TY  - JOUR
A1  - Lood, Kajsa
A1  - Schmidt, Bernd
T1  - Stereoselective synthesis of conjugated polyenes based on tethered olefin metathesis and carbonyl olefination
BT  - application to the total synthesis of (+)-bretonin B
JF  - The journal of organic chemistry
N2  - The combination of a highly stereoselective tethered olefin metathesis reaction and a Julia-Kocienski olefination is presented as a strategy for the synthesis of conjugated polyenes with at least one Z-configured C=C bond. The strategy is exemplified by the synthesis of the marine natural product (+)-bretonin B.
KW  - absolute-configuration
KW  - natural-products
KW  - formal synthesis
KW  - oxidation
KW  - derivatives
KW  - aldehydes
KW  - catalysts
KW  - alcohols
KW  - sponge
KW  - ethers
Y1  - 2020
U6  - https://doi.org/10.1021/acs.joc.0c00446
SN  - 0022-3263
SN  - 1520-6904
VL  - 85
IS  - 7
SP  - 5122
EP  - 5130
PB  - American Chemical Society
CY  - Washington
ER  -