TY - JOUR A1 - Dunst, Alexander T1 - "After trauma : time and affect in american culture beyond 9/11" Y1 - 2012 SN - 1353-4645 ER - TY - JOUR A1 - Warschburger, Petra A1 - Kröller, Katja T1 - "Childhood overweight and obesity maternal perceptions of the time for engaging in child weight management" JF - BMC public health N2 - Background: There is an increasing awareness of the impact of parental risk perception on the weight course of the child and the parent's readiness to engage in preventive efforts, but only less is known about factors related to the parental perception of the right time for the implementation of preventive activities. The aim of this study was to examine parental perceptions of the appropriate time to engage in child weight management strategies, and the factors associated with different weight points at which mothers recognize the need for preventive actions. Methods: 352 mothers with children aged 2-10 years took part in the study. We assessed mothers' perceptions of the actual and preferred weight status of their child, their ability to identify overweight and knowledge of its associated health risks, as well as perceptions of the right time for action to prevent overweight in their child. A regression analysis was conducted to examine whether demographic and weight related factors as well as the maternal general risk perception were associated with recognizing the need to implement prevention strategies. Results: Although most of the parents considered a BMI in the 75th to 90th percentile a valid reason to engage in the prevention of overweight, 19% of the mothers were not willing to engage in prevention until their child reached the 97th percentile. Whereas the child's sex and the identification of an elevated BMI were significant predictors for parents' recognition of the 75th percentile as right point to engage in prevention efforts, an inability to recognize physical health risks associated with overweight silhouettes emerged as a significant factor predicting which parents would delay prevention efforts until a child's BMI reached the 97th percentile. Conclusion: Parental misperceptions of overweight and associated health risks constitute unfavorable conditions for preventive actions. Feedback on the health risks associated with overweight could help increase maternal readiness for change. KW - Maternal perception KW - Need for action KW - Prevention KW - Obesity KW - Overweight KW - Children Y1 - 2012 U6 - https://doi.org/10.1186/1471-2458-12-295 SN - 1471-2458 VL - 12 IS - 12 PB - BioMed Central CY - London ER - TY - BOOK ED - Krämer, Raimund ED - Kleinwächter, Lutz T1 - "Den Geist der Epoche bezeugen..." : 20 Jahre WeltTrends - Zeitschrift für internationale Politik Y1 - 2012 SN - 978-3-941-880-49-8 PB - WeltTrends CY - Potsdam ER - TY - JOUR A1 - Schröder, Ariane T1 - "Descent into hell" : the cultural and biomedical signification of depression in William Styron's "Darkness Visible" Y1 - 2012 SN - 978-3-631-63614-5 ER - TY - JOUR A1 - Berner, Elisabeth T1 - "Erst wusste ich nicht, was tun …" BT - Das Tagebuch des Dawid Rubinowicz JF - Vielheit und Einheit der Germanistik weltweit Y1 - 2013 SN - 978-3-631-63211-6 IS - 11 SP - 189 EP - 203 PB - Lang CY - Frankfurt am Main ER - TY - JOUR A1 - Dornick, Sahra T1 - "Footnotes to the Family" Performativity to the trauma of the Holocaust in the German-Jewish Family novels "So are we" (Gila Lustiger) and "Family Life" (Viola Roggenkamp) JF - Zeitschrift für Religions- und Geistesgeschichte Y1 - 2012 SN - 0044-3441 VL - 64 IS - 2 SP - 138 EP - 151 PB - Brill CY - Leiden ER - TY - JOUR A1 - Stockhorst, Stefanie T1 - "Geiles 17. Jahrhundert" : zur Barock-Rezeption Thomas Klings Y1 - 2012 SN - 978-3-389971-874-4 ER - TY - JOUR A1 - Szelat, Sebastian A1 - Wehr, Katharina T1 - "Military history editions today new challenges, old problems?" Workshop of the military history research institute, 1-2 June 2012 in Potsdam JF - Militärgeschichtliche Zeitschrift Y1 - 2012 SN - 2193-2336 VL - 71 IS - 2 SP - 398 EP - 402 PB - De Gruyter Oldenbourg CY - Potsdam ER - TY - JOUR A1 - Schwarz, Anja T1 - "That's not a story i could tell" : commemorating the other side of the colonial frontier in Australian literature of reconciliation Y1 - 2012 SN - 978-0-230-30200-6 ER - TY - JOUR A1 - Sutton, Katie T1 - "We too deserve a place in the sun" the politics of transvestiteidentity in Weimar Germany JF - German studies review N2 - Cross-dressing took on new political meanings in Germany's Weimar Republic, with the emergence of organizations and periodicals aimed at promoting the interests of self-identified "transvestites." This new sexological category, developed by Magnus Hirschfeld in 1910, formed the basis for a shared sense of identity and belonging among individuals who identified as members of the "opposite" sex. Drawing on the experiences of the homosexual emancipation movement and discourses of bourgeois respectability, middle-class transvestites came together to demand legal and social recognition, including acknowledgement of "transsexual" desires. Their efforts represent a critical but forgotten moment in the history of transgender political activism. Y1 - 2012 SN - 0149-7952 VL - 35 IS - 2 SP - 335 EP - 354 PB - Johns Hopkins Univ. Press CY - Tempe ER - TY - JOUR A1 - Eckstein, Lars T1 - "We're destroyed if we mix : and we're destroyed if we don't" : indigeneity in the modern world system and the politics of tricksterese in Pauline Melville's the ventriloquist's tale Y1 - 2012 SN - 978-3-938944- 60-8 ER - TY - JOUR A1 - Raphael-Hernandez, Heike T1 - 'Yes, I will blow up this place, but first I have my coffee.' Representations of Arab Americans in post-9/11 American Films Y1 - 2012 SN - 978-38-2553-5891-4 ER - TY - JOUR A1 - Göse, Frank T1 - ... die Racce davon so guht ist, das sie auf alle art meritiret, conserviret zu werden : das Verhältnis Friedrichs des Grossen zum brandenburgischen Adel Y1 - 2012 SN - 978-3-86732-138-9 ER - TY - JOUR A1 - Kammer, Stefan A1 - Starke, Ines A1 - Pietrucha, Andreas A1 - Kelling, Alexandra A1 - Mickler, Wulfhard A1 - Schilde, Uwe A1 - Dosche, Carsten A1 - Kleinpeter, Erich A1 - Holdt, Hans-Jürgen T1 - 1,12-Diazaperylene and 2,11-dialkylated-1,12-diazaperylene iridium(III) complexes [Ir((CN)-N-boolean AND)(2)((NN)-N-boolean AND)]PF6: new supramolecular assemblies JF - Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry N2 - A series of new monocationic iridium(III) complexes [Ir((CN)-N-boolean AND)(2)((NN)-N-boolean AND)]PF6 with "large-surface" alpha,alpha'-diimin ligands (NN)-N-boolean AND (dap = 1,12-diazaperylene, dmedap = 2,11-dimethyl-1,12-diazaperylene, dipdap = 2,11-diisopropyl-1,12-diazaperylene) and different cyclometalating ligands (CN)-N-boolean AND (piq = 1-phenylisoquinoline, bzq = benzo[h]quinoline, ppz = 1-phenylpyrazole, thpy = 2-(2-thienyl)pyridine, ppy = 2-phenylpyridine, meppy = 2-(4-methylphenyl)pyridine, dfppy = 2-(2,4-difluorophenyl)pyridine) were synthesized. The solid structures of the complexes [Ir(piq)(2)(dap)]PF6, [Ir(bzq)(2)(dap)]PF6, [Ir(ppy)(2)(dipdap)]PF6, [Ir(piq)(2)(dmedap)]PF6, [Ir(ppy)(2)(dap)]PF6 and [Ir(ppz)(2)(dap)]PF6 are reported. In [Ir(piq)(2)(dap)]PF6, the dap ligand and one of the piq ligands of each cationic complex are involved in pi-pi stacking interactions forming supramolecular channels running along the crystallographic c axis. In the crystalline [Ir(bzq)(2)(dap)]PF6 pi-pi stacking interactions between the metal complexes lead to the formation of a 2D layer structure. In addition, CH-pi interactions were found in all compounds, which are what stabilizes the solid structure. In particular, a significant number of them were found in [Ir(piq)(2)(dap)]PF6 and [Ir(bzq)(2)(dap)]PF6. The crystal structures of [Ir(ppy)(2)(dipdap)]PF6 and [Ir(ppy)(2)(dmedap)]PF6 are also presented, being the first examples of bis-cyclometalated iridium(III) complexes with phenanthroline-type alpha,alpha'-diimin ligands bearing bulky alkyl groups in the neighbourhood of the N-donor atoms. These ligands implicate a distorted octahedral coordination geometry that in turn destabilized the Ir-N-N boolean AND N bonds. The new iridium (III) complexes are not luminescent. All compounds show an electrochemically irreversible anodic peak between 1.15 and 1.58 V, which is influenced by the different cyclometalated ligands. All of the new complexes show two reversible successive one-electron "large-surface" ligand-centred reductions around -0.70 V and -1.30 V. Electrospray ionisation mass spectrometry (ESI-MS) and collision induced decomposition (CID) measurements were used to investigate the stability of the new complexes. Thereby, the stability agreed well with the order of the Ir-N-N boolean AND N bond lengths. Y1 - 2012 U6 - https://doi.org/10.1039/c2dt30412k SN - 1477-9226 VL - 41 IS - 34 SP - 10219 EP - 10227 PB - Royal Society of Chemistry CY - Cambridge ER - TY - INPR A1 - Neumann, Mike T1 - 15 years younger chemists GDCh-Forum - the Future firmly in sight T2 - Chemie in unserer Zeit Y1 - 2012 U6 - https://doi.org/10.1002/ciuz.201290028 SN - 0009-2851 VL - 46 IS - 3 SP - 131 EP - 131 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Uhlig, Katja A1 - Madaboosi, Narayanan A1 - Schmidt, Stephan A1 - Jäger, Magnus S. A1 - Rose, Jürgen A1 - Duschl, Claus A1 - Volodkin, Dmitry V. T1 - 3d localization and diffusion of proteins in polyelectrolyte multilayers JF - Soft matter N2 - The interaction of diverse biomaterials with surfaces is more crucial than ever for biomedical applications to ensure efficiency and reproducibility. Very interesting surface materials are micrometer-thick polyelectrolyte multilayers. Not only their surface but also the bulk can be loaded with biomaterials like proteins or DNA for various purposes. Therefore, we established a method to analyze the lateral and vertical distribution of fluorescently labelled proteins of various size and charge in polyelectrolyte films composed of poly(L-lysine) and hyaluronic acid by confocal laser scanning microscopy. This approach enables us to measure the diffusion coefficients of the proteins via fluorescence recovery after photobleaching as a function of their vertical position in the film and facilitates the understanding of molecular interactions in the film with a high resolution in both space and time. As a result, we confirm that protein loading in the film is driven by electrostatic interactions - uncharged dextran molecules of 10 and 500 kDa do not diffuse into the film. Proteins of different sizes (3-11 nm) can diffuse relatively fast (D = 2-4 mm(2) s(-1)) independent of their net charge, indicating complex interpolymer interactions. This approach is a new powerful experimental tool to design the polyelectrolyte multilayers for bio-applications by finding a relationship between intermolecular interactions and mobility and availability of biomolecules to biological samples (e.g. cells) or detection units (e.g. biosensors). Y1 - 2012 U6 - https://doi.org/10.1039/c2sm26500a SN - 1744-683X VL - 8 IS - 47 SP - 11786 EP - 11789 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Thompson, W. T. A1 - Kliem, Bernhard A1 - Toeroek, Tibor T1 - 3D reconstruction of a rotating erupting prominence JF - Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics N2 - A bright prominence associated with a coronal mass ejection (CME) was seen erupting from the Sun on 9 April 2008. This prominence was tracked by both the Solar Terrestrial Relations Observatory (STEREO) EUVI and COR1 telescopes, and was seen to rotate about the line of sight as it erupted; therefore, the event has been nicknamed the "Cartwheel CME." The threads of the prominence in the core of the CME quite clearly indicate the structure of a weakly to moderately twisted flux rope throughout the field of view, up to heliocentric heights of 4 solar radii. Although the STEREO separation was 48A degrees, it was possible to match some sharp features in the later part of the eruption as seen in the 304 line in EUVI and in the H alpha-sensitive bandpass of COR1 by both STEREO Ahead and Behind. These features could then be traced out in three-dimensional space, and reprojected into a view in which the eruption is directed toward the observer. The reconstructed view shows that the alignment of the prominence to the vertical axis rotates as it rises up to a leading-edge height of a parts per thousand aEuro parts per thousand 2.5 solar radii, and then remains approximately constant. The alignment at 2.5 solar radii differs by about 115A degrees from the original filament orientation inferred from H alpha and EUV data, and the height profile of the rotation, obtained here for the first time, shows that two thirds of the total rotation are reached within a parts per thousand aEuro parts per thousand 0.5 solar radii above the photosphere. These features are well reproduced by numerical simulations of an unstable moderately twisted flux rope embedded in external flux with a relatively strong shear field component. KW - Corona, active KW - Prominences, active KW - Coronal mass ejections KW - Initiation and propagation KW - Magnetic fields, corona Y1 - 2012 U6 - https://doi.org/10.1007/s11207-011-9868-5 SN - 0038-0938 VL - 276 IS - 1-2 SP - 241 EP - 259 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Gruden, Kristina A1 - Hren, Matjaz A1 - Herman, Ana A1 - Blejec, Andrej A1 - Albrecht, Tanja A1 - Selbig, Joachim A1 - Bauer, Christian G. A1 - Schuchardt, Johannes A1 - Or-Guil, Michal A1 - Zupancic, Klemen A1 - Svajger, Urban A1 - Stabuc, Borut A1 - Ihan, Alojz A1 - Kopitar, Andreja Natasa A1 - Ravnikar, Maja A1 - Knezevic, Miomir A1 - Rozman, Primoz A1 - Jeras, Matjaz T1 - A "Crossomics" study analysing variability of different components in peripheral blood of healthy caucasoid individuals JF - PLoS one N2 - Background: Different immunotherapy approaches for the treatment of cancer and autoimmune diseases are being developed and tested in clinical studies worldwide. Their resulting complex experimental data should be properly evaluated, therefore reliable normal healthy control baseline values are indispensable. Methodology/Principal Findings: To assess intra- and inter-individual variability of various biomarkers, peripheral blood of 16 age and gender equilibrated healthy volunteers was sampled on 3 different days within a period of one month. Complex "crossomics'' analyses of plasma metabolite profiles, antibody concentrations and lymphocyte subset counts as well as whole genome expression profiling in CD4(+)T and NK cells were performed. Some of the observed age, gender and BMI dependences are in agreement with the existing knowledge, like negative correlation between sex hormone levels and age or BMI related increase in lipids and soluble sugars. Thus we can assume that the distribution of all 39.743 analysed markers is well representing the normal Caucasoid population. All lymphocyte subsets, 20% of metabolites and less than 10% of genes, were identified as highly variable in our dataset. Conclusions/Significance: Our study shows that the intra- individual variability was at least two-fold lower compared to the inter-individual one at all investigated levels, showing the importance of personalised medicine approach from yet another perspective. Y1 - 2012 U6 - https://doi.org/10.1371/journal.pone.0028761 SN - 1932-6203 VL - 7 IS - 1 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Isaeva, Olga B. A1 - Kuznetsov, Sergey P. A1 - Sataev, Igor R. T1 - A "saddle-node" bifurcation scenario for birth or destruction of a Smale-Williams solenoid JF - Chaos : an interdisciplinary journal of nonlinear science N2 - Formation or destruction of hyperbolic chaotic attractor under parameter variation is considered with an example represented by Smale-Williams solenoid in stroboscopic Poincare map of two alternately excited non-autonomous van der Pol oscillators. The transition occupies a narrow but finite parameter interval and progresses in such way that periodic orbits constituting a "skeleton" of the attractor undergo saddle-node bifurcation events involving partner orbits from the attractor and from a non-attracting invariant set, which forms together with its stable manifold a basin boundary of the attractor. Y1 - 2012 U6 - https://doi.org/10.1063/1.4766590 SN - 1054-1500 VL - 22 IS - 4 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Costa, A. C. A1 - Bronstert, Axel A1 - de Araujo, Jose Carlos T1 - A channel transmission losses model for different dryland rivers JF - Hydrology and earth system sciences : HESS N2 - Channel transmission losses in drylands take place normally in extensive alluvial channels or streambeds underlain by fractured rocks. They can play an important role in streamflow rates, groundwater recharge, freshwater supply and channel-associated ecosystems. We aim to develop a process-oriented, semi-distributed channel transmission losses model, using process formulations which are suitable for data-scarce dryland environments and applicable to both hydraulically disconnected losing streams and hydraulically connected losing(/gaining) streams. This approach should be able to cover a large variation in climate and hydro-geologic controls, which are typically found in dryland regions of the Earth. Our model was first evaluated for a losing/gaining, hydraulically connected 30 km reach of the Middle Jaguaribe River (MJR), Ceara, Brazil, which drains a catchment area of 20 000 km(2). Secondly, we applied it to a small losing, hydraulically disconnected 1.5 km channel reach in the Walnut Gulch Experimental Watershed (WGEW), Arizona, USA. The model was able to predict reliably the streamflow volume and peak for both case studies without using any parameter calibration procedure. We have shown that the evaluation of the hypotheses on the dominant hydrological processes was fundamental for reducing structural model uncertainties and improving the streamflow prediction. For instance, in the case of the large river reach (MJR), it was shown that both lateral stream-aquifer water fluxes and groundwater flow in the underlying alluvium parallel to the river course are necessary to predict streamflow volume and channel transmission losses, the former process being more relevant than the latter. Regarding model uncertainty, it was shown that the approaches, which were applied for the unsaturated zone processes (highly nonlinear with elaborate numerical solutions), are much more sensitive to parameter variability than those approaches which were used for the saturated zone (mathematically simple water budgeting in aquifer columns, including backwater effects). In case of the MJR-application, we have seen that structural uncertainties due to the limited knowledge of the subsurface saturated system interactions (i.e. groundwater coupling with channel water; possible groundwater flow parallel to the river) were more relevant than those related to the subsurface parameter variability. In case of the WEGW application we have seen that the non-linearity involved in the unsaturated flow processes in disconnected dryland river systems (controlled by the unsaturated zone) generally contain far more model uncertainties than do connected systems controlled by the saturated flow. Therefore, the degree of aridity of a dryland river may be an indicator of potential model uncertainty and subsequent attainable predictability of the system. Y1 - 2012 U6 - https://doi.org/10.5194/hess-16-1111-2012 SN - 1027-5606 VL - 16 IS - 4 SP - 1111 EP - 1135 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Salazar, S. A1 - Frances, F. A1 - Komma, J. A1 - Blume, Theresa A1 - Francke, Till A1 - Bronstert, Axel A1 - Blöschl, Günter T1 - A comparative analysis of the effectiveness of flood management measures based on the concept of "retaining water in the landscape" in different European hydro-climatic regions JF - Natural hazards and earth system sciences N2 - In this paper, we analyse the effectiveness of flood management measures based on the concept known as "retaining water in the landscape". The investigated measures include afforestation, micro-ponds and small-reservoirs. A comparative and model-based methodological approach has been developed and applied for three meso-scale catchments located in different European hydro-climatological regions: Poyo (184 km(2)) in the Spanish Mediterranean, Upper Iller (954 km(2)) in the German Alps and Kamp (621 km(2)) in Northeast-Austria representing the Continental hydro-climate. This comparative analysis has found general similarities in spite of the particular differences among studied areas. In general terms, the flood reduction through the concept of "retaining water in the landscape" depends on the following factors: the storage capacity increase in the catchment resulting from such measures, the characteristics of the rainfall event, the antecedent soil moisture condition and the spatial distribution of such flood management measures in the catchment. In general, our study has shown that, this concept is effective for small and medium events, but almost negligible for the largest and less frequent floods: this holds true for all different hydro-climatic regions, and with different land-use, soils and morphological settings. Y1 - 2012 U6 - https://doi.org/10.5194/nhess-12-3287-2012 SN - 1561-8633 VL - 12 IS - 11 SP - 3287 EP - 3306 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Ziege, Madlen A1 - Hennige-Schulz, Carmen A1 - Muecksch, Frauke A1 - Bierbach, David A1 - Tiedemann, Ralph A1 - Streit, Bruno A1 - Plath, Martin T1 - A comparison of two methods to assess audience-induced changes in male mate choice JF - Current zoology N2 - Multidirectional communicative interactions in social networks can have a profound effect on mate choice behavior. Male Atlantic molly Poecilia mexicana exhibit weaker mating preferences when an audience male is presented. This could be a male strategy to reduce sperm competition risk: interacting more equally with different females may be advantageous because rivals might copy mate choice decisions. In line with this hypothesis, a previous study found males to show a strong audience effect when being observed while exercising mate choice, but not when the rival was presented only before the choice tests. Audience effects on mate choice decisions have been quantified in poeciliid fishes using association preference designs, but it remains unknown if patterns found from measuring association times translate into actual mating behavior. Thus, we created five audience treatments simulating different forms of perceived sperm competition risk and determined focal males' mating preferences by scoring pre-mating (nipping) and mating behavior (gonopodial thrusting). Nipping did not reflect the pattern that was found when association preferences were measured, while a very similar pattern was uncovered in thrusting behavior. The strongest response was observed when the audience could eavesdrop on the focal male's behavior. A reduction in the strength of focal males' preferences was also seen after the rival male had an opportunity to mate with the focal male's preferred mate. In comparison, the reduction of mating preferences in response to an audience was greater when measuring association times than actual mating behavior. While measuring direct sexual interactions between the focal male and both stimulus females not only the male's motivational state is reflected but also females' behavior such as avoidance of male sexual harassment. KW - Communication networks KW - Male mate choice KW - Non-independent mate choice KW - Sexual selection KW - Sperm competition risk KW - Audience effect Y1 - 2012 SN - 1674-5507 VL - 58 IS - 1 SP - 84 EP - 94 PB - Current Zoology CY - Beijing ER - TY - JOUR A1 - Zhang, Zhuo-dong A1 - Wieland, Ralf A1 - Reiche, Matthias A1 - Funk, Roger A1 - Hoffmann, Carsten A1 - Li, Yong A1 - Sommer, Michael T1 - A computational fluid dynamics model for wind simulation: model implementation and experimental validation JF - Journal of Zhejiang University : an international journal ; Science A, Applied physics & engineering : an international applied physics & engineering journal N2 - To provide physically based wind modelling for wind erosion research at regional scale, a 3D computational fluid dynamics (CFD) wind model was developed. The model was programmed in C language based on the Navier-Stokes equations, and it is freely available as open source. Integrated with the spatial analysis and modelling tool (SAMT), the wind model has convenient input preparation and powerful output visualization. To validate the wind model, a series of experiments was conducted in a wind tunnel. A blocking inflow experiment was designed to test the performance of the model on simulation of basic fluid processes. A round obstacle experiment was designed to check if the model could simulate the influences of the obstacle on wind field. Results show that measured and simulated wind fields have high correlations, and the wind model can simulate both the basic processes of the wind and the influences of the obstacle on the wind field. These results show the high reliability of the wind model. A digital elevation model (DEM) of an area (3800 m long and 1700 m wide) in the Xilingele grassland in Inner Mongolia (autonomous region, China) was applied to the model, and a 3D wind field has been successfully generated. The clear implementation of the model and the adequate validation by wind tunnel experiments laid a solid foundation for the prediction and assessment of wind erosion at regional scale. KW - Wind model KW - Computational fluid dynamics (CFD) KW - Wind erosion KW - Wind tunnel experiments KW - Spatial analysis and modelling tool (SAMT) KW - Open source Y1 - 2012 U6 - https://doi.org/10.1631/jzus.A1100231 SN - 1673-565X VL - 13 IS - 4 SP - 274 EP - 283 PB - Zhejiang University Press CY - Hangzou ER - TY - CHAP A1 - Engbert, Ralf T1 - A computational model of microsaccadic responses to shifts of covert attention T2 - Perception Y1 - 2012 SN - 0301-0066 SN - 1468-4233 VL - 41 SP - 55 EP - 55 PB - Sage Publ. CY - London ER - TY - JOUR A1 - Kleinpeter, Erich A1 - Balci, Kubilay A1 - Yapar, G. A1 - Akkaya, S. A1 - Akyuz, S. A1 - Koch, Andreas T1 - A conformational analysis and vibrational spectroscopic investigation on 1,2-bis(o-carboxyphenoxy) ethane molecule N2 - The minima on the potential energy surface of 1,2-bis(o-carboxyphenoxy) ethane (CPE) molecule in its electronic ground state were searched by a molecular dynamics simulation performed with MM2 force field. For each of the found minimum-energy conformers, the corresponding equilibrium geometry, charge distribution, HOMO-LUMO energy gap, force field, vibrational normal modes and associated IR and Raman spectral data were determined by means of the density functional theory (DFT) based electronic structure calculations carried out by using B3LYP method and various Pople- style basis sets. The obtained theoretical data confirmed the significant effects of the intra- and inter-molecular hydrogen bonding interactions on the conformational structure, force field, and group vibrations of the molecule. The same data have also revealed that two of the determined stable conformers, both of which exhibit pseudo-crown structure, are considerably more favorable in energy to the others and accordingly provide the major c ntribution to the experimental spectra of CPE. In the light of the improved vibrational spectral data obtained within the "SQM FF" methodology and "Dual Scale Factors" approach for the monomer and dimer forms of these two conformers, a reliable assignment of the fundamental bands observed in the experimental room-temperature IR and Raman spectra of the molecule was given, and the sensitivities of its group vibratb20s to conformation, substitution and dimerization were discussed. Y1 - 2012 ER - TY - JOUR A1 - Balci, Kubilay A1 - Yapar, G. A1 - Akkaya, Y. A1 - Akyuz, S. A1 - Koch, Andreas A1 - Kleinpeter, Erich T1 - A conformational analysis and vibrational spectroscopic investigation on 1,2-bis(o-carboxyphenoxy) ethane molecule JF - Vibrational spectroscopy : an international journal devoted to applications of infrared and raman spectroscopy N2 - The minima on the potential energy surface of 1,2-bis(o-carboxyphenoxy)ethane (CPE) molecule in its electronic ground state were searched by a molecular dynamics simulation performed with MM2 force field. For each of the found minimum-energy conformers, the corresponding equilibrium geometry, charge distribution, HOMO-LUMO energy gap, force field, vibrational normal modes and associated IR and Raman spectral data were determined by means of the density functional theory (DFT) based electronic structure calculations carried out by using B3LYP method and various Pople-style basis sets. The obtained theoretical data confirmed the significant effects of the intra- and inter-molecular hydrogen bonding interactions on the conformational structure, force field, and group vibrations of the molecule. The same data have also revealed that two of the determined stable conformers, both of which exhibit pseudo-crown structure, are considerably more favorable in energy to the others and accordingly provide the major contribution to the experimental spectra of CPE. In the light of the improved vibrational spectral data obtained within the "SQM FF" methodology and "Dual Scale Factors" approach for the monomer and dimer forms of these two conformers, a reliable assignment of the fundamental bands observed in the experimental room-temperature IR and Raman spectra of the molecule was given, and the sensitivities of its group vibrations to conformation, substitution and dimerization were discussed. KW - Glycol podands KW - Salicylic acid KW - IR and Raman spectra KW - SQM FF KW - Dual Scale Factors Y1 - 2012 U6 - https://doi.org/10.1016/j.vibspec.2011.11.011 SN - 0924-2031 VL - 58 IS - 1-2 SP - 27 EP - 43 PB - Elsevier CY - Amsterdam ER - TY - THES A1 - Hennemann, Anja T1 - A context-sensitive and funktional approach to evidentiality in Spanish or why evidentiality needs a superordinate category T2 - Potsdam Linguistic Investigations Y1 - 2012 SN - 978-3-631-62636-8 VL - 10 PB - Peter Lang CY - Frankfurt am Main, New York ER - TY - JOUR A1 - Schewe, Jacob A1 - Levermann, Anders A1 - Cheng, Hai T1 - A critical humidity threshold for monsoon transitions JF - Climate of the past : an interactive open access journal of the European Geosciences Union N2 - Monsoon systems around the world are governed by the so-called moisture-advection feedback. Here we show that, in a minimal conceptual model, this feedback implies a critical threshold with respect to the atmospheric specific humidity q(o) over the ocean adjacent to the monsoon region. If q(o) falls short of this critical value q(o)(c), monsoon rainfall over land cannot