TY - JOUR A1 - Heuer, Axel A1 - Menzel, Ralf T1 - Principles of Phase Conjugating Brillouin Mirrors Y1 - 2004 SN - 0-471-43957-6 ER - TY - THES A1 - Illya, Gregoria T1 - Bilayer material properties and domain formation from dissipative particle dynamics Y1 - 2004 CY - Potsdam ER - TY - THES A1 - Török, Tibor T1 - Instabilität magnetischer Flußröhren in solaren Eruptionen Y1 - 2004 CY - Potsdam ER - TY - THES A1 - Läuter, Matthias T1 - Großräumige Zirkulationsstrukturen in einem nichtlinearen adaptiven Atmosphärenmodell Y1 - 2004 CY - Potsdam ER - TY - THES A1 - Hildebrandt, Lars T1 - Durchstimmbare externe Resonatoren mit entspiegelten GaN-Laserdioden für die Atomabsorptionsspektroskopie Y1 - 2004 ER - TY - THES A1 - Dosche, Carsten T1 - Elektronisch angeregte Zustände und Deaktivierungsprozesse von [N]Phenylenen Y1 - 2004 ER - TY - THES A1 - Hänisch, Christoph T1 - Stimulierte Brillouin-Streuung in Multimode-Faserverstärkern zur optischen Phasenkonjugation Y1 - 2004 ER - TY - BOOK A1 - Donner, Reik Volker A1 - Cser, Adrienn A1 - Schwarz, Udo A1 - Otto, Andreas H. A1 - Feudel, Ulrike T1 - An approach to a process model of laser beam melt ablation using methods of linear and non-linear data analysis N2 - As a non-contact process laser beam melt ablation offers several advantages compared to conventional processing mechanisms. During ablation the surface of the workpiece is molten by the energy of a CO2-laser beam, this melt is then driven out by the impulse of an additional process gas. Although the idea behind laser beam melt ablation is rather simple, the process itself has a major limitation in practical applications: with increasing ablation rate surface quality of the workpiece processed declines rapidly. With different ablation rates different surface structures can be distinguished, which can be characterised by suitable surface parameters. The corresponding regimes of pattern formation are found in linear and non-linear statistical properties of the recorded process emissions as well. While the ablation rate can be represented in terms of the line-energy, this parameter does not provide sufficient information about the full behaviour of the system. The dynamics of the system is dominated by oscillations due to the laser cycle but includes some periodically driven non-linear processes as well. Upon the basis of the measured time series, a corresponding model is developed. The deeper understanding of the process can be used to develop strategies for a process control. Y1 - 2004 SN - 3-527-40430-9 ER - TY - THES A1 - Carroll, Thorsten Anthony T1 - Zur Linienentstehung und Diagnostik in kleinskaligen Magnetfeldern der solaren Photosphäre Y1 - 2004 ER - TY - BOOK ED - Mendes, Alexanda Navas ED - Vazquez, Graciela T1 - Adieu plus : comprension auditiva y visual de clases magistrales ; 14 CD-ROM T3 - Arqueología 02 Y1 - 2004 SN - 3-935024-93-2 VL - 2 PB - Univ.-Verl. CY - Potsdam ER - TY - JOUR A1 - Pena, M A1 - Peimbert, A. A1 - Hamann, Wolf-Rainer A1 - Ruiz, M. T. A1 - Peimbert, M. T1 - The extraordinary planetary nebula N66 in the LMC N2 - Morphology of the planetary nebula LMC-N66 (ionized by a [WN] star) indicates that the nebula is a multipolar object with a very narrow waist. It shows several jets, knots and filaments in opposite directions from the central star. A couple of twisted long filaments could be interpreted as due to point-symmetric type ejection. If such is the case, the progenitor would be a binary precessing system. High resolution spectroscopy shows that most of the material is approaching or receding from the star. However the line profiles are very complex, showing several components at different velocities. Our high resolution spectroscopic data show that the different structures (knots, filaments, ...) present different radial velocities spreading from 240 to more than 400 km/s. The system velocity is 300 km/s. There are high velocity knots located to the north of the central star, moving at more than 100 km/s relative to the system velocity. Y1 - 2004 SN - 3-12-283174-0 ER - TY - JOUR A1 - Blasius, Bernd A1 - Clodong, Sébastien T1 - Chaos in a periodically forced chemostat with algal mortality N2 - We study the possibility of chaotic dynamics in the externally driven Droop model. This model describes a phytoplankton population in a chemostat under periodic supply of nutrients. Previously it has been proven under very general assumptions that such systems are not able to exhibit chaotic dynamics. Here we show that the simple introduction of algal mortality may lead to chaotic oscillations of algal density in the forced chemostat. Our numerical simulations show that the existence of chaos is intimately related to plankton overshooting in the unforced model. We provide a simple measure, based on stability analysis, for estimating the amount of overshooting. These findings are not restricted to the Droop model but hold also for other chemostat models with mortality. Our results suggest periodically driven chemostats as a simple model system for the experimental verification of chaos in ecology. Y1 - 2004 ER - TY - JOUR A1 - Shikin, A. M. A1 - Varykhalov, Andrei A1 - Prudnikova, G. V. A1 - Adamchuk, V. K. A1 - Gudat, Wolfgang A1 - Rader, Oliver T1 - Photoemission from stepped W(110) : Initial or final state effect? N2 - The electronic structure of the (110)-oriented terraces of stepped W(331) and W(551) is compared to the one of flat W(110) using angle-resolved photoemission. We identify a surface-localized state which develops perpendicular to the steps into a repeated band structure with the periodicity of the step superlattices. It is shown that a final-state diffraction process rather than an initial-state superlattice effect is the origin of the observed behavior and why it does not affect the entire band structure Y1 - 2004 SN - 0031-9007 ER - TY - JOUR A1 - Zhu, M. Q. A1 - Armbruster, Dieter A1 - Katzorke, Ines T1 - Does synchronization of networks of chaotic maps lead to control? N2 - We consider networks of chaotic maps with different network topologies. In each case, they are coupled in such a way as to generate synchronized chaotic solutions. By using the methods of control of chaos we are controlling a single map into a predetermined trajectory. We analyze the reaction of the network to such a control. Specifically we show that a line of one-dimensional logistic maps that are unidirectionally coupled can be controlled from the first oscillator whereas a ring of diffusively coupled maps cannot be controlled for more than 5 maps. We show that rings with more elements can be controlled if every third map is controlled. The dependence of unidirectionally coupled maps on noise is studied. The noise level leads to a finite synchronization lengths for which maps can be controlled by a single location. A two-dimensional lattice is also studied. (C) 2005 American Institute of Physics Y1 - 2005 SN - 1054-1500 ER - TY - JOUR A1 - Zillmer, Rüdiger A1 - Pikovskij, Arkadij T1 - Continuous approach for the random-field Ising chain N2 - We study the random-field Ising chain in the limit of strong exchange coupling. In order to calculate the free energy we apply a continuous Langevin-type approach. This continuous model can be solved exactly, whereupon we are able to locate the crossover between an exponential and a power-law decay of the free energy with increasing coupling strength. In terms of magnetization, this crossover restricts the validity of the linear scaling. The known analytical results for the free energy are recovered in the corresponding limits. The outcomes of numerical computations for the free energy are presented, which confirm the results of the continuous approach. We also discuss the validity of the replica method which we then utilize to investigate the sample-to-sample fluctuations of the finite size free energy Y1 - 2005 ER - TY - JOUR A1 - Zhang, B. A1 - Henkel, Carsten A1 - Haller, E. A1 - Wildermuth, S. A1 - Hofferberth, S. A1 - Kruger, P. A1 - Schmiedmayer, Jörg T1 - Relevance of sub-surface chip layers for the lifetime of magnetically trapped atoms N2 - We investigate the lifetime of magnetically trapped atoms above a planar, layered atom chip structure. Numerical calculations of the thermal magnetic noise spectrum are performed, based on the exact magnetic Green function and multi layer reflection coefficients. We have performed lifetime measurements where the center of a side guide trap is laterally shifted with respect to the current carrying wire using additional bias fields. Comparing the experiment to theory, we find a fair agreement and demonstrate that for a chip whose topmost layer is metallic, the magnetic noise depends essentially on the thickness of that layer, as long as the layers below have a, much smaller conductivity; essentially the same magnetic noise would be obtained with a metallic membrane suspended in vacuum. Based on our theory we give general scaling laws of how to reduce the effect of surface magnetic noise on the trapped atoms Y1 - 2005 ER - TY - JOUR A1 - Zen, Achmad A1 - Saphiannikova, Marina A1 - Neher, Dieter A1 - Asawapirom, Udom A1 - Scherf, Ullrich T1 - Comparative study of the field-effect mobility of a copolymer and a binary blend based on poly(3- alkylthiophene)s N2 - The performance of highly soluble regioregular poly[ (3-hexylthiophene)-co-(3-octylthiophetie)] (P3HTOT) as a semiconducting material in organic field-effect transistors (OFETs) is presented in comparison to that of the corresponding homopolymers. Transistors made from as-prepared layers of P3HTOT exhibit a mobility of ca. 7 x 10(-3) cm(2) V-1 s(-1), which is comparable to the performance of transistors made from as-prepared poly(3-hexylthiophene) (P3HT) and almost 6 times larger than the mobility of transistors prepared with poly(3-octylthiophene) (P3OT). On the other hand, the solubility parameter delta(p) of P3HTOT is close to that of the highly soluble P3OT. Moreover, compared to a physical blend of poly(3-hexylthiophene) and poly(3-octylthiophene), the mobility of P3HTOT devices is almost twice as large and the performance does not degrade upon annealing at elevated temperatures. Therefore, the copolymer approach outlined here may be one promising step toward an optimum balance between a Sufficient processability of the polymers from common organic solvents, a high solid state order, and applicable OFET performances Y1 - 2005 SN - 0897-4756 ER - TY - JOUR A1 - Zoller, Gert A1 - Hainzl, Sebastian A1 - Holschneider, Matthias A1 - Ben-Zion, Yehuda T1 - Aftershocks resulting from creeping sections in a heterogeneous fault N2 - We show that realistic aftershock sequences with space-time characteristics compatible with observations are generated by a model consisting of brittle fault segments separated by creeping zones. The dynamics of the brittle regions is governed by static/kinetic friction, 3D elastic stress transfer and small creep deformation. The creeping parts are characterized by high ongoing creep velocities. These regions store stress during earthquake failures and then release it in the interseismic periods. The resulting postseismic deformation leads to aftershock sequences following the modified Omori law. The ratio of creep coefficients in the brittle and creeping sections determines the duration of the postseismic transients and the exponent p of the modified Omori law Y1 - 2005 SN - 0094-8276 ER - TY - JOUR A1 - Zhou, Changsong A1 - Kurths, Jürgen T1 - Noise-sustained and controlled synchronization of stirred excitable media by external forcing N2 - Most of the previous studies on constructive effects of noise in spatially extended systems have focused on static media, e.g., of the reaction diffusion type. Because many active chemical or biological processes occur in a fluid environment with mixing, we investigate here the interplay among noise, excitability, mixing and external forcing in excitable media advected by a chaotic flow, in a two-dimensional FitzHugh-Nagumo model described by a set of reaction- advection-diffusion equations. In the absence of external forcing, noise may generate sustained coherent oscillations of the media in a range of noise intensities and stirring rates. We find that these noise-sustained oscillations can be synchronized by external periodic signals much smaller than the threshold. Analysis of the locking regions in the parameter space of the signal period, stirring rate and noise intensity reveals that the mechanism underlying the synchronization behaviour is a matching between the time scales of the forcing signal and the noise-sustained oscillations. The results demonstrate that, in the presence of a suitable level of noise, the stirred excitable media act as self-sustained oscillatory systems and become much easier to be entrained by weak external forcing. Our results may be verified in experiments and are useful to understand the synchronization of population dynamics of oceanic ecological systems by annual cycles Y1 - 2005 SN - 1367-2630 ER - TY - JOUR A1 - Zen, Achmad A1 - Neher, Dieter A1 - Silmy, Kamel A1 - Hollander, A. A1 - Asawapirom, Udom A1 - Scherf, Ullrich T1 - Improving the performance of organic field effect transistor by optimizing the gate insulator surface N2 - The effect of oxygen plasma treatment and/or silanization with hexamethyldisilazane (HMDS) on the surface chemistry and the morphology of the SiO2-gate insulator were studied with respect to the performance of organic field effect transistors. Using X-ray photoelectron spectroscopy (XPS), it is shown that silanization leads to the growth of a polysiloxane interfacial layer and that longer silanization times increase the thickness of this layer. Most important, silanization reduces the signal from surface contaminations such as oxidized hydrocarbon molecules. In fact, the lowest concentration of these contaminations was found after a combined oxygen plasma/silanization treatment. The results of these