TY - JOUR A1 - Janietz, Dietmar A1 - Festag, R. A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz T1 - Amphotropic oligomeric 1,3,5-triazines containing disc-shaped pentaalkyne and triphenylene side groups Y1 - 1996 ER - TY - JOUR A1 - Goldmann, Daniela A1 - Janietz, Dietmar A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz T1 - Columnar liquid crystalline phases through hydrogen bonding and nanoscale segregation N2 - Two columnar phases forming 2,4,6-triarylamino-1,3,5-triazines have been investigated in binary mixtures with calamitic and non-liquid crystalline benzoic acids carrying one or two alkoxy chains at the aromatic core. The triazines form hydrogen bonded aggregates with the complementary acids. Each investigated equimolar mixture exhibits a columnar mesophase due to segregation of the H-bonded polar core region from the lipophilic aliphatic molecular segments. The cross sectional shape of cylindrical aggregates and, therefore, the two-dimensional lattice symmetries, hexagonal or rectangular, are defined by the number of alkoxy chains of the benzoic acid component Y1 - 2004 SN - 0959-9428 ER - TY - JOUR A1 - Goldmann, Daniela A1 - Janietz, Dietmar A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz T1 - Disc-shaped mesogens based on 1,3,5-triazines : variation and induction of columnar mesophases through complementary intermolecular interactions Y1 - 1996 ER - TY - JOUR A1 - Wilke, Max A1 - Partzsch, G. M. A1 - Schmidt, C. A1 - Farges, Francois T1 - In-situ study of the iron species in silicate melts Y1 - 2004 SN - 0016-7037 ER - TY - JOUR A1 - Janietz, Dietmar A1 - Festag, R. A1 - Schmidt, C. A1 - Tsukruk, V. V. A1 - Wendorff, Joachim Heinz T1 - Interfacial behaviour and thermal properties of triazine modified triphenylene oligomers Y1 - 1995 ER - TY - JOUR A1 - Goldmann, Daniela A1 - Janietz, Dietmar A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz T1 - Liquid crystalline 1,3,5-triazines incorporating rod-like azobenzene sub-units Y1 - 1998 ER - TY - JOUR A1 - Goldmann, Daniela A1 - Mahlstedt, S. A1 - Janietz, Dietmar A1 - Busch, P. A1 - Schmidt, C. A1 - Stracke, A. A1 - Wendorff, Joachim Heinz T1 - Mesomorphic donor-acceptor twin molecules with covalently linked sheet-like pentaalkyne and nitrofluorenone subunits Y1 - 1998 ER - TY - JOUR A1 - Munz, Matthias A1 - Oswald, Sascha A1 - Schmidt, C. T1 - Sand box experiments to evaluate the influence of subsurface temperature probe design on temperature based water flux calculation JF - Hydrology and earth system sciences : HESS N2 - Quantification of subsurface water fluxes based on the one dimensional solution to the heat transport equation depends on the accuracy of measured subsurface temperatures. The influence of temperature probe setup on the accuracy of vertical water flux calculation was systematically evaluated in this experimental study. Four temperature probe setups were installed into a sand box experiment to measure temporal highly resolved vertical temperature profiles under controlled water fluxes in the range of +/- 1.3 md(-1). Pass band filtering provided amplitude differences and phase shifts of the diurnal temperature signal varying with depth depending on water flux. Amplitude ratios of setups directly installed into the saturated sediment significantly varied with sand box hydraulic gradients. Amplitude ratios provided an accurate basis for the analytical calculation of water flow velocities, which matched measured flow velocities. Calculated flow velocities were sensitive to thermal properties of saturated sediment and to temperature sensor spacing, but insensitive to thermal dispersivity equal to solute dispersivity. Amplitude ratios of temperature probe setups indirectly installed into piezometer pipes were influenced by thermal exchange processes within the pipes and significantly varied with