TY - JOUR A1 - Gaal, P. A1 - Schick, Daniel A1 - Herzog, Marc A1 - Bojahr, Andre A1 - Shayduk, Roman A1 - Goldshteyn, J. A1 - Navirian, Hengameh A. A1 - Leitenberger, Wolfram A1 - Vrejoiu, Ionela A1 - Khakhulin, D. A1 - Wulff, M. A1 - Bargheer, Matias T1 - Time-domain sampling of x-ray pulses using an ultrafast sample response JF - Applied physics letters N2 - We employ the ultrafast response of a 15.4 nm thin SrRuO3 layer grown epitaxially on a SrTiO3 substrate to perform time-domain sampling of an x-ray pulse emitted from a synchrotron storage ring. Excitation of the sample with an ultrashort laser pulse triggers coherent expansion and compression waves in the thin layer, which turn the diffraction efficiency on and off at a fixed Bragg angle during 5 ps. This is significantly shorter than the duration of the synchrotron x-ray pulse of 100 ps. Cross-correlation measurements of the ultrafast sample response and the synchrotron x-ray pulse allow to reconstruct the x-ray pulse shape. Y1 - 2012 U6 - https://doi.org/10.1063/1.4769828 SN - 0003-6951 VL - 101 IS - 24 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Telezhinsky, Igor O. A1 - Dwarkadas, Vikram V. A1 - Pohl, Martin T1 - Time-dependent escape of cosmic rays from supernova remnants, and their interaction with dense media JF - Astronomy and astrophysics : an international weekly journal N2 - Context. Supernova remnants (SNRs) are thought to be the main source of Galactic cosmic rays (CRs) up to the "knee" in CR spectrum. During the evolution of a SNR, the bulk of the CRs are confined inside the SNR shell. The highest-energy particles leave the system continuously, while the remaining adiabatically cooled particles are released when the SNR has expanded sufficiently and decelerated so that the magnetic field at the shock is no longer able to confine them. Particles escaping from the parent system may interact with nearby molecular clouds, producing.-rays in the process via pion decay. The soft gamma-ray spectra observed for a number of SNRs interacting with molecular clouds, however, challenge current theories of non-linear particle acceleration that predict harder spectra. Aims. We study how the spectrum of escaped particles depends on the time-dependent acceleration history in both Type Ia and core-collapse SNRs, as well as on different assumptions about the diffusion coefficient in the vicinity of the SNR. Methods. We solve the CR transport equation in a test-particle approach combined with numerical simulations of SNR evolution. Results. We extend our method for calculating the CR acceleration in SNRs to trace the escaped particles in a large volume around SNRs. We calculate the evolution of the spectra of CRs that have escaped from a SNR into a molecular cloud or dense shell for two diffusion models. We find a strong confinement of CRs in a close region around the SNR, and a strong dilution effect for CRs that were able to propagate out as far as a few SNR radii. KW - ISM: supernova remnants KW - ISM: clouds KW - cosmic rays Y1 - 2012 U6 - https://doi.org/10.1051/0004-6361/201118639 SN - 0004-6361 VL - 541 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Surlan, B. A1 - Hamann, Wolf-Rainer A1 - Kubat, Jirij A1 - Oskinova, Lidia M. A1 - Feldmeier, Achim T1 - Three-dimensional radiative transfer in clumped hot star winds I influence of clumping on the resonance line formation JF - Astronomy and astrophysics : an international weekly journal N2 - Context. The true mass-loss rates from massive stars are important for many branches of astrophysics. For the correct modeling of the resonance lines, which are among the key diagnostics of stellar mass-loss, the stellar wind clumping has been found to be very important. To incorporate clumping into a radiative transfer calculation, three-dimensional (3D) models are required. Various properties of the clumps may have a strong impact on the resonance line formation and, therefore, on the determination of empirical mass-loss rates. Aims. We incorporate the 3D nature of the stellar wind clumping into radiative transfer calculations and investigate how different model parameters influence the resonance line formation. Methods. We develop a full 3D Monte Carlo radiative transfer code for inhomogeneous expanding stellar winds. The number density of clumps follows the mass conservation. For the first time, we use realistic 3D models that describe the dense as well as the tenuous wind components to model the formation of resonance lines in a clumped stellar wind. At the same time, we account for non-monotonic velocity fields. Results. The 3D density and velocity wind inhomogeneities show that there is a very strong impact on the resonance line formation. The different