TY - JOUR A1 - Carrapa, Barbara A1 - Garcia-Castellanos, D. T1 - Western Alpine back-thrusting as subsidence mechanism in the Tertiary Piedmont Basin (Western Po Plain, NW Italy) N2 - Basin formation dynamics of the Tertiary Piedmont Basin (TPB) are here investigated by means of cross-section numerical modelling. Previous works hypothesised that basin subsidence occurred due first to extension (Oligocene) and then to subsequent loading due to back-thrusting (Miocene). However, structural evidence shows that the TPB was mainly under contraction from Oligocene until post Pliocene time while extension played a minor role. Furthermore, thermal indicators strongly call for a cold (flexure-induced) mechanism but are strictly inconsistent with a hot (thermally induced) mechanism. Our new modelling shows that the TPB stratigraphic features can be reproduced by flexure of a visco- elastic plate loaded by backthrusts active in the Western Alps in Oligo-Miocene times. Far-field compression contributed to the TPB subsidence and controlled the basin infill geometry by enhancing basin tilting, forebulge uplift and erosion of the southern margin of the basin. These results suggest that the TPB subsidence is the result of a combination of mechanisms including thrust loading and farfield compressional stresses. (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0040-1951 ER - TY - JOUR A1 - Chambodut, Aude A1 - Panet, I. A1 - Mandea, Mioara A1 - Diament, M. A1 - Holschneider, Matthias A1 - Jamet, O. T1 - Wavelet frames : an alternative to spherical harmonic representation of potential fields N2 - Potential fields are classically represented on the sphere using spherical harmonics. However, this decomposition leads to numerical difficulties when data to be modelled are irregularly distributed or cover a regional zone. To overcome this drawback, we develop a new representation of the magnetic and the gravity fields based on wavelet frames. In this paper, we first describe how to build wavelet frames on the sphere. The chosen frames are based on the Poisson multipole wavelets, which are of special interest for geophysical modelling, since their scaling parameter is linked to the multipole depth (Holschneider et al.). The implementation of wavelet frames results from a discretization of the continuous wavelet transform in space and scale. We also build different frames using two kinds of spherical meshes and various scale sequences. We then validate the mathematical method through simple fits of scalar functions on the sphere, named 'scalar models'. Moreover, we propose magnetic and gravity models, referred to as 'vectorial models', taking into account geophysical constraints. We then discuss the representation of the Earth's magnetic and gravity fields from data regularly or irregularly distributed. Comparisons of the obtained wavelet models with the initial spherical harmonic models point out the advantages of wavelet modelling when the used magnetic or gravity data are sparsely distributed or cover just a very local zone Y1 - 2005 SN - 0956-540X ER - TY - JOUR A1 - Farges, Francois A1 - Djanarthany, S A1 - de Wispelaere, S A1 - Munoz, Manuel A1 - Magassouba, B A1 - Haddi, A A1 - Wilke, Max A1 - Schmidt, C. A1 - Borchert, Manuela A1 - Trocellier, P A1 - Crichton, W A1 - Simionovici, Alexandre A1 - Petit, Pierre-Emanuel A1 - Mezouar, Mohamed A1 - Etcheverry, M. P. A1 - Pallot-Frossard, I A1 - Bargar, John Reeder A1 - Brown, G. E. A1 - Grolimund, D A1 - Scheidegger, A T1 - Water in silicate glasses and melts of environmental interest : from volcanoes to cathedrals N2 - In silicate glasses and melts, water acts according to two main processes. First, it can be dissolved in high temperature/high pressure melts. Second, it constitutes a weathering agent on the glass surface. A number of in-situ x- ray absorption fine structure (XAFS) studies for Fe, Ni, Zr, Th and U show that the more charged cations (Zr, Nb, Mo, Ta, Sn, Th and U) are little affected by the presence of dissolved water in the melt. In contrast, divalent iron and nickel are highly sensitive to the presence of water, which enhance nucleation processes, for example, of phyllosilicates at the angstrom-scale. Such information provides additional constraints on the role of water deep in the Earth, particularly in magmatology. By contrast, the weathering of glass surfaces by water can be studied from a durability perspective. Experimental weathering experiments