TY - JOUR A1 - Rebok, Sandra A1 - Winkle, Timothy T1 - “Mason without apron” BT - Alexander von Humboldt and the world of Freemasonry JF - HiN : Alexander von Humboldt im Netz ; international review for Humboldtian studies N2 - Während das Fehlen einer religiösen Haltung in Humboldts Werk, sowie die Kritik, die er diesbezüglich erhalten hat, allgemein bekannt sind, ist sein möglicher Bezug zur Freimaurerei noch weitgehend unerforscht. Zwar erscheint Humboldt auf einigen Listen von „illustren Freimaurern“, zudem tragen mehrere Logen seinen Namen, aber die Frage bleibt offen, ob Humboldt wirklich ein Freimaurer war. Wenn ja, wann und wo ist er einer Loge beigetreten? Gibt es vielleicht Kommentare von ihm zu dieser Art von Geheimbünden? Und wer waren die bekanntesten Freimaurer in seiner Umgebung? Der Artikel beantwortet diese Punkte, aber wichtiger noch geht er der Frage nach, was eine Mitgliedschaft für Humboldts wissenschaftliche Arbeit bedeutet haben könnte, insbesondere im Hinblick auf den herausragenden Erfolg, den er in den Vereinigten Staaten zu Beginn des 19. Jahrhunderts hatte und die Gründe hierfür. Was hätten solche Verbindungen für ihn bedeutet und wie wurde er von den wichtigsten freimaurerischen Persönlichkeiten und Logen in der transatlantischen Welt wahrgenommen? N2 - While the lack of religion in Alexander von Humboldt’s work and the criticism he received is well known, his relationship with Freemasonry is relatively unexplored. Humboldt appears on some lists of “illustrious Masons,” and several lodges carry his name, but was he really a member? If so, when and where did he join a lodge? Are there any comments by him about Freemasonry? Who were the renowned Masons he was surrounded by? This paper examines these questions, but more importantly it analyzes what a membership might have meant for Humboldt’s scholarly work. It looks particularly at the unprecedented success he enjoyed in the United States in the early 19th century and the factors behind it. What could he have gained from these connections and how was he viewed by Masonic leaders and lodges in the trans-Atlantic world? N2 - Mientras que la falta de religiosidad en la obra de Alexander von Humboldt, así como las críticas por ello recibidas, son bien conocidas, su posible relación con la masonería es relativamente incógnita. Humboldt aparece en algunas listas de “masones ilustres” y varias logias llevan su nombre pero, ¿fue realmente miembro de una de ellas? Y en este supuesto, ¿cuándo y dónde se adhirió?, ¿existen comentarios suyos sobre la masonería?, ¿qué masones de renombre le rodearon? Este artículo estudia estas cuestiones pero, de manera más importante, analiza lo que la membresía de una logia masónica podría haber significado para el trabajo académico de Humboldt. En particular, mira el éxito sin precedentes del que disfrutó en los Estados Unidos a comienzos del siglo xix y los motivos para ello. ¿Qué podria haber ganado de estas conexiones y cómo fue visto por los líderes y logias masónicas en el mundo transatlántico? KW - Masonry KW - Atlantic history KW - intellectual networks KW - religion KW - Enlightenment KW - Masonería KW - Historia atlántica KW - redes intelectuales KW - religión KW - Ilustración KW - Freimaurerei KW - Atlantische Geschichte KW - intellektuelle Netzwerke KW - Religion KW - Aufklärung Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-434735 SN - 2568-3543 SN - 1617-5239 VL - XX IS - 38 SP - 31 EP - 50 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Hennemann, Anja T1 - “I mean, no soy psicóloga” BT - The English discourse marker I mean in Spanish and Portuguese online communication N2 - This paper is concerned with the qualitative analysis of the use of the English discourse marker I mean in Spanish and Portuguese online discourses (in online fora, blogs or user comments on websites). The examples are retrieved from the Corpus del Español (Web/ Dialects) as well as the Corpus do Português (Web/ Dialects). KW - I mean KW - discourse marker KW - Spanish discourse KW - Portuguese discourse KW - Code-switching KW - Borrowing Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-430984 ER - TY - JOUR A1 - Baesler, Jessica A1 - Kopp, Johannes Florian A1 - Pohl, Gabriele A1 - Aschner, Michael A1 - Haase, Hajo A1 - Schwerdtle, Tanja A1 - Bornhorst, Julia T1 - Zn homeostasis in genetic models of Parkinson’s disease in Caenorhabditis elegans JF - Journal of Trace Elements in Medicine and Biology N2 - While the underlying mechanisms of Parkinson’s disease (PD) are still insufficiently studied, a complex interaction between genetic and environmental factors is emphasized. Nevertheless, the role of the essential trace element zinc (Zn) in this regard remains controversial. In this study we altered Zn balance within PD models of the versatile model organism Caenorhabditis elegans (C. elegans) in order to examine whether a genetic predisposition in selected genes with relevance for PD affects Zn homeostasis. Protein-bound and labile Zn species act in various areas, such as enzymatic catalysis, protein stabilization pathways and cell signaling. Therefore, total Zn and labile Zn were quantitatively determined in living nematodes as individual biomarkers of Zn uptake and bioavailability with inductively coupled plasma tandem mass spectrometry (ICP-MS/MS) or a multi-well method using the fluorescent probe ZinPyr-1. Young and middle-aged deletion mutants of catp-6 and pdr-1, which are orthologues of mammalian ATP13A2 (PARK9) and parkin (PARK2), showed altered Zn homeostasis following Zn exposure compared to wildtype worms. Furthermore, age-specific differences in Zn uptake were observed in wildtype worms for total as well as labile Zn species. These data emphasize the importance of differentiation between Zn species as meaningful biomarkers of Zn uptake as well as the need for further studies investigating the role of dysregulated Zn homeostasis in the etiology of PD. KW - Caenorhabditis elegans KW - Zinc KW - Zinc homeostasis KW - Parkinson disease KW - Labile zinc Y1 - 2019 U6 - https://doi.org/10.1016/j.jtemb.2019.05.005 VL - 55 SP - 44 EP - 49 PB - Elsevier CY - München ER - TY - JOUR A1 - Baesler, Jessica A1 - Kopp, Johannes F. A1 - Pohl, Gabriele A1 - Aschner, Michael A1 - Haase, Hajo A1 - Schwerdtle, Tanja A1 - Bornhorst, Julia T1 - Zn homeostasis in genetic models of Parkinson’s disease in Caenorhabditis elegans JF - Journal of trace elements in medicine and biology KW - Caenorhabditis elegans KW - Zinc KW - Zinc homeostasis KW - Parkinson disease KW - Labile zinc Y1 - 2019 U6 - https://doi.org/10.1016/j.jtemb.2019.05.005 SN - 0946-672X VL - 55 SP - 44 EP - 49 PB - Elsevier GMBH CY - München ER - TY - JOUR A1 - Strotseva-Feinschmidt, Anna A1 - Schipke, Christine S. A1 - Gunter, Thomas C. A1 - Brauer, Jens A1 - Friederici, Angela D. T1 - Young children’s sentence comprehension T1 - Neural correlates of syntax-semantic competition JF - Brain and cognition : a journal of experimental and clinical research N2 - Sentence comprehension requires the assignment of thematic relations between the verb and its noun arguments in order to determine who is doing what to whom. In some languages, such as English, word order is the primary syntactic cue. In other languages, such as German, case-marking is additionally used to assign thematic roles. During development children have to acquire the thematic relevance of these syntactic cues and weigh them against semantic cues. Here we investigated the processing of syntactic cues and semantic cues in 2- and 3-year-old children by analyzing their behavioral and neurophysiological responses. Case-marked subject-first and object-first sentences (syntactic cue) including animate and inanimate nouns (semantic cue) were presented auditorily. The semantic animacy cue either conflicted with or supported the thematic roles assigned by syntactic case-marking. In contrast to adults, for whom semantics did not interfere with case-marking, children attended to both syntactic and to semantic cues with a stronger reliance on semantic cues in early development. Children’s event-related brain potentials indicated sensitivity to syntactic information but increased processing costs when case-marking and animacy assigned conflicting thematic roles. These results demonstrate an early developmental sensitivity and ongoing shift towards the use of syntactic cues during sentence comprehension. Y1 - 2018 U6 - https://doi.org/10.1016/j.bandc.2018.09.003 SN - 0278-2626 SN - 1090-2147 VL - 134 SP - 110 EP - 121 PB - Elsevier CY - San Diego ER - TY - JOUR A1 - Kayhan, Ezgi A1 - Heil, Lieke A1 - Kwisthout, Johan A1 - van Rooij, Iris A1 - Hunnius, Sabine A1 - Bekkering, Harold T1 - Young children integrate current observations, priors and agent information to predict others’ actions JF - PLOS ONE / Public Library of Science N2 - From early on in life, children are able to use information from their environment to form predictions about events. For instance, they can use statistical information about a population to predict the sample drawn from that population and infer an agent’s preferences from systematic violations of random sampling. We investigated whether and how young children infer an agent’s sampling biases. Moreover, we examined whether pupil data of toddlers follow the predictions of a computational model based on the causal Bayesian network formalization of predictive processing. We formalized three hypotheses about how different explanatory variables (i.e., prior probabilities, current observations, and agent characteristics) are used to predict others’ actions. We measured pupillary responses as a behavioral marker of ‘prediction errors’ (i.e., the perceived mismatch between what one’s model of an agent predicts and what the agent actually does). Pupillary responses of 24-month-olds, but not 18-month-olds, showed that young children integrated information about current observations, priors and agents to make predictions about agents and their actions. These findings shed light on the mechanisms behind toddlers’ inferences about agent-caused events. To our knowledge, this is the first study in which young children's pupillary responses are used as markers of prediction errors, which were qualitatively compared to the predictions by a computational model based on the causal Bayesian network formalization of predictive processing. Y1 - 2019 U6 - https://doi.org/10.1371/journal.pone.0200976 SN - 1932-6203 VL - 14 IS - 5 PB - PLOS CY - San Fransisco ER - TY - JOUR A1 - Pliatsikas, Christos A1 - Verissimo, Joao Marques A1 - Babcock, Laura A1 - Pullman, Mariel Y. A1 - Glei, Dana A. A1 - Weinstein, Maxine A1 - Goldman, Noreen A1 - Ullman, Michael T. T1 - Working memory in older adults declines with age, but is modulated by sex and education JF - The quarterly journal of experimental psychology N2 - Working memory (WM), which underlies the temporary storage and manipulation of information, is critical for multiple aspects of cognition and everyday life. Nevertheless, research examining WM specifically in older adults remains limited, despite the global rapid increase in human life expectancy. We examined WM in a large sample (N=754) of healthy older adults (aged 58-89) in a non-Western population (Chinese speakers) in Taiwan, on a digit n-back task. We tested not only the influence of age itself and of load (1-back vs. 2-back) but also the effects of both sex and education, which have been shown to modulate WM abilities. Mixed-effects regression revealed that, within older adulthood, age negatively impacted WM abilities (with linear, not nonlinear, effects), as did load (worse performance at 2-back). In contrast, education level was positively associated with WM. Moreover, both age and education interacted with sex. With increasing age, males showed a steeper WM decline than females; with increasing education, females showed greater WM gains than males. Together with other findings, the evidence suggests that age, sex, and education all impact WM in older adults, but interact in particular ways. The results have both basic research and translational implications and are consistent with particular benefits from increased education for women. KW - Ageing KW - sex differences KW - education KW - working memory KW - n back Y1 - 2018 U6 - https://doi.org/10.1177/1747021818791994 SN - 1747-0218 SN - 1747-0226 VL - 72 IS - 6 SP - 1308 EP - 1327 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Eiteljoerge, Sarah F. V. A1 - Adam, Maurits A1 - Elsner, Birgit A1 - Mani, Nivedita T1 - Word-object and action-object association learning across early development JF - PLoS one N2 - Successful communication often involves comprehension of both spoken language and observed actions with and without objects. Even very young infants can learn associations between actions and objects as well as between words and objects. However, in daily life, children are usually confronted with both kinds of input simultaneously. Choosing the critical information to attend to in such situations might help children structure the input, and thereby, allow for successful learning. In the current study, we therefore, investigated the developmental time course of children’s and adults’ word and action learning when given the opportunity to learn both word-object and action-object associations for the same object. All participants went through a learning phase and a test phase. In the learning phase, they were presented with two novel objects which were associated with a distinct novel name (e.g., “Look, a Tanu”) and a distinct novel action (e.g., moving up and down while tilting sideways). In the test phase, participants were presented with both objects on screen in a baseline phase, then either heard one of the two labels or saw one of the two actions in a prime phase, and then saw the two objects again on screen in a recognition phase. Throughout the trial, participants’ target looking was recorded to investigate whether participants looked at the target object upon hearing its label or seeing its action, and thus, would show learning of the word-object and action-object associations. Growth curve analyses revealed that 12-month-olds showed modest learning of action-object associations, 36-month-olds learned word-object associations, and adults learned word-object and action-object associations. These results highlight how children attend to the different information types from the two modalities through which communication is addressed to them. Over time, with increased exposure to systematic word-object mappings, children attend less to action-object mappings, with the latter potentially being mediated by word-object learning even in adulthood. Thus, choosing between different kinds of input that may be more relevant in their rich environment encompassing different modalities might help learning at different points in development. Y1 - 2019 U6 - https://doi.org/10.1371/journal.pone.0220317 SN - 1932-6203 VL - 14 IS - 8 PB - PLoS CY - San Fransisco ER - TY - JOUR A1 - Paraskevopoulou, Sofia A1 - Dennis, Alice B. A1 - Weithoff, Guntram A1 - Hartmann, Stefanie A1 - Tiedemann, Ralph T1 - Within species expressed genetic variability and gene expression response to different temperatures in the rotifer Brachionus calyciflorus sensu stricto JF - PLoS ONE N2 - Genetic divergence is impacted by many factors, including phylogenetic history, gene flow, genetic drift, and divergent selection. Rotifers are an important component of aquatic ecosystems, and genetic variation is essential to their ongoing adaptive diversification and local adaptation. In addition to coding sequence divergence, variation in gene expression may relate to variable heat tolerance, and can impose ecological barriers within species. Temperature plays a significant role in aquatic ecosystems by affecting species abundance, spatio-temporal distribution, and habitat colonization. Recently described (formerly cryptic) species of the Brachionus calyciflorus complex exhibit different temperature tolerance both in natural and in laboratory studies, and show that B. calyciflorus sensu stricto (s.s.) is a thermotolerant species. Even within B. calyciflorus s.s., there is a tendency for further temperature specializations. Comparison of expressed genes allows us to assess the impact of stressors on both expression and sequence divergence among disparate populations within a single species. Here, we have used RNA-seq to explore expressed genetic diversity in B. calyciflorus s.s. in two mitochondrial DNA lineages with different phylogenetic histories and differences in thermotolerance. We identify a suite of candidate genes that may underlie local adaptation, with a particular focus on the response to sustained high or low temperatures. We do not find adaptive divergence in established candidate genes for thermal adaptation. Rather, we detect divergent selection among our two lineages in genes related to metabolism (lipid metabolism, metabolism of xenobiotics). Y1 - 2019 U6 - https://doi.org/10.1371/journal.pone.0223134 SN - 1932-6203 VL - 9 IS - 14 PB - PLoS ONE CY - San Francisco, California ER - TY - JOUR A1 - Busch, Verena A1 - Klaus, Valentin Helmut A1 - Schaefer, Deborah A1 - Prati, Daniel A1 - Boch, Steffen A1 - Müller, Jörg A1 - Chiste, Melanie A1 - Mody, Karsten A1 - Blüthgen, Nico A1 - Fischer, Markus A1 - Hölzel, Norbert A1 - Kleinebecker, Till T1 - Will I stay or will I go? Plant species-specific response and tolerance to high land-use intensity in temperate grassland ecosystems JF - Journal of vegetation science KW - community composition KW - ecological strategies KW - Ellenberg indicator values KW - land-use intensity niche KW - plant functional traits KW - species-specific niche breadth KW - species-specific niche optima KW - temperate grasslands KW - vegetation dynamics Y1 - 2019 U6 - https://doi.org/10.1111/jvs.12749 SN - 1100-9233 SN - 1654-1103 VL - 30 IS - 4 SP - 674 EP - 686 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Treat, Claire C. A1 - Kleinen, Thomas A1 - Broothaerts, Nils A1 - Dalton, April S. A1 - Dommain, Rene A1 - Douglas, Thomas A. A1 - Drexler, Judith Z. A1 - Finkelstein, Sarah A. A1 - Grosse, Guido A1 - Hope, Geoffrey A1 - Hutchings, Jack A1 - Jones, Miriam C. A1 - Kuhry, Peter A1 - Lacourse, Terri A1 - Lahteenoja, Outi A1 - Loisel, Julie A1 - Notebaert, Bastiaan A1 - Payne, Richard J. A1 - Peteet, Dorothy M. A1 - Sannel, A. Britta K. A1 - Stelling, Jonathan M. A1 - Strauss, Jens A1 - Swindles, Graeme T. A1 - Talbot, Julie A1 - Tarnocai, Charles A1 - Verstraeten, Gert A1 - Williams, Christopher J. A1 - Xia, Zhengyu A1 - Yu, Zicheng A1 - Valiranta, Minna A1 - Hattestrand, Martina A1 - Alexanderson, Helena A1 - Brovkin, Victor T1 - Widespread global peatland establishment and persistence over the last 130,000 y JF - Proceedings of the National Academy of Sciences of the United States of America N2 - Glacial-interglacial variations in CO2 and methane in polar ice cores have been attributed, in part, to changes in global wetland extent, but the wetland distribution before the Last Glacial Maximum (LGM, 21 ka to 18 ka) remains virtually unknown. We present a study of global peatland extent and carbon (C) stocks through the last glacial cycle (130 ka to present) using a newly compiled database of 1,063 detailed stratigraphic records of peat deposits buried by mineral sediments, as well as a global peatland model. Quantitative agreement between modeling and observations shows extensive peat accumulation before the LGM in northern latitudes (> 40 degrees N), particularly during warmer periods including the last interglacial (130 ka to 116 ka, MIS 5e) and the interstadial (57 ka to 29 ka, MIS 3). During cooling periods of glacial advance and permafrost formation, the burial of northern peatlands by glaciers and mineral sediments decreased active peatland extent, thickness, and modeled C stocks by 70 to 90% from warmer times. Tropical peatland extent and C stocks show little temporal variation throughout the study period. While the increased burial of northern peats was correlated with cooling periods, the burial of tropical peat was predominately driven by changes in sea level and regional hydrology. Peat burial by mineral sediments represents a mechanism for long-term terrestrial C storage in the Earth system. These results show that northern peatlands accumulate significant C stocks during warmer times, indicating their potential for C sequestration during the warming Anthropocene. KW - peatlands KW - carbon KW - methane KW - carbon burial KW - Quaternary Y1 - 2019 U6 - https://doi.org/10.1073/pnas.1813305116 SN - 0027-8424 VL - 116 IS - 11 SP - 4822 EP - 4827 PB - National Acad. of Sciences CY - Washington ER - TY - JOUR A1 - Stöver, Bernd T1 - Why no global peace order in 1945? BT - On the Failure of a World Security System after World War II JF - Historisches Jahrbuch Y1 - 2019 SN - 0018-2621 VL - 139 SP - 131 EP - 162 PB - Herder CY - Freiburg Breisgau ER - TY - JOUR A1 - Błaszczak, Joanna T1 - Why is a predicate inversion analysis problematic? BT - Insights from existential, locative and possessive constructions JF - Of trees and birds. A Festschrift for Gisbert Fanselow KW - Festschrift KW - Informationsstruktur KW - Linguistik KW - Morphologie KW - Syntax KW - festschrift KW - information structure KW - linguistics KW - morphology KW - syntax Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-432240 SN - 978-3-86956-457-9 SP - 119 EP - 133 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Moffitt, Ursula Elinor A1 - Juang, Linda P. T1 - Who is "German" and who is a "migrant?" Constructing Otherness in education and psychology research JF - European Educational Research Journal N2 - Despite growing