investigations were correlated with the characteristic device parameters of polymer field effect transistors with poly(3-hexylthiophene)s as the semiconducting layer. We found that the field effect mobility correlates with the concentration of contaminations as measured by XPS. We, finally, demonstrate that silanization significantly improves the operational stability of the device in air compared to the untreated devices Y1 - 2005 ER - TY - JOUR A1 - York, T. A1 - Jackson, N. A1 - Browne, Ian W. A. A1 - Wucknitz, Olaf A1 - Skelton, J. E. T1 - The Hubble constant from the gravitational lens CLASS B0218+357 using the Advanced Camera for Surveys N2 - We present deep optical observations of the gravitational lens system CLASS B0218 + 357, from which we derive an estimate for the Hubble constant (H-0). Extensive radio observations using the VLA, MERLIN, the VLBA and VLBI have reduced the degeneracies between H-0 and the mass model parameters in this lens to one involving only the position of the radio-quiet lensing galaxy with respect to the lensed images. B0218 + 357 has an image separation of only 334 mas, so optical observations have, up until now, been unable to resolve the lens galaxy from the bright lensed images. Using the new Advanced Camera for Surveys (ACS), installed on the Hubble Space Telescope in 2002, we have obtained deep optical images of the lens system and surrounding field. These observations have allowed us to determine the separation between the lens galaxy centre and the brightest image, and so estimate H-0. We find an optical galaxy position, and hence an H0 value, that varies depending on our approach to the spiral arms in B0218 + 357. If the most prominent spiral arms are left unmasked, we find H-0 = 70 +/- 5 km s(-1) Mpc(-1) (95 per cent confidence). If the spiral arms are masked out, we find H-0 = 61 +/- 7 km s(-1) Mpc(-1) (95 per cent confidence) Y1 - 2005 SN - 0035-8711 ER - TY - JOUR A1 - Wong, J. E. A1 - Detert, H. A1 - Brehmer, Ludwig A1 - Schrader, Sigurd T1 - Green light-emitting devices based on soluble oligo(phenylenevinylenes) N2 - In this work, we report our investigations on the film-forming properties as well as the optical and electroluminescent characterisations of a series of lateral-substituted soluble oligo(phenylenevinylenes) of various conjugation length. Preliminary investigations show that these materials are potential candidates for use in organic light-emitting devices (OLEDs). Two types of OLEDs were fabricated: single layer (SL) and single heterostructure (SHS), with poly(p-phenylenevinylene) (PPV) as hole transporting layer. Our best results were obtained with single layer device emitting green light with a luminance of 0.18 cd m(-2) and 0.24 cd m(-2) at a driving voltage of 10 V. (c) 2004 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0169-4332 ER - TY - JOUR A1 - Wolf, M. M. A1 - Eisert, Jens T1 - Classical information capacity of a class of quantum channels N2 - We consider the additivity of the minimal output entropy and the classical information capacity of a class of quantum channels. For this class of channels, the norm of the output is maximized for the output being a normalized projection. We prove the additivity of the minimal output Renyi entropies with entropic parameters alpha is an element of [ 0, 2], generalizing an argument by Alicki and Fannes, and present a number of examples in detail. In order to relate these results to the classical information capacity, we introduce a weak form of covariance of a channel. We then identify various instances of weakly covariant channels for which we can infer the additivity of the classical information capacity. Both additivity results apply to the case of an arbitrary number of different channels. Finally, we relate the obtained results to instances of bi-partite quantum states for which the entanglement cost can be calculated Y1 - 2005 SN - 1367-2630 ER - TY - JOUR A1 - Witt, Annette A1 - Schumann, A. Y. T1 - Holocene climate variability on millennial scales recorded in Greenland ice cores N2 - Climate variability is triggered by several solar and orbital cycles as well as by the intern ocean dynamics. Consequently, paleoclimate proxy records are expected to vary on very different time scales ranging from subdecadal to millennial duration. We demonstrate, that Foster's (Foster, 1996) wavelet analysis technique is an appropriate tool for investigating temporarily changing spectral properties of records characterized by awkward sampling quality, which is a typical feature of climate proxy records. By applying it to the Holocene part of different glaciochemical records of Greenland ice cores we proof evidence for a significant contribution of the 1.47 kiloyears cycle over alomst the entire Holocene Y1 - 2005 SN - 1023-5809 ER - TY - JOUR A1 - Zaikin, Alexei A1 - Kurths, Jürgen A1 - Saparin, Peter A1 - Gowin, W. A1 - Prohaska, Steffen T1 - Modeling bone resorption in 2D CT and 3D mu CT images N2 - We study several algorithms to simulate bone mass loss in two-dimensional and three-dimensional computed tomography bone images. The aim is to extrapolate and predict the bone loss, to provide test objects for newly developed structural measures, and to understand the physical mechanisms behind the bone alteration. Our bone model approach differs from those already reported in the literature by two features. First, we work with original bone images, obtained by computed tomography (CT); second, we use structural measures of complexity to evaluate bone resorption and to compare it with the data provided by CT. This gives us the possibility to test algorithms of bone resorption by comparing their results with experimentally found dependencies of structural measures of complexity, as well as to show efficiency of the complexity measures in the analysis of bone models. For two-dimensional images we suggest two algorithms, a threshold algorithm and a virtual slicing algorithm. The threshold algorithm simulates bone resorption on a boundary between bone and marrow, representing an activity of osteoclasts. The virtual slicing algorithm uses a distribution of the bone material between several virtually created slices to achieve statistically correct results, when the bone-marrow transition is not clearly defined. These algorithms have been tested for original CT 10 mm thick vertebral slices and for simulated 10 mm thick slices constructed from ten I mm thick slices. For three-dimensional data, we suggest a variation of the threshold algorithm and apply it to bone images. The results of modeling have been compared with CT images using structural measures of complexity in two- and three-dimensions. This comparison has confirmed credibility of a virtual slicing modeling algorithm for two-dimensional data and a threshold algorithm for three-dimensional data Y1 - 2005 SN - 0218-1274 ER - TY - JOUR A1 - von Bloh, Werner A1 - Romano, Maria Carmen A1 - Thiel, Marco T1 - Long-term predictability of mean daily temperature data N2 - We quantify the long-term predictability of global mean daily temperature data by means of the Renyi entropy of second order K-2. We are interested in the yearly amplitude fluctuations of the temperature. Hence, the data are low- pass filtered. The obtained oscillatory signal has a more or less constant frequency, depending on the geographical coordinates, but its amplitude fluctuates irregularly. Our estimate of K-2 quantifies the complexity of these amplitude fluctuations. We compare the results obtained for the CRU data set (interpolated measured temperature in the years 1901- 2003 with 0.5 degrees resolution, Mitchell et al., 2005(1)) with the ones obtained for the temperature data from a coupled ocean-atmosphere global circulation model (AOGCM, calculated at DKRZ). Furthermore, we compare the results obtained by means of K-2 with the linear variance of the temperature data Y1 - 2005 SN - 1023-5809 ER - TY - JOUR A1 - Viana, R. L. A1 - Grebogi, Celso A1 - Pinto, S. E. D. A1 - Lopes, S. R. A1 - Batista, A. M. A1 - Kurths, Jürgen T1 - Bubbling bifurcation : loss of synchronization and shadowing breakdown in complex systems N2 - Complex dynamical systems with many degrees of freedom may exhibit a wealth of collective phenomena related to high-dimensional chaos. This paper focuses on a lattice of coupled logistic maps to investigate the relationship between the loss of chaos synchronization and the onset of shadowing breakdown via unstable dimension variability in complex systems. In the neighborhood of the critical transition to strongly non-hyperbolic behavior, the system undergoes on-off intermittency with respect to the synchronization manifold. This has been confirmed by numerical diagnostics of synchronization and non-hyperbolic behavior, the latter using the statistical properties of finite-time Lyapunov exponents. (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 ER - TY - JOUR A1 - Zeimer, Ute A1 - Pietsch, Ullrich A1 - Grenzer, Joerg A1 - Fricke, J. A1 - Knauer, A. A1 - Weyers, Markus T1 - Optimised two layer overgrowth of a lateral strain-modulated nanostructure N2 - Recently it has been shown that lateral carrier confinement in an InGaAs quantum well (QW) embedded in GaAs can be achieved by using a laterally patterned InGaP stressor layer on top of the heterostructure. To exploit this effect in a device the structure has to be planarized by a second epitaxial step. It has been shown that the lateral strain modulation almost vanishes after overgrowth with GaAs, whereas overgrowth with a single ternary layer of opposite strain compared to the stressor layer suffers from strain induced decomposition. Here we show that the lateral carrier confinement of the initially free standing nanostructure can almost be maintained using a two step process for overgrowth, where a strained thin ternary layer is grown first followed by GaAs up to complete planarization of the patterned structure. Thickness and composition of the ternary layer are adjusted on the basis of finite element calculations of the strain distribution (FEM). The strain field achieved after overgrowth is probed by X-ray grazing- incidence diffraction (GID). (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0925-8388 ER - TY - JOUR A1 - Wegener, Michael A1 - Bergweiler, Steffen A1 - Wirges, Werner A1 - Pucher, Andreas A1 - Tuncer, Enis A1 - Gerhard, Reimund T1 - Piezoelectric two-layer stacks of cellular polypropylene ferroelectrets : transducer response at audio and ultrasound frequencies N2 - Piezoelectric cellular polypropylene films, so-called ferroelectrets, are assembled in a stack with two active transducer layers. The stack is characterized with respect to its linear and quadratic response in a frequency range from 1 kHz to 80 kHz. A relatively smooth frequency response in the sound-pressure level is found for the individual layers as well as for both layers driven in phase. The piezoelectric response of the two-layer stack is twice the response of an individual layer over a rather broad frequency range. Furthermore, the influence of the preparation conditions on the resonance frequency and the effect of the quadratic distortion on the radiated sound are investigated both for the individual transducer films in the stack and for the stack system as a whole Y1 - 2005 SN - 0885-3010 ER - TY - JOUR A1 - Rader, Oliver A1 - Fauth, K. A1 - Gould, C. A1 - Ruster, C. A1 - Schott, G. M. A1 - Schmidt, G. A1 - Brunner, K. A1 - Molenkamp, Laurens W. A1 - Schutz, G. A1 - Kronast, F. A1 - Durr, H. A. A1 - Eberhardt, W. A1 - Gudat, Wolfgang T1 - Identification of extrinsic Mn contributions in Ga1-xMnxAs by field-dependent magnetic circular X-ray dichroism N2 - We combine sensitivity to atomic number, chemical shifts, probing depth, and magnetic order in a field- dependent magnetic circular X-ray dichroism study at the Mn L-edge of the diluted ferromagnetic semiconductor Ga1-xMnxAs and observe different Mn constituents: ferromagnetic Mn with an n(d) > 5 lineshape and paramagnetic Mn with distinct n(d) = 5 lineshape. The paramagnetic Mn is assigned to interstitials with surface segregation tendency. (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0368-2048 ER - TY - JOUR A1 - Tuncer, Enis A1 - Wegener, Michael A1 - Gerhard, Reimund T1 - Distribution of relaxation times in alpha-phase polyvinylidene fluoride N2 - In this paper, a recently developed numerical method to analyze dielectric-spectroscopy data is applied to alpha-phase polyvinylidene fluoride (PVDF). The numerical procedure is non-parametric and does not contain any of the extensively used empirical formulas mentioned in the literature. The method basically recovers the unknown distribution of relaxation times of the generalized dielectric function representation by simultaneous application of the Monte Carlo integration method and of the constrained least-squares optimization. The relaxation map constructed after the numerical analysis is compared to a-phase PVDF data presented in the literature and results of the parametric analysis with a well- known empirical formula. (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0022-3093 ER - TY - JOUR A1 - Tuncer, Enis A1 - Wegener, Michael A1 - Frubing, Peter A1 - Gerhard, Reimund T1 - Origin of temperature dependent conductivity of alpha-polyvinylidene fluoride N2 - The conductivity of alpha-polyvinylidene fluoride is obtained from dielectric measurements performed in the frequency domain at several temperatures. At temperatures above the glass-transition, the conductivity can be interpreted as an ionic conductivity, which confirms earlier results reported in the literature. Our investigation shows that the observed ionic conductivity is closely related to the amorphous phase of the polymer. (C) 2005 American Institute of Physics Y1 - 2005 SN - 0021-9606 ER - TY - JOUR A1 - Tuncer, Enis A1 - Lang, Sidney B. T1 - Numerical extraction of distributions of space-charge and polarization from laser