TY - JOUR A1 - Baier, Heiko A1 - Kelling, Alexandra A1 - Jackstell, Ralf A1 - Holdt, Hans-Jürgen T1 - Rhodium(I) and Silver(I) Complexes of 4,5-Dicyano-1,3-dimesityl- and 4,5-Dicyano-1,3-dineopentylimidazol-2-ylidene JF - Zeitschrift für anorganische und allgemeine Chemie N2 - The new N-heterocyclic carbene (NHC) precursors 4,5-dicyano-1, -dimesityl- (9) and 4, 5-dicyano-1, 3-dineopentyl-2-(pentafluorophenyl)imidazoline (14) were synthesized. 9 could be determined by X-ray crystallography. With the 2-pentafluorophenyl-substituted imidazolines 9 and 14, the [AgCl(NHC)], [RhCl(COD)(NHC)], and [RhCl(CO)(2)(NHC)] complexes [NHC = 4, 5-dicyano-1, 3-dimesitylimidazol-2-ylidene (3) and 4, 5-dicyano-1, 3-dineopentylimidazol-2-ylidene (4)] were obtained. Crystal structures of [AgCl(3)] (15), [RhCl(COD)(3)] (17), [RhCl(COD)(4)] (18), and [RhCl(CO)(2)(3)] (19) were solved and with the crystal data of 19, the percent buried volume (%V-bur) of 31.8(+/- 0.1)% was determined for NHC 3. Infrared spectra of the imidazolines 9 and 14 and of the complexes 15-20 were recorded and the CO stretching frequencies of complexes 19 and 20 were used to determine the 3 ( (-1)) and 4 ( (-1)), thus proving that 1, 3-substitution of maleonitrile-NHCs does not have a significant effect for the high -acceptor strength of these carbenes. KW - Carbenes KW - Rhodium KW - Silver KW - Crystal structure KW - Diaminomaleonitrile Y1 - 2013 U6 - https://doi.org/10.1002/zaac.201300250 SN - 0044-2313 SN - 1521-3749 VL - 639 IS - 10 SP - 1731 EP - 1739 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Bailleul, Frederic A1 - Grimm, Volker A1 - Chion, Clement A1 - Hammill, Mike T1 - Modeling implications of food resource aggregation on animal migration phenology JF - Ecology and evolution N2 - The distribution of poikilotherms is determined by the thermal structure of the marine environment that they are exposed to. Recent research has indicated that changes in migration phenology of beluga whales in the Arctic are triggered by changes in the thermal structure of the marine environment in their summering area. If sea temperatures reflect the spatial distribution of food resources, then changes in the thermal regime will affect how homogeneous or clumped food is distributed. We explore, by individual-based modelling, the hypothesis that changes in migration phenology are not necessarily or exclusively triggered by changes in food abundance, but also by changes in the spatial aggregation of food. We found that the level of food aggregation can significantly affect the relationship between the timing of the start of migration to the winter grounds and the total prey capture of individuals. Our approach strongly indicates that changes in the spatial distribution of food resources should be considered for understanding and quantitatively predicting changes in the phenology of animal migration. KW - Animal migration KW - food structuring KW - global change KW - individual-based model KW - polar environment Y1 - 2013 U6 - https://doi.org/10.1002/ece3.656 SN - 2045-7758 VL - 3 IS - 8 SP - 2535 EP - 2546 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Baillot, Anne T1 - Kommunikation Y1 - 2013 SN - 978-3-8353-1255-5 ER - TY - JOUR A1 - Balderjahn, Ingo A1 - Buerke, Anja A1 - Kirchgeorg, Manfred A1 - Peyer, Mathias A1 - Seegebarth, Barbara A1 - Wiedmann, Klaus-Peter T1 - Consciousness for sustainable consumption : scale development and new insights in the economic dimension of consumers’ sustainability JF - AMS review : official publication of the Academy of Marketing Scienc N2 - The “triple bottom line” concept (planet, people, and profit) represents an important guideline for the sustainable, hence future-oriented, development of societies and for the behaviors of all societal members. For institutions promoting societal change, as well as for companies being confronted with growing expectations regarding compelling contributions to sustainable changes, it is of great importance to know if, and to what extent, consumers have already internalized the idea of sustainability. Against the background of existing research gaps regarding a comprehensive measurement of the consciousness for sustainable consumption (CSC), the authors present the result of a scale development. Consciousness was operationalized by weighting personal beliefs with the importance attached by consumers to sustainability dimensions. Four separate tests of the CSC scale indicated an appropriate psychometric quality of the scale and provided support for this new measurement approach that incorporates the environmental, social and economic dimensions of sustainability. KW - Sustainability KW - Consciousness for sustainable consumption KW - Scale development Y1 - 2013 U6 - https://doi.org/10.1007/s13162-013-0057-6 SN - 1869-814X SN - 1869-8182 VL - 3 IS - 4 SP - 181 EP - 192 PB - Springer CY - New York ER - TY - JOUR A1 - Balderjahn, Ingo A1 - Peyer, Mathias A1 - Paulssen, Marcel T1 - Consciousness for fair consumption : conceptualization, scale development and empirical validation JF - International Journal of Consumer Studies N2 - Sustainable consumption means that consumers act in an environmentally and socially responsible manner. Compared with the vast amount of studies concerning environmentally conscious consumer behaviour, relatively little is known about socially conscious consumption. The present paper focuses on fair