European and global interconnectedness, questions of national identity have only gained in importance in recent years. Yet the role researchers play in perpetuating norms of national belonging has gone largely unexamined. Who is included in unmarked national group labels such as German, Dutch, or Danish, who is understood as Other, and how terminology relates to exclusionary notions of national identity warrants greater investigation. Thus, using an exploratory review of recent research in the German context, the current study aimed to (a) identify relevant terminology in empirical education and psychology studies; (b) employ constructionist analysis to examine its situated meaning; (c) discuss societal and methodological implications; and (d) propose guidelines for more accurate and inclusive research. Based on a constructionist thematic analysis, a reiteration of a white ingroup and perceived immigrant Other was found. This dichotomy reinforces an exclusionary notion of who is German while omitting relevant information, such as participant generation or citizenship, from analyses. In doing so, researchers are perpetuating essentialized notions of national belonging while reporting incomplete and potentially inaccurate findings. Though selecting demographic information can be complex, recognizing the impact of labels and acknowledging heterogeneity are essential elements of inclusive and representative research. KW - Exploratory review KW - German identity KW - migration background KW - group labels KW - social constructionism KW - education research KW - psychology research KW - racialization Y1 - 2019 U6 - https://doi.org/10.1177/1474904119827459 SN - 1474-9041 VL - 18 IS - 6 SP - 656 EP - 674 PB - Sage Publ. CY - London ER - TY - JOUR A1 - Krah, Markus A1 - Thulin, Mirjam T1 - Which Works in Jewish Studies Should Urgently Be (Re-)Translated? JF - PaRDeS : Zeitschrift der Vereinigung für Jüdische Studien = Transformative Translations in Jewish History and Culture Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-471426 SN - 978-3-86956-468-5 SN - 1614-6492 SN - 1862-7684 VL - 2019 IS - 25 SP - 147 EP - 155 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Zhu, Chuanbin A1 - Pilz, Marco A1 - Cotton, Fabrice T1 - Which is a better proxy, site period or depth to bedrock, in modelling linear site response in addition to the average shear-wave velocity? JF - Bulletin of earthquake engineering : official publication of the European Association for Earthquake Engineering N2 - This study aims to identify the best-performing site characterization proxy alternative and complementary to the conventional 30 m average shear-wave velocity V-S30, as well as the optimal combination of proxies in characterizing linear site response. Investigated proxies include T-0 (site fundamental period obtained from earthquake horizontal-to-vertical spectral ratios), V-Sz (measured average shear-wave velocities to depth z, z = 5, 10, 20 and 30 m), Z(0.8) and Z(1.0) (measured site depths to layers having shear-wave velocity 0.8 and 1.0 km/s, respectively), as well as Z(x-infer) (inferred site depths from a regional velocity model, x = 0.8 and 1.0, 1.5 and 2.5 km/s). To evaluate the performance of a site proxy or a combination, a total of 1840 surface-borehole recordings is selected from KiK-net database. Site amplifications are derived using surface-to-borehole response-, Fourier- and cross-spectral ratio techniques and then are compared across approaches. Next, the efficacies of 7 single-proxies and 11 proxy-pairs are quantified based on the site-to-site standard deviation of amplification residuals of observation about prediction using the proxy or the pair. Our results show that T-0 is the best-performing single-proxy among T-0, Z(0.8), Z(1.0) and V-Sz. Meanwhile, T-0 is also the best-performing proxy among T-0, Z(0.8), Z(1.0) and Z(x-infer) complementary to V-S30 in accounting for the residual amplification after V-S30-correction. Besides, T-0 alone can capture most of the site effects and should be utilized as the primary site indicator. Though (T-0, V-S30) is the best-performing proxy pair among (V-S30, T-0), (V-S30, Z(0.8)), (V-S30, Z(1.0)), (V-S30, Z(x-infer)) and (T-0, V-Sz), it is only slightly better than (T-0, V-S20). Considering both efficacy and engineering utility, the combination of T-0 (primary) and V-S20 (secondary) is recommended. Further study is needed to test the performances of various proxies on sites in deep sedimentary basins. KW - Site effects KW - Amplification KW - Site proxy KW - Surface-to-borehole spectral ratios KW - KiK-net KW - Earthquake Y1 - 2019 U6 - https://doi.org/10.1007/s10518-019-00738-6 SN - 1570-761X SN - 1573-1456 VL - 18 IS - 3 SP - 797 EP - 820 PB - Springer CY - Dordrecht ER - TY - JOUR A1 - Hall, Joan Kelly A1 - Malabarba, Taiane A1 - Kimura, Daisuke T1 - What’s Symmetrical? BT - A Teacher’s Cooperative Management of Learner Turns in a Read-aloud Activity JF - The Embodied Work of Teaching N2 - This chapter investigates teacher management of learner turns in an American second-grade classroom during a read-aloud activity. A read-aloud is a whole-group instructional activity which involves a teacher read-ing aloud a book to a cohort of students as they listen (Tainio & Slotte, 2017). Using ethnomethodological conversation analysis (EMCA) and drawing on the concepts of alignment and affi liation (Steensig, 2012; Stivers, 2008; Stivers et al., 2011), we investigate how embodied practices such as gaze, facial expressions, body positioning and gestures in addition to verbal practices are used by the teacher separately and together to respond to learner turns in ways that keep the learners aff ectively engaged and, at the same time, ensure the orderly progression of the lesson. Our analysis shows that teacher cooperative management of learners’ turns involves: (1) orient-ing to them as affi liative tokens in order to neutralize their disaligning force while still treating learners as cooperative participants in the activity; and (2) managing turns not only according to their sequential positions and the actions they project but, just as importantly, to the larger instructional proj-ect being accomplished. The study contributes to the re-specifi cation of the everyday grounds of teaching in order to broaden understandings of the specialized nature of such work (Macbeth, 2014). Y1 - 2019 SN - 978-1-78892-548-8 SN - 978-1-78892-550-1 SN - 978-1-78892-549-5 U6 - https://doi.org/10.21832/9781788925501-006 VL - 75 SP - 37 EP - 56 PB - Multilingual Matters CY - Bristol ER - TY - JOUR A1 - Heße, Falk A1 - Comunian, Alessandro A1 - Attinger, Sabine T1 - What We Talk About When We Talk About Uncertainty BT - Toward a Unified, Data-Driven Framework for Uncertainty Characterization in Hydrogeology JF - Frontiers in Earth Science KW - Bayesianism KW - uncertainty analysis KW - hydrogeology KW - data science KW - opinion KW - prior derivation Y1 - 2019 U6 - https://doi.org/10.3389/feart.2019.00118 SN - 2296-6463 VL - 7 PB - Frontiers Media CY - Lausanne ER - TY - JOUR A1 - Fay, Doris A1 - Urbach, Tina A1 - Scheithauer, Linda T1 - What motivates you right now? BT - Development of a measure of momentary-chronic regulatory focus JF - Measurement Instruments for the Social Sciences N2 - Regulatory focus is a motivational construct that describes humans’ motivational orientation during goal pursuit. It is conceptualized as a chronic, trait-like, as well as a momentary, state-like orientation. Whereas there is a large number of measures to capture chronic regulatory focus, measures for its momentary assessment are only just emerging. This paper presents the development and validation of a measure of Momentary–Chronic Regulatory Focus. Our development incorporates the distinction between self-guide and reference-point definitions of regulatory focus. Ideals and ought striving are the promotion and prevention dimension in the self-guide system; gain and non-loss regulatory focus are the respective dimensions within the reference-point system. Three-survey-based studies test the structure, psychometric properties, and validity of the measure in its version to assess chronic regulatory focus (two samples of working participants, N = 389, N = 672; one student sample [time 1, N = 105; time 2, n = 91]). In two further studies, an experience sampling study with students (N = 84, k = 1649) and a daily-diary study with working individuals (N = 129, k = 1766), the measure was applied to assess momentary regulatory focus. Multilevel analyses test the momentary measure’s factorial structure, provide support for its sensitivity to capture within-person fluctuations, and provide evidence for concurrent construct validity. KW - Regulatory focus KW - State and trait measurement KW - Scale development KW - Diary study KW - Experience sampling method Y1 - 2019 U6 - https://doi.org/10.1186/s42409-019-0007-7 SN - 2523-8930 VL - 2 IS - 5 PB - BioMed Central CY - London ER - TY - JOUR A1 - Richter, Dirk A1 - Kleinknecht, Marc A1 - Gröschner, Alexander T1 - What motivates teachers to participate in professional development? An empirical investigation of motivational orientations and the uptake of formal learning opportunities JF - Teaching and Teacher Education Y1 - 2019 U6 - https://doi.org/10.1016/j.tate.2019.102929 SN - 0742-051X VL - 86 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Schosser, Josef A1 - Ströbele, Heiko T1 - What is the value of Facebook? BT - Evidence from the Schwartz/Moon model JF - Journal of risk finance N2 - On May 17, 2012, the social networking company Facebook Inc. fixes its initial public offering (IPO) price at $38.00 a share. Over the next couple of months, contrary to expectations raised by previous IPOs, the stock price crashes more than 50 per cent. Immediately, the question arises whether the issuer’s or the stock market’s pricing of the share are in line with the firm’s fundamentals. Thus, the purpose of this paper is to determine the company value in close proximity to the date of IPO. KW - Facebook KW - Firm valuation KW - Growth company KW - Initial public offering KW - Real options KW - Schwartz KW - Moon model KW - G32 Y1 - 2019 U6 - https://doi.org/10.1108/JRF-05-2018-0069 SN - 1526-5943 SN - 2331-2947 VL - 20 IS - 3 SP - 267 EP - 290 PB - Emerald Group Publishing Limited CY - Bingley ER - TY - JOUR A1 - Mah, Dana-Kristin A1 - Ifenthaler, Dirk T1 - What do first-year students need? BT - digital badges for academic support to enhance student retention JF - Journal of applied research in higher education N2 - The purpose of this paper is to analyse data on first-year students’ needs regarding academic support services and reasons for their intention to leave the institution prior to degree completion. On the basis of the findings, a digital badge outline is proposed which could contribute to improved communication of academic requirements in order to help students to better adapt to higher education demands. Digital badges might also serve as an indicator for students’ needing additional academic support services. KW - Higher education KW - Retention KW - Learning analytics KW - First-year students Y1 - 2019 U6 - https://doi.org/10.1108/JARHE-12-2018-0258 SN - 2050-7003 SN - 1758-1184 VL - 12 IS - 1 SP - 86 EP - 96 PB - Emerald Group Publishing Limited CY - Bingley ER - TY - JOUR A1 - Tötzke, Christian A1 - Kardjilov, Nikolay A1 - Lenoir, Nicolas A1 - Manke, Ingo A1 - Oswald, Sascha A1 - Tengattini, Alessandro T1 - What comes NeXT? BT - High-Speed Neutron Tomography at ILL JF - Optics express : the international electronic journal of optics N2 - Here, we report on a new record in the acquisition time for fast neutron tomography. With an optimized imaging setup, it was possible to acquire single radiographic projection images with 10 ms and full tomographies with 155 projections images and a physical spatial resolution of 200 mu m within 1.5 s. This is about 6.7 times faster than the current record. We used the technique to investigate the water infiltration in the soil with a living lupine root system. The fast imaging setup will be part of the future NeXT instrument at ILL in Grenoble with a great field of possible future applications. (C) 2019 Optical Society of America under the terms of the OSA Open Access Publishing Agreement Y1 - 2019 U6 - https://doi.org/10.1364/OE.27.028640 SN - 1094-4087 VL - 27 IS - 20 SP - 28640 EP - 28648 PB - Optical Society of America CY - Washington ER - TY - JOUR A1 - Aldrup, Marit T1 - Well let me put it uhm the other way around maybe’ BT - Managing students’ trouble displays in the CLIL classroom JF - Classroom discourse N2 - This study is concerned with repair practices that a teacher and students employ to restore intersubjectivity when faced with interactional problems in a Content and Language Integrated Learning (CLIL) classroom. Adopting a conversation analytic (CA) approach, it examines the interactional treatment of students’ verbal and embodied trouble displays in a video-recorded, teacher-fronted geography lesson held in English at a German high school. At the same time, it explores to what extent the repair practices employed are fitted to this specific interactional context. The analysis shows that students’ verbal trouble displays often result in extensive repair sequences, whereas students’ embodied trouble displays are usually met with teacher self-repair in the transition space. In this way, the latter are resolved much earlier and more quickly. The study further reveals practices like reformulation and translation to be especially useful for repairing interactional problems in classrooms in which a foreign language is used as the medium of instruction. The findings may be of interest for prospective as well as practicing teachers in that they provide relevant insights into how interactional trouble can be successfully managed in (CLIL) classroom interaction. KW - Trouble displays KW - repair KW - embodiment KW - classroom interaction KW - conversation analysis Y1 - 2019 U6 - https://doi.org/10.1080/19463014.2019.1567360 SN - 1946-3014 SN - 1946-3022 VL - 10 IS - 1 SP - 46 EP - 70 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Kalczewiak, Mariusz T1 - We Hope to Find a Way Out from Our Unpleasant Situation BT - Polish-Jewish Refugees and the Escape from Nazi Europe to Latin America JF - American Jewish History Y1 - 2019 U6 - https://doi.org/10.1353/ajh.2019.0002 SN - 0164-0178 SN - 1086-3141 VL - 103 IS - 1 SP - 25 EP - 49 PB - Johns Hopkins Univ. Press CY - Baltimore ER - TY - JOUR A1 - Maheswaran, Rathinasamy A1 - Agarwal, Ankit A1 - Sivakumar, Bellie A1 - Marwan, Norbert A1 - Kurths, Jürgen T1 - Wavelet analysis of precipitation extremes over India and teleconnections to climate indices JF - Stochastic Environmental Research and Risk Assessment N2 - Precipitation patterns and extremes are significantly influenced by various climatic factors and large-scale atmospheric circulation patterns. This study uses wavelet coherence analysis to detect significant interannual and interdecadal oscillations in monthly precipitation extremes across India and their teleconnections to three prominent climate indices, namely, Nino 3.4, Pacific Decadal Oscillation, and Indian Ocean Dipole (IOD). Further, partial wavelet coherence analysis is used to estimate the standalone relationship between the climate indices and precipitation after removing the effect of interdependency. The wavelet analysis of monthly precipitation extremes at 30 different locations across India reveals that (a) interannual (2-8 years) and interdecadal (8-32 years) oscillations are statistically significant, and (b) the oscillations vary in both time and space. The results from the partial wavelet coherence analysis reveal that Nino 3.4 and IOD are the significant drivers of Indian precipitation at interannual and interdecadal scales. Intriguingly, the study also confirms that the strength of influence of large-scale atmospheric circulation patterns on Indian precipitation extremes varies with spatial physiography of the region. KW - Extreme precipitation KW - Teleconnection patterns KW - Wavelets KW - Partial wavelet coherence KW - India Y1 - 2019 U6 - https://doi.org/10.1007/s00477-019-01738-3 SN - 1436-3240 SN - 1436-3259 VL - 33 IS - 11-12 SP - 2053 EP - 2069 PB - Springer CY - New York ER - TY - JOUR A1 - Stolterfoht, Martin A1 - Le Corre, Vincent M. A1 - Feuerstein, Markus A1 - Caprioglio, Pietro A1 - Koster, Lambert Jan Anton A1 - Neher, Dieter T1 - Voltage-Dependent Photoluminescence and How It Correlates with the Fill Factor and Open-Circuit Voltage in Perovskite Solar Cells JF - Acs energy letters N2 - Optimizing the photoluminescence (PL) yield of a solar cell has long been recognized as a key principle to maximize the power conversion efficiency. While PL measurements are routinely applied to perovskite films and solar cells under open circuit conditions (V-OC), it remains unclear how the emission depends on the applied voltage. Here, we performed PL(V) measurements on perovskite cells with different hole transport layer thicknesses and doping concentrations, resulting in remarkably different fill factors (FFs). The results reveal that PL(V) mirrors the current-voltage (JV) characteristics in the power-generating regime, which highlights an interesting correlation between radiative and nonradiative recombination losses. In particular, high FF devices show a rapid quenching of PL(V) from open-circuit to the maximum power point. We conclude that, while the PL has to be maximized at V-OC at lower biases < V-OC the PL must be rapidly quenched as charges need to be extracted prior to recombination. Y1 - 2019 U6 - https://doi.org/10.1021/acsenergylett.9b02262 SN - 2380-8195 VL - 4 IS - 12 SP - 2887 EP - 2892 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Gerecke, Christian A1 - Schumacher, Fabian A1 - Berndzen, Alide A1 - Homann, Thomas A1 - Kleuser, Burkhard T1 - Vitamin C in combination with inhibition of mutant IDH1 synergistically activates TET enzymes and epigenetically modulates gene silencing in colon cancer cells JF - Epigenetics : the official journal of the DNA Methylation Society N2 - Mutations in the enzyme isocitrate dehydrogenase 1 (IDH1) lead to metabolic alterations and a sustained formation of 2-hydroxyglutarate (2-HG). 2-HG is an oncometabolite as it inhibits the activity of alpha-ketoglutarate-dependent dioxygenases such as ten-eleven translocation (TET) enzymes. Inhibitors of mutant IDH enzymes, like ML309, are currently tested in order to lower the levels of 2-HG. Vitamin C (VC) is an inducer of TET enzymes. To test a new therapeutic avenue of synergistic effects, the anti-neoplastic activity of inhibition of mutant IDH1 via ML309 in the presence of VC was investigated in the colon cancer cell line HCT116 IDH1(R132H/+) (harbouring a mutated IDH1 allele) and the parental cells HCT116 IDH1(+/+) (wild type IDH1). Measurement of the oncometabolite indicated a 56-fold higher content of 2-HG in mutated cells compared to wild type cells. A significant reduction of 2-HG was observed in mutated cells after treatment with ML 309, whereas VC produced only minimally changes of the oncometabolite. However, combinatorial treatment with both, ML309 and VC, in mutated cells induced pronounced reduction of 2-HG leading to levels comparable to those in wild type cells. The decreased level of 2-HG in mutated cells after combinatorial treatment was accompanied by an enhanced global DNA hydroxymethylation and an increased gene expression of certain tumour suppressors. Moreover, mutated cells showed an increased percentage of apoptotic cells after treatment with non-cytotoxic concentrations of ML309 and VC. These results suggest that combinatorial therapy is of interest for further investigation to rescue TET activity and treatment of IDH1/2 mutated cancers. KW - Vitamin C KW - epigenetics KW - IDH1 KW - TET KW - cancer cells Y1 - 2019 U6 - https://doi.org/10.1080/15592294.2019.1666652 SN - 1559-2294 SN - 1559-2308 VL - 15 IS - 3 SP - 307 EP - 322 PB - Taylor & Francis Group CY - Philadelphia ER - TY - JOUR A1 - Ugwuja, Chidinma G. A1 - Adelowo, Olawale O. A1 - Ogunlaja, Aemere A1 - Omorogie, Martins O. A1 - Olukanni, Olumide D. A1 - Ikhimiukor, Odion O. A1 - Iermak, Ievgeniia A1 - Kolawole, Gabriel A. A1 - Günter, Christina A1 - Taubert, Andreas A1 - Bodede, Olusola A1 - Moodley, Roshila A1 - Inada, Natalia M. A1 - Camargo, Andrea S.S. de A1 - Unuabonah, Emmanuel Iyayi T1 - Visible-Light-Mediated Photodynamic Water Disinfection @ Bimetallic-Doped Hybrid Clay Nanocomposites JF - ACS applied materials & interfaces N2 - This study reports a new class of photocatalytic hybrid clay nanocomposites prepared from low-cost sources (kaolinite clay and Carica papaya seeds) doped with Zn and Cu salts via a solvothermal process. X-ray diffraction analysis suggests that Cu-doping and Cu/Zn-doping introduce new phases into the crystalline structure of Kaolinite clay, which is linked to the reduced band gap of kaolinite from typically between 4.9 and 8.2 eV to 2.69 eV for Cu-doped and 1.5 eV for Cu/Zn hybrid clay nanocomposites (Nisar, J.; Arhammar, C.; Jamstorp, E.; Ahuja, R. Phys. Rev. B 2011, 84, 075120). In the presence of solar light irradiation, Cu- and Cu/Zn-doped nanocomposites facilitate the electron hole pair separation. This promotes the generation of singlet oxygen which in turn improves the water disinfection efficiencies of these novel nanocomposite materials. The nanocomposite materials were further characterized using high-resolution scanning electron microscopy, fluorimetry, therrnogravimetric analysis, and Raman spectroscopy. The breakthrough times of the nanocomposites for a fixed bed mode of disinfection of water