TY - JOUR A1 - Wilke, Max A1 - Behrens, Harald T1 - The Dependence of the partitioning of iron and europium between plagioclase and hydrous tonalitic melt on oxygen fugacity Y1 - 1999 ER - TY - JOUR A1 - Richet, Pascal A1 - Whittington, Alan A1 - Holtz, Francois A1 - Behrens, Harald A1 - Ohlhorst, Susanne A1 - Wilke, Max T1 - Water and the density of silicate glasses Y1 - 2000 ER - TY - JOUR A1 - Martel, Caroline A1 - Dingwell, Donald Bruce A1 - Spieler, Oliver A1 - Pichavant, Michel A1 - Wilke, Max T1 - Fragmentation of foamed in silicic melts : an experimental study Y1 - 2000 ER - TY - JOUR A1 - Petit, Pierre-Emanuel A1 - Farges, Francois A1 - Wilke, Max A1 - Solé, V. Armando T1 - Determination of the iron oxidation state in Earth materials using XANES pre-edge information Y1 - 2001 ER - TY - JOUR A1 - Wilke, Max A1 - Farges, Francois A1 - Petit, Pierre-Emanuel A1 - Brown Jr., Gordon E. A1 - Martin, Francois T1 - Oxidation state and coordination of Fe in minerals : an Fe K XANES spectroscopic study Y1 - 2001 ER - TY - JOUR A1 - Martel, Caroline A1 - Dingwell, Donald Bruce A1 - Spieler, Oliver A1 - Pichavant, Michel A1 - Wilke, Max T1 - Experimental fragmentation of crystal- and vesicle-bearing silicic melts Y1 - 2001 ER - TY - JOUR A1 - Wilke, Max A1 - Behrens, Harald A1 - Burkhard, Dorothee J. M. A1 - Rossano, Stephanie T1 - The oxidation state of iron in silicic melt at 500 MPa water pressure Y1 - 2002 ER - TY - JOUR A1 - Wilke, Max A1 - Nabelek, Peter I. A1 - Glascock, Michael D. T1 - B and Li in Proterozoic metapelites from the Black Hills, U.S.A. : Implications for the origin of leucogranitic magmas Y1 - 2002 ER - TY - JOUR A1 - Wilke, Max A1 - Partzsch, G. M. A1 - Schmidt, C. A1 - Farges, Francois T1 - In-situ study of the iron species in silicate melts Y1 - 2004 SN - 0016-7037 ER - TY - JOUR A1 - Botcharnikov, Roman E. A1 - Koepke, J. A1 - Holtz, Francois A1 - McCammon, C. A1 - Wilke, Max T1 - The oxidation and structural state of Fe in hydrous ferrobasaltic melt Y1 - 2004 ER - TY - JOUR A1 - Kanngiesser, Birgit A1 - Hahn, O. A1 - Wilke, Max A1 - Nekat, B. A1 - Malzer, Wolfgang A1 - Erko, Alexei T1 - Investigation of oxidation and migration processes of inorganic compounds in ink-corroded manuscripts N2 - We studied the oxidation and migration processes of inorganic compounds in iron gall inks with a combination of micro X-ray fluorescence analysis (micro-XRF) and micro X-ray absorption near edge structure spectroscopy (micro-XANES). With elemental mapping by micro-XRF, the correlation of the minor elements in the ink to the major element Fe was investigated. Along concentration profiles of Fe, micro-XANES measurements were carried out in order to determine the oxidation state and the local environment. With the help of model inks, we could show that Cu is a further important element in the paper degradation process due to iron gall ink corrosion. (C) 2004 Elsevier B.V. All rights reserved Y1 - 2004 SN - 0584-8547 ER - TY - JOUR A1 - Nabelek, Peter I. A1 - Wilke, Max A1 - Huff, T. A. T1 - Methane production during metamorphism of graphitic pelites, Black Hills, USA Y1 - 2004 SN - 0016-7037 ER - TY - JOUR A1 - Wilke, Max A1 - Partzsch, G. M. A1 - Bernhardt, Rita A1 - Lattard, D. T1 - Determination of the iron oxidation state in basaltic glasses using XANES at the K-edge N2 - Fe K-edge X-ray absorption near edge structure (XANES) and Mossbauer spectra were collected on synthetic glasses of basaltic composition and of glasses on the sodium oxide-silica binary to establish a relation between the pre- edge of the XANES at the K-edge and the Fe oxidation state of depolymerised glasses. Charges of sample material were equilibrated at ambient pressure, superliquidus temperatures and oxygen fugacities that were varied over a range of about 15 orders of magnitude. Most experiments were carried out in gas-flow furnaces, either with pure oxygen, air, or different CO/CO2 mixtures. For the most reduced conditions, the samples charges were enclosed together with a pellet of the IQF oxygen buffer in an evacuated silica glass ampoule. Fe3+/SigmaFe x 100 of the samples determined by Mossbauer spectroscopy range between 0% and 100%. Position and intensity of the pre-edge centroid position vary strongly depending on the Fe oxidation state. The pre-edge centroid position and the Fe oxidation state determined by Mossbauer spectroscopy are nonlinearly related and have been fitted by a quadratic polynomial. Alternatively, the ratio of intensities measured at positions sensitive to Fe2+ and Fe3+, respectively, provides an even more sensitive method. Pre- edge intensities of the sample suite indicate average Fe co-ordination between 4 and 6 for all samples regardless of oxidation state. A potential application of the calibration given here opens the possibility of determining Fe oxidation state in glasses of similar compositions with high spatial resolution by use of a Micro-XANES setup (e.g., glass inclusions in natural minerals). (C) 2004 Elsevier B.V. All rights reserved Y1 - 2004 SN - 0009-2541 ER - TY - JOUR A1 - Wilke, Max A1 - Partzsch, G. M. A1 - Farges, Francois T1 - XAFS of iron in silicate melt at high temperature Y1 - 2004 SN - 0024-4937 ER - TY - JOUR A1 - Nabelek, Peter I. A1 - Labotka, Theodore C. A1 - Helms, Thomas S. A1 - Wilke, Max T1 - Fluid-mediated mineral consumption and growth in polymetamorphosed metapelites of the Black Hills, South Dakota Y1 - 2005 SN - 0016-7037 ER - TY - JOUR A1 - Botcharnikov, Roman E. A1 - Koepke, J. A1 - Holtz, Francois A1 - McCammon, C. A1 - Wilke, Max T1 - The effect of water activity on the oxidation and structural state of Fe in a ferro-basaltic melt N2 - Experimental investigations have been performed at T = 1200 degrees C, P = 200 MPa and fH(2) corresponding to H2O-MnO-Mn3O4 and H2O-QFM redox buffers to study the effect of H2O activity on the oxidation and structural state of Fe in an iron-rich basaltic melt. The analysis of Mossbauer and Fe K-edge X-ray absorption nearedge structure (XANES) spectra of the quenched hydrous ferrobasaltic glasses shows that the Fe3+/Sigma Fe ratio of the glass is directly related to aH(2)O in a H-2-buffered system and, consequently, to the prevailing oxygen fugacity (through the reaction of water dissociation H2O <-> H-2 + 1/2 O-2). However, water as a chemical component of the silicate melt has an indistinguishable effect on the redox state of iron at studied conditions. The experimentally obtained relationship between fO(2) and Fe3+/Fe2+ in the hydrous ferrobasaltic melt can be adequately predicted in the investigated range by the existing empiric and thermodynamic models. The ratio of ferric and ferrous Fe is proportional to the oxygen fugacity to the power of similar to 0.25 which agrees with the theoretical value from the stoichiometry of the Fe redox reaction (FeO + 1/4 O-2 = FeO1.5). The mean centre shifts for Fe2+ and Fe3+ absorption doublets in Mossbauer spectra show little change with increasing Fe3+/Sigma Fe, suggesting no significant change in the type of iron coordination. Similarly, XANES preedge spectra indicate a mixed (C3h, Td, and Oh, i.e., 5-, 4-, and sixfold) coordination of Fe in hydrous basaltic glasses. Copyright (c) 2005 Elsevier Ltd Y1 - 2005 SN - 0016-7037 ER - TY - JOUR A1 - Wilke, Max A1 - Partzsch, G. M. A1 - Bernhardt, Rita A1 - Lattar, D. T1 - Determination of the iron oxidation state in basaltic glasses using XANES at the K-edge N2 - Fe K-edge X-ray absorption near edge structure (XANES) and Mossbauer spectra were collected on synthetic glasses of basaltic composition and of glasses on the sodium oxide-silica binary to establish a relation between the pre- edge of the XANES at the K-edge and the Fe oxidation state of depolymerised glasses. Charges of sample material were equilibrated at ambient pressure, superliquidus temperatures and oxygen fugacities that were varied over a range of about 15 orders of magnitude. Most experiments were carried out in gas-flow furnaces, either with pure oxygen, air, or different CO/CO2 mixtures. For the most reduced conditions, the samples charges were enclosed together with a pellet of the IQF oxygen buffer in an evacuated silica glass ampoule. Fe3+/Sigma Fe x 100 of the samples determined by Mossbauer spectroscopy range between 0% and 100%. Position and intensity of the pre-edge centroid position vary strongly depending on the Fe oxidation state. The pre-edge centroid position and the Fe oxidation state determined by Mossbauer spectroscopy are nonlinearly related and have been fitted by a quadratic polynomial. Alternatively, the ratio of intensities measured at positions sensitive to Fe2+ and Fe3+, respectively, provides an even more sensitive method. Pre- edge intensities of the sample suite indicate average Fe co-ordination between 4 and 6 for all samples regardless of oxidation state. A potential application of the calibration given here opens the possibility of determining Fe oxidation state in glasses of similar compositions with high spatial resolution by use of a Micro-XANES setup (e.g., glass inclusions in natural minerals). (c) 2004 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0009-2541 ER - TY - JOUR A1 - Wilke, Max T1 - Fe in magma : an overview N2 - The strong influence of physical conditions during magma formation on Fe equilibria offers a large variety of possibilities to deduce these conditions