TY  - JOUR
A1  - Xie, Zai-Lai
A1  - Taubert, Andreas
T1  - Thermomorphic behavior of the ionic liquids [C(4)mim][FeCl4] and [C(12)mim][FeCl4]
JF  - ChemPhysChem : a European journal of chemical physics and physical chemistry
N2  - The iron-containing ionic liquids 1-butyl-3-methylimidazolium tetrachloroferrate(III) [C(4)mim][FeCl4] and 1-dodecyl-3-methylimidazolium tetrachloroferrate(III) [C(12)mim][FeCl4] exhibit a thermally induced demixing with water (thermomorphism). The phase separation temperature varies with IL weight fraction in water and can be tuned between 100 degrees C and room temperature. The reversible lower critical solution temperature (LCST) is only observed at IL weight fractions below ca. 35% in water. UV/Vis, IR, and Raman spectroscopy along with elemental analysis prove that the yellow-brown liquid phase recovered after phase separation is the starting IL [C(4)mim][FeCl4] and [C(12)mim][FeCl4], respectively. Photometry and ICP-OES show that about 40% of iron remains in the water phase upon phase separation. Although the process is thus not very efficient at the moment, the current approach is the first example of an LCST behavior of a metal-containing IL and therefore, although still inefficient, a prototype for catalyst removal or metal extraction.
KW  - imidazolium
KW  - ionic liquids
KW  - phase transitions
KW  - Raman spectroscopy
KW  - thermomorphism
Y1  - 2011
U6  - https://doi.org/10.1002/cphc.201000808
SN  - 1439-4235
VL  - 12
IS  - 2
SP  - 364
EP  - 368
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Douce, Laurent
A1  - Suisse, Jean-Moise
A1  - Guillon, Daniel
A1  - Taubert, Andreas
T1  - Imidazolium-based liquid crystals a modular platform for versatile new materials with finely tuneable properties and behaviour
JF  - Liquid crystals : an international journal of science and technology
N2  - Ionic liquid Crystals constitute highly versatile materials that have drawn much interest these past few years in the fields of academic research and industrial development. In this respect, the present article is intended as an update of K. Binnemans review published in 2005, but focusing exclusively on the imidazolium cation - the most widely studied. Herein, imidazolium-containing thermotropic liquid crystalline materials will be sorted by molecular structure (mono-, bis-, poly-imidazolium compounds, with symmetrical and non-symmetrical structures) and discussed. Their physico-chemical properties will be exposed in order to adduce the relevancy and potential of the imidazolium platform in various fields of research.
KW  - imidazolium
KW  - liquid crystal
KW  - ionic liquid
Y1  - 2011
U6  - https://doi.org/10.1080/02678292.2011.610474
SN  - 0267-8292
VL  - 38
IS  - 11-12
SP  - 1653
EP  - 1661
PB  - Routledge, Taylor & Francis Group
CY  - Abingdon
ER  -