contaminated with 2.32 x 10(7) cfu/mL E. coli ATCC 25922 under solar light irradiation are 25 h for Zn-doped, 30 h for Cu-doped, and 35 h for Cu/Zn-doped nanocomposites. In the presence of multidrug and multimetal resistant strains of E. coli, the breakthrough time decreases significantly. Zn-only doped nanocomposites are not photocatalytically active. In the absence of light, the nanocomposites are still effective in decontaminating water, although less efficient than under solar light irradiation. Electrostatic interaction, metal toxicity, and release of singlet oxygen (only in the Cu-doped and Cu/Zn-doped nanocomposites) are the three disinfection mechanisms by which these nanocomposites disinfect water. A regrowth study indicates the absence of any living E. coli cells in treated water even after 4 days. These data and the long hydraulic times (under gravity) exhibited by these nanocomposites during photodisinfection of water indicate an unusually high potential of these nanocomposites as efficient, affordable, and sustainable point-of-use systems for the disinfection of water in developing countries. KW - disinfection KW - nanocomposite material KW - multidrug-resistant Escherichia coli KW - water KW - reactive oxygen species Y1 - 2019 U6 - https://doi.org/10.1021/acsami.9b01212 SN - 1944-8244 SN - 1944-8252 VL - 11 IS - 28 SP - 25483 EP - 25494 PB - American Chemical Society CY - Washington, DC ER - TY - JOUR A1 - Xiong, Tao A1 - Saalfrank, Peter T1 - Vibrationally Broadened Optical Spectra of Selected Radicals and Cations Derived from Adamantane: A Time-Dependent Correlation Function Approach JF - The journal of physical chemistry : A, Molecules, spectroscopy, kinetics, environment & general theory N2 - Diamondoids are hydrogen-saturated molecular motifs cut out of diamond, forming a class of materials with tunable optoelectronic properties. In this work, we extend previous work on neutral, closed-shell diamondoids by computing with hybrid density functional theory and time-dependent correlation functions vibrationally broadened absorption spectra of cations and radicals derived from the simplest diamondoid, adamantane, namely, the neutral 1- and 2-adamantyl radicals (C10H15), the 1- and 2-adamantyl cations (C10H15+), and the adamantane radical cation (C10H16+). For selected cases, we also report vibrationally broadened emission, photoelectron, and resonance Raman spectra. Furthermore, the effect of the damping factor on the vibrational fine-structure is studied. The following trends are found: (1) Low-energy absorptions of the adamantyl radicals and cations, and of the adamantane cation, are all strongly red-shifted with respect to adamantane; (2) also, emission spectra are strongly red-shifted, whereas photoelectron spectra are less affected for the cases studied; (3) vibrational fine-structures are reduced compared to those of adamantane; (4) the spectroscopic signals of 1- and 2-adamantyl species are significantly different from each other; and (5) reducing the damping factor has only a limited effect on the vibrational fine-structure in most cases. This suggests that removing hydrogen atoms and/or electrons from adamantane leads to new optoelectronic properties, which should be detectable by vibronic spectroscopy. Y1 - 2019 U6 - https://doi.org/10.1021/acs.jpca.9b03305 SN - 1089-5639 SN - 1520-5215 VL - 123 IS - 41 SP - 8871 EP - 8880 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Melani, Giacomo A1 - Nagata, Yuki A1 - Campen, Richard Kramer A1 - Saalfrank, Peter T1 - Vibrational spectra of dissociatively adsorbed D2O on Al-terminated alpha-Al2O3(0001) surfaces from ab initio molecular dynamics JF - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr N2 - Water can adsorb molecularly or dissociatively onto different sites of metal oxide surfaces. These adsorption sites can be disentangled using surface-sensitive vibrational spectroscopy. Here, we model Vibrational Sum Frequency (VSF) spectra for various forms of dissociated, deuterated water on a reconstructed, Al-terminated α-Al2O3(0001) surface at submonolayer coverages (the so-called 1-2, 1-4, and 1-4′ modes). Using an efficient scheme based on velocity-velocity autocorrelation functions, we go beyond previous normal mode analyses by including anharmonicity, mode coupling, and thermal surface motion in the framework of ab initio molecular dynamics. In this way, we calculate vibrational density of states curves, infrared, and VSF spectra. Comparing computed VSF spectra with measured ones, we find that relative frequencies of resonances are in quite good agreement and linewidths are reasonably well represented, while VSF intensities coincide not well. We argue that intensities are sensitively affected by local interactions and thermal fluctuations, even at such low coverage, while absolute peak positions strongly depend on the choice of the electronic structure method and on the appropriate inclusion of anharmonicity. Y1 - 2019 U6 - https://doi.org/10.1063/1.5099895 SN - 0021-9606 SN - 1089-7690 VL - 150 IS - 24 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Scholz, Robert A1 - Lindner, Steven A1 - Loncaric, Ivor A1 - Tremblay, Jean Christophe A1 - Juaristi, J. A1 - Alducin, Maite A1 - Saalfrank, Peter T1 - Vibrational response and motion of carbon monoxide on Cu(100) driven by femtosecond laser pulses: Molecular dynamics with electronic friction JF - Physical review : B, Condensed matter and materials physics N2 - Carbon monoxide on copper surfaces continues to be a fascinating, rich microlab for many questions evolving in surface science. Recently, hot-electron mediated, femtosecond-laser pulse induced dynamics of CO molecules on Cu(100) were the focus of experiments [Inoue et al., Phys. Rev. Lett. 117, 186101 (2016)] and theory [Novko et al., Phys. Rev. Lett. 122, 016806 (2019)], unraveling details of the vibrational nonequilibrium dynamics on ultrashort (subpicoseconds) timescales. In the present work, full-dimensional time-resolved hot-electron driven dynamics are studied by molecular dynamics with electronic friction (MDEF). Dissipation is included by a friction term in a Langevin equation which describes the coupling of molecular degrees of freedom to electron-hole pairs in the copper surface, calculated from gradient-corrected density functional theory (DFT) via a local density friction approximation (LDFA). Relaxation due to surface phonons is included by a generalized Langevin oscillator model. The hot-electron induced excitation is described via a time-dependent electronic temperature, the latter derived from an improved two-temperature model. Our parameter-free simulations on a precomputed potential energy surface allow for excellent statistics, and the observed trends are confirmed by on-the-fly ab initio molecular dynamics with electronic friction (AIMDEF) calculations. By computing time-resolved frequency maps for selected molecular vibrations, instantaneous frequencies, probability distributions, and correlation functions, we gain microscopic insight into hot-electron driven dynamics and we can relate the time evolution of vibrational internal CO stretch-mode frequencies to measured data, notably an observed redshift. Quantitatively, the latter is found to be larger in MDEF than in experiment and possible reasons are discussed for this observation. In our model, in addition we observe the excitation and time evolution of large-amplitude low-frequency modes, lateral CO surface diffusion, and molecular desorption. Effects of surface atom motion and of the laser fluence are also discussed. Y1 - 2019 U6 - https://doi.org/10.1103/PhysRevB.100.245431 SN - 2469-9950 SN - 2469-9969 VL - 100 IS - 24 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Féry, Caroline A1 - Arnhold, Anja T1 - Verum focus and negation JF - Of trees and birds. A Festschrift for Gisbert Fanselow KW - Festschrift KW - Informationsstruktur KW - Linguistik KW - Morphologie KW - Syntax KW - festschrift KW - information structure KW - linguistics KW - morphology KW - syntax Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-432356 SN - 978-3-86956-457-9 SP - 213 EP - 229 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Tabares Jimenez, Ximena del Carmen A1 - Zimmermann, Heike Hildegard A1 - Dietze, Elisabeth A1 - Ratzmann, Gregor A1 - Belz, Lukas A1 - Vieth-Hillebrand, Andrea A1 - Dupont, Lydie A1 - Wilkes, Heinz A1 - Mapani, Benjamin A1 - Herzschuh, Ulrike T1 - Vegetation state changes in the course of shrub encroachment in an African savanna since about 1850 CE and their potential drivers JF - Ecology and evolution N2 - Shrub encroachment has far-reaching ecological and economic consequences in many ecosystems worldwide. Yet, compositional changes associated with shrub encroachment are often overlooked despite having important effects on ecosystem functioning. We document the compositional change and potential drivers for a northern Namibian Combretum woodland transitioning into a Terminalia shrubland. We use a multiproxy record (pollen, sedimentary ancient DNA, biomarkers, compound-specific carbon (delta C-13) and deuterium (delta D) isotopes, bulk carbon isotopes (delta(13)Corg), grain size, geochemical properties) from Lake Otjikoto at high taxonomical and temporal resolution. We provide evidence that state changes in semiarid environments may occur on a scale of one century and that transitions between stable states can span around 80 years and are characterized by a unique vegetation composition. We demonstrate that the current grass/woody ratio is exceptional for the last 170 years, as supported by n-alkane distributions and the delta C-13 and delta(13)Corg records. Comparing vegetation records to environmental proxy data and census data, we infer a complex network of global and local drivers of vegetation change. While our delta D record suggests physiological adaptations of woody species to higher atmospheric pCO(2) concentration and drought, our vegetation records reflect the impact of broad-scale logging for the mining industry, and the macrocharcoal record suggests a decrease in fire activity associated with the intensification of farming. Impact of selective grazing is reflected by changes in abundance and taxonomical composition of grasses and by an increase of nonpalatable and trampling-resistant taxa. In addition, grain-size and spore records suggest changes in the erodibility of soils because of reduced grass cover. Synthesis. We conclude that transitions to an encroached savanna state are supported by gradual environmental changes induced by management strategies, which affected the resilience of savanna ecosystems. In addition, feedback mechanisms that reflect the interplay between management legacies and climate change maintain the encroached state. KW - climate change KW - fossil pollen KW - land-use change KW - savanna ecology KW - sedimentary ancient DNA KW - state and transition KW - tree-grass interactions Y1 - 2019 U6 - https://doi.org/10.1002/ece3.5955 SN - 2045-7758 VL - 10 IS - 2 SP - 962 EP - 979 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Ben Dor, Yoav A1 - Neugebauer, Ina A1 - Enzel, Yehouda A1 - Schwab, Markus Julius A1 - Tjallingii, Rik A1 - Erel, Yigal A1 - Brauer, Achim T1 - Varves of the Dead Sea sedimentary record JF - Quaternary science reviews : the international multidisciplinary research and review journal N2 - The sedimentary record of the Dead Sea provides an exceptional high-resolution archive of past climate changes in the drought-sensitive eastern Mediterranean-Levant, a key region for the development of humankind at the boundary of global climate belts. Moreover, it is the only deep hypersaline lake known to have deposited long sequences of finely laminated, annually deposited sediments (i.e. varves) of varied compositions, including aragonite, gypsum, halite and clastic sediments. Vast efforts have been made over the years to decipher the environmental information stored in these evaporitic-clastic sequences spanning from the Pleistocene Lake Amora to the Holocene Dead Sea. A general characterisation of sediment facies has been derived from exposed sediment sections, as well as from shallow- and deep-water sediment cores. During high lake stands and episodes of positive water budget, mostly during glacial times, alternating aragonite and detritus laminae (‘aad’ facies) were accumulated, whereas during low lake stands and droughts, prevailing during interglacials, laminated detritus (‘ld’ facies) and laminated halite (‘lh’ facies) dominate the sequence. In this paper, we (i) review the three types of laminated sediments of the Dead Sea sedimentary record (‘aad’, ‘ld’ and ‘lh’ facies), (ii) discuss their modes of formation, deposition and accumulation, and their interpretation as varves, and (iii) illustrate how Dead Sea varves are utilized for palaeoclimate reconstructions and for establishing floating chronologies. KW - ICDP Dead Sea deep drilling KW - Hypersaline lake KW - Lacustrine sediments KW - Evaporitic varves KW - Palaeoclimate reconstruction KW - Varve chronologies Y1 - 2019 U6 - https://doi.org/10.1016/j.quascirev.2019.04.011 SN - 0277-3791 VL - 215 SP - 173 EP - 184 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Kaufmann, Felix E. D. A1 - Hoffmann, Marie C. A1 - Bachmann, Kai A1 - Veksler, Ilya V. A1 - Trumbull, Robert B. A1 - Hecht, Lutz T1 - Variations in Composition, Texture, and Platinum Group Element Mineralization in the Lower Group and Middle Group Chromitites of the Northwestern Bushveld Complex, South Africa JF - Economic geology N2 - Small-scale variations in mineral chemistry, textures, and platinum group element (PGE) mineralization were investigated in the Lower and Middle Group chromitite layers LG6, LG6a, MG1, MG2, and MG2 II from vertical drill core profiles at the Thaba mine in the northwestern limb of the Bushveld Complex. We present detailed geochemical profiles of chromite composition and chromite crystal size distribution curves to shed light on the processes of chromite accumulation and textural modification as well as mineralization. Multiple samples within each layer were assayed for PGE concentrations, and the respective platinum group mineral association was determined by mineral liberation analysis (MLA). There is strong evidence for postcumulus changes in the chromitites. The crystal size distribution curves suggest that the primary chromite texture was coarsened by a combination of adcumulus growth and textural equilibration, while compaction of the crystal mush played only a minor role. Mineral compositions were also modified by postcumulus processes, but because of the very high modal amount of chromite and its local preservation in orthopyroxene oikocrysts, that phase retained much primary information. Vertical variations of chromite composition within chromitite layers and from one layer to another do not support the idea of chromite accumulation from crystal-rich slurries or crystal settling from a large magma chamber. Instead, we favor a successive buildup of chromitite layers by repeated injections of relatively thin layers of chromite-saturated magmas, with in situ crystallization occurring at the crystal mush-magma interface. The adcumulus growth of chromite grains to form massive chromitite required addition of Cr to the layers, which we attribute to downward percolation from the overlying magma. The PGE concentrations are elevated in all chromitite layers compared to adjacent silicate rocks and show a systematic increase upward from LG6 (avg 807 ppb Ir + Ru + Rh + Pt + Pd + Au) to MG2 II (avg 2,062 ppb). There are also significant internal variations in all layers, with enrichments at hanging and/or footwalls. The enriched nature of chromitites in PGEs compared to host pyroxenites is a general feature, independent of the layer thickness. The MLA results distinguish two principal groups of PGE mineral associations: the LG6, LG6, and MG1 are dominated by the malanite series, laurite, and PGE sulfarsenides, while the MG2 and MG2 II layers are characterized by laurite and PGE sulfides as well as Pt-Fe-Sn and PGE-Sb-Bi-Pb alloys. Differences in the PGE associations are attributed to postcumulus alteration of the MG2 and MG2 II layer, while the chromitites below, particularly LG6 and LG6a, contain a more pristine association. Y1 - 2019 U6 - https://doi.org/10.5382/econgeo.4641 SN - 0361-0128 SN - 1554-0774 VL - 114 IS - 3 SP - 569 EP - 590 PB - The Economic Geology Publ. Co CY - Littleton ER - TY - JOUR A1 - Guislain, Alexis A1 - Beisner, Beatrix E. A1 - Köhler, Jan T1 - Variation in species light acquisition traits under fluctuating light regimes BT - implications for non-equilibrium coexistence JF - Oikos N2 - Resource distribution heterogeneity offers niche opportunities for species with different functional traits to develop and potentially coexist. Available light (photosynthetically active radiation or PAR) for suspended algae (phytoplankton) may fluctuate greatly over time and space. Species-specific light acquisition traits capture important aspects of the ecophysiology of phytoplankton and characterize species growth at either limiting or saturating daily PAR supply. Efforts have been made to explain phytoplankton coexistence using species-specific light acquisition traits under constant light conditions, but not under fluctuating light regimes that should facilitate non-equilibrium coexistence. In the well-mixed, hypertrophic Lake TaiHu (China), we incubated the phytoplankton community in bottles placed either at fixed depths or moved vertically through the water column to mimic vertical mixing. Incubations at constant depths received only the diurnal changes in light, while the moving bottles received rapidly fluctuating light. Species-specific light acquisition traits of dominant cyanobacteria (Anabaena flos-aquae, Microcystis spp.) and diatom (Aulacoseira granulata, Cyclotella pseudostelligera) species were characterized from their growth-light relationships that could explain relative biomasses along the daily PAR gradient under both constant and fluctuating light. Our study demonstrates the importance of interspecific differences in affinities to limiting and saturating light for the coexistence of phytoplankton species in spatially heterogeneous light conditions. Furthermore, we observed strong intraspecific differences in light acquisition traits between incubation under constant and fluctuating light - leading to the reversal of light utilization strategies of species. This increased the niche space for acclimated species, precluding competitive exclusion. These observations could enhance our understanding of the mechanisms behind the Paradox of the Plankton. KW - niche partitioning KW - phytoplankton photoacclimation Y1 - 2018 U6 - https://doi.org/10.1111/oik.05297 SN - 0030-1299 SN - 1600-0706 VL - 128 IS - 5 SP - 716 EP - 728 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Gerlitz, Lars A1 - Steirou, Eva A1 - Schneider, Christoph A1 - Moron, Vincent A1 - Vorogushyn, Sergiy A1 - Merz, Bruno T1 - Variability of the Cold Season Climate in Central Asia. Part II: Hydroclimatic Predictability JF - Journal of climate N2 - Central Asia (CA) is subjected to a large variability of precipitation. This study presents a statistical model, relating precipitation anomalies in three subregions of CA in the cold season (November-March) with various predictors in the preceding October. Promising forecast skill is achieved for two subregions covering 1) Uzbekistan, Turkmenistan, Kyrgyzstan, Tajikistan, and southern Kazakhstan and 2) Iran, Afghanistan, and Pakistan. ENSO in October is identified as the major predictor. Eurasian snow cover and the quasi-biennial oscillation further improve the forecast performance. To understand the physical mechanisms, an analysis of teleconnections between these predictors and the wintertime circulation over CA is conducted. The correlation analysis of predictors and large-scale circulation indices suggests a seasonal persistence of tropical circulation modes and a dynamical forcing of the westerly circulation by snow cover variations over Eurasia. An EOF analysis of pressure and humidity patterns allows separating the circulation variability over CA into westerly and tropical modes and confirms that the identified predictors affect the respective circulation characteristics. Based on the previously established weather type classification for CA, the predictors are investigated with regard to their effect on the regional circulation. The results suggest a modification of the Hadley cell due to ENSO variations, with enhanced moisture supply from the Arabian Gulf during El Nino. They further indicate an influence of Eurasian snow cover on the wintertime Arctic Oscillation (AO) and Northern Hemispheric Rossby wave tracks. Positive anomalies favor weather types associated with dry conditions, while negative anomalies promote the formation of a quasi-stationary trough over CA, which typically occurs during positive AO conditions. KW - Asia KW - Climate prediction KW - Seasonal forecasting KW - North Atlantic Oscillation KW - Southern Oscillation Y1 - 2019 U6 - https://doi.org/10.1175/JCLI-D-18-0892.1 SN - 0894-8755 SN - 1520-0442 VL - 32 IS - 18 SP - 6015 EP - 6033 PB - American Meteorological Soc. CY - Boston ER - TY - JOUR A1 - Höhle, Barbara A1 - Bijeljac-Babic, Ranka A1 - Nazzi, Thierry T1 - Variability and stability in early language acquisition BT - comparing recognition and bilingual infants' speech perception and word recognition JF - Bilingualism : language and cognition N2 - Many human infants grow up learning more than one language simultaneously but only recently has research started to study early language acquisition in this population more systematically. The