes T1 - Italien am Scheideweg : das erste Halbjahr der Regierung Letta N2 - Italien ist ein Land des Wandels, vor allem wechseln seine Regierungen sehr häufig. Regierungen in Italien haben es nicht leicht, ihre Legislaturperiode zu beenden. Der neue Mann nach dem verhängnisvollen Berlusconi und dem kurzen Intermezzo des Technokraten Monti ist der Politiker Enrico Letta. Wird er eine regierungsfähige Koalition erhalten und kann er die ernsten Probleme des Landes nachhaltig lösen? KW - Italien KW - Südeuropa KW - Parteien KW - Wirtschaftskrise Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-69161 ER - TY - GEN T1 - Indien inside N2 - Die Bilder vom heutigen Indien faszinieren, aber mehr noch erschrecken sie. Der gnadenlose Kontrast, der mehr ist als „soziale Ungleichheit“, die grausame Armut, die trotz Wachstum in den vergangenen Jahren dramatisch angestiegen ist. 42 Prozent der Inder leben heute unter der Armutsgrenze. Das sind 500 Millionen Menschen! Dazu kommen die sich über das ganze Land ausbreitende, oft tödliche Gewalt, nicht nur, aber vor allem gegen „Indiens Töchter“, ein fortdauerndes archaisches Kastenwesen, ein immer stärker werdender Separatismus, der die nationale Einheit ernsthaft infrage stellt, bürgerkriegsartige Zustände in einigen Bundesstaaten und eine massive Zerstörung der Umwelt. KW - Indien KW - Italien KW - Afrika Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-69197 ER - TY - GEN A1 - Masala, Carlo T1 - Niemals geht man so ganz : ein Nachruf auf Kenneth N. Waltz N2 - Durch den Tod von Kenneth N. Waltz hat die akademische Disziplin der Internationalen Beziehungen ihren gegenwärtig größten und einflussreichsten Denker verloren. In verschiedenen Nachrufen von Schülern und Kollegen wurde zu Recht darauf hingewiesen, dass Kenneth Waltz, egal wie man zu seiner Theorie des strukturellen Realismus (der Begriff, den er dem des Neorealismus vorzog) steht, wie kein anderer die Disziplin der Internationalen Beziehungen nach dem Ende des Zweiten Weltkrieges geprägt hat. KW - Internationale Politik KW - Waltz Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-67896 ER - TY - GEN A1 - Zamirirad, Azadeh T1 - Mit dem Schlüssel zum Erfolg : Irans neuer Präsident ; ein Kommentar N2 - Iranische Präsidentschaftswahlen sind immer für eine Überraschung gut. Noch eine Woche vor der Wahl dürften die wenigsten mit einem Erdrutschsieg Hassan Rouhanis gerechnet haben. Der neue Mann ist dabei ein Altbekannter. Zahlreiche Posten hat er in der Islamischen Republik bereits bekleidet und sich als Chefunterhändler auch im Ausland einen Namen gemacht. Welche Erwartungen werden an ihn gerichtet und welche Herausforderungen gilt es nun zu meistern? KW - Iran KW - Wahlen KW - Naher und Mittlerer Osten Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-67881 ER - TY - GEN A1 - Gündüz, Zuhal Yesilyurt T1 - Explosive Türkei : ein Bericht zum Widerstand gegen ein autoritäres Regime N2 - Noch vor zwei Monaten sprach man hierzulande von einer stabilen Türkei. Das war ganz offensichtlich falsch. Seit gut zwei Jahren wächst der Unmut gegen Erdogan und die AKP-Regierung. Immer deutlicher zeigen sich die antiliberalen, autoritären Züge eines bonapartistischen Regimes, das im Namen der „Mehrheit“ Grundfreiheiten massiv einschränkt und sich nicht scheut, mit brutaler Gewalt gegen Teile der Bevölkerung, vor allem gegen die e-politisierte Jugend, vorzugehen. Die türkische Autorin Zuhal Yesilyurt Gündüz schickte uns diesen Bericht zu den Ereignissen am Taksim-Platz, die zu einer neuen Qualität der Proteste geführt haben. KW - Türkei KW - Innenpolitik KW - Proteste KW - Autoritarismus Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-67879 ER - TY - GEN T1 - Kriminelle Welt N2 - Im Schwerpunkt begeben wir uns in Schlupfwinkel der organisierten Kriminalität, die längst nicht nur Sache der berüchtigten italienischen Mafia ist. Transnationale Kriminalität ist ein den Globus umspannendes Phänomen - ein Phänomen mit diversen Ursprüngen, geografisch wie motivisch. Wir spüren ihren Linien im 21. Jahrhundert nach und diskutieren Strategien ihrer Bekämpfung. KW - Geldwäsche KW - Kosovo KW - Piraterie KW - Kriminalität Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-67903 ER - TY - GEN T1 - Türkei offensiv N2 - Die Türkei hat sich zum strategischen Spieler im Nahen Osten entwickelt. Unübersehbar ist der Wandel vom laizistischen Staatsmodell zur Islamisierung. Das spiegelt sich auch in einer offensiven Außenpolitik wider. Verfolgt Erdogan eine neo-osmanische Strategie? Deutsche und türkische Autoren leuchten die „Tiefe“ des türkischen Raumes aus. Afghanistan im Comic? Graphic Novels zeichnen Linien der globalen Politik artistisch nach – oft ungeschminkt, mit der Wucht der Kunst. Wir stellen Neuerscheinungen aus der Welt der politischen Comics vor. KW - Türkei KW - Außenpolitik KW - Nahost KW - Erdogan Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-66697 ER - TY - GEN T1 - Glosse: Steueroasen : Paradies auf Erden N2 - Das Paradies ist der Ort, an dem der Mensch Gott am nächsten ist. Aber was für ein Ort ist das? Gibt es dort so etwas wie eine staatliche Verfasstheit? Ist es gerade deshalb ein Paradies, weil es dafür keine Anzeichen gibt? Welchen Raum nimmt dieser himmlische Garten ein? Ist er grenzenlos oder endlich? Fiktion kennt keine Grenzen. Geld auch nicht. Staaten sehr wohl, und ein nicht unerheblicher Batzen, den sie für ihre Existenz beanspruchen, soll möglichst innerhalb dieser Grenzen bleiben. Dieses Geld – im Volksmund auch Kröten, Kies oder Moos genannt, was auf die Zugehörigkeit zu einem ökologischen Raum schließen lässt – nennen wir Steueraufkommen (das Existenzminimum eines Staates oder auch Staats-Hartz-IV). In jedem Staat werden Steuern für seine Bürger fällig. Allerdings nicht im Paradies. Und deshalb ist es – ja, was wohl? – auch ein Steuerparadies. KW - Steueroasen KW - Finanzen KW - Europa Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-66671 ER - TY - GEN A1 - Kiraly, Attila T1 - Hoher Besuch : Xi Jinping in Russland N2 - Wenn ein neuer Mann (das gilt auch für entsprechende Frauen) an die Spitze des Staates oder der Regierung tritt, macht er Besuche im Ausland. Allerdings hatte schon der chinesische Philosoph Laotse im 6. Jahrhundert v. u. Z. festgestellt: „Auch der längste Marsch beginnt mit dem ersten Schritt.“ Es gibt immer nur einen ersten Schritt, bereits der zweite ist nicht mehr der erste. So kann auch ein Staatsoberhaupt nur einen ersten Auslandsbesuch machen. KW - China KW - Russland KW - Diplomatie KW - Jinping Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-66669 ER - TY - GEN A1 - Pizzi, José Luis T1 - Habemus Papam, nostrum? : eine argentinische Sicht auf den neuen Papst N2 - Wurde uns ein neuer Star geboren? Die Begeisterung im globalen Süden, sofern katholisch, und besonders in Argentinien, die mit der Wahl von Jorge María Bergoglio zum Papst Franziskus verbunden war, scheint dies zu belegen. Diese Freude ließ die Probleme, die mit der Wahl dieses neuen Papstes sowohl in der katholischen Kirche als auch mit seiner „argentinischen Geschichte“ verbunden sind, in den Hintergrund, ja fast in Vergessenheit geraten. KW - Papst KW - Bergoglio KW - Argentinien KW - Vatikan KW - Lateinamerika Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-66651 