from Fe-bearing phases and phase assemblages found in magmatic rocks. Conditions of magma genesis and their evolution are of major interest for the understanding of volcanic eruptions. A brief overview on the most common methods used is given together with potential problems and limitations. Fe equilibria are not only sensitive to changes in intensive parameters (especially T and fO(2)) and extensive parameters like composition also have major effects, so that direct application of experimentally calibrated equilibria to natural systems is not always possible. Best estimates for pre-eruptive conditions are certainly achieved by studies that relate field observations directly to experimental observations for the composition of interest using as many constraints as possible (phase stability relations, Fe-Ti oxides, Fe partitioning between phases, Fe oxidation state in glass etc.). Local structural environment of Fe in silicate melts is an important parameter that is needed to understand the relationship between melt transport properties and melt structure. Assignment of Fe co-ordination and its relationship to the oxidation state seems not to be straightforward. In addition, there is considerable evidence that the co- ordination of Fe in glass differs from that in the melt, which has to be taken into account when linking melt structure to physical properties of silicate melts at T and P. Y1 - 2005 ER - TY - JOUR A1 - Rusu, Viorel Marin A1 - Ng, C. H. A1 - Wilke, Max A1 - Tiersch, Brigitte A1 - Fratzl, Peter A1 - Peter, Martin G. T1 - Size-controlled hydroxyapatite nanoparticles as self-organized organic-in organic composite materials N2 - This paper presents some results concerning the size-controlled hydroxyapatite nanoparticles obtained in aqueous media in a biopolymer matrix from soluble precursors salts. Taking the inspiration from nature, where composite materials made of a polymer matrix and inorganic fillers are often found, e.g. bone, shell of crustaceans, shell of eggs, etc., the feasibility on making composite materials containing chitosan and nanosized hydroxyapatite was investigated. A stepwise co-precipitation approach was used to obtain different types of composites by means of different ratio between components. The synthesis of hydroxyapatite was carried out in the chitosan matrix from calcium chloride and sodium dihydrogenphosphate in alkaline solutions at moderate pH of 10-11 for 24 h. Our research is focused on studying and understanding the structure of this class of composites, aiming at the development of novel materials, controlled at the nanolevel scale. The X-ray diffraction technique was employed in order to study the kinetic of hydroxyapatite formation in the chitosan matrix as well as to determine the HAp crystallite sizes in the composite samples. The hydroxyapatite synthesized using this route was found to be nano-sized (15-50nm). Moreover, applying an original approach to analyze the (002) XRD diffraction peak profile of hydroxyapatite by using a sum of two Gauss functions, the bimodal distribution of nanosized hydroxyapatite within the chitosan matrix was revealed. Two types of size distribution domains such as cluster-like (between 200 and 400 nm), which are the habitat of "small" hydroxyapatite nanocrystallites and scattered-like, which are the habitat of "large" hydroxyapatite nanocrystallites was probed by TEM and CSLM. The structural features of composites suggest that self-assembly processes might be involved. The composites contain nanosized hydroxyapatite with structural features close to those of biological apatites that make them attractive for bone tissue engineering applications. (c) 2005 Elsevier Ltd. All rights reserved Y1 - 2005 SN - 0142-9612 ER - TY - JOUR A1 - Farges, Francois A1 - Djanarthany, S A1 - de Wispelaere, S A1 - Munoz, Manuel A1 - Magassouba, B A1 - Haddi, A A1 - Wilke, Max A1 - Schmidt, C. A1 - Borchert, Manuela A1 - Trocellier, P A1 - Crichton, W A1 - Simionovici, Alexandre A1 - Petit, Pierre-Emanuel A1 - Mezouar, Mohamed A1 - Etcheverry, M. P. A1 - Pallot-Frossard, I A1 - Bargar, John Reeder A1 - Brown, G. E. A1 - Grolimund, D A1 - Scheidegger, A T1 - Water in silicate glasses and melts of environmental interest : from volcanoes to cathedrals N2 - In silicate glasses and melts, water acts according to two main processes. First, it can be dissolved in high temperature/high pressure melts. Second, it constitutes a weathering agent on the glass surface. A number of in-situ x- ray absorption fine structure (XAFS) studies for Fe, Ni, Zr, Th and U show that the more charged cations (Zr, Nb, Mo, Ta, Sn, Th and U) are little affected by the presence of dissolved water in the melt. In contrast, divalent iron and nickel are highly sensitive to the presence of water, which enhance nucleation processes, for example, of phyllosilicates at the angstrom-scale. Such information provides additional constraints on the role of water deep in the Earth, particularly in magmatology. By contrast, the weathering of glass surfaces by water can be studied from a durability perspective. Experimental weathering experiments Of nuclear waste glasses performed in the laboratory show a variety of surface enrichments (carbon, chlorine, alkalis, iron) after exposure to atmospheric fluids and moisture. Mn-, and Fe-surface enrichments of analogous glasses of the XIVth century are related to the formation of Mn and Fe oxy/ hydroxides on the surface. The impact on the glass darkening is considered in terms of urban pollution and mass tourism Y1 - 2005 ER - TY - JOUR A1 - Nabelek, Peter I. A1 - Labotka, Theodore C. A1 - Helms, Thomas S. A1 - Wilke, Max T1 - Fluid-mediated polymetamorphism related to proterozoic collision of Archean Wyoming and Superior Provinces in the Black Hills, South Dakota Y1 - 2006 ER - TY - JOUR A1 - Wilke, Max A1 - Schmidt, Christian A1 - Farges, Francois A1 - Malavergne, Valerie A1 - Gautron, Laurent A1 - Simionovici, Alexandre A1 - Hahn, Matthias A1 - Petit, Pierre-Emanuel T1 - Structural environment of iron in hydrous aluminosilicate glass and melt-evidence from X-ray absorption spectroscopy N2 - The iron speciation in hydrous haplotonalitic and haplogranitic silicate glasses was studied using XAFS spectroscopy and transmission electron microscopy (TEM). Spectral features occurring at the main crest of the XANES at the iron K-edge of hydrous glasses indicate contributions to the spectra by iron-moieties present in a more ordered structural environment than found in the dry glass. These differences are also suggested by analysis of the EXAFS. These effects are not completely suppressed even for those samples that were quenched with a higher cooling rate. Strongest differences to the dry glass are observed for a sample that was quenched slowly through the temperature of glass transformation. Crystals (60 to 1500 nm in size) of magnetite, maghemite and another unidentified phase were observed in this sample by TEM, whereas no crystals were found in samples quenched with regular or high cooling rates. In-situ XANES measurements up to 700 degrees C and 500 MPa were performed to reveal the origin (i.e., during synthesis or quench) of the structural differences for those hydrous glasses that do not display any detectable crystallization. The comparison of XANES spectra collected on Fe2+ in water-saturated haplogranitic melt at 700 degrees C and 500 MPa and on Fe2+ in dry melt at 1150 degrees C shows that the local structural environment of Fe2+ in both systems is similar. This indicates that there is no detectable and direct influence of water on the local structure around iron in this type of melt. Hence, the differences observed between hydrous and dry glasses can only be related to artefacts formed during the quench process. (c) 2006 Elsevier B.V. All rights reserved Y1 - 2006 U6 - https://doi.org/10.1016/j.chemgeo.2006.01.017 ER - TY - THES A1 - Wilke, Max T1 - Untersuchungen zur Eisenspeziation in Mineralphasen unter besonderer Berücksichtigung der Röntgenabsorptionsspektroskopie (XAFS) Y1 - 2006 CY - Potsdam ER - TY - JOUR A1 - Wilke, Max A1 - Farges, Francois A1 - Partzsch, G. M. A1 - Schmidt, C. A1 - Behrens, Harald T1 - Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy Y1 - 2007 ER - TY - JOUR A1 - Wilke, Max A1 - Partzsch, G. M. A1 - Welter, E. A1 - Farges, Francois T1 - Redox Reaction In Silicate Melts Monitored By Static In-Situ Fe K-edge XANES Up To 1180 C Y1 - 2007 ER - TY - JOUR A1 - Farges, Francois A1 - de Wispelaere, S. A1 - Rossano, Stephanie A1 - Munoz, Manuel A1 - Wilke, Max A1 - Flank, Anne-Marie A1 - Lagarde, Pierre T1 - Local structures around Si, Al, and Na in hydrated silicate glasses Y1 - 2008 ER - TY - JOUR A1 - Borchert, Manuela A1 - Wilke, Max A1 - Schmidt, Christian A1 - Rickers, Karen T1 - Partitioning and equilibration of Rb and Sr between silicate melts and aqueous fluids N2 - Trace element concentrations in aqueous fluids in equilibrium with haplogranitic melt were determined in situ at elevated P-T conditions using hydrothermal diamond-anvil cells and synchrotron-radiation XRF microanalyses. Time- resolved analyses showed that the Rb and Sr concentrations in the fluids became constant in less than 2000 s at all temperatures (500 to 780 degrees C). Although fluid-melt equilibration was very rapid, the change in the concentration of both elements in the fluid with