paper gives an overview on findings on early language acquisition in bilingual infants during the first two years of life and compares these findings to current knowledge on early language acquisition in monolingual infants. Given the state of the research, the overview focuses on research on phonological and early lexical development in the first two years of life. We will show that the developmental trajectory of early language acquisition in these areas is very similar in mono- and bilingual infants suggesting that these early steps into language are guided by mechanisms that are rather robust against the differences in the conditions of language exposure that mono- and bilingual infants typically experience. KW - language acquisition KW - bilingual infants KW - bilingual phonological KW - development KW - bilingual lexical development KW - simultaneous bilingualism Y1 - 2019 U6 - https://doi.org/10.1017/S1366728919000348 SN - 1366-7289 SN - 1469-1841 VL - 23 IS - 1 SP - 56 EP - 71 PB - Cambridge Univ. Press CY - New York ER - TY - JOUR A1 - Jessen, Anna A1 - Verissimo, João Marques A1 - Clahsen, Harald T1 - Variability and consistency in late bilinguals’ morphology BT - an ERP production study JF - The mental lexicon N2 - Speaking a late-learned second language (L2) is supposed to yield more variable and less consistent output than speaking one’s first language (L1), particularly with respect to reliably adhering to grammatical morphology. The current study investigates both internal processes involved in encoding morphologically complex words – by recording event-related brain potentials (ERPs) during participants’ silent productions – and the corresponding overt output. We specifically examined compounds with plural or singular modifiers in English. Thirty-one advanced L2 speakers of English (L1: German) were compared to a control group of 20 L1 English speakers from an earlier study. We found an enhanced (right-frontal) negativity during (silent) morphological encoding for compounds produced from regular plural forms relative to compounds formed from irregular plurals, replicating the ERP effect obtained for the L1 group. The L2 speakers’ overt productions, however, were significantly less consistent than those of the L1 speakers on the same task. We suggest that L2 speakers employ the same mechanisms for morphological encoding as L1 speakers, but with less reliance on grammatical constraints than L1 speakers. KW - event-related potentials (ERP) KW - plurals in compounds KW - morphological constraints KW - harmonic grammars KW - morphological processing Y1 - 2019 U6 - https://doi.org/10.1075/ml.18002.jes SN - 1871-1340 SN - 1871-1375 VL - 13 IS - 2 SP - 186 EP - 214 PB - John Benjamins Publishing Co. CY - Amsterdam ER - TY - JOUR A1 - Ciaccio, Laura Anna A1 - Clahsen, Harald T1 - Variability and consistency in first and second language processing BT - A masked morphological priming study on prefixation and suffixation JF - Language Learning N2 - Word forms such as walked or walker are decomposed into their morphological constituents (walk + -ed/-er) during language comprehension. Yet, the efficiency of morphological decomposition seems to vary for different languages and morphological types, as well as for first and second language speakers. The current study reports results from a visual masked priming experiment focusing on different types of derived word forms (specifically prefixed vs. suffixed) in first and second language speakers of German. We compared the present findings with results from previous studies on inflection and compounding and proposed an account of morphological decomposition that captures both the variability and the consistency of morphological decomposition for different morphological types and for first and second language speakers. Open Practices This article has been awarded an Open Materials badge. Study materials are publicly accessible via the Open Science Framework at . Learn more about the Open Practices badges from the Center for Open Science: . KW - prefixed words KW - derivation KW - second language processing KW - masked priming KW - morphology Y1 - 2019 U6 - https://doi.org/10.1111/lang.12370 SN - 0023-8333 SN - 1467-9922 VL - 70 IS - 1 SP - 103 EP - 136 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Zude, Manuela A1 - Hashim, Norhashila A1 - Hass, Roland A1 - Polley, Nabarun A1 - Regen, Christian T1 - Validation study for measuring absorption and reduced scattering coefficients by means of laser-induced backscattering imaging JF - Postharvest Biology and Technology N2 - Decoupling of optical properties appears challenging, but vital to get better insight of the relationship between light and fruit attributes. In this study, nine solid phantoms capturing the ranges of absorption (μa) and reduced scattering (μs’) coefficients in fruit were analysed non-destructively using laser-induced backscattering imaging (LLBI) at 1060 nm. Data analysis of LLBI was carried out on the diffuse reflectance, attenuation profile obtained by means of Farrell’s diffusion theory either calculating μa [cm−1] and μs’ [cm−1] in one fitting step or fitting only one optical variable and providing the other one from a destructive analysis. The nondestructive approach was approved when calculating one unknown coefficient non-destructively, while no ability of the method was found to analysis both, μa and μs’, non-destructively. Setting μs’ according to destructive photon density wave (PDW) spectroscopy and fitting μa resulted in root mean square error (rmse) of 18.7% in comparison to fitting μs’ resulting in rmse of 2.6%, pointing to decreased measuring uncertainty, when the highly variable μa was known. The approach was tested on European pear, utilizing destructive PDW spectroscopy for setting one variable, while LLBI was applied for calculating the remaining coefficient. Results indicated that the optical properties of pear obtained from PDW spectroscopy as well as LLBI changed concurrently in correspondence to water content mainly. A destructive batch-wise analysis of μs’ and online analysis of μa may be considered in future developments for improved fruit sorting results, when considering fruit with high variability of μs’. KW - Absorption KW - European pear KW - Fruit quality KW - Phantoms KW - Reduced scattering coefficient KW - Scattering KW - Spatially resolved spectroscopy Y1 - 2019 U6 - https://doi.org/10.1016/j.postharvbio.2019.04.002 SN - 0925-5214 SN - 1873-2356 VL - 153 SP - 161 EP - 168 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Wells, Robert A1 - Poppenhäger, Katja A1 - Watson, C. A. T1 - Validation of a temperate fourth planet in the K2-133 multiplanet system JF - Monthly notices of the Royal Astronomical Society N2 - We present follow-up observations of the K2-133 multiplanet system. Previously, we announced that K2-133 contained three super-Earths orbiting an M1.5V host star – with tentative evidence of a fourth outer-planet orbiting at the edge of the temperate zone. Here, we report on the validation of the presence of the fourth planet, determining a radius of 1.73+0.14−0.13 R⊕. The four planets span the radius gap of the exoplanet population, meaning further follow-up would be worthwhile to obtain masses and test theories of the origin of the gap. In particular, the trend of increasing planetary radius with decreasing incident flux in the K2-133 system supports the claim that the gap is caused by photo-evaporation of exoplanet atmospheres. Finally, we note that K2-133 e orbits on the edge of the star's temperate zone, and that our radius measurement allows for the possibility that this is a rocky world. Additional mass measurements are required to confirm or refute this scenario. KW - techniques: photometric KW - planets and satellites: general KW - stars: individual: LP 358-499 KW - stars: individual: K2-133 KW - stars: low-mass Y1 - 2019 U6 - https://doi.org/10.1093/mnras/stz1334 SN - 0035-8711 SN - 1365-2966 VL - 487 IS - 2 SP - 1865 EP - 1873 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Alxatib, Sam A1 - Sauerland, Ulrich T1 - Vagueness JF - The Oxford Handbook of Experimental Semantics and Pragmatics N2 - Though vague phenomena have been studied extensively for many decades, it is only in recent years that researchers sought the support of quantitative data. This chapter highlights and discusses the insights that experimental methods brought to the study of vagueness. One area focused on are ‘borderline contradictions’, that is, sentences like ‘She is neither tall nor not tall’ that are contradictory when analysed in classical logic, but are actually acceptable as descriptions of borderline cases. The flourishing of theories and experimental studies that borderline contradictions have led to are examined closely. Beyond this illustrative case, an overview of recent studies that concern the classification of types of vagueness, the use of numbers, rounding, number modification, and the general pragmatic status of vagueness is provided. KW - vagueness KW - gradability KW - categories KW - borderline cases KW - contradiction KW - valency KW - imprecision KW - hysteresis KW - pragmatics KW - semantics Y1 - 2019 U6 - https://doi.org/10.1093/oxfordhb/9780198791768.013.24 PB - Oxford University Press CY - Oxford ER - TY - JOUR A1 - Vogel, Stefanie A1 - Ebel, Kenny A1 - Heck, Christian A1 - Schürmann, Robin Mathis A1 - Milosavljevic, Aleksandar R. A1 - Giuliani, Alexandre A1 - Bald, Ilko T1 - Vacuum-UV induced DNA strand breaks BT - influence of the radiosensitizers 5-bromouracil and 8-bromoadenine JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - Radiation therapy is a basic part of cancer treatment. To increase the DNA damage in carcinogenic cells and preserve healthy tissue at the same time, radiosensitizing molecules such as halogenated nucleobase analogs can be incorporated into the DNA during the cell reproduction cycle. In the present study 8.44 eV photon irradiation induced single strand breaks (SSB) in DNA sequences modified with the radiosensitizer 5-bromouracil (U-5Br) and 8-bromoadenine ((8Br)A) are investigated. U-5Br was incorporated in the 13mer oligonucleotide flanked by different nucleobases. It was demonstrated that the highest SSB cross sections were reached, when cytosine and thymine were adjacent to U-5Br, whereas guanine as a neighboring nucleobase decreases the activity of U-5Br indicating that competing reaction mechanisms are active. This was further investigated with respect to the distance of guanine to U-5Br separated by an increasing number of adenine nucleotides. It was observed that the SSB cross sections were decreasing with an increasing number of adenine spacers between guanine and U-5Br until the SSB cross sections almost reached the level of a non-modified DNA sequence, which demonstrates the high sequence dependence of the sensitizing effect of U-5Br. (8Br)A was incorporated in a 13mer oligonucleotide as well and the strand breaks were quantified upon 8.44 eV photon irradiation in direct comparison to a non-modified DNA sequence of the same composition. No clear enhancement of the SSB yield of the modified in comparison to the non-modified DNA sequence could be observed. Additionally, secondary electrons with a maximum energy of 3.6 eV were generated when using Si as a substrate giving rise to further DNA damage. A clear enhancement in the SSB yield can be ascertained, but to the same degree for both the non-modified DNA sequence and the DNA sequence modified with (8Br)A. Y1 - 2019 U6 - https://doi.org/10.1039/c8cp06813e SN - 1463-9076 SN - 1463-9084 VL - 21 IS - 4 SP - 1972 EP - 1979 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Vogel, Stefanie A1 - Ebel, Kenny A1 - Schürmann, Robin Mathis A1 - Heck, Christian A1 - Meiling, Till A1 - Milosavljevic, Aleksandar R. A1 - Giuliani, Alexandre A1 - Bald, Ilko T1 - Vacuum-UV and Low-Energy Electron-Induced DNA Strand Breaks BT - Influence of the DNA Sequence and Substrate JF - ChemPhysChem : a European journal of chemical physics and physical chemistry N2 - DNA is effectively damaged by radiation, which can on the one hand lead to cancer and is on the other hand directly exploited in the treatment of tumor tissue. DNA strand breaks are already induced by photons having an energy below the ionization energy of DNA. At high photon energies, most of the DNA strand breaks are induced by low-energy secondary electrons. In the present study we quantified photon and electron induced DNA strand breaks in four different 12mer oligonucleotides. They are irradiated directly with 8.44 eV vacuum ultraviolet (VUV) photons and 8.8 eV low energy electrons (LEE). By using Si instead of VUV transparent CaF2 as a substrate the VUV exposure leads to an additional release of LEEs, which have a maximum energy of 3.6 eV and can significantly enhance strand break cross sections. Atomic force microscopy is used to visualize strand breaks on DNA origami platforms and to determine absolute values for the strand break cross sections. Upon irradiation with 8.44 eV photons all the investigated sequences show very similar strand break cross sections in the range of 1.7-2.3x10(-16) cm(2). The strand break cross sections for LEE irradiation at 8.8 eV are one to two orders of magnitude larger than the ones for VUV photons, and a slight sequence dependence is observed. The sequence dependence is even more pronounced for LEEs with energies <3.6 eV. The present results help to assess DNA damage by photons and electrons close to the ionization threshold. KW - DNA origami KW - DNA radiation damage KW - DNA strand breaks KW - low-energy electrons KW - vacuum-UV radiation Y1 - 2019 U6 - https://doi.org/10.1002/cphc.201801152 SN - 1439-4235 SN - 1439-7641 VL - 20 IS - 6 SP - 823 EP - 830 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Vos, Joris A1 - Vuckovic, Maja A1 - Chen, X. A1 - Han, Zh A1 - Boudreaux, Thomas A1 - Barlow, Brad N. A1 - Ostensen, R. A1 - Nemeth, Péter T1 - Using wide hot subdwarf binaries to constrain Roche-lobe overflow models JF - Contributions of the Astronomical Observatory Skalnaté Pleso N2 - Hot subdwarf B (sdB) stars are evolved core helium burning stars that have lost most of their hydrogen envelope due to binary interaction on the red giant branch. As sdB stars in wide binary systems can only be created by stable Roche lobe overflow, they are a great test sample to constrain the theoretical models for stable mass loss on the red giant branch. We present here the findings of a long term monitoring program of wide sdB+MS binaries. We found two main features in the orbital parameters. The majority of the systems have eccentric orbits with systems on longer orbital period having a higher eccentricity. As these systems have undergone mass loss near the tip of the RGB, tidal circularisation theory predicts them to be circularized. Our observations suggest that efficient eccentricity pumping mechanisms are active during the mass loss phase. Secondly we find a strong correlation between the mass ratio and the orbital period. Using binary evolution models, this relation is used to derive both an upper and lower limit on the initial mass ratio at which RLOF will be stable. These limits depend on the core mass of the sdB progenitor. KW - stars: subdwarfs KW - stars: binaries: spectroscopic KW - stars: fundamental parameters KW - stars: evolution Y1 - 2019 SN - 1335-1842 SN - 1336-0337 VL - 49 IS - 2 SP - 264 EP - 270 PB - Astronomický Ústav SAV CY - Tatranská Lomnica ER - TY - JOUR A1 - Leopold, Henrik A1 - van der Aa, Han A1 - Offenberg, Jelmer A1 - Reijers, Hajo A. T1 - Using Hidden Markov Models for the accurate linguistic analysis of process model activity labels JF - Information systems N2 - Many process model analysis techniques rely on the accurate analysis of the natural language contents captured in the models’ activity labels. Since these labels are typically short and diverse in terms of their grammatical style, standard natural language processing tools are not suitable to analyze them. While a dedicated technique for the analysis of process model activity labels was proposed in the past, it suffers from considerable limitations. First of all, its performance varies greatly among data sets with different characteristics and it cannot handle uncommon grammatical styles. What is more, adapting the technique requires in-depth domain knowledge. We use this paper to propose a machine learning-based technique for activity label analysis that overcomes the issues associated with this rule-based state of the art. Our technique conceptualizes activity label analysis as a tagging task based on a Hidden Markov Model. By doing so, the analysis of activity labels no longer requires the manual specification of rules. An evaluation using a collection of 15,000 activity labels demonstrates that our machine learning-based technique outperforms the state of the art in all aspects. KW - Label analysis KW - Process model KW - Natural language KW - Hidden Markov models Y1 - 2019 U6 - https://doi.org/10.1016/j.is.2019.02.005 SN - 0306-4379 SN - 1873-6076 VL - 83 SP - 30 EP - 39 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Ramezani Ziarani, Maryam A1 - Bookhagen, Bodo A1 - Schmidt, Torsten A1 - Wickert, Jens A1 - de la Torre, Alejandro A1 - Hierro, Rodrigo T1 - Using Convective Available Potential Energy (CAPE) and Dew-Point Temperature to Characterize Rainfall-Extreme Events in the South-Central Andes JF - Atmosphere N2 - The interactions between atmosphere and steep topography in the eastern south–central Andes result in complex relations with inhomogenous rainfall distributions. The atmospheric conditions leading to deep convection and extreme rainfall and their spatial patterns—both at the valley and mountain-belt scales—are not well understood. In this study, we aim to identify the dominant atmospheric conditions and their spatial variability by analyzing the convective available potential energy (CAPE) and dew-point temperature (Td). We explain the crucial effect of temperature on extreme rainfall generation along the steep climatic and topographic gradients in the NW Argentine Andes stretching from the low-elevation eastern foreland to the high-elevation central Andean Plateau in the west. Our analysis relies on version 2.0 of the ECMWF’s (European Centre for Medium-RangeWeather Forecasts) Re-Analysis (ERA-interim) data and TRMM (Tropical Rainfall Measuring Mission) data. We make the following key observations: First, we observe distinctive gradients along and across strike of the Andes in dew-point temperature and CAPE that both control rainfall distributions. Second, we identify a nonlinear correlation between rainfall and a combination of dew-point temperature and CAPE through a multivariable regression analysis. The correlation changes in space along the climatic and topographic gradients and helps to explain controlling factors for extreme-rainfall generation. Third, we observe more contribution (or higher importance) of Td in the tropical low-elevation foreland and intermediate-elevation areas as compared to the high-elevation central Andean Plateau for 90th percentile rainfall. In contrast, we observe a higher contribution of CAPE in the intermediate-elevation area between low and high elevation, especially in the transition zone between the tropical and subtropical areas for the 90th percentile rainfall. Fourth, we find that the parameters of the multivariable regression using CAPE and Td can explain rainfall with higher statistical significance for the 90th percentile compared to lower rainfall percentiles. Based on our results, the spatial pattern of rainfall-extreme events during the past ∼16 years can be described by a combination of dew-point temperature and CAPE in the south–central Andes. KW - eastern south–central Andes KW - extreme rainfall KW - deep convection KW - convective available potential energy KW - dew-point temperature Y1 - 2019 U6 - https://doi.org/10.3390/atmos10070379 SN - 2073-4433 VL - 10 IS - 7 PB - MDPI CY - Basel ER - TY - JOUR A1 - Kirsch, Fabian A1 - Busching, Robert A1 - Rohlf, Helena A1 - Krahé, Barbara T1 - Using behavioral observation for the longitudinal study of anger regulation in middle childhood JF - Applied Developmental Science N2 - Assessing anger regulation via self-reports is fraught with problems, especially among children. Behavioral observation provides an ecologically valid alternative for measuring anger regulation. The present study uses data from two waves of a longitudinal study to present a behavioral observation approach for measuring anger regulation in middle childhood. At T1, 599 children from Germany (6-10 years old) were observed during an anger eliciting task, and the use of anger regulation strategies was coded. At T2, 3 years later, the observation was repeated with an age-appropriate version of the same task. Partial metric measurement invariance over time demonstrated the structural equivalence of the two versions. Maladaptive anger regulation between the two time points showed moderate stability. Validity was established by showing correlations with aggressive behavior, peer problems, and conduct problems (concurrent and predictive criterion validity). The study presents an ecologically valid and economic approach to assessing anger regulation strategies in situ. Y1 - 2019 U6 - https://doi.org/10.1080/10888691.2017.1325325 SN - 1088-8691 SN - 1532-480X VL - 23 IS - 2 SP - 105 EP - 118 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Grafen, Anika A1 - Schumacher, Fabian A1 - Chithelen, Janice A1 - Kleuser, Burkhard A1 - Beyersdorf, Niklas A1 - Schneider-Schaulies, Jürgen T1 - Use of Acid Ceramidase and Sphingosine Kinase Inhibitors as Antiviral