TY - JOUR A1 - Corti, Giacomo A1 - Cioni, Raffaello A1 - Franceschini, Zara A1 - Sani, Federico A1 - Scaillet, Stephane A1 - Molin, Paola A1 - Isola, Ilaria A1 - Mazzarini, Francesco A1 - Brune, Sascha A1 - Keir, Derek A1 - Erbello Doelesso, Asfaw A1 - Muluneh, Ameha A1 - Illsley-Kemp, Finnigan A1 - Glerum, Anne T1 - Aborted propagation of the Ethiopian rift caused by linkage with the Kenyan rift JF - Nature Communications N2 - Continental rift systems form by propagation of isolated rift segments that interact, and eventually evolve into continuous zones of deformation. This process impacts many aspects of rifting including rift morphology at breakup, and eventual ocean-ridge segmentation. Yet, rift segment growth and interaction remain enigmatic. Here we present geological data from the poorly documented Ririba rift (South Ethiopia) that reveals how two major sectors of the East African rift, the Kenyan and Ethiopian rifts, interact. We show that the Ririba rift formed from the southward propagation of the Ethiopian rift during the Pliocene but this propagation was short-lived and aborted close to the Pliocene-Pleistocene boundary. Seismicity data support the abandonment of laterally offset, overlapping tips of the Ethiopian and Kenyan rifts. Integration with new numerical models indicates that rift abandonment resulted from progressive focusing of the tectonic and magmatic activity into an oblique, throughgoing rift zone of near pure extension directly connecting the rift sectors. Y1 - 2019 U6 - https://doi.org/10.1038/s41467-019-09335-2 SN - 2041-1723 VL - 10 PB - Nature Publ. Group CY - London ER - TY - JOUR A1 - Didovets, Iulii A1 - Krysanova, Valentina A1 - Bürger, Gerd A1 - Snizhko, Sergiy A1 - Balabukh, Vira A1 - Bronstert, Axel T1 - Climate change impact on regional floods in the Carpathian region JF - Journal of hydrology : Regional studies N2 - Study region: Tisza and Prut catchments, originating on the slopes of the Carpathian mountains. Study focus: The study reported here investigates (i) climate change impacts on flood risk in the region, and (ii) uncertainty related to hydrological modelling, downscaling techniques and climate projections. The climate projections used in the study were derived from five GCMs, downscaled either dynamically with RCMs or with the statistical downscaling model XDS. The resulting climate change scenarios were applied to drive the eco-hydrological model SWIM, which was calibrated and validated for the catchments in advance using observed climate and hydrological data. The changes in the 30-year flood hazards and 98 and 95 percentiles of discharge were evaluated for the far future period (2071-2100) in comparison with the reference period (1981-2010). New hydrological insights for the region: The majority of model outputs under RCP 4.5 show a small to strong increase of the 30-year flood level in the Tisza ranging from 4.5% to 62%, and moderate increase in the Prut ranging from 11% to 22%. The impact results under RCP 8.5 are more uncertain with changes in both directions due to high uncertainties in GCM-RCM climate projections, downscaling methods and the low density of available climate stations. KW - Climate change impact KW - Floods KW - Hydrological modelling KW - SWIM KW - Tisza KW - Prut KW - Carpathians KW - Ukraine Y1 - 2019 U6 - https://doi.org/10.1016/j.ejrh.2019.01.002 SN - 2214-5818 VL - 22 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Erdal, Daniel A1 - Baroni, Gabriele A1 - Sánchez León, Eduardo Emilio A1 - Cirpka, Olaf A. T1 - The value of simplified models for spin up of complex models with an application to subsurface hydrology JF - Computers & geosciences : an international journal devoted to the publication of papers on all aspects of geocomputation and to the distribution of computer programs and test data sets ; an official journal of the International Association for Mathematical Geology N2 - Spinning up large-scale coupled surface-subsurface numerical models can be a time and resource consuming task. If an uninformed initial condition is chosen, the spin-up can easily require 20 years of repeated simulations on high-performance computing machines. In this paper we compare the classical approach of starting from a fixed shallow depth to groundwater (here 3 m) with three more informed approaches for the definition of initial conditions in the spin up. In the first of these three approaches, we start from a known-steady state groundwater table, calculated with a 2-D groundwater model and the