TY - THES A1 - Emberson, Robert T1 - Chemical weathering driven by bedrock landslides Y1 - 2016 ER - TY - JOUR A1 - Emberson, Robert A1 - Hovius, Niels A1 - Galy, Albert A1 - Marc, Odin T1 - Chemical weathering in active mountain belts controlled by stochastic bedrock landsliding JF - Nature geoscience N2 - A link between chemical weathering and physical erosion exists at the catchment scale over a wide range of erosion rates(1,2). However, in mountain environments, where erosion rates are highest, weathering may be kinetically limited(3-5) and therefore decoupled from erosion. In active mountain belts, erosion is driven by bedrock landsliding(6) at rates that depend strongly on the occurrence of extreme rainfall or seismicity(7). Although landslides affect only a small proportion of the landscape, bedrock landsliding can promote the collection and slow percolation of surface runoff in highly fragmented rock debris and create favourable conditions for weathering. Here we show from analysis of surface water chemistry in the Southern Alps of New Zealand that weathering in bedrock landslides controls the variability in solute load of these mountain rivers. We find that systematic patterns in surface water chemistry are strongly associated with landslide occurrence at scales from a single hillslope to an entire mountain belt, and that landslides boost weathering rates and river solute loads over decades. We conclude that landslides couple erosion and weathering in fast-eroding uplands and, thus, mountain weathering is a stochastic process that is sensitive to climatic and tectonic controls on mass wasting processes. Y1 - 2016 U6 - https://doi.org/10.1038/NGEO2600 SN - 1752-0894 SN - 1752-0908 VL - 9 SP - 42 EP - + PB - Nature Publ. Group CY - New York ER - TY - JOUR A1 - Emberson, Robert A1 - Galy, Albert A1 - Hovius, Niels T1 - Combined effect of carbonate and biotite dissolution in landslides biases silicate weathering proxies JF - Geochimica et cosmochimica acta : journal of the Geochemical Society and the Meteoritical Society N2 - Long-term estimates of the dissolution of silicate rock are generally derived from a range of isotopic proxies, such as the radiogenic strontium isotope ratio (Sr-87/Sr-86), which are preserved in sediment archives. For these systems to fairly represent silicate weathering, the changes in isotopic ratios in terrestrial surface waters should correspond to changes in the overall silicate dissolution. This assumes that the silicate mineral phases that act as sources of a given isotope dissolve at a rate that is proportional to the overall silicate weathering. Bedrock landsliding exhumes large quantities of fresh rock for weathering in transient storage, and rapid weathering in these deposits is controlled primarily by dissolution of the most reactive phases. In this study, we test the hypothesis that preferential weathering of these labile minerals can decouple the dissolution of strontium sources from the actual silicate weathering rates in the rapidly eroding Western Southern Alps (WSA) of New Zealand. We find that rapid dissolution of relatively radiogenic calcite and biotite in landslides leads to high local fluxes in strontium with isotopic ratios that offer no clear discrimination between sources. These higher fluxes of radiogenic strontium are in contrast to silicate weathering rates in landslides that are not systematically elevated. On a mountain belt scale, radiogenic strontium fluxes are not coupled to volumes of recent landslides in large (>100 km(2)) catchments, but silicate weathering fluxes are. Such decoupling is likely due first to the broad variability in the strontium content of carbonate minerals, and second to the combination of radiogenic strontium released from both biotite and carbonate in recent landslides. This study supports previous work suggesting the limited utility of strontium isotopes as a system to study silicate weathering in the WSA. Crucially however, in settings where bedrock landsliding is a dominant erosive process there is potential for both random and systematic bias in isotope proxies if the most reactive phases exposed for dissolution by landslides disproportionately contribute to the proxy of choice. This clearly suggests that the isotopic composition of marine Sr is a proxy for periods of rapid mountain uplift and erosion rather than for the associated enhanced silicate weathering. (C) 2017 Elsevier Ltd. All rights reserved. KW - Landslides KW - Silicate weathering KW - Isotope proxy KW - New Zealand Y1 - 2017 U6 - https://doi.org/10.1016/j.gca.2017.07.014 SN - 0016-7037 SN - 1872-9533 VL - 213 SP - 418 EP - 434 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Emberson, Robert A1 - Hovius, Niels A1 - Galy, Albert A1 - Marc, Odin T1 - Oxidation of sulfides and rapid weathering in recent landslides JF - Earth surface dynamics N2 - Bedrock landslides, by excavating deep below saprolite-rock interfaces, create conditions for weathering in which all mineral phases in a lithology are initially unweathered within landslide deposits. As a result, the most labile phases dominate the weathering immediately after mobilisation and during a transient period of depletion. This mode of dissolution can strongly alter the overall output of solutes from catchments and their contribution to global chemical cycles if landslide-derived material is retained in catchments for extended periods after mass wasting. Y1 - 2016 U6 - https://doi.org/10.5194/esurf-4-727-2016 SN - 2196-6311 SN - 2196-632X VL - 4 SP - 727 EP - 742 PB - Copernicus CY - Göttingen ER - TY - GEN A1 - Emberson, Robert A1 - Hovius, Niels A1 - Galy, Albert A1 - Marc, Odin T1 - Oxidation of sulfides and rapid weathering in recent landslides T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Linking together the processes of rapid physical erosion and the resultant chemical dissolution of rock is a crucial step in building an