temperature was fairly small (a slight increase for Rb and a slight decrease for Sr). This permitted partitioning data for Rb and Sr between haplogranitic melt and H2O or NaCl+KCl+HCl aqueous solutions at 750 degrees C and 200 to 700 MPa to be obtained from EMP analyses of the quenched melt and the in situ SR-XRF analyses of the equilibrated fluid. The resulting D-Rb(f/m) and D-Sr(f/m) were 0.01 +/- 0.002 and 0.006 +/- 0.001 for water as starting fluid, and increased to 0.47 +/- 0.08 and 0.23 +/- 0.03 for 3.56 m (NaCl+KCl)+0.04 in HCl at pressures of 224 to 360 MPa. In the experiments with H2O as starting fluid, the partition coefficients increased with pressure, i.e. D- Rb(f/m) from 0.01 +/- 0.002 to 0.22 +/- 0.02 and D-Sr(f/m) from 0.006 0.001 to 0.02 +/- 0.005 with a change in pressure from 360 to 700 MPa. At pressures to 360 MPa, the Rb/Sr ratio in the fluid was found to be independent of the initial salt concentration (Rb/Sr = 1.45 +/- 0.6). This ratio increased to 7.89 +/- 1.95 at 700 MPa in experiments with chloride free fluids, which indicates different changes in the Rb and Sr speciation with pressure. Y1 - 2009 UR - http://www.sciencedirect.com/science/journal/00092541 U6 - https://doi.org/10.1016/j.chemgeo.2008.10.019 SN - 0009-2541 ER - TY - JOUR A1 - Schmitz, Sylvia A1 - Moeller, Andreas A1 - Wilke, Max A1 - Malzer, Wolfgang A1 - Kanngiesser, Birgit A1 - Bousquet, Romain A1 - Berger, Alfons A1 - Schefer, Senecio T1 - Chemical U-Th-Pb dating of monazite by 3D-Micro X-ray fluorescence analysis with synchrotron radiation N2 - A confocal set-up for three-dimensional (3D) micro X-ray fluorescence (micro-XRF) was used at the mySpot beamline at BESSY II, which allows compositional depth profiling for various applications. We present results obtained with a confocal 3D micro-XRF set-up for chemical age dating using the U, Th and Pb concentrations of monazite within rock thin sections. The probing volume was determined to be approximately 21 x 21 x 24 mu m(3) for W-L alpha using an excitation energy of 19 keV. The relative detection limits particularly for Pb are below 10 ppm (for Counting times Y1 - 2009 UR - http://eurjmin.geoscienceworld.org/ U6 - https://doi.org/10.1127/0935-1221/2009/0021-1964 SN - 0935-1221 ER - TY - JOUR A1 - Wilke, Max A1 - Appel, Karen A1 - Vincze, Laszlo A1 - Schmidt, Christian A1 - Borchert, Manuela A1 - Pascarelli, Sakura T1 - A confocal set-up for micro-XRF and XAFS experiments using diamond-anvil cells N2 - A confocal set-up is presented that improves micro-XRF and XAFS experiment with high-pressure e diamond-anvil cells (DACs) In this experiment a probing volume is defined by the focus of the incoming synchrotron radiation beam and that of a polycapillary X-ray half-lens with a very long working distance, which is placed in front of the fluorescence detector This set-up enhances the quality of the fluorescence and XAFS spectra, and thus the sensitivity for detecting elements at low concentrations. It efficiently suppresses signal from outside the sample chamber, which stems from elastic and inelastic scattering of the incoming beam by the diamond anvils as well as from excitation of fluorescence from the body of the DAC Y1 - 2010 UR - http://journals.iucr.org/s/journalhomepage.html U6 - https://doi.org/10.1107/S0909049510023654 SN - 0909-0495 ER - TY - JOUR A1 - Borchert, Manuela A1 - Wilke, Max A1 - Schmidt, Christian A1 - Cauzid, Jean A1 - Tucoulou, Rémi T1 - Partitioning of Ba, La, Yb and Y between haplogranitic melts and aqueous solutions : an experimental study N2 - Barium, lanthanum, ytterbium, and yttrium partitioning experiments between fluid-saturated haplogranitic melts and aqueous solutions were conducted at 750 to 950 degrees C and 0.2 to 1 GPa to investigate the effects of melt and fluid composition, pressure, and temperature. Partition coefficients were determined using different experimental methods. On one hand quenched experiments were performed, and on the other hand, trace element contents in the aqueous fluid were determined directly using a hydrothermal diamond-anvil cell and synchrotron radiation X-ray fluorescence microanalysis of K-lines. The latter required a high excitation energy of 50 key due to the high energies necessary to excite the K-lines of the studied elements. The data from these two techniques showed good agreement for chloridic solutions, whereas quenching had a significant effect on results of the experiments with only water in the case of Ba. In Cl-free experiments, lanthanum and yttrium, trace element contents were even below detection limit in the quenched fluids, whereas small concentrations were detected in comparable in-situ experiments. This distinct difference is likely due to back reactions between fluid and melt upon cooling. The partitioning data of all elements show no dependence on the temperature and only small dependence on pressure. In contrast, the partitioning is strongly influenced by the composition of the starting fluid and melt. For chloridic fluids, there was a sharp increase in the Ba, La, Y and Yb partition coefficients with the alumina saturation index (ASI). The Ba partition coefficient increased from 0.002 at an ASI of 0.8 to 0.55 at an ASI of 1.07. At higher ASI, it decreased slightly to 0.2 at an ASI of similar to 1.3. Likewise, it was one to two orders of magnitude higher in chloridic fluids compared to those found in H2O experiments. Fluid-melt partition coefficients of La and Y increased from 0.002 at an ASI of similar to 0.8 to similar to 0.1 at an ASI of 1.2. In the same ASI range, the Yb partition coefficient increased to a maximum value of 0.02. Even at high salinities all elements fractionate into the melt. The compositional dependence of the partitioning data imply that both melt composition and fluid composition have a strong influence on trace element behavior and that complexation of Ba. REE and Y tin the fluid is not only controlled by the presence of Cl- in the fluid. Instead, interaction of these elements with major melt components dissolved in the fluid is very likely. Y1 - 2010 UR - http://www.sciencedirect.com/science/journal/00092541 U6 - https://doi.org/10.1016/j.chemgeo.2010.06.009 SN - 0009-2541 ER - TY - JOUR A1 - Borchert, Manuela A1 - Wilke, Max A1 - Schmidt, Christian A1 - Rickers, Karen T1 - Rb and Sr partitioning between haplogranitic melts and aqueous solutions N2 - Rubidium and strontium partitioning experiments between haplogranitic melts and aqueous fluids (water or 1.16- 3.56 m (NaCl + KCl) +/- HCl) were conducted at 750-950 degrees C and 0.2-1.4 GPa to investigate the effects of melt and fluid composition, pressure, and temperature. In addition, we studied if the applied technique (rapid and slow quench, and in-situ determination of trace element concentration in the fluid) has a bearing on the obtained data. There is good agreement of the data from different techniques for chloridic solutions, whereas back reactions between fluid and Melt upon cooling have a significant effect on results from the experiments with water. The Rb fluid-melt partition coefficient shows no recognizable dependence on melt composition and temperature. For chloridic Solutions, it is similar to 0.4, independent of pressure. In experiments with water, it is one to two orders of magnitude lower and increases with pressure. The strontium fluid-melt partition coefficient does not depend on temperature. It increases slightly with pressure in Cl free experiments. In chloridic fluids, there is a sharp increase in the Sr partition coefficient with the alumina saturation index (ASI) from 0.003 at an ASI of 0.8 to a maximum of 0.3 at an ASI of 1.05. At higher ASI, it decreases slightly to 0.2 at an ASI of 1.6. It is one to two orders of magnitude higher in chloridic fluids compared to those found in H2O experiments. The Rb/Sr ratio in non-chloridic solutions in equilibrium with metaluminous melts increases with pressure, whereas the Rb/Sr ratio in chloridic fluids is independent of pressure and decreases with fluid salinity. The obtained fluid-melt partition coefficients are in good agreement with data from natural cogenetic fluid and melt inclusions. Numerical modeling shows that although the Rb/Sr ratio in the residual melt is particularly sensitive to the degree of fractional crystallization, exsolution of a fluid phase, and associated fluid-melt partitioning is not a significant factor controlling Rb and Sr concentrations in the residual melt during crystallization of most granitoids. Y1 - 2010 UR - http://www.sciencedirect.com/science/journal/00167037 U6 - https://doi.org/10.1016/j.gca.2009.10.033 SN - 0016-7037 ER - TY - JOUR A1 - Qiu, C. A1 - Krüger, Y. A1 - Wilke, Max A1 - Marti, D. A1 - Ricka, J. A1 - Frenz, M. T1 - Exploration of the phase diagram of liquid water in the low-temperature metastable region using synthetic fluid inclusions JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - We present new experimental data of the low-temperature metastable region of liquid water derived from high-density synthetic fluid inclusions (996-916 kg m(-3)) in quartz. Microthermometric measurements include: (i) prograde (upon heating) and retrograde (upon cooling) liquid-vapour homogenisation. We used single ultrashort laser pulses to stimulate vapour bubble nucleation in initially monophase liquid inclusions. Water densities were calculated