yearly net recharge, and combine it with an unsaturated zone that assumes hydrostatic conditions. In the second approach, we start from the same groundwater table combined with vertical profiles in the unsaturated zone with uniform vertical flow identical to the groundwater recharge. In the third approach we calculate a dynamic steady state from a simplified subsurface model combining a transient 2-D groundwater model with a limited number of 1-D transient unsaturated zone columns on top. Results for spinning-up a 3-D Parflow-CLM model using the different initial conditions show that large gains can be made by considering states in groundwater and the vadose zone that are consistent, i.e. where groundwater recharge and the vertical flux in the vadose zone agree. By this, the spin-up time was reduced from about 10 years to about 3 years of simulated time. In the light of seasonal fluctuations of net recharge, using the transient approach showed more stable results. KW - Model spin-up KW - Groundwater-model KW - Unsaturated zone KW - 2.5-D model KW - Computation time Y1 - 2019 U6 - https://doi.org/10.1016/j.cageo.2019.01.014 SN - 0098-3004 SN - 1873-7803 VL - 126 SP - 62 EP - 72 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Fairey, Brenton J. A1 - Timmerman, Martin Jan A1 - Sudo, Masafumi A1 - Tsikos, Harilaos T1 - The role of hydrothermal activity in the formation of Karst-hosted manganese deposits of the Postmasburg Mn Field, Northern Cape Province, South Africa JF - Minerals N2 - The Postmasburg Manganese Field (PMF), Northern Cape Province, South Africa, once represented one of the largest sources of manganese ore worldwide. Two belts of manganese ore deposits have been distinguished in the PMF, namely the Western Belt of ferruginous manganese ores and the Eastern Belt of siliceous manganese ores. Prevailing models of ore formation in these two belts invoke karstification of manganese-rich dolomites and residual accumulation of manganese wad which later underwent diagenetic and low-grade metamorphic processes. For the most part, the role of hydrothermal processes and metasomatic alteration towards ore formation has not been adequately discussed. Here we report an abundance of common and some rare Al-, Na-, K- and Ba-bearing minerals, particularly aegirine, albite, microcline, banalsite, serandite-pectolite, paragonite and natrolite in Mn ores of the PMF, indicative of hydrothermal influence. Enrichments in Na, K and/or Ba in the ores are generally on a percentage level for most samples analysed through bulk-rock techniques. The presence of As-rich tokyoite also suggests the presence of As and V in the hydrothermal fluid. The fluid was likely oxidized and alkaline in nature, akin to a mature basinal brine. Various replacement textures, particularly of Na- and K- rich minerals by Ba-bearing phases, suggest sequential deposition of gangue as well as ore-minerals from the hydrothermal fluid, with Ba phases being deposited at a later stage. The stratigraphic variability of the studied ores and their deviation from the strict classification of ferruginous and siliceous ores in the literature, suggests that a re-evaluation of genetic models is warranted. New Ar-Ar ages for K-feldspars suggest a late Neoproterozoic timing for hydrothermal activity. This corroborates previous geochronological evidence for regional hydrothermal activity that affected Mn ores at the PMF but also, possibly, the high-grade Mn ores of the Kalahari Manganese Field to the north. A revised, all-encompassing model for the development of the manganese deposits of the PMF is then proposed, whereby the source of metals is attributed to underlying carbonate rocks beyond the Reivilo Formation of the Campbellrand Subgroup. The main process by which metals are primarily accumulated is attributed to karstification of the dolomitic substrate. The overlying Asbestos Hills Subgroup banded iron formation (BIF) is suggested as a potential source of alkali metals, which also provides a mechanism for leaching of these BIFs to form high-grade residual iron ore deposits. KW - manganese ore KW - Postmasburg manganese field KW - hydrothermal KW - karst KW - South Africa Y1 - 2019 U6 - https://doi.org/10.3390/min9070408 SN - 2075-163X VL - 9 IS - 7 PB - MDPI CY - Basel ER - TY - JOUR A1 - Fohlmeister, Jens Bernd A1 - Lechleitner, Franziska A. T1 - STAlagmite dating by radiocarbon (star) BT - a software tool for reliable and fast age depth modelling JF - Quaternary geochronology : the international research and