be sustained. Such a case could occur if evaporation from the ocean was reduced, e.g. due to low sea surface temperatures. Within the restrictions of the conceptual model, we estimate q(o)(c) from present-day reanalysis data for four major monsoon systems, and demonstrate how this concept can help understand abrupt variations in monsoon strength on orbital timescales as found in proxy records. Y1 - 2012 U6 - https://doi.org/10.5194/cp-8-535-2012 SN - 1814-9324 VL - 8 IS - 2 SP - 535 EP - 544 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Ettlinger, Julia A1 - Schenk, Jörg A. A1 - Micheel, Burkhard A1 - Ehrentreich-Förster, Eva A1 - Gajovic-Eichelmann, Nenad T1 - A direct competitive homogeneous immunoassay for progesterone - the Redox Quenching Immunoassay JF - Electroanalysis : an international journal devoted to fundamental and practical aspects of electroanalysis N2 - A direct competitive amperometric immunoassay format for the detection of haptens and proteins was developed. The method is based on the quenching of electroactivity of ferrocenium, which is coupled to the antigen and used as the primary reporter, upon binding to a monoclonal anti-ferrocenium antibody, which is coupled to the detection antibody and used as a secondary reporter. A separation-free progesterone immunoassay with a lower detection limit of 1 ng?mL-1 (3.18 nmol?L-1) in 1?:?2 diluted blood serum was realised by combining two bifunctional conjugates, a ferrocenium-PEG-progesterone tracer and a bioconjugate of one anti-progesterone and one anti-ferrocenium antibody. The immune complex is formed within 30 s upon addition of progesterone, resulting in a total analysis time of 1.5 min. KW - Immunoassay KW - Amperometry KW - Ferrocene KW - Progesterone Y1 - 2012 U6 - https://doi.org/10.1002/elan.201200107 SN - 1040-0397 VL - 24 IS - 7 SP - 1567 EP - 1575 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Struch, Georg T1 - A distributional analysis of recent reform proposals on the german income tax rate JF - Jahrbücher für Nationalökonomie und Statistik = Journal of economics and statistics N2 - The present paper investigates potential fiscal and distributional effects which emerge due to four reform scenarios on the German income tax rate. The analysis is based on a static simulation model for the German tax system using income tax micro-data. The data shows that changing the present progressive tax system to a flat-tax, which was proposed by the FDP in 2010, could reduce the tax revenue by 15 billion Euro. Such a tax regime would increase the unequal distribution and polarisation of net incomes. The IW Koln suggested an alternative tax rate in 2008. This regime would increase unequal distribution and polarisation of disposable incomes to a greater extent than the FDP-tax rate. An implementation of this income tax scale would go along with losses in tax revenue of 18.8 billion Euro. Likewise, the implementation of a 2009 SPD tax rate proposal would reduce tax revenue by 14.8 billion Euro. Although this regime would reduce unequal distribution, the effect on the polarization of disposable incomes is not definitely predictable. In contrast to all the other scenarios, the realisation of the recent SPD tax rate proposal from 2011 could enlarge tax revenue by 4.7 billion Euro. This tax regime would reduce unequal distribution and polarisation of disposable incomes even more than the present tax system. Y1 - 2012 SN - 0021-4027 VL - 232 IS - 5 SP - 567 EP - 588 PB - Lucius & Lucius CY - Stuttgart ER - TY - JOUR A1 - Reich, Sebastian T1 - A Gaussian-mixture ensemble transform filter JF - Quarterly journal of the Royal Meteorological Society N2 - We generalize the popular ensemble Kalman filter to an ensemble transform filter, in which the prior distribution can take the form of a Gaussian mixture or a Gaussian kernel density estimator. The design of the filter is based on a continuous formulation of the Bayesian filter analysis step. We call the new filter algorithm the ensemble Gaussian-mixture filter (EGMF). The EGMF is implemented for three simple test problems (Brownian dynamics in one dimension, Langevin dynamics in two dimensions and the three-dimensional Lorenz-63 model). It is demonstrated that the EGMF is capable of tracking systems with non-Gaussian uni- and multimodal ensemble distributions. KW - data assimilation KW - ensemble Kalman filter KW - nonlinear filtering KW - Gaussian mixtures KW - Gaussian kernel estimators Y1 - 2012 U6 - https://doi.org/10.1002/qj.898 SN - 0035-9009 VL - 138 IS - 662 SP - 222 EP - 233 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Khare, Varsha A1 - Ruby, Christian A1 - Sonkaria, Sanjiv T1 - A green and sustainable nanotechnology role of ionic liquids JF - International journal of precision engineering and manufacturing N2 - In the present study, the effects of ionic liquids (ILs) on the stability of nanoparticles in several IL compositions were investigated. In this context, we examined the primary role of ILs in the synthesis of metal/metal oxide nanoparticles and their dispersions extensively. However, the focus of the discussion in this communication centers mainly on the effect of EMIM Ethyl Sulfate on growth and stability of nanoparticles. The dispersion properties of ILs based on their ability to aid the synthesis of uniformly dispersed nanoparticles have been further explored to produce nanoparticles of an effective catalyst useful in water purification, soil remediation and battery applications. Two independent protocols were developed for the synthesis of nanoparticles, namely (a) one pot process via chemical reduction (b) dispersion of the inorganic material in ILs. The protocols are simple, sustainable and environmentally friendly because the processes are conducted in ILs as harmless non-toxic green solvent materials. The catalysts were analyzed by x-ray diffraction, electron microscopy, UV visible spectroscopy and dynamic light scattering as the main methodologies. KW - Nanotechnology KW - Green synthesis KW - Ionic liquid KW - Green rust KW - Gold nanoparticles Y1 - 2012 U6 - https://doi.org/10.1007/s12541-012-0160-x SN - 2234-7593 VL - 13 IS - 7 SP - 1207 EP - 1213 PB - Korean Society of Precision Engineering CY - Seoul ER - TY - CHAP A1 - Fischer, Martin H. T1 - A hierarchical view of grounded, embodied, and situated numerical cognition T2 - Cognitive processing : international quarterly of cognitive science Y1 - 2012 SN - 1612-4782 VL - 13 SP - S14 EP - S15 PB - Springer CY - Heidelberg ER - TY - JOUR A1 - Fischer, Martin H. T1 - A hierarchical view of grounded, embodied, and situated numerical cognition JF - Cognitive processing : international quarterly of cognitive science N2 - There is much recent interest in the idea that we represent our knowledge together with the sensory and motor features that were activated during its acquisition. This paper reviews the evidence for such "embodiment" in the domain of numerical cognition, a traditional stronghold of abstract theories of knowledge representation. The focus is on spatial-numerical associations, such as the SNARC effect (small numbers are associated with left space, larger numbers with right space). Using empirical evidence from behavioral research, I first describe sensory and motor biases induced by SNARC, thus identifying numbers as embodied concepts. Next, I propose a hierarchical relationship between grounded, embodied, and situated aspects of number knowledge. This hierarchical conceptualization helps to understand the variety of SNARC-related findings and yields testable predictions about numerical cognition. I report several such tests, ranging from cross-cultural comparisons of horizontal and vertical SNARC effects (Shaki and Fischer in J Exp Psychol Hum Percept Perform 38(3): 804-809, 2012) to motor cortical activation studies in adults with left- and right-hand counting preferences (Tschentscher et al. in NeuroImage 59: 3139-3148, 2012). It is concluded that the diagnostic features for each level of the proposed hierarchical knowledge representation, together with the spatial associations of numbers, make the domain of numerical knowledge an ideal testing ground for embodied cognition research. KW - Embodied cognition KW - Grounded cognition KW - Numerical cognition KW - SNARC effect Y1 - 2012 U6 - https://doi.org/10.1007/s10339-012-0477-5 SN - 1612-4782 VL - 13 SP - S161 EP - S164 PB - Springer CY - Heidelberg ER - TY - THES A1 - Paschke, Marco T1 - A highly resolved P-velocity image of the Messum igneous complex in Namibia obtained by waveform tomography Y1 - 2012 CY - Potsdam ER - TY - JOUR A1 - Batsios, Petros A1 - Peter, Tatjana A1 - Baumann, Otto A1 - Stick, Reimer A1 - Meyer, Irene A1 - Gräf, Ralph T1 - A lamin in lower eukaryotes? JF - Nucleus N2 - Lamins are the major components of the nuclear lamina and serve not only as a mechanical support, but are also involved in chromatin organization, epigenetic regulation, transcription and mitotic events. Despite these universal tasks, lamins have so far been found only in metazoans. Yet, recently we have identified Dictyostelium NE81 as the first lamin-like protein in a lower eukaryote. Based on the current knowledge, we draw a model for nuclear envelope organization in Dictyostelium in this Extra View and we review the experimental data that justified this classification. Furthermore we provide unpublished data underscoring the requirement of posttranslational CaaX-box processing for proper protein localization at the nuclear envelope. Sequence comparison of NE81 sequences from four Dictyostelia with bona fide lamins illustrates the evolutional relationship between these proteins. Under certain conditions these usually unicellular social amoebae congregate to form a multicellular body. We propose that the evolution of the lamin-like NE81 went along with the invention of multicellularity. KW - dictyostelium KW - lamin KW - intermediate filament KW - centrosome KW - nucleus Y1 - 2012 U6 - https://doi.org/10.4161/nucl.20149 SN - 1949-1034 VL - 3 IS - 3 SP - 237 EP - 243 PB - Landes Bioscience CY - Austin ER - TY - THES A1 - Scherfenberg, Ivonne T1 - A logic-based Framwork to enable Attribute Assurance for Digital Identities in Service-oriented Architectures and the Web Y1 - 2012 CY - Potsdam ER - TY - JOUR A1 - Girbig, Dorothee A1 - Selbig, Joachim A1 - Grimbs, Sergio T1 - A MATLAB toolbox for structural kinetic modeling JF - Bioinformatics N2 - Structural kinetic modeling (SKM) enables the analysis of dynamical properties of metabolic networks solely based on topological information and experimental data. Current SKM-based experiments are hampered by the time-intensive process of assigning model parameters and choosing appropriate sampling intervals for MonteCarlo experiments. We introduce a toolbox for the automatic and efficient construction and evaluation of structural kinetic models (SK models). Quantitative and qualitative analyses of network stability properties are performed in an automated manner. We illustrate the model building and analysis process in detailed example scripts that provide toolbox implementations of previously published literature models. Y1 - 2012 U6 - https://doi.org/10.1093/bioinformatics/bts473 SN - 1367-4803 VL - 28 IS - 19 SP - 2546 EP - 2547 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Fürst, Johannes J. A1 - Levermann, Anders T1 - A minimal model for wind- and mixing-driven overturning threshold behavior for both driving mechanisms JF - Climate dynamics : observational, theoretical and computational research on the climate system N2 - We present a minimal conceptual model for the Atlantic meridional overturning circulation which incorporates the advection of salinity and the basic dynamics of the oceanic pycnocline. Four tracer transport processes following Gnanadesikan in Science 283(5410):2077-2079, (1999) allow for a dynamical adjustment of the oceanic pycnocline which defines the vertical extent of a mid-latitudinal box. At the same time the model captures the salt-advection feedback (Stommel in Tellus 13(2):224-230, (1961)). Due to its simplicity the model can be solved analytically in the purely wind- and purely mixing-driven cases. We find the possibility of abrupt transition in response to surface freshwater forcing in both cases even though the circulations are very different in physics and geometry. This analytical approach also provides expressions for the critical freshwater input marking the change in the dynamics of the system. Our analysis shows that including the pycnocline dynamics in a salt-advection model causes a decrease in the freshwater sensitivity of its northern sinking up to a threshold at which the circulation breaks down. Compared to previous studies the model is restricted to the essential ingredients. Still, it exhibits a rich behavior which reaches beyond the scope of this study and might be used as a paradigm for the qualitative behaviour of the Atlantic overturning in the discussion of driving mechanisms. KW - Meridional overturning circulation KW - Northern sinking KW - Critical freshwater threshold KW - Overturning sensitivity KW - Conceptual model KW - Stability KW - Atlantic meridional overturning circulation KW - Pycnocline depth KW - Driving mechanism Y1 - 2012 U6 - https://doi.org/10.1007/s00382-011-1003-7 SN - 0930-7575 VL - 38 IS - 1-2 SP - 239 EP - 260 PB - Springer CY - New York ER - TY - JOUR A1 - Ette, Ottmar A1 - Müller, Gesine T1 - A modo de introducción Y1 - 2012 SN - 978-8-48-489670-8 ER - TY - JOUR A1 - Broeker, Patrick A1 - Luecke, Klaus A1 - Perpeet, Markus A1 - Gronewold, Thomas M. A. T1 - A nanostructured SAW chip-based biosensor detecting cancer cells JF - SENSORS AND ACTUATORS B-CHEMICAL N2 - A nanostructured chip surface was fabricated enabling binding via spaced antibodies specifically targeting surface proteins of cancer cells and detection of extremely low numbers of circulating tumor cells (CTC) without labeling using a sam (R) 5 biosensor. The antibody surfaces mostly were generated by self assembly of antibodies to gold nanospots on the sensitive SiO2-surface of a sam (R) 5 chip. Compared with a complete gold surface, only 40% of the amount of antibodies was bound to the nanospot surface, but structured such that 15-fold higher sensitivity to vital cancer cells was achieved. Human cancer cell lines JEG-3 (lmphoblastic leukemia) and MOLT-17 (placental choriocarcinoma) from cell cultures were successfully detected. The sensor showed significant responses on less than 10 cells injected in a single run. The extreme increase in sensitivity and its simple regeneration emphasizes the usefulness of its introduction in biomedical applications. (C) 2011 Elsevier B.V. All rights reserved. KW - Nanospots KW - Nanostructured surfaces KW - SAW sensor KW - Cell detection KW - Cancer cells KW - sam (R) 5 Y1 - 2012 U6 - https://doi.org/10.1016/j.snb.2011.11.022 SN - 0925-4005 VL - 165 IS - 1 SP - 1 EP - 6 PB - ELSEVIER SCIENCE SA CY - LAUSANNE ER - TY - THES A1 - Oskinova, Lida T1 - A new understanding of the structured winds from massive stars : the implications for their X-ray emission, mass-loss diagnostics, and feedback Y1 - 2012 CY - Potsdam ER - TY - JOUR A1 - Haase, A. A1 - Mantion, A. A1 - Graf, P. A1 - Plendl, J. A1 - Thünemann, Andreas F. A1 - Meier, Wolfgang P. A1 - Taubert, Andreas A1 - Luch, A. T1 - A novel type of silver nanoparticles and their advantages in toxicity testing in