TY - GEN A1 - Mondal, Suvendu Sekhar A1 - Dey, Subarna A1 - Baburin, Igor A. A1 - Kelling, Alexandra A1 - Schilde, Uwe A1 - Seifert, Gotthard A1 - Janiak, Christoph A1 - Holdt, Hans-Jürgen T1 - Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal–organic frameworks with flexible ethoxy substituent N2 - A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 234 KW - adsorption KW - behavior KW - carbon-dioxide KW - crystals KW - gases KW - ligand KW - pressure KW - selectivity KW - temperature KW - zinc Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-94360 SP - 9394 EP - 9399 ER -