intensity modulation method N2 - The Fredholm integral equation of the laser intensity modulation method is an ill-conditioned problem with multiple solutions. An approach based on an application of the Monte Carlo technique and a least-squares solver is developed and tested on simulated data containing both Gaussian and white noise. Good agreement between the original polarization and the estimated one was found. The influences of bin size and spacing, and errors in material properties, are discussed. It is shown that the presented approach is an alternative to other data analysis techniques in the literature based on regularization algorithms. (C) 2005 American Institute of Physics Y1 - 2005 SN - 0003-6951 ER - TY - JOUR A1 - Tuncer, Enis T1 - Structure-property relationship in dielectric mixtures: application of the spectral density theory N2 - This paper presents numerical simulations performed on dielectric properties of two-dimensional binary composites. The influence of structural differences and intrinsic electrical properties of constituents on the composite's overall electrical properties is investigated. The structural differences are resolved by fitting the dielectric data with an empirical formula and by the spectral density representation approach. At low concentrations of inclusions (concentrations lower than the percolation threshold), the spectral density functions are delta-sequences, which corresponds to the predictions of the general Maxwell-Garnett (MG) mixture formula. At high concentrations of inclusions (close to the percolation threshold) systems exhibit non-Debye-type dielectric dispersions, and the spectral density functions differ from each other and that predicted by the MG expression. The analysis of the dielectric dispersions with an empirical formula also brings out the structural differences between the considered geometries, however, the information is not qualitative. The empirical formula can only be used to compare structures. The spectral representation method on the other hand is a concrete way of characterizing the structures of the dielectric mixtures. Therefore, as in other spectroscopic techniques, a look-up table might be useful to classify/characterize structures of composite materials. This can be achieved by generating dielectric data for known structures by using ab initio calculations, as presented and emphasized in this study. The numerical technique presented here is not based on any a priori assumption methods Y1 - 2005 SN - 0022-3727 ER - TY - JOUR A1 - Tuncer, Enis T1 - Numerical calculations of effective elastic properties of two cellular structures N2 - Young's moduli of regular two-dimensional truss-like and eye-shaped structures are simulated using the finite element method. The structures are idealizations of soft polymeric materials used in ferro-electret applications. In the simulations, the length scales of the smallest representative units are varied, which changes the dimensions of the cell walls in the structures. A power-law expression with a quadratic as the exponent term is proposed for the effective Young's moduli of the systems as a function of the solid volume fraction. The data are divided into three regions with respect to the volume fraction: low, intermediate and high. The parameters of the proposed power-law expression in each region are later represented as a function of the structural parameters, the unit-cell dimensions. The expression presented can be used to predict a structure/property relationship in materials with similar cellular structures. The contribution of the cell-wall thickness to the elastic properties becomes significant at concentrations > 0.15. The cell-wall thickness is the most significant factor in predicting the effective Young's modulus of regular cellular structures at high volume fractions of solid. At lower concentrations of solid, the eye-shaped structure yields a lower Young's modulus than a truss-like structure with similar anisotropy. Comparison of the numerical results with those of experimental data for poly(propylene) show good aggreement regarding the influence of cell-wall thickness on elastic properties of thin cellular films Y1 - 2005 SN - 0022-3727 ER - TY - JOUR A1 - Tuncer, Enis T1 - Extracting the spectral density function of a binary composite without a priori assumptions N2 - The spectral representation separates the contributions of geometrical arrangement (topology) and intrinsic constituent properties in a composite. The aim of this Brief Report is to present a numerical algorithm based on the Monte Carlo integration and constrained least-squares methods to resolve the spectral density function for a given system. The numerical method is verified by testing it on the well-known Maxwell Garnett expression. Later, it is applied to a well-studied rock-and-brine system to instruct its utility. The presented method yields significant microstructural information in improving our understanding of how microstructure influences the macroscopic behavior of composites without any intricate mathematics Y1 - 2005 SN - 1098-0121 ER - TY - JOUR A1 - Surovyatkina, E. D. A1 - Kravtsov, Y. A. A1 - Kurths, Jürgen T1 - Fluctuation growth and saturation in nonlinear oscillators on the threshold of bifurcation of spontaneous symmetry breaking N2 - We study prebifurcation fluctuation amplification in nonlinear oscillators subject to bifurcations of spontaneous symmetry breaking which are manifest in the doubling of stable equilibrium states. Our theoretical estimates of both the linear growth and the nonlinear saturation of the fluctuations are in good agreement with our results from numerical simulations. We show that in the saturation mode, the fluctuation variance is proportional to the standard deviation of the external noise, whereas in the linear mode, the fluctuation variance is proportional to the noise variance. It is demonstrated that the phenomenon of prebifurcation noise amplification is more pronounced in the case of a slow transition through the bifurcation point. The amplification of fluctuations in this case makes it easier to form a symmetric probability of the final equilibrium states. In contrast, for a fast transition through the bifurcation point, the effect of amplification is much less pronounced. Under backward and forward passages through the bifurcation point, a loop of noise-dependent hysteresis emerges here. We find that for a fast transition of the nonlinear oscillator through the bifurcation point, the probability symmetry of the final equilibrium states is destroyed Y1 - 2005 SN - 1539-3755 ER - TY - JOUR A1 - Stiller, Burkhard A1 - Geue, Thomas A1 - Morawetz, Knut A1 - Saphiannikova, Marina T1 - Optical patterning in azobenzene polymer films N2 - Thin azobenzene polymer films show a very unusual property, namely optically induced material transport. The underlying physics for this phenomenon has not yet been thoroughly explained. Nevertheless, this effect enables one to inscribe different patterns onto film surfaces, including one- and two-dimensional periodic structures. Typical sizes of such structures are of the order of micrometers, i.e. related to the interference pattern made by the laser used for optical excitation. In this study we have measured the mechanical properties of one- and two-dimensional gratings, with a high lateral resolution, using force-distance curves and pulse force mode of the atomic force microscope. We also report on the generation of considerably finer structures, with a typical size of 100 nm, which were inscribed onto the polymer surface by the tip of a scanning near-field optical microscope used as an optical pen. Such inscription not only opens new application possibilities but also gives deeper insight into the fundamentals physics underlying optically induced material transport Y1 - 2005 SN - 0022-2720 ER - TY - JOUR A1 - Tuncer, Enis A1 - Wegener, Michael A1 - Gerhard, Reimund T1 - Modeling electro-mechanical properties of layered electrets : application of the finite-element method N2 - We present calculations on the deformation of two- and three-layer electret systems. The electrical field is coupled with the stress-strain equations by means of the Maxwell stress tensor. In the simulations, two-phase systems are considered, and intrinsic relative dielectric permittivity and Young's modulus of the phases are altered. The numerically calculated electro-mechanical activity is compared to an analytical expression. Simulations are performed on two- and three-layer systems. Various parameters in the model are systematically varied and their influence on the resulting piezoelectricity is estimated. In three-layer systems with bipolar charge, the piezoelectric coefficients exhibit a strong dependence on the elastic moduli of the phases. However, with mono-polar charge, there is no significant piezoelectric effect. A two-dimensional simulation illustrated that higher piezoelectric coefficients can be obtained for non-uniform surface charges and low Poisson's ratio of phases. Irregular structures considered exhibit low piezoelectric activity compared to two-layer structures. (C) 2004 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0304-3886 ER - TY - JOUR A1 - Sremcevic, Miodrag A1 - Krivov, Alexander V. A1 - Krüger, Harald A1 - Spahn, Frank T1 - Impact-generated dust clouds around planetary satellites : model versus Galileo N2 - This paper focuses on tenuous dust clouds of Jupiter's Galilean moons Europa, Ganymede and Callisto. In a companion paper (Sremcevic et al., Planet. Space Sci. 51 (2003) 455-471) an analytical model of impact-generated ejecta dust clouds surrounding planetary satellites has been developed. The main aim of the model is to predict the asymmetries in the dust clouds which may arise from the orbital motion of the parent body through a field of impactors. The Galileo dust detector data from flybys at Europa, Ganymede and Callisto are compatible with the model, assuming projectiles to be interplanetary micrometeoroids. The analysis of the data suggests that two interplanetary impactor populations are most likely the source of the measured dust clouds: impactors with isotropically distributed velocities and micrometeoroids in retrograde orbits. Other impactor populations, namely those originating in the Jovian system, or interplanetary projectiles with low orbital eccentricities and inclinations, or interstellar stream particles, can be ruled out by the statistical analysis of the data. The data analysis also suggests that the mean ejecta velocity angle to the normal at the satellite surface is around 30°, which is in agreement with laboratory studies of the hypervelocity impacts. © 2004 Elsevier Ltd. All rights reserved Y1 - 2005 SN - 0032-0633 ER - TY - JOUR A1 - Shabunin, A. A1 - Astakhov, Vladimir V. A1 - Kurths, Jürgen T1 - Quantitative analysis of chaotic synchronization by means of coherence N2 - We use an index of chaotic synchronization based on the averaged coherence function for the quantitative analysis of the process of the complete synchronization loss in unidirectionally coupled oscillators and maps. We demonstrate that this value manifests different stages of the synchronization breaking. It is invariant to time delay and insensitive to small noise and distortions, which can influence the accessible signals at measurements. Peculiarities of the synchronization destruction in maps and oscillators are investigated Y1 - 2005 SN - 1539-3755 ER - TY - JOUR A1 - Zoller, Gert A1 - Holschneider, Matthias A1 - Ben-Zion, Yehuda T1 - The role of heterogeneities as a tuning parameter of earthquake dynamics N2 - We investigate the influence of spatial heterogeneities on various aspects of brittle failure and seismicity in a model of a large strike-slip fault. The model dynamics is governed by realistic boundary conditions consisting of constant velocity motion of regions around the fault, static/kinetic friction laws, creep with depth-dependent coefficients, and 3-D elastic stress transfer. The dynamic rupture is approximated on a continuous time scale using a finite stress propagation velocity ("quasidynamic model''). The model produces a "brittle- ductile'' transition at a depth of about 12.5 km, realistic hypocenter distributions, and other features of seismicity compatible with observations. Previous work suggested that the range of size scales in the distribution of strength-stress heterogeneities acts as a tuning parameter of the dynamics. Here we test this hypothesis by performing a systematic parameter-space study with different forms of heterogeneities. In particular, we analyze spatial heterogeneities that can be tuned by a single parameter in two distributions: ( 1) high stress drop barriers in near- vertical directions and ( 2) spatial heterogeneities with fractal properties and variable fractal dimension. The results indicate that the first form of heterogeneities provides an effective means of tuning the behavior while the second does not. In relatively homogeneous cases, the fault self-organizes to large-scale patches and big events are associated with inward failure of individual patches and sequential failures of different patches. The frequency-size event statistics in such cases are compatible with the characteristic earthquake distribution and large events are quasi-periodic in time. In strongly heterogeneous or near-critical cases, the rupture histories are highly discontinuous and consist of complex migration patterns of slip on the fault. In such cases, the frequency-size and temporal statistics follow approximately power-law relations Y1 - 2005 SN - 0033-4553 ER - TY - JOUR A1 - Schellnhuber, Hans Joachim A1 - Crutzen, P. J. A1 - Clark, W. C. A1 - Hunt, J. T1 - Earth system analysis for sustainability N2 - Anthropogenic interference has resulted in climate change, ocean acidification, eutrophication and toxic pollution of the earth and it's ecosystems. The Earth System