cell culture systems JF - Archives of toxicology : official journal of EUROTOX N2 - Silver nanoparticles (SNPs) are among the most commercialized nanoparticles worldwide. Often SNP are used because of their antibacterial properties. Besides that they possess unique optic and catalytic features, making them highly interesting for the creation of novel and advanced functional materials. Despite its widespread use only little data exist in terms of possible adverse effects of SNP on human health. Conventional synthesis routes usually yield products of varying quality and property. It thus may become puzzling to compare biological data from different studies due to the great variety in sizes, coatings or shapes of the particles applied. Here, we applied a novel synthesis approach to obtain SNP of well-defined colloidal and structural properties. Being stabilized by a covalently linked small peptide, these particles are nicely homogenous, with narrow size distribution, and form monodisperse suspensions in aqueous solutions. We applied these peptide-coated SNP in two different sizes of 20 or 40 nm (Ag20Pep and Ag40Pep) and analyzed responses of THP-1-derived human macrophages while being exposed against these particles. Gold nanoparticles of similar size and coating (Au20Pep) were used for comparison. The cytotoxicity of particles was assessed by WST-1 and LDH assays, and the uptake into the cells was confirmed via transmission electron microscopy. In summary, our data demonstrate that this novel type of SNP is well suited to serve as model system for nanoparticles to be tested in toxicological studies in vitro. KW - Silver nanoparticles KW - Peptide coating KW - Nanotoxicity Y1 - 2012 U6 - https://doi.org/10.1007/s00204-012-0836-0 SN - 0340-5761 VL - 86 IS - 7 SP - 1089 EP - 1098 PB - Springer CY - Heidelberg ER - TY - JOUR A1 - Kliem, Bernhard A1 - Török, Tibor A1 - Thompson, William T. T1 - A parametric study of erupting flux rope rotation modeling the "Cartwheel CME" on 9 April 2008 JF - Solar physics : a journal for solar and solar-stellar research and the study of solar terrestrial physics N2 - The rotation of erupting filaments in the solar corona is addressed through a parametric simulation study of unstable, rotating flux ropes in bipolar force-free initial equilibrium. The Lorentz force due to the external shear-field component and the relaxation of tension in the twisted field are the major contributors to the rotation in this model, while reconnection with the ambient field is of minor importance, due to the field's simple structure. In the low-beta corona, the rotation is not guided by the changing orientation of the vertical field component's polarity inversion line with height. The model yields strong initial rotations which saturate in the corona and differ qualitatively from the profile of rotation vs. height obtained in a recent simulation of an eruption without preexisting flux rope. Both major mechanisms writhe the flux rope axis, converting part of the initial twist helicity, and produce rotation profiles which, to a large part, are very similar within a range of shear-twist combinations. A difference lies in the tendency of twist-driven rotation to saturate at lower heights than shear-driven rotation. For parameters characteristic of the source regions of erupting filaments and coronal mass ejections, the shear field is found to be the dominant origin of rotations in the corona and to be required if the rotation reaches angles of order 90 degrees and higher; it dominates even if the twist exceeds the threshold of the helical kink instability. The contributions by shear and twist to the total rotation can be disentangled in the analysis of observations if the rotation and rise profiles are simultaneously compared with model calculations. The resulting twist estimate allows one to judge whether the helical kink instability occurred. This is demonstrated for the erupting prominence in the "Cartwheel CME" on 9 April 2008, which has shown a rotation of a parts per thousand aEuro parts per thousand 115(a similar to) up to a height of 1.5 R (aS (TM)) above the photosphere. Out of a range of initial equilibria which include strongly kink-unstable (twist I broken vertical bar=5 pi), weakly kink-unstable (I broken vertical bar=3.5 pi), and kink-stable (I broken vertical bar=2.5 pi) configurations, only the evolution of the weakly kink-unstable flux rope matches the observations in their entirety. KW - Corona, active KW - Prominences, dynamics KW - Coronal mass ejections, initiation and propagation KW - Magnetic fields, corona KW - Magnetohydrodynamics Y1 - 2012 U6 - https://doi.org/10.1007/s11207-012-9990-z SN - 0038-0938 VL - 281 IS - 1 SP - 137 EP - 166 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Blüthgen, Nico A1 - Dormann, Carsten F. A1 - Prati, Daniel A1 - Klaus, Valentin H. A1 - Kleinebecker, Till A1 - Hoelzel, Norbert A1 - Alt, Fabian A1 - Boch, Steffen A1 - Gockel, Sonja A1 - Hemp, Andreas A1 - Müller, Jörg A1 - Nieschulze, Jens A1 - Renner, Swen C. A1 - Schöning, Ingo A1 - Schumacher, Uta A1 - Socher, Stephanie A. A1 - Wells, Konstans A1 - Birkhofer, Klaus A1 - Buscot, Francois A1 - Oelmann, Yvonne A1 - Rothenwöhrer, Christoph A1 - Scherber, Christoph A1 - Tscharntke, Teja A1 - Weiner, Christiane N. A1 - Fischer, Markus A1 - Kalko, Elisabeth K. V. A1 - Linsenmair, Karl Eduard A1 - Schulze, Ernst-Detlef A1 - Weisser, Wolfgang W. T1 - A quantitative index of land-use intensity in grasslands integrating mowing, grazing and fertilization JF - Basic and applied ecology : Journal of the Gesellschaft für Ökologie N2 - Land use is increasingly recognized as a major driver of biodiversity and ecosystem functioning in many current research projects. In grasslands, land use is often classified by categorical descriptors such as pastures versus meadows or fertilized versus unfertilized sites. However, to account for the quantitative variation of multiple land-use types in heterogeneous landscapes, a quantitative, continuous index of land-use intensity (LUI) is desirable. Here we define such a compound, additive LUI index for managed grasslands including meadows and pastures. The LUI index summarizes the standardized intensity of three components of land use, namely fertilization, mowing, and livestock grazing at each site. We examined the performance of the LUI index to predict selected response variables on up to 150 grassland sites in the Biodiversity Exploratories in three regions in Germany(Alb, Hainich, Schorlheide). We tested the average Ellenberg nitrogen indicator values of the plant community, nitrogen and phosphorus concentration in the aboveground plant biomass, plant-available phosphorus concentration in the top soil, and soil C/N ratio, and the first principle component of these five response variables. The LUI index significantly predicted the principal component of all five response variables, as well as some of the individual responses. Moreover, vascular plant diversity decreased significantly with LUI in two regions (Alb and Hainich). Inter-annual changes in management practice were pronounced from 2006 to 2008, particularly due to variation in grazing intensity. This rendered the selection of the appropriate reference year(s) an important decision for analyses of land-use effects, whereas details in the standardization of the index were of minor importance. We also tested several alternative calculations of a LUI index, but all are strongly linearly correlated to the proposed index. The proposed LUI index reduces the complexity of agricultural practices to a single dimension and may serve as a baseline to test how different groups of organisms and processes respond to land use. In combination with more detailed analyses, this index may help to unravel whether and how land-use intensities, associated disturbance levels or other local or regional influences drive ecological processes. KW - Agro-ecosystems KW - Biodiversity exploratories KW - Grassland management KW - Land-use impacts KW - Livestock density KW - Meadows KW - Nitrogen KW - Pastures Y1 - 2012 U6 - https://doi.org/10.1016/j.baae.2012.04.001 SN - 1439-1791 VL - 13 IS - 3 SP - 207 EP - 220 PB - Elsevier CY - Jena ER - TY - JOUR A1 - Evans, C. J. A1 - Hainich, Rainer A1 - Oskinova, Lida A1 - Gallagher, J. S. A1 - Chu, Y.-H. A1 - Gruendl, R. A. A1 - Hamann, Wolf-Rainer A1 - Henault-Brunet, V. A1 - Todt, Helge Tobias T1 - A rare early-type star revealed in the wing of the small megellanic cloud JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - Sk 183 is the visually brightest star in the N90 nebula, a young star-forming region in the Wing of the Small Magellanic Cloud (SMC). We present new optical spectroscopy from the Very Large Telescope which reveals Sk 183 to be one of the most massive O-type stars in the SMC. Classified as an O3-type dwarf on the basis of its nitrogen spectrum, the star also displays broadened He I absorption, which suggests a later type. We propose that Sk 183 has a composite spectrum and that it is similar to another star in the SMC, MPG 324. This brings the number of rare O2- and O3-type stars known in the whole of the SMC to a mere four. We estimate physical parameters for Sk 183 from analysis of its spectrum. For a single-star model, we estimate an effective temperature of 46 +/- 2 kK, a low mass-loss rate of similar to 10(-7) M-circle dot yr(-1), and a spectroscopic mass of 46(-8)(+ 9) M-circle dot (for an adopted distance modulus of 18.7 mag to the young population in the SMC Wing). An illustrative binary model requires a slightly hotter temperature (similar to 47.5 kK) for the primary component. In either scenario, Sk 183 is the earliest-type star known in N90 and will therefore be the dominant source of hydrogen-ionizing photons. This suggests Sk 183 is the primary influence on the star formation along the inner edge of the nebula. KW - open clusters and associations: individual (NGC 602) KW - stars: early-type KW - stars: fundamental parameters KW - stars: individual (Sanduleak 183) Y1 - 2012 U6 - https://doi.org/10.1088/0004-637X/753/2/173 SN - 0004-637X VL - 753 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - THES A1 - Müller, Jürgen J. T1 - A real-time in-memory discovery service Y1 - 2012 CY - Potsdam ER - TY - JOUR A1 - Nehring, Benjamin A1 - Zessin, Hans T1 - A representation of the moment measures of the general ideal Boe gas JF - Mathematische Nachrichten N2 - We reconsider the fundamental work of Fichtner 2 and exhibit the permanental structure of the ideal Bose gas again, using a new approach which combines a characterization of infinitely divisible random measures (due to Kerstan, Kummer and Matthes 4, 6 and Mecke 9, 10) with a decomposition of the moment measures into its factorial measures due to Krickeberg 5. To be more precise, we exhibit the moment measures of all orders of the general ideal Bose gas in terms of certain loop integrals. This representation can be considered as a point process analogue of the old idea of Symanzik 15 that local times and self-crossings of the Brownian motion can be used as a tool in quantum field theory. Behind the notion of a general ideal Bose gas there is a class of infinitely divisible point processes of all orders with a Levy-measure belonging to some large class of measures containing that of the classical ideal Bose gas considered by Fichtner. It is well-known that the calculation of moments of higher order of point processes is notoriously complicated. See for instance Krickebergs calculations for the Poisson or the Cox process in 5. Relations to the work of Shirai, Takahashi 12 and Soshnikov 14 on permanental and determinantal processes are outlined. KW - Infinitely divisible point processes KW - integration by parts formula KW - random KMM-measure KW - permanental and determinantal point processes (MSC 2010) 35K55 KW - 35K65 Y1 - 2012 U6 - https://doi.org/10.1002/mana.201000111 SN - 0025-584X VL - 285 IS - 7 SP - 878 EP - 888 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Hammer, Conny A1 - Beyreuther, Moritz A1 - Ohrnberger, Matthias T1 - A seismic-event spotting system for volcano fast-response systems JF - Bulletin of the Seismological Society of America N2 - Volcanic eruptions are often preceded by seismic activity that can be used to quantify the volcanic activity. In order to allow consistent inference of the volcanic activity state from the observed seismicity patterns, objective and time-invariant classification results achievable by automatic systems should be preferred. Most automatic classification approaches need a large preclassified data set for training the system. However, in case of a volcanic crisis, we are often confronted with a lack of training data due to insufficient prior observations. In the worst case (e. g., volcanic crisis related reconfiguration of stations), there are even no prior observations available. Finally, due to the imminent crisis there might be no time for the time-consuming process of preparing a training data set. For this reason, we have developed a novel seismic-event spotting technique in order to be less dependent on previously acquired data bases and classification schemes. We are using a learning-while-recording approach based on a minimum number of reference waveforms, thus allowing for the build-up of a classification scheme as early as interesting events have been identified. First, short-term wave-field parameters (here, polarization and spectral attributes) are extracted from a continuous seismic data stream. The sequence of multidimensional feature vectors is then used to identify a fixed number of clusters in the feature space. Based on this general description of the overall wave field by a mixture of multivariate Gaussians, we are able to learn particular event classifiers (here, hidden Markov models) from a single waveform example. To show the capabilities of this new approach we apply the algorithm to a data set recorded at Soufriere Hills volcano, Montserrat. Supported by very high classification rates, we conclude that the suggested approach provides a valuable tool for volcano monitoring systems. Y1 - 2012 U6 - https://doi.org/10.1785/0120110167 SN - 0037-1106 VL - 102 IS - 3 SP - 948 EP - 960 PB - Seismological Society of America CY - Albany ER - TY - JOUR A1 - Kunnus, Kristjan A1 - Rajkovic, Ivan A1 - Schreck, Simon A1 - Quevedo, Wilson A1 - Eckert, Sebastian A1 - Beye, Martin A1 - Suljoti, Edlira A1 - Weniger, Christian A1 - Kalus, Christian A1 - Gruebel, Sebastian A1 - Scholz, Mirko A1 - Nordlund, Dennis A1 - Zhang, Wenkai A1 - Hartsock, Robert W. A1 - Gaffney, Kelly J. A1 - Schlotter, William F. A1 - Turner, Joshua J. A1 - Kennedy, Brian A1 - Hennies, Franz A1 - Techert, Simone A1 - Wernet, Philippe A1 - Föhlisch, Alexander T1 - A setup for resonant inelastic soft x-ray scattering on liquids at free electron laser light sources JF - Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques N2 - We present a flexible and compact experimental setup that combines an in vacuum liquid jet with an x-ray emission spectrometer to enable static and femtosecond time-resolved resonant inelastic soft x-ray scattering (RIXS) measurements from liquids at free electron laser (FEL) light sources. We demonstrate the feasibility of this type of experiments with the measurements performed at the Linac Coherent Light Source FEL facility. At the FEL we observed changes in the RIXS spectra at high