overall deterministic understanding of weathering in mountain belts. Landslides, which are the most volumetrically important geomorphic process at these high rates of erosion, can generate extremely high rates of very localised weathering. To elucidate how this process works we have taken advantage of uniquely intense landsliding, resulting from Typhoon Morakot, in the T'aimali River and surrounds in southern Taiwan. Combining detailed analysis of landslide seepage chemistry with estimates of catchment-by-catchment landslide volumes, we demonstrate that in this setting the primary role of landslides is to introduce fresh, highly labile mineral phases into the surface weathering environment. There, rapid weathering is driven by the oxidation of pyrite and the resultant sulfuric-acid-driven dissolution of primarily carbonate rock. The total dissolved load correlates well with dissolved sulfate - the chief product of this style of weathering - in both landslides and streams draining the area (R-2 = 0.841 and 0.929 respectively; p < 0.001 in both cases), with solute chemistry in seepage from landslides and catchments affected by significant landsliding governed by the same weathering reactions. The predominance of coupled carbonate-sulfuric-acid-driven weathering is the key difference between these sites and previously studied landslides in New Zealand (Emberson et al., 2016), but in both settings increasing volumes of landslides drive greater overall solute concentrations in streams. Bedrock landslides, by excavating deep below saprolite-rock interfaces, create conditions for weathering in which all mineral phases in a lithology are initially unweathered within landslide deposits. As a result, the most labile phases dominate the weathering immediately after mobilisation and during a transient period of depletion. This mode of dissolution can strongly alter the overall output of solutes from catchments and their contribution to global chemical cycles if landslide-derived material is retained in catchments for extended periods after mass wasting. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 553 KW - physical erosion KW - Mountain Belt KW - Southwestern Taiwan KW - athmospheric CO2 KW - New-Zealand KW - climatic controls KW - Himalayan Rivers KW - Southern Alps KW - carbon-cycle KW - model Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-412326 SN - 1866-8372 IS - 553 ER - TY - JOUR A1 - Emberson, Robert A1 - Galy, Albert A1 - Hovius, Niels T1 - Weathering of Reactive Mineral Phases in Landslides Acts as a Source of Carbon Dioxide in Mountain Belts JF - Journal of geophysical research : Earth surface N2 - Bedrock landsliding in mountain belts can elevate overall chemical weathering rates through rapid dissolution of exhumed reactive mineral phases in transiently stored deposits. This link between a key process of erosion and the resultant weathering affects the sequestering of carbon dioxide through weathering of silicate minerals and broader links between erosion in active orogens and climate change. Here we address the effect on the carbon cycle of weathering induced by bedrock landsliding in Taiwan and the Western Southern Alps of New Zealand. Using solute chemistry data from samples of seepage from landslide deposits and river discharge from catchments with variable proportions of landsliding, we model the proportion of silicate and carbonate weathering and the balance of sulfuric and carbonic acids that act as weathering agents. We correct for secondary precipitation, geothermal, and cyclic input, to find a closer approximation of the weathering explicitly occurring within landslide deposits. We find highly variable proportions of sulfuric and carbonic acids driving weathering in landslides and stable hillslopes. Despite this variability, the predominance of rapid carbonate weathering within landslides and catchments where mass wasting is prevalent results at best in limited sequestration of carbon dioxide by this process of rapid erosion. In many cases where sulfuric acid is a key weathering agent, a net release of CO2 to the atmosphere occurs. This suggests that a causal link between erosion in mountain belts and climate change through the sequestration of CO2, if it exists, must operate through a process other than chemical weathering driven by landsliding. Plain Language Summary There is a long-standing debate surrounding the link between erosion and climate. It is often suggested that as temperatures increase, rainier and stormier weather could increase erosion of rock; as that rock is exposed, silicate minerals within could break down, which, on long time scales, can remove CO2 from the atmosphere, lowering global temperatures and acting as a negative feedback. Recent studies have shown that landslide deposits are key locations for the link between chemical weathering and physical erosion in some mountain belts. To test how landslides affect the erosion-climate link, we used samples of water seeping through landslides in Taiwan and New Zealand to calculate the amount of carbon dioxide that is either absorbed or released through this chemical reaction. We find that the large amount of freshly exposed rock in Taiwanese landslide deposits contains significant carbonate rock and sulfide minerals; the net result of the weathering of these minerals is a release of carbon dioxide, which inverts the traditional perspective on the role erosion plays in controlling carbon dioxide release. In some mountain belts, it seems that increased erosion and resulting landsliding may act to increase carbon dioxide in the air, opening further questions into the nature of erosional-climatic links. KW - chemical weathering KW - landslides KW - erosion-climate link KW - carbon dioxide Y1 - 2018 U6 - https://doi.org/10.1029/2018JF004672 SN - 2169-9003 SN - 2169-9011 VL - 123 IS - 10 SP - 2695 EP - 2713 PB - American Geophysical Union CY - Washington ER -