parameters describing the clumping and the velocity field results in different line strengths and profiles. We present a set of representative models for various sets of model parameters and investigate how the resonance lines are affected. Our 3D models show that the line opacity is lower for a larger clump separation and shallower velocity gradients within the clumps. Conclusions. Our model demonstrates that to obtain empirically correct mass-loss rates from the UV resonance lines, the wind clumping and its 3D nature must be taken into account. KW - stars: winds, outflows KW - stars: mass-loss KW - stars: early-type Y1 - 2012 U6 - https://doi.org/10.1051/0004-6361/201118590 SN - 0004-6361 VL - 541 PB - EDP Sciences CY - Les Ulis ER - TY - CHAP A1 - Wang, Victor C. A1 - Mayer, Frank A1 - Dorenkamp, Marc A1 - Bonaventura, Klaus T1 - Three-dimensional global area tracking is a valuable quantitative parameter for left ventricular function in athletes T2 - Medicine and science in sports and exercise : official journal of the American College of Sports Medicine Y1 - 2012 SN - 0195-9131 VL - 44 SP - 850 EP - 850 PB - Lippincott Williams & Wilkins CY - Philadelphia ER - TY - JOUR A1 - Maslin, Mark A. A1 - Pancost, Richard D. A1 - Wilson, Katy E. A1 - Lewis, Jonathan A1 - Trauth, Martin H. T1 - Three and half million year history of moisture availability of South West Africa evidence from ODP site 1085 biomarker records JF - Palaeogeography, palaeoclimatology, palaeoecology : an international journal for the geo-sciences N2 - Ocean Drilling Program Site 1085 provides a continuous marine sediment record off southern South West Africa for at least the last three and half million years. The n-alkane partial derivative(13) C record from this site records changes in past vegetation and provides an indication of the moisture availability of SW Africa during this time period. Very little variation, and no apparent trend, is observed in the n-alkane delta C-13 record, suggesting stable long-term conditions despite significant changes in East African tectonics and global climate. Slightly higher n-alkane delta C-13 values occur between 3.5 and 2.7 Ma suggesting slightly drier conditions than today. Between 2.5 and 2.7 Ma there is a shift to more negative n-alkane delta C-13 values suggesting slightly wetter conditions during a similar to 0.2 Ma episode that coincides with the intensification of Northern Hemisphere Glaciation (iNHG). From 2.5 to 0.4 Ma the n-alkane delta C-13 values are very consistent, varying by less than +/- 0.5 parts per thousand and suggesting little or no long-term change in the moisture availability of South West Africa over the last 2.5 million years. This is in contrast to the long-term drying trend observed further north offshore from the Namib Desert and in East Africa. A comparison of the climate history of these regions suggests that Southern Africa may have been an area of long-term stability over the last 3.5 Myrs. KW - Plio-Pleistocene KW - Aridity KW - SW Africa KW - Biomarkers KW - Palaeoclimate KW - Human evolution Y1 - 2012 U6 - https://doi.org/10.1016/j.palaeo.2011.12.009 SN - 0031-0182 VL - 317 SP - 41 EP - 47 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Sarauli, David A1 - Xu, Chenggang A1 - Dietzel, Birgit A1 - Stiba, Konstanze A1 - Leimkühler, Silke A1 - Schulz, Burkhard A1 - Lisdat, Fred T1 - Thin films of substituted polyanilines interactions with biomolecular systems JF - Soft matter N2 - We use substituted polyanilines for the construction of new polymer electrodes for interaction studies with the redox protein cytochrome c (cyt c) and the enzyme sulfite oxidase (SO). For these purposes four different polyaniline copolymers are chemically synthesized. Three of them are copolymers, containing 2-methoxyaniline-5-sulfonic acid with variable ratios of aniline; the fourth copolymer consists of 3-amino-benzoic acid and aniline. The results show that all polymers are suitable for being immobilized as thin stable films on gold wire and indium tin oxide (ITO) electrode surfaces from DMSO solution. This can be demonstrated by cyclic voltammetry and UV-Vis spectroscopy measurements. Moreover, cyt c can be electrochemically detected not only in solution, but also immobilized on top of the polymer films. Furthermore, the appearance of a significant catalytic current has been demonstrated for the sulfonated polyanilines, when the polymer-coated protein electrode is being measured upon addition of sulfite oxidase, confirming the establishment of a bioanalytical signal chain. Best results have been obtained for the polymer with highest sulfonation grade. The redox switching of the polymer by the enzymatic reaction can also be analyzed by following the