consumption as an important aspect of social consumption. In our study, consciousness for fair consumption (CFC) is defined as a latent disposition of consumers to prefer products that are produced and traded in compliance with fair labour and business practices. A scale to measure CFC was conceptualized and tested in three independent empirical studies. Two studies were conducted at European universities (2010 and 2012) and used 352 and 362 undergraduate business students respectively. The third study, conducted in 2011, used 141 employees at a European university. The results confirmed the reliability and validity of the new CFC scale across samples. While being moderately related to other aspects of sustainable consumption such as ecological concern and moral reasoning, CFC was significantly distinct from those concepts. Most importantly, it was established that the CFC, as measured by the new CFC scale, is a strong determinant of consumption of fair trade products that has been neglected in existing research. Y1 - 2013 U6 - https://doi.org/10.1111/ijcs.12030 SN - 1470-6431 SN - 1470-6423 VL - 37 IS - 5 SP - 546 EP - 555 PB - Wiley-Blackwell CY - Oxford ER - TY - JOUR A1 - Balderjahn, Ingo A1 - Peyer, Mathias A1 - Paulssen, Marcel T1 - Consciousness for fair consumption - conceptualization, scale development and empirical validation JF - International journal of consumer studies N2 - Sustainable consumption means that consumers act in an environmentally and socially responsible manner. Compared with the vast amount of studies concerning environmentally conscious consumer behaviour, relatively little is known about socially conscious consumption. The present paper focuses on fair consumption as an important aspect of social consumption. In our study, consciousness for fair consumption (CFC) is defined as a latent disposition of consumers to prefer products that are produced and traded in compliance with fair labour and business practices. A scale to measure CFC was conceptualized and tested in three independent empirical studies. Two studies were conducted at European universities (2010 and 2012) and used 352 and 362 undergraduate business students respectively. The third study, conducted in 2011, used 141 employees at a European university. The results confirmed the reliability and validity of the new CFC scale across samples. While being moderately related to other aspects of sustainable consumption such as ecological concern and moral reasoning, CFC was significantly distinct from those concepts. Most importantly, it was established that the CFC, as measured by the new CFC scale, is a strong determinant of consumption of fair trade products that has been neglected in existing research. KW - Sustainable consumption KW - socially conscious consumption KW - consciousness for fair consumption KW - scale development KW - fair trade Y1 - 2013 U6 - https://doi.org/10.1111/ijcs.12030 SN - 1470-6423 VL - 37 IS - 5 SP - 546 EP - 555 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Balderjahn, Ingo A1 - Silbermann, Alexandra T1 - Die Rolle der Selbstaufmerksamkeit beim Bewusstsein für einen gesunden Konsum : Überblick und Konzeptentwicklung JF - International Journal of Marketing : IJM Y1 - 2013 SN - 2306-7217 VL - 52 IS - 1 SP - 37 EP - 48 PB - Verlag Österreich CY - Wien ER - TY - JOUR A1 - Ballato, Paolo A1 - Stockli, Daniel F. A1 - Ghassemi, Mohammad R. A1 - Landgraf, Angela A1 - Strecker, Manfred A1 - Hassanzadeh, Jamshid A1 - Friedrich, Anke M. A1 - Tabatabaei, Saeid H. T1 - Accommodation of transpressional strain in the Arabia-Eurasia collision zone new constraints from (U-Th)/He thermochronology in the Alborz mountains, north Iran JF - Tectonics N2 - The Alborz range of N Iran provides key information on the spatiotemporal evolution and characteristics of the Arabia-Eurasia continental collision zone. The southwestern Alborz range constitutes a transpressional duplex, which accommodates oblique shortening between Central Iran and the South Caspian Basin. The duplex comprises NW-striking frontal ramps that are kinematically linked to inherited E-W-striking, right-stepping lateral to obliquely oriented ramps. New zircon and apatite (U-Th)/He data provide a high-resolution framework to unravel the evolution of collisional tectonics in this region. Our data record two pulses of fast cooling associated with SW-directed thrusting across the frontal ramps at similar to 18-14 and 9.5-7.5 Ma, resulting in the tectonic repetition of a fossil zircon partial retention zone and a cooling pattern with a half U-shaped geometry. Uniform cooling ages of similar to 7-6 Ma along the southernmost E-W striking oblique ramp and across its associated NW-striking frontal ramps suggests that the ramp was reactivated as a master throughgoing, N-dipping thrust. We interpret this major change in fault kinematics and deformation style to be related to a change in the shortening direction from NE to N/NNE. The reduction in the obliquity of thrusting may indicate the termination of strike-slip faulting (and possibly thrusting) across the Iranian Plateau, which could have been triggered by an increase in elevation. Furthermore, we suggest that similar to 7-6-m.y.