TY - JOUR A1 - Noiray, Aude A1 - Menard, Lucie A1 - Iskarous, Khalil T1 - The development of motor synergies in children ultrasound and acoustic measurements JF - The journal of the Acoustical Society of America N2 - The present study focuses on differences in lingual coarticulation between French children and adults. The specific question pursued is whether 4-5 year old children have already acquired a synergy observed in adults in which the tongue back helps the tip in the formation of alveolar consonants. Locus equations, estimated from acoustic and ultrasound imaging data were used to compare coarticulation degree between adults and children and further investigate differences in motor synergy between the front and back parts of the tongue. Results show similar slope and intercept patterns for adults and children in both the acoustic and articulatory domains, with an effect of place of articulation in both groups between alveolar and non-alveolar consonants. These results suggest that 4-5 year old children (1) have learned the motor synergy investigated and (2) have developed a pattern of coarticulatory resistance depending on a consonant place of articulation. Also, results show that acoustic locus equations can be used to gauge the presence of motor synergies in children. Y1 - 2013 U6 - https://doi.org/10.1121/1.4763983 SN - 0001-4966 SN - 1520-8524 VL - 133 IS - 1 SP - 444 EP - 452 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Tsukaya, Hirokazu A1 - Byrne, Mary E. A1 - Horiguchi, Gorou A1 - Sugiyama, Munetaka A1 - Van Lijsebettens, Mieke A1 - Lenhard, Michael T1 - How do 'housekeeping' genes control organogenesis?-unexpected new findings on the role of housekeeping genes in cell and organ differentiation JF - Journal of plant research N2 - In recent years, an increasing number of mutations in what would appear to be 'housekeeping genes' have been identified as having unexpectedly specific defects in multicellular organogenesis. This is also the case for organogenesis in seed plants. Although it is not surprising that loss-of-function mutations in 'housekeeping' genes result in lethality or growth retardation, it is surprising when (1) the mutant phenotype results from the loss of function of a 'housekeeping' gene and (2) the mutant phenotype is specific. In this review, by defining housekeeping genes as those encoding proteins that work in basic metabolic and cellular functions, we discuss unexpected links between housekeeping genes and specific developmental processes. In a surprising number of cases housekeeping genes coding for enzymes or proteins with functions in basic cellular processes such as transcription, post-transcriptional modification, and translation affect plant development. KW - Development KW - Housekeeping genes KW - Post-transcriptional modification KW - RNAPII KW - Pre-mRNA splicing KW - Ribosome KW - 3 '-end processing KW - Transcription KW - Translation Y1 - 2013 U6 - https://doi.org/10.1007/s10265-012-0518-2 SN - 0918-9440 VL - 126 IS - 1 SP - 3 EP - 15 PB - Springer CY - Tokyo ER - TY - JOUR A1 - Hartwich, Melanie A1 - Martin-Creuzburg, Dominik A1 - Wacker, Alexander T1 - Seasonal changes in the accumulation of polyunsaturated fatty acids in zooplankton JF - Journal of plankton research N2 - In aquatic food webs, consumers, such as daphnids and copepods, differ regarding their accumulation of polyunsaturated fatty acids (PUFAs). We tested if the accumulation of PUFAs in a seston size fraction containing different consumers and in Daphnia as a separate consumer is subject to seasonal changes in a large deep lake due to changes in the dietary PUFA supply and specific demands of different consumers. We found that the accumulation of arachidonic acid (ARA) in Daphnia increased from early summer to late summer and autumn. However, ARA requirements of Daphnia appeared to be constant throughout the year, because the accumulation of ARA increased when the dietary ARA supply decreased. In the size fraction 140 m, we found an increased accumulation of docosahexaenoic acid (DHA) during late summer and autumn. These seasonal changes in DHA accumulation were linked to changes in the proportion of copepods in this size fraction, which may have increasingly accumulated DHA for active overwintering. We show that consumer-specific PUFA demands can result in seasonal changes in PUFA accumulation, which may influence the trophic transfer of PUFAs within the food web. KW - accumulation KW - Daphnia KW - copepods KW - ARA KW - DHA Y1 - 2013 U6 - https://doi.org/10.1093/plankt/fbs078 SN - 0142-7873 VL - 35 IS - 1 SP - 121 EP - 134 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Burchert, Frank A1 - Hanne, Sandra A1 - Vasishth, Shravan T1 - Sentence comprehension disorders in aphasia the concept of chance performance revisited JF - Aphasiology : an international, interdisciplinary journal N2 - Background: In behavioural tests of sentence comprehension in aphasia, correct and incorrect responses are often randomly distributed. Such a pattern of chance performance is a typical trait of Broca's aphasia, but can be found in other aphasic syndromes as well. Many researchers have argued that chance behaviour is the result of a guessing strategy, which is adopted in the face of a syntactic breakdown in sentence processing. Aims: Capitalising on new evidence from recent studies investigating online sentence comprehension in aphasia using the visual world paradigm, the aim of this paper is to review the concept of chance performance as a reflection of a syntactic impairment in sentence processing and to re-examine the conventional interpretation of chance performance as a guessing behaviour. Main Contribution: Based on a review of recent evidence from visual world paradigm studies, we argue that the assumption of chance performance equalling guessing is not necessarily compatible with actual real-time parsing procedures in people with aphasia. We propose a reinterpretation of the concept of chance performance by assuming that there are two distinct processing mechanisms underlying sentence comprehension in aphasia. Correct responses are always the result of normal-like parsing mechanisms, even in those cases where the overall performance pattern is at chance. Incorrect responses, on the other hand, are the result of intermittent deficiencies of the parser. Hence the random guessing behaviour that persons with aphasia often display does not necessarily reflect a syntactic breakdown in sentence comprehension and a random selection between alternatives. Instead it should be regarded as a result of temporal deficient parsing procedures in otherwise normal-like comprehension routines. Conclusion: Our conclusion is that the consideration of behavioural offline data alone may not be sufficient to interpret a performance in language tests and subsequently draw theoretical conclusions about language impairments. Rather it is important to call on additional data from online studies that look at language processing in real time in order to gain a comprehensive picture about syntactic comprehension abilities of people with aphasia and possible underlying deficits. KW - Sentence comprehension in aphasia KW - Chance performance KW - Visual world paradigm KW - Eye tracking KW - Online sentence processing Y1 - 2013 U6 - https://doi.org/10.1080/02687038.2012.730603 SN - 0268-7038 VL - 27 IS - 1 SP - 112 EP - 125 PB - Wiley CY - Hove ER - TY - JOUR A1 - Mühlbauer, Thomas A1 - Besemer, Carmen A1 - Wehrle, Anja A1 - Gollhofer, Albert A1 - Granacher, Urs T1 - Relationship between strength; balance and mobility in children aged 7-10 years JF - Gait & posture N2 - The purpose of this study was to investigate the association between variables of lower extremity muscle strength, balance, and mobility assessed under various task conditions. Twenty-one healthy children (mean age: 9 +/- 1 years) were tested for their isometric and dynamic strength as well as for their steady-state, proactive, and reactive balance and mobility. Balance and mobility tests were conducted under single and dual task conditions. Significant positive correlations were detected between measures of isometric and dynamic leg muscle strength. Hardly any significant associations were observed between variables of strength and balance/mobility and between measures of steady-state, proactive, and reactive balance. Additionally, no significant correlations were detected between balance/mobility tests performed under single and dual task conditions. The predominately non-significant correlations between different balance components and mobility imply that balance and mobility performance is task specific. Further, strength and balance/mobility as well as balance under single and dual task conditions seem to be independent of each other and may have to be tested and trained complementarily. KW - Steady-state balance KW - Proactive/reactive balance KW - Maximal isometric force KW - Jumping height KW - Single/dual tasking KW - Cognitive/motor interference Y1 - 2013 U6 - https://doi.org/10.1016/j.gaitpost.2012.06.022 SN - 0966-6362 VL - 37 IS - 1 SP - 108 EP - 112 PB - Elsevier CY - Clare ER - TY - JOUR A1 - Wissel, Jörg A1 - Manack, Aubrey A1 - Brainin, Michael T1 - Toward an epidemiology of poststroke spasticity JF - Neurology : official journal of the American Academy of Neurology N2 - Poststroke spasticity (PSS)-related disability is emerging as a significant health issue for stroke survivors. There is a need for predictors and early identification of PSS in order to minimize complications and maladaptation from spasticity. Reviewing the literature on stroke and upper motor neuron syndrome, spasticity, contracture, and increased muscle tone measured with the Modified Ashworth Scale and the Tone Assessment Scale provided data on the dynamic time course of PSS. Prevalence estimates of PSS were highly variable, ranging from 4% to 42.6%, with the prevalence of disabling spasticity ranging from 2% to 13%. Data on phases of the PSS continuum revealed evidence of PSS in 4% to 27% of those in the early time course (1-4 weeks poststroke), 19% to 26.7% of those in the postacute phase (1-3 months poststroke), and 17% to 42.6% of those in the chronic phase (>3 months poststroke). Data also identified key risk factors associated with the development of spasticity, including lower Barthel Index scores, severe degree of paresis, stroke-related pain, and sensory deficits. Although such indices could be regarded as predictors of PSS and thus enable early identification and treatment, the different measures of PSS used in those studies limit the strength of the findings. To optimize evaluation in the different phases of care, the best possible assessment of PSS would make use of a combination of indicators for clinical impairment, motor performance, activity level, quality of life, and patient-reported outcome measures. Applying these recommended measures, as well as increasing our knowledge of the physiologic predictors of PSS, will enable us to perform clinical and epidemiologic studies that will facilitate identification and early, multimodal treatment. Y1 - 2013 SN - 0028-3878 VL - 80 IS - 1 SP - S13 EP - S19 PB - Lippincott Williams & Wilkins CY - Philadelphia ER - TY - JOUR A1 - Richter, Michael A1 - van Hout, Roeland T1 - Interpreting resultative sentences in German BT - stages in L1 acquisition JF - Linguistics : an interdisciplinary journal of the language sciences N2 - This article presents the results of a study on the interpretation and acceptance of adjectival resultatives of German children between 6 and 9 years of age and adults. These results brought to light significant differences, due to age, in the interpretation and acceptance of these resultatives, that is to say, sentences with an adjective in the final position. The youngest participants were prone to accept ungrammatical sentences by assigning a resultative meaning. The ungrammaticality of the sentences in question was not due to semantic inconsistencies but to violations of the selectional properties of verbs, as for instance in *die Kinder erschrecken die Katze angstlich 'the children frighten the cat scared'. In contrast, the adults rejected or amended those sentences. The conclusion is (a) that the children seemed to rely on the sentence structure as a primary cue to compute the meaning of an utterance and (b) that, in contrast with adults, the youngest children in particular had not yet learned the relevant semantic properties of verbs that determine the selectional restrictions and thus the syntactic options of verbs. This means that differences in interpretation and acceptance of sentences are due to differences in knowledge of semantic verb properties between adults and children. The relevant semantic knowledge increases in gradual stages during language acquisition. KW - first language acquisition KW - frame compliance KW - grammatical judgments KW - verb classes KW - resultative sentences Y1 - 2013 U6 - https://doi.org/10.1515/ling-2013-0004 SN - 0024-3949 VL - 51 IS - 1 SP - 117 EP - 144 PB - De Gruyter Mouton CY - Berlin ER - TY - JOUR A1 - Kranich, Svenja T1 - Functional layering and the English progressive JF - Linguistics : an interdisciplinary journal of the language sciences N2 - In this article, it will be argued that the concept of functional layering - an extension of Hopper's (1991) concept of layering - can be fruitfully applied to understand the mechanisms behind the sometimes large and messy looking synchronic picture of diverse meanings which one and the same construction can fulfill at a particular point in time. The concept will be used to account for the meaning spectrum of the present-day English progressive, which, it will be argued, no monosemic approach to date can account for. Taking a look at the diachrony of the construction will help to reveal that the various "exceptions" found in the use of the progressive can be understood as reflections of different stages in its development. Older, less grammaticalized or less well-defined usage patterns thus often survive in certain restricted niches next to the newer, more grammaticalized or more clear-cut functions, representing different diachronic layers. In addition to this diachronic motivation for synchronic meaning variety, the article will also address the crucial question of how a present-day hearer of a progressive form is able to decode the specific meaning intended by the speaker based on contextual clues. The article ends with some suggestions for further applications of the concept of functional layering. KW - grammaticalization KW - subjectification KW - semantic change KW - the English progressive construction KW - polysemy Y1 - 2013 U6 - https://doi.org/10.1515/ling-2013-0001 SN - 0024-3949 VL - 51 IS - 1 SP - 1 EP - 32 PB - De Gruyter Mouton CY - Berlin ER - TY - JOUR A1 - Hammer, Conny A1 - Ohrnberger, Matthias A1 - Faeh, Donat T1 - Classifying seismic waveforms from scratch: a case study in the alpine environment JF - Geophysical journal international N2 - Nowadays, an increasing amount of seismic data is collected by daily observatory routines. The basic step for successfully analyzing those data is the correct detection of various event types. However, the visually scanning process is a time-consuming task. Applying standard techniques for detection like the STA/LTAtrigger still requires the manual control for classification. Here, we present a useful alternative. The incoming data stream is scanned automatically for events of interest. A stochastic classifier, called hidden Markov model, is learned for each class of interest enabling the recognition of highly variable waveforms. In contrast to other automatic techniques as neural networks or support vector machines the algorithm allows to start the classification from scratch as soon as interesting events are identified. Neither the tedious process of collecting training samples nor a time-consuming configuration of the classifier is required. An approach originally introduced for the volcanic task force action allows to learn classifier properties from a single waveform example and some hours of background recording. Besides a reduction of required workload this also enables to detect very rare events. Especially the latter feature provides a milestone point for the use of seismic devices in alpine warning systems. Furthermore, the system offers the opportunity to flag new signal classes that have not been defined before. We demonstrate the application of the classification system using a data set from the Swiss Seismological Survey achieving very high recognition rates. In detail we document all refinements of the classifier providing a step-by-step guide for the fast set up of a well-working classification system. KW - Time series analysis KW - Neural networks, fuzzy logic KW - Seismic monitoring and test-ban treaty verification KW - Early warning KW - Probability distributions Y1 - 2013 U6 - https://doi.org/10.1093/gji/ggs036 SN - 0956-540X SN - 1365-246X VL - 192 IS - 1 SP - 425 EP - 439 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Hobiger, M. A1 - Cornou, C. A1 - Wathelet, M. A1 - Di Giulio, G. A1 - Knapmeyer-Endrun, B. A1 - Renalier, F. A1 - Bard, Pierre-Yves A1 - Savvaidis, Alexandros A1 - Hailemikael, S. A1 - Le Bihan, N. A1 - Ohrnberger, Matthias A1 - Theodoulidis, N. T1 - Ground structure imaging by inversions of Rayleigh wave ellipticity sensitivity analysis and application to European strong-motion sites JF - Geophysical journal international N2 - The knowledge of the local soil structure is important for the assessment of seismic hazards. A widespread, but time-consuming technique to retrieve the parameters of the local underground is the drilling of boreholes. Another way to obtain the shear wave velocity profile at a given location is the inversion of surface wave dispersion curves. To ensure a good resolution for both superficial and deeper layers, the used dispersion curves need to cover a wide frequency range. This wide frequency range can be obtained using several arrays of seismic sensors or a single array comprising a large number of sensors. Consequently, these measurements are time-consuming. A simpler alternative is provided by the use of the ellipticity of Rayleigh waves. The frequency dependence of the ellipticity is tightly linked to the shear wave velocity profile. Furthermore, it can be measured using a single seismic sensor. As soil structures obtained by scaling of a given model exhibit the same ellipticity curve, any inversion of the ellipticity curve alone will be ambiguous. Therefore, additional measurements which fix the absolute value of the shear wave velocity profile at some points have to be included in the inversion process. Small-scale spatial autocorrelation measurements or MASW measurements can provide the needed data. Using a theoretical soil structure, we show which parts of the ellipticity curve have to be included in the inversion process to get a reliable result and which parts can be omitted. Furthermore, the use of autocorrelation or high-frequency dispersion curves will be highlighted. The resulting guidelines for inversions including ellipticity data are then applied to real data measurements collected at 14 different sites during the European NERIES project. It is found that the results are in good agreement with dispersion curve measurements. Furthermore, the method can help in identifying the mode of Rayleigh waves in dispersion curve measurements. KW - Inverse theory KW - Surface waves and free oscillations KW - Site effects KW - Computational seismology KW - Wave propagation Y1 - 2013 U6 - https://doi.org/10.1093/gji/ggs005 SN - 0956-540X VL - 192 IS - 1 SP - 207 EP - 229 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Sachse, Rita A1 - Wüstenhagen, Doreen Anja A1 - Samalikova, Maria A1 - Gerrits, Michael A1 - Bier, Frank Fabian A1 - Kubick, Stefan T1 - Synthesis of membrane proteins in eukaryotic cell-free systems JF - Engineering in life sciences : Industry, Environment, Plant, Food N2 - Cell-free protein synthesis (CFPS) is a valuable method for the fast expression of difficult-to-express proteins as well as posttranslationally modified proteins. Since cell-free systems circumvent possible cytotoxic effects caused by protein overexpression in living cells, they significantly enlarge the scale and variety of proteins that can be characterized. We demonstrate the high potential of eukaryotic CFPS to express various types of membrane proteins covering a broad range of structurally and functionally diverse proteins. Our eukaryotic cell-free translation systems are capable to provide high molecular weight membrane proteins, fluorescent-labeled membrane proteins, as well as posttranslationally modified proteins for further downstream analysis. KW - Cell-free protein expression KW - In vitro protein synthesis KW - Labeled membrane proteins KW - Synthetic glycoprotein Y1 - 2013 U6 - https://doi.org/10.1002/elsc.201100235 SN - 1618-0240 VL - 13 IS - 1 SP - 39 EP - 48 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Häring, Tim A1 - Reger, Birgit A1 - Ewald, Jörg A1 - Hothorn, Torsten A1 - Schröder-Esselbach, Boris T1 - Predicting Ellenberg's soil moisture indicator value in the Bavarian Alps using additive georegression JF - Applied vegetation science : official organ of the International Association for Vegetation Science N2 - Questions Can forest site characteristics be used to predict Ellenberg indicator values for soil moisture? Which is the best averaged mean value for modelling? Does the distribution of soil moisture depend on spatial information? Location Bavarian Alps, Germany. Methods We used topographic, climatic and edaphic variables to model the mean soil moisture value as found on 1505 forest plots from the database WINALPecobase. All predictor variables were taken from area-wide geodata layers so that the model can be applied to some 250 000 ha of forest in the target region. We adopted methods developed in species distribution modelling to regionalize Ellenberg indicator values. Therefore, we use the additive georegression framework for spatial prediction of Ellenberg values with the R-library mboost, which is a feasible way to consider environmental effects, spatial autocorrelation, predictor interactions and non-stationarity simultaneously in our data. The framework is much more flexible than established statistical and machine-learning models in species distribution modelling. We estimated five different mboost models reflecting different model structures on 50 bootstrap samples in each case. Results Median R2 values calculated on independent test samples ranged from 0.28 to 0.45. Our results show a significant influence of interactions and non-stationarity in addition to environmental covariates. Unweighted mean indicator values can be modelled better than abundance-weighted values, and the consideration of bryophytes did not improve model performance. Partial response curves indicate meaningful dependencies between moisture indicator values and environmental covariates. However, mean indicator values <4.5 and >6.0 could not be modelled correctly, since they were poorly represented in our calibration sample. The final map represents high-resolution information of site hydrological conditions. Conclusions Indicator values offer an effect-oriented alternative to physically-based hydrological models to predict water-related site conditions, even at landscape scale. The presented approach is applicable to all kinds of Ellenberg indicator values. Therefore, it is a significant step towards a new generation of models of forest site types and potential natural vegetation. KW - Boosting KW - Mboost KW - Non-stationarity KW - Predictive vegetation mapping KW - Site ecology KW - Species distribution modelling Y1 - 2013 U6 - https://doi.org/10.1111/j.1654-109X.2012.01210.x SN - 1402-2001 VL - 16 IS - 1 SP - 110 EP - 121 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Wessig, Pablo A1 - Matthes, Annika T1 - Photochemical synthesis and properties of 1,6- and 1,8-Naphthalenophanes JF - Molecules N2 - Various 1,6- and 1,8-naphthalenophanes were synthesized by using the Photo-Dehydro-Diels-Alder (PDDA) reaction of bis-ynones. These compounds are easily accessible from omega-(3-iodophenyl)carboxylic acids in three steps. The obtained naphthalenophanes are axially chiral and the activation barrier for the atropisomerization could be determined in some cases by means of dynamic NMR (DNMR) and/or dynamic HPLC (DHPLC) experiments. KW - photo-dehydro-Diels-Alder reaction KW - naphthalenophanes KW - atropisomerism KW - dynamic NMR KW - dynamic HPLC Y1 - 2013 U6 - https://doi.org/10.3390/molecules18011314 SN - 1420-3049 VL - 18 IS - 1 SP - 1314 EP - 1324 PB - MDPI CY - Basel ER - TY - JOUR A1 - Javanainen, Matti A1 - Hammaren, Henrik A1 - Monticelli, Luca A1 - Jeon, Jae-Hyung A1 - Miettinen, Markus S. A1 - Martinez-Seara, Hector A1 - Metzler, Ralf A1 - Vattulainen, Ilpo T1 - Anomalous and normal diffusion of proteins and lipids in crowded lipid membranes JF - Faraday discussions N2 - Lateral diffusion plays a crucial role in numerous processes that take place in cell membranes, yet it is quite poorly understood in native membranes characterized by, e.g., domain formation and large concentration of proteins. In this article, we use atomistic and coarse-grained simulations to consider how packing of membranes and crowding with proteins affect the lateral dynamics of lipids and membrane proteins. We find that both packing and protein crowding have a profound effect on lateral diffusion, slowing it down. Anomalous diffusion is observed to be an inherent property in both protein-free and protein-rich membranes, and the time scales of anomalous diffusion and the exponent associated with anomalous diffusion are found to strongly depend on packing and crowding. Crowding with proteins also has a striking effect on the decay rate of dynamical correlations associated with lateral single-particle motion, as the transition from anomalous to normal diffusion is found to take place at macroscopic time scales: while in protein-poor conditions normal diffusion is typically observed in hundreds of nanoseconds, in protein-rich conditions the onset of normal diffusion is tens of microseconds, and in the most crowded systems as large as milliseconds. The computational challenge which results from these time scales is not easy to deal with, not even in coarse-grained simulations. We also briefly discuss the physical limits of protein motion. Our results suggest that protein concentration is anything but constant in the plane of cell membranes. Instead, it is strongly dependent on proteins' preference for aggregation. Y1 - 2013 U6 - https://doi.org/10.1039/c2fd20085f SN - 1359-6640 VL - 161 IS - 1 SP - 397 EP - 417 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Schnabel, Konrad A1 - Asendorpf, Jens B. T1 - Free associations as a measure of stable implicit attitudes JF - European journal of personality N2 - Two studies explored the psychometric properties of free association methods for the assessment of attitudes. Even though the stability of the actual associations was rather low, psychometric properties of the valence estimates of the free associations were highly satisfactory. Valence estimates of associations were provided by independent judges who rated the valence of the associations that were generated by participants. Valence estimates of the associations showed satisfactory internal consistencies and retest reliabilities over three weeks. Additionally, valence estimates of the associations were significantly and independently related to both explicit self-reported attitudes and implicit attitudes that were assessed with an OssiWessi Implicit Association Test. Free association methods represent a useful complement to the family of implicit measures and are especially suitable for the assessment of non-relative attitudes towards single attitude objects. KW - free associations KW - automatic associations KW - automatic attitudes KW - social cognition KW - implicit measures Y1 - 2013 U6 - https://doi.org/10.1002/per.1890 SN - 0890-2070 VL - 27 IS - 1 SP - 39 EP - 50 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Badalyan, Artavazd A1 - Neumann-Schaal, Meina A1 - Leimkühler, Silke A1 - Wollenberger, Ursula T1 - A Biosensor for aromatic aldehydes comprising the mediator dependent PaoABC-Aldehyde oxidoreductase JF - Electroanalysis : an international journal devoted to fundamental and practical aspects of electroanalysis N2 - A novel aldehyde oxidoreductase (PaoABC) from Escherichia coli was utilized for the development of an oxygen insensitive biosensor for benzaldehyde. The enzyme was immobilized in polyvinyl alcohol and currents were measured for aldehyde oxidation with different one and two electron mediators with the highest sensitivity for benzaldehyde in the presence of hexacyanoferrate(III). The benzaldehyde biosensor was optimized with respect to mediator concentration, enzyme loading and pH using potassium hexacyanoferrate(III). The linear measuring range is between 0.5200 mu M benzaldehyde. In correspondence with the substrate selectivity of the enzyme in solution the biosensor revealed a preference for aromatic aldehydes and less effective conversion of aliphatic aldehydes. The biosensor is oxygen independent, which is a particularly attractive feature for application. The biosensor can be applied to detect contaminations with benzaldehyde in solvents such as benzyl alcohol, where traces of benzaldehyde in benzyl alcohol down to 0.0042?% can be detected. KW - Aldehyde oxidoreductase KW - Benzaldehyde KW - Biosensor KW - Aromatic aldehydes KW - Molybdenum cofactor Y1 - 2013 U6 - https://doi.org/10.1002/elan.201200362 SN - 1040-0397 VL - 25 IS - 1 SP - 101 EP - 108 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Sliusarenko, O. Yu. A1 - Surkov, D. A. A1 - Gonchar, V. Yu. A1 - Chechkin, Aleksei V. T1 - Stationary states in bistable system driven by Levy noise JF - European physical journal special topics N2 - We study the properties of the probability density function (PDF) of a bistable system driven by heavy tailed white symmetric L,vy noise. The shape of the stationary PDF is found analytically for the particular case of the L,vy index alpha = 1 (Cauchy noise). For an arbitrary L,vy index we employ numerical methods based on the solution of the stochastic Langevin equation and space fractional kinetic equation. In contrast to the bistable system driven by Gaussian noise, in the L,vy case, the positions of maxima of the stationary PDF do not coincide with the positions of minima of the bistable potential. We provide a detailed study of the distance between the maxima and the minima as a function of the depth of the potential and the L,vy noise parameters. Y1 - 2013 U6 - https://doi.org/10.1140/epjst/e2013-01736-0 SN - 1951-6355 VL - 216 IS - 1 SP - 133 EP - 138 PB - Springer CY - Heidelberg ER - TY - JOUR A1 - von Czapiewski, Marc A1 - Kreye, Oliver A1 - Mutlu, Hatice A1 - Meier, Michael A. R. T1 - Cross-metathesis versus palladium-catalyzed C-H activation acetoxy ester functionalization of unsaturated fatty acid methyl esters JF - European journal of lipid science and technology N2 - Two synthetic approaches to functionalize plant oil derived platform chemicals were investigated. For this purpose, methyl 10-undecenoate, which can be obtained by pyrolysis of castor oil, was used in olefin cross-metathesis under neat conditions forming an unsaturated a,?-acetoxy ester. A catalyst screening with 11 different ruthenium-based metathesis catalysts was performed, revealing that well-suited catalysts allow for full conversion and very good cross-metathesis selectivity at a loading of only 0.5?mol%. An alternative possibility to the aforementioned synthetic method is a palladium-catalyzed reaction of methyl 10-undecenoate with acetic acid in the presence of dimethyl sulfoxide. Here, the formation of linear and branched unsaturated acetoxy esters as well as a ketone was observed. The conversion as well as the selectivity of this procedure was studied under different reaction conditions and compared to the cross-metathesis results. Based on the successful functionalization of methyl 10-undecenoate, methyl oleate was investigated in this palladium-catalyzed C?H activation reaction. Due to the lower reactivity of the internal double bond the desired acetoxy ester was only obtained in moderate conversion in this case. In summary, this study clearly shows that palladium-catalyzed functionalization of unsaturated fatty compounds via C?H activation is an attractive alternative to the well-established olefin cross-metathesis procedure. KW - a KW - -Acetoxy esters KW - C?H oxidation KW - Cross-metathesis KW - Fatty acids KW - Pd catalysis Y1 - 2013 U6 - https://doi.org/10.1002/ejlt.201200196 SN - 1438-7697 VL - 115 IS - 1 SP - 76 EP - 85 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Herder, Martin A1 - Utecht, Manuel Martin A1 - Manicke, Nicole A1 - Grubert, Lutz A1 - Pätzel, Michael A1 - Saalfrank, Peter A1 - Hecht, Stefan T1 - Switching with orthogonal stimuli electrochemical ring-closure and photochemical ring-opening of bis(thiazolyl) maleimides JF - Chemical science N2 - The photochemistry as well as electrochemistry of novel donor-acceptor bis(morpholinothiazolyl)maleimides has been investigated. Proper substitution of these diarylethene-type molecular switches leads to the unique situation in which their ring-closure can only be accomplished electrochemically, while ring-opening can only be achieved photochemically. Hence, these switches operate with orthogonal stimuli, i.e. redox potential and light, respectively. The switch system could be optimized by introducing trifluoromethyl groups at the reactive carbon atoms in order to avoid by-product formation during oxidative ring closure. Both photochemical and electrochemical pathways were investigated for methylated, trifluoromethylated, and nonsymmetrical bis(morpholinothiazolyl) maleimides as well as the bis(morpholinothiazolyl) cyclopentene reference compound. With the aid of the nonsymmetrical "mixed" derivative, the mechanism of electrochemically driven ring closure could be elucidated and seems to proceed via a dicationic intermediate generated by two-fold oxidation. All experimental work has been complemented by density functional theory that provides detailed insights into the thermodynamics of the ring-open and closed forms, the nature of their excited states, and the reactivity of their neutral as well as ionized species in different electronic configurations. The particular diarylethene systems described herein could serve in multifunctional (logic) devices operated by different stimuli (inputs) and may pave the way to converting light into electrical energy via photoinduced "pumping" of redox-active meta-stable states. Y1 - 2013 U6 - https://doi.org/10.1039/c2sc21681g SN - 2041-6520 VL - 4 IS - 3 SP - 1028 EP - 1040 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Li, Hongguang A1 - Babu, Sukumaran Santhosh A1 - Turner, Sarah T. A1 - Neher, Dieter A1 - Hollamby, Martin J. A1 - Seki, Tomohiro A1 - Yagai, Shiki A1 - Deguchi, Yonekazu A1 - Möhwald, Helmuth A1 - Nakanishi, Takashi T1 - Alkylated-C-60 based soft materials regulation of self-assembly and optoelectronic properties by chain branching JF - Journal of materials chemistry : C, Materials for optical and electronic devices N2 - Derivatization of fullerene (C-60) with branched aliphatic chains softens C-60-based materials and enables the formation of thermotropic liquid crystals and room temperature nonvolatile liquids. This work demonstrates that by carefully tuning parameters such as type, number and substituent position of the branched chains, liquid crystalline C-60 materials with mesophase temperatures suited for photovoltaic cell fabrication and room temperature nonvolatile liquid fullerenes with tunable viscosity can be obtained. In particular, compound 1, with branched chains, exhibits a smectic liquid crystalline phase extending from 84 degrees C to room temperature. Analysis of bulk heterojunction (BHJ) organic solar cells with a ca. 100 nm active layer of compound 1 and poly(3-hexylthiophene) (P3HT) as an electron acceptor and an electron donor, respectively, reveals an improved performance (power conversion efficiency, PCE: 1.6 + 0.1%) in comparison with another compound, 10 (PCE: 0.5 + 0.1%). The latter, in contrast to 1, carries linear aliphatic chains and thus forms a highly ordered solid lamellar phase at room temperature. The solar cell performance of 1 blended with P3HT approaches that of PCBM/P3HT for the same active layer thickness. This indicates that C-60 derivatives bearing branched tails are a promising class of electron acceptors in soft (flexible) photovoltaic devices. Y1 - 2013 U6 - https://doi.org/10.1039/c3tc00066d SN - 2050-7526 VL - 1 IS - 10 SP - 1943 EP - 1951 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Tomczyk, Jaroslaw A1 - Sobolewska, Anna A1 - Nagy, Zsuzsanna T. A1 - Guillon, Daniel A1 - Donnio, Bertrand A1 - Stumpe, Joachim T1 - Photo- and thermal-processing of azobenzene-containing star-shaped liquid crystals JF - Journal of materials chemistry : C, Materials for optical and electronic devices N2 - A new class of star-shaped, liquid crystalline, low-molecular weight compounds functionalized with photochromic azobenzene and mesogenic groups was investigated in terms of light-induced anisotropy. The behaviour of the materials under the action of light with simultaneous or subsequent thermal treatment was examined with respect to the induction of anisotropy. The unconventional UV light treatment prior to the irradiation with linearly polarized light allowed induction of very high values of anisotropy (D = 0.77) at room temperature. Moreover, the simultaneous action of light and temperature led to the induction of higher values of dichroism in comparison with anisotropy generated by the standard procedure. Subsequent thermal treatment led to dewetting and the formation of 3D macroscopic stripe- and dome-like structures for one of the investigated compounds. Despite photoinduction of anisotropy by a single beam, the formation of polarization and surface relief gratings by two-beam interference pattern was also investigated. Y1 - 2013 U6 - https://doi.org/10.1039/c2tc00627h SN - 2050-7526 VL - 1 IS - 5 SP - 924 EP - 932 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Scheffler, Christiane T1 - Variable and invariable proportions in the ontogenesis of the human face JF - The journal of craniofacial surgery : an international journal dedicated to the practice of the art and science of craniofacial surgery ; official publication of the American Association of Pediatric Plastic Surgeons N2 - The human face shows individual features and features that are characteristic for sex and age (the loss of childlike characteristics during maturation). The analysis of facial dimensions is essential for identifying individual features also for forensic issues. The analysis of facial proportions was performed on photogrammetric data from front views of 125 children. The data were pooled from 2 different studies. The children's data were obtained from a longitudinal study and reduced by random generator to ensure the data of adults from a separate cross-sectional study. We applied principal component analysis on photogrammetric facial proportions of 169 individuals: 125 children (63 boys and 62 girls) aged 2-7 years and 44 adults (18 men and 26 women) aged 18-65 years. Facial proportions depend on age and sex. Three components described age: (1) proportions of facial height to head height, (2) proportions that involve endocanthal breadth, and (3) bigonial to bizygonial proportions. Proportions that associate with sex are connected with nasal distances and nasal to bizygonial distances. Twenty-three percent of the variance, particularly variance that are connected with proportions of lower and middle face heights to head height, do neither depend on sex nor on age and thus appear useful for screening purposes, eg, for dysmorphic genetic syndromes. KW - Human face KW - face proportions KW - ontogenesis KW - principal component analysis Y1 - 2013 U6 - https://doi.org/10.1097/SCS.0b013e31826d07a3 SN - 1049-2275 VL - 24 IS - 1 SP - 237 EP - 241 PB - Lippincott Williams & Wilkins CY - Philadelphia ER - TY - JOUR A1 - Barthold, Frauke Katrin A1 - Wiesmeier, Martin A1 - Breuer, L. A1 - Frede, Hans-Georg A1 - Wu, J. A1 - Blank, F. Benjamin T1 - Land use and climate control the spatial distribution of soil types in the grasslands of Inner Mongolia JF - Journal of arid environments N2 - The spatial distribution of soil types is controlled by a set of environmental factors such as climate, organisms, parent material and topography as well as time and space. A change of these factors will lead to a change in the spatial distribution of soil types. In this study, we use a digital soil mapping approach to improve our knowledge about major soil type distributing factors in the steppe regions of Inner Mongolia (China) which currently undergo tremendous environmental change, e.g. climate and land use change. We use Random Forests in an effort to map Reference Soil Groups according to the World Reference Base for Soil Resources (WRB) in the Xilin River catchment. We benefit from the superior prediction capabilities of RF and additional interpretive results in order to identify the major environmental factors that control spatial patterns of soil types. The nine WRB soil groups that were identified and spatially predicted for the study area are Arenosol, Calcisol, Cambisol, Chernozem, Cryosol, Gleysol, Kastanozem, Phaeozem and Regosol. Model and prediction performances of the RF model are high with an Out-of-Bag error of 51.6% for the model and a misclassification error for the predicted map of 28.9%. The main controlling factors of soil type distribution are land use, a set of topographic variables, geology and climate. However, land use and climate are of major importance and topography and geology are of minor importance. The visualizations of the predictions, the variable importance measures as result of RF and the comparisons of these with the spatial distribution of the environmental