review journal on advances in quaternary dating techniques N2 - Speleothems, secondary cave carbonates, are important tools for climate reconstruction, especially as they often can be very precisely dated with the UTh method. If the U-Th method fails, dating becomes difficult, and often results in abandonment of samples and study sites. Radiocarbon dating is the only other radiometric dating technique applicable to the last similar to 50 ka, but presents complexities related to temporal variability of the reservoir effect in speleothems. Thus, radiocarbon dating of speleothems is not straightforward, and there are currently no publicly available tools to define proper age-depth relationships with this method. Here, we present an improved version of a previously published radiocarbon based age-depth modelling approach (star, Lechleitner et al., 2016b), which is now made freely available. The software is easy to use and provides the possibility to obtain reliable age-depth relationships, without prior knowledge of reservoir effects and their variability. In addition, star is able to detect and handle growth stops and phases with different growth rates. We test star on artificially constructed data sets and illustrate steps to improve the model performance. Furthermore, we apply the new approach to published radiocarbon data of U-Th dated stalagmites. This offers the possibility to investigate the strengths and weaknesses of the new approach with respect to potentially significant long term trends in the radiocarbon reservoir effect, which might otherwise remain undetected. In summary, we have produced a valuable software, which easily enables to construct age-depth relationships on the basis of reservoir effect disturbed radiocarbon measurements. Y1 - 2019 U6 - https://doi.org/10.1016/j.quageo.2019.02.008 SN - 1871-1014 SN - 1878-0350 VL - 51 SP - 120 EP - 129 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Foster, William J. A1 - Heindel, Katrin A1 - Richoz, Sylvain A1 - Gliwa, Jana A1 - Lehrmann, Daniel J. A1 - Baud, Aymon A1 - Kolar-Jurkovsek, Tea A1 - Aljinovic, Dunja A1 - Jurkovsek, Bogdan A1 - Korn, Dieter A1 - Martindale, Rowan C. A1 - Peckmann, Jörn T1 - Suppressed competitive exclusion enabled the proliferation of Permian/Triassic boundary microbialites JF - The Depositional Record : the open access journal of the International Association of Sedimentologists N2 - During the earliest Triassic microbial mats flourished in the photic zones of marginal seas, generating widespread microbialites. It has been suggested that anoxic conditions in shallow marine environments, linked to the end-Permian mass extinction, limited mat-inhibiting metazoans allowing for this microbialite expansion. The presence of a diverse suite of proxies indicating oxygenated shallow sea-water conditions (metazoan fossils, biomarkers and redox proxies) from microbialite successions have, however, challenged the inference of anoxic conditions. Here, the distribution and faunal composition of Griesbachian microbialites from China, Iran, Turkey, Armenia, Slovenia and Hungary are investigated to determine the factors that allowed microbialite-forming microbial mats to flourish following the end-Permian crisis. The results presented here show that Neotethyan microbial buildups record a unique faunal association due to the presence of keratose sponges, while the Palaeotethyan buildups have a higher proportion of molluscs and the foraminifera Earlandia. The distribution of the faunal components within the microbial fabrics suggests that, except for the keratose sponges and some microconchids, most of the metazoans were transported into the microbial framework via wave currents. The presence of both microbialites and metazoan associations were limited to oxygenated settings, suggesting that a factor other than anoxia resulted in a relaxation of ecological constraints following the mass extinction event. It is inferred that the end-Permian mass extinction event decreased the diversity and abundance of metazoans to the point of significantly reducing competition, allowing photosynthesis-based microbial mats to flourish in shallow water settings and resulting in the formation of widespread microbialites. KW - Competitive exclusion KW - Permian KW - Triassic KW - mass extinction KW - microbialites KW - palaeoecology Y1 - 2019 U6 - https://doi.org/10.1002/dep2.97 SN - 2055-4877 VL - 6 IS - 1 SP - 62 EP - 74 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Freymark, Jessica A1 - Bott, Judith