Analysis is an international research program on global environmental change to understand these processes in order to work towards global sustainability Y1 - 2005 SN - 0013-9157 ER - TY - JOUR A1 - Sava, Ion A1 - Bruma, Maria A1 - Schulz, Burkhard A1 - Köpnick, Thomas T1 - Comparison of properties of silicon-containing poly(amide-imide)s N2 - New silicon-containing poly(amide-imide)s have been synthesized by direct polycondensation of various aromatic diamines with a dicarboxylic acid containing the dimethylsilylene group and preformed in-tide cycles. These polymers are easily soluble in polar amidic solvents such as N-methylpyrrolidinone (NMP) or dimethylformamide (DMF) and can be cast into thin flexible films or coatings from such solutions. They show high thermal stability, with initial decomposition temperature being above 400 C and glass transition temperature in the range of 220-270 degrees C. Very thin polymer films deposited by spincoating technique onto silicon wafers showed a smooth, pinhole-free surface in atomic force microscopy investigations Y1 - 2005 SN - 0954-0083 ER - TY - JOUR A1 - Saphiannikova, Marina A1 - Neher, Dieter T1 - Thermodynamic theory of light-induced material transport in amorphous azobenzene polymer films N2 - It was discovered 10 years ago that the exposure of an initially flat layer of an azobenzene-containing polymer to an inhomogeneous light pattern leads to the formation of surface relief structures, accompanied by a mass transport over several micrometers. However, the driving force of this process is still unclear. We propose a new thermodynamic approach that explains a number of experimental findings including the light-induced deformation of free-standing films and the formation of surface relief gratings for main inscription geometries. Our basic assumption is that under homogeneous illumination, an initially isotropic sample should stretch itself along the polarization direction to compensate the entropy decrease produced by the photoinduced reorientation of azobenzene chromophores. The magnitude of the elastic stress, estimated by taking the derivative of the free energy over the sample deformation, is shown to be sufficient to induce plastic deformation of the polymer film. Orientational distributions of chromophores predicted by our model are compared with those deduced from Raman intensity measurements Y1 - 2005 SN - 1520-6106 ER - TY - JOUR A1 - Schneider, M. A1 - Teuchner, Klaus A1 - Leupold, Dieter T1 - Two-photon fluorescence of ocular melanomas. Studies on a new diagnostic method N2 - Choroidal melanoma is the most frequent form of primary neoplasia among malignant ocular tumors. Since it is presumed that metastasis often occurs before the primary tumor is first diagnosed, early detection is exigent. The aim of the studies described in this report was to develop an objective, noninvasive method for the diagnosis of choroidal melanoma. The underlying new principle of fluorescence excitation is presented. This is based on the observation that melanin, due to its unique absorption characteristics, is selectively excited into fluorescence via stepwise absorption of two photons of a femtosecond laser emitting at 800 nm. In the experiment described, the fluorescence of excised tissue from healthy choroidal pigment epithelium was compared to that of excised choroidal melanoma. The fluorescence of choroidal melanomas exhibited a more reddish appearance and less intensity than that of healthy tissue. This implies that the configuration of melanin apparently changes during the process of malignant degeneration. The method described here could thus serve as an evidentiary objective diagnostic technique before initiating treatment for choroidal melanomas Y1 - 2005 SN - 0941-293X ER - TY - JOUR A1 - Romano, Maria Carmen A1 - Thiel, M. A1 - Kurths, Jürgen A1 - Kiss, Istvan Z. A1 - Hudson, J. L. T1 - Detection of synchronization for non-phase-coherent and non-stationary data N2 - We present a new method to detect phase as well as generalized synchronization in a wide class of complex systems. It is based on the recurrences of the system's trajectory to the neighborhood of a former state in phase space. We illustrate the applicability of the algorithm for the paradigmatic chaotic Rossler system in the funnel regime and for noisy data, where other methods to detect phase synchronization fail. Furthermore, we demonstrate for electrochemical experiments that the method can easily detect phase and generalized synchronization in non-phase- coherent and even non-stationary time series Y1 - 2005 SN - 0295-5075 ER - TY - JOUR A1 - Saparin, P. I. A1 - Thomsen, J. S. A1 - Prohaska, Steffen A1 - Zaikin, Alexei A1 - Kurths, Jürgen A1 - Hege, H. C. A1 - Gowin, W. T1 - Quantification of spatial structure of human proximal tibial bone biopsies using 3D measures of complexity N2 - Changes in trabecular bone composition during development of osteoporosis are used as a model for bone loss in microgravity conditions during a space flight. Symbolic dynamics and measures of complexity are proposed and applied to assess quantitatively the structural composition of bone tissue from 3D data sets of human tibia bone biopsies acquired by a micro-CT scanner. In order to justify the newly proposed approach, the measures of complexity of the bone architecture were compared with the results of traditional 2D bone histomorphometry. The proposed technique is able to quantify the structural loss of the bone tissue and may help to diagnose and to monitor changes in bone structure of patients on Earth as well as of the space-flying personnel. © 2005 Elsevier Ltd. All rights reserved Y1 - 2005 SN - 0094-5765 ER - TY - JOUR A1 - Varykhalov, Andrei A1 - Rader, Oliver A1 - Gudat, Wolfgang T1 - Structure and quantum-size effects in a surface carbide : W(110)/C-R(15 X 3) N2 - Results of the combined investigation of atomic and electronic structure of the W(110)/C-R(15x3) surface carbide are reported. A variety of experimental techniques has been involved such as scanning tunneling microscopy (STM), low-energy electron diffraction, x-ray photoelectron spectroscopy, and angle-resolved photoemission (ARPES). Distance-dependent STM measurements show a nontrivial geometrical behavior in the topography data, demonstrating five different patterns representing the superstructure at different values of the tip-surface separation. Atomic resolution was achieved at lower tunneling gap resistance. An unexpected spatial asymmetry in the distribution of the local density of states across the surface unit cell has been observed as well. Photoelectron spectroscopy of C1s and W4f core levels clarifies the nature of the chemical bonding in the system. The band mapping with ARPES provides information on the wave- vector dependence of the electronic states. Notable quantum size and superlattice effects were discovered in the dispersion of the valence-band states. The experimental data suggests an apparent one-dimensional character of the electronic structure. Lateral quantization and umklapp scattering are proposed as explanation. Finally, based on photoemission and STM measurements, an improved crystallographic model of the tungsten surface carbide is introduced Y1 - 2005 SN - 1098-0121 ER - TY - JOUR A1 - Rappich, J. A1 - Hartig, P. A1 - Nickel, N. H. A1 - Sieber, I. A1 - Schulze, S. A1 - Dittrich, T. T1 - Stable electrochemically passivated Si surfaces by ultra thin benzene-type layers N2 - Ultra thin organic layers of benzene-type molecules are able to passivate Si surfaces. The organic layers were electrochemically deposited on Si surfaces from aqueous solution of diazonium compounds and show a blocking of the charge transfer from Si into the electrolyte after the deposition process. Electron microscopic images reveal a compact and homogeneous organic layer of 4-bromobenzene on the Si. The surface recombination increases only slightly with respect to a well H-passivated Si surface, so that the interface state density is about 10(11) cm(2) or slightly below. Organic layer modified Si surfaces are much longer stable in ambient air than the H-terminated surface as observed by a slower decay of the integrated photoluminescence intensity with time. Thermal desorption measurements show that the organic layer is stable up to about 200 degrees C. Y1 - 2005 SN - 0167-9317 ER - TY - JOUR A1 - Poschel, T. A1 - Brilliantov, Nikolai V. A1 - Schwager, T. T1 - Transient clusters in granular gases N2 - The most striking phenomenon in the dynamics of granular gases is the formation of clusters and other structures. We investigate a gas of dissipatively colliding particles with a velocity dependent coefficient of restitution where cluster formation occurs as a transient phenomenon. Although for small impact velocity the particles collide elastically, surprisingly the temperature converges to zero Y1 - 2005 SN - 0953-8984 ER - TY - JOUR A1 - Qiu, X. L. A1 - Wegener, Michael A1 - Wirges, Werner A1 - Zhang, X. Q. A1 - Hillenbrand, J. A1 - Xia, Zhongfu A1 - Gerhard, Reimund A1 - Sessler, G. M. T1 - Penetration of sulfur hexafluoride into cellular polypropylene films and its effect on the electric charging and electromechanical response of ferroelectrets N2 - Cellular polypropylene (PP) films were treated with sulfur hexafluoride (SF6) gas in order to study the SF6 penetration behaviour and optimize the electric charging conditions. There were differences in the penetration of SF6 for different cellular PP materials, depending on the microscopic properties, which manifest themselves in the voided structure as well as in the mechanical stiffnesses of the cellular films. The penetration of SF6 after long-term pressure treatment is confirmed in strongly inflated cellular PP films with a low mechanical stiffness of about 1 MPa. No SF6 penetration occurs for slightly inflated cellular PP films with smaller void sizes and higher mechanical stiffnesses of around 5.8 MPa. The observed thickness variations, the higher charging fields during corona charging because of SF6 penetration and the SF6 environment, as well as the resulting electromechanical properties are discussed Y1 - 2005 SN - 0022-3727 ER - TY - JOUR A1 - Pietsch, Ullrich A1 - Panzner, Tobias A1 - Leitenberger, Wolfram A1 - Vartanyants, Ivan A. T1 - Coherence experiments using white synchrotron radiation N2 - Experiments at the bending magnet beamline at BESSY II (EDR beamline) profit from the excellent coherence properties of third generation synchrotron sources. Considering the exponentially decaying incident spectrum, and because no optical elements are installed except slits and vacuum windows, coherence experiments can be performed between 5 keV < E < 15 keV. First, the energy dependence of spatial coherence properties were determined measuring diffraction at single and double pinholes. Next, the coherent white radiation was used to probe the morphology of thin films in reflection geometry. The recorded intensity maps (reflectivity versus sample position) provide speckle patterns which reveal the locally varying sample morphology. Setting the incident angle, alpha(i), smaller or larger than the critical angle of total external reflection, alpha(c), one should be able to separate the surface height profile from the subsurface density modulation of a sample. The validity of this approach is verified at the example of reciprocal space maps taken from a polymer surface where we could reconstruct the lateral height profile from speckle data. (C) 2004 Elsevier B.V. All rights reserved Y1 - 2005 ER - TY - JOUR A1 - Penacorada, Florencio A1 - Souto, Jorge A1 - de Saja, J. A. A1 - Brehmer, Ludwig T1 - Brewster angle microscopy and surface potential measurements of Langmuir-Blodgett films of zinc tri(tert-butyl)- 4-sulphophthalocyanine N2 - The formation of a Langmuir monolayer of an amphiphilic derivative of zinc phthalocyanine (Na[(ZnPcSO3)-S-t]) has been studied by means of surface potential technique and Brewster angle microscopy. The experiments were undertaken in order to understand the behaviour of this monolayer with a well-defined surface pressure isotherm. The floating film is described as a truly monomolecular layer formed by very rigid islands in which the phthalocyanine units tend to take on a preferential orientation with their planes perpendicular to the air-water interface, for high values of the surface pressure. (c) 2004 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0169-4332 ER - TY - JOUR A1 - Pietsch, Ullrich A1 - Panzner, Tobias A1 - Pfeiffer, Franz A1 - Robinson, Ian K. T1 - Substrate morphology repetition in "thick" polymer films N2 - Using Grazing-incidence small-angle scattering (GISAXS) technique we investigated the surface morphology of polymer films spin-coated on different silicon substrates. As substrates we used either technologically smooth silicon wafers or the same silicon wafer coated with thin aluminium or gold films which show a granular structure at the surface. Although the polymer thickness exceeds 300 nm the GISAXS pattern of the film shows the same in-plane angle distribution Delta2theta as the underlying substrate. Annealing the polymer films at a temperature above its glass transition temperature Delta2theta changed from a broad to a narrow distribution as it is typically for films on pure silicon. The experiment can be interpreted by roughness replication and density fluctuation within the polymer film created while spin-coating at room temperature. Due to the low segment mobility there are density fluctuations which repeat the surface morphology of the substrate. Above the glass temperature the polymer density can be homogenized independently from the morphology of the substrate. (C) 2004 Elsevier B.V. All rights reserved Y1 - 2005 ER - TY - JOUR A1 - Schneider, J. A1 - Fernandez, V. A1 - Hernandez-Garcia, E. T1 - Leaking method approach to surface transport in the Mediterranean Sea from a numerical ocean model N2 - We