factors delivered additional, quantitative information of these controlling factors and revealed that intensively grazed areas are subjected to soil degradation. However, most of the area is still governed by natural soil forming processes which are driven by climate, topography and geology. Most importantly though, our study revealed that a shift towards warmer temperatures and lower precipitation regimes will lead to a change of the spatial distribution of RSGs towards steppe soils that store less carbon, i.e. a decrease of spatial extent of Phaeozems and an increase of spatial extent of Chernozems and Kastanozems. KW - Random Forests KW - Soil-environmental relationships KW - Steppe KW - Inner Mongolia KW - Land use change KW - Climate change Y1 - 2013 U6 - https://doi.org/10.1016/j.jaridenv.2012.08.004 SN - 0140-1963 VL - 88 IS - 1 SP - 194 EP - 205 PB - Elsevier CY - London ER - TY - JOUR A1 - Carregari, Victor Corasolla A1 - Floriano, Rafael Stuani A1 - Rodrigues-Simioni, Lea A1 - Winck, Flavia V. A1 - Baldasso, Paulo Aparecido A1 - Ponce-Soto, Luis Alberto A1 - Marangoni, Sergio T1 - Biochemical, Pharmacological, and Structural Characterization of New Basic PLA(2) Bbil-TX from Bothriopsis bilineata Snake Venom JF - BioMed research international N2 - Bbil-TX, a PLA(2), was purified from Bothriopsis bilineata snake venom after only one chromatographic step using RP-HPLC on mu-Bondapak C-18 column. A molecular mass of 14243.8 Da was confirmed by -Tof ltima API ESI/ MS (TOF MS mode) mass spectrometry. The partial protein sequence obtained was then submitted to BLASTp, with the search restricted to PLA(2) from snakes and shows high identity values when compared to other PLA(2)s. PLA(2) activity was presented in the presence of a synthetic substrate and showed a minimum sigmoidal behavior, reaching its maximal activity at pH 8.0 and 25-37 degrees C. Maximum PLA(2) activity required Ca2+ and in the presence of Cd2+, Zn2+, Mn2+, and Mg2+ it was reduced in the presence or absence of Ca2+. Crotapotin from Crotalus durissus cascavella rattlesnake venom and antihemorrhagic factor DA2-II from Didelphis albiventris opossum sera under optimal conditions significantly inhibit the enzymatic activity. Bbil-TX induces myonecrosis in mice. The fraction does not show a significant cytotoxic activity in myotubes and myoblasts (C2C12). The infiammatory events induced in the serum of mice by Bbil-TX isolated from Bothriopsis bilineata snake venom were investigated. An increase in vascular permeability and in the levels of TNF-a, IL-6, and IL-1 was was induced. Since Bbil-TX exerts a stronger proinfiammatory effect, the phospholipid hydrolysis may be relevant for these phenomena. Y1 - 2013 U6 - https://doi.org/10.1155/2013/612649 SN - 2314-6133 SN - 2314-6141 PB - Hindawi Publishing Corp. CY - New York ER - TY - JOUR A1 - Jaramillo-Vogel, David A1 - Strasser, Andre A1 - Frijia, Gianluca A1 - Spezzaferri, Silvia T1 - Neritic isotope and sedimentary records of the Eocene-Oligocene greenhouse-icehouse transition the Calcare di Nago Formation (northern Italy) in a global context JF - Palaeogeography, palaeoclimatology, palaeoecology : an international journal for the geo-sciences N2 - From the Middle Eocene to Early Oligocene, the Earth experienced the most significant climatic cooling of the Cenozoic era. The Eocene-Oligocene transition (EOT) represents the culmination of this climatic cooling, leading to the onset of the Antarctic glaciation and, consequently, to the beginning of the present-day icehouse world. Whereas the response of deep-sea systems to this climate transition has been widely studied, its impact on the shallow-water carbonate realm is poorly constrained. Here, the sedimentary expression of the EOT in two shallow-marine carbonate successions (Nago and San Valentino, northern Italy) belonging to the Calcare di Nago Formation is presented. The chronostratigraphic framework was constructed by integrating litho-, bio-, and isotope-stratigraphic data (C and Sr isotopes), allowing to correlate these shallow-marine successions with pelagic sections in central Italy (Massignano), Tanzania (TOP Sites 12 and 17), and the Indian Ocean (ODP Site 744). Within several sections in northern Italy, including Nago and San Valentino, a Priabonian (Late Eocene) transgression is recorded. Oxygen isotopes of ODP Site 744 show a coeval negative shift of 0.4 parts per thousand., suggesting a glacio-eustatic origin for this transgression. In the Nago and San Valentino sections, no prominent sequence boundary has been detected that would indicate a rapid sea-level drop occurring together with the positive shift in delta O-18 defining the EOT-1 cooling event. Instead, a gradual shallowing of the depositional environment is observed. At TDP Sites 12 and 17, the EOT-1 is followed by a negative shift in delta O-18 of around 0.4 parts per thousand, which correlates with a relative deepening of the environment in the studied sections and suggests a melting pulse between EOT-1 and the Oligocene isotope event 1 (Oi-1). The positive delta O-18 shift related to the Oi-1 translates in San Valentino into a change in carbonate factory from a photozoan association dominated by larger benthic foraminifera, corals, and red algae to a heterozoan association dominated by bryozoans. The same bryozoan fades occurs in several Italian localities near the Eocene-Oligocene boundary. This fades is interpreted to represent an analogue of modern cool-water carbonates and results from a cooling pulse of at least regional scale, associated to the Oi-1 event. KW - Eocene-Oligocene transition KW - Shallow-water carbonates KW - Carbon-isotope stratigraphy KW - Strontium-isotope stratigraphy KW - Sea-level changes Y1 - 2013 U6 - https://doi.org/10.1016/j.palaeo.2012.11.003 SN - 0031-0182 VL - 369 SP - 361 EP - 376 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Chaudhary, Tanja A1 - Walch, Elisabeth A1 - Herold, Birgit A1 - Metze, B. A1 - Lejeune, A. A1 - Burkhardt, F. A1 - Buehrer, C. T1 - Predictive and concurrent validity of standardized neurodevelopmental examinations by the griffiths scales and bayley scales of infant development II JF - Klinische Pädiatrie : clinical research and practice in pediatrics N2 - Background: Standardized examinations of preterm infants are used to identify candidates for early intervention. We aimed to assess the predictive power and concurrent validity of the mental development index of the Bayley scales of infant development II (Bayley MDI) and the Griffiths scales developmental quotient (Griffiths DQ) in healthy term and preterm infants < 1 500 g birth weight without major perinatal complications. Methods: 137 Infants (89 term, 48 preterm) were examined by both tests at a corrected age of 6, 12, and 22 months, and 114 went on to undergo Bayley assessments at 39 months. Results: There were significant correlations between Bayley and Griffiths results at 6, 12, and 22 months (r = 0.530, 0.714, and 0.833, respectively, p < 0.001) but Bland Altman plots revealed major systematic bias at 6 months (Griffiths > Bayley, mean differences 14.3 +/- 9.8) and 22 months (Bayley > Griffiths, mean difference 5.2 +/- 13.9) and wide 95% limits of agreement at 6, 12 and 22 months (35.9%, 40.0%, and 52.4%, respectively). The agreement for a presumptive diagnosis of developmental impairment in the group of preterm infants between Bayley examinations obtained at 39 months corrected age (reference) and previous examinations was poor at 6, 12, and 22 months for both Bayley and Griffiths (Cohen's kappa for Griffiths: 0.225, 0.192, 0.369; for Bayley: 0.121, 0.316, 0.369, respectively). Conclusion: Caution should be exercised when interpreting results from standardized neurodevelopmental examinations obtained during the first 2 years of life in comparatively well preterm infants. KW - very low birth weight infant KW - outcome KW - neurodevelopmental impairment Y1 - 2013 U6 - https://doi.org/10.1055/s-0032-1331169 SN - 0300-8630 VL - 225 IS - 1 SP - 8 EP - 12 PB - Thieme CY - Stuttgart ER - TY - JOUR A1 - Vicedo, Vicent A1 - Caus, Esmeralda A1 - Frijia, Gianluca T1 - Late Cretaceous alveolinaceans (larger foraminifera) of the Caribbean palaeobioprovince and their stratigraphic distribution JF - Journal of systematic palaeontology N2 - Architectural analysis of the Late Cretaceous alveolinaceans of the Caribbean palaeobioprovince has made it possible to separate four genera: Praechubbina, Chubbinella gen. nov., Chubbina and Caribalveolina. The first three genera belong to the family Rhapydioninidae, while the fourth is placed in the family Alveolinidae. Two species, Praechubbina breviclaustra and P. oxchucensis sp. nov., represent the primitive genus Praechubbina, while the species cardenasensis and obesa, previously ascribed to this genus, must be reassigned respectively to Chubbinella gen. nov. and Caribalveolina. The species Chubbina jamaicensis, C. macgillavryi and C. fourcadei sp. nov. complete the inventory of Chubbina. The alveolinid genus Caribalveolina comprises two species, C. obesa and C. michaudi. Caribbean alveolinaceans include two successive assemblages. The lower assemblage is characterized by Praechubbina oxchucensis, P. brevisclaustra, Chubbinella cardenasensis and Caribalveolina obesa. The upper assemblage is represented by the genus Chubbina, with C. fourcadei, C. jamaicensis and C. macgillavryi, and Caribalveolina michaudi. The age of the lower assemblage is uncertain (probably Late CampanianEarly Maastrichtian), while the upper assemblage has been dated by strontium isotope stratigraphy as Late Maastrichtian. KW - alveolinaceans KW - larger foraminifera KW - shell-architecture KW - Caribbean KW - biostratigraphy KW - Sr-isotope stratigraphy Y1 - 2013 U6 - https://doi.org/10.1080/14772019.2011.637517 SN - 1477-2019 VL - 11 IS - 1 SP - 1 EP - 25 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Czerwon, Beate A1 - Hohlfeld, Annette A1 - Wiese, Heike A1 - Werheid, Katja T1 - Syntactic structural parallelisms influence processing of positive stimuli evidence from cross-modal ERP priming JF - International journal of psychophysiology N2 - Language can strongly influence the emotional state of the recipient. In contrast to the broad body of experimental and neuroscientific research on semantic information and prosodic speech, the emotional impact of grammatical structure has rarely been investigated. One reason for this might be, that measuring effects of syntactic structure involves the use of complex stimuli, for which the emotional impact of grammar is difficult to isolate. In the present experiment we examined the emotional impact of structural parallelisms, that is, repetitions of syntactic features, on the emotion-sensitive "late positive potential" (LPP) with a cross-modal priming paradigm. Primes were auditory presented nonsense sentences which included grammatical-syntactic parallelisms. Visual targets were positive, neutral, and negative faces, to be classified as emotional or non-emotional by the participants. Electrophysiology revealed diminished LPP amplitudes for positive faces following parallel primes. Thus, our findings suggest that grammatical structure creates an emotional context that facilitates processing of positive emotional information. KW - Language KW - Emotion KW - Priming KW - ERP KW - Late positive potential KW - Structural parallelisms Y1 - 2013 U6 - https://doi.org/10.1016/j.ijpsycho.2012.10.014 SN - 0167-8760 SN - 1872-7697 VL - 87 IS - 1 SP - 28 EP - 34 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Marwan, Norbert A1 - Schinkel, Stefan A1 - Kurths, Jürgen T1 - Recurrence plots 25 years later -Gaining confidence in dynamical transitions JF - epl : a letters journal exploring the frontiers of physics N2 - Recurrence-plot-based time series analysis is widely used to study changes and transitions in the dynamics of a system or temporal deviations from its overall dynamical regime. However, most studies do not discuss the significance of the detected variations in the recurrence quantification measures. In this letter we propose a novel method to add a confidence measure to the recurrence quantification analysis. We show how this approach can be used to study significant changes in dynamical systems due to a change in control parameters, chaos-order as well as chaos-chaos transitions. Finally we study and discuss climate transitions by analysing a marine proxy record for past sea surface temperature. This paper is dedicated to the 25th anniversary of the introduction of recurrence plots. Y1 - 2013 U6 - https://doi.org/10.1209/0295-5075/101/20007 SN - 0295-5075 VL - 101 IS - 2 PB - EDP Sciences CY - Mulhouse ER - TY - JOUR A1 - Zerbian, Sabine T1 - Prosodic marking of narrow focus across varieties of South African English JF - English world-wide : a journal of varieties of English N2 - This paper reports on an elicited production study which investigates prosodic marking of narrow focus in modified noun phrases in varieties of South African English. The acoustic analysis of fundamental frequency, intensity, and duration in narrow focus is presented and discussed. The results suggest that these three acoustic parameters are manipulated differently in narrow focus in the varieties of English as a Second Language as compared to General South African English. The article compares the results to what is known about prosodic marking of information structure in other varieties of English as a Second Language and underlines the necessity of carefully controlled data in the investigation of phonological and phonetic variation in varieties of English. KW - South African English KW - Black South African English KW - English as a Second Language (ESL) KW - prosody KW - focus KW - fundamental frequency KW - intensity KW - duration KW - contact variety Y1 - 2013 U6 - https://doi.org/10.1075/eww.34.1.02zer SN - 0172-8865 VL - 34 IS - 1 SP - 26 EP - 47 PB - Benjamins CY - Amsterdam ER - TY - JOUR A1 - Elsner, Birgit A1 - Jeschonek, Susanna A1 - Pauen, Sabina T1 - Event-related potentials for 7-month-olds' processing of animals and furniture items JF - Developmental cognitive neuroscience : a journal for cognitive, affective and social developmental neuroscience N2 - Event-related potentials (ERPs) to single visual stimuli were recorded in 7-month-old infants. In a three-stimulus oddball paradigm, infants watched one frequently occurring standard stimulus (either an animal or a furniture item) and two infrequently occurring oddball stimuli, presenting one exemplar from the same and one from the different super-ordinate category as compared to the standard stimulus. Additionally, visual attributes of the stimuli were controlled to investigate whether infants focus on category membership or on perceptual similarity when processing the stimuli. Infant ERPs indicated encoding of the standard stimulus and discriminating it from the two oddball stimuli by larger Nc peak amplitude and late-slow-wave activity for the infrequent stimuli. Moreover, larger Nc latency and positive-slow-wave activity indicated increased processing for the different-category as compared to the same-category oddball. Thus, 7-month-olds seem to encode single stimuli not only by surface perceptual features, but they also regard information of category membership, leading to facilitated processing of the oddball that belongs to the same domain as the standard stimulus. KW - Category identification KW - Infants (age: 7 months) KW - Event-related potentials KW - Visual stimulus processing KW - Recognition memory Y1 - 2013 U6 - https://doi.org/10.1016/j.dcn.2012.09.002 SN - 1878-9293 VL - 3 IS - 1 SP - 53 EP - 60 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Thiel, Kerstin A1 - Zehbe, Rolf A1 - Röser, Jerome A1 - Strauch, Peter A1 - Enthaler, Stephan A1 - Thomas, Arne T1 - A polymer analogous reaction for the formation of imidazolium and NHC based porous polymer networks JF - Polymer Chemistry N2 - A polymer analogous reaction was carried out to generate a porous polymeric network with N-heterocyclic carbenes (NHC) in the polymer backbone. Using a stepwise approach, first a polyimine network is formed by polymerization of the tetrafunctional amine tetrakis(4-aminophenyl)methane. This polyimine network is converted in the second step into polyimidazolium chloride and finally to a polyNHC network. Furthermore a porous Cu(II)-coordinated polyNHC network can be generated. Supercritical drying generates polymer networks with high permanent surface areas and porosities which can be applied for different catalytic reactions. The catalytic properties were demonstrated for example in the activation of CO2 or in the deoxygenation of sulfoxides to the corresponding sulfides. Y1 - 2013 U6 - https://doi.org/10.1039/c2py20947k SN - 1759-9954 VL - 4 IS - 6 SP - 1848 EP - 1856 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Palm, Juliane A1 - van Schaik, N. Loes M. B. A1 - Schröder-Esselbach, Boris T1 - Modelling distribution patterns of anecic, epigeic and endogeic earthworms at catchment-scale in agro-ecosystems JF - Pedobiologia : international journal of soil biology N2 - Species distribution models are useful for identifying driving environmental factors that determine earthworm distributions as well as for predicting earthworm distribution patterns and abundances at different scales. However, due to large efforts in data acquisition, studies on larger scales are rare and often focus on single species or earthworms in general. In this study, we use boosted regression tree models (BRTs) for predicting the distribution of the three functional earthworm types, i.e. anecics, endogeics and epigeics, in an agricultural area in Baden-Wurttemberg (Southwest Germany). First, we predicted presence and absence and later earthworm abundances, considering predictors depicting land management, topography, and soil conditions as well as biotic interaction by using the abundance of the other functional earthworm types. The final presence-absence models performed reasonably well, with explained deviances between 24 and 51% after crossvalidation. Models for abundances of anecics and endogeics were less successful, since the high small-scale variability and patchiness in earthworm abundance influenced the representativeness of the field measurements. This resulted in a significant model uncertainty, which is practically very difficult to overcome with earthworm sampling campaigns at the catchment scale. Results showed that management practices (i.e. disturbances), topography, soil conditions, and biotic interactions with other earthworm groups are the most relevant predictors for spatial distribution (incidence) patterns of all three functional groups. The response curves and contributions of predictors differ for the three functional earthworm types. Epigeics are also controlled by topographic features, endogeics by soil parameters. KW - Species distribution models KW - Earthworms KW - Soil hydrology KW - Boosted regression trees (BRT) KW - Distribution patterns KW - Biotic interactions Y1 - 2013 U6 - https://doi.org/10.1016/j.pedobi.2012.08.007 SN - 0031-4056 VL - 56 IS - 1 SP - 23 EP - 31 PB - Elsevier CY - Jena ER - TY - JOUR A1 - Granacher, Urs A1 - Lacroix, Andre A1 - Mühlbauer, Thomas A1 - Röttger, Katrin A1 - Gollhofer, Albert T1 - Effects of core instability strength training on trunk muscle strength, spinal mobility, dynamic balance and functional mobility in older adults JF - Gerontology N2 - Background: Age-related postural misalignment, balance deficits and strength/power losses are associated with impaired functional mobility and an increased risk of falling in seniors. Core instability strength training (CIT) involves exercises that are challenging for both trunk muscles and postural control and may thus have the potential to induce benefits in trunk muscle strength, spinal mobility and balance performance. Objective: The objective was to investigate the effects of CIT on measures of trunk muscle strength, spinal mobility, dynamic balance and functional mobility in seniors. Methods: Thirty-two older adults were randomly assigned to an intervention group (INT; n = 16, aged 70.8 +/- 4.1 years) that conducted a 9-week progressive CIT or to a control group (n = 16, aged 70.2 +/- 4.5 years). Maximal isometric strength of the trunk flexors/extensors/lateral flexors (right, left)/rotators (right, left) as well as of spinal mobility in the sagittal and the coronal plane was measured before and after the intervention program. Dynamic balance (i.e. walking 10 m on an optoelectric walkway, the Functional Reach test) and functional mobility (Timed Up and Go test) were additionally tested. Results: Program compliance was excellent with participants of the INT group completing 92% of the training sessions. Significant group x test interactions were found for the maximal isometric strength of the trunk flexors (34%, p < 0.001), extensors (21%, p < 0.001), lateral flexors (right: 48%, p < 0.001; left: 53%, p < 0.001) and left rotators (42%, p < 0.001) in favor of the INT group. Further, training-related improvements were found for spinal mobility in the sagittal (11%, p < 0.001) and