TY - GEN A1 - Steeples, Elliot A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Esposito, Davide T1 - Amino acid-derived N-heterocyclic carbene palladium complexes for aqueous phase Suzuki–Miyaura couplings N2 - In this work, three ligands produced from amino acids were synthesized and used to produce five bis- and PEPPSI-type palladium–NHC complexes using a novel synthesis route from sustainable starting materials. Three of these complexes were used as precatalysts in the aqueous-phase Suzuki–Miyaura coupling of various substrates displaying high activity. TEM and mercury poisoning experiments provide evidence for Pd-nanoparticle formation stabilized in water. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 319 KW - transition-metal-complexes KW - imidazolium salts KW - green chemistry KW - water KW - catalysts KW - nhc KW - hydrogenation KW - isomerization KW - nanoparticles KW - precatalysts Y1 - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-394488 SP - 4922 EP - 4930 ER -