Compounds Against Measles Virus Infection of Lymphocytes in vitro JF - Frontiers in Cell and Developmental Biology N2 - As structural membrane components and signaling effector molecules sphingolipids influence a plethora of host cell functions, and by doing so also the replication of viruses. Investigating the effects of various inhibitors of sphingolipid metabolism in primary human peripheral blood lymphocytes (PBL) and the human B cell line BJAB we found that not only the sphingosine kinase (SphK) inhibitor SKI-II, but also the acid ceramidase inhibitor ceranib-2 efficiently inhibited measles virus (MV) replication. Virus uptake into the target cells was not grossly altered by the two inhibitors, while titers of newly synthesized MV were reduced by approximately 1 log (90%) in PBL and 70-80% in BJAB cells. Lipidomic analyses revealed that in PBL SKI-II led to increased ceramide levels, whereas in BJAB cells ceranib-2 increased ceramides. SKI-II treatment decreased sphingosine-1-phosphate (S1P) levels in PBL and BJAB cells. Furthermore, we found that MV infection of lymphocytes induced a transient (0.5-6 h) increase in S1P, which was prevented by SKI-II. Investigating the effect of the inhibitors on the metabolic (mTORC1) activity we found that ceranib-2 reduced the phosphorylation of p70 S6K in PBL, and that both inhibitors, ceranib-2 and SKI-II, reduced the phosphorylation of p70 S6K in BJAB cells. As mTORC1 activity is required for efficient MV replication, this effect of the inhibitors is one possible antiviral mechanism. In addition, reduced intracellular S1P levels affect a number of signaling pathways and functions including Hsp90 activity, which was reported to be required for MV replication. Accordingly, we found that pharmacological inhibition of Hsp90 with the inhibitor 17-AAG strongly impaired MV replication in primary PBL. Thus, our data suggest that treatment of lymphocytes with both, acid ceramidase and SphK inhibitors, impair MV replication by affecting a number of cellular activities including mTORC1 and Hsp90, which alter the metabolic state of the cells causing a hostile environment for the virus. KW - measles virus KW - sphingolipids KW - acid ceramidase KW - acid ceramidase inhibitor ceranib-2 KW - sphingosine kinase KW - sphingosine kinase inhibitor SKI-II Y1 - 2019 U6 - https://doi.org/10.3389/fcell.2019.00218 SN - 2296-634X VL - 7 PB - Frontiers Research Foundation CY - Lausanne ER - TY - JOUR A1 - Abdalla, Hassan E. A1 - Aharonian, Felix A. A1 - Benkhali, F. Ait A1 - Anguener, E. O. A1 - Arakawa, M. A1 - Arcaro, C. A1 - Armand, C. A1 - Ashkar, H. A1 - Backes, M. A1 - Martins, V. Barbosa A1 - Barnard, M. A1 - Becherini, Y. A1 - Berge, D. A1 - Bernloehr, K. A1 - Blackwell, R. A1 - Boettcher, M. A1 - Boisson, C. A1 - Bolmont, J. A1 - Bonnefoy, S. A1 - Bregeon, J. A1 - Breuhaus, M. A1 - Brun, F. A1 - Brun, P. A1 - Bryan, M. A1 - Buechele, M. A1 - Bulik, T. A1 - Bylund, T. A1 - Capasso, M. A1 - Caroff, S. A1 - Carosi, A. A1 - Casanova, Sabrina A1 - Cerruti, M. A1 - Chakraborty, N. A1 - Chand, T. A1 - Chandra, S. A1 - Chaves, R. C. G. A1 - Chen, A. A1 - Colafrancesco, S. A1 - Curylo, M. A1 - Davids, I. D. A1 - Deil, C. A1 - Devin, J. A1 - de Wilt, P. A1 - Dirson, L. A1 - Djannati-Atai, A. A1 - Dmytriiev, A. A1 - Donath, A. A1 - Doroshenko, V A1 - Dyks, J. A1 - Egberts, Kathrin A1 - Emery, G. A1 - Ernenwein, J-p A1 - Eschbach, S. A1 - Feijen, K. A1 - Fegan, S. A1 - Fiasson, A. A1 - Fontaine, G. A1 - Funk, S. A1 - Fuessling, M. A1 - Gabici, S. A1 - Gallant, Y. A. A1 - Gate, F. A1 - Giavitto, G. A1 - Glawion, D. A1 - Glicenstein, J. F. A1 - Gottschall, D. A1 - Grondin, M-H A1 - Hahn, J. A1 - Haupt, M. A1 - Heinzelmann, G. A1 - Henri, G. A1 - Hermann, G. A1 - Hinton, James Anthony A1 - Hofmann, W. A1 - Hoischen, Clemens A1 - Holch, Tim Lukas A1 - Holler, M. A1 - Horns, D. A1 - Huber, D. A1 - Iwasaki, H. A1 - Jamrozy, M. A1 - Jankowsky, D. A1 - Jankowsky, F. A1 - Jung-Richardt, I A1 - Kastendieck, M. A. A1 - Katarzynski, K. A1 - Katsuragawa, M. A1 - Katz, U. A1 - Khangulyan, D. A1 - Khelifi, B. A1 - King, J. A1 - Klepser, S. A1 - Kluzniak, W. A1 - Komin, Nu A1 - Kosack, K. A1 - Kostunin, D. A1 - Kraus, M. A1 - Lamanna, G. A1 - Lau, J. A1 - Lemiere, A. A1 - Lemoine-Goumard, M. A1 - Lenain, J-P A1 - Leser, Eva A1 - Levy, C. A1 - Lohse, T. A1 - Lopez-Coto, R. A1 - Lypova, I A1 - Mackey, J. A1 - Majumdar, J. A1 - Malyshev, D. A1 - Marandon, V A1 - Marcowith, Alexandre A1 - Mares, A. A1 - Mariaud, C. A1 - Marti-Devesa, G. A1 - Marx, R. A1 - Maurin, G. A1 - Meintjes, P. J. A1 - Mitchell, A. M. W. A1 - Moderski, R. A1 - Mohamed, M. A1 - Mohrmann, L. A1 - Muller, J. A1 - Moore, C. A1 - Moulin, Emmanuel A1 - Murach, T. A1 - Nakashima, S. A1 - de Naurois, M. A1 - Ndiyavala, H. A1 - Niederwanger, F. A1 - Niemiec, J. A1 - Oakes, L. A1 - Odaka, H. A1 - Ohm, S. A1 - Wilhelmi, E. de Ona A1 - Ostrowski, M. A1 - Oya, I A1 - Panter, M. A1 - Parsons, R. D. A1 - Perennes, C. A1 - Petrucci, P-O A1 - Peyaud, B. A1 - Piel, Q. A1 - Pita, S. A1 - Poireau, V A1 - Noel, A. Priyana A1 - Prokhorov, D. A. A1 - Prokoph, H. A1 - Puehlhofer, G. A1 - Punch, M. A1 - Quirrenbach, A. A1 - Raab, S. A1 - Rauth, R. A1 - Reimer, A. A1 - Reimer, O. A1 - Remy, Q. A1 - Renaud, M. A1 - Rieger, F. A1 - Rinchiuso, L. A1 - Romoli, C. A1 - Rowell, G. A1 - Rudak, B. A1 - Ruiz-Velasco, E. A1 - Sahakian, V A1 - Saito, S. A1 - Sanchez, David M. A1 - Santangelo, Andrea A1 - Sasaki, M. A1 - Schlickeiser, R. A1 - Schussler, F. A1 - Schulz, A. A1 - Schutte, H. A1 - Schwanke, U. A1 - Schwemmer, S. A1 - Seglar-Arroyo, M. A1 - Senniappan, M. A1 - Seyffert, A. S. A1 - Shafi, N. A1 - Shiningayamwe, K. A1 - Simoni, R. A1 - Sinha, A. A1 - Sol, H. A1 - Specovius, A. A1 - Spir-Jacob, M. A1 - Stawarz, L. A1 - Steenkamp, R. A1 - Stegmann, Christian A1 - Steppa, Constantin Beverly A1 - Takahashi, T. A1 - Tavernier, T. A1 - Taylor, A. M. A1 - Terrier, R. A1 - Tiziani, D. A1 - Tluczykont, M. A1 - Trichard, C. A1 - Tsirou, M. A1 - Tsuji, N. A1 - Tuffs, R. A1 - Uchiyama, Y. A1 - van der Walt, D. J. A1 - van Eldik, C. A1 - van Rensburg, C. A1 - van Soelen, B. A1 - Vasileiadis, G. A1 - Veh, J. A1 - Venter, C. A1 - Vincent, P. A1 - Vink, J. A1 - Voisin, F. A1 - Voelk, H. J. A1 - Vuillaume, T. A1 - Wadiasingh, Z. A1 - Wagner, S. J. A1 - White, R. A1 - Wierzcholska, A. A1 - Yang, R. A1 - Yoneda, H. A1 - Zacharias, M. A1 - Zanin, R. A1 - Zdziarski, A. A. A1 - Zech, Alraune A1 - Ziegler, A. A1 - Zorn, J. A1 - Zywucka, N. A1 - Maxted, N. T1 - Upper limits on very-high-energy gamma-ray emission from core-collapse supernovae observed with H.E.S.S. JF - Astronomy and astrophysics : an international weekly journal N2 - Young core-collapse supernovae with dense-wind progenitors may be able to accelerate cosmic-ray hadrons beyond the knee of the cosmic-ray spectrum, and this may result in measurable gamma-ray emission. We searched for gamma-ray emission from ten super- novae observed with the High Energy Stereoscopic System (H.E.S.S.) within a year of the supernova event. Nine supernovae were observed serendipitously in the H.E.S.S. data collected between December 2003 and December 2014, with exposure times ranging from 1.4 to 53 h. In addition we observed SN 2016adj as a target of opportunity in February 2016 for 13 h. No significant gamma-ray emission has been detected for any of the objects, and upper limits on the >1 TeV gamma-ray flux of the order of similar to 10(-13) cm(-)(2)s(-1) are established, corresponding to upper limits on the luminosities in the range similar to 2 x 10(39) to similar to 1 x 10(42) erg s(-1). These values are used to place model-dependent constraints on the mass-loss rates of the progenitor stars, implying upper limits between similar to 2 x 10(-5) and similar to 2 x 10(-3) M-circle dot yr(-1) under reasonable assumptions on the particle acceleration parameters. KW - gamma rays: general KW - supernovae: general KW - cosmic rays Y1 - 2019 U6 - https://doi.org/10.1051/0004-6361/201935242 SN - 1432-0746 VL - 626 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Kelly, Laura A1 - Prabhakar, Janani A1 - Khemlani, Sangeet T1 - Updating and reasoning BT - Different processes, different models, different functions JF - Behavioral and brain sciences : an international journal of current research and theory with open peer commentary N2 - Two issues should be addressed to refine and extend the distinction between temporal updating and reasoning advocated by Hoerl & McCormack. First, do the mental representations constructed during updating differ from those used for reasoning? Second, are updating and reasoning the only two processes relevant to temporal thinking? If not, is a dual-systems framework sensible? We address both issues below. Y1 - 2019 U6 - https://doi.org/10.1017/S0140525X19000554 SN - 0140-525X SN - 1469-1825 VL - 42 SP - 30 EP - 31 PB - Cambridge Univ. Press CY - New York ER - TY - JOUR A1 - Kurths, Jürgen A1 - Agarwal, Ankit A1 - Shukla, Roopam A1 - Marwan, Norbert A1 - Maheswaran, Rathinasamy A1 - Caesar, Levke A1 - Krishnan, Raghavan A1 - Merz, Bruno T1 - Unravelling the spatial diversity of Indian precipitation teleconnections via a non-linear multi-scale approach JF - Nonlinear processes in geophysics N2 - A better understanding of precipitation dynamics in the Indian subcontinent is required since India's society depends heavily on reliable monsoon forecasts. We introduce a non-linear, multiscale approach, based on wavelets and event synchronization, for unravelling teleconnection influences on precipitation. We consider those climate patterns with the highest relevance for Indian precipitation. Our results suggest significant influences which are not well captured by only the wavelet coherence analysis, the state-of-the-art method in understanding linkages at multiple timescales. We find substantial variation across India and across timescales. In particular, El Niño–Southern Oscillation (ENSO) and the Indian Ocean Dipole (IOD) mainly influence precipitation in the south-east at interannual and decadal scales, respectively, whereas the North Atlantic Oscillation (NAO) has a strong connection to precipitation, particularly in the northern regions. The effect of the Pacific Decadal Oscillation (PDO) stretches across the whole country, whereas the Atlantic Multidecadal Oscillation (AMO) influences precipitation particularly in the central arid and semi-arid regions. The proposed method provides a powerful approach for capturing the dynamics of precipitation and, hence, helps improve precipitation forecasting. Y1 - 2019 U6 - https://doi.org/10.5194/npg-26-251-2019 SN - 1023-5809 SN - 1607-7946 VL - 26 IS - 3 SP - 251 EP - 266 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Tarazona, Natalia A. A1 - Machatschek, Rainhard Gabriel A1 - Lendlein, Andreas T1 - Unraveling the interplay between abiotic hydrolytic degradation and crystallization of bacterial polyesters comprising short and medium side-chain-length Polyhydroxyalkanoates JF - Biomacromolecules : an interdisciplinary journal focused at the interface of polymer science and the biological sciences N2 - Polyhydroxyalkanoates (PHAs) have attracted attention as degradable (co)polyesters which can be produced by microorganisms with variations in the side chain. This structural variation influences not only the thermomechanical properties of the material but also its degradation behavior. Here, we used Langmuir monolayers at the air-water (A-W) interface as suitable models for evaluating the abiotic degradation of two PHAs with different side-chain lengths and crystallinity. By controlling the polymer state (semi crystalline, amorphous), the packing density, the pH, and the degradation mechanism, we could draw several significant conclusions. (i) The maximum degree of crystallinity for a PHA film to be efficiently degraded up to pH = 12.3 is 40%. (ii) PHA made of repeating units with shorter side-chain length are more easily hydrolyzed under alkaline conditions. The efficiency of alkaline hydrolysis decreased by about 65% when the polymer was 40% crystalline. (iii) In PHA films with a relatively high initial crystallinity, abiotic degradation initiated a chemicrystallization phenomenon, detected as an increase in the storage modulus (E'). This could translate into an increase in brittleness and reduction in the material degradability. Finally, we demonstrate the stability of the measurement system for long-term experiments, which allows degradation conditions for polymers that could closely simulate real-time degradation. Y1 - 2019 U6 - https://doi.org/10.1021/acs.biomac.9b01458 SN - 1525-7797 SN - 1526-4602 VL - 21 IS - 2 SP - 761 EP - 771 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Zu, Fengshuo A1 - Wolff, Christian Michael A1 - Ralaiarisoa, Maryline A1 - Amsalem, Patrick A1 - Neher, Dieter A1 - Koch, Norbert T1 - Unraveling the Electronic Properties of Lead Halide Perovskites with Surface Photovoltage in Photoemission Studies JF - ACS applied materials & interfaces N2 - The tremendous success of metal-halide perovskites, especially in the field of photovoltaics, has triggered a substantial number of studies in understanding their optoelectronic properties. However, consensus regarding the electronic properties of these perovskites is lacking due to a huge scatter in the reported key parameters, such as work function (Φ) and valence band maximum (VBM) values. Here, we demonstrate that the surface photovoltage (SPV) is a key phenomenon occurring at the perovskite surfaces that feature a non-negligible density of surface states, which is more the rule than an exception for most materials under study. With ultraviolet photoelectron spectroscopy (UPS) and Kelvin probe, we evidence that even minute UV photon fluxes (500 times lower than that used in typical UPS experiments) are sufficient to induce SPV and shift the perovskite Φ and VBM by several 100 meV compared to dark. By combining UV and visible light, we establish flat band conditions (i.e., compensate the surface-state-induced surface band bending) at the surface of four important perovskites, and find that all are p-type in the bulk, despite a pronounced n-type surface character in the dark. The present findings highlight that SPV effects must be considered in all surface studies to fully understand perovskites’ photophysical properties. KW - lead halide perovskite films KW - ultraviolet photoelectron spectroscopy KW - Kelvin probe KW - surface band bending KW - surface photovoltage KW - surface states Y1 - 2019 U6 - https://doi.org/10.1021/acsami.9b05293 SN - 1944-8244 SN - 1944-8252 VL - 11 IS - 24 SP - 21578 EP - 21583 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Gutmann, Tobias A1 - Schmeiss, Jessica A1 - Stubner, Stephan T1 - Unmasking Smart Capital How Corporate Venture Capital Units Configure Value-Adding Services JF - Research-Technology Management N2 - Corporate venture capital (CVC) units help their ventures flourish by offering value-adding services. Effective CVC initiatives offer services that help ventures design, implement, and manage activities to create and capture value. Our qualitative multiple case study across 26 CVC units reveals a comprehensive set of value creation and value capture services that these units offer, configured in any of four different ways to provide tailor-made support for specific venture needs and sponsor strategic goals. KW - Corporate venture capital KW - Value capture KW - Value creation Y1 - 2019 U6 - https://doi.org/10.1080/08956308.2019.1613117 SN - 0895-6308 SN - 1930-0166 VL - 62 IS - 4 SP - 27 EP - 36 PB - Industrial Research Institute CY - Arlington ER - TY - JOUR A1 - Dehm, Daniel A1 - Krumbholz, Julia A1 - Baunach, Martin A1 - Wiebach, Vincent A1 - Hinrichs, Katrin A1 - Guljamow, Arthur A1 - Tabuchi, Takeshi A1 - Jenke-Kodama, Holger A1 - Süssmuth, Roderich D. A1 - Dittmann-Thünemann, Elke T1 - Unlocking the spatial control of secondary metabolism uncovers hidden natural product diversity in nostoc punctiforme JF - ACS chemical biology N2 - Filamentous cyanobacteria belong to the most prolific producers of structurally unique and biologically active natural products, yet the majority of biosynthetic gene clusters predicted for these multicellular collectives are currently orphan. Here, we present a systems analysis of secondary metabolite gene expression in the model strain Nostoc punctiforme PCC73102 using RNA-seq and fluorescence reporter analysis. Our data demonstrate that the majority of the cryptic gene clusters are not silent but are expressed with regular or sporadic pattern. Cultivation of N. punctiforme using high-density fermentation overrules the spatial control and leads to a pronounced upregulation of more than 50% of biosynthetic gene clusters. Our data suggest that a combination of autocrine factors, a high CO2 level, and high light account for the upregulation of individual pathways. Our overarching study not only sheds light on the strategies of filamentous cyanobacteria to share the enormous metabolic burden connected with the production of specialized molecules but provides an avenue for the genome-based discovery of natural products in multicellular cyanobacteria as exemplified by the discovery of highly unusual variants of the tricyclic peptide microviridin. Y1 - 2019 U6 - https://doi.org/10.1021/acschembio.9b00240 SN - 1554-8929 SN - 1554-8937 VL - 14 IS - 6 SP - 1271 EP - 1279 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Seyfried, Markus T1 - Undisclosed desires BT - quality managers’ normative notions regarding the implementation of quality management JF - Assessment & Evaluation in Higher Education N2 - Following decades of quality management featuring in higher education settings, questions regarding its implementation, impact and outcomes remain. Indeed, leaving aside anecdotal case studies and value-laden documentaries of best practice, current research still knows very little about the implementation of quality management in teaching and learning within higher education institutions. Referring to data collected from German higher education institutions in which a quality management department or functional equivalent was present, this article theorises and provides evidence for the supposition that the implementation of quality management follows two implicit logics. Specifically, it tends either towards the logic of appropriateness or, contrastingly, towards the logic of consequentialism. This study’s results also suggest that quality managers’ socialisation is related to these logics and that it influences their views on quality management in teaching and learning. KW - Higher education KW - quality manager KW - teaching and learning KW - appropriateness Y1 - 2019 U6 - https://doi.org/10.1080/02602938.2019.1573970 SN - 0260-2938 SN - 1469-297X VL - 44 IS - 7 SP - 1106 EP - 1119 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Wenninger, Helena Eva A1 - Krasnova, Hanna A1 - Buxmann, Peter T1 - Understanding the role of social networking sites in the subjective well-being of users BT - a diary study JF - European Journal of Information Systems N2 - Given the rising popularity of social networking sites (SNSs), the influence of these platforms on the subjective well-being (SWB) of their users is an emerging topic in information systems research. Building on the norm of reciprocity and the social functional approach to positive emotions, we posit that targeted reciprocity-evoking forms of SNS activities are best suited to promote users’ positive emotions. The favourable potential of these activities is likely to be particularly pronounced among adolescents who pay special attention to social acceptance, which can be channelled with the help of reciprocal communication. Therefore, we conducted a quantitative 7-day diary study of 162 adolescent Facebook users attending German schools, looking at the impact of their daily SNS activities on their SWB. Based on a linear mixed model analysis, our results confirm a positive link between targeted reciprocity-evoking activities – such as chatting, giving and receiving feedback – and adolescents’ positive emotions. Our findings provide a reassuring perspective on the implications of the sociotechnical design of SNS communication channels. Specifically, by encouraging targeted activities, providers, users, and other stakeholders can ensure the beneficial impact of this technology on users’ SWB. KW - non-targeted SNS activities KW - norm of reciprocity KW - social functional approach to positive emotions KW - adolescents KW - subjective well-being Y1 - 2018 U6 - https://doi.org/10.1080/0960085X.2018.1496883 SN - 0960-085X SN - 1476-9344 VL - 28 IS - 2 SP - 126 EP - 148 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Wachs, Sebastian A1 - Wright, Michelle F. A1 - Vazsonyi, Alexander Thomas T1 - Understanding the overlap between cyberbullying and cyberhate perpetration BT - Moderating effects of toxic online disinhibition JF - Criminal Behavior And Mental Health N2 - Background Problem behaviour theory postulates that different forms of norm violations cluster and can be explained by similar antecedents. One such cluster may include cyberbullying and cyberhate perpetration. A potential explanatory mechanism includes toxic online disinhibition, characterised by anonymity, an inability to empathise and to recognise and interpret social cues. The current study to develop a better understanding of the relationship between cyberhate and cyberbullying to inform effective intervention and prevention efforts. Aims To test the link between cyberbullying and cyberhate and whether this relationship was moderated by toxic online disinhibition. Methods Self-report questionnaires on cyberbullying, cyberhate, and toxic online disinhibition were completed by 