coronal plane (11%, p = 0.06) directions, for stride velocity (9%, p < 0.05), the coefficient of variation in stride velocity (31%, p < 0.05), the Functional Reach test (20%, p < 0.05) and the Timed Up and Go test (4%, p < 0.05) in favor of the INT group. Conclusion: CIT proved to be a feasible exercise program for seniors with a high adherence rate. Age-related deficits in measures of trunk muscle strength, spinal mobility, dynamic balance and functional mobility can be mitigated by CIT. This training regimen could be used as an adjunct or even alternative to traditional balance and/or resistance training. KW - Elderly KW - Gait KW - Muscle strength KW - Physical performance KW - Postural balance Y1 - 2013 U6 - https://doi.org/10.1159/000343152 SN - 0304-324X VL - 59 IS - 2 SP - 105 EP - 113 PB - Karger CY - Basel ER - TY - JOUR A1 - Peitsch, Helmut T1 - Literature as a public Defense of the Right of Criticism To F. C. Delius' Documentary polemic "We Entrepreneurs" JF - Text + Kritik : Zeitschrift für Literatur Y1 - 2013 SN - 0040-5329 IS - 197 SP - 44 EP - 54 PB - Edition Text + Kritik im Richard Boorberg Verlag GmbH & Co KG CY - München ER - TY - JOUR A1 - Menzel, Ralf A1 - Heuer, Axel A1 - Puhlmann, Dirk A1 - Dechoum, K. A1 - Hillery, M. A1 - Spaehn, M. J. A. A1 - Schleich, W. P. T1 - A two-photon double-slit experiment JF - Journal of modern optics N2 - We employ a photon pair created by spontaneous parametric down conversion (SPDC) where the pump laser is in the TEM01 mode to perform a Young's double-slit experiment. The signal photon illuminates the two slits and displays interference fringes in the far-field while the idler photon measured in the near-field in coincidence with the signal photon provides us with which-slit' information. We explain the results of these experiments with the help of an analytical expression for the second-order correlation function derived from an elementary model of SPDC. Our experiment emphasizes the crucial role of the mode function in the quantum theory of radiation. KW - complementarity KW - wave-particle dualism KW - Young's double-slit experiment KW - spontaneous parametric down conversion KW - TEM01 mode Y1 - 2013 U6 - https://doi.org/10.1080/09500340.2012.746400 SN - 0950-0340 VL - 60 IS - 1 SP - 86 EP - 94 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Messerschmidt, Katrin A1 - Heilmann, Katja T1 - Toxin-antigen conjugates as selection tools for antibody producing cells JF - Journal of immunological methods N2 - The generation of antibodies with designated specificity requires cost-intensive and time-consuming screening procedures. Here we present a new method by which hybridoma cells can be selected based on the specificity of the produced antibody by the use of antigen-toxin-conjugates thus eliminating the need of a screening procedure. Initial experiments were done with methotrexate as low molecular weight toxin and fluorescein as model antigen. Methotrexate and a methotrexate-fluorescein conjugate were characterized regarding their toxicity. Afterwards the effect of the fluorescein-specific antibody B13-DE1 on the toxicity of the methotrexate-fluorescein conjugate was determined. Finally, first results showed that hybridoma cells that produce fluorescein specific antibodies are able to grow in the presence of fluorescein-toxin-conjugates. KW - Monoclonal antibody KW - Hybridoma technology KW - Selection of antibody producing cells Y1 - 2013 U6 - https://doi.org/10.1016/j.jim.2012.10.010 SN - 0022-1759 VL - 387 IS - 1-2 SP - 167 EP - 172 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Clahsen, Harald A1 - Balkhair, Loay A1 - Schutter, John-Sebastian A1 - Cunnings, Ian T1 - The time course of morphological processing in a second language JF - Second language research N2 - We report findings from psycholinguistic experiments investigating the detailed timing of processing morphologically complex words by proficient adult second (L2) language learners of English in comparison to adult native (L1) speakers of English. The first study employed the masked priming technique to investigate -ed forms with a group of advanced Arabic-speaking learners of English. The results replicate previously found L1/L2 differences in morphological priming, even though in the present experiment an extra temporal delay was offered after the presentation of the prime words. The second study examined the timing of constraints against inflected forms inside derived words in English using the eye-movement monitoring technique and an additional acceptability judgment task with highly advanced Dutch L2 learners of English in comparison to adult L1 English controls. Whilst offline the L2 learners performed native-like, the eye-movement data showed that their online processing was not affected by the morphological constraint against regular plurals inside derived words in the same way as in native speakers. Taken together, these findings indicate that L2 learners are not just slower than native speakers in processing morphologically complex words, but that the L2 comprehension system employs real-time grammatical analysis (in this case, morphological information) less than the L1 system. KW - compounds KW - derivational morphology KW - English as a seond language KW - inflectional morphology KW - late bilinguals KW - masked priming KW - morphology processing KW - past tense KW - shallow structure hypothesis Y1 - 2013 U6 - https://doi.org/10.1177/0267658312464970 SN - 0267-6583 VL - 29 IS - 1 SP - 7 EP - 31 PB - Sage Publ. CY - London ER - TY - JOUR A1 - Pfestorf, H. A1 - Weiss, L. A1 - Müller, J. A1 - Boch, Steffen A1 - Socher, S. A. A1 - Prati, Daniel A1 - Schöning, Ingo A1 - Weisser, W. A1 - Fischer, M. A1 - Jeltsch, Florian T1 - Community mean traits as additional indicators to monitor effects of land-use intensity On grassland plant diversity JF - Perspectives in plant ecology, evolution and systematics N2 - Semi-natural grasslands, biodiversity hotspots in Central-Europe, suffer from the cessation of traditional land-use. Amount and intensity of these changes challenge current monitoring frameworks typically based on classic indicators such as selected target species or diversity indices. Indicators based on plant functional traits provide an interesting extension since they reflect ecological strategies at individual and ecological processes at community levels. They typically show convergent responses to gradients of land-use intensity over scales and regions, are more directly related to environmental drivers than diversity components themselves and enable detecting directional changes in whole community dynamics. However, probably due to their labor- and cost intensive assessment in the field, they have been rarely applied as indicators so far. Here we suggest overcoming these limitations by calculating indicators with plant traits derived from online accessible databases. Aiming to provide a minimal trait set to monitor effects of land-use intensification on plant diversity we investigated relationships between 12 community mean traits, 2 diversity indices and 6 predictors of land-use intensity within grassland communities of 3 different regions in Germany (part of the German 'Biodiversity Exploratory' research network). By standardization of traits and diversity measures, use of null models and linear mixed models we confirmed (i) strong links between functional community composition and plant diversity, (ii) that traits are closely related to land-use intensity, and (iii) that functional indicators are equally, or even more sensitive to land-use intensity than traditional diversity indices. The deduced trait set consisted of 5 traits, i.e., specific leaf area (SLA), leaf dry matter content (LDMC), seed release height, leaf distribution, and onset of flowering. These database derived traits enable the early detection of changes in community structure indicative for future diversity loss. As an addition to current monitoring measures they allow to better link environmental drivers to processes controlling community dynamics. KW - Biodiversity Exploratories KW - Biological conservation KW - (Semi-natural) Grasslands KW - Plant functional traits KW - Indicators KW - Land-use intensity Y1 - 2013 U6 - https://doi.org/10.1016/j.ppees.2012.10.003 SN - 1433-8319 VL - 15 IS - 1 SP - 1 EP - 11 PB - Elsevier CY - Jena ER - TY - JOUR A1 - Dormann, Carsten F. A1 - Elith, Jane A1 - Bacher, Sven A1 - Buchmann, Carsten M. A1 - Carl, Gudrun A1 - Carre, Gabriel A1 - Garcia Marquez, Jaime R. A1 - Gruber, Bernd A1 - Lafourcade, Bruno A1 - Leitao, Pedro J. A1 - Münkemüller, Tamara A1 - McClean, Colin A1 - Osborne, Patrick E. A1 - Reineking, Bjoern A1 - Schröder-Esselbach, Boris A1 - Skidmore, Andrew K. A1 - Zurell, Damaris A1 - Lautenbach, Sven T1 - Collinearity a review of methods to deal with it and a simulation study evaluating their performance JF - Ecography : pattern and diversity in ecology ; research papers forum N2 - Collinearity refers to the non independence of predictor variables, usually in a regression-type analysis. It is a common feature of any descriptive ecological data set and can be a problem for parameter estimation because it inflates the variance of regression parameters and hence potentially leads to the wrong identification of relevant predictors in a statistical model. Collinearity is a severe problem when a model is trained on data from one region or time, and predicted to another with a different or unknown structure of collinearity. To demonstrate the reach of the problem of collinearity in ecology, we show how relationships among predictors differ between biomes, change over spatial scales and through time. Across disciplines, different approaches to addressing collinearity problems have been developed, ranging from clustering of predictors, threshold-based pre-selection, through latent variable methods, to shrinkage and regularisation. Using simulated data with five predictor-response relationships of increasing complexity and eight levels of collinearity we compared ways to address collinearity with standard multiple regression and machine-learning approaches. We assessed the performance of each approach by testing its impact on prediction to new data. In the extreme, we tested whether the methods were able to identify the true underlying relationship in a training dataset with strong collinearity by evaluating its performance on a test dataset without any collinearity. We found that methods specifically designed for collinearity, such as latent variable methods and tree based models, did not outperform the traditional GLM and threshold-based pre-selection. Our results highlight the value of GLM in combination with penalised methods (particularly ridge) and threshold-based pre-selection when omitted variables are considered in the final interpretation. However, all approaches tested yielded degraded predictions under change in collinearity structure and the folk lore'-thresholds of correlation coefficients between predictor variables of |r| >0.7 was an appropriate indicator for when collinearity begins to severely distort model estimation and subsequent prediction. The use of ecological understanding of the system in pre-analysis variable selection and the choice of the least sensitive statistical approaches reduce the problems of collinearity, but cannot ultimately solve them. Y1 - 2013 U6 - https://doi.org/10.1111/j.1600-0587.2012.07348.x SN - 0906-7590 SN - 1600-0587 VL - 36 IS - 1 SP - 27 EP - 46 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Jekauc, Darko A1 - Wagner, Matthias O. A1 - Kahlert, Daniela A1 - Woll, Alexander T1 - Reliability and validity of MoMo-Physical-Activity-Questionnaire for Adolescents (MoMo-AFB) JF - Diagnostica N2 - This paper presents the psychometric properties of the MoMo-AFB (Bos, Worth, Opper, Oberger & Woll, 2009), a questionnaire designed to measure the physical activity of children and adolescents. The MoMo-AFB consists of 28 items, covering the fields of everyday physical activity, sports within and outside of organised clubs, physical education as well as compliance with physical activity guidelines. A study was conducted with 109 boys and 87 girls aged between 9 and 17 years. The MoMo-AFB was given on two separate occasions to evaluate reliability and was compared with accelerometry data of ActiGraph GT1X to evaluate validity. The overall kappa/weighted kappa coefficient for the one-week testretest reliability was .66 (SD = .19) and the overall intraclass correlation (ICC) .68. Self-reported and accelerometer-measured average weekly time spent performing moderate to vigorous physical activity were significantly correlated (Spearman r = .29). Regarding reliability and validity, the MoMo-AFB is comparable with other international published physical activity questionnaires for adolescents. KW - physical activity KW - physical activity questionnaire KW - MoMo-AFB KW - adolescents Y1 - 2013 U6 - https://doi.org/10.1026/0012-1924/a000083 SN - 0012-1924 VL - 59 IS - 2 SP - 100 EP - 111 PB - Hogrefe CY - Göttingen ER - TY - JOUR A1 - Uhlemann, S. A1 - Bertelmann, Roland A1 - Merz, Bruno T1 - Data expansion the potential of grey literature for understanding floods JF - Hydrology and earth system sciences : HESS N2 - Sophisticated methods have been developed and become standard in analysing floods as well as for assessing flood risk. However, increasingly critique of the current standards and scientific practice can be found both in the flood hydrology community as well as in the risk community who argue that the considerable amount of information already available on natural disasters has not been adequately deployed and brought to effective use. We describe this phenomenon as a failure to synthesize knowledge that results from barriers and ignorance in awareness, use and management of the entire spectrum of relevant content, that is, data, information and knowledge. In this paper we argue that the scientific community in flood risk research ignores event-specific analysis and documentations as another source of data. We present results from a systematic search that includes an intensive study on sources and ways of information dissemination of flood-relevant publications. We obtain 186 documents that contain information on the sources, pathways, receptors and/or consequences for any of the 40 strongest trans-basin floods in Germany in the period 1952-2002. This study therefore provides the most comprehensive metadata collection of flood documentations for the considered geographical space and period. A total of 87.5% of all events have been documented, and especially the most severe floods have received extensive coverage. Only 30% of the material has been produced in the scientific/academic environment, and the majority of all documents (about 80%) can be considered grey literature (i.e. literature not controlled by commercial publishers). Therefore, ignoring grey sources in flood research also means ignoring the largest part of knowledge available on single flood events (in Germany). Further, the results of this study underpin the rapid changes in information dissemination of flood event literature over the last decade. We discuss the options and obstacles of incorporating this data into the knowledge-building process in light of the current technological developments and international, interdisciplinary debates for data curation. Y1 - 2013 U6 - https://doi.org/10.5194/hess-17-895-2013 SN - 1027-5606 VL - 17 IS - 3 SP - 895 EP - 911 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Heistermann, Maik A1 - Jacobi, S. A1 - Pfaff, T. T1 - Technical note an open source library for processing weather radar data (wradlib) JF - Hydrology and earth system sciences : HESS N2 - The potential of weather radar observations for hydrological and meteorological research and applications is undisputed, particularly with increasing world-wide radar coverage. However, several barriers impede the use of weather radar data. These barriers are of both scientific and technical nature. The former refers to inherent measurement errors and artefacts, the latter to aspects such as reading specific data formats, geo-referencing, visualisation. The radar processing library wradlib is intended to lower these barriers by providing a free and open source tool for the most important steps in processing weather radar data for hydro-meteorological and hydrological applications. Moreover, the community-based development approach of wradlib allows scientists to share their knowledge about efficient processing algorithms and to make this knowledge available to the weather radar community in a transparent, structured and well-documented way. Y1 - 2013 U6 - https://doi.org/10.5194/hess-17-863-2013 SN - 1027-5606 VL - 17 IS - 2 SP - 863 EP - 871 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Koppitz, Jörg A1 - Supaporn, Worakrit T1 - Categary equivalences of clones of operations preserving unaryoperations JF - COMPTES RENDUS DE L ACADEMIE BULGARE DES SCIENCES N2 - Any clones on arbitrary set A can be written of the form Pol (A)Q for some set Q of relations on A. We consider clones of the form Pal (A)Q where Q is a set of unary relations on a finite set A. A clone Pol (A)Q is said to be a clone on a set of the smallest cardinality with respect to category equivalence if vertical bar A vertical bar <= vertical bar S vertical bar for all finite sets S and all clones C on S that category equivalent to Pol (A)Q. We characterize the clones on a set of the smallest cardinality with respect to category equivalent and show how we can find a clone on a set of the smallest cardinality that category equivalent to a given clone. KW - category equivalence of clones KW - clone of operations Y1 - 2013 SN - 1310-1331 VL - 66 IS - 2 SP - 177 EP - 184 PB - Publ. House of the Bulgarian Acad. of Sciences CY - Sofia ER - TY - JOUR A1 - Simal Duran, Juan Luis T1 - An Atlantic perspective for Spanish history in the age of revolutions JF - Ayer : revista de historia contemporánea N2 - This bibliographical essay seeks to evaluate the impact that the historiographical trend known as Atlantic history, which emerged in the Anglo-Saxon academia, has had on the Spanish-American one. It also considers the criticisms and reticence that it has triggered. The analysis focuses on the applicability and relevance as an analytical tool for the Spanish case of the concept of Atlantic revolutions. It also wants to assess the benefits that geographically broad approaches -even beyond the Atlantic- present to nineteenth-century Spanish historiography. KW - Atlantic History KW - Transnational History KW - Global History KW - Age of Revolutions KW - Spain Y1 - 2013 SN - 1134-2277 IS - 89 SP - 199 EP - 212 PB - Asociación de Historia Contemporánea CY - Madrid ER - TY - JOUR A1 - Hickmann, Thomas T1 - Private authority in global climate governance the case of the clean development mechanism JF - Climate & development N2 - The Clean Development Mechanism (CDM) is a prominent example of the mix of public and private authority in global climate policy-making. While national governments hold the supreme authority in the CDM, the oversight and daily supervision of the project-based mechanism have been delegated via an intergovernmental body to private corporations that evaluate the environmental performance of individual CDM projects. By focusing on the CDM as a particular instance of private authority in global climate governance, this article analyses the consequences associated with the delegation of authority to private actors. The article critically assesses the role of private auditing corporations, labelled Designated Operational Entities, in the regulatory framework of the CDM and points to serious trade-offs which accompany the privatisation of authority. The article's findings suggest that the promise of innovative modes of governance to increase the effectiveness of international regulation is seriously compromised by the profit-seeking behaviour of private actors. Hence, the article underscores the need to reconsider the balance between public and private authority in global (climate) governance. KW - carbon markets KW - Clean Development Mechanism KW - climate policy KW - global climate governance KW - post-2012 negotiations KW - private authority Y1 - 2013 U6 - https://doi.org/10.1080/17565529.2013.768174 SN - 1756-5529 VL - 5 IS - 1 SP - 46 EP - 54 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Ballato, Paolo A1 - Stockli, Daniel F. A1 - Ghassemi, Mohammad R. A1 - Landgraf, Angela A1 - Strecker, Manfred A1 - Hassanzadeh, Jamshid A1 - Friedrich, Anke M. A1 - Tabatabaei, Saeid H. T1 - Accommodation of transpressional strain in the Arabia-Eurasia collision zone new constraints from (U-Th)/He thermochronology in the Alborz mountains, north Iran JF - Tectonics N2 - The Alborz range of N Iran provides key information on the spatiotemporal evolution and characteristics of the Arabia-Eurasia continental collision zone. The southwestern Alborz range constitutes a transpressional duplex, which accommodates oblique shortening between Central Iran and the South Caspian Basin. The duplex comprises NW-striking frontal ramps that are kinematically linked to inherited E-W-striking, right-stepping lateral to obliquely oriented ramps. New zircon and apatite (U-Th)/He data provide a high-resolution framework to unravel the evolution of collisional tectonics in this region. Our data record two pulses of fast cooling associated with SW-directed thrusting across the frontal ramps at similar to 18-14 and 9.5-7.5 Ma, resulting in the tectonic repetition of a fossil zircon partial retention zone and a cooling pattern with a half U-shaped geometry. Uniform cooling ages of similar to 7-6 Ma along the southernmost E-W striking oblique ramp and across its associated NW-striking frontal ramps suggests that the ramp was reactivated as a master throughgoing, N-dipping thrust. We interpret this major change in fault kinematics and deformation style to be related to a change in the shortening direction from NE to N/NNE. The reduction in the obliquity of thrusting may indicate the termination of strike-slip faulting (and possibly thrusting) across the Iranian Plateau, which could have been triggered by an increase in elevation. Furthermore, we suggest that similar to 7-6-m.y.