based on prograde homogenisation temperatures using the IAPWS-95 formulation. We found retrograde liquid-vapour homogenisation temperatures in excellent agreement with IAPWS-95. (ii) Retrograde ice nucleation. Raman spectroscopy was used to determine the nucleation of ice in the absence of the vapour bubble. Our ice nucleation data in the doubly metastable region are inconsistent with the low-temperature trend of the spinodal predicted by IAPWS-95, as liquid water with a density of 921 kg m(-3) remains in a homogeneous state during cooling down to a temperature of -30.5 degrees C, where it is transformed into ice whose density corresponds to zero pressure. (iii) Ice melting. Ice melting temperatures of up to 6.8 degrees C were measured in the absence of the vapour bubble, i.e. in the negative pressure region. (iv) Spontaneous retrograde and, for the first time, prograde vapour bubble nucleation. Prograde bubble nucleation occurred upon heating at temperatures above ice melting. The occurrence of prograde and retrograde vapour bubble nucleation in the same inclusions indicates a maximum of the bubble nucleation curve in the R-T plane at around 40 degrees C. The new experimental data represent valuable benchmarks to evaluate and further improve theoretical models describing the p-V-T properties of metastable water in the low-temperature region. Y1 - 2016 U6 - https://doi.org/10.1039/c6cp04250c SN - 1463-9076 SN - 1463-9084 VL - 18 SP - 28227 EP - 28241 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Sternemann, C. A1 - Wilke, Max T1 - Spectroscopy of low and intermediate Z elements at extreme conditions: in situ studies of Earth materials at pressure and temperature via X-ray Raman scattering JF - High pressure research N2 - X-ray Raman scattering spectroscopy is an emerging method in the study of low and intermediate Z elements' core-electron excitations at extreme conditions in order to reveal information on local structure and electronic state of matter in situ. We discuss the capabilities of this method to address questions in Earth materials' science and demonstrate its sensitivity to detect changes in the oxidation state, electronic structure, coordination, and spin state. Examples are presented for the study of the oxygen K-, silicon L- and iron M-edges. We assess the application of both temperature and pressure in such investigations exploiting diamond anvil cells in combination with resistive or laser heating which is required to achieve realistic conditions of the Earth's crust, mantle, and core. KW - X-ray Raman scattering KW - inelastic X-ray scattering KW - X-ray absorption KW - high pressure research KW - diamond anvil cell KW - minerals KW - glasses KW - melts KW - Earth materials KW - spin transition KW - bonding transition KW - coordination transformation KW - oxidation state KW - electronic structure Y1 - 2016 U6 - https://doi.org/10.1080/08957959.2016.1198903 SN - 0895-7959 SN - 1477-2299 VL - 36 SP - 275 EP - 292 PB - IOP Publ. Ltd. CY - Abingdon ER - TY - JOUR A1 - Rosa, A. D. A1 - Pohlenz, Julia A1 - de Grouchy, C. A1 - Cochain, B. A1 - Kono, Y. A1 - Pasternak, S. A1 - Mathon, O. A1 - Irifune, T. A1 - Wilke, Max T1 - In situ characterization of liquid network structures at high pressure and temperature using X-ray absorption spectroscopy coupled with the Paris-Edinburgh press JF - High pressure research N2 - We review recent progress in studying structural properties of liquids using X-ray absorption spectroscopy coupled with the Paris-Edinburgh press at third-generation synchrotron facilities. This experimental method allows for detecting subtle changes in atomic arrangements of melts over a wide pressure-temperature range. It has been also employed to monitor variations of the local coordination environment of diluted species contained in glasses, liquids and crystalline phases as a function of the pressure and temperature. Such information is of great importance for gaining deeper insights into the physico-chemical properties of liquids at extreme condition, including the understanding of such phenomena as liquid-liquid phase transitions, viscosity drops and various transport properties of geological melts. Here, we describe the experimental approach and discuss its potential in structural characterization on selected scientific highlights. Finally, the current ongoing instrumental developments and future scientific opportunities are discussed. KW - X-ray absorption KW - Paris-Edinburgh press KW - liquid structure KW - high pressure and temperature KW - EXAFS Y1 - 2016 U6 - https://doi.org/10.1080/08957959.2016.1199693 SN - 0895-7959 SN - 1477-2299 VL - 36 SP - 332 EP - 347 PB - American Geophysical Union CY - Abingdon ER - TY - JOUR A1 - Schaffer, Mario A1 - Idzik, Krzysztof R. A1 - Wilke, Max A1 - Licha, Tobias T1 - Amides as thermo-sensitive tracers for investigating the thermal state of geothermal reservoirs JF - Geothermics : an international journal of geothermal research and its applications N2 - The application of thermo-sensitive tracers is a promising technique for evaluating the thermal state of geothermal reservoirs. To extend the compound spectrum for hydrolyzable compounds to reservoir temperatures between 100 and 200 degrees C carboxamides were studied. The kinetic parameters of 17 self-synthesized amides were determined in hydrothermal batch and autoclave experiments. The influence of the molecular structure and the role of pH/pOH on hydrolysis kinetics were studied. Additionally, the thermal stabilities of the hydrolysis products were evaluated. The results demonstrate the high potential of tracers based on amide hydrolysis for use in medium enthalpy reservoirs. (C) 2016 Elsevier Ltd. All rights reserved. KW - Thermo-sensitive tracers KW - Amides KW - Hydrolysis KW - Kinetics KW - Reservoir temperature KW - Molecular design Y1 - 2016 U6 - https://doi.org/10.1016/j.geothermics.2016.05.004 SN - 0375-6505 SN - 1879-3576 VL - 64 SP - 180 EP - 186 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Spiekermann, Georg A1 - Wilke, Max A1 - Jahn, Sandro T1 - Structural and dynamical properties of supercritical H2O-SiO2 fluids studied by ab initio molecular dynamics JF - Chemical geology : official journal of the European Association for Geochemistry N2 - In this study we report the structure of supercritical H2O-SiO2 fluid composed of 50 mol% H2O and 50 mol% SiO2 at 3000 K and 2400 K. investigated by means of ab initio molecular dynamics of models comprising 192 and 96 atoms. The density is set constant to 138 g/cm(3), which yields a pressure of 4.3 GPa at 3000 K and 3.6 GPa at 2400 K. Throughout the trajec[ories, water molecules are formed and dissociated via the network modifying reaction 2 SiOH = SiOSi + H2O The calculation of the reaction constant K- [OH](2)/[H2O][O2-] is carried out on the basis of the experimentally relevant Q ' species notation and agrees well with an extrapolation of experimental data to 3000 K. After quench from 3000 K to 2400 K, the degree of polymerization of the silicate network in the 192-atom models increases noticeably within several tens of picoseconds, accompanied by release of molecular H2O. An unexpected opposite trend is observed in smaller 96-atom models, due to a finite size effect, as several uncorrelated models of 192 and 96 atoms indicate. The temperature-dependent slowing down of the H2O-silica interaction dynamics is described on the basis of the bond autocorrelation function. (C) 2016 Elsevier B.V. All rights reserved. KW - Fluid KW - SiO2-H2O KW - SiO(2)Molecular dynamics KW - Polymerization KW - DFT Y1 - 2016 U6 - https://doi.org/10.1016/j.chemgeo.2016.01.010 SN - 0009-2541 SN - 1878-5999 VL - 426 SP - 85 EP - 94 PB - Elsevier CY - Amsterdam ER - TY - GEN A1 - Qiu, Chen A1 - Krüger, Yves A1 - Wilke, Max A1 - Marti, Dominik A1 - Rička, Jaro A1 - Frenz, Martin T1 - Exploration of the phase diagram of liquid water in the low-temperature metastable region using synthetic fluid inclusions N2 - We present new experimental data of the low-temperature metastable region of liquid water derived from high-density synthetic fluid inclusions (996–916 kg m−3) in quartz. Microthermometric measurements include: (i) prograde (upon heating) and retrograde (upon cooling) liquid–vapour homogenisation. We used single ultrashort laser pulses to stimulate vapour bubble nucleation in initially monophase liquid inclusions. Water densities were calculated based on prograde homogenisation temperatures using the IAPWS-95 formulation. We found retrograde liquid–vapour homogenisation temperatures in excellent agreement with IAPWS-95. (ii) Retrograde ice nucleation. Raman spectroscopy was used to determine the nucleation of ice in the absence of the vapour bubble. Our ice nucleation data in the doubly metastable region are inconsistent with the low-temperature trend of the spinodal predicted by IAPWS-95, as liquid water with a density of 921 kg m−3 remains in a homogeneous state during cooling down to a temperature of −30.5 °C, where it is transformed into ice whose density corresponds to zero pressure. (iii) Ice melting. Ice melting temperatures of up to 6.8 °C were measured in the absence of the vapour bubble, i.e. in the negative pressure region. (iv) Spontaneous retrograde and, for the first time, prograde vapour bubble nucleation. Prograde bubble nucleation occurred upon heating at temperatures above ice melting. The occurrence of prograde and retrograde vapour bubble nucleation in the same inclusions indicates a maximum of the bubble nucleation curve in the ϱ–T plane at around 40 °C. The new experimental data represent valuable benchmarks to evaluate and further improve theoretical models describing the p–V–T properties of metastable water in the low-temperature region. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 327 Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-394993 ER - TY - JOUR A1 - Grüneberger, Anja Maria A1 - Schmidt, Christian A1 - Jahn, Sandro A1 - Rhede, Dieter A1 - Loges, Anselm A1 - Wilke, Max T1 - Interpretation of Raman spectra of the zircon-hafnon solid solution JF - European journal of mineralogy N2 - Zircon (ZrSiO4), hafnon (HfSiO4) and five intermediate compositions were synthesized from a Pb silicate melt. The resulting crystals were 20-300 mu m in size and displayed sector and growth zoning. Raman spectra were acquired at locations in the sample for which preceding electron microprobe (EMP) analyses revealed sufficient compositional homogeneity. The dataset documents shifts of Raman bands with changing composition. In this study, bands that have previously not been reported were found for the intermediate compositions and for pure hafnon, in particular at wavenumbers less than 200 cm(-1). For these external modes, the dataset provides new insight into the compositional dependence of their frequencies. Density-functional theory calculations support the observations and are used for a detailed interpretation of the spectra. The pitfalls of the EMP analysis along the zircon-hafnon join are highlighted. KW - zircon KW - hafnon KW - solid solution KW - Raman spectroscopy KW - synthesis KW - density-functional theory KW - hafnium analysis Y1 - 2016 U6 - https://doi.org/10.1127/ejm/2016/0028-2551 SN - 0935-1221 SN - 1617-4011 VL - 28 SP - 721 EP - 733 PB - Schweizerbart CY - Stuttgart ER - TY - JOUR A1 - Sirbescu, Mona-Liza C. A1 - Schmidt, Christian A1 - Veksler, Ilya V. A1 - Whittington, Alan G. A1 - Wilke, Max T1 - Experimental crystallization of undercooled felsic liquids BT - generation of pegmatitic texture JF - Journal of petrology N2 - The crystallization kinetics of silicate liquids were studied experimentally in the system haplogranite-B-Li-H2O, at variable degrees of undercooling and variable water concentration. We investigated the kinetics of nucleation and crystallization of unseeded synthetic hydrous haplogranite with 1 wt % Li2O + 2 center dot 3 wt % B2O3 added (composition C1) and 2 wt % Li2O + 4 center dot 6 wt % B2O3 added (composition C2). Compositions C1 and C2 are simplified representative bulk compositions of Li-rich pegmatites and their highly differentiated cores, respectively. Starting water contents varied between 3 and 9 wt %. With few exceptions, the system remained water-undersaturated. About 86 isothermal runs of 1-60 days duration, grouped in 25 time series of constant temperature and initial H2O content, were carried out at temperatures from 400 to 700A degrees C at 300 MPa, corresponding to variable degrees of undercooling between the liquidus and glass transition. Viscosity measurements indicate that the glass transition for both compositions is below 400A degrees C for 3 wt % water and below 300A degrees C for 6 center dot 5 wt % water. The melts remained virtually crystal free at 400A degrees C, about 100A degrees C and 120A degrees C above the glass transition for compositions C1 and C2, respectively, in experiments up to 30 days long. This result is consistent with the existence of low-temperature, undercooled melts in the crust. At lower values of undercooling the runs crystallized partially, up to about 70% volume fraction. Undercooling and the amount of water are the main factors controlling nucleation and growth rates, and therefore textures. Minerals nucleate and grow sequentially according to mineral-specific nucleation delays. The mineral assemblage started with Li-Al stuffed quartz (in C1) and virgilite (in C2), solid-solutions between quartz and gamma-spodumene. The quartz-like phases were typically followed by spherulitic alkali feldspar-quartz intergrowths, euhedral petalite, and fine-grained muscovite. Nearly pure quartz formed as rims and replacement of metastable virgilite and stuffed quartz, in particular at the boron- and water-rich crystallization front of large feldspar or petalite. With the exception of muscovite, all minerals nucleated heterogeneously, on the capsule wall or on pre-existing minerals, and grew inwards, towards the capsule center. Experimental textures resembled the textures of zoned pegmatites, including skeletal, graphic, unidirectional, radiating, spherulitic, massive, and replacement textures. In some cases, when fluid saturation was reached, miarolitic cavities developed containing euhedral crystals. Although unidirectional growth rates appeared to slow down in time, volumetric rates for stable graphic alkali-feldspar quartz intergrowths and petalite remained constant for up to 60 days and similar to 70% crystallization. Metastable stuffed quartz and virgilite diminished in their growth rates in runs of 30 days or longer, were resorbed in the melt, and were partially replaced by second-generation quartz. Unobstructed, self-sustained crystal growth in conditions of very low nucleation density appears to be the dominant mechanism to form giant pegmatitic crystals, although experimental growth rates are much slower than predicted in nature based on conductive-cooling models. KW - experimental petrology KW - lithium pegmatites KW - igneous texture KW - viscosity KW - crystal nucleation KW - crystal growth rate Y1 - 2017 U6 - https://doi.org/10.1093/petrology/egx027 SN - 0022-3530 SN - 1460-2415 VL - 58 IS - 3 SP - 539 EP - 568 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Sahle, Christoph J. A1 - Niskanen, Johannes A1 - Schmidt, Christian A1 - Stefanski, Johannes A1 - Gilmore, Keith A1 - Forov, Yury A1 - Jahn, Sandro A1 - Wilke, Max A1 - Sternemann, Christian T1 - Cation Hydration in Supercritical NaOH and HCl Aqueous Solutions JF - The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces & biophysical chemistry N2 - We present a study of the local atomic environment of the oxygen atoms in the aqueous solutions of NaOH and HCl under simultaneous high-temperature and high-pressure conditions. Experimental nonresonant X-ray Raman scattering core-level spectra at the oxygen K-edge show systematic changes as a function of temperature and pressure. These systematic changes are distinct for the two different solutes and are described well by calculations within the Bethe- Salpeter formalism for snapshots from ab initio molecular dynamics simulations. The agreement between experimental and simulation results allows us to use the computations for a detailed fingerprinting analysis in an effort to elucidate the local atomic structure and hydrogen-bonding topology in these relevant solutions. We observe that both electrolytes, especially NaOH, enhance hydrogen bonding and tetrahedrality in the water structure at supercritical conditions, in particular in the vicinity of the hydration shells. This effect is accompanied with the association of the HCl and NaOH molecules at elevated temperatures. Y1 - 2017 U6 - https://doi.org/10.1021/acs.jpcb.7b09688 SN - 1520-6106 VL - 121 SP - 11383 EP - 11389 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Weis, Christopher A1 - Sternemann, Christian A1 - Cerantola, Valerio A1 - Sahle, Christoph J. A1 - Spiekermann, Georg A1 - Harder, Manuel A1 - Forov, Yury A1 - Kononov, Alexander A1 - Sakrowski, Robin A1 - Yavas, Hasan A1 - Tolan, Metin A1 - Wilke, Max T1 - Pressure driven spin transition in siderite and magnesiosiderite single crystals JF - Scientific reports Y1 - 2017 U6 - https://doi.org/10.1038/s41598-017-16733-3 SN - 2045-2322 VL - 7 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Holten, Vincent A1 - Qiu, Chen A1 - Guillerm, Emmanuel A1 - Wilke, Max A1 - Ricka, Jaroslav A1 - Frenz, Martin A1 - Caupin, Frederic T1 - Compressibility Anomalies in Stretched Water and Their Interplay with Density Anomalies JF - The journal of physical chemistry letters N2 - Water keeps puzzling scientists because of its numerous properties which behave oppositely to those of usual liquids: for instance, water expands upon cooling, and liquid water is denser than ice. To explain this anomalous behavior, several theories have been proposed, with different predictions for the properties of supercooled water (liquid at conditions where ice is stable). However, discriminating between those theories with experiments has remained elusive because of spontaneous ice nucleation. Here we measure the sound velocity in liquid water stretched to negative pressure and derive an experimental equation of state, which reveals compressibility anomalies. We show by rigorous thermodynamic relations how these anomalies are intricately linked with the density anomaly. Some features we observe are necessary conditions for the validity of two theories of water. Y1 - 2017 U6 - https://doi.org/10.1021/acs.jpclett.7b02563 SN - 1948-7185 VL - 8 SP - 5519 EP - 5522 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Benard, Antoine A1 - Klimm, Kevin A1 - Woodland, Alan B. A1 - Arculus, Richard J. A1 - Wilke, Max A1 - Botcharnikov, Roman