-old S-directed thrusting predated inception of the westward motion of the South Caspian Basin. Citation: Ballato, P., D. F. Stockli, M. R. Ghassemi, A. Landgraf, M. R. Strecker, J. Hassanzadeh, A. Friedrich, and S. H. Tabatabaei (2012), Accommodation of transpressional strain in the Arabia-Eurasia collision zone: new constraints from (U-Th)/He thermochronology in the Alborz mountains. Y1 - 2013 U6 - https://doi.org/10.1029/2012TC003159 SN - 0278-7407 VL - 32 IS - 1 SP - 1 EP - 18 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Balling, Philipp A1 - Maystrenko, Yuriy A1 - Scheck-Wenderoth, Magdalena T1 - The deep thermal field of the Glückstadt Graben JF - Environmental earth sciences N2 - With this paper, we assess the present-day conductive thermal field of the Glueckstadt Graben in NW Germany that is characterized by large salt walls and diapirs structuring the graben fill. We use a finite element method to calculate the 3D steady-state conductive thermal field based on a lithosphere-scale 3D structural model that resolves the first-order structural characteristics of the graben and its underlying lithosphere. Model predictions are validated against measured temperatures in six deep wells. Our investigations show that the interaction of thickness distributions and thermal rock properties of the different geological layers is of major importance for the distribution of temperatures in the deep subsurface of the Glueckstadt Graben. However, the local temperatures may result from the superposed effects of different controlling factors. Especially, the upper sedimentary part of the model exhibits huge lateral temperature variations, which correlate spatially with the shape of the thermally highly conductive Permian salt layer. Variations in thickness and geometry of the salt cause two major effects, which provoke considerable lateral temperature variations for a given depth. (1) The "chimney effect" causes more efficient heat transport within salt diapirs. As a consequence positive thermal anomalies develop in the upper part and above salt structures, where the latter are covered by much less conductive sediments. In contrast, negative thermal anomalies are noticeable underneath salt structures. (2) The "thermal blanketing effect" is caused by thermally low conductive sediments that provoke the local storage of heat where these insulating sediments are present. The latter effect leads to both local and regional thermal anomalies. Locally, this translates to higher temperatures where salt margin synclines are filled with thick insulating clastic sediments. For the regional anomalies the cumulative insulating effects of the entire sediment fill results in a long-wavelength variation of temperatures in response to heat refraction effects caused by the contrast between insulating sediments and highly conductive crystalline crust. Finally, the longest wavelength of temperature variations is caused by the depth position of the isothermal lithosphere-asthenosphere boundary defining the regional variations of the overall geothermal gradient. We find that a conductive thermal model predicts observed temperatures reasonably well for five of the six available wells, whereas the steady-state conductive approach appears not to be valid for the sixth well. KW - Conductive thermal field KW - 3D thermal modelling KW - Zechstein salt KW - Lithosphereasthenosphere boundary KW - Schleswig-Holstein KW - Glueckstadtgraben Y1 - 2013 U6 - https://doi.org/10.1007/s12665-013-2750-z SN - 1866-6280 SN - 1866-6299 VL - 70 IS - 8 SP - 3505 EP - 3522 PB - Springer CY - New York ER - TY - JOUR A1 - Banbara, Mutsunori A1 - Soh, Takehide A1 - Tamura, Naoyuki A1 - Inoue, Katsumi A1 - Schaub, Torsten H. T1 - Answer set programming as a modeling language for course timetabling JF - Theory and practice of logic programming N2 - The course timetabling problem can be generally defined as the task of assigning a number of lectures to a limited set of timeslots and rooms, subject to a given set of hard and soft constraints. The modeling language for course timetabling is required to be expressive enough to specify a wide variety of soft constraints and objective functions. Furthermore, the resulting encoding is required to be extensible for capturing new constraints and for switching them between hard and soft, and to be flexible enough to deal with different formulations. In this paper, we propose to make effective use of ASP as a modeling language for course timetabling. We show that our ASP-based approach can naturally satisfy the above requirements, through an ASP encoding of the curriculum-based course timetabling problem proposed in the third track of the second international timetabling competition (ITC-2007). Our encoding is compact and human-readable, since each constraint is individually expressed by either one or two rules. Each hard constraint is expressed by using integrity constraints and aggregates of ASP. Each soft constraint S is expressed by rules in which the head is the form of penalty (S, V, C), and a violation V and its penalty cost C are detected and calculated respectively in the body. We carried out experiments on four different benchmark sets with five different formulations. We succeeded either in improving the bounds or producing the same bounds for many combinations of problem instances and formulations, compared with the previous best known bounds. KW - answer set programming KW - educational timetabling KW - course timetabling Y1 - 2013 U6 - https://doi.org/10.1017/S1471068413000495 SN - 1471-0684 VL - 13 IS - 2 SP - 783 EP - 798 PB - Cambridge Univ. Press CY - New York ER -