TY  - JOUR
A1  - Hartmann, K.
A1  - Kim, Boo Geun
A1  - Linker, Torsten
T1  - Manganese(III)-mediated radical reactions in carbohydrate chemistry : a new route to 3-deoxy-D-manno-oct-2- ulosonic acid (KDO)
N2  - An acyclic alkene derived from a carbohydrate is employed as a substrate for manganese-mediated radical reactions for the first time. The addition of malonate is interesting for the mechanism of such reactions, whereas acetic acid as radical precursor affords lactones in excellent yield. The main diastereomer was easily separated and represents a key intermediate in the synthesis of KDO
Y1  - 2004
SN  - 0936-5214
ER  - 
TY  - THES
A1  - Kim, Boo Geun
T1  - Radikalische Additionen an ungesättigte Kohlenhydrate als Schlüsselschritt in der Synthese von Kohlenhydrat-C-Analoga
Y1  - 2006
CY  - Potsdam
ER  - 
TY  - JOUR
A1  - Kim, Boo Geun
A1  - Schilde, Uwe
A1  - Linker, Torsten
T1  - New radical approaches to 3-deoxy-D-oct-2-ulosonic acids (KDO)
N2  - Two different approaches. with an unsaturated carbohydrate as a radical acceptor and a carbohydrate derived aldehyde as a radical precursor, led to key intermediates in the synthesis of 3-deoxy-D-oct-2-ulosonic acids (KDO). Manganese(III) acetate and cerium(IV) ammonium nitrate were the reagents of choice for the oxidative generation of radicals, whereas samarium(II) iodide was employed for reductive couplings. Both strategies were realized by using easily available starting materials, with acetic acid as C-2 and ethyl acrylate as C-3 building blocks, respectively
Y1  - 2005
SN  - 0039-7881
ER  - 
TY  - JOUR
A1  - Peters, Karl
A1  - Peters, E. M.
A1  - Kim, Boo Geun
A1  - Linker, Torsten
T1  - Crystal structure of ethyl (3aR,4R,5R,6R,7aR)-4,5-diacetoxy-6-acetoxymethyl-2-oxy-3a,5,6,7a-tetrahy dro-4H- pyrano[3,2-d]isoxazole-3-carboxylate, C16H21NO11
N2  - C16H21NO11, monoclinic, P12(1)1 (no. 4), a = 8.181(1) angstrom, b = 11.604(2) angstrom, c = 10.193(1) angstrom, beta = 101.59(1)degrees, V = 947.9 angstrom(3), Z = 2, R-gt(F) = 0.068, wR(ref)(F-2) = 0.177, T = 293 K.
Y1  - 2005
SN  - 1433-7266
ER  - 
TY  - JOUR
A1  - Sommermann, T.
A1  - Kim, Boo Geun
A1  - Peters, Karl
A1  - Peters, E. M.
A1  - Linker, Torsten
T1  - Short and stereoselective synthesis of C-glycosylated glycine derivatives from glycals by radical addition and reduction
N2  - Only three steps are required for the convenient synthesis of 2-C-branched glyco-amino acids from glycals with good yields and stereoselectivities
Y1  - 2004
SN  - 1359-7345
ER  -