peak fluences which currently sets a limit to maximum attainable count rate at FELs. The setup presented here opens up new possibilities to study the structure and dynamics in liquids. Y1 - 2012 U6 - https://doi.org/10.1063/1.4772685 SN - 0034-6748 VL - 83 IS - 12 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Sereshki, L. E. A1 - Lomholt, M. A. A1 - Metzler, Ralf T1 - A solution to the subdiffusion-efficiency paradox inactive states enhance reaction efficiency at subdiffusion conditions in living cells JF - epl : a letters journal exploring the frontiers of physics N2 - Macromolecular crowding in living biological cells effects subdiffusion of larger biomolecules such as proteins and enzymes. Mimicking this subdiffusion in terms of random walks on a critical percolation cluster, we here present a case study of EcoRV restriction enzymes involved in vital cellular defence. We show that due to its so far elusive propensity to an inactive state the enzyme avoids non-specific binding and remains well-distributed in the bulk cytoplasm of the cell. Despite the reduced volume exploration capability of subdiffusion processes, this mechanism guarantees a high efficiency of the enzyme. By variation of the non-specific binding constant and the bond occupation probability on the percolation network, we demonstrate that reduced nonspecific binding are beneficial for efficient subdiffusive enzyme activity even in relatively small bacteria cells. Our results corroborate a more local picture of cellular regulation. Y1 - 2012 U6 - https://doi.org/10.1209/0295-5075/97/20008 SN - 0295-5075 VL - 97 IS - 2 PB - EDP Sciences CY - Mulhouse ER - TY - JOUR A1 - Schewe, Jacob A1 - Levermann, Anders T1 - A statistically predictive model for future monsoon failure in India JF - Environmental research letters N2 - Indian monsoon rainfall is vital for a large share of the world's population. Both reliably projecting India's future precipitation and unraveling abrupt cessations of monsoon rainfall found in paleorecords require improved understanding of its stability properties. While details of monsoon circulations and the associated rainfall are complex, full-season failure is dominated by large-scale positive feedbacks within the region. Here we find that in a comprehensive climate model, monsoon failure is possible but very rare under pre-industrial conditions, while under future warming it becomes much more frequent. We identify the fundamental intraseasonal feedbacks that are responsible for monsoon failure in the climate model, relate these to observational data, and build a statistically predictive model for such failure. This model provides a simple dynamical explanation for future changes in the frequency distribution of seasonal mean all-Indian rainfall. Forced only by global mean temperature and the strength of the Pacific Walker circulation in spring, it reproduces the trend as well as the multidecadal variability in the mean and skewness of the distribution, as found in the climate model. The approach offers an alternative perspective on large-scale monsoon variability as the result of internal instabilities modulated by pre-seasonal ambient climate conditions. KW - monsoon failure KW - climate change KW - coupled climate model KW - stochastic model KW - non-linear dynamics Y1 - 2012 U6 - https://doi.org/10.1088/1748-9326/7/4/044023 SN - 1748-9326 VL - 7 IS - 4 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Amselem, Gabriel A1 - Theves, Matthias A1 - Bae, Albert J. A1 - Bodenschatz, Eberhard A1 - Beta, Carsten T1 - A stochastic description of dictyostelium chemotaxis JF - PLoS one N2 - Chemotaxis, the directed motion of a cell toward a chemical source, plays a key role in many essential biological processes. Here, we derive a statistical model that quantitatively describes the chemotactic motion of eukaryotic cells in a chemical gradient. Our model is based on observations of the chemotactic motion of the social ameba Dictyostelium discoideum, a model organism for eukaryotic chemotaxis. A large number of cell trajectories in stationary, linear chemoattractant gradients is measured, using microfluidic tools in combination with automated cell tracking. We describe the directional motion as the interplay between deterministic and stochastic contributions based on a Langevin equation. The functional form of this equation is directly extracted from experimental data by angle-resolved conditional averages. It contains quadratic deterministic damping and multiplicative noise. In the presence of an external gradient, the deterministic part shows a clear angular dependence that takes the form of a force pointing in gradient direction. With increasing gradient steepness, this force passes through a maximum that coincides with maxima in both speed and directionality of the cells. The stochastic part, on the other hand, does not depend on the orientation of the directional cue and remains independent of the gradient magnitude. Numerical simulations of our probabilistic model yield quantitative agreement with the experimental distribution functions. Thus our model captures well the dynamics of chemotactic cells and can serve to quantify differences and similarities of different chemotactic eukaryotes. Finally, on the basis of our model, we can characterize the heterogeneity within a population of chemotactic cells. Y1 - 2012 U6 - https://doi.org/10.1371/journal.pone.0037213 SN - 1932-6203 VL - 7 IS - 5 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Sauer, Patrick A1 - Glombitza, Clemens A1 - Kallmeyer, Jens T1 - A system for incubations at high gas partial pressure JF - Frontiers in microbiology N2 - High-pressure is a key feature of deep subsurface environments. High partial pressure of dissolved gasses plays an important role in microbial metabolism, because thermodynamic feasibility of many reactions depends on the concentration of reactants. For gases, this is controlled by their partial pressure, which can exceed 1 MPa at in situ conditions. Therefore, high hydrostatic pressure alone is not sufficient to recreate true deep subsurface in situ conditions, but the partial pressure of dissolved gasses has to be controlled as well. We developed an incubation system that allows for incubations at hydrostatic pressure up to 60 MPa, temperatures up to 120 degrees C, and at high gas partial pressure. The composition and partial pressure of gasses can be manipulated during the experiment. To keep costs low, the system is mainly made from off-the-shelf components with only very few custommade parts. A flexible and inert PVDF (polyvinylidene fluoride) incubator sleeve, which is almost impermeable for gases, holds the sample and separates it from the pressure fluid. The flexibility of the incubator sleeve allows for sub-sampling of the medium without loss of pressure. Experiments can be run in both static and flow-through mode. The incubation system described here is usable for versatile purposes, not only the incubation of microorganisms and determination of growth rates, but also for chemical degradation or extraction experiments under high gas saturation, e.g., fluid-gas-rock-interactions in relation to carbon dioxide sequestration. As an application of the system we extracted organic compounds from sub-bituminous coal using H2O as well as a H2O-CO2 mixture at elevated temperature (90 degrees C) and pressure (5 MPa). Subsamples were taken at different time points during the incubation and analyzed by ion chromatography. Furthermore we demonstrated the applicability of the system for studies of microbial activity, using samples from the Isis mud volcano. We could detect an increase in sulfate reduction rate upon the addition of methane to the sample. KW - high-pressure incubation system KW - gas partial pressure KW - sub-sampling KW - carbon dioxide KW - low molecular weight organic acids Y1 - 2012 U6 - https://doi.org/10.3389/fmicb.2012.00025 SN - 1664-302X VL - 3 PB - Frontiers Research Foundation CY - Lausanne ER - TY - JOUR A1 - Xie, Zai-Lai A1 - Xu, Hai-Bing A1 - Gessner, Andre A1 - Kumke, Michael Uwe A1 - Priebe, Magdalena A1 - Fromm, Katharina M. A1 - Taubert, Andreas T1 - A transparent, flexible, ion conductive, and luminescent PMMA ionogel based on a Pt/Eu bimetallic complex and the ionic liquid [Bmim][N(Tf)(2)] JF - Journal of materials chemistry N2 - Transparent, ion-conducting, luminescent, and flexible ionogels based on the room temperature ionic liquid (IL) 1-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide [Bmim][N(Tf)(2)], a PtEu2 chromophore, and poly(methylmethacrylate) (PMMA) have been prepared. The thermal stability of the PMMA significantly increases with IL incorporation. In particular, the onset weight loss observed at ca. 229 degrees C for pure PMMA increases to 305 degrees C with IL addition. The ionogel has a high ionic conductivity of 10(-3) S cm(-1) at 373 K and exhibits a strong emission in the red with a long average luminescence decay time of tau = 890 mu s. The resulting material is a new type of soft hybrid material featuring useful thermal, optical, and ion transport properties. Y1 - 2012 U6 - https://doi.org/10.1039/c2jm15862k SN - 0959-9428 VL - 22 IS - 16 SP - 8110 EP - 8116 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Gündelman, Eduardo A1 - Singleton, Douglas A1 - Yongram, N. T1 - A two measure model of dark energy and dark matter JF - Journal of cosmology and astroparticle physics N2 - In this work we construct a unified model of dark energy and dark matter. This is done with the following three elements: a gravitating scalar field, phi with a non-conventional kinetic term, as in the string theory tachyon; an arbitrary potential, V (phi); two measures - a metric measure (root-g) and a non-metric measure (Phi). The model has two interesting features: (i) For potentials which are unstable and would give rise to tachyonic scalar field, this model can stabilize the scalar field. (ii) The form of the dark energy and dark matter that results from this model is fairly insensitive to the exact form of the scalar field potential. KW - modified gravity KW - dark matter theory KW - dark energy theory Y1 - 2012 U6 - https://doi.org/10.1088/1475-7516/2012/11/044 SN - 1475-7516 IS - 11 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Thielemann-Kühn, Nele A1 - Hoffmann, P. A1 - Föhlisch, Alexander T1 - A versatile detector for total fluorescence and electron yield experiments JF - Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques N2 - The combination of a non-coated silicon photodiode with electron repelling meshes makes a versatile detector for total fluorescence yield and electron yield techniques highly suitable for x-ray absorption spectroscopy. In particular, a copper mesh with a bias voltage allows to suppress or transmit the electron yield signal. The performance of this detection scheme has been characterized by near edge x-ray absorption fine structure studies of thermal oxidized silicon and sapphire. The results show that the new detector probes both electron yield and for a bias voltage exceeding the maximum photon energy the total fluorescence yield. Y1 - 2012 U6 - https://doi.org/10.1063/1.4754126 SN - 0034-6748 VL - 83 IS - 9 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Risse, Sebastian A1 - Kussmaul, Björn A1 - Krüger, Hartmut A1 - Kofod, Guggi T1 - A versatile method for enhancement of electromechanical sensitivity of silicone elastomers JF - RSC Advances N2 - Dielectric elastomer actuators (DEAs) draw their function from their dielectric and mechanical properties. The paper describes the fabrication and various properties of molecularly grafted silicone elastomer films. This was achieved by addition of high-dipole molecular co-substituents to off-the-shelf silicone elastomer kits, Elastosil RT 625 and Sylgard 184 by Wacker and Dow Corning, respectively. Strong push-pull dipoles were chemically grafted to both polymer networks during a one step film formation process. All manufactured films were characterized using (13) C-NMR and FT-IR spectroscopy, confirming a successful attachment of the dipoles to the silicone network. Differential scanning calorimetry (DSC) results showed that grafted dipoles were distributed homogeneously throughout the material avoiding the formation of nano-scale aggregates. The permittivity increased with the amount of dipole at all frequencies, while the Young's modulus and electrical breakdown strength were reduced. Actuation strain measurements in the pure shear configuration independently confirmed the increase in electromechanical sensitivity. The ability to enhance electromechanical properties of off-the-shelf materials could strongly expand the range of actuator properties available to researchers and end-users. Y1 - 2012 U6 - https://doi.org/10.1039/c2ra21541a SN - 2046-2069 VL - 2 IS - 24 SP - 9029 EP - 9035 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Neugebauer, Ina A1 - Brauer, Achim A1 - Draeger, Nadine A1 - Dulski, Peter A1 - Wulf, Sabine A1 - Plessen, Birgit A1 - Mingram, Jens A1 - Herzschuh, Ulrike A1 - Brande, Arthur T1 - A Younger Dryas varve chronology from the Rehwiese palaeolake record in NE-Germany JF - Quaternary science reviews : the international multidisciplinary research and review journal N2 - The first 1400-year floating varve chronology for north-eastern Germany covering the late Allered to the early Holocene has been established by microscopic varve counts from the Rehwiese palaeolake sediment record. The Laacher See Tephra (LST), at the base of the studied interval, forms the tephrochronological anchor point. The fine laminations were examined using a combination of micro-facies and mu XRF analyses and are typical of calcite varves, which in this case provide mainly a warm season signal. Two varve types with different sub-layer structures have been distinguished: (I) complex varves consisting of up to four seasonal sub-layers formed during the Allered and early Holocene periods, and, (II) simple two sub-layer type varves only occurring during the Younger Dryas. The precision of the chronology has been improved by varve-to-varve comparison of two independently analyzed sediment profiles based on well-defined micro-marker layers. This has enabled both (1) the precise location of single missing varies in one of the sediment profiles, and, (2) the verification of varve interpolation in disturbed varve intervals in the parallel core. Inter-annual and decadal-scale variability in sediment deposition processes were traced by multi-proxy data series including seasonal layer thickness, high-resolution element scans and total organic and inorganic carbon data at a five-varve resolution. These data support the idea of a two-phase Younger Dryas, with the first interval (12,675-12,275 varve years BP) characterised by a still significant but gradually decreasing warm-season calcite precipitation and a second phase (12,275-11,690 varve years BP) with only weak calcite precipitation. Detailed correlation of these two phases with the Meerfelder Maar record based on the LST isochrone and independent varve counts provides clues about regional differences and seasonal aspects of YD climate change along a transect from a location proximal to the North Atlantic in the west to a more continental site in the east KW - Varve chronology KW - Micro-fades KW - Micro-XRF KW - Younger Dryas KW - North-eastern Germany Y1 - 2012 U6 - https://doi.org/10.1016/j.quascirev.2011.12.010 SN - 0277-3791 VL - 36 IS - 10 SP - 91 EP - 102 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Zimmermann, Andreas T1 - Abiding by and enforcing international humanitarian law in asymmetric warfare : the case of "operation cast lead" Y1 - 2012 SN - 0554-498x ER - TY - JOUR A1 - Nagy, Gabriel A1 - Trautwein, Ulrich A1 - Maaz, Kai T1 - Ability and interest profiles at the end of lower secondary school structure, specification, and associations with educational choices JF - Zeitschrift für pädagogische Psychologie. N2 - This paper investigates the role of ability profiles and profiles of vocational interests at the transition from "Realschule" (lower secondary level) into the academic and vocational oriented "Gymnasium" (upper secondary track) school. Based on Guttman's (1954) radex model of cognitive and academic abilities as well as Holland's (1997) circumplex model of vocational interests, we developed statistical models for assessing individual differences in intraindividual profiles. The empirical results underscore the validity of our profile approach. Particularly (1) profiles derived on basis of test scores, grades, and interests were associated with all educational choices under consideration, and (2) decisions for different gymnasia types were systematically and meaningfully associated with individual profile parameters. In addition (3) criterion correlations of interest and ability measures could be explained by individual profile parameters. KW - ability profiles KW - interest profiles KW - radex model KW - circumplex model KW - educational choices Y1 - 2012 U6 - https://doi.org/10.1024/1010-0652/a000063 SN - 1010-0652 VL - 26 IS - 2 SP - 79 EP - 99 PB - Hogrefe CY - Bern ER - TY - JOUR A1 - Tepper-Garcia, Thorsten A1 - Richter, Philipp A1 - Schaye, Joop A1 - Booth, C. M. A1 - Dalla Vecchia, Claudio A1 - Theuns, Tom T1 - Absorption signatures of warm-hot gas at low redshift: broad H?i Lya absorbers JF - Monthly notices of the Royal Astronomical Society N2 - We investigate the physical state of H?i absorbing gas at low redshift (z = 0.25) using a subset of cosmological, hydrodynamic simulations from the OverWhelmingly Large Simulations project, focusing in particular on broad (bHI=40 km s-1) H?i Lya absorbers (BLAs), which are believed to originate in shock-heated gas in the warm-hot intergalactic medium (WHIM). Our fiducial model, which includes radiative cooling by heavy elements and feedback by supernovae and active galactic nuclei, predicts that by z = 0.25 nearly 60?per cent of the gas mass ends up at densities and temperatures characteristic of the WHIM and we find that half of this fraction is due to outflows. The standard H?i observables (distribution of H?i column densities NH?I, distribution of Doppler parameters bHI, bHINH?I correlation) and the BLA line number density predicted by our simulations are in remarkably good agreement with observations. BLAs arise in gas that is hotter, more highly ionized and more enriched than the gas giving rise to typical Lya forest absorbers. The majority of the BLAs arise in warm-hot [log?(T/?K) similar to 5] gas at low (log?? < 1.5) overdensities. On average, thermal broadening accounts for at least 60?per cent of the BLA linewidth, which in turn can be used as a rough indicator of the thermal state of the gas. Detectable BLAs account for only a small fraction of the true baryon content of the WHIM at low redshift. In order to detect the bulk of the mass in this gas phase, a sensitivity at least one order of magnitude better than achieved by current ultraviolet spectrographs is required. We argue that BLAs mostly trace gas that has been shock heated and enriched by outflows and that they therefore provide an important window on a poorly understood feedback process. KW - methods: numerical KW - galaxies: formation KW - intergalactic medium KW - quasars: absorption lines KW - cosmology: theory Y1 - 2012 U6 - https://doi.org/10.1111/j.1365-2966.2012.21545.x SN - 0035-8711 VL - 425 IS - 3 SP - 1640 EP - 1663 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Fabian, Benjamin A1 - Kunz, Steffen A1 - Konnegen, Marcel A1 - Müller, Sebastian A1 - Günther, Oliver T1 - Access control for semantic data federations in industrial product-lifecycle management JF - Computers in industry : an international, application oriented research journal N2 - Information integration across company borders becomes increasingly important for the success of product lifecycle management in industry and complex supply chains. Semantic technologies are about to play a crucial role in this integrative process. However, cross-company data exchange requires mechanisms to enable fine-grained access control definition and enforcement, preventing unauthorized leakage of confidential data across company borders. Currently available semantic repositories are not sufficiently equipped to satisfy this important requirement. This paper presents an infrastructure for controlled sharing of semantic data between cooperating business partners. First, we motivate the need for access control in semantic data federations by a case study in the industrial service sector. Furthermore, we present an architecture for controlling access to semantic repositories that is based on our newly developed SemForce security service. Finally, we show the practical feasibility of this architecture by an implementation and several performance experiments. KW - Access control KW - Data federation KW - Information integration KW - Product lifecycle management KW - Semantic data Y1 - 2012 U6 - https://doi.org/10.1016/j.compind.2012.08.015 SN - 0166-3615 VL - 63 IS - 9 SP - 930 EP - 940 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Zurita-Sanchez, Jorge R. A1 - Henkel, Carsten T1 - Acoustic waves from mechanical impulses due to fluorescence resonant energy (Forster) transfer Blowing a whistle with light JF - epl : a letters journal exploring the frontiers of physics N2 - We present a momentum transfer mechanism mediated by electromagnetic fields that originates in a system of two nearby molecules: one excited (donor D*) and the other in ground state (acceptor A). An intermolecular force related to fluorescence resonant energy or Forster transfer (FRET) arises in the unstable D* A molecular system, which differs from the equilibrium van der Waals interaction. Due to the its finite lifetime, a mechanical impulse is imparted to the relative motion in the system. We analyze the FRET impulse when the molecules are embedded in free space and find that its magnitude can be much greater than the single recoil photon momentum, getting comparable with the thermal momentum (Maxwell-Boltzmann distribution) at room temperature. In addition, we propose that this FRET impulse can be exploited in the generation of acoustic waves inside a film containing layers of donor and acceptor molecules, when a picosecond laser pulse excites the donors. This acoustic transient is distinguishable from that produced by thermal stress due to laser absorption, and may therefore play a role in photoacoustic spectroscopy. The effect can be seen as exciting a vibrating system like a string or organ pipe with light; it may be used as an opto-mechanical transducer. Y1 - 2012 U6 - https://doi.org/10.1209/0295-5075/97/43002 SN - 0295-5075 VL - 97 IS - 4 PB - EDP Sciences CY - Mulhouse ER - TY - CHAP A1 - Lindemann, Oliver A1 - Paulus, Markus T1 - Acquisition of action knowledge through verbal and social learning T2 - Cognitive processing : international quarterly of cognitive science Y1 - 2012 SN - 1612-4782 VL - 13 IS - 3 SP - S10 EP - S10 PB - Springer CY - Heidelberg ER - TY - BOOK ED - Sternagel, Jörg ED - Levitt, Deborah ED - Mersch, Dieter T1 - Acting and performance in moving image culture : bodies, screens, renderings T3 - Metabasis Y1 - 2012 SN - 978-3-8376-1648-4 U6 - https://doi.org/10.14361/transcript.9783839416488 VL - 7 PB - transcript; de Gruyter CY - Bielefeld; Berlin ER - TY - JOUR A1 - Ribeiro, Dimas M. A1 - Araujo, Wagner L. A1 - Fernie, Alisdair R. A1 - Schippers, Jos H. M. A1 - Müller-Röber, Bernd T1 - Action of Gibberellins on growth and metabolism of arabidopsis plants Associated with high concentration of carbon dioxide JF - Plant physiology : an international journal devoted to physiology, biochemistry, cellular and molecular biology, biophysics and environmental biology of plants N2 - Although the positive effect of elevated CO2 concentration [CO2] on plant growth is well known, it remains unclear whether global climate change will positively or negatively affect crop yields. In particular, relatively little is known about the role of hormone pathways in controlling the growth responses to elevated [CO2]. Here, we studied the impact of elevated [CO2] on plant biomass and metabolism in Arabidopsis (Arabidopsis thaliana) in relation to the availability of gibberellins (GAs). Inhibition of growth by the GA biosynthesis inhibitor paclobutrazol (PAC) at ambient [CO2] (350 mu mol CO2 mol(-1)) was reverted by elevated [CO2] (750 mu mol CO2 mol(-1)). Thus, we investigated the metabolic adjustment and modulation of gene expression in response to changes in growth of plants imposed by varying the GA regime in ambient and elevated [CO2]. In the presence of PAC (low-GA regime), the activities of enzymes involved in photosynthesis and inorganic nitrogen assimilation were markedly increased at elevated [CO2], whereas the activities of enzymes of organic acid metabolism were decreased. Under ambient [CO2], nitrate, amino acids, and protein accumulated upon PAC treatment; however, this was not the case when plants were grown at elevated [CO2]. These results suggest that only under ambient [CO2] is GA required for the integration of carbohydrate and nitrogen metabolism underlying optimal biomass determination. Our results have implications concerning the action of the Green Revolution genes in future environmental conditions. Y1 - 2012 U6 - https://doi.org/10.1104/pp.112.204842 SN - 0032-0889 VL - 160 IS - 4 SP - 1781 EP - 1794 PB - American Society of Plant Physiologists CY - Rockville ER - TY - JOUR A1 - Green-Saxena, A. A1 - Feyzullayev, A. A1 - Hubert, C. R. J. A1 - Kallmeyer, Jens A1 - Krueger, M. A1 - Sauer, P. A1 - Schulz, Hans-Martin A1 - Orphan, V. J. T1 - Active sulfur cycling by diverse mesophilic and thermophilic microorganisms in terrestrial mud volcanoes of Azerbaijan JF - Environmental microbiology N2 - Terrestrial mud volcanoes (TMVs) represent geochemically diverse habitats with varying sulfur sources and yet sulfur cycling in these environments remains largely unexplored. Here we characterized the sulfur-metabolizing microorganisms and activity in four TMVs in Azerbaijan. A combination of geochemical analyses, biological rate measurements and molecular diversity surveys (targeting metabolic genes aprA and dsrA and SSU ribosomal RNA) supported the presence of active sulfur-oxidizing and sulfate-reducing guilds in all four TMVs across a range of physiochemical conditions, with diversity of these guilds being unique to each TMV. The TMVs varied in potential sulfate reduction rates (SRR) by up to four orders of magnitude with highest SRR observed in sediments where in situ sulfate concentrations were highest. Maximum temperatures at which SRR were measured was 60 degrees C in two TMVs. Corresponding with these trends in SRR, members of the potentially thermophilic, spore-forming, Desulfotomaculum were detected in these TMVs by targeted 16S rRNA analysis. Additional sulfate-reducing bacterial lineages included members of the Desulfobacteraceae and Desulfobulbaceae detected by aprA and dsrA analyses and likely contributing to the mesophilic SRR measured. Phylotypes affiliated with sulfide-oxidizing Gamma- and Betaproteobacteria were abundant in aprA libraries from low sulfate TMVs, while the highest sulfate TMV harboured 16S rRNA phylotypes associated with sulfur-oxidizing Epsilonproteobacteria. Altogether, the biogeochemical and microbiological data indicate these unique terrestrial habitats support diverse active sulfur-cycling microorganisms reflecting the in situ geochemical environment. Y1 - 2012 U6 - https://doi.org/10.1111/1462-2920.12015 SN - 1462-2912 VL - 14 IS - 12 SP - 3271 EP - 3286 PB - Wiley-Blackwell CY - Hoboken ER - TY - BOOK A1 - Petersen, Jens T1 - Adam Smith als Rechtstheoretiker Y1 - 2012 SN - 978-3-11-028347-1 U6 - https://doi.org/10.1515/9783110283525 PB - de Gruyter CY - Berlin ER - TY - THES A1 - Schwartze, Michael T1 - Adaption to temporal structure T2 - MPI series in human cognitive and brain sciences Y1 - 2012 SN - 978-3-941504-22-6 VL - 138 PB - Max-Planck-Institut für Kognitions- und Neurowissenschaften CY - Leipzig ER - TY - JOUR A1 - Bodrova, Anna A1 - Schmidt, Jürgen A1 - Spahn, Frank A1 - Brilliantov, Nikolai V. T1 - Adhesion and collisional release of particles in dense planetary rings JF - Icarus : international journal of solar system studies N2 - We propose a simple theoretical model for aggregative and fragmentative collisions in Saturn's dense rings. In this model the ring matter consists of a bimodal size distribution: large (meter sized) boulders and a population of smaller particles (tens of centimeters down to dust). The small particles can adhesively stick to the boulders and can be released as debris in binary collisions of their carriers. To quantify the adhesion force we use the JKR theory (Johnson, K., Kendall, K., Roberts, A. [1971]. Proc. R. Soc. Lond. A 324, 301-313). The rates of release and adsorption of particles are calculated, depending on material parameters, sizes, and plausible velocity dispersions of carriers and debris particles. In steady state we obtain an expression for the amount of free debris relative to the fraction still attached to the carriers. In terms of this conceptually simple model a paucity of subcentimeter particles in Saturn's rings (French, R.G., Nicholson, P.D. [2000]. Icarus 145, 502-523; Marouf, E. et al. [2008]. Abstracts for "Saturn after Cassini-Huygens" Symposium, Imperial College London, UK, July 28 to August 1, p. 113) can be understood as a consequence of the increasing strength of adhesion (relative to inertial forces) for decreasing particle size. In this case particles smaller than a certain critical radius remain tightly attached to the surfaces of larger boulders, even when the boulders collide at their typical speed. Furthermore, we find that already a mildly increased velocity dispersion of the carrier-particles may significantly enhance the fraction of free debris particles, in this way increasing the optical depth of the system. KW - Planetary rings KW - Saturn, Rings KW - Collisional physics Y1 - 2012 U6 - https://doi.org/10.1016/j.icarus.2011.11.011 SN - 0019-1035 SN - 1090-2643 VL - 218 IS - 1 SP - 60 EP - 68 PB - Elsevier CY - San Diego ER - TY - INPR A1 - Bühler, Markus J. A1 - Rabu, Pierre A1 - Taubert, Andreas T1 - Advanced hybrid materials - design and applications T2 - European journal of inorganic chemistry : a journal of ChemPubSoc Europe Y1 - 2012 U6 - https://doi.org/10.1002/ejic.201201263 SN - 1434-1948 IS - 32 SP - 5092 EP - 5093 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Roy, Hans A1 - Kallmeyer, Jens A1 - Adhikari, Rishi Ram A1 - Pockalny, Robert A1 - Jorgensen, Bo Barker A1 - D'Hondt, Steven T1 - Aerobic microbial respiration in 86-million-year-old deep-sea red clay JF - Science N2 - Microbial