TY  - GEN
A1  - Löhmannsröben, Hans-Gerd
A1  - Kantor, Zoltan
A1  - Kumke, Michael Uwe
A1  - Schmälzlin, Elmar
A1  - Reich, Oliver
T1  - OPQS – optische Prozess- und Qualitäts-Sensorik
N2  - Im vorliegenden Beitrag wird an Hand dreier Beispiele der Einsatz von optischer Sensorik zur Produktcharakterisierung dargestellt, nämlich Untersuchungen zum O2-Gehalt in Fruchtsäften, zur Isotopiesignatur von CO2 in Mineralwässern und zu Lichtstreueigenschaften eines Sonnenschutzmittels. Inhalt: Bestimmung von O2 mit Lumineszenzsonden Isotopenselektive Bestimmung von CO2 mit TDLAS Optische Charakterisierung stark streuender Materialien mit Photonendichtewellen
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 028 
KW  - Sensorik
KW  - Prozesskontrolle
KW  - Absorption
KW  - Lumineszenz
KW  - Lichtstreuung
KW  - Isotopie
Y1  - 2005
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13205
ER  - 
TY  - GEN
A1  - Dosche, Carsten
A1  - Kumke, Michael Uwe
A1  - Löhmannsröben, Hans-Gerd
A1  - Ariese, F.
A1  - Bader, Arjen N.
A1  - Gooijer, C.
A1  - Miljanic, O. S.
A1  - Iwamoto, M.
A1  - Vollhardt, K. Peter C.
A1  - Puchta, R. ; van Eikema Hommes, N. J. R.
T1  - Deuteration effects on the vibronic structure of the fluorescence spectra and the internal conversion rates of triangular [4]Phenylene
N2  - Deuteration effects on the vibronic structure of the emission and excitation spectra of triangular [4]phenylene (D3h[4]phenylene) were studied using laser-excited Shpolskii spectroscopy (LESS) in an octane matrix at 4.2 K. For correct assignment of the vibrational modes, the experimental results were compared with calculated frequencies (B3LYP/6-31G*). CH vibrations were identified by their characteristic isotopic shifts in the spectra of deuterated triangular [4]phenylenes. Two CC stretching modes, at 100 cm–1 and 1176 cm–1, suitable as probes for bond strength changes in the excited state, were identified. The isotope effect on the internal conversion rates of triangular [4]phenylene was evaluated from measurements of temperature dependent lifetime. Isotope dependency and the magnitude of the internal conversion rates indicate that internal conversion in triangular [4]phenylene is most likely induced by CH vibrations. The results obtained by LESS and lifetime measurements were compared with PM3 PECI calculations of the excited state structure. The theoretical results and the relation between ground and excited state vibration energies of the 1176 cm–1 probe vibration indicate a reduction of bond alternation of the central cyclohexatriene ring in the excited state.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 002 
Y1  - 2004
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-11881
ER  - 
TY  - GEN
A1  - Dosche, Carsten
A1  - Kumke, Michael Uwe
A1  - Ariese, F.
A1  - Bader, Arjen N.
A1  - Gooijer, C.
A1  - Dosa, P. I.
A1  - Han, S.
A1  - Miljanic, O. S.
A1  - Vollhardt, K. Peter C.
A1  - Puchta, R.
A1  - Eikema Hommes, N. J. R. van
T1  - Shpol’skii spectroscopy and vibrational analysis of [N]phenylenes
N2  - Vibrationally resolved fluorescence spectra of four angular [N]phenylenes were recorded with laser excited Shpol’skii spectroscopy (LESS) in an n-octane matrix at 10 K. In general, the same vibrational frequencies were observed in the fluorescence excitation and emission spectra, indicating that the geometries of ground and electronically excited state are very similar. Because of intensity borrowing from the S2 state, vibrations of two different symmetries were observed in the fluorescence excitation spectra of angular [3]phenylene and zig-zag[5]phenylene. This finding allowed the location of the S2 state for these compounds. DFT calculations(RB3LYP/6-31G*) of the ground state vibrational frequencies were made. The calculated vibrational modes were in reasonably good agreement with the experimental data. A new very low-frequency vibration of approximately 100 cm-1 was predicted and experimentally confirmed for all [N]phenylenes investigated. This vibration seems to be unique for [N]phenylenes and is attributed to an in-plane movement of the carbon backbone.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 024 
Y1  - 2003
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13075
ER  - 
TY  - GEN
A1  - Frimmel, Fritz Hartmann
A1  - Kumke, Michael Uwe
T1  - Optische Parameter zur Stoffcharakterisierung vom Trinkwasser bis zum Abwasser
N2  - Die Anwendung von optischen Parametern zur Stoffcharakterisierung wird diskutiert. Dabei ist der Schwerpunkt der Diskussion auf absorptions- und fluoreszenzspektroskopische Methoden gesetzt. Beide Methoden können schnell und zuverlässig – auch im on-line Betrieb – eingesetzt werden. Der Beitrag soll einen Überblick über die grundlegenden Möglichkeiten der Anwendung beider Methoden geben.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 025 
KW  - Absorptionsspektroskopie
KW  - SAK
KW  - Fluoreszenzspektroskopie
KW  - Summenparameter
KW  - Huminstoffe
KW  - polyzyklische aromatische Kohlenwasserstoffe
Y1  - 1998
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13088
ER  -