TY - JOUR A1 - Garcin, Yannick A1 - Schwab, Valerie F. A1 - Gleixner, Gerd A1 - Kahmen, Ansgar A1 - Todou, Gilbert A1 - Sene, Olivier A1 - Onana, Jean-Michel A1 - Achoundong, Gaston A1 - Sachse, Dirk T1 - Hydrogen isotope ratios of lacustrine sedimentary n-alkanes as proxies of tropical African hydrology insights from a calibration transect across Cameroon JF - Geochimica et cosmochimica acta : journal of the Geochemical Society and the Meteoritical Society N2 - Hydrogen isotope values (delta D) of sedimentary aquatic and terrestrial lipid biomarkers, originating from algae, bacteria, and leaf wax, have been used to record isotopic properties of ancient source water (i.e., precipitation and/or lake water) in several mid-and high-latitude lacustrine environments. In the tropics, however, where both processes associated with isotope fractionation in the hydrologic system and vegetation strongly differ from those at higher latitudes, calibration studies for this proxy are not yet available. To close this gap of knowledge, we sampled surface sediments from 11 lakes in Cameroon to identify those hydro-climatological processes and physiological factors that determine the hydrogen isotopic composition of aquatic and terrestrial lipid biomarkers. Here we present a robust framework for the application of compound-specific hydrogen isotopes in tropical Africa. Our results show that the delta D values of the aquatic lipid biomarker n-C(17) alkane were not correlated with the delta D values of lake water. Carbon isotope measurements indicate that the n-C(17) alkane was derived from multiple source organisms that used different hydrogen pools for biosynthesis. We demonstrate that the delta D values of the n-C(29) alkane were correlated with the delta D values of surface water (i.e., river water and groundwater), which, on large spatial scales, reflect the isotopic composition of mean annual precipitation. Such a relationship has been observed at higher latitudes, supporting the robustness of the leaf-wax lipid delta D proxy on a hemispheric spatial scale. In contrast, the delta D values of the n-C(31) alkane did not show such a relationship but instead were correlated with the evaporative lake water delta D values. This result suggests distinct water sources for both leaf-wax lipids, most likely originating from two different groups of plants. These new findings have important implications for the interpretation of long-chain n-alkane delta D records from ancient lake sediments. In particular, a robust interpretation of palaeohydrological data requires knowledge of the vegetation in the catchment area as different plants may utilise different water sources. Our results also suggest that the combination of carbon and hydrogen isotopes does help to differentiate between the metabolic pathway and/or growth form of organisms and therefore, the source of hydrogen used during lipid biosynthesis. Y1 - 2012 U6 - https://doi.org/10.1016/j.gca.2011.11.039 SN - 0016-7037 VL - 79 IS - 4 SP - 106 EP - 126 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Melnick, Daniel A1 - Garcin, Yannick A1 - Quinteros, Javier A1 - Strecker, Manfred A1 - Olago, Daniel A1 - Tiercelin, Jean-Jacques T1 - Steady rifting in northern Kenya inferred from deformed Holocene lake shorelines of the Suguta and Turkana basins JF - Earth & planetary science letters N2 - A comparison of deformation rates in active rifts over different temporal scales may help to decipher variations in their structural evolution, controlling mechanisms, and evolution of sedimentary environments through time. Here we use deformed lake shorelines in the Suguta and Turkana basins in northern Kenya as strain markers to estimate deformation rates at the 10(3)-10(4) yr time scale and compare them with rates spanning 10(1)-10(7) yr. Both basins are internally drained today, but until 7 to 5 kyr lake levels were 300 and 100 m higher, respectively, maintained by the elevation of overflow sills connecting them with the Nile drainage. Protracted high lake levels resulted in formation of a maximum highstand shoreline - a distinct geomorphic feature virtually continuous for several tens of kilometers. We surveyed the elevation of this geomorphic marker at 45 sites along >100 km of the rift, and use the overflow sills as vertical datum. Thin-shell elastic and thermomechanical models for this region predict up to similar to 10 m of rapid isostatic rebound associated with lake-level falls lasting until similar to 2 kyr ago. Holocene cumulative throw rates along four rift-normal profiles are 6.8-8.5 mm/yr, or 7.5-9.6 mm/yr if isostatic rebound is considered. Assuming fault dips of 55-65, inferred from seismic reflection profiles, we obtained extension rates of 3.2-6 mm/yr (including uncertainties in field measurements, fault dips, and ages), or 3.5-6.7 mm/yr considering rebound. Our estimates are consistent, within uncertainties, with extension rates of 4-5.1 mm/yr predicted by a modern plate-kinematic model and plate reconstructions since 3.2 Myr. The Holocene strain rate of 10(-15) s(-1) is similar to estimates on the similar to 10(6) yr scale, but over an order of magnitude higher than on the similar to 10(7) yr scale. This is coherent with continuous localization and narrowing of the plate boundary, implying that the lithospheric blocks limiting the Kenya Rift are relatively rigid. Increasing strain rate under steady extension rate suggests that, as the magnitude of extension and crustal thinning increases, the role of regional processes such as weakening by volcanism becomes dominant over far-field plate tectonics controlling the breakup process and the transition from continental rifting to oceanic spreading. KW - continental rifting KW - East Africa KW - lake shorelines KW - Holocene extension KW - isostatic rebound Y1 - 2012 U6 - https://doi.org/10.1016/j.epsl.2012.03.007 SN - 0012-821X VL - 331 IS - 10 SP - 335 EP - 346 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Garcin, Yannick A1 - Melnick, Daniel A1 - Strecker, Manfred A1 - Olago, Daniel A1 - Tiercelin, Jean-Jacques T1 - East African mid-Holocene wet-dry transition recorded in palaeo-shorelines of Lake Turkana, northern Kenya Rift JF - Earth & planetary science letters N2 - The 'wet' early to mid-Holocene of tropical Africa, with its enhanced monsoon, ended with an abrupt shift toward drier conditions and was ultimately replaced by a drier climate that has persisted until the present day. The forcing mechanisms, the timing, and the spatial extent of this major climatic transition are not well understood and remain the subject of ongoing research. We have used a detailed palaeo-shoreline record from Lake Turkana (Kenya) to decipher and characterise this marked climatic transition in East Africa. We present a high-precision survey of well-preserved palaeo-shorelines, new radiocarbon ages from shoreline deposits, and oxygen-isotope measurements on freshwater mollusk shells to elucidate the Holocene moisture history from former lake water-levels in this climatically sensitive region. In combination with previously published data our study shows that during the early Holocene the water-level in Lake Turkana was high and the lake overflowed temporarily into the White Nile drainage system. During the mid-Holocene (similar to 5270 +/- 300 cal. yr BP), however, the lake water-level fell by similar to 50 m, coeval with major episodes of aridity on the African continent. A comparison between palaeo-hydrological and archaeological data from the Turkana Basin suggests that the mid-Holocene climatic transition was associated with fundamental changes in prehistoric cultures, highlighting the significance of natural climate variability and associated periods of protracted drought as major environmental stress factors affecting human occupation in the East African Rift System. ( KW - East African Rift System KW - Lake Turkana KW - Palaeo-shorelines KW - African Humid Period KW - Holocene KW - Tectonic deformation Y1 - 2012 U6 - https://doi.org/10.1016/j.epsl.2012.03.016 SN - 0012-821X VL - 331 SP - 322 EP - 334 PB - Elsevier CY - Amsterdam ER -