communities can subsist at depth in marine sediments without fresh supply of organic matter for millions of years. At threshold sedimentation rates of 1 millimeter per 1000 years, the low rates of microbial community metabolism in the North Pacific Gyre allow sediments to remain oxygenated tens of meters below the sea floor. We found that the oxygen respiration rates dropped from 10 micromoles of O-2 liter(-1) year(-1) near the sediment-water interface to 0.001 micromoles of O-2 liter(-1) year(-1) at 30-meter depth within 86 million-year-old sediment. The cell-specific respiration rate decreased with depth but stabilized at around 10(-3) femtomoles of O-2 cell(-1) day(-1) 10 meters below the seafloor. This result indicated that the community size is controlled by the rate of carbon oxidation and thereby by the low available energy flux. Y1 - 2012 U6 - https://doi.org/10.1126/science.1219424 SN - 0036-8075 VL - 336 IS - 6083 SP - 922 EP - 925 PB - American Assoc. for the Advancement of Science CY - Washington ER - TY - JOUR A1 - Dunst, Alexander T1 - After trauma time and affect in american culture beyond 9/11 JF - Parallax Y1 - 2012 U6 - https://doi.org/10.1080/13534645.2012.672244 SN - 1353-4645 VL - 18 IS - 2 SP - 56 EP - 71 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Lange, Dietrich A1 - Tilmann, Frederik A1 - Barrientos, Sergio E. A1 - Contreras-Reyes, Eduardo A1 - Methe, Pascal A1 - Moreno, Marcos A1 - Heit, Ben A1 - Agurto, Hans A1 - Bernard, Pascal A1 - Vilotte, Jean-Pierre A1 - Beck, Susan T1 - Aftershock seismicity of the 27 February 2010 Mw 8.8 Maule earthquake rupture zone JF - Earth & planetary science letters N2 - On 27 February 2010 the M-w 8.8 Maule earthquake in Central Chile ruptured a seismic gap where significant strain had accumulated since 1835. Shortly after the mainshock a dense network of temporary seismic stations was installed along the whole rupture zone in order to capture the aftershock activity. Here, we present the aftershock distribution and first motion polarity focal mechanisms based on automatic detection algorithms and picking engines. By processing the seismic data between 15 March and 30 September 2010 from stations from IRIS, IPGP, GFZ and University of Liverpool we determined 20,205 hypocentres with magnitudes M-w between 1 and 5.5. Seismic activity occurs in six groups: 1.) Normal faulting outer rise events 2.) A shallow group of plate interface seismicity apparent at 25-35 km depth and 50-120 km distance to the trench with some variations between profiles. Along strike, the aftershocks occur largely within the zone of coseismic slip but extend similar to 50 km further north, and with predominantly shallowly dipping thrust mechanisms. Along dip, the events are either within the zone of coseismic slip, or downdip from it, depending on the coseismic slip model used. 3.) A third band of seismicity is observed further downdip at 40-50 km depth and further inland at 150-160 km trench perpendicular distance, with mostly shallow dipping (similar to 28 degrees) thrust focal mechanisms indicating rupture of the plate interface significantly downdip of the coseismic rupture, and presumably above the intersection of the continental Moho with the plate interface. 4.) A deep group of intermediate depth events between 80 and 120 km depth is present north of 36 degrees S. Within the Maule segment, a large portion of events during the inter-seismic phase originated from this depth range. 5.) The magmatic arc exhibits a small amount of crustal seismicity but does not appear to show significantly enhanced activity after the M-w 8.8 Maule 2010 earthquake. 6.) Pronounced crustal aftershock activity with mainly normal faulting mechanisms is found in the region of Pichilemu (similar to 34.5 degrees S). These crustal events occur in a similar to 30 km wide region with sharp inclined boundaries and oriented oblique to the trench. The best-located events describe a plane dipping to the southwest, consistent with one of the focal planes of the large normal-faulting aftershock (M-w = 6.9) on 11 March 2010. KW - Maule 2010 earthquake KW - local seismicity KW - aftershock distribution KW - subduction zone KW - Central Chile KW - seismogenic zone Y1 - 2012 U6 - https://doi.org/10.1016/j.epsl.2011.11.034 SN - 0012-821X VL - 317 IS - 2 SP - 413 EP - 425 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Guimaraes, Ana H. F. A1 - Albers, Nicole A1 - Spahn, Frank A1 - Seiss, Martin A1 - Vieira-Neto, Ernesto A1 - Brilliantov, Nikolai V. T1 - Aggregates in the strength and gravity regime Particles sizes in Saturn's rings JF - Icarus : international journal of solar system studies N2 - Particles in Saturn's main rings range in size from dust to kilometer-sized objects. Their size distribution is thought to be a result of competing accretion and fragmentation processes. While growth is naturally limited in tidal environments, frequent collisions among these objects may contribute to both accretion and fragmentation. As ring particles are primarily made of water ice attractive surface forces like adhesion could significantly influence these processes, finally determining the resulting size distribution. Here, we derive analytic expressions for the specific self-energy Q and related specific break-up energy Q(star) of aggregates. These expressions can be used for any aggregate type composed of monomeric constituents. We compare these expressions to numerical experiments where we create aggregates of various types including: regular packings like the face-centered cubic (fcc), Ballistic Particle Cluster Aggregates (BPCA), and modified BPCAs including e.g. different constituent size distributions. We show that accounting for attractive surface forces such as adhesion a simple approach is able to: (a) generally account for the size dependence of the specific break-up energy for fragmentation to occur reported in the literature, namely the division into "strength" and "gravity" regimes and (b) estimate the maximum aggregate size in a collisional ensemble to be on the order of a few tens of meters, consistent with the maximum particle size observed in Saturn's rings of about 10 m. KW - Collisional physics KW - Accretion KW - Planetary rings KW - Saturn, Rings Y1 - 2012 U6 - https://doi.org/10.1016/j.icarus.2012.06.005 SN - 0019-1035 SN - 1090-2643 VL - 220 IS - 2 SP - 660 EP - 678 PB - Elsevier CY - San Diego ER - TY - JOUR A1 - Steyrleuthner, Robert A1 - Schubert, Marcel A1 - Howard, Ian A1 - Klaumünzer, Bastian A1 - Schilling, Kristian A1 - Chen, Zhihua A1 - Saalfrank, Peter A1 - Laquai, Frederic A1 - Facchetti, Antonio A1 - Neher, Dieter T1 - Aggregation in a high-mobility n-type low-bandgap copolymer with implications on semicrystalline morphology JF - Journal of the American Chemical Society N2 - We explore the photophysics of P(NDI2OD-T2), a high-mobility and air-stable n-type donor/acceptor polymer. Detailed steady-state UV-vis and photoluminescence (PL) measurements on solutions of P(NDI2OD-T2) reveal distinct signatures of aggregation. By performing quantum chemical calculations, we can assign these spectral features to unaggregated and stacked polymer chains. NMR measurements independently confirm the aggregation phenomena of P(NDI2OD-T2) in solution. The detailed analysis of the optical spectra shows that aggregation is a two-step process with different types of aggregates, which we confirm by time-dependent PL measurements. Analytical ultracentrifugation measurements suggest that aggregation takes place within the single polymer chain upon coiling. By transferring these results to thin P(NDI2OD-T2) films, we can conclude that film formation is mainly governed by the chain collapse, leading in general to a high aggregate content of similar to 45%. This process also inhibits the formation of amorphous and disordered P(NDI2OD-T2) films. Y1 - 2012 U6 - https://doi.org/10.1021/ja306844f SN - 0002-7863 VL - 134 IS - 44 SP - 18303 EP - 18317 PB - American Chemical Society CY - Washington ER - TY - BOOK ED - Ette, Ottmar ED - Kutzinski, Vera ED - Dassow Walls, Laura T1 - Alexander von Humboldt and the Americas T3 - Potsdamer inter- und transkulturelle Texte : POINTE Y1 - 2012 SN - 978-3-938944-63-9 VL - 3 PB - Ed. Tranvia Frey CY - Berlin ER - TY - JOUR A1 - Khuroo, Anzar A. A1 - Reshi, Zafar A. A1 - Malik, Akhtar H. A1 - Weber, Ewald A1 - Rashid, Irfan A1 - Dar, G. H. T1 - Alien flora of India taxonomic composition, invasion status and biogeographic affiliations JF - Biological invasions : unique international journal uniting scientists in the broad field of biological invasions N2 - The wide knowledge gaps in invasion biology research that exist in the developing world are crucial impediments to the scientific management and global policymaking on biological invasions. In an effort to fill such knowledge gaps, we present here an inventory of the alien flora of India, based on systematic reviews and rigorous analyses of research studies (ca. 190) published over the last 120 years (1890-2010 AD), and updated with field records of the last two decades. Currently, the inventory comprises of 1,599 species, belonging to 842 genera in 161 families, and constitutes 8.5% of the total Indian vascular flora. The three most species-rich families are Asteraceae (134 spp.), Papilionaceae (114 spp.) and Poaceae (106 spp.), and the three largest genera are Eucalyptus (25 spp.), Ipomoea (22 spp.), and Senna (21 spp.). The majority of these species (812) have no report of escaping from cultivation. Of the remaining subset of 787 species, which have either escaped from intentional cultivation, or spread after unintentional introduction, casuals are represented by 57 spp., casual/naturalised by 114 spp., naturalised by 257 spp., naturalised/invasive by 134 spp., and invasive by 225 spp. Biogeographically, more than one-third (35%) of the alien flora in India has its native ranges in South America, followed by Asia (21%), Africa (20%), Europe (11%), Australia (8%), North America (4%); and cryptogenic (1%). The inventory is expected to serve as the scientific baseline on plant invasions in India, with implications for conservation of global biodiversity. KW - Biodiversity KW - Biological invasions KW - Alien plants KW - Taxonomy KW - Biogeography KW - India Y1 - 2012 U6 - https://doi.org/10.1007/s10530-011-9981-2 SN - 1387-3547 VL - 14 IS - 1 SP - 99 EP - 113 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Vukicevic, Radovan A1 - Schwadtke, Ulrike A1 - Schmuecker, Simon A1 - Schaefer, Philipp A1 - Kuckling, Dirk A1 - Beuermann, Sabine T1 - Alkyne-azide coupling of tailored poly(vinylidene fluoride) and polystyrene for the synthesis of block copolymers JF - Polymer Chemistry N2 - The synthesis of block copolymers consisting of poly(vinylidene fluoride) (PVDF) and polystyrene (PS) is reported. Firstly, a propargyl-functionalized alkoxyamine initiator (PgOTIPNO) was prepared and subsequently used for the preparation of a propargyl-terminated PS homopolymer of different chain lengths with low dispersities via nitroxide-mediated radical polymerization. A tailored PVDF homopolymer with iodine end groups originating from iodine transfer polymerization was transformed to PVDF with azide end group. Then, alkyne-terminated PS with different molecular weights and azide-terminated PVDF were joined together via copper-catalyzed alkyne-azide coupling. The block copolymers were characterized using H-1-NMR, F-19-NMR, IR, SEC, and DSC. Y1 - 2012 U6 - https://doi.org/10.1039/c1py00427a SN - 1759-9954 VL - 3 IS - 2 SP - 409 EP - 414 PB - Royal Society of Chemistry CY - Cambridge ER - TY - INPR A1 - Lenhard, Michael T1 - All's well that ends well arresting cell proliferation in leaves T2 - Developmental cell N2 - The transition from cell proliferation to cell expansion is critical for determining leaf size. Andriankaja et al. (2012) demonstrate that in leaves of dicotyledonous plants, a basal proliferation zone is maintained for several days before abruptly disappearing, and that chloroplast differentiation is required to trigger the onset of cell expansion. Y1 - 2012 U6 - https://doi.org/10.1016/j.devcel.2011.12.004 SN - 1534-5807 VL - 22 IS - 1 SP - 9 EP - 11 PB - Cell Press CY - Cambridge ER - TY - JOUR A1 - Schröder, Christiane A1 - Pokorny, Ina A1 - Dolgener, Nicola A1 - Herden, Christoph A1 - Drews, Hauke A1 - Tiedemann, Ralph T1 - Allochthonous individuals in managed populations of the fire-bellied toad Bombina bombina genetic detection and conservation implications JF - Limnologica : ecology and management of inland waters N2 - The ongoing global amphibian decline calls for an increase of habitat and population management efforts. Pond restoration and construction is more and more accompanied by breeding and translocation programs. However, the appropriateness of translocations as a tool for conservation has been widely debated, as it can cause biodiversity loss through genetic homogenization and can disrupt local adaptation, eventually leading to outbreeding depression. In this study, we investigated the genetic structure of two translocated populations of the critically endangered fire-bellied toad Bombina bombina at its north western distribution edge using supposedly neutral genetic markers (variation in the mitochondrial control region and microsatellites) as well as a marker under selection (major histocompatibility complex (MHC) genes). While one of the newly established populations showed the typical genetic composition of surrounding populations, the other was extremely diverged without clear affinity to its putative source. In this population we detected a profound impact of allochthonous individuals: 100% of the analyzed individuals exhibited a highly divergent mitochondrial haplotype which was otherwise found in Austria. 