TY  - JOUR
A1  - Guillemoteau, Julien
A1  - Simon, Francois-Xavier
A1  - Hulin, Guillaume
A1  - Dousteyssier, Bertrand
A1  - Dacko, Marion
A1  - Tronicke, Jens
T1  - 3-D imaging of subsurface magnetic permeability/susceptibility with portable frequency domain electromagnetic sensors for near surface exploration
JF  - Geophysical journal international
N2  - The in-phase response collected by portable loop-loop electromagnetic induction (EMI) sensors operating at low and moderate induction numbers (<= 1) is typically used for sensing the magnetic permeability (or susceptibility) of the subsurface. This is due to the fact that the in-phase response contains a small induction fraction and a preponderant induced magnetization fraction. The magnetization fraction follows the magneto-static equations similarly to the magnetic method but with an active magnetic source. The use of an active source offers the possibility to collect data with several loop-loop configurations, which illuminate the subsurface with different sensitivity patterns. Such multiconfiguration soundings thereby allows the imaging of subsurface magnetic permeability/susceptibility variations through an inversion procedure. This method is not affected by the remnant magnetization and theoretically overcomes the classical depth ambiguity generally encountered with passive geomagnetic data. To invert multiconfiguration in-phase data sets, we propose a novel methodology based on a full-grid 3-D multichannel deconvolution (MCD) procedure. This method allows us to invert large data sets (e.g. consisting of more than a hundred thousand of data points) for a dense voxel-based 3-D model of magnetic susceptibility subject to smoothness constraints. In this study, we first present and discuss synthetic examples of our imaging procedure, which aim at simulating realistic conditions. Finally, we demonstrate the applicability of our method to field data collected across an archaeological site in Auvergne (France) to image the foundations of a Gallo-Roman villa built with basalt rock material. Our synthetic and field data examples demonstrate the potential of the proposed inversion procedure offering new and complementary ways to interpret data sets collected with modern EMI instruments.
KW  - Magnetic properties
KW  - Controlled source electromagnetics (CSEM)
KW  - Electromagnetic theory
KW  - Environmental magnetism
KW  - Inverse theory
Y1  - 2019
U6  - https://doi.org/10.1093/gji/ggz382
SN  - 0956-540X
SN  - 1365-246X
VL  - 219
IS  - 3
SP  - 1773
EP  - 1785
PB  - Oxford Univ. Press
CY  - Oxford
ER  - 
TY  - JOUR
A1  - Alrefai, Anas
A1  - Mondal, Suvendu Sekhar
A1  - Wruck, Alexander
A1  - Kelling, Alexandra
A1  - Schilde, Uwe
A1  - Brandt, Philipp
A1  - Janiak, Christoph
A1  - Schoenfeld, Sophie
A1  - Weber, Birgit
A1  - Rybakowski, Lawrence
A1  - Herrman, Carmen
A1  - Brennenstuhl, Katlen
A1  - Eidner, Sascha
A1  - Kumke, Michael Uwe
A1  - Behrens, Karsten
A1  - Günter, Christina
A1  - Müller, Holger
A1  - Holdt, Hans-Jürgen
T1  - Hydrogen-bonded supramolecular metal-imidazolate frameworks: gas sorption, magnetic and UV/Vis spectroscopic properties
JF  - Journal of Inclusion Phenomena and Macrocyclic Chemistry
N2  - By varying reaction parameters for the syntheses of the hydrogen-bonded metal-imidazolate frameworks (HIF) HIF-1 and HIF-2 (featuring 14 Zn and 14 Co atoms, respectively) to increase their yields and crystallinity, we found that HIF-1 is generated in two different frameworks, named as HIF-1a and HIF-1b. HIF-1b is isostructural to HIF-2. We determined the gas sorption and magnetic properties of HIF-2. In comparison to HIF-1a (Brunauer-Emmett-Teller (BET) surface area of 471m(2) g(-1)), HIF-2 possesses overall very low gas sorption uptake capacities [BET(CO2) surface area=85m(2) g(-1)]. Variable temperature magnetic susceptibility measurement of HIF-2 showed antiferromagnetic exchange interactions between the cobalt(II) high-spin centres at lower temperature. Theoretical analysis by density functional theory confirmed this finding. The UV/Vis-reflection spectra of HIF-1 (mixture of HIF-1a and b), HIF-2 and HIF-3 (with 14 Cd atoms) were measured and showed a characteristic absorption band centered at 340nm, which was indicative for differences in the imidazolate framework.
KW  - Gas-sorption
KW  - Ligand design
KW  - Magnetic properties
KW  - Supramolecular chemistry
KW  - Solvothermal synthesis
Y1  - 2019
U6  - https://doi.org/10.1007/s10847-019-00926-6
SN  - 1388-3127
SN  - 1573-1111
VL  - 94
IS  - 3-4
SP  - 155
EP  - 165
PB  - Springer
CY  - Dordrecht
ER  -