ER - TY - GEN T1 - Russland und Wir N2 - „Wir wollen Russland als Partner“, stellte jüngst Außenminister Westerwelle fest. Das ist anspruchsvoll. Ein Blick zurück genügt, um zu sehen, dass Russland und wir in der Vergangenheit ein häufig schwieriges Verhältnis hatten. Nach dem Ende des Kalten Krieges sollte es anders werden. Wie steht es im Hier und Jetzt um die deutsch-russischen Beziehungen? In WeltTrends ziehen russische und deutsche Autoren eine kritische Bilanz, die konstruktive Anregung sein sollte, über die Zukunft dieser Beziehungen, die weit über das Bilaterale ausstrahlen, nachzudenken. Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-65203 ER - TY - GEN A1 - Schwarz, Wolfgang T1 - Drohnen : the smart art of killing? N2 - Das Pro und Contra hinsichtlich bewaffneter Drohnen für die Bundeswehr schwelte hierzulande bereits seit Längerem, als Bundesverteidigungsminister de Maizière 2012 mit einem befürwortenden Plädoyer aus der Deckung trat und solche Kampfmaschinen als „ethisch neutral“ einstufte. Inzwischen könnte – ohne Einbeziehung des Parlaments – eine Entscheidung der Bundesregierung gefallen sein. In der Antwort auf eine parlamentarische Anfrage der Linkspartei hieß es, „dass eine durchhaltefähige bewaffnete Aufklärung […] als Schutz bei plötzlich auftretenden gravierenden Lageänderungen unbedingt erforderlich ist“. KW - Drohnen KW - Pakistan KW - Afghanistan KW - Bundeswehr KW - Krieg Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-65198 ER - TY - GEN A1 - Grant, Charles T1 - The UK and the European Union : about Cameron’s optimistic, risky and ambiguous strategy N2 - Für den Fall seiner Wiederwahl kündigt Cameron ein Referendum an. Verlässt Großbritannien dann die EU? Zwei Jahre vor der nächsten Wahl verhält sich der britische Premierminister David Cameron zwar taktisch klug für sein politisches Überleben, aber zugleich sehr riskant, für sich und für Europa. Seine europhoben Tories fordern den Austritt aus dem Staatenverbund, zumindest aber Verhandlungen über nationale Sonderregelungen. Damit setzt er die EU unter erheblichen (zusätzlichen) Druck. Aber geht Camerons Rechnung auf? Schätzt er die Position Deutschlands richtig ein? KW - Euroskeptizismus KW - Großbritannien KW - EU KW - Krise KW - Cameron Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-65173 ER - TY - GEN A1 - Plenefisch, Julian A1 - Spremberg, Felix T1 - Rechtsruck in Japan N2 - Ein dreifacher Rechtsruck geht nach den Wahlen durch Japan: Die rechtsradikale Restaurationspartei feiert ihren Aufstieg zur drittstärksten Macht, der rechte Flügel des Wahlverlierers, der Demokratischen Partei, hat überlebt und der rückwärtsgewandte Wahlsieger der Liberaldemokratischen Partei, Abe Shinzō, regiert wieder. Wie werden diese Veränderungen die Außen- und Sicherheitspolitik Japans beeinflussen? KW - Japan KW - Wahlen KW - Nationalismus KW - Außenpolitik Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-65181 ER - TY - GEN A1 - Hacke, Christian T1 - Eindämmung und Einbindung : Obamas globale Strategie N2 - Präsident Obama reagiert auf drei zentrale Machtverschiebungen, auf die weltpolitische von West nach Ost, auf die angestiegene Bedeutung der asiatischen Region und schließlich auf die wachsenden Konflikte im asiatischen Raum. Er weiß um die begrenzte Fähigkeit der USA zur globalen Einflussnahme. Zwar wankt der alte Hegemon USA derzeit, jedoch hält die bislang nur schemenhafte neue Weltordnung für den Westen mehr Chancen als Risiken bereit – wenn er klüger als bisher für die eigenen Werte und Interessen einsteht. KW - USA KW - Weltordnung KW - Obama KW - Wahlen KW - Pazifik Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-64251 SN - 0944-8101 ER - TY - GEN A1 - Schwarz, Wolfgang T1 - Atommacht Pakistan - "The Ally From Hell" N2 - Die genaue Anzahl einsatzfähiger Nuklearsprengköpfe Pakistans, einer nach den Standards des internationalen Regimes zur Nichtweiterverbreitung von Kernwaffen (NPT) illegalen Atommacht, ist nicht bekannt. Hans Kristensen, Direktor des Nuclear Information Project der unabhängigen Federation of American Scientists und Kenner der Materie, rechnet mit 90 bis 110, Tendenz: kontinuierlich steigend. Diese Waffen befinden sich in einem Land, das seit Jahrzehnten vom Militär beherrscht wird, das aufgrund der extremen Armut einer Mehrheit der Bevölkerung erheblichen sozialen Sprengstoff in sich birgt und in dem sich Guerilla-Angriffe separatistischer paschtunischer Taliban auch gegen Militärbasen richten, die mit den Kernstreitkräften des Landes in Verbindung gebracht werden. Experten warnen daher vor der Möglichkeit eines fundamental-islamistischen Umsturzes ebenso wie vor der Gefahr, dass einzelne Atomwaffen in die Hände terroristischer Gruppen geraten könnten. Was den letzteren Aspekt anbetrifft, so beruhigt es auch nicht, wenn die pakistanischen Taliban – wie im Mai 2011 – erklären, dass „Pakistan die einzige muslimische Atommacht“ sei und man an diesem Status nichts ändern wolle. KW - Pakistan KW - Atomwaffen KW - Krieg KW - Nuklear KW - USA Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-64245 ER - TY - GEN A1 - Abdel Shafi, Salah T1 - Historischer November in Palästina : Zwei-Staaten-Lösung versus dauerhafte Besatzung durch Israel N2 - Der November 2012 wird sicherlich als ein historischer Monat in die palästinensische Geschichte eingehen. Im November begann die israelische Armee mit der gezielten Tötung eines hohen Funktionärs der Hamas einen Luftkrieg gegen den Gazastreifen. Nach acht Tagen wurde Israel durch internationalen Druck gezwungen, einen Waffenstillstand mit der Hamas zu akzeptieren. Einmal mehr zeigte sich, dass der Nahostkonflikt nicht mit militärischer Gewalt zu lösen ist. Dies kann nur mit einer Zwei-Staaten-Lösung erreicht werden, der substanzielle und ehrliche Verhandlungen vorausgehen. KW - Israel KW - Palästina KW - Gaza KW - Frieden KW - UNO Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-64236 ER - TY - GEN T1 - China und die Welt N2 - Was will China? Diese Frage wird immer wieder gestellt, wenn es um die internationale Positionierung der Volksrepublik geht. In den letzten Heften diskutierte WeltTrends die neue(n) Weltunordnung(en) des 21. Jahrhunderts. Einig war man sich in der Einschätzung, welche Rolle China in der Welt von übermorgen übernehmen wird: Es wird eine globale Macht sein. Ein Autor datierte sogar die Übernahme der hegemonialen Rolle der USA durch China präzise auf das Jahr 2035. Im asiatisch-pazifischen Raum versteht sich China als „Großmacht“. Die Zahl der Nachbarn ist groß und China steht seit Jahrtausenden mit ihnen in einem spannungsreichen Verhältnis. Territorialkonflikte schwelen und brechen von Zeit zu Zeit aus. Auch die USA verstehen sich als pazifische Macht. Dies wurde durch Obama, dem „ersten pazifischen Präsidenten“ der USA, zum neuen außenpolitischen Programm, das militärisch untersetzt wird. Gefährlich, auch für den globalen Frieden, kann es werden, wenn in diesem Raum aus der Konkurrenz zweier großer Mächte ein Kampf wird. Das Rasseln von Säbeln ist bereits hörbar. Dass sich die chinesische Diplomatie dieser Herausforderung mit konfuzianischer Klugheit stellt, überrascht. KW - China KW - Außenpolitik KW - Menschenrechte KW - USA Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-64267 ER -