TY - JOUR A1 - Busch, Jan Philip A1 - Meissner, Tobias A1 - Potthoff, Annegret A1 - Oswald, Sascha T1 - Investigations on mobility of carbon colloid supported nanoscale zero-valent iron (nZVI) in a column experiment and a laboratory 2D-aquifer test system JF - Environmental science and pollution research : official organ of the EuCheMS Division for Chemistry and the Environment, EuCheMS DCE N2 - Nanoscale zero-valent iron (nZVI) has recently gained great interest in the scientific community as in situ reagent for installation of permeable reactive barriers in aquifer systems, since nZVI is highly reactive with chlorinated compounds and may render them to harmless substances. However, nZVI has a high tendency to agglomerate and sediment; therefore it shows very limited transport ranges. One new approach to overcome the limited transport of nZVI in porous media is using a suited carrier colloid. In this study we tested mobility of a carbon colloid supported nZVI particle "Carbo-Iron Colloids" (CIC) with a mean size of 0.63 mu m in a column experiment of 40 cm length and an experiment in a two-dimensional (2D) aquifer test system with dimensions of 110x40x5 cm. Results show a breakthrough maximum of 82 % of the input concentration in the column experiment and 58 % in the 2D-aquifer test system. Detected residuals in porous media suggest a strong particle deposition in the first centimeters and few depositions in the porous media in the further travel path. Overall, this suggests a high mobility in porous media which might be a significant enhancement compared to bare or polyanionic stabilized nZVI. KW - Carbon colloid KW - Nanoscale zero-valent iron (nZVI) KW - Aquifer systems Y1 - 2014 U6 - https://doi.org/10.1007/s11356-014-3049-7 SN - 0944-1344 SN - 1614-7499 VL - 21 IS - 18 SP - 10908 EP - 10916 PB - Springer CY - Heidelberg ER - TY - JOUR A1 - Böttcher, Steven A1 - Merz, Christoph A1 - Lischeid, Gunnar A1 - Dannowski, Ralf T1 - Using Isomap to differentiate between anthropogenic and natural effects on groundwater dynamics in a complex geological setting JF - Journal of hydrology N2 - Due to increasing demands and competition for high quality groundwater resources in many parts of the world, there is an urgent need for efficient methods that shed light on the interplay between complex natural settings and anthropogenic impacts. Thus a new approach is introduced, that aims to identify and quantify the predominant processes or factors of influence that drive groundwater and lake water dynamics on a catchment scale. The approach involves a non-linear dimension reduction method called Isometric feature mapping (Isomap). This method is applied to time series of groundwater head and lake water level data from a complex geological setting in Northeastern Germany. Two factors explaining more than 95% of the observed spatial variations are identified: (1) the anthropogenic impact of a waterworks in the study area and (2) natural groundwater recharge with different degrees of dampening at the respective sites of observation. The approach enables a presumption-free assessment to be made of the existing geological conception in the catchment, leading to an extension of the conception. Previously unknown hydraulic connections between two aquifers are identified, and connections revealed between surface water bodies and groundwater. (C) 2014 Elsevier B.V. All rights reserved. KW - Groundwater KW - Lake KW - Interaction KW - Isometric feature mapping KW - Time series analysis Y1 - 2014 U6 - https://doi.org/10.1016/j.jhydrol.2014.09.048 SN - 0022-1694 SN - 1879-2707 VL - 519 SP - 1634 EP - 1641 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Bürger, Gerd A1 - Heistermann, Maik A1 - Bronstert, Axel T1 - Towards subdaily rainfall disaggregation via Clausius-Clapeyron JF - Journal of hydrometeorology N2 - Two lines of research are combined in this study: first, the development of tools for the temporal disaggregation of precipitation, and second, some newer results on the exponential scaling of heavy short-term precipitation with temperature, roughly following the Clausius-Clapeyron (CC) relation. Having no extra temperature dependence, the traditional disaggregation schemes are shown to lack the crucial CC-type temperature dependence. The authors introduce a proof-of-concept adjustment of an existing disaggregation tool, the multiplicative cascade model of Olsson, and show that, in principal, it is possible to include temperature dependence in the disaggregation step, resulting in a fairly realistic temperature dependence of the CC type. They conclude by outlining the main calibration steps necessary to develop a full-fledged CC disaggregation scheme and discuss possible applications. Y1 - 2014 U6 - https://doi.org/10.1175/JHM-D-13-0161.1 SN - 1525-755X SN - 1525-7541 VL - 15 IS - 3 SP - 1303 EP - 1311 PB - American