E. A1 - Shimizu, Nobumichi A1 - Nebel, Oliver A1 - Rivard, Camille A1 - Ionov, Dmitri A. T1 - Oxidising agents in sub-arc mantle melts link slab devolatilisation and arc magmas JF - Nature Communications N2 - Subduction zone magmas are more oxidised on eruption than those at mid-ocean ridges. This is attributed either to oxidising components, derived from subducted lithosphere (slab) and added to the mantle wedge, or to oxidation processes occurring during magma ascent via differentiation. Here we provide direct evidence for contributions of oxidising slab agents to melts trapped in the sub-arc mantle. Measurements of sulfur (S) valence state in sub-arc mantle peridotites identify sulfate, both as crystalline anhydrite (CaSO4) and dissolved SO42- in spinel-hosted glass (formerly melt) inclusions. Copper-rich sulfide precipitates in the inclusions and increased Fe3+/Sigma Fe in spinel record a S6+-Fe2+ redox coupling during melt percolation through the sub-arc mantle. Sulfate-rich glass inclusions exhibit high U/Th, Pb/Ce, Sr/Nd and delta S-34 (+ 7 to + 11%), indicating the involvement of dehydration products of serpentinised slab rocks in their parental melt sources. These observations provide a link between liberated slab components and oxidised arc magmas. Y1 - 2018 U6 - https://doi.org/10.1038/s41467-018-05804-2 SN - 2041-1723 VL - 9 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Kutzschbach, Martin A1 - Guttmann, Peter A1 - Marquardt, K. A1 - Werner, S. A1 - Henzler, K. D. A1 - Wilke, Max T1 - A transmission x-ray microscopy and NEXAFS approach for studying corroded silicate glasses at the nanometre scale JF - European journal of glass science and technology / Deutsche Glastechnische Gesellschaft (DGG) and the Society of Glass Technology (SGT). B, Physics and chemistry of glasses N2 - In this study transmission X-ray microscopy (TXM) was tested as a method to investigate the chemistry and structure of corroded silicate glasses at the nanometer scale. Three different silicate glasses were altered in static corrosion experiments for 1-336 hours at temperatures between 60 degrees C and 85 degrees C using a 25% HCl solution. Thin lamellas were cut perpendicular to the surface of corroded glass monoliths and were analysed with conventional TEM as well as with TXM. By recording optical density profiles at photon energies around the Na and O K-edges, the shape of the corrosion rim/pristine glass interfaces and the thickness of the corrosion rims has been determined. Na and O near-edge X-ray absorption fine-structure spectra (NEXAFS) were obtained without inducing irradiation damage and have been used to detect chemical changes in the corrosion rims. Spatially resolved NEXAFS spectra at the O K-edge provided insight to structural changes in the corrosion layer on the atomic scale. By comparison to O K-edge spectra of silicate minerals and (hydrous) albite glass as well as to O K-edge NEXAFS of model structures simulated with ab initio calculations, evidence is provided that changes of the fine structure at the O K-edge are assigned to the formation of siloxane groups in the corrosion rim. Y1 - 2018 U6 - https://doi.org/10.13036/17533562.59.1.043 SN - 1753-3562 VL - 59 IS - 1 SP - 11 EP - 26 PB - Society of Glass Technology CY - Sheffield ER - TY - JOUR A1 - Dietrich, Marcel A1 - Behrens, Harald A1 - Wilke, Max T1 - A new optical cell for in situ Raman spectroscopy, and its application to study sulfur-bearing fluids at elevated pressures and temperatures JF - American mineralogist : an international journal of earth and planetary materials N2 - Sulfur is an important component in volcanic gases at the Earth surface but also present in the deep Earth in hydrothermal or magmatic fluids. Little is known about the evolution of such fluids during ascent in the crust. A new optical cell was developed for in situ Raman spectroscopic investigations on fluids allowing abrupt or continuous changes of pressure up to 200 MPa at temperatures up to 750 degrees C. The concept is based on a flexible gold bellow, which separates the sample fluid from the pressure medium water. To avoid reactions between aggressive fluids and the pressure cell, steel components in contact with the fluid are shielded by gold foil. The cell was tested to study redox reactions in fluids using aqueous ammonium sulfate solutions as a model system. During heating at constant pressure of 130 MPa, sulfate ions transform first to HSO4- ions and then to molecular units such as H2SO4. Variation of pressure shows that the stability of sulfate species relies on fluid density, i.e., highly charged species are stable only in high-density fluids. Partial decomposition of ammonium was evident above 550 degrees C by the occurrence of a nitrogen peak in the Raman spectra. Reduced sulfur species were observed above 700 degrees C by Raman signals near 2590 cm(-1) assigned to HS- and H2S. No clear evidence for the formation of sulfur dioxide was found in contrary to previous studies on aqueous H2SO4, suggesting very reducing conditions in our experiments. Fluid-mineral interaction was studied by inserting into the cell a small, semi-open capsule filled with a mixture of pyrite and pyrrhotite. Oxidation of the sample assembly was evident by transformation of pyrite to pyrrhotite. As a consequence, sulfide species were observed in the fluid already at temperatures of similar to 600 degrees C. KW - In situ Raman spectroscopy KW - fluids KW - decompression KW - optical cell KW - sulfur speciation KW - redox reactions Y1 - 2018 U6 - https://doi.org/10.2138/am-2018-6244 SN - 0003-004X SN - 1945-3027 VL - 103 IS - 3 SP - 418 EP - 429 PB - Mineralogical Society of America CY - Chantilly ER - TY - JOUR A1 - Wilke, Max T1 - X-Ray Absorption Spectroscopy Measurements JF - Magmas Under Pressure : Advances in High-Pressure Experiments on Structure and Properties of Melts N2 - An overview is given on the current state of X-ray absorption measurements on silicate melts and glasses. The challenges, limitations, and achievements of analyzing X-ray absorption spectra measured in liquids to determine structural properties of major and minor elements in magmas are described, with particular focus on describing non-Gaussian pair distribution functions in highly disordered glasses and melts, measured at in situ conditions. This includes a discussion on the progress of combining experiments with data from molecular dynamics simulations. For the measurements at conditions of the deep Earth, various experimental approaches and necessities are discussed and two examples are described in more detail. Finally, the achievements and prospects are presented for measuring X-ray absorption spectra indirectly by X-ray Raman scattering. Y1 - 2018 SN - 978-0-12-811274-8 SN - 978-0-12-811301-1 U6 - https://doi.org/10.1016/B978-0-12-811301-1.00006-X SP - 155 EP - 178 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Pohlenz, Julia A1 - Rosa, A. D. A1 - Mathon, O. A1 - Pascarelli, S. A1 - Belin, S. A1 - Landrot, G. A1 - Murzin, V. A1 - Veligzhanin, A. A1 - Shiryaev, A. A1 - Irifune, T. A1 - Wilke, Max T1 - Structural controls of CO2 on Y, La and Sr incorporation in sodium-rich silicate - carbonate melts by in-situ high P-T EXAFS JF - Chemical geology : official journal of the European Association for Geochemistry N2 - Carbonate-rich silicate and carbonate melts play a crucial role in deep Earth magmatic processes and their melt structure is a key parameter, as it controls physical and transport properties. Carbon-rich melts can be strongly enriched in trace elements, but the structural incorporation mechanisms of these elements are difficult to study because such melts generally cannot be quenched to glasses. In this contribution we investigate the influence of CO2 on the local environments of trace elements contained in silicate glasses with variable CO2 concentrations and in silicate and carbonate melts. The melts were studied in-situ at high pressure and temperature conditions using the Paris-Edinburgh press (2.2 to 2.6 GPa and 1200 to 1500 degrees C). The compositions studied include sodium-rich peralkaline silicate melts and glasses and carbonate melts similar to those occurring naturally at Oldoinyo Lengai volcano. The local environments of yttrium (Y), lanthanum (La) and strontium (Sr) were investigated using extended X-ray absorption fine structure (EXAFS) spectroscopy. Main findings of the study suggest: (1) In peralkaline silicate glasses the local structure of Y is unaffected by the CO2 content. Contrary, a slight increase of oxygen bond lengths of Sr and La is inferred with increasing CO2 content in peralkaline glasses, while they remain constant in glasses of even higher peralkalinity independent of the CO2 content. (2) In silicate melts of different CO2 contents Y-O bond lengths are constant, while a slight increase within carbonate melt compositions is deduced. On the other hand, a steady bond lengths increase over the whole compositional range is inferred for La-O and Sr-O. This may well be explained by distinct preferences of these elements for specific local environments. Based on these new data, we suggest potential mechanisms for the structural incorporation of these elements, a key step towards understanding their partitioning behavior in natural magmatic systems. KW - Silicate- carbonate melts/glasses KW - Local