A1 - Cacace, Mauro A1 - Ziegler, Moritz 0. A1 - Scheck-Wenderoth, Magdalena T1 - Influence of the Main Border Faults on the 3D Hydraulic Field of the Central Upper Rhine Graben JF - Geofluids N2 - The Upper Rhine Graben (URG) is an active rift with a high geothermal potential. Despite being a well-studied area, the three-dimensional interaction of the main controlling factors of the thermal and hydraulic regime is still not fully understood. Therefore, we have used a data-based 3D structural model of the lithological configuration of the central URG for some conceptual numerical experiments of 3D coupled simulations of fluid and heat transport. To assess the influence of the main faults bordering the graben on the hydraulic and the deep thermal field, we carried out a sensitivity analysis on fault width and permeability. Depending on the assigned width and permeability of the main border faults, fluid velocity and temperatures are affected only in the direct proximity of the respective border faults. Hence, the hydraulic characteristics of these major faults do not significantly influence the graben-wide groundwater flow patterns. Instead, the different scenarios tested provide a consistent image of the main characteristics of fluid and heat transport as they have in common: (1) a topography-driven basin-wide fluid flow perpendicular to the rift axis from the graben shoulders to the rift center, (2) a N/NE-directed flow parallel to the rift axis in the center of the rift and, (3) a pronounced upflow of hot fluids along the rift central axis, where the streams from both sides of the rift merge. This upflow axis is predicted to occur predominantly in the center of the URG (northern and southern model area) and shifted towards the eastern boundary fault (central model area). Y1 - 2019 U6 - https://doi.org/10.1155/2019/7520714 SN - 1468-8115 SN - 1468-8123 PB - Wiley-Hindawi CY - London ER - TY - JOUR A1 - Georgieva, Viktoria A1 - Gallagher, Kerry A1 - Sobczyk, Artur A1 - Sobel, Edward A1 - Schildgen, Taylor F. A1 - Ehlers, Todd A1 - Strecker, Manfred T1 - Effects of slab-window, alkaline volcanism, and glaciation on thermochronometer cooling histories, Patagonian Andes JF - Earth & planetary science letters N2 - Southern Patagonia is a prime example of ongoing oceanic ridge collision and slab-window formation sustained over several million years. The impact of these phenomena on the thermal structure and exhumation of the crust have been mainly assessed with low-temperature thermochronology of bedrock samples. Here, we infer thermal histories from new and existing thermochronological data from the region of most recent ridge collision. In particular, we evaluate the potential far-reaching thermal effects of the evolving slab window, which have previously been considered responsible for patterns of late Miocene reheating associated with back-arc alkaline volcanism. Our model results define protracted cooling since similar to 15 Ma and stepwise exhumation since the late Miocene. The pattern of stepwise exhumation closely matches the onset of Patagonian glaciation at 7 Ma and the successive pulse of glacial incision coeval with neotectonic activity since 3-4 Ma that are also documented by independent geological and geomorphological evidence in the region. Importantly, our findings challenge the recently suggested lack of glacial erosion and incision since 5 Ma in this region. Furthermore, in contrast to previous modelling studies, we find that the available data do not evidence a previously proposed northward-propagating heating event associated with alkaline volcanism. We hypothesize that the anomalous alkaline volcanism in the Patagonian back-arc might be related to trench-orthogonal tears aligned with transform faults in the subducting plate. The substantial differences from the previous modelling procedure on some of the same samples is demonstrated to result from an important lack of convergence in model runs. (C) 2019 Elsevier B.V. All rights reserved. KW - inverse thermal modelling KW - thermochronology KW - apatite (U-Th)/He KW - apatite fission track KW - Patagonian Andes KW - slab window Y1 - 2019 U6 - https://doi.org/10.1016/j.epsl.2019.01.030 SN - 0012-821X SN - 1385-013X VL - 511 SP - 164 EP - 176 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Gomez-Garcia, Angela Maria A1 - Meeßen, Christian A1 - Scheck-Wenderoth, Magdalena A1 - Monsalve, Gaspar A1 - Bott, Judith A1 - Bernhardt, Anne A1 - Bernal, Gladys T1 - 3-D Modeling of Vertical Gravity Gradients