1,480 adolescents between 12 and 17 years old (M = 14.21 years; SD = 1.68). Results Increases in cyberbullying perpetration and toxic online disinhibition were positively related to cyberhate perpetration. Furthermore, cyberbullies reported more cyberhate perpetration when they reported higher levels of toxic online disinhibition and less frequent cyberhate perpetration when they reported lower levels of toxic online disinhibition. Conclusion The current study provides evidence of a possible link between cyberbullying and cyberhate perpetration, moderated by toxic online disinhibition. This suggests that, to be effective, prevention and intervention programmes should (i) consider the co-occurrence of varying forms of cyberaggression and (ii) consider potential effects of the online environment on aggressive online behaviour among young people. Y1 - 2019 U6 - https://doi.org/10.1002/cbm.2116 SN - 0957-9664 SN - 1471-2857 VL - 29 IS - 3 SP - 179 EP - 188 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Yan, Runyu A1 - Josef, Elinor A1 - Huang, Haijian A1 - Leus, Karen A1 - Niederberger, Markus A1 - Hofmann, Jan P. A1 - Walczak, Ralf A1 - Antonietti, Markus A1 - Oschatz, Martin T1 - Understanding the charge storage mechanism to achieve high capacity and fast ion storage in sodium-ion capacitor anodes by using electrospun nitrogen-doped carbon fibers JF - Advanced functional materials N2 - Microporous nitrogen-rich carbon fibers (HAT-CNFs) are produced by electrospinning a mixture of hexaazatriphenylene-hexacarbonitrile (HAT-CN) and polyvinylpyrrolidone and subsequent thermal condensation. Bonding motives, electronic structure, content of nitrogen heteroatoms, porosity, and degree of carbon stacking can be controlled by the condensation temperature due to the use of the HAT-CN with predefined nitrogen binding motives. The HAT-CNFs show remarkable reversible capacities (395 mAh g(-1) at 0.1 A g(-1)) and rate capabilities (106 mAh g(-1) at 10 A g(-1)) as an anode material for sodium storage, resulting from the abundant heteroatoms, enhanced electrical conductivity, and rapid charge carrier transport in the nanoporous structure of the 1D fibers. HAT-CNFs also serve as a series of model compounds for the investigation of the contribution of sodium storage by intercalation and reversible binding on nitrogen sites at different rates. There is an increasing contribution of intercalation to the charge storage with increasing condensation temperature which becomes less active at high rates. A hybrid sodium-ion capacitor full cell combining HAT-CNF as the anode and salt-templated porous carbon as the cathode provides remarkable performance in the voltage range of 0.5-4.0 V (95 Wh kg(-1) at 0.19 kW kg(-1) and 18 Wh kg(-1) at 13 kW kg(-1)). KW - carbon fibers KW - nitrogen-doped carbon KW - sodium-ion capacitors KW - sodium storage mechanism Y1 - 2019 U6 - https://doi.org/10.1002/adfm.201902858 SN - 1616-301X SN - 1616-3028 VL - 29 IS - 26 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Ion, Alexandra A1 - Lindlbauer, David A1 - Herholz, Philipp A1 - Alexa, Marc A1 - Baudisch, Patrick Markus T1 - Understanding Metamaterial Mechanisms JF - Proceedings of the 2019 CHI Conference on Human Factors in Computing Systems N2 - In this paper, we establish the underlying foundations of mechanisms that are composed of cell structures-known as metamaterial mechanisms. Such metamaterial mechanisms were previously shown to implement complete mechanisms in the cell structure of a 3D printed material, without the need for assembly. However, their design is highly challenging. A mechanism consists of many cells that are interconnected and impose constraints on each other. This leads to unobvious and non-linear behavior of the mechanism, which impedes user design. In this work, we investigate the underlying topological constraints of such cell structures and their influence on the resulting mechanism. Based on these findings, we contribute a computational design tool that automatically creates a metamaterial mechanism from user-defined motion paths. This tool is only feasible because our novel abstract representation of the global constraints highly reduces the search space of possible cell arrangements. KW - Metamaterials KW - fabrication KW - computational design Y1 - 2019 SN - 978-1-4503-5970-2 U6 - https://doi.org/10.1145/3290605.3300877 PB - Association for Computing Machinery CY - New York ER - TY - JOUR A1 - Veh, Georg A1 - Korup, Oliver A1 - von Specht, Sebastian A1 - Rößner, Sigrid A1 - Walz, Ariane T1 - Unchanged frequency of moraine-dammed glacial lake outburst floods in the Himalaya JF - Nature climate change N2 - Shrinking glaciers in the Hindu Kush-Karakoram-Himalaya-Nyainqentanglha (HKKHN) region have formed several thousand moraine-dammed glacial lakes(1-3), some of these having grown rapidly in past decades(3,4). This growth may promote more frequent and potentially destructive glacial lake outburst floods (GLOFs)(5-7). Testing this hypothesis, however, is confounded by incomplete databases of the few reliable, though selective, case studies. Here we present a consistent Himalayan GLOF inventory derived automatically from all available Landsat imagery since the late 1980s. We more than double the known GLOF count and identify the southern Himalayas as a hotspot region, compared to the more rarely affected Hindu Kush-Karakoram ranges. Nevertheless, the average annual frequency of 1.3 GLOFs has no credible posterior trend despite reported increases in glacial lake areas in most of the HKKHN3,8, so that GLOF activity per unit lake area has decreased since the late 1980s. We conclude that learning more about the frequency and magnitude of outburst triggers, rather than focusing solely on rapidly growing glacial lakes, might improve the appraisal of GLOF hazards. KW - Climate change KW - Cryospheric science KW - Environmental impact KW - Geomorphology Y1 - 2019 U6 - https://doi.org/10.1038/s41558-019-0437-5 SN - 1758-678X SN - 1758-6798 VL - 9 IS - 5 SP - 379 EP - 383 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Friedrich, Tobias A1 - Kötzing, Timo A1 - Krejca, Martin Stefan T1 - Unbiasedness of estimation-of-distribution algorithms JF - Theoretical computer science N2 - In the context of black-box optimization, black-box complexity is used for understanding the inherent difficulty of a given optimization problem. Central to our understanding of nature-inspired search heuristics in this context is the notion of unbiasedness. Specialized black-box complexities have been developed in order to better understand the limitations of these heuristics - especially of (population-based) evolutionary algorithms (EAs). In contrast to this, we focus on a model for algorithms explicitly maintaining a probability distribution over the search space: so-called estimation-of-distribution algorithms (EDAs). We consider the recently introduced n-Bernoulli-lambda-EDA framework, which subsumes, for example, the commonly known EDAs PBIL, UMDA, lambda-MMAS(IB), and cGA. We show that an n-Bernoulli-lambda-EDA is unbiased if and only if its probability distribution satisfies a certain invariance property under isometric automorphisms of [0, 1](n). By restricting how an n-Bernoulli-lambda-EDA can perform an update, in a way common to many examples, we derive conciser characterizations, which are easy to verify. We demonstrate this by showing that our examples above are all unbiased. (C) 2018 Elsevier B.V. All rights reserved. KW - Estimation-of-distribution algorithm KW - Unbiasedness KW - Theory Y1 - 2019 U6 - https://doi.org/10.1016/j.tcs.2018.11.001 SN - 0304-3975 SN - 1879-2294 VL - 785 SP - 46 EP - 59 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Oskinova, Lida A1 - Bik, A. A1 - Mas-Hesse, J. M. A1 - Hayes, M. A1 - Adamo, A. A1 - Östlin, Göran A1 - Fürst, F. A1 - Otí-Floranes, H. T1 - ULX contribution to stellar feedback BT - an intermediate-mass black hole candidate and the population of ULXs in the low-metallicity starburst galaxy ESO338-4 JF - Astronomy and astrophysics : an international weekly journal N2 - Context. X-ray radiation from accreting compact objects is an important part of stellar feedback. The metal-poor galaxy ESO 338-4 has experienced vigorous starburst during the last <40 Myr and contains some of the most massive super star clusters in the nearby Universe. Given its starburst age and its star-formation rate, ESO 338-4 is one of the most efficient nearby manufactures of neutron stars and black holes, hence providing an excellent laboratory for feedback studies. Aims. We aim to use X-ray observations with the largest modern X-ray telescopes XMM-Newton and Chandra to unveil the most luminous accreting neutron stars and black holes in ESO 338-4. Methods. We compared X-ray images and spectra with integral field spectroscopic observations in the optical to constrain the nature of strong X-ray emitters. Results. X-ray observations uncover three ultraluminous X-ray sources (ULXs) in ESO 338-4. The brightest among them, ESO 338 X-1, has X-ray luminosity in excess of 10(40) erg s(-1). We speculate that ESO 338-4 X-1 is powered by accretion on an intermediate-mass (greater than or similar to 300 M-circle dot)black hole. We show that X-ray radiation from ULXs and hot superbubbles strongly contributes to He II ionization and general stellar feedback in this template starburst galaxy. KW - galaxies: dwarf KW - galaxies: individual: ESO 338-4 KW - X-rays: binaries KW - X-rays: ISM Y1 - 2019 U6 - https://doi.org/10.1051/0004-6361/201935414 SN - 1432-0746 VL - 627 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Pudell, Jan-Etienne A1 - Reppert, Alexander von A1 - Schick, D. A1 - Zamponi, F. A1 - Rössle, Matthias A1 - Herzog, Marc A1 - Zabel, Hartmut A1 - Bargheer, Matias T1 - Ultrafast negative thermal expansion driven by spin disorder JF - Physical review : B, Condensed matter and materials physics N2 - We measure the transient strain profile in a nanoscale multilayer system composed of yttrium, holmium, and niobium after laser excitation using ultrafast x-ray diffraction. The strain propagation through each layer is determined by transient changes in the material-specific Bragg angles. We experimentally derive the exponentially decreasing stress profile driving the strain wave and show that it closely matches the optical penetration depth. Below the Neel temperature of Ho, the optical excitation triggers negative thermal expansion, which is induced by a quasi-instantaneous contractive stress and a second contractive stress contribution increasing on a 12-ps timescale. These two timescales were recently measured for the spin disordering in Ho [Rettig et al., Phys. Rev. Lett. 116, 257202 (2016)]. As a consequence, we observe an unconventional bipolar strain pulse with an inverted sign traveling through the heterostructure. Y1 - 2019 U6 - https://doi.org/10.1103/PhysRevB.99.094304 SN - 2469-9950 SN - 2469-9969 VL - 99 IS - 9 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Betke, Alexander A1 - Lokstein, Heiko T1 - Two-photon excitation spectroscopy of photosynthetic light-harvesting complexes and pigments JF - Faraday discussions N2 - In addition to (bacterio)chlorophylls, (B)Chls, light-harvesting complexes (LHCs) bind carotenoids, and/or their oxygen derivatives, xanthophylls. Xanthophylls/carotenoids have pivotal functions in LHCs: in stabilization of the structure, as accessory light-harvesting pigments and, probably most importantly, in photoprotection. Xanthophylls are assumed to be involved in the not yet fully understood mechanism of energy-dependent (qE) non-photochemical quenching of Chl fluorescence (NPQ) in higher plants and algae. The so called "xanthophyll cycle" appears to be crucial in this regard. The molecular mechanism(s) of xanthophyll involvement in qE/NPQ have not been established, yet. Moreover, excitation energy transfer (EET) processes involving carotenoids are also difficult to study, due to the fact that transitions between the ground state (S-0, 1(1)A(g)(-)) and the lowest excited singlet state (S-1, 2(1)A(g)(-)) of carotenoids are optically one-photon forbidden ("dark"). Two-photon excitation spectroscopic techniques have been used for more than two decades to study one-photon forbidden states of carotenoids. In the current study, two-photon excitation profiles of LHCII samples containing different xanthophyll complements were measured in the presumed 1(1)A(g)(-) -> 2(1)A(g)(-) (S-0 -> S-1) transition spectral region of the xanthophylls, as well as for isolated chlorophylls a and b in solution. The results indicate that direct two-photon excitation of Chls in this spectral region is dominant over that by xanthophylls. Implications of the results for proposed mechanism(s) of qE/NPQ will be discussed. Y1 - 2019 U6 - https://doi.org/10.1039/c8fd00198g SN - 1359-6640 SN - 1364-5498 VL - 216 SP - 494 EP - 506 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Azzali, Sara A1 - Wahl, Charlotte T1 - Two-cocycle twists and Atiyah-Patodi-Singer index theory JF - Mathematical Proceedings of the Cambridge Philosophical Society N2 - We construct eta- and rho-invariants for Dirac operators, on the universal covering of a closed manifold, that are invariant under the projective action associated to a 2-cocycle of the fundamental group. We prove an Atiyah-Patodi-Singer index theorem in this setting, as well as its higher generalisation. Applications concern the classification of positive scalar curvature metrics on closed spin manifolds. We also investigate the properties of these twisted invariants for the signature operator and the relation to the higher invariants. Y1 - 2019 U6 - https://doi.org/10.1017/S0305004118000427 SN - 0305-0041 SN - 1469-8064 VL - 167 IS - 3 SP - 437 EP - 487 PB - Cambridge Univ. Press CY - New York ER - TY - JOUR A1 - Tyulkina, Irina V. A1 - Goldobin, Denis S. A1 - Klimenko, Lyudmila S. A1 - Pikovskij, Arkadij T1 - Two-Bunch Solutions for the Dynamics of Ott–Antonsen Phase Ensembles JF - Radiophysics and Quantum Electronics N2 - We have developed a method for deriving systems of closed equations for the dynamics of order parameters in the ensembles of phase oscillators. The Ott-Antonsen equation for the complex order parameter is a particular case of such equations. The simplest nontrivial extension of the Ott-Antonsen equation corresponds to two-bunch states of the ensemble. Based on the equations obtained, we study the dynamics of multi-bunch chimera states in coupled Kuramoto-Sakaguchi ensembles. We show an increase in the dimensionality of the system dynamics for two-bunch chimeras in the case of identical phase elements and a transition to one-bunch "Abrams chimeras" for imperfect identity (in the latter case, the one-bunch chimeras become attractive). Y1 - 2019 U6 - https://doi.org/10.1007/s11141-019-09924-7 SN - 0033-8443 SN - 1573-9120 VL - 61 IS - 8-9 SP - 640 EP - 649 PB - Springer CY - New York ER - TY - JOUR A1 - Omole, Ruth Anyango A1 - Moshi, Mainen Julius A1 - Heydenreich, Matthias A1 - Malebo, Hamisi Masanja A1 - Gathirwa, Jeremiah Waweru A1 - Ochieng, Sharon Alice A1 - Omosa, Leonida Kerubo A1 - Midiwo, Jacob Ogweno T1 - Two lignans derivatives and two fusicoccane diterpenoids from the whole plant of Hypoestes verticillaris (L.F.) Sol. Ex roem. & schult JF - Phytochemistry letters N2 - Bioassay-guided screening of Hypoestes verticillaris whole plant CH2Cl2: MeOH (1:1) extract for anti-plasmodial activity yielded four new compounds: two lignans 2, 6-dimethoxysavinin (1), 2,6-dimethoxy-(7E)-7,8-dehydroheliobuphthalmin (2); and two fusicoccane diterpenoids: 11(12)-epoxyhypoestenone (3) and 3(11)-epoxyhypoestenone (4). The chemical structures were determined using various spectroscopic techniques: UV-vis, IR, CD, 1D, 2D and MS. Two fractions (RAO-43B and RAO-43D) and the isolated compounds were tested for activity against CQ susceptible (D6) and resistant (W2) Plasmodium falciparum parasite strains, in vitro and the IC50 values determined. While the whole extract and some resultant fractions displayed moderate activity, the isolated compounds exhibited mild anti-plasmodial activity against the both strains ranging from IC50 value of 328 mu M in 1 to 93 mu M in 3 against W2 strain. KW - Fusicoccane diterpenes KW - Lignans KW - Hypoestes verticillaris KW - Anti-Plasmodial activity Y1 - 2019 U6 - https://doi.org/10.1016/j.phytol.2019.02.019 SN - 1874-3900 SN - 1876-7486 VL - 30 SP - 194 EP - 200 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Bolotov, Dmitry A1 - Bolotov, Maxim I. A1 - Smirnov, Lev A. A1 - Osipov, Grigory V. A1 - Pikovskij, Arkadij T1 - Twisted States in a System of Nonlinearly Coupled Phase Oscillators JF - Regular and chaotic dynamics : international scientific journal N2 - We study the dynamics of the ring of identical phase oscillators with nonlinear nonlocal coupling. Using the Ott - Antonsen approach, the problem is formulated as a system of partial derivative equations for the local complex order parameter. In this framework, we investigate the existence and stability of twisted states. Both fully coherent and partially coherent stable twisted states were found (the latter ones for the first time for identical oscillators). We show that twisted states can be stable starting from a certain critical value of the medium length, or on a length segment. The analytical results are confirmed with direct numerical simulations in finite ensembles. KW - twisted state KW - phase oscillators KW - nonlocal coupling KW - Ott - Antonsen reduction KW - stability analysis Y1 - 2019 U6 - https://doi.org/10.1134/S1560354719060091 SN - 1560-3547 SN - 1468-4845 VL - 24 IS - 6 SP - 717 EP - 724 PB - Pleiades publishing inc CY - Moscow ER - TY - JOUR A1 - Yılmaz, Zafer A1 - Turner, Bryan S. T1 - Turkey’s deepening authoritarianism and the fall of electoral democracy JF - British journal of Middle Eastern studies Y1 - 2019 U6 - https://doi.org/10.1080/13530194.2019.1642662 SN - 1353-0194 SN - 1469-3542 VL - 46 IS - 5 SP - 691 EP - 698 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Ganguli, Poulomi A1 - Merz, Bruno T1 - Trends in Compound Flooding in Northwestern Europe During 1901-2014 JF - Geophysical research letters N2 - We analyze trends in compound flooding resulting from high coastal water levels (HCWLs) and peak river discharge over northwestern Europe during 1901-2014. Compound peak discharge associated with 37 stream gauges with at least 70 years of record availability near the North and Baltic Sea coasts is used. Compound flooding is assessed using a newly developed index, compound hazard ratio, that compares the severity of river flooding associated with HCWL with the at-site, T-year (a flood with 1/T chance of being exceeded in any given year) fluvial peak discharge. Our findings suggest a spatially coherent pattern in the dependence between HCWL and river peaks and in compound flood magnitudes and frequency. For higher return levels, we find upward trends in compound hazard ratio frequency at midlatitudes (gauges from 47 degrees N to 60 degrees N) and downward trends along the high latitude (>60 degrees N) regions of northwestern Europe. Plain Language Summary Compound floods in delta areas, that is, the co-occurrence of high coastal water levels (HCWLs) and high river discharge, are a particular challenge for disaster management. Such events are caused by two distinct mechanisms: (1) HCWLs may affect river flows and water levels by backwater effects or by reversing the seaward flow of rivers, particularly in regions with elevation less than 10 m in northwestern Europe. (2) The correlation between HCWL and river flow peaks may also stem from a common meteorological driver. Severe storm periods may be associated with high winds leading to storm surges, and at the same time with high precipitation followed by inland flooding. Understanding the historical trends in compound flooding, owing to changes in relative sea levels, in river flooding and in the dependence between these two drivers, is essential for projecting future changes and disaster management. The risk assessment frameworks are often limited to assessing flood risk from a single driver only. We present a new approach to assess compound flood severity resulting from extreme coastal water level and peak river discharge. We find upward trends in compound flooding for midlatitude regions and downward trends for high latitudes in northwestern Europe. KW - compound flood KW - northwestern Europe KW - risk modeling KW - dependence Y1 - 2019 U6 - https://doi.org/10.1029/2019GL084220 SN - 0094-8276 SN - 1944-8007 VL - 46 IS - 19 SP - 10810 EP - 10820 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Rohn, Isabelle A1 - Raschke, Stefanie A1 - Aschner, Michael A1 - Tuck, Simon A1 - Kuehnelt, Doris A1 - Kipp, Anna Patricia A1 - Schwerdtle, Tanja A1 - Bornhorst, Julia T1 - Treatment of caenorhabditis elegans with small selenium species enhances antioxidant defense systems JF - Molecular nutrition & food research : bioactivity, chemistry, immunology, microbiology, safety, technology N2 - ScopeSmall selenium (Se) species play a key role in Se metabolism and act as dietary sources of the essential trace element. However, they are redox-active and trigger pro- and antioxidant responses. As health outcomes are strongly species-dependent, species-specific characteristics of Se compounds are tested in vivo. Methods and resultsIn the model organism Caenorhabditis elegans (C. elegans), immediate and sustained effects of selenite, selenomethionine (SeMet), and Se-methylselenocysteine (MeSeCys) are studied regarding their bioavailability, incorporation into proteins, as well as modulation of the cellular redox status. While all tested Se compounds are