spectral properties of the polymer electrode. Y1 - 2012 U6 - https://doi.org/10.1039/c2sm07261k SN - 1744-683X VL - 8 IS - 14 SP - 3848 EP - 3855 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - Miasnikova, Anna A1 - Laschewsky, André A1 - De Paoli, Gabriele A1 - Papadakis, Christine M. A1 - Müller-Buschbaum, Peter A1 - Funari, Sergio S. T1 - Thermoresponsive Hydrogels from Symmetrical Triblock Copolymers Poly(styrene-block-(methoxy diethylene glycol acrylate)-block-styrene) JF - Langmuir N2 - A series of symmetrical, thermo-responsive triblock copolymers was prepared by reversible addition fragmentation chain transfer (RAFT) polymerization, and studied in aqueous solution with respect to their ability to form hydrogels. Triblock copolymers were composed of two identical, permanently hydrophobic outer blocks, made of low molar mass polystyrene, and of a hydrophilic inner block of variable length, consisting of poly(methoxy diethylene glycol acrylate) PMDEGA. The polymers exhibited a LCST-type phase transition in the range of 20-40 degrees C, which markedly depended on molar mass and concentration. Accordingly, the triblock copolymers behaved as amphiphiles at low temperatures, but became water-insoluble at high temperatures. The temperature dependent self-assembly of the amphiphilic block copolymers in aqueous solution was studied by turbidimetry and rheology at concentrations up to 30 wt %, to elucidate the impact of the inner thermoresponsive block on the gel properties. Additionally, small-angle X-ray scattering (SAXS) was performed to access the structural changes in the gel with temperature. For all polymers a gel phase was obtained at low temperatures, which underwent a gel-sol transition at intermediate temperatures, well below the cloud point where phase separation occurred. With increasing length of the PMDEGA inner block, the gel-sol transition shifts to markedly lower concentrations, as well as to higher transition temperatures. For the longest PMDEGA block studied (DPn about 450), gels had already formed at 3.5 wt % at low temperatures. The gel-sol transition of the hydrogels and the LCST-type phase transition of the hydrophilic inner block were found to be independent of each other. Y1 - 2012 U6 - https://doi.org/10.1021/la204665q SN - 0743-7463 VL - 28 IS - 9 SP - 4479 EP - 4490 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Petrunin, Alexey G. A1 - Rioseco, Ernesto Meneses A1 - Sobolev, Stephan Vladimir A1 - Weber, Michael H. T1 - Thermomechanical model reconciles contradictory geophysical observations at the Dead Sea Basin JF - Geochemistry, geophysics, geosystems N2 - The Dead Sea Transform (DST) comprises a boundary between the African and Arabian plates. During the last 15-20 m.y. more than 100 km of left lateral transform displacement has been accumulated on the DST and about 10 km thick Dead Sea Basin (DSB) was formed in the central part of the DST. Widespread igneous activity since some 20 Ma ago and especially in the last 5 m.y., thin (60-80 km) lithosphere constrained by seismic data and absence of seismicity below the Moho, seem to be quite natural for this tectonically active plate boundary. However, surface heat flow values of less than 50-60 mW/m(2) and deep seismicity in the lower crust (deeper than 20 km) reported for this region are apparently inconsistent with the tectonic settings specific for an active continental plate boundary and with the crustal structure of the DSB. To address these inconsistencies which comprise what we call the "DST heat-flow paradox," we have developed a numerical model that assumes an erosion of initially thick and cold lithosphere just before or during the active faulting at the DST. The optimal initial conditions for the model are defined using transient thermal analysis. From the results of our numerical experiments we conclude that the entire set of observations for the DSB can be explained within the classical pull-apart model assuming that the lithosphere has been thermally eroded at about 20 Ma and the uppermost mantle in the region have relatively weak rheology consistent with experimental data for wet olivine or pyroxenite. KW - heat flow KW - pull-apart basin KW - tectonophysics KW - thermomechanical modeling KW - transform fault Y1 - 2012 U6 - https://doi.org/10.1029/2011GC003929 SN - 1525-2027 VL - 13 IS - 8 PB - American Geophysical Union CY - Washington ER - TY - THES A1 - Morgenstern, Anne T1 - Thermokarst and thermal erosion : degradation of Siberian ice-rich permafrost T1 - Thermokarst und Thermoerosion : Degradation von sibirischem eisreichem Permafrost N2 - Current climate warming is affecting arctic regions at a faster rate than the rest of the world. This has profound effects on