Meteorological Soc. CY - Boston ER - TY - THES A1 - Cao, Xianyong T1 - Vegetation and climate change in eastern continental Asia during the last 22 ka inferred from pollen data synthesis Y1 - 2014 ER - TY - JOUR A1 - Cao, Xianyong A1 - Herzschuh, Ulrike A1 - Telford, Richard J. A1 - Ni, Jian T1 - A modern pollen-climate dataset from China and Mongolia: assessing its potential for climate reconstruction JF - Review of palaeobotany and palynology : an international journal N2 - A modern pollen dataset from China and Mongolia (18-52 degrees N, 74-132 degrees E) is investigated for its potential use in climate reconstructions. The dataset includes 2559 samples, 229 terrestrial pollen taxa and four climatic variables - mean annual precipitation (P-ann): 35-2091 mm, mean annual temperature (T-ann): -12.1-25.8 degrees C, mean temperature in the coldest month (Mt(co).): -33.8-21.7 degrees C, and mean temperature in the warmest month (Mt(wa)): 03-29.8 degrees C. Modern pollen-climate relationships are assessed using canonical correspondence analysis (CCA), Huisman-Olff-Fresco (HOF) models, the modern analogue technique (MAT), and weighted averaging partial least squares (WA-PLS). Results indicate that P-ann is the most important climatic determinant of pollen distribution and the most promising climate variable for reconstructions, as assessed by the coefficient of determination between observed and predicted environmental values (r(2)) and root mean square error of prediction (RMSEP). Mt(co) and Mt(wa) may be reconstructed too, but with caution. Samples from different depositional environments influence the performance of cross-validation differently, with samples from lake sediment-surfaces and moss polsters having the best fit with the lowest RMSEP. The better model performances of MAT are most probably caused by spatial autocorrelation. Accordingly, the WA-PLS models of this dataset are deemed most suitable for reconstructing past climate quantitatively because of their more reliable predictive power. (C) 2014 Elsevier B.V. All rights reserved. KW - Calibration KW - Huisman-Olff-Fresco models KW - MAT KW - Pollen-climate transfer function KW - Spatial autocorrelation KW - WA-PLS Y1 - 2014 U6 - https://doi.org/10.1016/j.revpalbo.2014.08.007 SN - 0034-6667 SN - 1879-0615 VL - 211 SP - 87 EP - 96 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Carrapa, Barbara A1 - Mustapha, Fariq Shazanee A1 - Cosca, Michael A1 - Gehrels, George A1 - Schoenbohm, Lindsay M. A1 - Sobel, Edward A1 - DeCelles, Peter G. A1 - Russell, Joellen A1 - Goodman, Paul T1 - Multisystem dating of modern river detritus from Tajikistan and China: Implications for crustal evolution and exhumation of the Pamir JF - Lithosphere N2 - The Pamir is the western continuation of Tibet and the site of some of the highest mountains on Earth, yet comparatively little is known about its crustal and tectonic evolution and erosional history. Both Tibet and the Pamir are characterized by similar terranes and sutures that can be correlated along strike, although the details of such correlations remain controversial. The erosional history of the Pamir with respect to Tibet is significantly different as well: Most of Tibet has been characterized by internal drainage and low erosion rates since the early Cenozoic; in contrast, the Pamir is externally drained and topographically more rugged, and it has a strongly asymmetric drainage pattern. Here, we report 700 new U-Pb and Lu-Hf isotope determinations and >300 Ar-40/Ar-39 ages from detrital minerals derived from rivers in China draining the northeastern Pamir and >1000 apatite fission-track (AFT) ages from 12 rivers in Tajikistan and China draining the northeastern, central, and southern Pamir. U-Pb ages from rivers draining the northeastern Pamir are Mesozoic to Proterozoic and show affinity with the Songpan-Ganzi terrane of northern Tibet, whereas rivers draining the central and southern Pamir are mainly Mesozoic and show some affinity with the Qiangtang terrane of central Tibet. The epsilon(Hf) values are juvenile, between 15 and -5, for the northeastern Pamir and juvenile to moderately evolved, between 10 and -40, for the central and southern Pamir. Detrital mica Ar-40/Ar-39 ages for the northeastern Pamir (eastern drainages) are generally older than ages from the central and southern Pamir (western drainages), indicating younger or lower-magnitude exhumation of the northeastern Pamir compared to the central and southern Pamir. AFT data show strong Miocene-Pliocene signals at the orogen scale, indicating rapid erosion at the regional scale. Despite localized exhumation of the Mustagh-Ata and Kongur-Shan domes, average erosion rates for the northeastern Pamir are up to one order of magnitude lower than erosion rates recorded by the central and southern Pamir. Deeper exhumation of the central and southern Pamir is associated