use Lagrangian diagnostics (the leaking and the exchange methods) to characterize surface transport out of and between selected regions in the Western Mediterranean. Velocity fields are obtained from a numerical model. Residence times of water of Atlantic origin in the Algerian subbasin, with a strong seasonal dependence, are calculated. Exchange rates between these waters and the ones occupying the northern basin are also evaluated. At surface, northward transport is dominant, and involves filamental features and eddy structures that can be identified with the Algerian eddies. The impact on these results of the presence of small scale turbulent motions is evaluated by adding Lagrangian diffusion. (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0924-7963 ER - TY - JOUR A1 - Varykhalov, Andrei A1 - Shikin, A. M. A1 - Gudat, Wolfgang A1 - Moras, P. A1 - Grazioli, C. A1 - Carbone, C. A1 - Rader, Oliver T1 - Probing the ground state electronic structure of a correlated electron system by quantum well states: Ag/ Ni(111) N2 - The ground state electronic properties of the strongly correlated transition metal Ni are usually not accessible from the excitation spectra measured in photoelectron spectroscopy. We show that the bottom of the Ni d band along [111] can be probed through the energy dependence of the phase of quantum-well states in Ag/Ni(111). Our model description of the quantum-well energies measured by angle-resolved photoemission determines the bottom of the Lambda(1) d band of Ni as 2.6 eV, in full agreement with standard local density theory and at variance with the values of 1.7-1.8 eV from direct angle-resolved photoemission experiments of Ni Y1 - 2005 SN - 0031-9007 ER - TY - BOOK A1 - Ostermeyer, Martin A1 - Kappe, Philip A1 - Menzel, Ralf A1 - Sommer, S. A1 - Dausinger, Friedrich T1 - Laser drilling in thin materials with bursts of ns-pulses generated by stimulated Brillouin scattering (SBS) N2 - A passively Q-switched laser with a nonlinear mirror on the basis of stimulated Brillouin scattering (SBS), generates bursts of pulses with a few 10 ns pulse duration and a separation between 20-90 mu s. Percussion drilling and trepanning are performed in different materials with 1 mm thickness. The optimum parameter set of these pulse trains with regard to the burr height and ablation rate is investigated. Differences in the processing results between single pulse and multi pulse structures are discussed. In addition the laser allowed for transiently mode locked operation. Results for mode locked and merely Q-switched operation were compared Y1 - 2005 ER - TY - BOOK A1 - Ostermeyer, Martin A1 - Kappe, Philip A1 - Menzel, Ralf A1 - Wulfmeyer, Volker T1 - Diode-pumped Nd : YAG master oscillator power amplifier with high pulse energy, excellent beam quality, and frequency-stabilized master oscillator as a basis for a next-generation lidar system N2 - A pulsed, diode-laser-pumped Nd:YAG master oscillator power amplifier (MOPA) in rod geometry, frequency stabilized with a modified Pound-Drever-Hall scheme is presented. The apparatus delivers 33-ns pulses with a maximum pulse energy of 0.5 J at 1064 nm. The system was set up in two different configurations for repetition rates of 100 or 250 Hz. The beam quality was measured to be 1.5 times the diffraction limit at a pulse energy of 405 mJ and a repetition rate of 100 Hz. At 250 Hz with the same pulse energy, the M-2 was better than 2.1. The radiation is frequency converted with an efficiency of 50% to 532 nm. This MOPA system will be the pump laser of transmitters for a variety of high-end, scanning lidar systems. (C) 2005 Optical Society of America Y1 - 2005 ER - TY - BOOK A1 - Ostermeyer, Martin A1 - Brandenburg, Ingo T1 - Simulation of the extraction of near diffraction limited Gaussian beams from side pumped core doped ceramic Nd:YAG and conventional laser rods N2 - The application of the recently developed core doped ceramic Nd:YAG rods has the potential to provide better beam qualities compared to conventional rods since the hard aperture of the rod's boundary can be made wider while the width of the gain region remains the same. Thus, beam truncation and consequential diffraction can be reduced. We apply a finite elements model to calculate the resulting refractive index profiles in conventional and core doped rods. Propagating a Gaussian beam through both rod geometries the impact of aberrations and diffraction is compared for different side pumped scenarios. The potential advantage of the core doped geometry is discussed. (c) 2005 Optical Society of America Y1 - 2005 ER - TY - JOUR A1 - Oskinova, Lidia M. T1 - Evolution of X-ray emission from young massive star clusters N2 - The evolution of X-ray emission from young massive star clusters is modelled, taking into account the emission from the stars as well as from the cluster wind. It is shown that the level and character of the soft (0.2-10 keV) X-ray emission change drastically with cluster age and are tightly linked with stellar evolution. Using the modem X-ray observations of massive stars, we show that the correlation between bolometric and X-ray luminosity known for single O stars also holds for O + O and (Wolf-Rayet) WR + O binaries. The diffuse emission originates from the cluster wind heated by the kinetic energy of stellar winds and supernova explosions. To model the evolution of the cluster wind, the mass and energy yields from a population synthesis are used as input to a hydrodynamic model. It is shown that in a very young cluster the emission from the cluster wind is low. When the cluster evolves, WR stars are formed. Their strong stellar winds power an increasing X-ray emission of the cluster wind. Subsequent supernova explosions pump the level of diffuse emission even higher. Clusters at this evolutionary stage may have no X-ray-bright stellar point sources, but a relatively high level of diffuse emission. A supernova remnant may become a dominant X-ray source, but only for a short time interval of a few thousand years. We retrieve and analyse Chandra and XMM-Newton observations of six massive star clusters located in the Large Magellanic Cloud (LMC). Our model reproduces the observed diffuse and point-source emission from these LMC clusters, as well as from the Galactic clusters Arches, Quintuplet and NGC 3603 Y1 - 2005 SN - 0035-8711 ER - TY - JOUR A1 - Volkov, E. I. A1 - Ullner, Ekkehard A1 - Kurths, Jürgen T1 - Stochastic multiresonance in the coupled relaxation oscillators N2 - We study the noise-dependent dynamics in a chain of four very stiff excitable oscillators of the FitzHugh- Nagumo type locally coupled by inhibitor diffusion. We could demonstrate frequency- and noise-selective signal acceptance which is based on several noise-supported stochastic attractors that arise owing to slow variable diffusion between identical excitable elements. The attractors have different average periods distinct from that of an isolated oscillator and various phase relations between the elements. We explain the correspondence between the noise-supported stochastic attractors and the observed resonance peaks in the curves for the linear response versus signal frequency. (C) 2005 American Institute of Physics Y1 - 2005 SN - 1054-1500 ER - TY - JOUR A1 - Osipov, Grigory V. A1 - Ivanchenko, Mikhail V. A1 - Kurths, Jürgen A1 - Hu, B. T1 - Synchronized chaotic intermittent and spiking behavior in coupled map chains N2 - We study phase synchronization effects in a chain of nonidentical chaotic oscillators with a type-I intermittent behavior. Two types of parameter distribution, linear and random, are considered. The typical phenomena are the onset and existence of global (all-to-all) and cluster (partial) synchronization with increase of coupling. Increase of coupling strength can also lead to desynchronization phenomena, i.e., global or cluster synchronization is changed into a regime where synchronization is intermittent with incoherent states. Then a regime of a fully incoherent nonsynchronous state (spatiotemporal intermittency) appears. Synchronization-desynchronization transitions with increase of coupling are also demonstrated for a system resembling an intermittent one: a chain of coupled maps replicating the spiking behavior of neurobiological networks Y1 - 2005 SN - 1539-3755 ER - TY - JOUR A1 - Orgzall, Ingo A1 - Franco, Olga A1 - Reck, Guenter A1 - Schulz, Burkhard T1 - High-pressure studies on fluorine substituted 2,5-di(phenyl)-1,3,4-oxadiazoles N2 - Results are presented from structural and high-pressure investigations on four differently but symmetrically fluorine substituted 2,5di(phenyl)-1,3,4-oxadiazoles. The substitution pattern includes the para-, meta-, or ortho- substitution and the fully fluorinated 2,5-bis(pentafluorophenyl)-1,3,4-oxadiazole. The crystal structure depends on the molecular structure and results in a different high-pressure behavior. Parameters for the Murnaghan equation of state (EOS) are determined for every compound and the anisotropic pressure response of the crystal lattice is discussed. Although the EOS parameters, bulk modulus K. and its pressure derivative K'(o) are of the same order of magnitude for all four compounds, the anisotropy of strain is noticeably different. (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0022-2860 ER - TY - JOUR A1 - Negretti, Antonio A1 - Calarco, T. A1 - Cirone, M. A. A1 - Recati, A. T1 - Performance of quantum phase gates with cold trapped atoms N2 - We examine the performance of a quantum phase gate implemented with cold neutral atoms in microtraps, when anharmonic traps are employed and the effects of finite temperature are also taken into account. Both the anharmonicity and the temperature are found to pose limitations to the performance of the quantum gate. We present a quantitative analysis of the problem and show that the phase gate has a high quality performance for the experimental values that are presently or in the near future achievable in the laboratory Y1 - 2005 ER - TY - JOUR A1 - Muzikante, I. A1 - Fonavs, E. A1 - Tokmakov, A. A1 - Cepite, D. A1 - Stiller, Burkhard A1 - Brehmer, Ludwig A1 - Neilands, O. T1 - Optical and electrical properties of oriented thin films of oligomer containing betaine-type moiety in side chain N2 - Non-linear optical and electrical properties of polymer films obtained by dipole orientation of active units are reported. Novel polar oligomer with N-(indan-1,3-dion-2-yl)pyridinium betaine (IPB) as a side group is studied. Orientation of polar groups in oligomer thin films causes an increase of the photo-induced change of surface potential on irradiation in the region of photo-induced electron transfer (PIET) where the IPB group exhibits a reversible change of the value and sign of the dipole moment. At longer wavelengths, the value of the surface potential of the oligomer may be determined by transport of photo-generated charge carriers Y1 - 2005 SN - 0370-1972 ER - TY - JOUR A1 - Motter, Adilson E. A1 - Zhou, Changsong A1 - Kurths, Jürgen T1 - Enhancing complex-network synchronization N2 - Heterogeneity in the degree (connectivity) distribution has been shown to suppress synchronization in networks of symmetrically coupled oscillators with uniform coupling strength (unweighted coupling). Here we uncover a condition for enhanced synchronization in weighted networks with asymmetric coupling. We show that, in the optimum regime, synchronizability is solely determined by the average degree and does not depend on the system size and the details of the degree distribution. In scale-free networks, where the average degree may increase with heterogeneity, synchronizability is drastically enhanced and may become positively correlated with heterogeneity, while the overall cost involved in the network coupling is significantly reduced as compared to the case of unwcighted coupling Y1 - 2005 SN - 0295-5075 ER - TY - JOUR A1 - Mellinger, Axel A1 - Singh, Rajeev A1 - Gerhard, Reimund T1 - Fast thermal-pulse measurements of space-charge distributions in electret polymers N2 - Space-charge depth profiles in various electret polymers have been measured in both the time and the frequency domain using thermal pulses and waves, respectively. A comparison of the two techniques on corona-charged polytetrafluoroethylene showed that the thermal-pulse method yielded similar results as the thermal-wave technique, but approximately 20-50 times faster. The article discusses sensitivity limitations as well as possible applications, including the real-time monitoring of space-charge decay under UV irradiation. (C) 2005 American Institute of Physics Y1 - 2005 SN - 0034-6748 ER - TY - JOUR A1 - Mechau, Norman A1 - Saphiannikova, Marina A1 - Neher, Dieter T1 - Dielectric and mechanical properties of azobenzene polymer layers under visible and ultraviolet irradiation N2 - Photoinduced changes in the mechanical and dielectric properties of azobenzene polymer films were measured utilizing the method of electromechanical spectroscopy. The measurements revealed a strong correlation between the time- dependent behavior of the plate compliance and the dielectric constant under irradiation. Actinic light causes a light softening of the film that also manifests itself in the increase of the dielectric constant, whereas ultraviolet irradiation results in an initial plasticization of the film followed by its hardening. The latter is accompanied by decrease of the dielectric constant. A semiquantitative model based on the kinetics of the photoisomerization process in azobenzene polymers is proposed. We assume that both visible and ultraviolet irradiation increase the free volume in the layer due to photoisomerization. Additionally, ultraviolet light increases the modulus of the polymer matrix due to the presence of a high density of azobenzene moieties in the cis state. These assumptions allowed us to reproduce the time- dependent behavior of the bulk compliance as well as the dielectric