structure Yttrium, Strontium, Lanthanum KW - EXAFS KW - Paris-Edinburgh press Y1 - 2018 U6 - https://doi.org/10.1016/j.chemgeo.2017.12.023 SN - 0009-2541 SN - 1872-6836 VL - 486 SP - 1 EP - 15 PB - Elsevier CY - Amsterdam ER - TY - GEN A1 - Caupin, Frederic A1 - Holten, Vincent A1 - Qiu, Chen A1 - Guillerm, Emmanuel A1 - Wilke, Max A1 - Frenz, Martin A1 - Teixeira, Jose A1 - Soper, Alan K. T1 - Comment on "Maxima in the thermodynamic response and correlation functions of deeply supercooled water" T2 - Science N2 - Kim et al. recently measured the structure factor of deeply supercooled water droplets (Reports, 22 December 2017, p. 1589). We raise several concerns about their data analysis and interpretation. In our opinion, the reported data do not lead to clear conclusions about the origins of water’s anomalies. Y1 - 2018 U6 - https://doi.org/10.1126/science.aat1634 SN - 0036-8075 SN - 1095-9203 VL - 360 IS - 6390 PB - American Assoc. for the Advancement of Science CY - Washington ER - TY - JOUR A1 - Nunez Valdez, Maribel A1 - Efthimiopoulos, Ilias A1 - Taran, Michail A1 - Mueller, Jan A1 - Bykova, Elena A1 - McCammon, Catherine A1 - Koch-Müller, Monika A1 - Wilke, Max T1 - Evidence for a pressure-induced spin transition in olivine-type LiFePO4 triphylite JF - Physical review : B, Condensed matter and materials physics N2 - We present a combination of first-principles and experimental results regarding the structural and magnetic properties of olivine-type LiFePO4 under pressure. Our investigations indicate that the starting Pbnm phase of LiFePO4 persists up to 70 GPa. Further compression leads to an isostructural transition in the pressure range of 70-75 GPa, inconsistent with a former theoretical study. Considering our first-principles prediction for a high-spin to low-spin transition of Fe2+ close to 72 GPa, we attribute the experimentally observed isostructural transition to a change in the spin state of Fe2+ in LiFePO4. Compared to relevant Fe-bearing minerals, LiFePO4 exhibits the largest onset pressure for a pressure-induced spin state transition. Y1 - 2018 U6 - https://doi.org/10.1103/PhysRevB.97.184405 SN - 2469-9950 SN - 2469-9969 VL - 97 IS - 18 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Weis, Christopher A1 - Spiekermann, Georg A1 - Sternemann, Christian A1 - Harder, Manuel A1 - Vanko, Gyorgy A1 - Cerantola, Valerio A1 - Sahle, Christoph J. A1 - Forov, Yury A1 - Sakrowski, Robin A1 - Kupenko, Ilya A1 - Petitgirard, Sylvain A1 - Yavas, Hasan A1 - Bressler, Christian A1 - Gawelda, Wojciech A1 - Tolan, Metin A1 - Wilke, Max T1 - Combining X-ray K beta(1,3), valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature BT - the case of siderite JF - Journal of analytical atomic spectrometry N2 - X-ray emission and X-ray Raman scattering spectroscopy are powerful tools to investigate the local electronic and atomic structure of high and low Z elements in situ. Notably, these methods can be applied for in situ spectroscopy at high pressure and high temperature using resistively or laser-heated diamond anvil cells in order to achieve thermodynamic conditions which appear in the Earth's interior. We present a setup for combined X-ray emission and X-ray Raman scattering studies at beamline P01 of PETRA III using a portable wavelength-dispersive von Hamos spectrometer together with the permanently installed multiple-analyzer Johann-type spectrometer. The capabilities of this setup are exemplified by investigating the iron spin crossover of siderite FeCO3 up to 49.3 GPa by measuring the Fe M2,3-edge and the Fe Kβ1,3 emission line simultaneously. With this setup, the Fe valence-to-core emission can be detected together with the Kβ1,3 emission line providing complementary information on the sample's electronic structure. By implementing a laser-heating device, we demonstrate the strength of using a von Hamos type spectrometer for spin state mapping at extreme conditions. Finally, we give different examples of low Z elements' absorption edges relevant for application in geoscience that are accessible with the Johann-type XRS spectrometer. With this setup new insights into the spin transition and compression mechanisms of Earth's mantle materials can be obtained of importance for comprehension of the macroscopic physical and chemical properties of the Earth's interior. Y1 - 2018 U6 - https://doi.org/10.1039/c8ja00247a SN - 0267-9477 SN - 1364-5544 VL - 34 IS - 2 SP - 384 EP - 393 PB - Royal Society of Chemistry CY - Cambridge ER - TY - GEN A1 - Bénard, Antoine A1 - Klimm, Kevin A1 - Woodland, Alan B. A1 - Arculus, Richard J. A1 - Wilke, Max A1 - Botcharnikov, Roman E. A1 - Shimizu, Nobumichi A1 - Nebel, Oliver A1 - Rivard, Camille A1 - Ionov, Dmitri A. T1 - Oxidising agents in sub-arc mantle melts link slab devolatilisation and arc magmas T2 - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe N2 - Subduction zone magmas are more oxidised on eruption than those at mid-ocean ridges. This is attributed either to oxidising components, derived from subducted lithosphere (slab) and added to the mantle wedge, or to oxidation processes occurring during magma ascent via differentiation. Here we provide direct evidence for contributions of oxidising slab agents to melts trapped in the sub-arc mantle. Measurements of sulfur (S) valence state in sub-arc mantle peridotites identify sulfate, both as crystalline anhydrite (CaSO4) and dissolved SO42− in spinel-hosted glass (formerly melt) inclusions. Copper-rich sulfide precipitates in the inclusions and increased Fe3+/∑Fe in spinel record a S6+–Fe2+ redox coupling during melt percolation through the sub-arc mantle. Sulfate-rich glass inclusions exhibit high U/Th, Pb/Ce, Sr/Nd and δ34S (+ 7 to + 11‰), indicating the involvement of dehydration products of serpentinised slab rocks in their parental melt sources. These observations provide a link between liberated slab components and oxidised arc magmas. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 717 KW - Andesitic Avacha volcano KW - oxidation-state KW - oxygen fugacity KW - subduction zones KW - peridotite xenoliths KW - sulfur speciation KW - redox state KW - island-arc KW - dissolution mechanism KW - basaltic systems Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-426184 SN - 1866-8372 IS - 717 ER - TY - JOUR A1 - Cerantola, Valerio A1 - Wilke, Max A1 - Kantor, Innokenty A1 - Ismailova, Leyla A1 - Kupenko, Ilya A1 - McCammon, Catherine A1 - Pascarelli, Sakura A1 - Dubrovinsky, Leonid S. T1 - Experimental investigation of FeCO3 (siderite) stability in Earth's lower mantle using XANES spectroscopy JF - American mineralogist : an international journal of earth and planetary materials N2 - We studied FeCO3 using Fe K-edge X-ray absorption near-edge structure (XANES) spectroscopy at pressures up to 54 GPa and temperatures above 2000 K. First-principles calculations of Fe at the K-edge in FeCO3 were performed to support the interpretation of the XANES spectra. The variation of iron absorption edge features with pressure and temperature in FeCO3 matches well with recently reported observations on FeCO3 at extreme conditions, and provides new insight into the stability of Fe-carbonates in Earth's mantle. Here we show that at conditions of the mid-lower mantle, ~50 GPa and ~2200 K, FeCO3 melts and partially decomposes to high-pressure Fe3O4. Carbon (diamond) and oxygen are also inferred products of the reaction. We constrained the thermodynamic phase boundary between crystalline FeCO3 and melt to be at 51(1) GPa and ~1850 K. We observe that at 54(1) GPa, temperature-induced spin crossover of Fe2+ takes place from low to high spin such that at 1735(100) K, all iron in FeCO3 is in the high-spin state. A comparison between experiment and theory provides a more detailed understanding of FeCO3 decomposition observed in X-ray absorption spectra and helps to explain spectral changes due to pressure-induced spin crossover in FeCO3 at ambient temperature. KW - Deep carbon cycle KW - siderite KW - decomposition KW - melting KW - spin transition KW - Earth in Five Reactions: A Deep Carbon Perspective Y1 - 2019 U6 - https://doi.org/10.2138/am-2019-6428 SN - 0003-004X SN - 1945-3027 VL - 104 IS - 8 SP - 1083 EP - 1091 PB - Mineralogical Society of America CY - Chantilly ER - TY - JOUR A1 - Taran, Michail N. A1 - Nunez Valdez, Maribel A1 - Efthimiopoulos, Ilias A1 - Müller, J. A1 - Reichmann, Hans-Josef A1 - Wilke, Max A1 - Koch-Müller, Monika T1 - Spectroscopic and ab initio studies of the pressure-induced Fe2+ high-spin-to-low-spin electronic transition in natural triphylite-lithiophilite JF - Physics and Chemistry of Minerals N2 - Using optical absorption and Raman spectroscopic measurements, in conjunction with the first-principles calculations, a pressure-induced high-spin (HS)-to-low-spin (LS) state electronic transition of Fe2+ (M2-octahedral site) was resolved around 76-80GPa in a natural triphylite-lithiophilite sample with chemical composition (LiFe0.7082+Mn0.292PO4)-Li-M1-Fe-M2 (theoretical composition (LiFe0.52+Mn0.5PO4)-Li-M1-Fe-M2). The optical absorption spectra at ambient conditions consist of a broad doublet band with two constituents (1) (similar to 9330cm(-1)) and (2) (similar to 7110cm(-1)), resulting from the electronic spin-allowed transition (T2gEg)-T-5-E-5 of octahedral (HSFe2+)-Fe-M2. Both (1) and (2) bands shift non-linearly with