83% of them were also assigned to Austria by the analysis of microsatellites. Interestingly, for the adaptive marker (MHC) local alleles were predominant in this population, while only very few alleles were shared with the Austrian population. Probably Mendelian inheritance has reshuffled genotypes such that adaptive local alleles are maintained (here, MHC), while presumably neutral allochthonous alleles dominate at other loci. The release of allochthonous individuals generally increased the genetic variability of the affected population without wiping out locally adaptive genotypes. Thus, outbreeding depression might be less apparent than sometimes thought and natural selection appears strong enough to maintain locally adaptive alleles, at least in functionally important immune system genes. KW - Bombina bombina KW - Microsatellites KW - MHC KW - Mitochondrial DNA KW - Population management KW - Translocation Y1 - 2012 U6 - https://doi.org/10.1016/j.limno.2012.08.008 SN - 0075-9511 VL - 42 IS - 4 SP - 291 EP - 298 PB - Elsevier CY - Jena ER - TY - JOUR A1 - Schmidt, Bernd A1 - Kunz, Oliver T1 - alpha,beta-Unsaturated delta-Valerolactones through RCM-Isomerization Sequence JF - Synlett : accounts and rapid communications in synthetic organic chemistry N2 - alpha,beta-Unsaturated d-lactones are accessible via a sequential ring-closing metathesis (RCM) double-bond migration reaction starting from butenoates of allyl alcohols. This approach proceeds efficiently with lower catalyst loadings and higher initial substrate concentrations compared to the alternative RCM of acrylates derived from homoallylic alcohols. KW - ruthenium KW - lactones KW - tandem reactions KW - metathesis KW - esters Y1 - 2012 U6 - https://doi.org/10.1055/s-0031-1290488 SN - 0936-5214 IS - 6 SP - 851 EP - 854 PB - Thieme CY - Stuttgart ER - TY - JOUR A1 - Lehnert, Gertrud T1 - Als die Mode ins Bild drängte Y1 - 2012 ER - TY - JOUR A1 - Kilian, Sven Thorsten T1 - Alte neue Wut : Affektbearbeitungsstrategien in Eros e Priapo und Quer pasticciaccio brutto de via Merulana von Carlo Emilio Gadda Y1 - 2012 SN - 978-3-86596-386-4 ER - TY - CHAP A1 - Kilian, Sven Thorsten ED - Bauer, Lydia ED - Reinke, Kristin T1 - Alte neue Wut: Affektbearbeitungsstrategien in Eros e Priapo und Quer pasticciaccio brutto de via Merulana von Carlo Emilio Gadda T2 - Wut – zerstörerische Kraft und kreatives Potential. Emotionalität in Literatur und Sprache T2 - Colère - force destructive et potentiel créatif. L'émotivté dans la littérature et le langage Y1 - 2012 SN - 978-3-86596-386-4 SP - 239 EP - 258 PB - Frank & Timme CY - Berlin ER - TY - CHAP A1 - Doyon, Anke A1 - Schmiedchen, Bettina A1 - Bayazit, Aysun A1 - Canpolat, Nur A1 - Duzova, Ali A1 - Kracht, Daniela A1 - Litwin, Mieczyslaw A1 - Niemirska, Anna A1 - Sozeri, Betul A1 - Zeller, Rene A1 - Anarat, Ali A1 - Caliskan, Salim A1 - Mir, Sevgi A1 - Shroff, Rukshana A1 - Melk, Anette A1 - Wühl, Elke A1 - Schweigert, Florian J. A1 - Querfeld, Uwe A1 - Schäfer, Franz T1 - Altered arterial morphology and function in children with CKD Role of mineral-bone disorder T2 - Pediatric nephrology : journal of the International Pediatric Nephrology Association Y1 - 2012 SN - 0931-041X VL - 27 IS - 9 SP - 1606 EP - 1607 PB - Springer CY - New York ER - TY - JOUR A1 - Kossack, Peter T1 - Ambivalente Praxis der Studieneingangsphase Y1 - 2012 SN - 978-3- 937026-77-0 ER - TY - JOUR A1 - Zimmermann, Andreas T1 - Amending the amendment provisions of the rome statute : the kampala compromise on the crime of aggression and the law of treaties Y1 - 2012 ER - TY - JOUR A1 - Zimmermann, Andreas T1 - Amending the amendment provisions of the rome statute the kampala compromise on the crime of aggression and the law of treaties JF - Journal of international criminal justice N2 - The adoption, in Kampala in June 2010, of amendments to the Rome Statute on the crime of aggression was hailed as a historic milestone in the development of the international Criminal Court (ICC). However, the manner in which these amendments are supposed to enter into force runs the risk of undermining the rules of the international law of treaties, as well as the legality and acceptability of the Kampala compromise itself The author examines the relevant amendment procedures provided for in the ICC Statute and the compatibility with them of the amendment procedure chosen in Kampala and ultimately warns of the legal consequences which may follow from the Review Conference's somewhat-Alexandrian solution. Y1 - 2012 U6 - https://doi.org/10.1093/jicj/mqs002 SN - 1478-1387 VL - 10 IS - 1 SP - 209 EP - 227 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Wertheimer, Michael R. A1 - St-Georges-Robillard, Amelie A1 - Lerouge, Sophie A1 - Mwale, Fackson A1 - Elkin, Bentsian A1 - Oehr, Christian A1 - Wirges, Werner A1 - Gerhard, Reimund T1 - Amine-rich organic thin films for cell culture - possible electrostatic effects in cell-surface interactions JF - Japanese journal of applied physics N2 - In recent communications from these laboratories, we observed that amine-rich thin organic layers are very efficient surfaces for the adhesion of mammalian cells. We prepare such deposits by plasma polymerization at low pressure, atmospheric pressure, or by vacuum-ultraviolet photo-polymerization. More recently, we have also investigated a commercially available material, Parylene diX AM. In this article we first briefly introduce literature relating to electrostatic interactions between cells, proteins, and charged surfaces. We then present certain selected cell-response results that pertain to applications in orthopedic and cardiovascular medicine: we discuss the influence of surface properties on the observed behaviors of two particular cell lines, human U937 monocytes, and Chinese hamster ovary cells. Particular emphasis is placed on possible electrostatic attractive forces due to positively charged R-NH3+ groups and negatively charged proteins and cells, respectively. Experiments carried out with electrets, polymers with high positive or negative surface potentials are added for comparison. Y1 - 2012 U6 - https://doi.org/10.1143/JJAP.51.11PJ04 SN - 0021-4922 VL - 51 IS - 11 PB - Japan Soc. of Applied Physics CY - Tokyo ER - TY - JOUR A1 - Kunow, Rüdiger T1 - An ABC of Mobility : Reflections on analytical models and critical vocabularies Y1 - 2012 SN - 978-3-8253-6033-7 ER - TY - JOUR A1 - Ben Bekhti, Nadya A1 - Winkel, B. A1 - Richter, P. A1 - Kerp, J. A1 - Klein, U. A1 - Murphy, M. T. T1 - An absorption-selected survey of neutral gas in the Milky Way halo New results based on a large sample of Ca II, Na I, and H I spectra towards QSOs JF - Astronomy and astrophysics : an international weekly journal N2 - Aims. We aim at analysing systematically the distribution and physical properties of neutral and mildly ionised gas in the Milky Way halo, based on a large absorption-selected data set. Methods. Multi-wavelength studies were performed combining optical absorption line data of Ca II and Na I with follow-up H I 21-cm emission line observations along 408 sight lines towards low-and high-redshift QSOs. We made use of archival optical spectra obtained with UVES/VLT. H I data were extracted from the Effelsberg-Bonn H I survey and the Galactic All-Sky survey. For selected sight lines we obtained deeper follow-up observations using the Effelsberg 100-m telescope. Results. Ca II (Na I) halo absorbers at intermediate and high radial velocities are present in 40-55% (20-35%) of the sightlines, depending on the column density threshold chosen. Many halo absorbers show multi-component absorption lines, indicating the presence of sub-structure. In 65% of the cases, absorption is associated with H I 21-cm emission. The Ca II (Na I) column density distribution function follows a power-law with a slope of beta approximate to -2.2 (-1.4). Conclusions. Our absorption-selected survey confirms our previous results that the Milky Way halo is filled with a large number of neutral gas structures whose high column density tail represents the population of common H I high-and intermediate-velocity clouds seen in 21-cm observations. We find that Na I/Ca II column density ratios in the halo absorbers are typically smaller than those in the Milky Way disc, in the gas in the Magellanic Clouds, and in damped Lyman a systems. The small ratios (prominent in particular in high-velocity components) indicate a lower level of Ca depletion onto dust grains in Milky Way halo absorbers compared to gas in discs and inner regions of galaxies. KW - Galaxy: halo KW - ISM: structure Y1 - 2012 U6 - https://doi.org/10.1051/0004-6361/201118673 SN - 0004-6361 VL - 542 IS - 2 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Roschke, Sebastian A1 - Cheng, Feng A1 - Meinel, Christoph T1 - An alert correlation platform for memory-supported techniques JF - Concurrency and computation : practice & experience N2 - Intrusion Detection Systems (IDS) have been widely deployed in practice for detecting malicious behavior on network communication and hosts. False-positive alerts are a popular problem for most IDS approaches. The solution to address this problem is to enhance the detection process by correlation and clustering of alerts. To meet the practical requirements, this process needs to be finished fast, which is a challenging task as the amount of alerts in large-scale IDS deployments is significantly high. We identifytextitdata storage and processing algorithms to be the most important factors influencing the performance of clustering and correlation. We propose and implement a highly efficient alert correlation platform. For storage, a column-based database, an In-Memory alert storage, and memory-based index tables lead to significant improvements of the performance. For processing, algorithms are designed and implemented which are optimized for In-Memory databases, e.g. an attack graph-based correlation algorithm. The platform can be distributed over multiple processing units to share memory and processing power. A standardized interface is designed to provide a unified view of result reports for end users. The efficiency of the platform is tested by practical experiments with several alert storage approaches, multiple algorithms, as well as a local and a distributed deployment. KW - memory-based correlation KW - memory-based clustering KW - memory-based databases KW - IDS management Y1 - 2012 U6 - https://doi.org/10.1002/cpe.1750 SN - 1532-0626 VL - 24 IS - 10 SP - 1123 EP - 1136 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Sternagel, Jörg T1 - An emphasis in Being : moving towards a responsive phenomenology of film('s) performance Y1 - 2012 SN - 978-3-8376-1648-4 ER - TY - JOUR A1 - Bergemann, Kay A1 - Reich, Sebastian T1 - An ensemble Kalman-Bucy filter for continuous data assimilation JF - Meteorologische Zeitschrift N2 - The ensemble Kalman filter has emerged as a promising filter algorithm for nonlinear differential equations subject to intermittent observations. In this paper, we extend the well-known Kalman-Bucy filter for linear differential equations subject to continous observations to the ensemble setting and nonlinear differential equations. The proposed filter is called the ensemble Kalman-Bucy filter and its performance is demonstrated for a simple mechanical model (Langevin dynamics) subject to incremental observations of its velocity. Y1 - 2012 U6 - https://doi.org/10.1127/0941-2948/2012/0307 SN - 0941-2948 VL - 21 IS - 3 SP - 213 EP - 219 PB - Schweizerbart CY - Stuttgart ER - TY - THES A1 - Patil, Umesh T1 - An evaluation of a cognitive architecture of sentence processing : computational and empirical assessment Y1 - 2012 CY - Potsdam ER - TY - JOUR A1 - Frijia, Gianluca A1 - Di Lucia, Matteo A1 - Vicedo, Vicent A1 - Günter, Christina A1 - Ziemann, Martin Andreas A1 - Mutti, Maria T1 - An extraordinary single-celled architect A multi-technique study of the agglutinated shell of the larger foraminifer Mesorbitolina from the Lower Cretaceous of southern Italy JF - Marine micropaleontology N2 - Orbitolinids are larger foraminifera widespread in Lower Cretaceous shallow-water carbonates of the Tethyan realm. They are among the most important fossil groups used for Biostratigraphy. Despite this and although the structural features of the group have been described in detail, very little is known about the composition of their agglutinated test and the process by which they selected foreign grains. In this study, the test of Orbitolina d'Orbigny, 1850 (subgenus Mesorbitolina Schroeder, 1962) from Aptian shallow-water carbonate deposits of southern Italy has been studied in detail. We combine petrographic techniques (optical microscope and SEM) with energy-dispersive x-ray spectrometry (EDS), electron probe microanalyzer (EPMA), X-ray diffraction and Raman spectroscopy analyses. The results show that the test of Mesorbitolina is composed of carbonate and non-carbonate agglutinated grains with the latter distributed across the test with a specific pattern, moving from the marginal to the central zone. In the marginal zone, non-carbonate grains are found only in the epidermis and along the septa which are composed of quartz, with smaller amounts of illite/muscovite and K-feldspar grains. In the central zone of the test, non-carbonate grains are distributed in two ways. Coarse grains of quartz and K-feldspar are abundant and randomly placed in the endoskeleton embedded in a mosaic of minute carbonate grains. Flat grains, mainly of illite/muscovite constitute the external part of the septa. Our observations indicate that Mesorbitolina did select and place agglutinated grains across its test, mainly according to their shape, whereas it did not select particles according to grain size. The distribution of agglutinated particles according to their mineralogical composition shows some contradictory evidence and therefore, at the moment, grain selection in function of mineralogy cannot be completely confirmed or ruled out. Analogies in the test composition of Mesorbitolina specimens from coeval deposits from different areas of southern Italy indicate that the features of their agglutinated test are typical characters of the genus Mesorbitolina. However, it is still unclear what advantage was obtained by the foraminifer by the described test features. KW - Agglutinated foraminifera KW - Mesorbitolina KW - Shallow-water carbonates KW - Lower Cretaceous KW - Southern Italy Y1 - 2012 U6 - https://doi.org/10.1016/j.marmicro.2012.04.002 SN - 0377-8398 VL - 90-91 IS - 7 SP - 60 EP - 71 PB - Elsevier CY - Amsterdam ER - TY - BOOK A1 - Lerch, Alexander T1 - An introduction to audio content analysis : applications in signal processing and music informatics Y1 - 2012 SN - 978-1-118-26682-3 U6 - https://doi.org/10.1002/9781118393550 PB - Wiley CY - Hoboken, N.J ER - TY - JOUR A1 - Debatin, Franziska A1 - Behrens, Karsten A1 - Weber, Jens A1 - Baburin, Igor A. A1 - Thomas, Arne A1 - Schmidt, Johannes A1 - Senkovska, Irena A1 - Kaskel, Stefan A1 - Kelling, Alexandra A1 - Hedin, Niklas A1 - Bacsik, Zoltan A1 - Leoni, Stefano A1 - Seifert, Gotthard A1 - Jäger, Christian A1 - Günter, Christina A1 - Schilde, Uwe A1 - Friedrich, Alwin A1 - Holdt, Hans-Jürgen T1 - An isoreticular family of microporous metal-organic frameworks based on zinc and 2-substituted imidazolate-4-amide-5-imidate Syntheses, structures and properties JF - Chemistry - a European journal N2 - We report on a new series of isoreticular frameworks based on zinc and 2-substituted imidazolate-4-amide-5-imidate (IFP-14, IFP=imidazolate framework Potsdam) that form one-dimensional, microporous hexagonal channels. Varying R in the 2-substitued linker (R=Me (IFP-1), Cl (IFP-2), Br (IFP-3), Et (IFP-4)) allowed the channel diameter (4.01.7 angstrom), the polarisability and functionality of the channel walls to be tuned. Frameworks IFP-2, IFP-3 and IFP-4 are isostructural to previously reported IFP-1. The structures of IFP-2 and IFP-3 were solved by X-ray crystallographic analyses. The structure of IFP-4 was determined by a combination of PXRD and structure modelling and was confirmed by IR spectroscopy and 1H MAS and 13C CP-MAS NMR spectroscopy. All IFPs showed high thermal stability (345400?degrees C); IFP-1 and IFP-4 were stable in boiling water for 7 d. A detailed porosity analysis was performed on the basis of adsorption measurements by using various gases. The potential of the materials to undergo specific interactions with CO2 was investigated by measuring the isosteric heats of adsorption. The capacity to adsorb CH4 (at 298 K), CO2 (at 298 K) and H2 (at 77 K) at high pressure were also investigated. In situ IR spectroscopy showed that CO2 is physisorbed on IFP-14 under dry conditions and that both CO2 and H2O are physisorbed on IFP-1 under moist conditions. KW - adsorption KW - metal- organic frameworks KW - microporous materials KW - N KW - O ligands KW - zinc Y1 - 2012 U6 - https://doi.org/10.1002/chem.201200889 SN - 0947-6539 VL - 18 IS - 37 SP - 11630 EP - 11640 PB - Wiley-VCH CY - Weinheim ER -