constant at different irradiation intensities, for both visible and ultraviolet light, with only two adjustable parameters Y1 - 2005 SN - 0024-9297 ER - TY - JOUR A1 - Materzanini, G. A1 - Tantardini, G. F. A1 - Lindan, P. J. D. A1 - Saalfrank, Peter T1 - Water adsorption at metal surfaces : a first-principles study of the p(root 3x root 3)R30 degrees H2O bilayer on Ru(0001) N2 - In the light of recent intensity-voltage low energy electron diffraction (LEED-IV) experiments [Surf. Sci. 316, 92 (1994); Surf. Rev. Lett. 10, 487 (2003)], the electronic and geometric structure of a water bilayer adsorbed at the Ru(0001) surface are investigated through first-principles total energy calculations, using periodic slab geometries and gradient-corrected density functional theory (DFT). We consider five possible bilayer structures, all roughly consistent with the LEED-IV analysis (three intact structures and two half-dissociated), and a water single layer at Ru(0001). Adsorption energies and substrate-adsorbate geometry parameters are given and discussed in the light of the experiments. We also give a comparative analysis of the electron density redistribution (Delta rho) and of the dipole moment change (Delta mu) induced by water adsorption on the Ru(0001) surface. In agreement with Feibelman [Science 295, 99 (2002)], the half-dissociated structures are found to be more stable than the intact ones, and their adsorption geometries in better agreement with the LEED-IV data. However, the Delta rho analysis shows that a half-dissociated structure induces a Delta mu>0, which would be incompatible with the experimentally measured decrease of the work function following bilayer adsorption; the latter would be consistent, instead, with the Delta mu < 0 induced by the intact structures. It is the aim of this paper to compare various possible adsorption structures, most of them already considered previously, with one and the same method. For this purpose, thick slabs and restrictive computational parameters are chosen to generally address the accuracy and the limits of DFT in reproducing adsorption energies and bond lengths of water-metal interacting systems Y1 - 2005 SN - 1098-0121 ER - TY - JOUR A1 - Marwan, Norbert A1 - Kurths, Jürgen T1 - Line structures in recurrence plots N2 - Recurrence plots exhibit line structures which represent typical behaviour of the investigated system. The local slope of these line structures is connected with a specific transformation of the time scales of different segments of the phase-space trajectory. This provides us a better understanding of the structures occurring in recurrence plots. The relationship between the time-scales and line structures are of practical importance in cross recurrence plots. Using this relationship within cross recurrence plots, the time-scales of differently sampled or time- transformed measurements can be adjusted. An application to geophysical measurements illustrates the capability of this method for the adjustment of time-scales in different measurements. (C) 2005 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0375-9601 ER - TY - JOUR A1 - Maraun, Douglas A1 - Kurths, Jürgen T1 - Epochs of phase coherence between El Nino/Southern Oscillation and Indian monsoon N2 - We present a modern method used in nonlinear time series analysis to investigate the relation of two oscillating systems with respect to their phases, independently of their amplitudes. We study the difference of the phase dynamics between El Nino/Southern Oscillation (ENSO) and the Indian Monsoon on inter-annual time scales. We identify distinct epochs, especially two intervals of phase coherence, 1886 - 1908 and 1964 - 1980, corroborating earlier findings from a new point of view. A significance test shows that the coherence is very unlikely to be the result of stochastic fluctuations. We also detect so far unknown periods of coupling which are invisible to linear methods. These findings suggest that the decreasing correlation during the last decades might be a typical epoch of the ENSO/ Monsoon system having occurred repeatedly. The high time resolution of the method enables us to present an interpretation of how volcanic radiative forcing could cause the coupling Y1 - 2005 SN - 0094-8276 ER - TY - JOUR A1 - Motter, Adilson E. A1 - Zhou, Changsong A1 - Kurths, Jürgen T1 - Network synchronization, diffusion, and the paradox of heterogeneity N2 - Many complex networks display strong heterogeneity in the degree (connectivity) distribution. Heterogeneity in the degree distribution often reduces the average distance between nodes but, paradoxically, may suppress synchronization in networks of oscillators coupled symmetrically with uniform coupling strength. Here we offer a solution to this apparent paradox. Our analysis is partially based on the identification of a diffusive process underlying the communication between oscillators and reveals a striking relation between this process and the condition for the linear stability of the synchronized states. We show that, for a given degree distribution, the maximum synchronizability is achieved when the network of couplings is weighted and directed and the overall cost involved in the couplings is minimum. This enhanced synchronizability is solely determined by the mean degree and does not depend on the degree distribution and system size. Numerical verification of the main results is provided for representative classes of small-world and scale-free networks Y1 - 2005 SN - 1063-651X ER - TY - JOUR A1 - Lyubimov, Dmitry V. A1 - Straube, Arthur V. A1 - Lyubimova, T. P. T1 - Capture of particles of dust by convective flow N2 - Interaction of particles of dust with vortex convective flows is under theoretical consideration. It is assumed that the volume fraction of solid phase is small, variations of density due to nonuniform distribution of particles and those caused by temperature nonisothermality of medium are comparable. Equations for the description of thermal buoyancy convection of a dusty medium are developed in the framework of the generalized Boussinesq approximation taking into account finite velocity of particle sedimentation. The capture of a cloud of dust particles by a vortex convective flow is considered, general criterion for the formation of such a cloud is obtained. The peculiarities of a steady state in the form of a dust cloud and backward influence of the solid phase on the carrier flow are studied in detail for a vertical layer heated from the sidewalls. It is shown that in the case, when this backward influence is essential, a hysteresis behavior is possible. The stability analysis of the steady state is performed. It turns out that there is a narrow range of governing parameters, in which such a steady state is stable. (c) 2005 American Institute of Physics Y1 - 2005 SN - 1070-6631 ER - TY - JOUR A1 - Lopez, S. A1 - Reimers, Dieter A1 - Gregg, M. D. A1 - Wisotzki, Lutz A1 - Wucknitz, Olaf A1 - Guzman, A. T1 - Metal abundances in a damped Ly alpha system along two lines of sight at z=0.93 N2 - We study metal abundances in the z = 0.9313 damped Ly alpha system observed along the two lines of sight, A and B, toward the gravitationally lensed double QSO HE 0512-3329. Spatially resolved Space Telescope Imaging Spectrograph spectra constrain the neutral-gas column density to be N(H I) = 1020.5 cm(-2) in both A and B. UV-visual Echelle Spectrograph spectra ( spectral resolution FWHM = 9.8 km s(-1)) show, in contrast, significant line-of-sight differences in the column densities of Mn II and Fe II; these are not due to observational systematics. We find that [Mn/H] = -1.44 and [Fe/H] = -1.52 in damped Ly alpha system A, while [Mn/H] = -0.98 and [Fe/H] > -1.32, and possibly as high as [Fe/H] approximate to -1, in damped Ly alpha system B. A careful assessment of possible systematic errors leads us to conclude that these transverse differences are significant at a 5 sigma level or greater. Although nucleosynthesis effects may also be at play, we favor differential dust depletion as the main mechanism producing the observed abundance gradient. The transverse separation is 5 h(70)(-1) kpc at the redshift of the absorber, which is also likely to be the lensing galaxy. The derived abundances therefore probe two opposite sides of a single galaxy hosting both damped Ly alpha systems. This is the first time firm abundance constraints have been obtained for a single damped system probed by two lines of sight. The significance of this finding for the cosmic evolution of metals is discussed Y1 - 2005 SN - 0004-637X ER - TY - JOUR A1 - Liang, Jin-Rong A1 - Moshel, Shay A1 - Zivotofsky, Ari Z. A1 - Caspi, Avi A1 - Engbert, Ralf A1 - Kliegl, Reinhold A1 - Havlin, Shlomo T1 - Scaling of horizontal and vertical fixational eye movements N2 - Eye movements during fixation of a stationary target prevent the adaptation of the visual system to continuous illumination and inhibit fading of the image. These random, involuntary, small movements are restricted at long time scales so as to keep the target at the center of the field of view. Here we use detrended fluctuation analysis in order to study the properties of fixational eye movements at different time scales. Results show different scaling behavior between horizontal and vertical movements. When the small ballistic movements, i.e., microsaccades, are removed, the scaling exponents in both planes become similar. Our findings suggest that microsaccades enhance the persistence at short time scales mostly in the horizontal component and much less in the vertical component. This difference may be due to the need for continuously moving the eyes in the horizontal plane, in order to match the stereoscopic image for different viewing distances Y1 - 2005 SN - 1063-651X ER - TY - JOUR A1 - Kulesh, Michail A. A1 - Diallo, Mamadou Sanou A1 - Holschneider, Matthias T1 - Wavelet analysis of ellipticity, dispersion, and dissipation properties of Rayleigh waves N2 - This paper is devoted to the digital processing of multicomponent seismograms using wavelet analysis. The goal of this processing is to identify Rayleigh surface elastic waves and determine their properties. A new method for calculating the ellipticity parameters of a wave in the form of a time-frequency spectrum is proposed, which offers wide possibilities for filtering seismic signals in order to suppress or extract the Rayleigh components. A model of dispersion and dissipation of elliptic waves written in terms of wavelet spectra of complex (two-component) signals is also proposed. The model is used to formulate a nonlinear minimization problem that allows for a high-accuracy calculation of the group and phase velocities and the attenuation factor for a propagating elliptic Rayleigh wave. All methods considered in the paper are illustrated with the use of test signals. (c) 2005 Pleiades Publishing, Inc Y1 - 2005 SN - 1063-7710 ER - TY - JOUR A1 - Kuhlbrodt, B. A1 - Orndahl, E. A1 - Wisotzki, Lutz A1 - Jahnke, Knud T1 - High-redshift quasar host galaxies with adaptive optics N2 - We present K band adaptive optics observations of three high-redshift ( z similar to 2.2) high-luminosity quasars, all of which were studied for the first time. We also observed several point spread function ( PSF) calibrators, non-simultaneously because of the small field of view. The significant temporal PSF variations on timescales of minutes inhibited a straightforward scaled PSF removal from the quasar images. Characterising the degree of PSF concentration by the radii encircling 20% and 80% of the total flux, respectively, we found that even under very different observing conditions the r(20) vs. r(80) relation varied coherently between individual short exposure images, delineating a well-defined relation for point sources. Placing the quasar images on this relation, we see indications that all three objects were resolved. We designed a procedure to estimate the significance of this result, and to estimate host galaxy parameters, by reproducing the statistical distribution of the individual short exposure images. We find in all three cases evidence for a luminous host galaxy, with a mean absolute magnitude of M-R = - 27.0 and scale lengths around similar to 4 - 12 kpc. Together with a rough estimate of the central black hole masses obtained from C.. line widths, the location of the objects on the bulge luminosity vs. black hole mass relation is not significantly different from the low-redshift regime, assuming only passive evolution of the host galaxy. Corresponding Eddington luminosities are L-nuc/L-Edd similar to 0.1 - 0.6 Y1 - 2005 SN - 0004-6361 ER - TY - JOUR A1 - Kubas, Daniel A1 - Cassan, A. A1 - Beaulieu, Jean-Philippe A1 - Coutures, C. A1 - Dominik, M. A1 - Albrow, Michael D. A1 - Brillant, Stephane A1 - Caldwell, John A. R. A1 - Dominis, Dijana A1 - Donatowicz, J. A1 - Fendt, Christian A1 - Fouque, P. A1 - Jorgensen, Uffe Grae A1 - Greenhill, John A1 - Hill, K. A1 - Heinmüller, Janine A1 - Horne, Keith A1 - Kane, Stephen R. A1 - Marquette, Jean-Baptiste A1 - Martin, Ralph A1 - Menzies, J. W. A1 - Pollard, K. R. A1 - Sahu, K. C. A1 - Vinter, C. A1 - Wambsganss, Joachim A1 - Watson, R. A1 - Williams, A. A1 - Thurl, C. T1 - Full characterization of binary-lens event OGLE-2002-BLG-069 from PLANET observations N2 - We analyze the photometric data obtained by PLANET and OGLE on the caustic-crossing binary-lens microlensing event OGLE-2002-BLG-069. Thanks to the excellent photometric and spectroscopic coverage of the event, we are able to constrain the lens model up to the known ambiguity between close and wide binary lenses. The detection of annual parallax in combination with measurements of extended-source effects allows us to determine the mass, distance and velocity of the lens components for the competing models. While the model involving a close binary lens leads to a Bulge- Disc lens scenario with a lens mass of M = (0.51 ± 