and the Delimitation of Tectonic Boundaries: The Caribbean Oceanic Domain as a Case Study JF - Geochemistry, geophysics, geosystems N2 - Geophysical data acquisition in oceanic domains is challenging, implying measurements with low and/or nonhomogeneous spatial resolution. The evolution of satellite gravimetry and altimetry techniques allows testing 3-D density models of the lithosphere, taking advantage of the high spatial resolution and homogeneous coverage of satellites. However, it is not trivial to discretise the source of the gravity field at different depths. Here, we propose a new method for inferring tectonic boundaries at the crustal level. As a novelty, instead of modeling the gravity anomalies and assuming a flat Earth approximation, we model the vertical gravity gradients (VGG) in spherical coordinates, which are especially sensitive to density contrasts in the upper layers of the Earth. To validate the methodology, the complex oceanic domain of the Caribbean region is studied, which includes different crustal domains with a tectonic history since Late Jurassic time. After defining a lithospheric starting model constrained by up-to-date geophysical data sets, we tested several a-priory density distributions and selected the model with the minimum misfits with respect to the VGG calculated from the EIGEN-6C4 data set. Additionally, the density of the crystalline crust was inferred by inverting the VGG field. Our methodology enabled us not only to refine, confirm, and/or propose tectonic boundaries in the study area but also to identify a new anomalous buoyant body, located in the South Lesser Antilles subduction zone, and high-density bodies along the Greater, Lesser, and Leeward Antilles forearcs. KW - Vertical Gravity Gradients KW - Gravity modelling KW - Crustal structure KW - Caribbean KW - Tectonic boundaries KW - 3D lithospheric model Y1 - 2019 U6 - https://doi.org/10.1029/2019GC008340 SN - 1525-2027 VL - 20 IS - 11 SP - 5371 EP - 5393 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Haber-Pohlmeier, Sabina A1 - Tötzke, Christian A1 - Lehmann, E. A1 - Kardjilov, Nikolay A1 - Pohlmeier, A. A1 - Oswald, Sascha T1 - Combination of magnetic resonance imaging and neutron computed tomography for three-dimensional rhizosphere imaging JF - Vadose zone journal N2 - Core Ideas 3D MRI relaxation time maps reflect water mobility in root, rhizosphere, and soil. 3D NCT water content maps of the same plant complement relaxation time maps. The relaxation time T1 decreases from soil to root, whereas water content increases. Parameters together indicate modification of rhizosphere pore space by gel phase. The zone of reduced T1 corresponds to the zone remaining dry after rewetting. In situ investigations of the rhizosphere require high‐resolution imaging techniques, which allow a look into the optically opaque soil compartment. We present the novel combination of magnetic resonance imaging (MRI) and neutron computed tomography (NCT) to achieve synergistic information such as water mobility in terms of three‐dimensional (3D) relaxation time maps and total water content maps. Besides a stationary MRI scanner for relaxation time mapping, we used a transportable MRI system on site in the NCT facility to capture rhizosphere properties before desiccation and after subsequent rewetting. First, we addressed two questions using water‐filled test capillaries between 0.1 and 5 mm: which root diameters can still be detected by both methods, and to what extent are defined interfaces blurred by these imaging techniques? Going to real root system architecture, we demonstrated the sensitivity of the transportable MRI device by co‐registration with NCT and additional validation using X‐ray computed tomography. Under saturated conditions, we observed for the rhizosphere in situ a zone with shorter T1 relaxation time across a distance of about 1 mm that was not caused by reduced water content, as proven by successive NCT measurements. We conclude that the effective pore size in the pore network had changed, induced by a gel phase. After rewetting, NCT images showed a dry zone persisting while the MRI intensity inside the root increased considerably, indicating water uptake from the surrounding bulk soil through the still hydrophobic rhizosphere. Overall, combining NCT and MRI allows a more detailed analysis of the rhizosphere's functioning. Y1 - 2019 U6 - https://doi.org/10.2136/vzj2018.09.0166 SN - 1539-1663 VL - 18 IS - 1 PB - Soil Science Society of America CY - Madison ER -