water flux direction only. Temperature time lags of small sensor distances of all setups were found to be insensitive to vertical water flux. Y1 - 2011 U6 - https://doi.org/10.5194/hess-15-3495-2011 SN - 1027-5606 VL - 15 IS - 11 SP - 3495 EP - 3510 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Janietz, Dietmar A1 - Festag, R. A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz T1 - Self-organization of new oligomers containing disc-shaped side groups Y1 - 1994 ER - TY - JOUR A1 - Goldmann, Daniela A1 - Dietel, Reinhard A1 - Janietz, Dietmar A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz T1 - Sheet-shaped mesogens based on 1,3,5-Triazines : variation of columnar mesophases through intermolecular hydrogen bonding Y1 - 1998 ER - TY - JOUR A1 - Goldmann, Daniela A1 - Nordsieck, A. A1 - Janietz, Dietmar A1 - Frese, T. A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz T1 - Smectic and columnar liquid crystalline phases through charge-transfer interactions N2 - New heterocyclic electron donors based on. a 1,3,5-triazine nucleus are presented. Three phenyl rings are grafted to the triazine core either via secondary amino groups or by a direct C,C-linkage and a specific number of decyloxy chains is attached to the molecular periphery. The compounds are non-liquid crystalline in their pure states. Lamellar or columnar mesophases are induced by attractive interactions with electron acceptors Y1 - 2004 SN - 1058-725X ER - TY - JOUR A1 - Wilke, Max A1 - Farges, Francois A1 - Partzsch, G. M. A1 - Schmidt, C. A1 - Behrens, Harald T1 - Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy Y1 - 2007 ER - TY - JOUR A1 - Festag, R. A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz A1 - Janietz, Dietmar T1 - Structure and dynamics of new triazine based polymers with discotic side groups Y1 - 1995 ER - TY - JOUR A1 - Janietz, Dietmar A1 - Festag, R. A1 - Schmidt, C. A1 - Wendorff, Joachim Heinz T1 - Supramolecular assemblies of new amphotropic oligomers with disc-shaped side groups Y1 - 1995 ER - TY - JOUR A1 - Farges, Francois A1 - Djanarthany, S A1 - de Wispelaere, S A1 - Munoz, Manuel A1 - Magassouba, B A1 - Haddi, A A1 - Wilke, Max A1 - Schmidt, C. A1 - Borchert, Manuela A1 - Trocellier, P A1 - Crichton, W A1 - Simionovici, Alexandre A1 - Petit, Pierre-Emanuel A1 - Mezouar, Mohamed A1 - Etcheverry, M. P. A1 - Pallot-Frossard, I A1 - Bargar, John Reeder A1 - Brown, G. E. A1 - Grolimund, D A1 - Scheidegger, A T1 - Water in silicate glasses and melts of environmental interest : from volcanoes to cathedrals N2 - In silicate glasses and melts, water acts according to two main processes. First, it can be dissolved in high temperature/high pressure melts. Second, it constitutes a weathering agent on the glass surface. A number of in-situ x- ray absorption fine structure (XAFS) studies for Fe, Ni, Zr, Th and U show that the more charged cations (Zr, Nb, Mo, Ta, Sn, Th and U) are little affected by the presence of dissolved water in the melt. In contrast, divalent iron and nickel are highly sensitive to the presence of water, which enhance nucleation processes, for example, of phyllosilicates at the angstrom-scale. Such information provides additional constraints on the role of water deep in the Earth, particularly in magmatology. By contrast, the weathering of glass surfaces by water can be studied from a durability perspective. Experimental weathering experiments Of nuclear waste glasses performed in the laboratory show a variety of surface enrichments (carbon, chlorine, alkalis, iron) after exposure to atmospheric fluids and moisture. Mn-, and Fe-surface enrichments of analogous glasses of the XIVth century are related to the formation of Mn and Fe oxy/ hydroxides on the surface. The impact on the glass darkening is considered in terms of urban pollution and mass tourism Y1 - 2005 ER -