0.15) M-&ODOT; and distance of D-L = (2.9 ± 0.4) kpc, the wide binary lens solution requires a rather implausible binary black-hole lens ( M &GSIM; 126 M-&ODOT;). Furthermore we compare current state-of-the-art numerical and empirical models for the surface brightness profile of the source, a G5III Bulge giant. We find that a linear limb-darkening model for the atmosphere of the source star is consistent with the data whereas a PHOENIX atmosphere model assuming LTE and with no free parameter does not match our observations Y1 - 2005 SN - 0004-6361 ER - TY - JOUR A1 - Krivov, Alexander V. A1 - Sremcevic, Miodrag A1 - Spahn, Frank T1 - Evolution of a Keplerian disk of colliding and fragmenting particles: a kinetic model with application to the Edgeworth-Kuiper belt N2 - We present a kinetic model of a disk of solid particles, orbiting a primary and experiencing inelastic collisions. In distinction to other collisional models that use a 2D (mass-sernimajor axis) binning and perform a separate analysis of the velocity (eccentricity, inclination) evolution, we choose mass and orbital elements as independent variables of a phase space. The distribution function in this space contains full information on the combined mass, spatial, and velocity distributions of particles. A general kinetic equation for the distribution function is derived, valid for any set of orbital elements and for any collisional outcome, specified by a single kernel function. The first implementation of the model utilizes a 3D phase space (mass-semimajor axis-eccentricity) and involves averages over the inclination and all angular elements. We assume collisions to be destructive, simulate them with available material- and size-dependent scaling laws, and include collisional damping. A closed set of kinetic equations for a mass-semimajor axis-eccentricity distribution is written and transformation rules to usual mass and spatial distributions of the disk material are obtained. The kinetic "core" of our approach is generic. It is possible to add inclination as an additional phase space variable, to include cratering collisions and agglomeration, dynamical friction and viscous stirring, gravity of large perturbers, drag forces, and other effects into the model. As a specific application, we address the collisional evolution of the classical population in the Edgeworth-Kuiper belt (EKB). We run the model for different initial disk's masses and radial profiles and different impact strengths of objects. Our results for the size distribution, collisional timescales, and mass loss are in agreement with previous studies. In particular, collisional evolution is found to be most substantial in the inner part of the EKB, where the separation size between the survivors over EKB ' s age and fragments of earlier collisions lies between a few and several tens of km. The size distribution in the EKB is not a single Dohnanyi-type power law, reflecting the size dependence of the critical specific energy in both strength and gravity regimes. The net mass loss rate of an evolved disk is nearly constant and is dominated by disruption of larger objects. Finally, assuming an initially uniform distribution of orbital eccentricities, we show that an evolved disk contains more objects in orbits with intermediate eccentricities than in nearly circular or more eccentric orbits. This property holds for objects of any size and is explained in terms of collisional probabilities. The effect should modulate the eccentricity distribution shaped by dynamical mechanisms, such as resonances and truncation of perihelia by Neptune. (c) 2004 Elsevier Inc. All rights reserved Y1 - 2005 SN - 0019-1035 ER - TY - JOUR A1 - Nehls, B. S. A1 - Fuldner, S. A1 - Preis, E. A1 - Farrell, Tony A1 - Scherf, Ullrich T1 - Microwave-assisted synthesis of 1,5-and 2,6-linked naphthylene-based ladder polymers N2 - A series of novel arylene ladder polymers incorporating conjugated 1,5- and 2,6-naphthylene building blocks were synthesized. The polyketone ladder polymer precursors were prepared via a palladium-mediated Suzuki-type cross- coupling reaction using both conventional and microwave heating. While the 2,6-naphthylene polyketone precursor (2,6- NPK) was accessible from both heating protocols. the 1,5-naphthylene linked polyketones were only accessible via microwave-assisted (uW) procedures. and the polymer 1,5-NLP2 is the first example of a ladder polymer consisting exclusively of alternating six-membered rings prepared from this reaction sequence. The solution optical spectra of the final naphthylene ladder polymers exhibit the characteristic spectral shapes with a steep absorption edge and a vibronic fine structure common to fully rigidified ladder structures. The structural modification of the substitution pattern and the linkage positions at the naphthylene unit allows some tuning of the absorption and emission bands of the ladder polymers. The 2,6-naphthylene derivative exhibits an intense blue photoluminescence, while the two 1,5-naphthylene- linked ladder polymers exhibit a red shift of the 0-0 electronic transitions, leading to a blue-green photoluminescence Y1 - 2005 SN - 0024-9297 ER - TY - JOUR A1 - Kietzke, Thomas A1 - Stiller, Burkhard A1 - Landfester, Katharina A1 - Montenegro, Rivelino V. D. A1 - Neher, Dieter T1 - Probing the local optical properties of layers prepared from polymer nanoparticles N2 - It is well known that the performance of solar cells based on a blend of hole-accepting and electron-accepting conjugated polymers as the active material depend crucially on the length scale of the resulting phase separated morphology. However, a direct control of this morphology is difficult if the layer is prepared from an organic solvent. To circumvent this difficulty, recently a universal method to fabricate defined nano-structured blend layer using nanoparticles dispersed in water was demonstrated. These nanoparticles were prepared with the miniemulsion method, which allows for the preparation of semiconducting polymer nanospheres (SPNs) with diameters in the range of 30 to 300 nanometres. Since the process starts from the active material dissolved in a common solvent, it can be applied to the fabrication of nanoparticles of blends of polymers with oligomers or even with inorganic materials. We present here for the first time scanning near field optical microscopy (SNOM) investigations on these novel nanostructured polymer layers. We show that by spin-coating a mixture of two different dispersions a nanoparticle monolayer with a statistically distribution of the nanoparticles can be obtained. Mixing conjugated polymer nanoparticles with some inert particles like polystyrene beads may allow for the preparation of nano-sized light emitters Y1 - 2005 SN - 0379-6779 ER - TY - JOUR A1 - Karageorgiev, Peter A1 - Neher, Dieter A1 - Schulz, Burkhard A1 - Stiller, Burkhard A1 - Pietsch, Ullrich A1 - Giersig, Michael A1 - Brehmer, Ludwig T1 - From anisotropic photo-fluidity towards nanomanipulation in the optical near-field N2 - An increase in random molecular vibrations of a solid owing to heating above the melting point leads to a decrease in its long-range order and a loss of structural symmetry. Therefore conventional liquids are isotropic media. Here we report on a light-induced isothermal transition of a polymer film from an isotropic solid to an anisotropic liquid state in which the degree of mechanical anisotropy can be controlled by light. Whereas during irradiation by circular polarized light the film behaves as an isotropic viscoelastic fluid, it shows considerable fluidity only in the direction parallel to the light field vector under linear polarized light. The fluidization phenomenon is related to photoinduced motion of azobenzene-functionalized molecular units, which can be effectively activated only when their transition dipole moments are oriented close to the direction of the light polarization. We also describe here how the photofluidization allows nanoscopic elements of matter to be precisely manipulated Y1 - 2005 SN - 1476-1122 ER - TY - JOUR A1 - Kappe, Philip A1 - Ostermeyer, Martin A1 - Menzel, Ralf T1 - Active mode locking of a phase-conjugating SBS-laser oscillator N2 - We present a flashlamp-pumped Nd: YAG laser simultaneously emitting pulse structures on microsecond, nanosecond and picosecond time scales. Within a microsecond flashlamp pump pulse a nonlinear reflector based on stimulated Brillouin scattering (SBS) generates several Q-switch pulses. The phase-conjugating effect of the SBS reflector provides a compensation of phase distortions generated inside the laser rod, resulting in transverse fundamental mode operation. Additional acousto-optic loss modulation inside the resonator leads to mode locking. As a result, each Q-switch pulse is subdivided into several picosecond pulses. Energies of up to 2 mJ for the mode-locked pulses with durations between 220 and 800 ps are demonstrated. The wide variability of the laser's temporal output parameters as well as its high beam quality make it a splendid tool for fundamental research in laser materials processing Y1 - 2005 SN - 0946-2171 ER - TY - JOUR A1 - Kalkbrenner, T. A1 - Hakanson, U. A1 - Schadle, A. A1 - Burger, S. A1 - Henkel, Carsten A1 - Sandoghdar, Vahid T1 - Optical microscopy via spectral modifications of a nanoantenna N2 - The existing optical microscopes form an image by collecting photons emitted from an object. Here we report on the experimental realization of microscopy without the need for direct optical communication with the sample. To achieve this, we have scanned a single gold nanoparticle acting as a nanoantenna in the near field of a sample and have studied the modification of its intrinsic radiative properties by monitoring its plasmon spectrum Y1 - 2005 SN - 0031-9007 ER - TY - JOUR A1 - Makuch, Martin A1 - Krivov, Alexander V. A1 - Spahn, Frank T1 - Long-term dynamical evolution of dusty ejecta from Deimos N2 - We re-assess expected properties of the presumed dust belt of Mars formed by impact ejecta from Deimos. Previous studies have shown that dynamics of Deimos particles are dominated by two perturbing forces: radiation pressure (RP) and Mars' oblateness (J2). At the same time, they have demonstrated that lifetimes of particles, especially of grains about ten of micrometers in size, may reach more than 10(4) years. On such timescales, the Poynting-Robertson drag (PR) becomes important. Here we provide a study of the dynamics under the combined action of all three perturbing forces. We show that a PR decay of the semimajor axes leads to an adiabatic decrease of amplitudes and periods of oscillations in orbital inclinations predicted in the framework of the underlying RP+J2 problem. Furthermore, we show that smallest of the long-lived Deimos grains (radius approximate to 5-10 mum) may reach a chaotic regime, resulting in unpredictable and abrupt changes of their dynamics. The particles just above that size (approximate to 10- 15 mum) should be the most abundant in the Deimos torus. Our dynamical analysis, combined with a more accurate study of the particle lifetimes, provides corrections to earlier predictions about the dimensions and geometry of the Deimos torus. In addition to a population, appreciably inclined and shifted towards the Sun, the torus should contain a more contracted, less asymmetric, and less tilted component between the orbits of Phobos and Deimos. (C) 2004 Elsevier Ltd. All rights reserved Y1 - 2005 SN - 0032-0633 ER - TY - JOUR A1 - Jarosz, Grazyna A1 - Quinn, P. D. A1 - Stephan, Niels A1 - Brehmer, Ludwig T1 - Dielectric properties of zinc phthalocyanine thin films : effects of annealing in air and in N-2 N2 - This work presents the effects of ambient conditions, in particular oxygen and humidity, on the dielectric spectra of thin zinc phthalocyanine (ZnPc) films equipped with interdigitated electrodes and the effect of annealing in dry N-2 or in ambient air. The measurements were performed in the frequency range 10(-2)-10(5) Hz. The results indicate that the electric properties of ZnPc films are not only affected by oxygen but also by water vapour the presence of which always leads to the drop in alternating current conductance (ac-conductance). Moreover, at room temperature, the ac-conductance of ZnPc films previously exposed to air exhibits a reversible change with humidity, which makes these films attractive for humidity sensing applications. (C) 2004 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0040-6090 ER - TY - JOUR A1 - Huber, C. A1 - Klamroth, Tillmann T1 - Simulation of two-photon-photoelectron spectra at a jellium-vacuum interface N2 - In this paper we report on time dependent configuration interaction singles (TD-CIS) calculations aimed at simulating two-photon-photoelectron emission (2PPE) spectra of metal films, the latter treated within a one-dimensional jellium model. The method is based on a many-electron approach in which electron-electron-scattering is approximately accounted for and no artificial lifetimes have to be assumed for excited electrons. This contrasts with one-electron models where lifetimes and "dissipation" have to be introduced. The driving force for the photoelectron ejection in 2PPE experiments is the electric field of two laser pulses that are generally separated by a delay time, Delta t. To compute energy- and time-resolved 2PPE signals P(E, Delta t), a new scheme based on the time-energy method is proposed to analyze electronic wave packets in asymptotic regions of the potential Y1 - 2005 ER - TY - JOUR A1 - Holzer, Wolfgang A1 - Penzkofer, Alfons A1 - Schrader, Sigurd A1 - Grimm, Bernhard T1 - Photo-physical and lasing characterisation of a polyparaphenylenevinylene (PPV) neat film N2 - The wave-guided travelling-wave laser action (amplified spontaneous emission) of a neat film of poly(p- phenylenevinylene) (PPV) on a quartz glass substrate prepared by a sulfinyl precursor technique is studied. The