-old S-directed thrusting predated inception of the westward motion of the South Caspian Basin. Citation: Ballato, P., D. F. Stockli, M. R. Ghassemi, A. Landgraf, M. R. Strecker, J. Hassanzadeh, A. Friedrich, and S. H. Tabatabaei (2012), Accommodation of transpressional strain in the Arabia-Eurasia collision zone: new constraints from (U-Th)/He thermochronology in the Alborz mountains. Y1 - 2013 U6 - https://doi.org/10.1029/2012TC003159 SN - 0278-7407 VL - 32 IS - 1 SP - 1 EP - 18 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Heistermann, Maik A1 - Crisologo, Irene A1 - Abon, Catherine Cristobal A1 - Racoma, B. A. A1 - Jacobi, S. A1 - Servando, N. T. A1 - David, C. P. C. A1 - Bronstert, Axel T1 - Using the new Philippine radar network to reconstruct the Habagat of August 2012 monsoon event around Metropolitan Manila JF - Natural hazards and earth system sciences N2 - From 6 to 9 August 2012, intense rainfall hit the northern Philippines, causing massive floods in Metropolitan Manila and nearby regions. Local rain gauges recorded almost 1000mm within this period. However, the recently installed Philippine network of weather radars suggests that Metropolitan Manila might have escaped a potentially bigger flood just by a whisker, since the centre of mass of accumulated rainfall was located over Manila Bay. A shift of this centre by no more than 20 km could have resulted in a flood disaster far worse than what occurred during Typhoon Ketsana in September 2009. Y1 - 2013 U6 - https://doi.org/10.5194/nhess-13-653-2013 SN - 1561-8633 VL - 13 IS - 3 SP - 653 EP - 657 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Dobler, C. A1 - Bürger, Gerd A1 - Stötter, J. T1 - Simulating future precipitation extremes in a complex Alpine catchment JF - Natural hazards and earth system sciences N2 - The objectives of the present investigation are (i) to study the effects of climate change on precipitation extremes and (ii) to assess the uncertainty in the climate projections. The investigation is performed on the Lech catchment, located in the Northern Limestone Alps. In order to estimate the uncertainty in the climate projections, two statistical downscaling models as well as a number of global and regional climate models were considered. The downscaling models applied are the Expanded Downscaling (XDS) technique and the Long Ashton Research Station Weather Generator (LARS-WG). The XDS model, which is driven by analyzed or simulated large-scale synoptic fields, has been calibrated using ECMWF-interim reanalysis data and local station data. LARS-WG is controlled through stochastic parameters representing local precipitation variability, which are calibrated from station data only. Changes in precipitation mean and variability as simulated by climate models were then used to perturb the parameters of LARS-WG in order to generate climate change scenarios. In our study we use climate simulations based on the A1B emission scenario. The results show that both downscaling models perform well in reproducing observed precipitation extremes. In general, the results demonstrate that the projections are highly variable. The choice of both the GCM and the downscaling method are found to be essential sources of uncertainty. For spring and autumn, a slight tendency toward an increase in the intensity of future precipitation extremes is obtained, as a number of simulations show statistically significant increases in the intensity of 90th and 99th percentiles of precipitation on wet days as well as the 5- and 20-yr return values. Y1 - 2013 U6 - https://doi.org/10.5194/nhess-13-263-2013 SN - 1561-8633 VL - 13 IS - 2 SP - 263 EP - 277 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Kleger, Heinz A1 - Mehlhausen, Thomas T1 - Indisputable and still disputed - European solidarity during the Euro crisis JF - Politische Vierteljahresschrift : Zeitschrift der Deutschen Vereinigung für Politische Wissenschaft N2 - The term solidarity is lacking a precise definition despite being embedded as primary law in the EU treaties and regardless of its pivotal role in the current debate on the euro crisis. Once the semantic core is unearthed we sketch three dimensions of European solidarity (motives, references, level of action). Through this we shall distil three ideal types of an intergovernmental European solidarity: a federal, an organic and a distributive type. Empirically we assign the most relevant measures, which were discussed and partially enacted in the course of the euro crisis, to the three ideal types where we identify an increasing tendency towards a distributive solidarity. Once the first elements will be upgraded to a full-blown distributive solidarity through further integration, several risks arise from a normative perspective. KW - Solidarity KW - Euro Crisis KW - European Union KW - Democracy KW - Justice Y1 - 2013 SN - 0032-3470 VL - 54 IS - 1 SP - 50 EP - 74 PB - Nomos CY - Hannover ER - TY - JOUR A1 - Kröller, Katja A1 - Kröller, Alexander A1 - Warschburger, Petra T1 - What do you like to eat? Correlation between food familiarity and actual preference JF - Zeitschrift für Gesundheitspsychologie N2 - The preference for fruits and vegetables is the main predictor for the longtime healthy eating behavior. There are many factors which affect the development of food preferences. The familiarity with different foods seems to be a special aspect associated with the corresponding preference. To establish a preference for fruits and vegetables during early childhood, we need to know more about the factors that affect this preference development. So far, research has mostly concentrated on the food intake and less on the corresponding preference. Additionally, it is often based on studies of the mere-exposure effect or on older children and their ability to label fruits and vegetables correctly. Findings about the level of food familiarity in young children and its relation to the actual food preference are still missing. Our study focuses on different aspects of food familiarity as well as on their relationship to the child's preference and presents results from 213 children aged 2 to 10 years. Using standardized photos, the food preference was measured with a computer-based method that ran automatically without influence from parents or interviewer. The children knew fewer of the presented vegetables (66 %) than fruits or sweets (78 % each). About the same number of vegetables (63 %) had already been tasted by the children and were considered tasty. Only 48 % of the presented vegetables were named correctly - an ability that increases in older children. Concerning the relationship between the familiarity with vegetables and their preference, the different familiarity aspects showed that vegetables of lower preference were less often recognized, tasted, considered tasty, or named correctly. KW - food preference KW - familiarity KW - fruits and vegetables KW - children Y1 - 2013 U6 - https://doi.org/10.1026/0943-8149/a000089 SN - 0943-8149 VL - 21 IS - 2 SP - 53 EP - 61 PB - Hogrefe CY - Göttingen ER - TY - JOUR A1 - Goychuk, I. A1 - Kharchenko, V. O. T1 - Rocking subdiffusive ratchets origin, optimization and efficiency JF - Mathematical modelling of natural phenomena N2 - We study origin, parameter optimization, and thermodynamic efficiency of isothermal rocking ratchets based on fractional subdiffusion within a generalized non-Markovian Langevin equation approach. A corresponding multi-dimensional Markovian embedding dynamics is realized using a set of auxiliary Brownian particles elastically coupled to the central Brownian particle (see video on the journal web site). We show that anomalous subdiffusive transport emerges due to an interplay of nonlinear response and viscoelastic effects for fractional Brownian motion in periodic potentials with broken space-inversion symmetry and driven by a time-periodic field. The anomalous transport becomes optimal for a subthreshold driving when the driving period matches a characteristic time scale of interwell transitions. It can also be optimized by varying temperature, amplitude of periodic potential and driving strength. The useful work done against a load shows a parabolic dependence on the load strength. It grows sublinearly with time and the corresponding thermodynamic efficiency decays algebraically in time because the energy supplied by the driving field scales with time linearly. However, it compares well with the efficiency of normal diffusion rocking ratchets on an appreciably long time scale. KW - anomalous Brownian motion KW - generalized Langevin equation KW - memory effects KW - viscoelasticity KW - ratchet transport KW - stochastic thermodynamics Y1 - 2013 U6 - https://doi.org/10.1051/mmnp/20138210 SN - 0973-5348 VL - 8 IS - 2 SP - 144 EP - 158 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Chechkin, Aleksei V. A1 - Zaid, I. M. A1 - Lomholt, M. A. A1 - Sokolov, Igor M. A1 - Metzler, Ralf T1 - Bulk-mediated surface diffusion on a cylinder in the fast exchange limit JF - Mathematical modelling of natural phenomena N2 - In various biological systems and small scale technological applications particles transiently bind to a cylindrical surface. Upon unbinding the particles diffuse in the vicinal bulk before rebinding to the surface. Such bulk-mediated excursions give rise to an effective surface translation, for which we here derive and discuss the dynamic equations, including additional surface diffusion. We discuss the time evolution of the number of surface-bound particles, the effective surface mean squared displacement, and the surface propagator. In particular, we observe sub- and superdiffusive regimes. A plateau of the surface mean-squared displacement reflects a stalling of the surface diffusion at longer times. Finally, the corresponding first passage problem for the cylindrical geometry is analysed. KW - Bulk-mediated diffusion KW - anomalous diffusion KW - Levy flights KW - stochastic processes Y1 - 2013 U6 - https://doi.org/10.1051/mmnp/20138208 SN - 0973-5348 VL - 8 IS - 2 SP - 114 EP - 126 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Petrov, Veselin A1 - Schippers, Jos A1 - Benina, Maria A1 - Minkov, Ivan A1 - Müller-Röber, Bernd A1 - Gechev, Tsanko S. T1 - In search for new players of the oxidative stress network by phenotyping an Arabidopsis T-DNA mutant collection on reactive oxygen species-eliciting chemicals JF - Plant omics N2 - The ability of some chemical compounds to cause oxidative stress offers a fast and convenient way to study the responses of plants to reactive oxygen species (ROS). In order to unveil potential novel genetic players of the ROS-regulatory network, a population of similar to 2,000 randomly selected Arabidopsis thaliana T-DNA insertion mutants was screened for ROS sensitivity/resistance by growing seedlings on agar medium supplemented with stress-inducing concentrations of the superoxide-eliciting herbicide methyl viologen or the catalase inhibitor 3-amino-triazole. A semi-robotic setup was used to capture and analyze images of the chemically treated seedlings which helped interpret the screening results by providing quantitative information on seedling area and healthy-to-chlorotic tissue ratios for data verification. A ROS-related phenotype was confirmed in three of the initially selected 33 mutant candidates, which carry T-DNA insertions in genes encoding a Ring/Ubox superfamily protein, ABI5 binding protein 1 (AFP1), previously reported to be involved in ABA signaling, and a protein of unknown function, respectively. In addition, we identified six mutants, most of which have not been described yet, that are related to growth or chloroplast development and show defects in a ROS-independent manner. Thus, semi-automated image capturing and phenotyping applied on publically available T-DNA insertion collections adds a simple means for discovering novel mutants in complex physiological processes and identifying the genes involved. KW - growth KW - image analysis KW - methyl viologen KW - LemnaTec KW - screening KW - superoxide Y1 - 2013 SN - 1836-0661 VL - 6 IS - 1 SP - 46 EP - 54 PB - Southern Cross Publ. CY - Lismore ER - TY - JOUR A1 - Schmidt, Bernd A1 - Elizarov, Nelli A1 - Berger, René A1 - Hoelter, Frank T1 - Scope and limitations of the Heck-Matsuda-coupling of phenol diazonium salts and styrenes a protecting-group economic synthesis of phenolic stilbenes JF - Organic & biomolecular chemistry : an international journal of synthetic, physical and biomolecular organic chemistry N2 - 4-Phenol diazonium salts undergo Pd-catalyzed Heck reactions with various styrenes to 4'-hydroxy stilbenes. In almost all cases higher yields and fewer side products were observed, compared to the analogous 4-methoxy benzene diazonium salts. In contrast, the reaction fails completely with 2- and 3-phenol diazonium salts. For these substitution patterns the methoxy-substituted derivatives are superior. Y1 - 2013 U6 - https://doi.org/10.1039/c3ob40420j SN - 1477-0520 VL - 11 IS - 22 SP - 3674 EP - 3691 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Tentschert, J. A1 - Draude, F. A1 - Jungnickel, H. A1 - Haase, A. A1 - Mantion, Alexandre A1 - Galla, S. A1 - Thuenemann, Andreas F. A1 - Taubert, Andreas A1 - Luch, A. A1 - Arlinghaus, H. F. T1 - TOF-SIMS analysis of cell membrane changes in functional impaired human macrophages upon nanosilver treatment JF - Surface and interface analysis : an international journal devoted to the development and application of techniques for the analysis surfaces, interfaces and thin films N2 - Silver nanoparticles (SNP) are among the most commercialized nanoparticles. Here, we show that peptide-coated SNP cause functional impairment of human macrophages. A dose-dependent inhibition of phagocytosis is observed after nanoparticle treatment, and pretreatment of cells with N-acetyl cysteine (NAC) can counteract the phagocytosis disturbances caused by SNP. Using the surface-sensitive mode of time-of-flight secondary ion mass spectrometry, in combination with multivariate statistical methods, we studied the composition of cell membranes in human macrophages upon exposure to SNP with and without NAC preconditioning. This method revealed characteristic changes in the lipid pattern of the cellular membrane outer leaflet in those cells challenged by SNP. Statistical analyses resulted in 19 characteristic ions, which can be used to distinguish between NAC pretreated and untreated macrophages. The present study discusses the assignments of surface cell membrane phospholipids for the identified ions and the resulting changes in the phospholipid pattern of treated cells. We conclude that the adverse effects in human macrophages caused by SNP can be partially reversed through NAC administration. Some alterations, however, remained. KW - silver nanoparticles KW - lipidomics KW - N-acetyl cysteine KW - phagocytosis KW - oxidative stress Y1 - 2013 U6 - https://doi.org/10.1002/sia.5155 SN - 0142-2421 VL - 45 IS - 1 SP - 483 EP - 485 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Draude, F. A1 - Galla, S. A1 - Pelster, Axel A1 - Tentschert, J. A1 - Jungnickel, H. A1 - Haase, Alfred A1 - Mantion, Alexandre A1 - Thuenemann, Andreas F. A1 - Taubert, Andreas A1 - Luch, A. A1 - Arlinghaus, H. F. T1 - ToF-SIMS and Laser-SNMS analysis of macrophages after exposure to silver nanoparticles JF - Surface and interface analysis : an international journal devoted to the development and application of techniques for the analysis surfaces, interfaces and thin films N2 - Silver nanoparticles (SNPs) are among the most commercialized nanoparticles because of their antibacterial effects. Besides being employed, e. g. as a coatingmaterial for sterile surfaces in household articles and appliances, the particles are also used in a broad range of medical applications. Their antibacterial properties make SNPs especially useful for wound disinfection or as a coating material for prostheses and surgical instruments. Because of their optical characteristics, the particles are of increasing interest in biodetection as well. Despite the widespread use of SNPs, there is little knowledge of their toxicity. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) and laser post-ionization secondary neutral mass spectrometry (Laser-SNMS) were used to investigate the effects of SNPs on human macrophages derived from THP-1 cells in vitro. For this purpose, macrophages were exposed to SNPs. The SNP concentration ranges were chosen with regard to functional impairments of the macrophages. To optimize the analysis of the macrophages, a special silicon wafer sandwich preparation technique was employed; ToF-SIMS was employed to characterize fragments originating from macrophage cell membranes. With the use of this optimized sample preparation method, the SNP-exposed macrophages were analyzed with ToF-SIMS and with Laser-SNMS. With Laser-SNMS, the three-dimensional distribution of SNPs in cells could be readily detected with very high efficiency, sensitivity, and submicron lateral resolution. We found an accumulation of SNPs directly beneath the cell membrane in a nanoparticular state as well as agglomerations of SNPs inside the cells. KW - Laser-SNMS KW - ToF-SIMS KW - life sciences KW - imaging KW - nanoparticles KW - three-dimensional depth profiling Y1 - 2013 U6 - https://doi.org/10.1002/sia.4902 SN - 0142-2421 VL - 45 IS - 1 SP - 286 EP - 289 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Mackenbach, Werner T1 - The recolution as novel - the revolution novel? on the metaphorizationof the sandinist revolution in the Nicaraguan Narrative JF - Revista iberoamericana : organo del Instituto Internacional de Literatura Iberoamericana Y1 - 2013 SN - 0034-9631 VL - 79 IS - 242 SP - 75 EP - 94 PB - University Library System, University of Pittsburgh CY - Pittsburgh ER - TY - JOUR A1 - Schmidt, Bernd A1 - Hauke, Sylvia T1 - Cross metathesis of allyl alcohols how to suppress and how to promote double bond isomerization JF - Organic & biomolecular chemistry : an international journal of synthetic, physical and biomolecular organic chemistry N2 - Under standard conditions the cross metathesis of allyl alcohols and methyl acrylate is accompanied by the formation of ketones, resulting from uncontrolled and undesired double bond isomerization. By conducting the CM in the presence of phenol, the catalyst loading and the reaction time required for quantiative conversion can be reduced, and isomerization can be suppressed. On the other hand, consecutive isomerization can be deliberately promoted by evaporating excess methyl acrylate after completing cross metathesis and by adding a base or silane as chemical triggers. Y1 - 2013 U6 - https://doi.org/10.1039/c3ob40167g SN - 1477-0520 VL - 11 IS - 25 SP - 4194 EP - 4206 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Ohl, Sven A1 - Brandt, Stephan A. A1 - Kliegl, Reinhold T1 - The generation of secondary saccades without postsaccadic visual feedback JF - Journal of vision N2 - Primary saccades are often followed by small secondary saccades, which are generally thought to reduce the distance between the saccade endpoint and target location. Accumulated evidence demonstrates that secondary saccades are subject to various influences, among which retinal feedback during postsaccadic fixation constitutes only one important signal. Recently, we reported that target eccentricity and an orientation bias influence the generation of secondary saccades. In the present study, we examine secondary saccades in the absence of postsaccadic visual feedback. Although extraretinal signals (e.g., efference copy) have received widespread attention in eye-movement studies, it is still unclear whether an extraretinal error signal contributes to the programming of secondary saccades. We have observed that secondary saccade latency and amplitude depend on primary saccade error despite the absence of postsaccadic visual feedback. Strong evidence for an extraretinal error signal influencing secondary saccade programming