bioavailable, only SeMet persistently accumulates and is non-specifically incorporated into proteins. However, the protection toward chemically-induced formation of reactive species is independent of the applied Se compound. Increased thioredoxin reductase (TXNRD) activity and changes in mRNA expression levels of antioxidant proteins indicate the activation of cellular defense mechanisms. However, in txnrd-1 deletion mutants, no protective effects of the Se species are observed anymore, which is also reflected by differential gene expression data. ConclusionSe species protect against chemically-induced reactive species formation. The identified immediate and sustained systemic effects of Se species give rise to speculations on possible benefits facing subsequent periods of inadequate Se intake. KW - antioxidant defense systems KW - caenorhabditis elegans KW - selenium KW - oxidative stress KW - selenoproteins Y1 - 2019 U6 - https://doi.org/10.1002/mnfr.201801304 SN - 1613-4125 SN - 1613-4133 VL - 63 IS - 9 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Grebenkov, Denis S. A1 - Metzler, Ralf A1 - Oshanin, Gleb A1 - Dagdug, Leonardo A1 - Berezhkovskii, Alexander M. A1 - Skvortsov, Alexei T. T1 - Trapping of diffusing particles by periodic absorbing rings on a cylindrical tube JF - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr Y1 - 2019 U6 - https://doi.org/10.1063/1.5098390 SN - 0021-9606 SN - 1089-7690 VL - 150 IS - 20 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Sheikholeslami, Mohammad Reza A1 - Oberhänsli, Roland A1 - Ghassemi, Mohammad R. T1 - Transpression tectonics in the eastern Binalud Mountains, northeast Iran; Insight from finite strain analysis, vorticity and Ar-40/Ar-39 dating JF - Journal of Asian earth sciences N2 - Different tectonic episodes from Late Triassic to recent times in the eastern Binalud Mountains have resulted from convergence and transpression between the Turan and Central Iran plates. Heterogeneous deformation and variable portions of pure and simple shear, demonstrated by finite strain and vorticity analysis in the Mashhad metamorphic rocks, indicate strain partitioning during the first tectonic episode. Modern strain partitioning is characterized by reverse and strike-slip faulting along the Neyshabur fault system and Shandiz fault zone in the southern and northern flanks of the eastern Binalud, respectively. Time-transgressive regional deformation migrated from the hinterland of the belt into the foreland basin, from northeast to the southwest of the mountains. Different generations of deformation resulted in obliteration of the subduction-related accretionary wedge, and growth of an orogenic wedge resulted from collision between the Central Iran and Turan plates. KW - Transpression KW - Binalud Mountains KW - Deformation KW - Orogenic wedge KW - Northeast Iran Y1 - 2019 U6 - https://doi.org/10.1016/j.jseaes.2019.04.014 SN - 1367-9120 SN - 1878-5786 VL - 179 SP - 219 EP - 237 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Teomy, Eial A1 - Metzler, Ralf T1 - Transport in exclusion processes with one-step memory: density dependence and optimal acceleration JF - Journal of physics : A, Mathematical and theoretical N2 - We study a lattice gas of persistent walkers, in which each site is occupied by at most one particle and the direction each particle attempts to move to depends on its last step. We analyse the mean squared displacement (MSD) of the particles as a function of the particle density and their persistence (the tendency to continue moving in the same direction). For positive persistence the MSD behaves as expected: it increases with the persistence and decreases with the density. However, for strong anti-persistence we find two different regimes, in which the dependence of the MSD on the density is non-monotonic. For very strong anti-persistence there is an optimal density at which the MSD reaches a maximum. In an intermediate regime, the MSD as a function of the density exhibits both a minimum and a maximum, a phenomenon which has not been observed before. We derive a mean-field theory which qualitatively explains this behaviour. KW - exclusion process KW - persistence KW - lattice gas Y1 - 2019 U6 - https://doi.org/10.1088/1751-8121/ab37e4 SN - 1751-8113 SN - 1751-8121 VL - 52 IS - 38 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Aseev, Nikita A1 - Shprits, Yuri Y. A1 - Wang, Dedong A1 - Wygant, John A1 - Drozdov, Alexander A1 - Kellerman, Adam C. A1 - Reeves, Geoffrey D. T1 - Transport and loss of ring current electrons inside geosynchronous orbit during the 17 March 2013 storm JF - Journal of geophysical research : Space physics N2 - Ring current electrons (1–100 keV) have received significant attention in recent decades, but many questions regarding their major transport and loss mechanisms remain open. In this study, we use the four‐dimensional Versatile Electron Radiation Belt code to model the enhancement of phase space density that occurred during the 17 March 2013 storm. Our model includes global convection, radial diffusion, and scattering into the Earth's atmosphere driven by whistler‐mode hiss and chorus waves. We study the sensitivity of the model to the boundary conditions, global electric field, the electric field associated with subauroral polarization streams, electron loss rates, and radial diffusion coefficients. The results of the code are almost insensitive to the model parameters above 4.5 RERE, which indicates that the general dynamics of the electrons between 4.5 RE and the geostationary orbit can be explained by global convection. We found that the major discrepancies between the model and data can stem from the inaccurate electric field model and uncertainties in lifetimes. We show that additional mechanisms that are responsible for radial transport are required to explain the dynamics of ≥40‐keV electrons, and the inclusion of the radial diffusion rates that are typically assumed in radiation belt studies leads to a better agreement with the data. The overall effect of subauroral polarization streams on the electron phase space density profiles seems to be smaller than the uncertainties in other input parameters. This study is an initial step toward understanding the dynamics of these particles inside the geostationary orbit. KW - ring current electrons KW - magnetospheric convection KW - ensemble modeling KW - inner magnetosphere KW - electron transport KW - wave-particle interactions Y1 - 2019 U6 - https://doi.org/10.1029/2018JA026031 SN - 2169-9380 SN - 2169-9402 VL - 124 IS - 2 SP - 915 EP - 933 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Driver, Cory T1 - Translating Jewish Cemeteries in Morocco JF - PaRDeS : Zeitschrift der Vereinigung für Jüdische Studien = Transformative Translations in Jewish History and Culture N2 - This paper addresses issues of translating both words and rituals as Muslim cemetery keepers care for Jewish graves and recite traditional prayers for the dead in Morocco. Several issues of translation must be dealt with while considering these rare and disappearing practices. The first issue to be discussed is the translation of Hebrew inscriptions into French by cemetery keepers. One cemetery keeper in Meknes has tried to compile an exhaustive index of the names and dates represented on the gravestones under her care. The Muslim guard of the Jewish cemetery in Sefrou, on the other hand, has somewhat famously told visitors differing stories about his ability and willingness to pray the Kaddish over the graves of emigrated relatives who cannot return to mark an anniversary death. These practices provide the context for considering how the act of Muslims caring for Jewish graves creates linguistic and ritual translations of traditional Jewish ancestor care. Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-471385 SN - 978-3-86956-468-5 SN - 1614-6492 SN - 1862-7684 VL - 2019 IS - 25 SP - 89 EP - 102 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Thapa, Samudrajit A1 - Lukat, Nils A1 - Selhuber-Unkel, Christine A1 - Cherstvy, Andrey G. A1 - Metzler, Ralf T1 - Transient superdiffusion of polydisperse vacuoles in highly motile amoeboid cells JF - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr N2 - We perform a detailed statistical analysis of diffusive trajectories of membrane-enclosed vesicles (vacuoles) in the supercrowded cytoplasm of living Acanthamoeba castellanii cells. From the vacuole traces recorded in the center-of-area frame of moving amoebae, we examine the statistics of the time-averaged mean-squared displacements of vacuoles, their generalized diffusion coefficients and anomalous scaling exponents, the ergodicity breaking parameter, the non-Gaussian features of displacement distributions of vacuoles, the displacement autocorrelation function, as well as the distributions of speeds and positions of vacuoles inside the amoeba cells. Our findings deliver novel insights into the internal dynamics of cellular structures in these infectious pathogens. Published under license by AIP Publishing. Y1 - 2019 U6 - https://doi.org/10.1063/1.5086269 SN - 0021-9606 SN - 1089-7690 VL - 150 IS - 14 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Draisbach, Uwe A1 - Christen, Peter A1 - Naumann, Felix T1 - Transforming pairwise duplicates to entity clusters for high-quality duplicate detection JF - ACM Journal of Data and Information Quality N2 - Duplicate detection algorithms produce clusters of database records, each cluster representing a single real-world entity. As most of these algorithms use pairwise comparisons, the resulting (transitive) clusters can be inconsistent: Not all records within a cluster are sufficiently similar to be classified as duplicate. Thus, one of many subsequent clustering algorithms can further improve the result.
We explain in detail, compare, and evaluate many of these algorithms and introduce three new clustering algorithms in the specific context of duplicate detection. Two of our three new algorithms use the structure of the input graph to create consistent clusters. Our third algorithm, and many other clustering algorithms, focus on the edge weights, instead. For evaluation, in contrast to related work, we experiment on true real-world datasets, and in addition examine in great detail various pair-selection strategies used in practice. While no overall winner emerges, we are able to identify best approaches for different situations. In scenarios with larger clusters, our proposed algorithm, Extended Maximum Clique Clustering (EMCC), and Markov Clustering show the best results. EMCC especially outperforms Markov Clustering regarding the precision of the results and additionally has the advantage that it can also be used in scenarios where edge weights are not available. KW - Record linkage KW - data matching KW - entity resolution KW - deduplication KW - clustering Y1 - 2019 U6 - https://doi.org/10.1145/3352591 SN - 1936-1955 SN - 1936-1963 VL - 12 IS - 1 SP - 1 EP - 30 PB - Association for Computing Machinery CY - New York ER - TY - JOUR A1 - Marszałek, Magdalena T1 - Transculturality and Its Discontents: Some Notes on Polish Literature “without a Fixed Abode” with a Focus on Jewish-Polish Literature between the Two World Wars JF - Slavia Iaponica N2 - Der Artikel fragt nach einem möglichen Geltungsbereich heutiger Konzeptualisierungen der literarischen Transkulturalität für die polnische(n) Literatur(en). Der Hintergrund der Überlegungen ist die ‚monokulturelle‘ Kondition der polnischen Gesellschaft nach den Katastrophen des 20. Jahrhunderts, die u.a. in den literarischen Rückgriffen auf die vergangene kulturelle Pluralität in den letzten drei Dekaden kritisch reflektiert wurde, heute aber wieder – in der populistisch-nationalistischen Politik – affirmiert wird. Dabei ermöglicht eine historische Perspektive auf die kulturellen Verflechtungen des literarischen Schreibens in der polnischen Sprache einen Einblick in die historisch heterogenen Formen literarischer Transkulturalität, die von den jeweiligen politischen und sozialen Kontexten abhängen. Eine umfassende Behandlung des Schreibens in der polnischen Sprache unter Bedingungen des Sprachwechsels bzw. der Mehrsprachigkeit seit der frühen Neuzeit bis zum 20. Jh. bleibt ein Desiderat. Den Höhepunkt einer auf diese Art gedachten Literaturgeschichte bildet – so die These des Artikels – die spezifische Ausprägung der polnisch-jüdischen Literatur in der Zwischenkriegszeit, in welcher Konzepte einer hybriden Doppelzugehörigkeit in linguistischen und topographischen Chiasmen dramatisch auf die Spitze getrieben werden und somit die ungelösten Probleme der Zeit spiegeln. Y1 - 2019 SN - ISSN 0913-0586 VL - 2019 IS - 22 SP - 31 EP - 44 CY - Tokio ER - TY - JOUR A1 - Zeuschner, Steffen Peer A1 - Parpiiev, Tymur A1 - Pezeril, Thomas A1 - Hillion, Arnaud A1 - Dumesnil, Karine A1 - Anane, Abdelmadjid A1 - Pudell, Jan-Etienne A1 - Willig, Lisa A1 - Rössle, Matthias A1 - Herzog, Marc A1 - Reppert, Alexander von A1 - Bargheer, Matias T1 - Tracking picosecond strain pulses in heterostructures that exhibit giant magnetostriction JF - Structural Dynamics N2 - We combine ultrafast X-ray diffraction (UXRD) and time-resolved Magneto-Optical Kerr Effect (MOKE) measurements to monitor the strain pulses in laser-excited TbFe2/Nb heterostructures. Spatial separation of the Nb detection layer from the laser excitation region allows for a background-free characterization of the laser-generated strain pulses. We clearly observe symmetric bipolar strain pulses if the excited TbFe2 surface terminates the sample and a decomposition of the strain wavepacket into an asymmetric bipolar and a unipolar pulse, if a SiO2 glass capping layer covers the excited TbFe2 layer. The inverse magnetostriction of the temporally separated unipolar strain pulses in this sample leads to a MOKE signal that linearly depends on the strain pulse amplitude measured through UXRD. Linear chain model simulations accurately predict the timing and shape of UXRD and MOKE signals that are caused by the strain reflections from multiple interfaces in the heterostructure. KW - Heterostructures KW - Magnetooptical effects KW - Metal oxides KW - Crystal lattices KW - Transition metals KW - Magnetism KW - Ultrafast X-ray diffraction KW - Lasers KW - Bragg peak KW - Phonons Y1 - 2019 U6 - https://doi.org/10.1063/1.5084140 SN - 2329-7778 VL - 6 IS - 2 PB - AIP Publishing LLC CY - Melville, NY ER - TY - JOUR A1 - Fages, Antoine A1 - Hanghoj, Kristian A1 - Khan, Naveed A1 - Gaunitz, Charleen A1 - Seguin-Orlando, Andaine A1 - Leonardi, Michela A1 - Constantz, Christian McCrory A1 - Gamba, Cristina A1 - Al-Rasheid, Khaled A. S. A1 - Albizuri, Silvia A1 - Alfarhan, Ahmed H. A1 - Allentoft, Morten A1 - Alquraishi, Saleh A1 - Anthony, David A1 - Baimukhanov, Nurbol A1 - Barrett, James H. A1 - Bayarsaikhan, Jamsranjav A1 - Benecke, Norbert A1 - Bernaldez-Sanchez, Eloisa A1 - Berrocal-Rangel, Luis A1 - Biglari, Fereidoun A1 - Boessenkool, Sanne A1 - Boldgiv, Bazartseren A1 - Brem, Gottfried A1 - Brown, Dorcas A1 - Burger, Joachim A1 - Crubezy, Eric A1 - Daugnora, Linas A1 - Davoudi, Hossein A1 - Damgaard, Peter de Barros A1 - de Chorro y de Villa-Ceballos, Maria de los Angeles A1 - Deschler-Erb, Sabine A1 - Detry, Cleia A1 - Dill, Nadine A1 - Oom, Maria do Mar A1 - Dohr, Anna A1 - Ellingvag, Sturla A1 - Erdenebaatar, Diimaajav A1 - Fathi, Homa A1 - Felkel, Sabine A1 - Fernandez-Rodriguez, Carlos A1 - Garcia-Vinas, Esteban A1 - Germonpre, Mietje A1 - Granado, Jose D. A1 - Hallsson, Jon H. A1 - Hemmer, Helmut A1 - Hofreiter, Michael A1 - Kasparov, Aleksei A1 - Khasanov, Mutalib A1 - Khazaeli, Roya A1 - Kosintsev, Pavel A1 - Kristiansen, Kristian A1 - Kubatbek, Tabaldiev A1 - Kuderna, Lukas A1 - Kuznetsov, Pavel A1 - Laleh, Haeedeh A1 - Leonard, Jennifer A. A1 - Lhuillier, Johanna A1 - von Lettow-Vorbeck, Corina Liesau A1 - Logvin, Andrey A1 - Lougas, Lembi A1 - Ludwig, Arne A1 - Luis, Cristina A1 - Arruda, Ana Margarida A1 - Marques-Bonet, Tomas A1 - Silva, Raquel Matoso A1 - Merz, Victor A1 - Mijiddorj, Enkhbayar A1 - Miller, Bryan K. A1 - Monchalov, Oleg A1 - Mohaseb, Fatemeh A. A1 - Morales, Arturo A1 - Nieto-Espinet, Ariadna A1 - Nistelberger, Heidi A1 - Onar, Vedat A1 - Palsdottir, Albina H. A1 - Pitulko, Vladimir A1 - Pitskhelauri, Konstantin A1 - Pruvost, Melanie A1 - Sikanjic, Petra Rajic A1 - Papesa, Anita Rapan A1 - Roslyakova, Natalia A1 - Sardari, Alireza A1 - Sauer, Eberhard A1 - Schafberg, Renate A1 - Scheu, Amelie A1 - Schibler, Jorg A1 - Schlumbaum, Angela A1 - Serrand, Nathalie A1 - Serres-Armero, Aitor A1 - Shapiro, Beth A1 - Seno, Shiva Sheikhi A1 - Shevnina, Irina A1 - Shidrang, Sonia A1 - Southon, John A1 - Star, Bastiaan A1 - Sykes, Naomi A1 - Taheri, Kamal A1 - Taylor, William A1 - Teegen, Wolf-Rudiger A1 - Vukicevic, Tajana Trbojevic A1 - Trixl, Simon A1 - Tumen, Dashzeveg A1 - Undrakhbold, Sainbileg A1 - Usmanova, Emma A1 - Vahdati, Ali A1 - Valenzuela-Lamas, Silvia A1 - Viegas, Catarina A1 - Wallner, Barbara A1 - Weinstock, Jaco A1 - Zaibert, Victor A1 - Clavel, Benoit A1 - Lepetz, Sebastien A1 - Mashkour, Marjan A1 - Helgason, Agnar A1 - Stefansson, Kari A1 - Barrey, Eric A1 - Willerslev, Eske A1 - Outram, Alan K. A1 - Librado, Pablo A1 - Orlando, Ludovic T1 - Tracking five millennia of horse management with extensive ancient genome time series JF - Cell N2 - Horse domestication revolutionized warfare and accelerated travel, trade, and the geographic expansion of languages. Here, we present the largest DNA time series for a non-human organism to date, including genome-scale data from 149 ancient animals and 129 ancient genomes (>= 1-fold coverage), 87 of which are new. This extensive dataset allows us to assess the modem legacy of past equestrian civilisations. We find that two extinct horse lineages existed during early domestication, one at the far western (Iberia) and the other at the far eastern range (Siberia) of Eurasia. None of these contributed significantly to modern diversity. We show that the influence of Persian-related horse lineages increased following the Islamic conquests in Europe and Asia. Multiple alleles associated with elite-racing, including at the MSTN "speed gene," only rose in popularity within the last millennium. Finally, the development of modem breeding impacted genetic diversity more dramatically than the previous millennia of human management. Y1 - 2019 U6 - https://doi.org/10.1016/j.cell.2019.03.049 SN - 0092-8674 SN - 1097-4172 VL - 177 IS - 6 SP - 1419 EP - 1435 PB - Cell Press CY - Cambridge ER - TY - JOUR A1 - Calitri, Francesca A1 - Sommer, Michael A1 - Norton, Kevin A1 - Temme, Arnaud A1 - Brandova, Dagmar A1 - Portes, Raquel A1 - Christl, Marcus A1 - Ketterer, Mike E. A1 - Egli, Markus T1 - Tracing the temporal evolution of soil redistribution rates in an agricultural landscape using Pu239+240 and Be-10 JF - Earth surface processes and landforms : the journal of the British Geomorphological Research Group N2 - Two principal groups of processes shape mass fluxes from and into a soil: vertical profile development and lateral soil redistribution. Periods having predominantly progressive soil forming processes (soil profile development) alternate with periods having predominantly regressive processes (erosion). As a result, short‐term soil redistribution – years to decades – can differ substantially from long‐term soil redistribution; i.e. centuries to millennia. However, the quantification of these processes is difficult and consequently their rates are poorly understood. To assess the competing roles of erosion and deposition we determined short‐ and long‐term soil redistribution rates in a formerly glaciated area of the Uckermark, northeast Germany. We compared short‐term erosion or accumulation rates using plutonium‐239 and ‐240 (239+240Pu) and long‐term rates using both in situ and meteoric cosmogenic beryllium‐10 (10Be). Three characteristic process domains have been analysed in detail: a flat landscape position having no erosion/deposition, an erosion‐dominated mid‐slope, and a deposition‐dominated lower‐slope site. We show that the short‐term mass erosion and accumulation rates are about one order of magnitude higher than long‐term redistribution rates. Both, in situ and meteoric 10Be provide comparable results. Depth functions, and therefore not only an average value of the topsoil, give the most meaningful rates. The long‐term soil redistribution rates were in the range of −2.1 t ha‐1 yr‐1 (erosion) and +0.26 t ha‐1 yr‐1 (accumulation) whereas the short‐term erosion rates indicated strong erosion of up to 25 t ha‐1 yr‐1 and accumulation of 7.6 t ha‐1 yr‐1. Our multi‐isotope method identifies periods of erosion and deposition, confirming the ‘time‐split approach’ of distinct different phases (progressive/regressive) in soil evolution. With such an approach, temporally‐changing processes can be disentangled, which allows the identification of both the dimensions of and the increase in soil erosion due to human influence KW - soil erosion KW - Be-10 KW - Pu239+240 KW - temporal evolution KW - moraine landscape KW - agricultural soils Y1 - 2019 U6 - https://doi.org/10.1002/esp.4612 SN - 0197-9337 SN - 1096-9837 VL - 44 IS - 9 SP - 1783 EP - 1798 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Gasser, Lucy T1 - Towards Eurasia BT - remapping Europe as ‘upstart peripheral to an ongoing operation’ JF - Postcolonial Studies N2 - In order to heed the call in world literature studies to work against disciplinary Eurocentrism by refiguring both what constitutes world literature and how this is read, in this article I propose world literature as an archive of world-making practices and as an impulse for the articulation of alternative methodological approaches. This