TY - GEN A1 - Emberson, Robert A1 - Hovius, Niels A1 - Galy, Albert A1 - Marc, Odin T1 - Oxidation of sulfides and rapid weathering in recent landslides T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Linking together the processes of rapid physical erosion and the resultant chemical dissolution of rock is a crucial step in building an overall deterministic understanding of weathering in mountain belts. Landslides, which are the most volumetrically important geomorphic process at these high rates of erosion, can generate extremely high rates of very localised weathering. To elucidate how this process works we have taken advantage of uniquely intense landsliding, resulting from Typhoon Morakot, in the T'aimali River and surrounds in southern Taiwan. Combining detailed analysis of landslide seepage chemistry with estimates of catchment-by-catchment landslide volumes, we demonstrate that in this setting the primary role of landslides is to introduce fresh, highly labile mineral phases into the surface weathering environment. There, rapid weathering is driven by the oxidation of pyrite and the resultant sulfuric-acid-driven dissolution of primarily carbonate rock. The total dissolved load correlates well with dissolved sulfate - the chief product of this style of weathering - in both landslides and streams draining the area (R-2 = 0.841 and 0.929 respectively; p < 0.001 in both cases), with solute chemistry in seepage from landslides and catchments affected by significant landsliding governed by the same weathering reactions. The predominance of coupled carbonate-sulfuric-acid-driven weathering is the key difference between these sites and previously studied landslides in New Zealand (Emberson et al., 2016), but in both settings increasing volumes of landslides drive greater overall solute concentrations in streams. Bedrock landslides, by excavating deep below saprolite-rock interfaces, create conditions for weathering in which all mineral phases in a lithology are initially unweathered within landslide deposits. As a result, the most labile phases dominate the weathering immediately after mobilisation and during a transient period of depletion. This mode of dissolution can strongly alter the overall output of solutes from catchments and their contribution to global chemical cycles if landslide-derived material is retained in catchments for extended periods after mass wasting. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 553 KW - physical erosion KW - Mountain Belt KW - Southwestern Taiwan KW - athmospheric CO2 KW - New-Zealand KW - climatic controls KW - Himalayan Rivers KW - Southern Alps KW - carbon-cycle KW - model Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-412326 SN - 1866-8372 IS - 553 ER - TY - JOUR A1 - Emberson, Robert A1 - Hovius, Niels A1 - Galy, Albert A1 - Marc, Odin T1 - Oxidation of sulfides and rapid weathering in recent landslides JF - Earth surface dynamics N2 - Bedrock landslides, by excavating deep below saprolite-rock interfaces, create conditions for weathering in which all mineral phases in a lithology are initially unweathered within landslide deposits. As a result, the most labile phases dominate the weathering immediately after mobilisation and during a transient period of depletion. This mode of dissolution can strongly alter the overall output of solutes from catchments and their contribution to global chemical cycles if landslide-derived material is retained in catchments for extended periods after mass wasting. Y1 - 2016 U6 - https://doi.org/10.5194/esurf-4-727-2016 SN - 2196-6311 SN - 2196-632X VL - 4 SP - 727 EP - 742 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Emberson, Robert A1 - Hovius, Niels A1 - Galy, Albert A1 - Marc, Odin T1 - Chemical weathering in active mountain belts controlled by stochastic bedrock landsliding JF - Nature geoscience N2 - A link between chemical weathering and physical erosion exists at the catchment scale over a wide range of erosion rates(1,2). However, in mountain environments, where erosion rates are highest, weathering may be kinetically limited(3-5) and therefore decoupled from erosion. In active mountain belts, erosion is driven by bedrock landsliding(6) at rates that depend strongly on the occurrence of extreme rainfall or seismicity(7). Although landslides affect only a small proportion of the landscape, bedrock landsliding can promote the collection and slow percolation of surface runoff in highly fragmented rock debris and create favourable conditions for weathering. Here we show from analysis of surface water chemistry in the Southern Alps of New Zealand that weathering in bedrock landslides controls the variability in solute load of these mountain rivers. We find that systematic patterns in surface water chemistry are strongly associated with landslide occurrence at scales from a single hillslope to an entire mountain belt, and that landslides boost weathering rates and river solute loads over decades. We conclude that landslides couple erosion and weathering in fast-eroding uplands and, thus, mountain weathering is a stochastic process that is sensitive to climatic and tectonic controls on mass wasting processes. Y1 - 2016 U6 - https://doi.org/10.1038/NGEO2600 SN - 1752-0894 SN - 1752-0908 VL - 9 SP - 42 EP - + PB - Nature Publ. Group CY - New York ER - TY - THES A1 - Emberson, Robert T1 - Chemical weathering driven by bedrock landslides Y1 - 2016 ER -