pressure to higher energies up to similar to 55GPa. In the optical absorption spectrum measured at similar to 81GPa, the aforementioned HS-related bands disappear, whereas a new broadband with an intensity maximum close to 16,360cm(-1) appears, superimposed on the tail of the high-energy ligand-to-metal O2-Fe2+ charge-transfer absorption edge. We assign this new band to the electronic spin-allowed dd-transition (1)A(1g)(1)T(1g) of LS Fe2+ in octahedral coordination. The high-pressure Raman spectra evidence the Fe2+ HS-to-LS transition mainly from the abrupt shift of the P-O symmetric stretching modes to lower frequencies at similar to 76GPa, the highest pressure achieved in the Raman spectroscopic experiments. Calculations indicated that the presence of Mn-M2(2+) simply shifts the isostructural HS-to-LS transition to higher pressures compared to the triphylite Fe-M2(2+) end-member, in qualitative agreement with our experimental observations. KW - Phosphates KW - Triphylite KW - Raman KW - Infrared KW - Optical absorption spectroscopy KW - High pressure KW - Spin transition KW - DFT Y1 - 2019 U6 - https://doi.org/10.1007/s00269-018-1001-y SN - 0342-1791 SN - 1432-2021 VL - 46 IS - 3 SP - 245 EP - 258 PB - Springer CY - New York ER - TY - JOUR A1 - Petitgirard, Sylvian A1 - Sahle, C. J. A1 - Weis, C. A1 - Gilmore, K. A1 - Spiekermann, Georg A1 - Tse, J. S. A1 - Wilke, Max A1 - Cavallari, C. A1 - Cerantola, V A1 - Sternemann, Christian T1 - Magma properties at deep Earth’s conditions from electronic structure of silica JF - Geochemical perspectives letters N2 - SiO(2 )is the main component of silicate melts and thus controls their network structure and physical properties. The compressibility and viscosities of melts at depth are governed by their short range atomic and electronic structure. We measured the O K-edge and the Si L-2,L-3-edge in silica up to 110 GPa using X-ray Raman scattering spectroscopy, and found a striking match to calculated spectra based on structures from molecular dynamic simulations. Between 20 and 27 GPa, Si-[4] species are converted into a mixture of Si-[5] and Si-[6] species and between 60 and 70 GPa, Si-[6] becomes dominant at the expense of Si-[5] with no further increase up to at least 110 GPa. Coordination higher than 6 is only reached beyond 140 GPa, corroborating results from Brillouin scattering. Network modifying elements in silicate melts may shift this change in coordination to lower pressures and thus magmas could be denser than residual solids at the depth of the core-mantle boundary. Y1 - 2019 U6 - https://doi.org/10.7185/geochemlet.1902 SN - 2410-339X SN - 2410-3403 VL - 9 SP - 32 EP - 37 PB - Association of Geochemistry CY - Paris ER - TY - GEN A1 - Spiekermann, Georg A1 - Harder, M. A1 - Gilmore, Keith A1 - Zalden, Peter A1 - Sahle, Christoph J. A1 - Petitgirard, Sylvain A1 - Wilke, Max A1 - Biedermann, Nicole A1 - Weis, Thomas A1 - Morgenroth, Wolfgang A1 - Tse, John S. A1 - Kulik, E. A1 - Nishiyama, Norimasa A1 - Yavaş, Hasan A1 - Sternemann, Christian T1 - Persistent Octahedral Coordination in Amorphous GeO₂ Up to 100 GPa by Kβ'' X-Ray Emission Spectroscopy T2 - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe N2 - We measure valence-to-core x-ray emission spectra of compressed crystalline GeO₂ up to 56 GPa and of amorphous GeO₂ up to 100 GPa. In a novel approach, we extract the Ge coordination number and mean Ge-O distances from the emission energy and the intensity of the Kβ'' emission line. The spectra of high-pressure polymorphs are calculated using the Bethe-Salpeter equation. Trends observed in the experimental and calculated spectra are found to match only when utilizing an octahedral model. The results reveal persistent octahedral Ge coordination with increasing distortion, similar to the compaction mechanism in the sequence of octahedrally coordinated crystalline GeO₂ high-pressure polymorphs. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 699 KW - rutile-type KW - glass KW - crystalline KW - pressures KW - complexes KW - silicon KW - oxygen KW - SIO₂ KW - MO KW - CU Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-427755 SN - 1866-8372 IS - 699 ER - TY - JOUR A1 - Spiekermann, Georg A1 - Harder, M. A1 - Gilmore, Keith A1 - Zalden, Peter A1 - Sahle, Christoph J. A1 - Petitgirard, Sylvain A1 - Wilke, Max A1 - Biedermann, Nicole A1 - Weis, Thomas A1 - Morgenroth, Wolfgang A1 - Tse, John S. A1 - Kulik, E. A1 - Nishiyama, Norimasa A1 - Yavaş, Hasan A1 - Sternemann, Christian T1 - Persistent Octahedral Coordination in Amorphous GeO₂ Up to 100 GPa by Kβ'' X-Ray Emission Spectroscopy JF - Physical Review X N2 - We measure valence-to-core x-ray emission spectra of compressed crystalline GeO₂ up to 56 GPa and of amorphous GeO₂ up to 100 GPa. In a novel approach, we extract the Ge coordination number and mean Ge-O distances from the emission energy and the intensity of the Kβ'' emission line. The spectra of high-pressure polymorphs are calculated using the Bethe-Salpeter equation. Trends observed in the experimental and calculated spectra are found to match only when utilizing an octahedral model. The results reveal persistent octahedral Ge coordination with increasing distortion, similar to the compaction mechanism in the sequence of octahedrally coordinated crystalline GeO₂ high-pressure polymorphs. KW - rutile-type KW - glass KW - crystalline KW - pressures KW - complexes KW - silicon KW - oxygen KW - SIO₂ KW - MO KW - CU Y1 - 2019 U6 - https://doi.org/10.1103/PhysRevX.9.011025 SN - 2469-9926 SN - 0556-2791 SN - 1050-2947 SN - 1094-1622 VL - 9 IS - 1 PB - American Physical Society by the American Institute of Physics CY - Melville, NY ER - TY - JOUR A1 - Schultze, Dina A1 - Wirth, Richard A1 - Wunder, Bernd A1 - Loges, Anselm A1 - Wilke, Max A1 - Franz, Gerhard T1 - Corundum-quartz metastability BT - the influence of a nanometer-sized phase on mineral equilibria in the system Al2O3-SiO2-H2O JF - Contributions to mineralogy and petrology N2 - The metastable paragenesis of corundum and quartz is rare in nature but common in laboratory experiments where according to thermodynamic predictions aluminum-silicate polymorphs should form. We demonstrate here that the existence of a hydrous, silicon-bearing, nanometer-thick layer (called "HSNL") on the corundum surface can explain this metastability in experimental studies without invoking unspecific kinetic inhibition. We investigated experimentally formed corundum reaction products synthesized during hydrothermal and piston-cylinder experiments at 500-800 degrees C and 0.25-1.8 GPa and found that this HSNL formed inside and on the corundum crystals, thereby controlling the growth behavior of its host. The HSNL represents a substitution of Al with Si and H along the basal plane of corundum. Along the interface of corundum and quartz, the HSNL effectively isolates the bulk phases corundum and quartz from each other, thus apparently preventing their reaction to the stable aluminum silicate. High temperatures and prolonged experimental duration lead to recrystallization of corundum including the HSNL and to the formation of quartz + fluid inclusions inside the host crystal. This process reduces the phase boundary area between the bulk phases, thereby providing further opportunity to expand their coexistence. In addition to its small size, its transient nature makes it difficult to detect the HSNL in experiments and even more so in natural samples. Our findings emphasize the potential impact of nanometer-sized phases on geochemical reaction pathways and kinetics under metamorphic conditions in one of the most important chemical systems of the Earth's crust. KW - Experimental KW - Metastability KW - Corundum KW - Quartz KW - Nanolayers KW - Aluminium– silicates Y1 - 2021 U6 - https://doi.org/10.1007/s00410-021-01786-5 SN - 0010-7999 SN - 1432-0967 VL - 176 IS - 4 PB - Springer CY - Berlin ; Heidelberg ER - TY - JOUR A1 - Klemme, Stephan A1 - Feldhaus, Michael A1 - Potapkin, Vasily A1 - Wilke, Max A1 - Borchert, Manuela A1 - Louvel, Marion A1 - Loges, Anselm A1 - Rohrbach, Arno A1 - Weitkamp, Petra A1 - Welter, Edmund A1 - Kokh, Maria A. A1 - Schmidt, Christian A1 - Testemale, Denis T1 - A hydrothermal apparatus for x-ray absorption spectroscopy of hydrothermal fluids at DESY JF - Review of scientific instruments : a monthly journal devoted to scientific instruments, apparatus, and techniques N2 - We present a new autoclave that enables in situ characterization of hydrothermal fluids at high pressures and high temperatures at synchrotron x-ray radiation sources. The autoclave has been specifically designed to enable x-ray absorption spectroscopy in fluids with applications to mineral solubility and element speciation analysis in hydrothermal fluids in complex compositions. However, other applications, such as Raman spectroscopy, in high-pressure fluids are also possible with the autoclave. First experiments were run at pressures between 100 and 600 bars and at temperatures between 25 degrees C and 550 degrees C, and preliminary results on scheelite dissolution in fluids of different compositions show that the autoclave is well suited to study the behavior of ore-forming metals at P-T conditions relevant to the Earth's crust. Y1 - 2021 U6 - https://doi.org/10.1063/5.0044767 SN - 0034-6748 SN - 1089-7623 VL - 92 IS - 6 PB - AIP Publishing CY - Melville ER -