TY - JOUR A1 - León, Santiago A1 - Cardona, Agustín A1 - Mejia Velez, Dany A1 - Botello, G. E. A1 - Villa, Víctor A1 - Collo, Gilda A1 - Valencia, Victor A. A1 - Zapata, Sebastian Henao A1 - Avellaneda-Jimenez, D. S. T1 - Source area evolution and thermal record of an Early Cretaceous back-arc basin along the northwesternmost Colombian Andes JF - Journal of South American earth sciences N2 - Identifying the provenance signature and geodynamic setting on which sedimentary basins at convergent margins grow is challenging since they result from coupled erosional and tectonic processes, which shape the evolution of source areas and the stress regime. The Early Cretaceous evolution of the northern Andes of Colombia is characterized by extensional tectonics and the subsequent formation of a marginal basin. The Abejorral Formation and coeval volcano-sedimentary rocks are exposed along the western flank and axis of the Central Cordillera. They comprise an Early Cretaceous transgressive sequence initially accumulated in fluvial deltaic environments, which switched towards a deep-marine setting, and are interpreted as the infilling record of a marginal back-arc basin. Available provenance data suggest that Permian-Triassic metamorphic and less abundant Jurassic magmatic rocks forming the basement of the Central Cordillera sourced the Abejorral Formation. New detailed volcanic and metamorphic lithics analyses, conventional and varietal study of heavy minerals, detrital rutile mineral chemistry, allowed us to document changes in the source areas defined by the progressive appearance of both higher-grade and more distal low-grade metamorphic sources, which switched from pelitic to dominantly mafic in composition. Crystallochemical indexes of clay minerals of fine-grained rocks of the Abejorral Formation suggest that samples located close to the Romeral Fault System show characteristics of low-medium P-T low-grade metamorphism, whereas rocks located farther to the northeast preserve primary diagenetic features, which suggest a high heat-flow accumulation setting. We interpret that the Abejorral Formation records the progressive unroofing of the Central Cordillera basement that was being rapidly exhumed, as well as the incorporation of distal subduction-related metamorphic complexes to the west in response either to the widening of extensional front or the reactivation of fault structures on the oceanward margin of the basin. Although the deformational record of the Abejorral Formation would have resulted from over-imposed episodes, our new geochronological constraints suggest that this sedimentary sequence must have been deformed before the Paleocene due to the presence of arc-related intrusive non-deformed magmatic rocks with a crystallization age of ca. 60 Ma. KW - Back-arc basin KW - Northern Andes KW - Early cretaceous KW - Provenance KW - Clay mineralogy KW - Rutile mineral chemistry Y1 - 2019 U6 - https://doi.org/10.1016/j.jsames.2019.102229 SN - 0895-9811 VL - 94 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Messmer, Tobias A1 - Elsenbeer, Helmut A1 - Wilcke, Wolfgang T1 - High exchangeable calcium concentrations in soils on Barro Colorado Island, Panama JF - Geoderma : an international journal of soil science N2 - The soils on four lithologies (basaltic conglomerates, Bohio; Andesite; volcanoclastic sediments with basaltic agglomerates, Caimito volcanic; foraminiferal limestone, Caimito marine) on Barro Colorado Island (BCI have high exchangeable Ca concentrations and cation-exchange capacities (CEC) compared to other tropical soils on similar parent material. In the 0-10 cm layer of 24 mineral soils, pH values ranged from 5.7 (Caimito volcanic and Andesite) to 6.5 (Caimito marine), concentrations of exchangeable Ca from 134 mmol(c) kg(-1) (Caimito volcanic) to 585 mmolc kg-1 (Caimito marine), and cation exchange capacities from 317 mmol(c) kg(-1) (Caimito volcanic) to 933 mmol(c) kg(-1) (Caimito marine). X-ray diffractometry of the fraction <2 mu m revealed that smectites dominated the clay mineral assemblage in soil except on Caimito volcanic, where kaolinite was the dominant clay mineral. Exchangeable Ca concentrations decreased with increasing soil depth except on Caimito marine. The weathering indices Chemical Index of Alteration (CIA), Plagioclase Index of Alteration (PIA) and Weathering Index of Parker (WIP) determined for five soils on all geological formations, suggested that in contrast to expectation the topsoil (0-10 cm) appeared to be the least and the subsoil (50-70 cm) and saprolite (isomorphically weathered rock in the soil matrix) the most weathered. Additionally, the weathering indices indicated depletion of base cations and enrichment of Al-(hydr)oxides throughout the soil profile. Tree species did not have an effect on soil properties. Impeded leaching and the related occurrence of overland flow seem to be important in determining clay mineralogy. Our results suggest that (i) edaphic conditions favor the formation of smectites on most lithologies resulting in high CEC and thus high retention capacity for Ca and (ii) that there is an external source such as dust or sea spray deposition supplying Ca to the soils. KW - Panama KW - Cation-exchange capacity KW - Exchangeable Ca KW - Clay mineralogy KW - Weathering indices Y1 - 2014 U6 - https://doi.org/10.1016/j.geoderma.2013.10.021 SN - 0016-7061 SN - 1872-6259 VL - 217 SP - 212 EP - 224 PB - Elsevier CY - Amsterdam ER -