takes world literature from the postcolonial South as, following Pheng Cheah, instantiating a modality of world literature in which the need for imagining worlds with alternative centres to those determined by coloniality is particularly acute. A response to this is facilitated and illustrated by a reading of Bengali poet Rabindranath Tagore’s Letters from Russia (1930), and South African writer/activist Alex La Guma’s A Soviet Journey (1978). By drawing forward connections between the postcolonial South and the former Soviet Union, this complicates traditional colonial arrangements of the colonial ‘centre’ as cradle of civilisation and culture, as well as postcolonial scholarship’s cumulative fetishisation of ‘Europe’, by allowing a reshuffling of the co-ordinates determining ‘centres’ and ‘peripheries’ and a more nuanced grasp of ‘Europe’ simultaneously. These imaginative journeys destabilise ‘Europe’ as closed category and call forth Eurasia as a more appropriate categorical–cartographical framework for thinking this space and the connections and (hi)story-telling it stages and fosters. KW - Eurasia KW - Europe KW - Eurocentrism KW - Soviet Union KW - world literature Y1 - 2019 U6 - https://doi.org/10.1080/13688790.2019.1608798 SN - 1368-8790 SN - 1466-1888 VL - 22 IS - 2 SP - 188 EP - 202 PB - Routledge, Taylor & Francis Group CY - Abingdon ER - TY - JOUR A1 - Heger, Tina A1 - Bernard-Verdier, Maud A1 - Gessler, Arthur A1 - Greenwood, Alex D. A1 - Grossart, Hans-Peter A1 - Hilker, Monika A1 - Keinath, Silvia A1 - Kowarik, Ingo A1 - Küffer, Christoph A1 - Marquard, Elisabeth A1 - Mueller, Johannes A1 - Niemeier, Stephanie A1 - Onandia, Gabriela A1 - Petermann, Jana S. A1 - Rillig, Matthias C. A1 - Rodel, Mark-Oliver A1 - Saul, Wolf-Christian A1 - Schittko, Conrad A1 - Tockner, Klement A1 - Joshi, Jasmin Radha A1 - Jeschke, Jonathan M. T1 - Towards an Integrative, Eco-Evolutionary Understanding of Ecological Novelty: Studying and Communicating Interlinked Effects of Global Change JF - Bioscience N2 - Global change has complex eco-evolutionary consequences for organisms and ecosystems, but related concepts (e.g., novel ecosystems) do not cover their full range. Here we propose an umbrella concept of "ecological novelty" comprising (1) a site-specific and (2) an organism-centered, eco-evolutionary perspective. Under this umbrella, complementary options for studying and communicating effects of global change on organisms, ecosystems, and landscapes can be included in a toolbox. This allows researchers to address ecological novelty from different perspectives, e.g., by defining it based on (a) categorical or continuous measures, (b) reference conditions related to sites or organisms, and (c) types of human activities. We suggest striving for a descriptive, non-normative usage of the term "ecological novelty" in science. Normative evaluations and decisions about conservation policies or management are important, but require additional societal processes and engagement with multiple stakeholders. KW - Anthropocene KW - eco-evolutionary experience KW - global change KW - novel ecosystems KW - shifting baselines Y1 - 2019 U6 - https://doi.org/10.1093/biosci/biz095 SN - 0006-3568 SN - 1525-3244 VL - 69 IS - 11 SP - 888 EP - 899 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Bacskai-Atkari, Julia T1 - Towards a Fanselownian analysis of degree expressions JF - Of trees and birds. A Festschrift for Gisbert Fanselow KW - Festschrift KW - Informationsstruktur KW - Linguistik KW - Morphologie KW - Syntax KW - festschrift KW - information structure KW - linguistics KW - morphology KW - syntax Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-432222 SN - 978-3-86956-457-9 SP - 95 EP - 106 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - JOUR A1 - Ma, Xuemin A1 - Balazadeh, Salma A1 - Mueller-Roeber, Bernd T1 - Tomato fruit ripening factor NOR controls leaf senescence JF - Journal of experimental botany N2 - NAC transcription factors (TFs) are important regulators of expressional reprogramming during plant development, stress responses, and leaf senescence. NAC TFs also play important roles in fruit ripening. In tomato (Solanum lycopersicum), one of the best characterized NACs involved in fruit ripening is NON-RIPENING (NOR), and the non-ripening (nor) mutation has been widely used to extend fruit shelf life in elite varieties. Here, we show that NOR additionally controls leaf senescence. Expression of NOR increases with leaf age, and developmental as well as dark-induced senescence are delayed in the nor mutant, while overexpression of NOR promotes leaf senescence. Genes associated with chlorophyll degradation as well as senescence-associated genes (SAGs) show reduced and elevated expression, respectively, in nor mutants and NOR overexpressors. Overexpression of NOR also stimulates leaf senescence in Arabidopsis thaliana. In tomato, NOR supports senescence by directly and positively regulating the expression of several senescence-associated genes including, besides others, SlSAG15 and SlSAG113, SlSGR1, and SlYLS4. Finally, we find that another senescence control NAC TF, namely SlNAP2, acts upstream of NOR to regulate its expression. Our data support a model whereby NAC TFs have often been recruited by higher plants for both the control of leaf senescence and fruit ripening. KW - Aging KW - leaf KW - NAC KW - non-ripening KW - NOR KW - senescence KW - tomato KW - transcription factor Y1 - 2019 U6 - https://doi.org/10.1093/jxb/erz098 SN - 0022-0957 SN - 1460-2431 VL - 70 IS - 10 SP - 2727 EP - 2740 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Olas, Justyna Jadwiga A1 - Wahl, Vanessa T1 - Tissue-specific NIA1 and NIA2 expression in Arabidopsis thaliana JF - Plant Signaling & Behavior N2 - Nitrogen (N) is an essential macronutrient for optimal plant growth and ultimately for crop productivity Nitrate serves as the main N source for most plants. Although it seems a well-established fact that nitrate concentration affects flowering, its molecular mode of action in flowering time regulation was poorly understood. We recently found how nitrate, present at the shoot apical meristem (SAM), controls flowering time In this short communication, we present data on the tissue-specific expression patterns of NITRATE REDUCTASE 1 (NIA1) and NIA2 in planta. We show that transcripts of both genes are present throughout the life cycle of Arabidopsis thaliana plants with NIA1 being predominantly active in leaves and NIA2 in meristematic tissues. KW - Arabidopsis KW - NIA1 KW - NIA2 KW - nitrate assimilation KW - plant development KW - RNA in situ hybridization KW - expression KW - cell KW - and tissue-specificity Y1 - 2019 U6 - https://doi.org/10.1080/15592324.2019.1656035 SN - 1559-2316 SN - 1559-2324 VL - 14 IS - 11 PB - Taylor & Francis Group CY - Philadelphia ER - TY - JOUR A1 - Tchoumba Kwamen, Christelle Larodia A1 - Rössle, Matthias A1 - Leitenberger, Wolfram A1 - Alexe, Marin A1 - Bargheer, Matias T1 - Time-resolved X-ray diffraction study of the structural dynamics in an epitaxial ferroelectric thin Pb(Zr0.2Ti0.8)O-3 film induced by sub-coercive fields JF - Applied physics letters N2 - The electric field-dependence of structural dynamics in a tetragonal ferroelectric lead zirconate titanate thin film is investigated under subcoercive and above-coercive fields using time-resolved X-ray diffraction. The domain nucleation and growth are monitored in real time during the application of an external field to the prepoled thin film capacitor. We propose the observed broadening of the in-plane peak width of the symmetric 002 Bragg reflection as an indicator of the domain disorder and discuss the processes that change the measured peak intensity. Subcoercive field switching results in remnant disordered domain configurations. Published under license by AIP Publishing. Y1 - 2019 U6 - https://doi.org/10.1063/1.5084104 SN - 0003-6951 SN - 1077-3118 VL - 114 IS - 16 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Broeker, Nina K. A1 - Roske, Yvette A1 - Valleriani, Angelo A1 - Stephan, Mareike Sophia A1 - Andres, Dorothee A1 - Koetz, Joachim A1 - Heinemann, Udo A1 - Barbirz, Stefanie T1 - Time-resolved DNA release from an O-antigen-specific Salmonella bacteriophage with a contractile tail JF - The journal of biological chemistry N2 - Myoviruses, bacteriophages with T4-like architecture, must contract their tails prior to DNA release. However, quantitative kinetic data on myovirus particle opening are lacking, although they are promising tools in bacteriophage-based antimicrobial strategies directed against Gram-negative hosts. For the first time, we show time-resolved DNA ejection from a bacteriophage with a contractile tail, the multi-O-antigen-specific Salmonella myovirus Det7. DNA release from Det7 was triggered by lipopolysaccharide (LPS) O-antigen receptors and notably slower than in noncontractile-tailed siphoviruses. Det7 showed two individual kinetic steps for tail contraction and particle opening. Our in vitro studies showed that highly specialized tailspike proteins (TSPs) are necessary to attach the particle to LPS. A P22-like TSP confers specificity for the Salmonella Typhimurium O-antigen. Moreover, crystal structure analysis at 1.63 angstrom resolution confirmed that Det7 recognized the Salmonella Anatum O-antigen via an E15-like TSP, DettilonTSP. DNA ejection triggered by LPS from either host showed similar velocities, so particle opening is thus a process independent of O-antigen composition and the recognizing TSP. In Det7, at permissive temperatures TSPs mediate O-antigen cleavage and couple cell surface binding with DNA ejection, but no irreversible adsorption occurred at low temperatures. This finding was in contrast to short-tailed Salmonella podoviruses, illustrating that tailed phages use common particle-opening mechanisms but have specialized into different infection niches. KW - bacteriophage KW - lipopolysaccharide (YLPS) KW - structural biology KW - DNA viruses KW - glycobiology KW - fluorescence KW - Salmonella enterica KW - contractile tail KW - DNA ejection KW - O-antigen specificity KW - Salmonella myovirus KW - tailspike protein KW - molecular machine Y1 - 2019 U6 - https://doi.org/10.1074/jbc.RA119.008133 SN - 1083-351X VL - 294 IS - 31 SP - 11751 EP - 11761 PB - American Society for Biochemistry and Molecular Biology CY - Bethesda ER - TY - JOUR A1 - Mehrabi, Pedram A1 - Schulz, Eike C. A1 - Dsouza, Raison A1 - Müller-Werkmeister, Henrike A1 - Tellkamp, Friedjof A1 - Miller, R. J. Dwayne A1 - Pai, Emil F. T1 - Time-resolved crystallography reveals allosteric communication aligned with molecular breathing JF - Science N2 - A comprehensive understanding of protein function demands correlating structure and dynamic changes. Using time-resolved serial synchrotron crystallography, we visualized half-of-the-sites reactivity and correlated molecular-breathing motions in the enzyme fluoroacetate dehalogenase. Eighteen time points from 30 milliseconds to 30 seconds cover four turnover cycles of the irreversible reaction. They reveal sequential substrate binding, covalent-intermediate formation, setup of a hydrolytic water molecule, and product release. Small structural changes of the protein mold and variations in the number and placement of water molecules accompany the various chemical steps of catalysis. Triggered by enzyme-ligand interactions, these repetitive changes in the protein framework’s dynamics and entropy constitute crucial components of the catalytic machinery. Y1 - 2019 U6 - https://doi.org/10.1126/science.aaw9904 SN - 0036-8075 SN - 1095-9203 VL - 365 IS - 6458 SP - 1167 EP - 1170 PB - American Assoc. for the Advancement of Science CY - Washington ER - TY - JOUR A1 - Urbach, Tina A1 - Weigelt, Oliver T1 - Time pressure and proactive work behaviour: A week-level study on intraindividual fluctuations and reciprocal relationships JF - Journal of occupational and organizational psychology N2 - Recent research on proactive work behaviours (PWBs) pointed out that these behaviours can have negative consequences for the proactive individual. We add to this perspective by showing that PWBs may be a source of strain at work and result in elevated time pressure. Challenging the view of time pressure as a challenge stressor, we hypothesize that over the course of work weeks, time pressure will result in less (rather than more) PWB. We investigate these reciprocal effects as within-person, week-level fluctuations of time pressure and PWB based on experience sampling data (N = 52 participants, k = 274 observations). Over the course of three consecutive work weeks, results show a positive lagged effect of PWB in the first week on experiencing time pressure in the second week; in turn, time pressure in the second week had a negative lagged effect on PWB in the third week. Results further suggest that PWB is lowest in work weeks of low time pressure when following a week of high time pressure, indicating a conservation of resources interpretation of the results. KW - cross-lagged effects KW - experience sampling method KW - proactive work behaviour KW - stress KW - time pressure KW - week-level study Y1 - 2019 U6 - https://doi.org/10.1111/joop.12269 SN - 0963-1798 SN - 2044-8325 VL - 92 IS - 4 SP - 931 EP - 952 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Tang, Jing A1 - Werchmeister, Rebecka Maria Larsen A1 - Preda, Loredana A1 - Huang, Wei A1 - Zheng, Zhiyong A1 - Leimkühler, Silke A1 - Wollenberger, Ulla A1 - Xiao, Xinxin A1 - Engelbrekt, Christian A1 - Ulstrup, Jens A1 - Zhang, Jingdong T1 - Three-dimensional sulfite oxidase bioanodes based on graphene functionalized carbon paper for sulfite/O-2 biofuel cells JF - ACS catalysis N2 - We have developed a three-dimensional (3D) graphene electrode suitable for the immobilization of human sulfite oxidase (hSO), which catalyzes the electrochemical oxidation of sulfite via direct electron transfer (DET). The electrode is fabricated by drop-casting graphene-polyethylenimine (G-P) composites on carbon papers (CPs) precoated with graphene oxide (GO). The negatively charged hSO can be adsorbed electrostatically on the positively charged matrix (G-P) on CP electrodes coated with GO (CPG), with a proper orientation for accelerated DET. Notably, further electrochemical reduction of G-P on CPG electrodes leads to a 9-fold increase of the saturation catalytic current density (j(m)) for sulfite oxidation reaching 24.4 +/- 0.3 mu A to cm(-2), the highest value among reported DET-based hSO bioelectrodes. The increased electron transfer rate plays a dominating role in the enhancement of direct enzymatic current because of the improved electric contact of hSO with the electrode, The optimized hSO bioelectrode shows a significant catalytic rate (k(cat): 25.6 +/- 0.3 s(-1)) and efficiency (k(cat)/K-m: 0.231 +/- 0.003 s(-1) mu M-1) compared to the reported hSO bioelectrodes. The assembly of the hSO bioanode and a commercial platinum biocathode allows the construction of sulfite/O-2 enzymatic biofuel cells (EBFCs) with flowing fuels. The optimized EBFC displays an open-circuit voltage (OCV) of 0.64 +/- 0.01 V and a maximum power density of 61 +/- 6 mu W cm(-2) (122 +/- 12 mW m(-3)) at 30 degrees C, which exceeds the best reported value by more than 6 times. KW - enzymatic biofuel cell KW - reduced graphene oxide KW - sulfite oxidase KW - carbon paper KW - direct electron transfer Y1 - 2019 U6 - https://doi.org/10.1021/acscatal.9b01715 SN - 2155-5435 VL - 9 IS - 7 SP - 6543 EP - 6554 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Werchmeister, Rebecka Maria Larsen A1 - Tang, Jing A1 - Xiao, Xinxin A1 - Wollenberger, Ulla A1 - Hjuler, Hans Aage A1 - Ulstrup, Jens A1 - Zhang, Jingdong T1 - Three-Dimensional Bioelectrodes Utilizing Graphene Based Bioink JF - Journal of The Electrochemical Society N2 - Enzyme immobilization using nanomaterials offers new approaches to enhanced bioelectrochemical performance and is essential for the preparation of bioelectrodes with high reproducibility and low cost. In this report, we describe the development of new three-dimensional (3D) bioelectrodes by immobilizing a "bioink" of glucose oxidase (GOD) in a matrix of reduced graphene oxides (RGOs), polyethylenimine (PEI), and ferrocene carboxylic acid (FcCOOH) on carbon paper (CP). CP with 3D interwoven carbon fibers serves as a solid porous and electronically conducting skeleton, providing large surface areas and space for loading the bioink and diffusion of substrate molecules, respectively. RGO enhances contact between the GOD-matrix and CP, maintaining high conductivity. The composition of the bioink has been systematically optimized. The GOD bioelectrodes show linearly increasing electrocatalytic oxidation current toward glucose concentration up to 48 mM. A hybrid enzymatic biofuel cell equipped with the GOD bioelectrode as a bioanode and a platinum cathode furthermore registers a maximum power density of 5.1 mu W cm(-2) and an open circuit voltage of 0.40 V at 25 degrees C. The new method reported of preparing a bioelectrode by drop-casting the bioink onto the substrate electrode is facile and versatile, with the potential of application also for other enzymatic bioelectrodes. Y1 - 2019 U6 - https://doi.org/10.1149/2.0261916jes SN - 0013-4651 SN - 1945-7111 VL - 166 IS - 16 SP - G170 EP - G177 PB - The Electrochemical Society CY - Pennington ER - TY - JOUR A1 - Pilz, Sonja K. T1 - Three Strange Spaces: An Ethnographic Study in the Construction of Contemporary Jewish Sacred Spaces JF - Liturgy Y1 - 2019 U6 - https://doi.org/10.1080/0458063X.2019.1679580 SN - 0458-063X SN - 1557-3001 VL - 34 IS - 4 SP - 26 EP - 43 PB - Taylor & Francis Group CY - Philadelphia ER - TY - JOUR A1 - Folikumah, Makafui Yao A1 - Neffe, Axel T. A1 - Behl, Marc A1 - Lendlein, Andreas T1 - Thiol Michael-Type reactions of optically active mercapto-acids in aqueous medium JF - MRS advances : a journal of the Materials Research Society N2 - Defined chemical reactions in a physiological environment are a prerequisite for the in situ synthesis of implant materials potentially serving as matrix for drug delivery systems, tissue fillers or surgical glues. ‘Click’ reactions like thiol Michael-type reactions have been successfully employed as bioorthogonal reaction. However, due to the individual stereo-electronic and physical properties of specific substrates, an exact understanding their chemical reactivity is required if they are to be used for in-situ biomaterial synthesis. The chiral (S)-2-mercapto-carboxylic acid analogues of L-phenylalanine (SH-Phe) and L-leucine (SH-Leu) which are subunits of certain collagenase sensitive synthetic peptides, were explored for their potential for in-situ biomaterial formation via the thiol Michael-type reaction. In model reactions were investigated the kinetics, the specificity and influence of stereochemistry of this reaction. We could show that only reactions involving SH-Leu yielded the expected thiol-Michael product. The inability of SH-Phe to react was attributed to the steric hindrance of the bulky phenyl group. In aqueous media, successful reaction using SH-Leu is thought to proceed via the sodium salt formed in-situ by the addition of NaOH solution, which was intented to aid the solubility of the mercapto-acid in water. Fast reaction rates and complete acrylate/maleimide conversion were only realized at pH 7.2 or higher suggesting the possible use of SH-Leu under physiological conditions for thiol Michael-type reactions. This method of in-situ formed alkali salts could be used as a fast approach to screen mercapto-acids for thio Michael-type reactions without the synthesis of their corresponding esters. KW - biomaterial KW - biomedical KW - biomimetic (chemical reaction) KW - chemical synthesis Y1 - 2019 U6 - https://doi.org/10.1557/adv.2019.308 SN - 2059-8521 VL - 4 IS - 46-47 SP - 2515 EP - 2525 PB - Springer Nature Switzerland AG CY - Cham ER - TY - JOUR A1 - Walkowiak, Jacek A1 - Lu, Yan A1 - Gradzielski, Michael A1 - Zauscher, Stefan A1 - Ballauff, Matthias T1 - Thermodynamic analysis of the uptake of a protein in a spherical polyelectrolyte brush JF - Macromolecular rapid communications N2 - A thermodynamic study of the adsorption of Human Serum Albumin (HSA) onto spherical polyelectrolyte brushes (SPBs) by isothermal titration calorimetry (ITC) is presented. The SPBs are composed of a solid polystyrene core bearing long chains of poly(acrylic acid). ITC measurements done at different temperatures and ionic strengths lead to a full set of thermodynamicbinding constants together with the enthalpies and entropies of binding. The adsorption of HSA onto SPBs is described with a two-step model. The free energy of binding Delta Gb depends only weakly on temperature because of a marked compensation of enthalpy by entropy. Studies of the adsorbed HSA by Fourier transform infrared spectroscopy (FT-IR) demonstrate no significant disturbance in the secondary structure of the protein. The quantitative analysis demonstrates that counterion release is the major driving force for adsorption in a process where proteins become multivalent counterions of the polyelectrolyte chains upon adsorption. A comparison with the analysis of other sets of data related to the binding of HSA to polyelectrolytes demonstrates that the cancellation of enthalpy and entropy is a general phenomenon that always accompanies the binding of proteins to polyelectrolytes dominated by counterion release. KW - Spherical polyelectrolyte brushes KW - proteins KW - ITC KW - thermodynamics KW - enthalpy-entropy compensation (EEC) Y1 - 2019 U6 - https://doi.org/10.1002/marc.201900421 SN - 1022-1336 SN - 1521-3927 VL - 41 IS - 1 PB - Wiley-VCH CY - Weinheim ER -