is given by the observation that secondary saccades are more likely to be oriented in a direction opposite to the primary saccade as primary saccade error shifts from target undershoot to overshoot. We further show how the functional relationship between primary saccade landing position and secondary saccade characteristics varies as a function of target eccentricity. We propose that initial target eccentricity and an extraretinal error signal codetermine the postsaccadic activity distribution in the saccadic motor map when no visual feedback is available. KW - monocular deprivation KW - binocular combination KW - sensory balance Y1 - 2013 U6 - https://doi.org/10.1167/13.5.11 SN - 1534-7362 VL - 13 IS - 5 PB - Association for Research in Vision and Opthalmology CY - Rockville ER - TY - JOUR A1 - Bindschadler, Robert A. A1 - Nowicki, Sophie A1 - Abe-Ouchi, Ayako A1 - Aschwanden, Andy A1 - Choi, Hyeungu A1 - Fastook, Jim A1 - Granzow, Glen A1 - Greve, Ralf A1 - Gutowski, Gail A1 - Herzfeld, Ute A1 - Jackson, Charles A1 - Johnson, Jesse A1 - Khroulev, Constantine A1 - Levermann, Anders A1 - Lipscomb, William H. A1 - Martin, Maria A. A1 - Morlighem, Mathieu A1 - Parizek, Byron R. A1 - Pollard, David A1 - Price, Stephen F. A1 - Ren, Diandong A1 - Saito, Fuyuki A1 - Sato, Tatsuru A1 - Seddik, Hakime A1 - Seroussi, Helene A1 - Takahashi, Kunio A1 - Walker, Ryan A1 - Wang, Wei Li T1 - Ice-sheet model sensitivities to environmental forcing and their use in projecting future sea level (the SeaRISE project) JF - Journal of glaciology N2 - Ten ice-sheet models are used to study sensitivity of the Greenland and Antarctic ice sheets to prescribed changes of surface mass balance, sub-ice-shelf melting and basal sliding. Results exhibit a large range in projected contributions to sea-level change. In most cases, the ice volume above flotation lost is linearly dependent on the strength of the forcing. Combinations of forcings can be closely approximated by linearly summing the contributions from single forcing experiments, suggesting that nonlinear feedbacks are modest. Our models indicate that Greenland is more sensitive than Antarctica to likely atmospheric changes in temperature and precipitation, while Antarctica is more sensitive to increased ice-shelf basal melting. An experiment approximating the Intergovernmental Panel on Climate Change's RCP8.5 scenario produces additional first-century contributions to sea level of 22.3 and 8.1 cm from Greenland and Antarctica, respectively, with a range among models of 62 and 14 cm, respectively. By 200 years, projections increase to 53.2 and 26.7 cm, respectively, with ranges of 79 and 43 cm. Linear interpolation of the sensitivity results closely approximates these projections, revealing the relative contributions of the individual forcings on the combined volume change and suggesting that total ice-sheet response to complicated forcings over 200 years can be linearized. Y1 - 2013 U6 - https://doi.org/10.3189/2013JoG12J125 SN - 0022-1430 VL - 59 IS - 214 SP - 195 EP - 224 PB - International Glaciological Society CY - Cambridge ER - TY - JOUR A1 - Wiemann, Dirk T1 - Cities of the mind - villages of the mind BT - imagining urbanity in Contemporary India JF - Zeitschrift für Anglistik und Amerikanistik : a quarterly of language, literature and cultur N2 - Deep into the second half of the twentieth century the traditionalist definition of India as a country of villages remained dominant in official political rhetoric as well as cultural production. In the past two decades or so, this ruralist paradigm has been effectively superseded by a metropolitan imaginary in which the modern, globalised megacity increasingly functions as representative of India as a whole. Has the village, then, entirely vanished from the cultural imaginary in contemporary India? Addressing economic practices from upper-class consumerism to working-class family support strategies, this paper attempts to trace how 'the village' resurfaces or survives as a cultural reference point in the midst of the urban. Y1 - 2013 U6 - https://doi.org/10.1515/zaa.2013.61.1.59 SN - 0044-2305 VL - 61 IS - 1 SP - 59 EP - 72 PB - Königshausen & Neumann CY - Würzburg ER - TY - JOUR A1 - Sarrar, L. A1 - Warschburger, Petra A1 - Pfeiffer, E. A1 - Lehmkuhl, Ulrike A1 - Schneider, N. T1 - Cognitive flexibility in adolescent patients with unipolar affective disorders - gender differences JF - Zeitschrift für Kinder- und Jugendpsychiatrie und Psychotherapie N2 - Objective: Several studies have revealed impairments in cognitive functions among patients with affective disorders (AD). However, to date there are few neuropsychological studies on cognitive flexibility among adolescent patients with AD, especially on gender differences in AD. Here, we investigate cognitive functions, especially cognitive flexibility, in adolescent patients with unipolar AD (UAD) compared to a healthy control group (CG). Method: The study population consists of 17 male patients (M-age = 15.4 +/- 1.3) and 22 female patients with UAD (M-age = 15.6 +/- 1.4) as well as 20 male (M-age = 16.0 +/- 1.0) and 30 female (M-age = 15.7 +/- 0.9) healthy adolescents. A neuropsychological test battery was conducted, and depressive symptoms, psychological stress, and intelligence were also assessed. Results: The analyses revealed no significant group differences regarding cognitive flexibility or visual processing speed, albeit slight better performance in motor processing speed for the CG. Furthermore, no gender differences were observed regarding cognitive flexibility, though female subjects general displayed better performance in processing speed. Conclusions: Overall, there are no indications for serious deficits and specific gender differences in cognitive flexibility or processing speed in adolescent patients with UAD. Independent of psychological distress, female subjects seem to have some advantages in processing speed. KW - cognitive flexibility KW - unipolar affective disorders KW - sex differences KW - adolescents Y1 - 2013 U6 - https://doi.org/10.1024/1422-4917/a000240 SN - 1422-4917 VL - 41 IS - 4 SP - 261 EP - 270 PB - Hogrefe CY - Bern ER - TY - JOUR A1 - Nottebrock, Henning A1 - Esler, Karen J. A1 - Schurr, Frank Martin T1 - Effects of intraspecific and community density on the lifetime fecundity of long-lived shrubs JF - Perspectives in plant ecology, evolution and systematics N2 - Intra- and interspecific density dependence has profound consequences for plant population and community dynamics. In long-lived plants, however, lifetime patterns and mechanisms of density dependence are difficult to study. Here, we examine effects of intraspecific and community density on the lifetime fecundity of two long-lived shrub species from South African Fynbos: Protea repens (animal-pollinated, hermaphroditic) and Leucadendron rubrum (wind-pollinated, dioecious). Both species are serotinous, retaining seeds in cones until fire kills the mother plant. We measured lifetime fecundity as the product of cone number, proportion of cones that are not damaged by predation and seed set (fertile seeds per intact cone). Intraspecific and community densities were quantified by counting individuals of target species and all Proteaceae in small- and large-scale neighbourhoods (10 m and 50 m radius) around each focal individual. Additionally, we determined the age and size of focal individuals. We found that lifetime fecundity of the wind-pollinated L rubrum is density independent. In contrast, the lifetime fecundity of the animal-pollinated P. repens increases with large-scale intraspecific density and shows a hump-shaped relationship to large-scale community density. Community density has a hump-shaped effect on seed set (probably through partial absence of generalized pollinators at low and competition for pollinators at high densities) and negatively affects cone number per individual. For both species, plant age decreases seed set while increasing lifetime fecundity. The qualitative differences in the density dependence of lifetime fecundity may arise from differences between animal and wind pollination. In particular, interactions with generalized animal pollinators may cause community-level Allee effects with profound consequences for the future dynamics of long-lived plant populations and communities. KW - Competition KW - Community-level Allee effects KW - Facilitation KW - Fitness components KW - Interspecific interactions KW - Plant-animal interactions Y1 - 2013 U6 - https://doi.org/10.1016/j.ppees.2013.03.003 SN - 1433-8319 VL - 15 IS - 3 SP - 150 EP - 161 PB - Elsevier CY - Jena ER - TY - JOUR A1 - Hernandez de la Fuente, David T1 - The chorus of dionysus religion and education in Plato's Nomoi JF - Zeitschrift für Religions- und Geistesgeschichte Y1 - 2013 SN - 0044-3441 VL - 65 IS - 1 SP - 1 EP - 17 PB - Brill CY - Leiden ER - TY - JOUR A1 - Schaffner, Ellen A1 - Schiefele, Ulrich A1 - Schmidt, Meike T1 - The importance of family background for reading motivation and reading frequency of high school students JF - Zeitschrift für Entwicklungspsychologie und pädagogische Psychologie N2 - This article examines the relationships between family background and reading motivation (RM) as well as reading frequency in a sample of 156 high school students. To test the effects of family background (migration status, books at home, parents' appreciation of reading, parents' motivating practices), hierarchical regression analyses were applied. In these analyses, students' perceptions of reading incentives provided by the school and peer group were taken into account as control variables. Parents' learning-oriented appreciation of reading and motivating practices emerged as important predictors of intrinsic and extrinsic RM. Reading frequency was predicted by the number of books at home and parents' motivating practices. The effects of family background on extrinsic RM and reading frequency remained stable, even after controlling for reading incentives provided by the school and peer group. KW - reading motivation KW - reading frequency KW - family background Y1 - 2013 U6 - https://doi.org/10.1026/0049-8637/a000085 SN - 0049-8637 VL - 45 IS - 3 SP - 131 EP - 141 PB - Hogrefe CY - Göttingen ER - TY - JOUR A1 - Möller, Ingrid A1 - Krahé, Barbara A1 - Busching, Robert T1 - Consumption of media violence and aggressive behavior a longitudinal study of German adolescents with and without migration background JF - Zeitschrift für Entwicklungspsychologie und pädagogische Psychologie N2 - The consumption of media violence and aggressive behavior were assessed three times in a sample of N=1,052 German adolescents with and without migration background over a period of two years with 12-month intervals. The adolescents in the two groups, who were in grades 7 and 8 at T1, were matched by gender, age, type of school, and academic achievement. Students in the migrant group reported higher consumption of violent media. At T3, they showed more physical but less relational aggression than their peers of German background. Cross-lagged panel analyses showed parallel associations between media violence use and aggression in both groups: Media violence consumption at T1 and T2 predicted physical aggression at T2 and T3 independent of ethnic background. The reverse path from physical aggression to media violence consumption was nonsignificant. No link was found between media violence use and relational aggression over time. KW - media violence KW - aggression KW - migration KW - adolescence KW - longitudinal study Y1 - 2013 U6 - https://doi.org/10.1026/0049-8637/a000086 SN - 0049-8637 VL - 45 IS - 3 SP - 121 EP - 130 PB - Hogrefe CY - Göttingen ER - TY - JOUR A1 - Junginger, Mathias A1 - Kübel, Christian A1 - Schacher, Felix H. A1 - Müller, Axel H. E. A1 - Taubert, Andreas T1 - Crystal structure and chemical composition of biomimetic calcium phosphate nanofibers JF - RSC Advances N2 - Calcium phosphate nanofibers with a diameter of only a few nanometers and a cotton-ball-like aggregate morphology have been reported several times in the literature. Although fiber formation seems reproducible in a variety of conditions, the crystal structure and chemical composition of the fibers have been elusive. Using scanning transmission electron microscopy, low dose electron (nano) diffraction, energy-dispersive X-ray spectroscopy, and energy-filtered transmission electron microscopy, we have assigned crystal structures and chemical compositions to the fibers. Moreover, we demonstrate that the mineralization process yields true polymer/calcium phosphate hybrid materials where the block copolymer template is closely associated with the calcium phosphate. Y1 - 2013 U6 - https://doi.org/10.1039/c3ra23348k SN - 2046-2069 VL - 3 IS - 28 SP - 11301 EP - 11308 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Liang, Wei A1 - Heinrich, Ingo A1 - Helle, Gerhard A1 - Linan, Isabel Dorado A1 - Heinken, Thilo T1 - Applying CLSM to increment core surfaces for histometric analyses a novel advance in quantitative wood anatomy JF - Dendrochronologia : an interdisciplinary journal of tree-ring science N2 - A novel procedure has been developed to conduct cell structure measurements on increment core samples of conifers. The procedure combines readily available hardware and software equipment. The essential part of the procedure is the application of a confocal laser scanning microscope (CLSM) which captures images directly from increment cores surfaced with the advanced WSL core-microtome. Cell wall and lumen are displayed with a strong contrast due to the monochrome black and green nature of the images. Consecutive images are merged into long images representing entire increment cores which are then analysed for cell structures in suitable software. KW - Wood anatomy KW - Cell structures KW - Confocal laser scanning microscopy KW - CLSM KW - Dendrochronology KW - Surface preparation Y1 - 2013 U6 - https://doi.org/10.1016/j.dendro.2012.09.002 SN - 1125-7865 VL - 31 IS - 2 SP - 140 EP - 145 PB - Elsevier CY - Jena ER - TY - JOUR A1 - Tischer, Ute T1 - Manifestus error? Wrong Citation and literary Communication (on Gel. 15.6) JF - Mnemosyne : a journal of classical studies Y1 - 2013 SN - 0026-7074 VL - 66 IS - 3 SP - 411 EP - 432 PB - Brill CY - Leiden ER - TY - JOUR A1 - Conradt, Tobias A1 - Wechsung, F. A1 - Bronstert, Axel T1 - Three perceptions of the evapotranspiration landscape comparing spatial patterns from a distributed hydrological model, remotely sensed surface temperatures, and sub-basin water balances JF - Hydrology and earth system sciences : HESS N2 - A problem encountered by many distributed hydrological modelling studies is high simulation errors at interior gauges when the model is only globally calibrated at the outlet. We simulated river runoff in the Elbe River basin in central Europe (148 268 km(2)) with the semi-distributed eco-hydrological model SWIM (Soil and Water Integrated Model). While global parameter optimisation led to Nash-Sutcliffe efficiencies of 0.9 at the main outlet gauge, comparisons with measured runoff series at interior points revealed large deviations. Therefore, we compared three different strategies for deriving sub-basin evapotranspiration: (1) modelled by SWIM without any spatial calibration, (2) derived from remotely sensed surface temperatures, and (3) calculated from long-term precipitation and discharge data. The results show certain consistencies between the modelled and the remote sensing based evapotranspiration rates, but there seems to be no correlation between remote sensing and water balance based estimations. Subsequent analyses for single sub-basins identify amongst others input weather data and systematic error amplification in inter-gauge discharge calculations as sources of uncertainty. The results encourage careful utilisation of different data sources for enhancements in distributed hydrological modelling. Y1 - 2013 U6 - https://doi.org/10.5194/hess-17-2947-2013 SN - 1027-5606 VL - 17 IS - 7 SP - 2947 EP - 2966 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Sommer, Michael A1 - Jochheim, H. A1 - Höhn, Axel A1 - Breuer, Jörn A1 - Zagorski, Z. A1 - Busse, J. A1 - Barkusky, Dietmar A1 - Meier, K. A1 - Puppe, D. A1 - Wanner, Manfred A1 - Kaczorek, Danuta T1 - Si cycling in a forest biogeosystem - the importance of transient state biogenic Si pools JF - Biogeosciences N2 - The relevance of biological Si cycling for dissolved silica (DSi) export from terrestrial biogeosystems is still in debate. Even in systems showing a high content of weatherable minerals, like Cambisols on volcanic tuff, biogenic Si (BSi) might contribute > 50% to DSi (Gerard et al., 2008). However, the number of biogeosystem studies is rather limited for generalized conclusions. To cover one end of controlling factors on DSi, i.e., weatherable minerals content, we studied a forested site with absolute quartz dominance (> 95 %). Here we hypothesise minimal effects of chemical weathering of silicates on DSi. During a four year observation period (05/2007-04/2011), we quantified (i) internal and external Si fluxes of a temperate-humid biogeosystem (beech, 120 yr) by BIOME-BGC (version ZALF), (ii) related Si budgets, and (iii) Si pools in soil and beech, chemically as well as by SEM-EDX. For the first time two compartments of biogenic Si in soils were analysed, i.e., phytogenic and zoogenic Si pool (testate amoebae). We quantified an average Si plant uptake of 35 kg Si ha(-1) yr(-1) - most of which is recycled to the soil by litterfall - and calculated an annual biosilicification from idiosomic testate amoebae of 17 kg Si ha(-1). The comparatively high DSi concentrations (6 mg L-1) and DSi exports (12 kg Si ha(-1) yr(-1)) could not be explained by chemical weathering of feldspars or quartz dissolution. Instead, dissolution of a relictic, phytogenic Si pool seems to be the main process for the DSi observed. We identified canopy closure accompanied by a disappearance of grasses as well as the selective extraction of pine trees 30 yr ago as the most probable control for the phenomena observed. From our results we concluded the biogeosystem to be in a transient state in terms of Si cycling. Y1 - 2013 U6 - https://doi.org/10.5194/bg-10-4991-2013 SN - 1726-4170 VL - 10 IS - 7 SP - 4991 EP - 5007 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Solly, Emily A1 - Schöning, Ingo A1 - Boch, Steffen A1 - Mueller, J. A1 - Socher, S. A. A1 - Trumbore, S. E. A1 - Schrumpf, M. T1 - Mean age of carbon in fine roots from temperate forests and grasslands with different management JF - Biogeosciences N2 - Fine roots are the most dynamic portion of a plant's root system and a major source of soil organic matter. By altering plant species diversity and composition, soil conditions and nutrient availability, and consequently belowground allocation and dynamics of root carbon (C) inputs, land-use and management changes may influence organic C storage in terrestrial ecosystems. In three German regions, we measured fine root radiocarbon (C-14) content to estimate the mean time since C in root tissues was fixed from the atmosphere in 54 grassland and forest plots with different management and soil conditions. Although root biomass was on average greater in grasslands 5.1 +/- 0.8 g (mean +/- SE, n = 27) than in forests 3.1 +/- 0.5 g (n = 27) (p < 0.05), the mean age of C in fine roots in forests averaged 11.3 +/- 1.8 yr and was older and more variable compared to grasslands 1.7 +/- 0.4 yr (p < 0.001). We further found that management affects the mean age of fine root C in temperate grasslands mediated by changes in plant species diversity and composition. Fine root mean C age is positively correlated with plant diversity (r = 0.65) and with the number of perennial species (r = 0.77). Fine root mean C age in grasslands was also affected by study region with averages of 0.7 +/- 0.1 yr (n= 9) on mostly organic soils in northern Germany and of 1.8 +/- 0.3 yr (n = 9) and 2.6 +/- 0.3 (n = 9) in central and southern Germany (p < 0.05). This was probably due to differences in soil nutrient contents and soil moisture conditions between study regions, which affected plant species diversity and the presence of perennial species. Our results indicate more long-lived roots or internal redistribution of C in perennial species and suggest linkages between fine root C age and management in grasslands. These findings improve our ability to predict and model belowground C fluxes across broader spatial scales. Y1 - 2013 U6 - https://doi.org/10.5194/bg-10-4833-2013 SN - 1726-4170 VL - 10 IS - 7 SP - 4833 EP - 4843 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Thete, Aniket A1 - Rojas, Oscar A1 - Neumeyer, David A1 - Koetz, Joachim A1 - Dujardin, Erik T1 - Ionic liquid-assisted morphosynthesis of gold nanorods using polyethyleneimine-capped seeds JF - RSC Advances N2 - Seed-mediated gold nanorods with tunable lengths are prepared using new polyethyleneimine-capped gold nanoparticles synthesized in ionic liquid. The effect of polyethyleneimine and ionic liquid during nanorod growth is investigated and shows a marked effect on their final aspect ratio. Y1 - 