permafrost that underlies most of the arctic land area. Permafrost thawing can lead to the liberation of considerable amounts of greenhouse gases as well as to significant changes in the geomorphology, hydrology, and ecology of the corresponding landscapes, which may in turn act as a positive feedback to the climate system. Vast areas of the east Siberian lowlands, which are underlain by permafrost of the Yedoma-type Ice Complex, are particularly sensitive to climate warming because of the high ice content of these permafrost deposits. Thermokarst and thermal erosion are two major types of permafrost degradation in periglacial landscapes. The associated landforms are prominent indicators of climate-induced environmental variations on the regional scale. Thermokarst lakes and basins (alasses) as well as thermo-erosional valleys are widely distributed in the coastal lowlands adjacent to the Laptev Sea. This thesis investigates the spatial distribution and morphometric properties of these degradational features to reconstruct their evolutionary conditions during the Holocene and to deduce information on the potential impact of future permafrost degradation under the projected climate warming. The methodological approach is a combination of remote sensing, geoinformation, and field investigations, which integrates analyses on local to regional spatial scales. Thermokarst and thermal erosion have affected the study region to a great extent. In the Ice Complex area of the Lena River Delta, thermokarst basins cover a much larger area than do present thermokarst lakes on Yedoma uplands (20.0 and 2.2 %, respectively), which indicates that the conditions for large-area thermokarst development were more suitable in the past. This is supported by the reconstruction of the development of an individual alas in the Lena River Delta, which reveals a prolonged phase of high thermokarst activity since the Pleistocene/Holocene transition that created a large and deep basin. After the drainage of the primary thermokarst lake during the mid-Holocene, permafrost aggradation and degradation have occurred in parallel and in shorter alternating stages within the alas, resulting in a complex thermokarst landscape. Though more dynamic than during the first phase, late Holocene thermokarst activity in the alas was not capable of degrading large portions of Pleistocene Ice Complex deposits and substantially altering the Yedoma relief. Further thermokarst development in existing alasses is restricted to thin layers of Holocene ice-rich alas sediments, because the Ice Complex deposits underneath the large primary thermokarst lakes have thawed completely and the underlying deposits are ice-poor fluvial sands. Thermokarst processes on undisturbed Yedoma uplands have the highest impact on the alteration of Ice Complex deposits, but will be limited to smaller areal extents in the future because of the reduced availability of large undisturbed upland surfaces with poor drainage. On Kurungnakh Island in the central Lena River Delta, the area of Yedoma uplands available for future thermokarst development amounts to only 33.7 %. The increasing proximity of newly developing thermokarst lakes on Yedoma uplands to existing degradational features and other topographic lows decreases the possibility for thermokarst lakes to reach large sizes before drainage occurs. Drainage of thermokarst lakes due to thermal erosion is common in the study region, but thermo-erosional valleys also provide water to thermokarst lakes and alasses. Besides these direct hydrological interactions between thermokarst and thermal erosion on the local scale, an interdependence between both processes exists on the regional scale. A regional analysis of extensive networks of thermo-erosional valleys in three lowland regions of the Laptev Sea with a total study area of 5,800 km² found that these features are more common in areas with higher slopes and relief gradients, whereas thermokarst development is more pronounced in flat lowlands with lower relief gradients. The combined results of this thesis highlight the need for comprehensive analyses of both, thermokarst and thermal erosion, in order to assess past and future impacts and feedbacks of the degradation of ice-rich permafrost on hydrology and climate of a certain region. N2 - Die gegenwärtige Klimaerwärmung wirkt sich auf arktische Regionen stärker aus als auf andere Gebiete der Erde. Das hat weitreichende Konsequenzen für Permafrost, der weite Teile der terrestrischen Arktis unterlagert. Das Tauen von Permafrost kann zur Freisetzung erheblicher Mengen an Treibhausgasen sowie zu gravierenden Änderungen in der Geomorphologie, Hydrologie und Ökologie betroffener Landschaften führen, was wiederum