samples are transversally pumped with picosecond excitation pulses (wavelength 347.15 nm, duration 35 ps). Lasing occurs at 550 nm. The optical constants of the neat films are determined by transmittance measurements exploiting the multiple beam interference in the transparency region. A fluorescence spectroscopic characterisation is carried out determining the fluorescence quantum distribution, fluorescence quantum yield, degree of fluorescence polarisation, and fluorescence lifetime. The emitting chromophore size (emitting singlet exciton extension) is determined by the ratio of exciton radiative lifetime to repeat-unit based radiative lifetime. The obtained size of about two repeat units is discussed in a disordered solid-state polymer model Y1 - 2005 SN - 0306-8919 ER - TY - JOUR A1 - Heringer-Walther, Silvia A1 - Moreira, M. C. V. A1 - Wessel, Niels A1 - Saliba, J. L. A1 - Silvia-Barra, J. A1 - Pena, J. L. B. A1 - Becker, S. A1 - Siems, W. E. A1 - Schultheiss, H. P. A1 - Walther, T. T1 - Brain natriuretic peptide predicts survival in Chagas' disease more effectively than atrial natriuretic peptide Y1 - 2005 SN - 1355-6037 ER - TY - JOUR A1 - Henkel, Carsten A1 - Joulain, Karl T1 - Casimir force between designed materials : what is possible and what not N2 - We establish strict upper limits for the Casimir interaction between multilayered structures of arbitrary dielectric or diamagnetic materials. We discuss the appearance of different power laws due to frequency-dependent material constants. Simple analytical expressions are in good agreement with numerical calculations based on Lifshitz theory. We discuss the improvements required for current ( meta) materials to achieve a repulsive Casimir force Y1 - 2005 SN - 0295-5075 ER - TY - JOUR A1 - Henkel, Carsten T1 - Magnetostatic field noise near metallic surfaces N2 - We develop an effective low-frequency theory of the electromagnetic field in equilibrium with thermal objects. The aim is to compute thermal magnetic noise spectra close to metallic microstructures. We focus on the limit where the material response is characterised by the electric conductivity. At the boundary between empty space and metallic microstructures, a large jump occurs in the dielectric function which leads to a partial screening of low-frequency magnetic fields generated by thermal current fluctuations. We resolve a, discrepancy between two approaches used in the past to compute magnetic field noise spectra close to microstructured materials Y1 - 2005 ER - TY - JOUR A1 - Hainzl, Sebastian A1 - Ogata, Y. T1 - Detecting fluid signals in seismicity data through statistical earthquake modeling N2 - [1] According to the well-known Coulomb failure criterion the variation of either stress or pore pressure can result in earthquake rupture. Aftershock sequences characterized by the Omori law are often assumed to be the consequence of varying stress, whereas earthquake swarms are thought to be triggered by fluid intrusions. The role of stress triggering can be analyzed by modeling solely three-dimensional (3-D) elastic stress changes in the crust, but fluid flows which initiate seismicity cannot be investigated without considering complex seismicity patterns resulting from both pore pressure variations and earthquake-connected stress field changes. We show that the epidemic-type aftershock sequence (ETAS) model is an appropriate tool to extract the primary fluid signal from such complex seismicity patterns. We analyze a large earthquake swarm that occurred in 2000 in Vogtland/NW Bohemia, central Europe. By fitting the stochastic ETAS model, we find that stress triggering is dominant in creating the observed seismicity patterns and explains the observed fractal interevent time distribution. External forcing, identified with pore pressure changes due to fluid intrusion, is found to directly trigger only a few percent of the total activity. However, temporal deconvolution indicates that a pronounced fluid signal initiated the swarm. These results are confirmed by our analogous investigation of model simulations in which earthquakes are triggered by fluid intrusion as well as stress transfers on a fault plane embedded in a 3-D elastic half-space. The deconvolution procedure based on the ETAS model is able to reveal the underlying pore pressure variations Y1 - 2005 SN - 0148-0227 ER - TY - JOUR A1 - Gorfman, S. V. A1 - Tsirelson, Vladimir G. A1 - Pietsch, Ullrich T1 - X-ray diffraction by a crystal in a permanent external electric field : general considerations N2 - The variations of X-ray diffraction intensities from a crystal in the presence of a permanent external electric field is modeled analytically using a first-order stationary perturbation theory. The change in a crystal, induced by an external electric field, is separated into two contributions. The first one is related to a pure polarization of an electron subsystem, while the second contribution can be reduced to the displacements of the rigid pseudoatoms from their equilibrium positions. It is shown that a change of the X-ray diffraction intensities mainly originates from the second contribution, while the influence of the pure polarization of a crystal electron subsystem is negligibly small. The quantities restored from an X-ray diffraction experiment in the presence of an external electric field were analyzed in detail in terms of a rigid pseudoatomic model of electron density and harmonic approximation for the atomic thermal motion. Explicit relationships are derived that link the properties of phonon spectra with E-field-induced variations of a structure factor, pseudoatomic displacements and piezoelectric strains. The displacements can be numerically estimated using a model of independent atomic motion if the Debye - Waller factors and pseudoatomic charges are known either from a previous single-crystal X-ray diffraction study or from density functional theory calculations. The above estimations can be used to develop an optimum strategy for a data collection that avoids the measurements of reflections insensitive to the electric-field-induced variations Y1 - 2005 SN - 0108-7673 ER - TY - JOUR A1 - Goldobin, Denis S. A1 - Pikovskij, Arkadij T1 - Synchronization of self-sustained oscillators by common white noise N2 - We study the stability of self-sustained oscillations under the influence of external noise. For small-noise amplitude a phase approximation for the Langevin dynamics is valid. A stationary distribution of the phase is used for an analytic calculation of the maximal Lyapunov exponent. We demonstrate that for small noise the exponent is negative, which corresponds to synchronization of oscillators. (c) 2004 Elsevier B.V. All rights reserved Y1 - 2005 ER - TY - JOUR A1 - Galbrecht, Frank A1 - Yang, X. H. A1 - Nehls, B. S. A1 - Neher, Dieter A1 - Farrell, Tony A1 - Scherf, Ullrich T1 - Semiconducting polyfluorenes with electrophosphorescent on-chain platinum-salen chromophores N2 - The synthesis of statistical fluorene-type copolymers with on-chain Pt-salen phosphorescent units and their use in electrophosphorescent OLEDs is reported Y1 - 2005 SN - 1359-7345 ER - TY - JOUR A1 - Feudel, Fred A1 - Witt, Annette A1 - Gellert, Marcus A1 - Kurths, Jürgen A1 - Grebogi, Celso A1 - Sanjuan, Miguel Angel Fernandez T1 - Intersections of stable and unstable manifolds : the skeleton of Lagrangian chaos N2 - We study Hamiltonian chaos generated by the dynamics of passive tracers moving in a two-dimensional fluid flow and describe the complex structure formed in a chaotic layer that separates a vortex region from the shear flow. The stable and unstable manifolds of unstable periodic orbits are computed. It is shown that their intersections in the Poincare map as an invariant set of homoclinic points constitute the backbone of the chaotic layer. Special attention is paid to the finite time properties of the chaotic layer. In particular, finite time Lyapunov exponents are computed and a scaling law of the variance of their distribution is derived. Additionally, the box counting dimension as an effective dimension to characterize the fractal properties of the layer is estimated for different duration times of simulation. Its behavior in the asymptotic time limit is discussed. By computing the Lyapunov exponents and by applying methods of symbolic dynamics, the formation of the layer as a function of the external forcing strength, which in turn represents the perturbation of the originally integrable system, is characterized. In particular, it is shown that the capture of KAM tori by the layer has a remarkable influence on the averaged Lyapunov exponents. (C) 2004 Elsevier Ltd. All rights reserved Y1 - 2005 ER - TY - JOUR A1 - Evans, C. J. A1 - Smartt, S. J. A1 - Lee, J. K. A1 - Lennon, D. J. A1 - Kaufer, A. A1 - Dufton, P. L. A1 - Trundle, C. A1 - Herrero, A. A1 - Simon Díaz, Sergio A1 - de Koter, A. A1 - Hamann, Wolf-Rainer A1 - Hendry, M. A. A1 - Hunter, I. A1 - Irwin, M. J. A1 - Korn, A. J. A1 - Kudritzki, R. P. A1 - Langer, Norbert A1 - Mokiem, M. R. A1 - Najarro, F. A1 - Pauldrach, A. W. A. A1 - Przybilla, Norbert A1 - Puls, J. A1 - Ryans, R. S. I. A1 - Urbaneja, M. A. A1 - Venn, K. A. A1 - Villamariz, M. R. T1 - The VLT-FLAMES survey of massive stars : Observations in the Galactic clusters NGC3293, NGC4755 and NGC6611 N2 - We introduce a new survey of massive stars in the Galaxy and the Magellanic Clouds using the Fibre Large Array Multi- Element Spectrograph ( FLAMES) instrument at the Very Large Telescope ( VLT). Here we present observations of 269 Galactic stars with the FLAMES- Giraffe Spectrograph ( R similar or equal to 25 000), in fields centered on the open clusters NGC3293, NGC4755 and NGC6611. These data are supplemented by a further 50 targets observed with the Fibre- Fed Extended Range Optical Spectrograph ( FEROS, R = 48 000). Following a description of our scientific motivations and target selection criteria, the data reduction methods are described; of critical importance the FLAMES reduction pipeline is found to yield spectra that are in excellent agreement with less automated methods. Spectral classifications and radial velocity measurements are presented for each star, with particular attention paid to morphological peculiarities and evidence of binarity. These observations represent a significant increase in the known spectral content of NGC3293 and NGC4755, and will serve as standards against which our subsequent FLAMES observations in the Magellanic Clouds will be compared Y1 - 2005 ER - TY - JOUR A1 - Eisert, Jens T1 - Optimizing linear optics quantum gates N2 - In this Letter, the problem of finding optimal success probabilities of linear optics quantum gates is linked to the theory of convex optimization. It is shown that by exploiting this link, upper bounds for the success probability of networks realizing single-mode gates can be derived, which hold in generality for postselected networks of arbitrary size, any number of auxiliary modes, and arbitrary photon numbers. As a corollary, the previously formulated conjecture is proven that the optimal success probability of a nonlinear sign shift without feedforward is 1/4, a gate playing the central role in the scheme of Knill-Laflamme-Milburn for quantum computation. The concept of Lagrange duality is shown to be applicable to provide rigorous proofs for such bounds, although the original problem is a difficult nonconvex problem in infinitely many objective variables. The versatility of this approach is demonstrated Y1 - 2005 SN - 0031-9007 ER - TY - JOUR A1 - Egbe, D. A. M. A1 - Ulbricht, C. A1 - Orgis, Thomas A1 - Carbonnier, B. A1 - Kietzke, Thomas A1 - Peip, M. A1 - Metzner, M. A1 - Gericke, M. A1 - Birckner, Eckhard A1 - Pakula, T. A1 - Neher, Dieter A1 - Grumm, U. W. T1 - Odd-even effects and the influence of length and specific positioning of alkoxy side chains on the optical properties of PPE-PPV polymers N2 - This contribution reports the combined influences of odd-even effects and the specific positioning of alkoxy side chains OR1 = (OCn+H-10(2(n+10)+1)) and OR2 = (OCnH2n+1) (with n = 6, 7, 8, 9) on the phenylene-ethynylene and phenylene- vinylene segments, respectively, on the optical properties of hybrid polymers P(n+10)/n of general repeating unit: -Ph-C equivalent to C-Ph-C equivalent to C-Ph-CH=CH-Ph-CH=CH-. For the polymeric materials, visual color impression varies alternatively between orange red (P16/6 and P18/8) and yellow (P17/7 and P19/9) according to the odd and even features of the alkoxy side chains, where odd or even relates to the total number of sp(3)-hybridized atoms within the side chains. This side chain related effect is ascribed to both absorptive and emissive behaviors of the polymers on the basis of photophysical investigations in the bulk. Almost identical thin film absorption spectra were obtained for all four materials; however, the photoluminescence of the odd polymers, P16/6 (lambda(f) = 556 nm) and P18/ 8 (lambda(f) = 614 nm), was red-shifted relative to that of their even counterparts (lambda(f) = 535 nm). Further, the P18/8 maximum at 614 nm can be readily assigned to excimer emission, as evidenced by the largest Stokes shift (5600 cm(- 1)), largest fwhmf-value (3700 cm(-1))(,) and the lowest Phi(f)-value of 24%. The strong pi-pi interchain interaction in P18/8, due to loose alkoxy side chains packing, does not only favor fluorescence quenching but also enable an effective inter- as well as intra-molecular recombination of the generated positive and negative polarons in electrolurninescence, which explains the good EL properties of this polymer irrespective of the solvent used. A voltage-dependent blue shift of the EL spectra of up to 100 nm was observed for P18/8 devices prepared from aromatic solvents. This red to green EL shift as observed with increasing voltage is assigned to conformational changes of the polymer chains with increasing temperature Y1 - 2005 SN - 0897-4756 ER -