2013 U6 - https://doi.org/10.1039/c3ra22112a SN - 2046-2069 VL - 3 IS - 34 SP - 14294 EP - 14298 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Sultanow, Eldar A1 - Weber, Edzard T1 - Pharmataxigraphie Model of a Hybrid System of RFID Technology and optical Methods JF - Die pharmazeutische Industrie Y1 - 2013 SN - 0031-711X VL - 75 IS - 7 SP - 1197 EP - + PB - Editio-Cantor-Verl. für Medizin und Naturwiss. CY - Aulendorf ER - TY - JOUR A1 - Pattyn, Frank A1 - Perichon, Laura A1 - Durand, Gael A1 - Favier, Lionel A1 - Gagliardini, Olivier A1 - Hindmarsh, Richard C. A. A1 - Zwinger, Thomas A1 - Albrecht, Torsten A1 - Cornford, Stephen A1 - Docquier, David A1 - Furst, Johannes J. A1 - Goldberg, Daniel A1 - Gudmundsson, Gudmundur Hilmar A1 - Humbert, Angelika A1 - Huetten, Moritz A1 - Huybrechts, Philippe A1 - Jouvet, Guillaume A1 - Kleiner, Thomas A1 - Larour, Eric A1 - Martin, Daniel A1 - Morlighem, Mathieu A1 - Payne, Anthony J. A1 - Pollard, David A1 - Rueckamp, Martin A1 - Rybak, Oleg A1 - Seroussi, Helene A1 - Thoma, Malte A1 - Wilkens, Nina T1 - Grounding-line migration in plan-view marine ice-sheet models: results of the ice2sea MISMIP3d intercomparison JF - Journal of glaciology N2 - Predictions of marine ice-sheet behaviour require models able to simulate grounding-line migration. We present results of an intercomparison experiment for plan-view marine ice-sheet models. Verification is effected by comparison with approximate analytical solutions for flux across the grounding line using simplified geometrical configurations (no lateral variations, no buttressing effects from lateral drag). Perturbation experiments specifying spatial variation in basal sliding parameters permitted the evolution of curved grounding lines, generating buttressing effects. The experiments showed regions of compression and extensional flow across the grounding line, thereby invalidating the boundary layer theory. Steady-state grounding-line positions were found to be dependent on the level of physical model approximation. Resolving grounding lines requires inclusion of membrane stresses, a sufficiently small grid size (<500 m), or subgrid interpolation of the grounding line. The latter still requires nominal grid sizes of <5 km. For larger grid spacings, appropriate parameterizations for ice flux may be imposed at the grounding line, but the short-time transient behaviour is then incorrect and different from models that do not incorporate grounding-line parameterizations. The numerical error associated with predicting grounding-line motion can be reduced significantly below the errors associated with parameter ignorance and uncertainties in future scenarios. Y1 - 2013 U6 - https://doi.org/10.3189/2013JoG12J129 SN - 0022-1430 VL - 59 IS - 215 SP - 410 EP - 422 PB - International Glaciological Society CY - Cambridge ER - TY - JOUR A1 - Schleussner, Carl-Friedrich A1 - Feulner, G. T1 - A volcanically triggered regime shift in the subpolar North Atlantic Ocean as a possible origin of the Little Ice Age JF - Climate of the past : an interactive open access journal of the European Geosciences Union N2 - Among the climatological events of the last millennium, the Northern Hemisphere Medieval Climate Anomaly succeeded by the Little Ice Age are of exceptional importance. The origin of these regional climate anomalies remains a subject of debate and besides external influences like solar and volcanic activity, internal dynamics of the climate system might have also played a dominant role. Here, we present transient last millennium simulations of the fully coupled model of intermediate complexity Climber 3a forced with stochastically reconstructed wind-stress fields. Our results indicate that short-lived volcanic eruptions might have triggered a cascade of sea ice ocean feedbacks in the North Atlantic, ultimately leading to a persistent regime shift in the ocean circulation. We find that an increase in the Nordic Sea sea-ice extent on decadal timescales as a consequence of major volcanic eruptions in our model leads to a spin-up of the subpolar gyre and a weakened Atlantic meridional overturning circulation, eventually causing a persistent, basin-wide cooling. These results highlight the importance of regional climate feedbacks such as a regime shift in the subpolar gyre circulation for understanding the dynamics of past and future climate. Y1 - 2013 U6 - https://doi.org/10.5194/cp-9-1321-2013 SN - 1814-9324 SN - 1814-9332 VL - 9 IS - 3 SP - 1321 EP - 1330 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Girstmair, Hannah A1 - Saffert, Paul A1 - Rode, Sascha A1 - Czech, Andreas A1 - Holland, Gudrun A1 - Bannert, Norbert A1 - Ignatova, Zoya T1 - Depletion of Cognate Charged Transfer RNA Causes Translational Frameshifting within the Expanded CAG Stretch in Huntingtin JF - Cell reports N2 - Huntington disease (HD), a dominantly inherited neurodegenerative disorder caused by the expansion of a CAG-encoded polyglutamine (polyQ) repeat in huntingtin (Htt), displays a highly heterogeneous etiopathology and disease onset. Here, we show that the translation of expanded CAG repeats in mutant Htt exon 1 leads to a depletion of charged glutaminyl-transfer RNA (tRNA) Gln-CUG that pairs exclusively to the CAG codon. This results in translational frameshifting and the generation of various transframe-encoded species that differently modulate the conformational switch to nucleate fibrillization of the parental polyQ protein. Intriguingly, the frameshifting frequency varies strongly among different cell lines and is higher in cells with intrinsically lower concentrations of tRNA Gln-CUG. The concentration of tRNA Gln-CUG also differs among different brain areas in the mouse. We propose that translational frameshifting may act as a significant disease modifier that contributes to the cell-selective neurotoxicity and disease course heterogeneity of HD on both cellular and individual levels. Y1 - 2013 U6 - https://doi.org/10.1016/j.celrep.2012.12.019 SN - 2211-1247 VL - 3 IS - 1 SP - 148 EP - 159 PB - Cell Press CY - Cambridge ER - TY - JOUR A1 - Schiefele, Ulrich A1 - Schaffner, Ellen T1 - Reading motivation of Sixth-Grade Elementary School Students - results from an interview study JF - Psychologie in Erziehung und Unterricht : Zeitschrift für Forschung und Praxis N2 - Based on research by Wigfield and Guthrie (1997), Moller and Bonerad (2007) as well as Schaffner and Schiefele (2007) have developed questionnaires to assess students' reading motivation. The goal of the present study was to examine whether these instruments coincide with students' subjective views of their own reading motivation. In order to clarify this question, we conducted interviews with 26 elementary school students and applied content analysis to examine the interview protocols. Although the results support some of the theoretically postulated components, they suggest that questionnaire measures have neglected some important aspects of reading motivation (e. g., reading to regulate one's feelings, reading to relax). Finally, consequences for the revision of reading motivation questionnaires were discussed. KW - Reading motivation KW - interview method KW - elementary school Y1 - 2013 U6 - https://doi.org/10.2378/peu2013.art17d SN - 0342-183X VL - 60 IS - 3 SP - 214 EP - 233 PB - Reinhardt CY - München ER - TY - JOUR A1 - Dumont, Hanna A1 - Neumann, Marko A1 - Nagy, Gabriel A1 - Becker, Michael A1 - Rose, Norman A1 - Trautwein, Ulrich T1 - Class composition Effects in non-academic lower secondary school tracks in the state of Baden-Württemberg JF - Psychologie in Erziehung und Unterricht : Zeitschrift für Forschung und Praxis N2 - The study investigates the effects of classroom composition (average ability, achievement, and socio-economic background, proportion of immigrant students) on the development in mathematics achievement, and reading literacy from grade 5 to 6. The study draws on a sample of N=1892 students in vocational track schools (Hauptschule) and intermediate track schools (Realschule) in Baden-Wuerttemberg, Germany. After controlling for school type, and between-school differences in student intake characteristics, none of the compositional characteristics showed a statistically significant effect on achievement development. School track was associated with the development of reading literacy even after controlling for individual differences; however, this relationship lost its statistical significance after the composition of the student body was additionally taken into account. KW - Academic achievement KW - tracking KW - reading comprehension KW - mathematics KW - composition effects Y1 - 2013 U6 - https://doi.org/10.2378/peu2013.art16d SN - 0342-183X VL - 60 IS - 3 SP - 198 EP - 213 PB - Reinhardt CY - München ER - TY - JOUR A1 - Dumont, Hanna A1 - Neumann, Marko A1 - Maaz, Kai A1 - Trautwein, Ulrich T1 - The effect of student body composition on academic achievement International and National Evidence JF - Psychologie in Erziehung und Unterricht : Zeitschrift für Forschung und Praxis N2 - This paper reviews empirical evidence on the effect of the composition of a student body on academic achievement of students. After defining the term composition effect, methodological aspects regarding the study of composition effects are considered. International and national evidence for the composition of a student body with respect to students' abilities, social, and ethnic background is then presented. Whereas international studies find evidence for social, ethnic, and achievement composition variables, national studies reveal that mean achievement level of a school or class is the most important composition variable in Germany. However, this effect is confounded with school track and social composition, which itself exerts a small incremental effect. Ethnic composition, however, does not seem to play an important role. The paper closes with a presentation of the underlying processes of composition effects and a discussion on how the composition of a student body is considered in school governance practices. KW - Composition effects KW - academic achievement KW - tracking Y1 - 2013 U6 - https://doi.org/10.2378/peu2013.art14d SN - 0342-183X VL - 60 IS - 3 SP - 163 EP - 183 PB - Reinhardt CY - München ER - TY - JOUR A1 - Heinken, Thilo A1 - Weber, Ewald T1 - Consequences of habitat fragmentation for plant species do we know enough? JF - Perspectives in plant ecology, evolution and systematics N2 - Habitat fragmentation is one of the most important causes for the decline of plant species. However, plants differing in phylogeny, habitat requirements and biology are likely to respond differently to habitat fragmentation. We ask whether case studies on the effects of habitat fragmentation conducted so far allow generalizations about its effects on the fitness and genetic diversity of populations of endangered plant species. We compared the characteristics of plant species endangered in Germany whose sensitivity to habitat fragmentation had been studied with those of the endangered species that had not been studied. We found strong discrepancies between the two groups with regard to their taxonomy and traits relevant to their sensitivity to habitat fragmentation. Monocots, graminoids, clonal, abiotically pollinated and self compatible species were underrepresented among the studied species, and most study species were from a few habitat types, in particular grasslands. We conclude that our current knowledge of the effects of habitat fragmentation on plant populations is not sufficient to provide widely applicable guidelines for species management. The selection of species studied so far has been biased toward species from certain habitats and species exhibiting traits that probably make them vulnerable to habitat fragmentation. Future studies should include community-wide approaches in different habitats, e.g. re-visitation studies in which the species pool is assessed at different time intervals, and population-biological studies of species from a wide range of habitats, and of different life forms and growth strategies. A more representative picture of the effects of habitat fragmentation would allow a better assessment of threats and more specific recommendations for optimally managing populations of endangered plants. KW - CSR-strategies KW - Naturally rare species KW - Plant conservation KW - Recently rare species KW - Species traits KW - Taxonomic position Y1 - 2013 U6 - https://doi.org/10.1016/j.ppees.2013.05.003 SN - 1433-8319 VL - 15 IS - 4 SP - 205 EP - 216 PB - Elsevier CY - Jena ER - TY - JOUR A1 - Mondal, Suvendu Sekhar A1 - Bhunia, Asamanjoy A1 - Baburin, Igor A. A1 - Jäger, Christian A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Seifert, Gotthard A1 - Janiak, Christoph A1 - Holdt, Hans-Jürgen T1 - Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity JF - Chemical communications N2 - A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N-2 and CH4 gases. Y1 - 2013 U6 - https://doi.org/10.1039/c3cc42156b SN - 1359-7345 VL - 49 IS - 69 SP - 7599 EP - 7601 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Ozsayin, Erman A1 - Ciner, T. Attila A1 - Rojay, F. Bora A1 - Dirik, R. Kadir A1 - Melnick, Daniel A1 - Fernandez-Blanco, David A1 - Bertotti, Giovanni A1 - Schildgen, Taylor F. A1 - Garcin, Yannick A1 - Strecker, Manfred A1 - Sudo, Masafumi T1 - Plio-Quaternary extensional tectonics of the Central Anatolian Plateau a case study from the Tuz Golu Basin, Turkey JF - Turkish journal of earth sciences = Türk yerbilimleri dergisi N2 - The Tuz Golu Basin is the largest sedimentary depression located at the center of the Central Anatolian Plateau, an extensive, low-relief region with elevations of ca. 1 km located between the Pontide and Tauride mountains. Presently, the basin morphology and sedimentation processes are mainly controlled by the extensional Tuz Golu Fault Zone in the east and the transtensional Inonu-Eskisehir Fault System in the west. The purpose of this study is to contribute to the understanding of the Plio-Quaternary deformation history and to refine the timing of the latest extensional phase of the Tuz Golu Basin. Field observations, kinematic analyses, interpretations of seismic reflection lines, and Ar-40/Ar-39 dating of a key ignimbrite layer suggest that a regional phase of NNW-SSE to NE-SW contraction ended by 6.81 +/- 0.24 Ma and was followed by N-S to NE-SW extension during the Pliocene-Quaternary periods. Based on sedimentological and chronostratigraphic markers, the average vertical displacement rates over the past 5 or 3 Ma with respect to the central part of Tuz Golu Lake are 0.03 to 0.05 mm/year for the fault system at the western flank of the basin and 0.08 to 0.13 mm/year at the eastern flank. Paleo-shorelines of the Tuz Golu Lake, vestiges of higher lake levels related to Quaternary climate change, are important strain markers and were formed during Last Glacial Maximum conditions as indicated by a radiocarbon age of 21.8 +/- 0.4 ka BP obtained from a stromatolitic crust. Geomorphic observations and deformed lacustrine shorelines suggest that the main strand of the Tuz Golu Fault Zone straddling the foothills of the Sereflikochisar-Aksaray range has not been active during the Holocene. Instead, deformation appears to have migrated towards the interior of the basin along an offshore fault that runs immediately west of Sereflikochisar Peninsula. This basinward migration of deformation is probably associated with various processes acting at the lithospheric scale, such as plateau uplift and/or microplate extrusion. KW - Central Anatolia KW - Tuz Golu Basin KW - orogenic plateau evolution KW - extensional tectonics KW - kinematic analysis KW - lake shoreline Y1 - 2013 U6 - https://doi.org/10.3906/yer-1210-5 SN - 1300-0985 VL - 22 IS - 5 SP - 691 EP - 714 PB - Tübitak CY - Ankara ER - TY - JOUR A1 - Reich, Sebastian T1 - A nonparametric ensemble transform method for bayesian inference JF - SIAM journal on scientific computing N2 - Many applications, such as intermittent data assimilation, lead to a recursive application of Bayesian inference within a Monte Carlo context. Popular data assimilation algorithms include sequential Monte Carlo methods and ensemble Kalman filters (EnKFs). These methods differ in the way Bayesian inference is implemented. Sequential Monte Carlo methods rely on importance sampling combined with a resampling step, while EnKFs utilize a linear transformation of Monte Carlo samples based on the classic Kalman filter. While EnKFs have proven to be quite robust even for small ensemble sizes, they are not consistent since their derivation relies on a linear regression ansatz. In this paper, we propose another transform method, which does not rely on any a priori assumptions on the underlying prior and posterior distributions. The new method is based on solving an optimal transportation problem for discrete random variables. KW - Bayesian inference KW - Monte Carlo method KW - sequential data assimilation KW - linear programming KW - resampling Y1 - 2013 U6 - https://doi.org/10.1137/130907367 SN - 1064-8275 VL - 35 IS - 4 SP - A2013 EP - A2024 PB - Society for Industrial and Applied Mathematics CY - Philadelphia ER - TY - JOUR A1 - Itoh, N. A1 - Marwan, Norbert T1 - An extended singular spectrum transformation (SST) for the investigation of Kenyan precipitation data JF - Nonlinear processes in geophysics N2 - In this paper a change-point detection method is proposed by extending the singular spectrum transformation (SST) developed as one of the capabilities of singular spectrum analysis (SSA). The method uncovers change points related with trends and periodicities. The potential of the proposed method is demonstrated by analysing simple model time series including linear functions and sine functions as well as real world data (precipitation data in Kenya). A statistical test of the results is proposed based on a Monte Carlo simulation with surrogate methods. As a result, the successful estimation of change points as inherent properties in the representative time series of both trend and harmonics is shown. With regards to the application, we find change points in the precipitation data of Kenyan towns (Nakuru, Naivasha, Narok, and Kisumu) which coincide with the variability of the Indian Ocean Dipole (IOD) suggesting its impact of extreme climate in East Africa. Y1 - 2013 U6 - https://doi.org/10.5194/npg-20-467-2013 SN - 1023-5809 VL - 20 IS - 4 SP - 467 EP - 481 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Zibulski, Romy A1 - Herzschuh, Ulrike A1 - Pestryakova, Luidmila Agafyevna A1 - Wolter, Juliane A1 - Mueller, S. A1 - Schilling, N. A1 - Wetterich, Sebastian A1 - Schirrmeister, Lutz A1 - Tian, Fang T1 - River flooding as a driver of polygon dynamics: modern vegetation data and a millennial peat record from the Anabar River lowlands (Arctic Siberia) JF - Biogeosciences N2 - The spatial and temporal variability of a low-centred polygon on the eastern floodplain area of the lower Anabar River (72.070 degrees N, 113.921 degrees E; northern Yakutia, Siberia) has been investigated using a multi-method approach. The present-day vegetation in each square metre was analysed, revealing a community of Larix, shrubby Betula, and Salix on the polygon rim, a dominance of Carex and Andromeda polifolia in the rim-to-pond transition zone, and a predominantly monospecific Scorpidium scorpioides coverage within the pond. The total organic carbon (TOC) content, TOC/TN (total nitrogen) ratio, grain size, vascular plant macrofossils, moss remains, diatoms, and pollen were analysed for two vertical sections and a sediment core from a transect across the polygon. Radiocarbon dating indicates that the formation of the polygon started at least 1500 yr ago; the general positions of the pond and rim have not changed since that time. Two types of pond vegetation were identified, indicating two contrasting development stages of the polygon. The first was a well-established moss association, dominated by submerged or floating Scorpidium scorpioides and/or Drepanocladus spp. and overgrown by epiphytic diatoms such as Tabellaria flocculosa and Eunotia taxa. This stage coincides temporally with a period in which the polygon was only drained by lateral subsurface water flow, as indicated by mixed grain sizes. A different moss association occurred during times of repeated river flooding (indicated by homogeneous medium-grained sand that probably accumulated during the annual spring snowmelt), characterized by an abundance of Meesia triquetra and a dominance of benthic diatoms (e. g. Navicula vulpina), indicative of a relatively high pH and a high tolerance of disturbance. A comparison of the local polygon vegetation (inferred from moss and macrofossil spectra) with the regional vegetation (inferred from pollen spectra) indicated that the moss association with Scorpidium scorpioides became established during relatively favourable climatic conditions, while the association dominated by Meesia triquetra occurred during periods of harsh climatic conditions. Our study revealed a strong riverine influence (in addition to climatic influences) on