TY - JOUR A1 - Kuehn, Sergei A1 - Pingel, Patrick A1 - Breusing, Markus A1 - Fischer, Thomas A1 - Stumpe, Joachim A1 - Neher, Dieter A1 - Elsaesser, Thomas T1 - High-Resolution Near-Field Optical Investigation of Crystalline Domains in Oligomeric PQT-12 Thin Films JF - Advanced functional materials N2 - The structure and morphology on different length scales dictate both the electrical and optical properties of organic semiconductor thin films. Using a combination of spectroscopic methods, including scanning near-field optical microscopy, we study the domain structure and packing quality of highly crystalline thin films of oligomeric PQT-12 with 100 nanometer spatial resolution. The pronounced optical anisotropy of these layers measured by polarized light microscopy facilitates the identification of regions with uniform molecular orientation. We find that a hierarchical order on three different length scales exists in these layers, made up of distinct well-ordered dichroic areas at the ten-micrometer-scale, which are sub-divided into domains with different molecular in-plane orientation. These serve as a template for the formation of smaller needle-like crystallites at the layer surface. A high degree of crystalline order is believed to be the cause of the rather high field-effect mobility of these layers of 10(-3) cm 2 V(-1) s(-1), whereas it is limited by the presence of domain boundaries at macroscopic distances. Y1 - 2011 U6 - https://doi.org/10.1002/adfm.201001978 SN - 1616-301X VL - 21 IS - 5 SP - 860 EP - 868 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Hoffmann, Katrin A1 - Dietzel, Birgit A1 - Schulz, Burkhard A1 - Reck, Guenter A1 - Hoffmann, Angelika A1 - Orgzall, Ingo A1 - Resch-Genger, Ute A1 - Emmerling, Franziska T1 - Combined structural and fluorescence studies of methyl-substituted 2,5-diphenyl-1,3,4-oxadiazoles - Relation between electronic properties and packing motifs JF - Journal of molecular structure N2 - Prerequisite for the rational design of functional organic materials with tailor-made electronic properties is the knowledge of the structure-property relationship for the specific class of molecules under consideration. This encouraged us to systematically study the influence of the molecular structure and substitution pattern of aromatically substituted 1,3,4-oxadiazoles on the electronic properties and packing motifs of these molecules and on the interplay of these factors. For this purpose, seven diphenyl-oxadiazoles equipped with methyl substituents in the ortho- and meta-position(s) were synthesized and characterized. Absorption and fluorescence spectra in solution served here as tools to monitor substitution-induced changes in the electronic properties of the individual molecules whereas X-ray and optical measurements in the solid state provided information on the interplay of electronic and packing effects. In solution, the spectral position of the absorption maximum, the size of Stokes shift, and the fluorescence quantum yield are considerably affected by ortho-substitution in three or four ortho-positions. This results in blue shifted absorption bands, increased Stokes shifts, and reduced fluorescence quantum yields whereas the spectral position and vibrational structure of the emission bands remain more or less unaffected. In the crystalline state, however, the spectral position and shape of the emission bands display a strong dependence on the molecular structure and/or packing motifs that seem to control the amount of dye-dye-interactions. These observations reveal the limited value of commonly reported absorption and fluorescence measurements in solution for a straightforward comparison of spectroscopic results with single X-ray crystallography. This underlines the importance of solid state spectroscopic studies for a better understanding of the interplay of electronic effects and molecular order. KW - Diphenyl-oxadiazoles KW - X-ray structure KW - Packing motif KW - Optical properties KW - Fluorescence quantum yield Y1 - 2011 U6 - https://doi.org/10.1016/j.molstruc.2010.11.071 SN - 0022-2860 VL - 988 IS - 1-3 SP - 35 EP - 46 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Turukina, L. V. A1 - Pikovskij, Arkadij T1 - Hyperbolic chaos in a system of resonantly coupled weakly nonlinear oscillators JF - Modern physics letters : A, Particles and fields, gravitation, cosmology, nuclear physics N2 - We show that a hyperbolic chaos can be observed in resonantly coupled oscillators near a Hopf bifurcation, described by normal-form-type equations for complex amplitudes. The simplest example consists of four oscillators, comprising two alternatively