TY - JOUR A1 - Wang, Hao A1 - Wang, Xue-jiang A1 - Wang, Wei-shi A1 - Yan, Xiang-bo A1 - Xia, Peng A1 - Chen, Jie A1 - Zhao, Jian-fu T1 - Modeling and optimization of struvite recovery from wastewater and reusing for heavy metals immobilization in contaminated soil JF - Journal of chemical technology & biotechnology N2 - BACKROUND: Few studies have been carried out to connect nutrients recovery from wastewater and heavy metals immobilization in contaminated soil. To achieve the goal, ammonia nitrogen (AN) and phosphorus (P) were recovered from rare-earth wastewater by using the formation of struvite, which was used as the amendment with plant ash for copper, lead and chromium immobilization. RESULTS: AN removal efficiency and residual P reached 95.32 +/- 0.73% and 6.14 +/- 1.72mgL(-1) under optimal conditions: pH= 9.0, n(Mg): n(N): n(P)= 1.2: 1: 1.1, which were obtained using response surface methodology (RSM). The minimum available concentrations of Cu, Pb and Cr (CPC) separately reduced to 320.82 mg kg(-1), 190.77 mg kg(-1) and 121.46 mg kg(-1) with increasing immobilization time at the mass ratio of phosphate precipitate (PP)/plant ash (PA) of 1: 3. Humic acid (HA) and fulvic acid (FA) were beneficial to immobilize Cu, both of which showed no effect or even a negative effect on Pb and Cr immobilization. KW - precipitation KW - experimental design KW - immobilization KW - heavy metals KW - environmental remediation Y1 - 2016 U6 - https://doi.org/10.1002/jctb.4931 SN - 0268-2575 SN - 1097-4660 VL - 91 SP - 3045 EP - 3052 PB - Wiley-Blackwell CY - Hoboken ER -