polygon development and the type of peat accumulated. Y1 - 2013 U6 - https://doi.org/10.5194/bg-10-5703-2013 SN - 1726-4170 VL - 10 IS - 8 SP - 5703 EP - 5728 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Schrade, Lisa A1 - Scheffler, Christiane T1 - Assessing the applicability of the digital laser rangefinder GLM Professional (R) Bosch 250 VF for anthropometric field studies JF - Journal of biological and clinical anthropology : Anthropologischer Anzeiger ; Mitteilungsorgan der Gesellschaft für Anthropologie N2 - The digital laser rangefinder GLM Professional (R) BOSCH 250 VF was tested as a modified preproduction model with regard to its applicability of quantifying humans' height. The aim of this investigation was to determine and evaluate the instrument's precision, as well as its manageability within anthropometric field studies. Data collected by the digital laser rangefinder did not show a significant difference to data of control by an anthropometer. Furthermore, more than 96% of the difference values are located within area of agreement. Nevertheless, the GLM Professional (R) is a highly sensitive instrument and mean SD within threefold data acquisition is twice as high as SD resulting from data collection by an anthropometer. However, due to the minimal percentage differences within data acquisition and compared to the standard method, the GLM Professional (R) is proved to be a reliable instrument and to be highly applicable for anthropometric field studies. Furthermore, due to its excellent manageability and compact size, the GLM Professional (R) shows a very good applicability even for less trained anthropometrists and thus ameliorates the possibilities of collecting reliable data within anthropometric field studies. KW - anthropometric field studies KW - height KW - measuring instrument KW - digital laser range finder Y1 - 2013 U6 - https://doi.org/10.1127/0003-5548/2013/0223 SN - 0003-5548 VL - 70 IS - 2 SP - 137 EP - 145 PB - Schweizerbart CY - Stuttgart ER - TY - JOUR A1 - Inal, Sahika A1 - Koelsch, Jonas D. A1 - Chiappisi, Leonardo A1 - Janietz, Dietmar A1 - Gradzielski, Michael A1 - Laschewsky, André A1 - Neher, Dieter T1 - Structure-related differences in the temperature-regulated fluorescence response of LCST type polymers JF - Journal of materials chemistry : C, Materials for optical and electronic devices N2 - We demonstrate new fluorophore-labelled materials based on acrylamide and on oligo(ethylene glycol) (OEG) bearing thermoresponsive polymers for sensing purposes and investigate their thermally induced solubility transitions. It is found that the emission properties of the polarity-sensitive (solvatochromic) naphthalimide derivative attached to three different thermoresponsive polymers are highly specific to the exact chemical structure of the macromolecule. While the dye emits very weakly below the LCST when incorporated into poly(N-isopropylacrylamide) (pNIPAm) or into a polyacrylate backbone bearing only short OEG side chains, it is strongly emissive in polymethacrylates with longer OEG side chains. Heating of the aqueous solutions above their cloud point provokes an abrupt increase of the fluorescence intensity of the labelled pNIPAm, whereas the emission properties of the dye are rather unaffected as OEG-based polyacrylates and methacrylates undergo phase transition. Correlated with laser light scattering studies, these findings are ascribed to the different degrees of pre-aggregation of the chains at low temperatures and to the extent of dehydration that the phase transition evokes. It is concluded that although the temperature-triggered changes in the macroscopic absorption characteristics, related to large-scale alterations of the polymer chain conformation and aggregation, are well detectable and similar for these LCST-type polymers, the micro-environment provided to the dye within each polymer network differs substantially. Considering sensing applications, this finding is of great importance since the temperature-regulated fluorescence response of the polymer depends more on the macromolecular architecture than the type of reporter fluorophore. Y1 - 2013 U6 - https://doi.org/10.1039/c3tc31304b SN - 2050-7526 VL - 1 IS - 40 SP - 6603 EP - 6612 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Men, Yongjun A1 - Siebenbürger, Miriam A1 - Qiu, Xunlin A1 - Antonietti, Markus A1 - Yuan, Jiayin T1 - Low fractions of ionic liquid or poly(ionic liquid) can activate polysaccharide biomass into shaped, flexible and fire-retardant porous carbons JF - Journal of materials chemistry : A, Materials for energy and sustainability N2 - Sugar-based molecules and polysaccharide biomass can be turned into porous functional carbonaceous products at comparably low temperatures of 400 degrees C under a nitrogen atmosphere in the presence of an ionic liquid (IL) or a poly(ionic liquid) (PIL). The IL and PIL act as "activation agents" with own structural contribution, and effectively promote the conversion and pore generation in the biomaterials even at a rather low doping ratio (7 wt%). In addition, this "induced carbonization" and pore forming phenomenon enables the preservation of the biotemplate shape to the highest extent and was employed to fabricate shaped porous carbonaceous materials from carbohydrate-based biotemplates, exemplified here with cellulose filter membranes, coffee filter paper and natural cotton. These carbonized hybrids exhibit comparably good mechanical properties, such as bendability of membranes or shape recovery of foams. Moreover, the nitrogen atoms incorporated in the final products from the IL/PIL precursors further improve the oxidation stability in the fire-retardant tests. Y1 - 2013 U6 - https://doi.org/10.1039/c3ta12302b SN - 2050-7488 VL - 1 IS - 38 SP - 11887 EP - 11893 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Gross, Martina A1 - Warschburger, Petra T1 - Chronic abdominal pain psychosocial strain and treatment-associated changes in coping JF - Verhaltenstherapie N2 - Background: Chronic abdominal pain (CAP) in childhood is a commonly occurring condition and shows a high stability. Psychosocial dysfunctioning of children, such as increased stress experience, is a burden for children and parents and complicates clinical management. Additional comorbid disorders may develop. To minimize the onset of such disorders, treatment at an early stage and taking psychosocial aspects into consideration is strongly recommended. Through this approach, the cognitive-behavioral, child-centered group program 'Stop the pain with Happy-Pingu' was developed, applied, and subsequently evaluated. What is the psychosocial situation of the affected children? Can the cognitive-behavioral group program be applied to improve psychosocial limitations? Method: The cognitive-behavioral group program comprises 6 weekly sessions for children and 1 single meeting for parents. In a randomized controlled study, the program was evaluated with 29 children aged between 6 and 12 years. The evaluation was based on a comparison between the intervention group (IG) and the waiting list control group (WLC), measured at 3 measurement points: T1 (pre), T2 (post), and T3 (3-month follow-up). Results: Emotional problems in particular can emerge in children with CAP. The program was well received, with a high level of participation through to completion. The results demonstrate that children participating in the IG experience significant stress reduction and improved psychosocial functioning compared to children participating in the WLC. The effect sizes range from medium to high. Conclusions: Drawing upon the above findings, multimodal cognitive-behavioral techniques appear to be suitable to successfully treat children with CAP. However, further controlled studies are required to identify the specific elements of the training that are most effective in reducing pain. KW - Cognitive-behavioral therapy KW - Children KW - Abdominal pain KW - Psychosocial functioning KW - Coping Y1 - 2013 U6 - https://doi.org/10.1159/000351215 SN - 1016-6262 VL - 23 IS - 2 SP - 80 EP - 89 PB - Karger CY - Basel ER - TY - JOUR A1 - Nishikawa, Ken-Ichi A1 - Hardee, P. A1 - Zhang, B. A1 - Dutan, I. A1 - Medvedev, M. A1 - Choi, E. J. A1 - Min, K. W. A1 - Niemiec, J. A1 - Mizuno, Y. A1 - Nordlund, Ake A1 - Frederiksen, Jacob Trier A1 - Sol, H. A1 - Pohl, Martin A1 - Hartmann, D. H. T1 - Magnetic field generation in a jet-sheath plasma via the kinetic Kelvin-Helmholtz instability JF - Annales geophysicae N2 - We have investigated the generation of magnetic fields associated with velocity shear between an unmagnetized relativistic jet and an unmagnetized sheath plasma. We have examined the strong magnetic fields generated by kinetic shear (Kelvin-Helmholtz) instabilities. Compared to the previous studies using counter-streaming performed by Alves et al. (2012), the structure of the kinetic Kelvin-Helmholtz instability (KKHI) of our jet-sheath configuration is slightly different, even for the global evolution of the strong transverse magnetic field. In our simulations the major components of growing modes are the electric field E-z, perpendicular to the flow boundary, and the magnetic field B-y, transverse to the flow direction. After the B-y component is excited, an induced electric field E-x, parallel to the flow direction, becomes significant. However, other field components remain small. We find that the structure and growth rate of KKHI with mass ratios m(i)/m(e) = 1836 and m(i)/m(e) = 20 are similar. In our simulations in the nonlinear stage is not as clear as in counter-streaming cases. The growth rate for a mildly-relativistic jet case (gamma(j) = 1.5) is larger than for a relativistic jet case (gamma(j) = 15). KW - Solar physics KW - astrophysics KW - astronomy (Energetic particles) Y1 - 2013 U6 - https://doi.org/10.5194/angeo-31-1535-2013 SN - 0992-7689 VL - 31 IS - 9 SP - 1535 EP - 1541 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Peitsch, Helmut T1 - Rosa Luxembourg in 20th century german literature JF - Zeitschrift für Religions- und Geistesgeschichte Y1 - 2013 SN - 0044-3441 VL - 65 IS - 2 SP - 152 EP - 172 PB - Brill CY - Leiden ER - TY - JOUR A1 - Brechenmacher, Thomas T1 - The apostolic see and totalitarian ideologies the 1937 march-encyclicals in their inner context JF - Historisches Jahrbuch Y1 - 2013 SN - 0018-2621 VL - 133 IS - 2 SP - 342 EP - 364 PB - Alber CY - Freiburg Breisgau ER - TY - JOUR A1 - Huber, Robert A1 - Rigling, Andreas A1 - Bebi, Peter A1 - Brand, Fridolin Simon A1 - Briner, Simon A1 - Buttler, Alexandre A1 - Elkin, Che A1 - Gillet, Francois A1 - Gret-Regamey, Adrienne A1 - Hirschi, Christian A1 - Lischke, Heike A1 - Scholz, Roland Werner A1 - Seidl, Roman A1 - Spiegelberger, Thomas A1 - Walz, Ariane A1 - Zimmermann, Willi A1 - Bugmann, Harald T1 - Sustainable land use in Mountain Regions under global change synthesis across scales and disciplines JF - Ecology and society : a journal of integrative science for resilience and sustainability N2 - Mountain regions provide essential ecosystem goods and services (EGS) for both mountain dwellers and people living outside these areas. Global change endangers the capacity of mountain ecosystems to provide key services. The Mountland project focused on three case study regions in the Swiss Alps and aimed to propose land-use practices and alternative policy solutions to ensure the provision of key EGS under climate and land-use changes. We summarized and synthesized the results of the project and provide insights into the ecological, socioeconomic, and political processes relevant for analyzing global change impacts on a European mountain region. In Mountland, an integrative approach was applied, combining methods from economics and the political and natural sciences to analyze ecosystem functioning from a holistic human-environment system perspective. In general, surveys, experiments, and model results revealed that climate and socioeconomic changes are likely to increase the vulnerability of the EGS analyzed. We regard the following key characteristics of coupled human-environment systems as central to our case study areas in mountain regions: thresholds, heterogeneity, trade-offs, and feedback. Our results suggest that the institutional framework should be strengthened in a way that better addresses these characteristics, allowing for (1) more integrative approaches, (2) a more network-oriented management and steering of political processes that integrate local stakeholders, and (3) enhanced capacity building to decrease the identified vulnerability as central elements in the policy process. Further, to maintain and support the future provision of EGS in mountain regions, policy making should also focus on project-oriented, cross-sectoral policies and spatial planning as a coordination instrument for land use in general. KW - adaptive management KW - climate change KW - ecosystem services KW - experiments KW - interdisciplinary research KW - land-use change KW - modeling KW - transdisciplinary research Y1 - 2013 U6 - https://doi.org/10.5751/ES-05499-180336 SN - 1708-3087 VL - 18 IS - 3 PB - Resilience Alliance CY - Wolfville ER - TY - JOUR A1 - Cherstvy, Andrey G. A1 - Metzler, Ralf T1 - Population splitting, trapping, and non-ergodicity in heterogeneous diffusion processes JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - We consider diffusion processes with a spatially varying diffusivity giving rise to anomalous diffusion. Such heterogeneous diffusion processes are analysed for the cases of exponential, power-law, and logarithmic dependencies of the diffusion coefficient on the particle position. Combining analytical approaches with stochastic simulations, we show that the functional form of the space-dependent diffusion coefficient and the initial conditions of the diffusing particles are vital for their statistical and ergodic properties. In all three cases a weak ergodicity breaking between the time and ensemble averaged mean squared displacements is observed. We also demonstrate a population splitting of the time averaged traces into fast and slow diffusers for the case of exponential variation of the diffusivity as well as a particle trapping in the case of the logarithmic diffusivity. Our analysis is complemented by the quantitative study of the space coverage, the diffusive spreading of the probability density, as well as the survival probability. Y1 - 2013 U6 - https://doi.org/10.1039/c3cp53056f SN - 1463-9076 SN - 1463-9084 VL - 15 IS - 46 SP - 20220 EP - 20235 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Inal, Sahika A1 - Kölsch, Jonas D. A1 - Sellrie, Frank A1 - Schenk, Jörg A. A1 - Wischerhoff, Erik A1 - Laschewsky, André A1 - Neher, Dieter T1 - A water soluble fluorescent polymer as a dual colour sensor for temperature and a specific protein JF - Journal of materials chemistry : B, Materials for biology and medicine N2 - We present two thermoresponsive water soluble copolymers prepared via free radical statistical copolymerization of N-isopropylacrylamide (NIPAm) and of oligo(ethylene glycol) methacrylates (OEGMAs), respectively, with a solvatochromic 7-(diethylamino)-3-carboxy-coumarin (DEAC)-functionalized monomer. In aqueous solutions, the NIPAm-based copolymer exhibits characteristic changes in its fluorescence profile in response to a change in solution temperature as well as to the presence of a specific protein, namely an anti-DEAC antibody. This polymer emits only weakly at low temperatures, but exhibits a marked fluorescence enhancement accompanied by a change in its emission colour when heated above its cloud point. Such drastic changes in the fluorescence and absorbance spectra are observed also upon injection of the anti-DEAC antibody, attributed to the specific binding of the antibody to DEAC moieties. Importantly, protein binding occurs exclusively when the polymer is in the well hydrated state below the cloud point, enabling a temperature control on the molecular recognition event. On the other hand, heating of the polymer-antibody complexes releases a fraction of the bound antibody. In the presence of the DEAC-functionalized monomer in this mixture, the released antibody competitively binds to the monomer and the antibody-free chains of the polymer undergo a more effective collapse and inter-aggregation. In contrast, the emission properties of the OEGMA-based analogous copolymer are rather insensitive to the thermally induced phase transition or to antibody binding. These opposite behaviours underline the need for a carefully tailored molecular design of responsive polymers aimed at specific applications, such as biosensing. Y1 - 2013 U6 - https://doi.org/10.1039/c3tb21245a SN - 2050-750X SN - 2050-7518 VL - 1 IS - 46 SP - 6373 EP - 6381 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Mondal, Suvendu Sekhar A1 - Dey, Subarna A1 - Baburin, Igor A. A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Seifert, Gotthard A1 - Janiak, Christoph A1 - Holdt, Hans-Jürgen T1 - Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal-organic frameworks with flexible ethoxy substituent JF - CrystEngComm N2 - A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H-2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect. Y1 - 2013 U6 - https://doi.org/10.1039/c3ce41632a SN - 1466-8033 VL - 15 IS - 45 SP - 9394 EP - 9399 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Laubrock, Jochen A1 - Cajar, Anke A1 - Engbert, Ralf T1 - Control of fixation duration during scene viewing by interaction of foveal and peripheral processing JF - Journal of vision N2 - Processing in our visual system is functionally segregated, with the fovea specialized in processing fine detail (high spatial frequencies) for object identification, and the periphery in processing coarse information (low frequencies) for spatial orienting and saccade target selection. Here we investigate the consequences of this functional segregation for the control of fixation durations during scene viewing. Using gaze-contingent displays, we applied high-pass or low-pass filters to either the central or the peripheral visual field and compared eye-movement patterns with an unfiltered control condition. In contrast with predictions from functional segregation, fixation durations were unaffected when the critical information for vision was strongly attenuated (foveal low-pass and peripheral high-pass filtering); fixation durations increased, however, when useful information was left mostly intact by the filter (foveal high-pass and peripheral low-pass filtering). These patterns of results are difficult to explain under the assumption that fixation durations are controlled by foveal processing difficulty. As an alternative explanation, we developed the hypothesis that the interaction of foveal and peripheral processing controls fixation duration. To investigate the viability of this explanation, we implemented a computational model with two compartments, approximating spatial aspects of processing by foveal and peripheral activations that change according to a small set of dynamical rules. The model reproduced distributions of fixation durations from all experimental conditions by variation of few parameters that were affected by specific filtering conditions. KW - scene perception KW - spatial frequencies KW - fixation durations KW - computational modeling Y1 - 2013 U6 - https://doi.org/10.1167/13.12.11 SN - 1534-7362 VL - 13 IS - 12 PB - Association for Research in Vision and Opthalmology CY - Rockville ER - TY - JOUR A1 - Barthelme, Simon A1 - Trukenbrod, Hans Arne A1 - Engbert, Ralf A1 - Wichmann, Felix A. T1 - Modeling fixation locations using spatial point processes JF - Journal of vision N2 - Whenever eye movements are measured, a central part of the analysis has to do with where subjects fixate and why they fixated where they fixated. To a first approximation, a set of fixations can be viewed as a set of points in space; this implies that fixations are spatial data and that the analysis of fixation locations can be beneficially thought of as a spatial statistics problem. We argue that thinking of fixation locations as arising from point processes is a very fruitful framework for eye-movement data, helping turn qualitative questions into quantitative ones. We provide a tutorial introduction to some of the main ideas of the field of spatial statistics, focusing especially on spatial Poisson processes. We show how point processes help relate image properties to fixation locations. In particular we show how point processes naturally express the idea that image features' predictability for fixations may vary from one image to another. We review other methods of analysis used in the literature, show how they relate to point process theory, and argue that thinking in terms of point processes substantially extends the range of analyses that can be performed and clarify their interpretation. KW - eye movements KW - fixation locations KW - saliency KW - modeling KW - point process KW - spatial statistics Y1 - 2013 U6 - https://doi.org/10.1167/13.12.1 SN - 1534-7362 VL - 13 IS - 12 PB - Association for Research in Vision and Opthalmology CY - Rockville ER -