with tectonic exhumation of central Pamir domes. Deeper exhumation coincides with western and asymmetric drainages and with higher precipitation today, suggesting an orographic effect on exhumation. A younging-southward trend of cooling ages may reflect tectonic processes. Overall, cooling ages derived from the Pamir are younger than ages recorded in Tibet, indicating younger and higher magnitudes of erosion in the Pamir. Y1 - 2014 U6 - https://doi.org/10.1130/L360.1 SN - 1941-8264 SN - 1947-4253 VL - 6 IS - 6 SP - 443 EP - 455 PB - Geological Society of America CY - Boulder ER - TY - JOUR A1 - Carrapa, Barbara A1 - Reyes-Bywater, Sharon A1 - Safipour, Roxana A1 - Sobel, Edward A1 - Schoenbohm, Lindsay M. A1 - DeCelles, Peter G. A1 - Reiners, Peter W. A1 - Stockli, Daniel T1 - The effect of inherited paleotopography on exhumation of the Central Andes of NW Argentina JF - Geological Society of America bulletin N2 - Differential exhumation in the Puna Plateau and Eastern Cordillera of NW Argentina is controlled by inherited paleostructures and resulting paleotopography related to the Cretaceous Salta Rift paleomargins. The Ceno zoic deformation front related to the development of the Andean retro-arc orogenic system is generally associated with >4 km of exhumation, which is recorded by Cenozoic apatite fi ssion-track (AFT) and (U-Th-[Sm])/He ages (He ages) in the Eastern Cordillera of NW Argentina. New AFT ages from the top of the Nevado de Cachi document Oligocene (ca. 28 Ma) cooling, which, combined with existing data, indicates exhumation of this range between ca. 28 Ma and ca. 14 Ma. However, some of the highest ranges in the Eastern Cordillera preserve Cretaceous ages indicative of limited Cenozoic exhumation. Samples collected from an similar to 3-km-elevation transect along the northern part of the Sierra de Quilmes paleorift fl ank (Laguna Brava) show AFT ages between ca. 80 and ca. 50 Ma and He ages between ca. 45 and ca. 10 Ma. Another set of samples from an similar to 1-km-elevation transect farther to the southwest (La Quebrada) shows Cretaceous AFT ages between ca. 116 Ma and ca. 76 Ma, and mainly Cretaceous He ages, in agreement with AFT data. Analysis of existing AFT and He ages from the area once occupied by the Salta Rift reveals a pattern characterized by Cretaceous ages along paleorift highs and Cenozoic ages within paleorift hanging-wall basins and later foreland basin depocenters. This pattern is interrupted by the Sierras Pampeanas at similar to 28 degrees S, which record mid-Cenozoic ages. Our data are consistent with a complex inherited pattern of pre-Andean paleostructures, likely associated with paleotopography, which was beveled by the Cenozoic regional foreland basin and reactivated during the late Neogene (ca. <10 Ma), strongly controlling the magnitude of Cenozoic uplift and exhumation and thus cooling age distribution. This, combined with variable lithologic erodibility, resulted in an irregular distribution of themochronological ages. Y1 - 2014 U6 - https://doi.org/10.1130/B30844.1 SN - 0016-7606 SN - 1943-2674 VL - 126 IS - 1-2 SP - 66 EP - 77 PB - American Institute of Physics CY - Boulder ER - TY - JOUR A1 - Cesca, Simone A1 - Grigoli, Francesco A1 - Heimann, Sebastian A1 - Gonzalez, Alvaro A1 - Buforn, Elisa A1 - Maghsoudi, Samira A1 - Blanch, Estefania A1 - Dahm, Torsten T1 - The 2013 September-October seismic sequence offshore Spain: a case of seismicity triggered by gas injection? JF - Geophysical journal international N2 - A spatially localized seismic sequence originated few tens of kilometres offshore the Mediterranean coast of Spain, close to the Ebro river delta, starting on 2013 September 5, and lasting at least until 2013 October. The sequence culminated in a maximal moment magnitude M-w 4.3 earthquake, on 2013 October 1. The most relevant seismogenic feature in the area is the Fosa de Amposta fault system, which includes different strands mapped at different distances to the coast, with a general NE-SW orientation, roughly parallel to the coastline. However, no significant known historical seismicity has involved this fault system in the past. The epicentral region is also located near the offshore platform of the Castor project, where gas is conducted through a pipeline from mainland and where it was recently injected in a depleted oil reservoir, at about 2 km depth. We analyse the temporal evolution of the seismic sequence and use full waveform techniques to derive absolute and relative locations, estimate depths and focal mechanisms for the largest events in the sequence (with magnitude mbLg larger than 3), and compare them to a previous event (2012 April 8, mbLg 3.3) taking place in the same region prior to the gas injection. Moment tensor inversion results show that the overall seismicity in this sequence is characterized by oblique mechanisms with a normal