activated, due to an external periodic modulation, pairs. In terms of the stroboscopic Poincare map, the phase differences change according to an expanding Bernoulli map that depends on the coupling type. Several examples of hyperbolic chaos for different types of coupling are illustrated numerically. KW - Coupled oscillators KW - Hyperbolic chaos Y1 - 2011 U6 - https://doi.org/10.1016/j.physleta.2011.02.017 SN - 0375-9601 VL - 375 IS - 11 SP - 1407 EP - 1411 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Prosen, Tomaz T1 - Complexity and nonseparability of classical Liouvillian dynamics JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We propose a simple complexity indicator of classical Liouvillian dynamics, namely the separability entropy, which determines the logarithm of an effective number of terms in a Schmidt decomposition of phase space density with respect to an arbitrary fixed product basis. We show that linear growth of separability entropy provides a stricter criterion of complexity than Kolmogorov-Sinai entropy, namely it requires that the dynamics be exponentially unstable, nonlinear, and non-Markovian. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevE.83.031124 SN - 1539-3755 VL - 83 IS - 3 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Schaefer, Edith A1 - Westendorf, Christian A1 - Bodenschatz, Eberhard A1 - Beta, Carsten A1 - Geil, Burkhard A1 - Janshoff, Andreas T1 - Shape oscillations of dictyostelium discoideum cells on ultramicroelectrodes monitored by impedance analysis JF - Small Y1 - 2011 U6 - https://doi.org/10.1002/smll.201001955 SN - 1613-6810 VL - 7 IS - 6 SP - 723 EP - 726 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Floss, Gereon A1 - Klamroth, Tillmann A1 - Saalfrank, Peter T1 - Laser-controlled switching of molecular arrays in an dissipative environment JF - Physical review : B, Condensed matter and materials physics N2 - The optical switching of molecular ensembles in a dissipative environment is a subject of various fields of chemical physics and physical chemistry. Here we try to switch arrays of molecules from a stable collective ground state to a state in which all molecules have been transferred to another stable higher-energy configuration. In our model switching proceeds through electronically excited intermediates which are coherently coupled to each other through dipolar interactions, and which decay incoherently within a finite lifetime by coupling to a dissipative environment. The model is quite general, but parameters are chosen to roughly resemble the all-trans -> all-cis isomerization of an array of azobenzene molecules on a surface. Using analytical and optimal control pulses and the concept of "laser distillation," we demonstrate that for various aggregates (dimers up to hexamers), controlled and complete switching should be possible. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevB.83.104301 SN - 1098-0121 VL - 83 IS - 10 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Rychkov, Dmitry A1 - Gerhard, Reimund T1 - Stabilization of positive charge on polytetrafluoroethylene electret films treated with titanium-tetrachloride vapor JF - Applied physics letters N2 - The surface of polytetrafluoroethylene films was treated with titanium-tetrachloride vapor. The treatment was carried out in a flow reactor by means of molecular-layer deposition, a method from the arsenal of chemical nanotechnology. X-ray photoelectron spectroscopy reveals that such a treatment results in considerable changes in the chemical composition at and near the surface of the fluoropolymer film. Both, defluorination and oxidation of the surface were observed. At the same time, samples treated with titanium tetrachloride show a significant enhancement in the thermal stability of the positive homocharge. The thermally stimulated surface-potential-decay curves were observed to shift to higher temperatures by more than 100 degrees C. Y1 - 2011 U6 - https://doi.org/10.1063/1.3565166 SN - 0003-6951 VL - 98 IS - 12 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Campbell, Earl T. T1 - Catalysis and activation of magic states in fault-tolerant architectures JF - Physical review : A, Atomic, molecular, and optical physics N2 - In many architectures for fault-tolerant quantum computing universality is achieved by a combination of Clifford group unitary operators and preparation of suitable nonstabilizer states, the so-called magic states. Universality is possible even for some fairly noisy nonstabilizer states, as distillation can convert many noisy copies into fewer purer magic states. Here we propose protocols that exploit multiple species of magic states in surprising ways. These protocols provide examples of previously unobserved phenomena that are analogous to catalysis and activation well known in entanglement theory. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevA.83.032317 SN - 1050-2947 VL - 83 IS - 3 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Beye, Martin A1 - Föhlisch, Alexander T1 - A soft X-ray approach to electron-phonon interactions beyond the Born-Oppenheimer approximation JF - Journal of electron spectroscopy and related phenomena : the international journal on theoretical and experimental aspects of electron spectroscopy N2 - With modern soft X-ray methods, the whole field of electron-phonon interactions becomes accessible directly in the ultrafast time domain with ultrashort pulsed X-ray sources, as well as in the energy domain through modern highly resolving spectrometers. The well-known core-hole clock approach plays an intermediate role, resolving energetic and temporal features at the same time. In this perspective paper, we review several experiments to illustrate the modern advances in the selective study of electron-phonon interactions as fundamentally determining ingredients for materials properties. We present the different complementary approaches that can be taken with soft X-ray methods to conquer this field beyond the Born-Oppenheimer approximation. KW - Electron-phonon coupling KW - Resonant inelastic X-ray scattering KW - X-ray emission spectroscopy KW - Near edge X-ray absorption fine structure Y1 - 2011 U6 - https://doi.org/10.1016/j.elspec.2010.12.032 SN - 0368-2048 VL - 184 IS - 3-6 SP - 313 EP - 317 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Richter, Philipp A1 - Krause, F. A1 - Fechner, Cora A1 - Charlton, Jane C. A1 - Murphy, M. T. T1 - The neutral gas extent of galaxies as derived from weak intervening Ca II absorbers JF - Astronomy and astrophysics : an international weekly journal N2 - We present a systematic study of weak intervening CaII absorbers at low redshift (z < 0.5), based on the analysis of archival high-resolution (R >= 45 000) optical spectra of 304 quasars and active galactic nuclei observed with VLT/UVES. Along a total redshift path of Delta z approximate to 100 we detected 23 intervening CaII absorbers in both the CaII H & K lines, with rest frame equivalent widths W-r,W-3934 = 15-799 m angstrom and column densities log N(CaII) = 11.25-13.04 (obtained by fitting Voigt-profile components). We obtain a bias-corrected number density of weak intervening CaII absorbers of dN/dz = 0.117 +/- 0.044 at < z(abs)> = 0.35 for absorbers with log N(CaII) >= 11.65 (W-r,W-3934 >= 32 m angstrom). This is similar to 2.6 times the value obtained for damped Lyman alpha absorbers (DLAs) at low redshift. All CaII absorbers in our sample show associated absorption by other low ions such as MgII and FeII; 45 percent of them have associated NaI absorption. From ionization modelling we conclude that intervening CaII absorption with log N(CaII) >= 11.5 arises in DLAs, sub-DLAs and Lyman-limit systems (LLS) at HI column densities of log N(HI) >= 17.4. Using supplementary HI information for nine of the absorbers we find that the CaII/HI ratio decreases strongly with increasing HI column density, indicating a column-density-dependent dust depletion of Ca. The observed column density distribution function of CaII absorption components follows a relatively steep power law, f(N) proportional to N-beta, with a slope of -beta = -1.68, which again points towards an enhanced dust depletion in high column density systems. The relatively large cross section of these absorbers together with the frequent detection of CaII absorption in high-velocity clouds (HVCs) in the halo of the Milky Way suggests that a considerable fraction of the intervening CaII systems trace (partly) neutral gas structures in the halos and circumgalactic environment of galaxies (i.e., they are HVC analogs). Based on the recently measured detection rate of CaII absorption in the Milky Way HVCs we estimate that the mean (projected) CaII covering fraction of galaxies and their gaseous halos is < f(c,CaII)> = 0.33. Using this value and considering all galaxies with luminosities L >= 0.05 L-star we calculate that the characteristic radial extent of (partly) neutral gas clouds with log N(HI) >= 17.4 around low-redshift galaxies is R-HVC approximate to 55 kpc. KW - galaxies: halos KW - galaxies: formation KW - galaxies: ISM KW - intergalactic medium KW - quasars: absorption lines Y1 - 2011 U6 - https://doi.org/10.1051/0004-6361/201015566 SN - 0004-6361 VL - 528 IS - 4 PB - EDP Sciences CY - Les Ulis ER -