als positive Rückkopplung auf das Klimasystem wirken kann. Ausgedehnte Gebiete der ostsibirischen Tiefländer, die mit Permafrost des Yedoma Eiskomplex unterlagert sind, gelten aufgrund des hohen Eisgehalts dieser Permafrostablagerungen als besonders empfindlich gegenüber Klimaerwärmungen. Thermokarst und Thermoerosion sind zwei Hauptformen der Permafrostdegradation in periglazialen Landschaften. Die zugehörigen Landschaftsformen sind auf der regionalen Skala bedeutende Indikatoren klimainduzierter Umweltvariationen. Thermokarstseen und senken (Alasse) sowie Thermoerosionstäler sind in den Küstentiefländern der Laptewsee weit verbreitet. Die vorliegende Dissertation untersucht die räumliche Verbreitung und die morphometrischen Eigenschaften dieser Degradationsformen mit dem Ziel, ihre Entwicklungsbedingungen während des Holozäns zu rekonstruieren und Hinweise auf potenzielle Auswirkungen zukünftiger Permafrostdegradation im Zuge der erwarteten Klimaerwärmung abzuleiten. Der methodische Ansatz ist eine Kombination aus Fernerkundungs-, Geoinformations- und Geländeuntersuchungen, die Analysen auf lokalen bis regionalen räumlichen Skalen integriert. Thermokarst und Thermoerosion haben die Untersuchungsregion tiefgreifend geprägt. Im Eiskomplexgebiet des Lena-Deltas nehmen Thermokarstsenken eine weitaus größere Fläche ein als Thermokarstseen auf Yedoma-Hochflächen (20,0 bzw. 2,2 %), was darauf hin deutet, dass die Bedingungen für die Entwicklung von großflächigem Thermokarst in der Vergangenheit wesentlich günstiger waren als heute. Die Rekonstruktion der Entwicklung eines einzelnen Alas im Lena-Delta belegt eine andauernde Phase hoher Thermokarstaktivität seit dem Übergang vom Pleistozän zum Holozän, die zur Entstehung einer großen und tiefen Senke führte. Nach der Drainage des primären Thermokarstsees im mittleren Holozän erfolgten Permafrostaggradation und degradation parallel und in kürzeren abwechselnden Etappen innerhalb des Alas und führten zu einer komplexen Thermokarstlandschaft. Trotzdem die spätholozäne Thermokarstentwicklung im Alas dynamischer ablief als die erste Entwicklungsphase, resultierte sie nicht in der Degradation großer Teile pleistozäner Eiskomplexablagerungen und einer wesentlichen Veränderung des Yedoma-Reliefs. Weitere Thermokarstentwicklung in bestehenden Alassen ist begrenzt auf geringmächtige Lagen holozäner eisreicher Alas-Sedimente, da die Eiskomplexablagerungen unter den großen primären Thermokarstseen vollständig getaut waren und die unterlagernden Sedimente aus eisarmen, fluvialen Sanden bestehen. Thermokarstprozesse auf ungestörten Yedoma-Hochflächen wirken am stärksten verändernd auf Eiskomplexablagerungen, werden aber in Zukunft auf geringere Ausmaße begrenzt sein, da die Verfügbarkeit großer ungestörter, schwach drainierter Yedoma-Hochflächen abnimmt. Auf der Insel Kurungnakh im zentralen Lena-Delta beträgt der für zukünftige Thermokarstentwicklung verfügbare Anteil an Yedoma-Hochflächen nur 33,7 %. Die zunehmende Nähe von sich entwickelnden Thermokarstseen auf Yedoma-Hochflächen zu bestehenden Degradationsstrukturen und anderen negativen Reliefformen verringert die Möglichkeit der Thermokarstseen, große Ausmaße zu erreichen bevor sie drainieren. Die Drainage von Thermokarstseen durch Thermoerosion ist in der Untersuchungsregion weit verbreitet, aber Thermoerosionstäler versorgen Thermokarstseen und –senken auch mit Wasser. Neben diesen direkten hydrologischen Wechselwirkungen zwischen Thermokarst und Thermoerosion auf der lokalen Ebene existiert auch eine Interdependenz zwischen beiden Prozessen auf der regionalen Ebene. Eine regionale Analyse weitreichender Netze von Thermoerosionstälern in drei Tieflandgebieten der Laptewsee mit einer Fläche von insgesamt 5800 km² zeigte, dass diese Formen häufiger in Gebieten mit höheren Geländeneigungen und Reliefgradienten auftreten, während Thermokarstentwicklung stärker in flachen Tiefländern mit geringeren Reliefgradienten ausgeprägt ist. Die kombinierten Ergebnisse dieser Dissertation zeigen die Notwendigkeit von umfassenden Analysen beider Prozesse und Landschaftsformen, Thermokarst und Thermoerosion, im Hinblick auf die Abschätzung vergangener und zukünftiger Auswirkungen der Degradation eisreichen Permafrosts auf Hydrologie und Klima der betrachteten Region und deren Rückkopplungen. KW - Fernerkundung KW - GIS KW - räumliche Analyse KW - periglaziale Landschaften KW - Arktis KW - remote sensing KW - GIS KW - spatial analyses KW - periglacial landscapes KW - Arctic Y1 - 2012 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-62079 ER - TY - THES A1 - Mucic, Nenad T1 - Thermodynamics, kinetics and rheology of surfactant adsorption layers at water/oil interfaces Y1 - 2012 CY - Potsdam ER -