fault component, with a 30A degrees low-dip angle plane oriented NNE-SSW and a subvertical plane oriented NW-SE. The combined analysis of hypocentral location and focal mechanisms could indicate that the seismic sequence corresponds to rupture processes along shallow low-dip surfaces, which could have been triggered by the gas injection in the reservoir, and excludes the activation of the Amposta fault, as its known orientation is inconsistent with focal mechanism results. An alternative scenario includes the iterated triggering of a system of steep faults oriented NW-SE, which were identified by prior marine seismics investigations. KW - Earthquake dynamics KW - Earthquake source observations Y1 - 2014 U6 - https://doi.org/10.1093/gji/ggu172 SN - 0956-540X SN - 1365-246X VL - 198 IS - 2 SP - 941 EP - 953 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Cesca, Simone A1 - Sen, Ali Tolga A1 - Dahm, Torsten T1 - Seismicity monitoring by cluster analysis of moment tensors JF - Geophysical journal international N2 - We suggest a new clustering approach to classify focal mechanisms from large moment tensor catalogues, with the purpose of automatically identify families of earthquakes with similar source geometry, recognize the orientation of most active faults, and detect temporal variations of the rupture processes. The approach differs in comparison to waveform similarity methods since clusters are detected even if they occur in large spatial distances. This approach is particularly helpful to analyse large moment tensor catalogues, as in microseismicity applications, where a manual analysis and classification is not feasible. A flexible algorithm is here proposed: it can handle different metrics, norms, and focal mechanism representations. In particular, the method can handle full moment tensor or constrained source model catalogues, for which different metrics are suggested. The method can account for variable uncertainties of different moment tensor components. We verify the method with synthetic catalogues. An application to real data from mining induced seismicity illustrates possible applications of the method and demonstrate the cluster detection and event classification performance with different moment tensor catalogues. Results proof that main earthquake source types occur on spatially separated faults, and that temporal changes in the number and characterization of focal mechanism clusters are detected. We suggest that moment tensor clustering can help assessing time dependent hazard in mines. KW - Persistence KW - memory KW - correlations KW - clustering KW - Earthquake source observations Y1 - 2014 U6 - https://doi.org/10.1093/gji/ggt492 SN - 0956-540X SN - 1365-246X VL - 196 IS - 3 SP - 1813 EP - 1826 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Craddock, William H. A1 - Kirby, Eric A1 - Zhang, Huiping A1 - Clark, Marin K. A1 - Champagnac, Jean-Daniel A1 - Yuan, Daoyang T1 - Rates and style of Cenozoic deformation around the Gonghe Basin, northeastern Tibetan Plateau JF - Geosphere N2 - The northeastern Tibetan Plateau constitutes a transitional region between the low-relief physiographic plateau to the south and the high-relief ranges of the Qilian Shan to the north. Cenozoic deformation across this margin of the plateau is associated with localized growth of fault-cored mountain ranges and associated basins. Herein, we combine detailed structural analysis of the geometry of range-bounding faults and deformation of foreland basin strata with geomorphic and exhumational records of erosion in hangingwall ranges in order to investigate the magnitude, timing, and style of deformation along the two primary fault systems, the Qinghai Nan Shan and the Gonghe Nan Shan. Structural mapping shows that both ranges have developed above imbricate fans of listric thrust faults, which sole into decollements in the middle crust. Restoration of shortening along balanced cross sections suggests a minimum of 0.8-2.2 km and 5.1-6.9 km of shortening, respectively. Growth strata in the associated foreland basin record the onset of deformation on the two fault systems at ca. 6-10 Ma and ca. 7-10 Ma, respectively, and thus our analysis suggests late Cenozoic shortening rates of 0.2 +0.2/-0.1 km/m.y. and 0.7 +0.3/-0.2 km/m.y. along the north and south sides of Gonghe Basin. Along the Qinghai Nan Shan, these rates are similar to late Pleistocene slip rates of similar to 0.10 +/- 0.04 mm/yr, derived from restoration and dating of a deformed alluvial-fan surface. Collectively, our results imply that deformation along both flanks of the doubly vergent Qilian Shan-Nan Shan initiated by ca. 10 Ma and that subsequent shortening has been relatively steady since that time. Y1 - 2014 U6 - https://doi.org/10.1130/GES01024.1 SN - 1553-040X VL - 10 IS - 6 SP - 1255 EP - 1282 PB - Geological Society of America CY - Boulder ER -