Of nuclear waste glasses performed in the laboratory show a variety of surface enrichments (carbon, chlorine, alkalis, iron) after exposure to atmospheric fluids and moisture. Mn-, and Fe-surface enrichments of analogous glasses of the XIVth century are related to the formation of Mn and Fe oxy/ hydroxides on the surface. The impact on the glass darkening is considered in terms of urban pollution and mass tourism Y1 - 2005 ER - TY - JOUR A1 - Kruger, Frank A1 - Ohrnberger, Matthias T1 - Tracking the rupture of the M-w=9.3 Sumatra earthquake over 1,150 km at teleseismic distance N2 - On 26 December 2004, a moment magnitude M-w = 9.3 earthquake occurred along Northern Sumatra, the Nicobar and Andaman islands, resulting in a devastating tsunami in the Indian Ocean region(1). The rapid and accurate estimation of the rupture length and direction of such tsunami-generating earthquakes is crucial for constraining both tsunami wave- height models as well as the seismic moment of the events. Compressional seismic waves generated at the hypocentre of the Sumatra earthquake arrived after about 12 min at the broadband seismic stations of the German Regional Seismic Network (GRSN)(2,3), located approximately 9,000 km from the event. Here we present a modification of a standard array- seismological approach and show that it is possible to track the propagating rupture front of the Sumatra earthquake over a total rupture length of 1,150 km. We estimate the average rupture speed to be 2.3-2.7 km s(-1) and the total duration of rupture to be at least 430 s, and probably between 480 and 500 s. Y1 - 2005 SN - 0028-0836 ER - TY - JOUR A1 - Konrad-Schmolke, Matthias A1 - Handy, Mark R. A1 - Babist, Jochen A1 - O'Brien, Patrick J. T1 - Thermodynamic modelling of diffusion-controlled garnet growth N2 - Numerical thermodynamic modelling of mineral composition and modes for specified pressure-temperature paths reveals the strong influence of fractional garnet crystallisation, as well as water fractionation, on garnet growth histories in high pressure rocks. Disequilibrium element incorporation in garnet due to the development of chemical inhomogeneities around porphyroblasts leads to pronounced episodic growth and may even cause growth interruptions. Discontinuous growth, together with pressure- and temperature-dependent changes in garnet chemistry, cause zonation patterns that are indicative of different degrees of disequilibrium element incorporation. Chemical inhomogeneities in the matrix surrounding garnet porphyroblasts strongly affect garnet growth and lead to compositional discontinuities and steep compositional gradients in the garnet zonation pattern. Further, intergranular diffusion-controlled calcium incorporation can lead to a characteristic rise in grossular and spessartine contents at lower metamorphic conditions. The observation that garnet zonation patterns diagnostic of large and small fractionation effects coexist within the same sample suggests that garnet growth is often controlled by small-scale variations in the bulk rock chemistry. Therefore, the spatial distribution of garnet grains and their zonation patterns, together with numerical growth models of garnet zonation patterns, yield information about the processes limiting garnet growth. These processes include intercrystalline element transport and dissolution of pre-existing grains. Discontinuities in garnet growth induced by limited element supply can mask traces of the thermobarometric history of the rock. Therefore, thermodynamic modelling that considers fractional disequilibrium crystallisation is required to interpret compositional garnet zonation in terms of a quantitative pressure and temperature path of the host rock Y1 - 2005 SN - 0010-7999 ER - TY - JOUR A1 - Solva, H. A1 - Grasemann, B. A1 - Thoni, M. A1 - Thiede, Rasmus Christoph A1 - Habler, G. T1 - The Schneeberg Normal Fault Zone : Normal faulting associated with Cretaceous SE-directed extrusion in the Eastern Alps (Italy / Austria) N2 - The Cretaceous eo-Alpine collisional event in the European Eastern Alps is generally accepted to induce W-NW- directed thrusting both in basement and in sedimentary cover units. This study presents the first evidence of eo-Alpine W-NW directed normal kinematics along the Schneeberg Normal Fault Zone, which separates eo-Alpine high-pressure rocks in a footwall position from pre-Alpine basement rocks in a hanging wall position. New Garnet Sm-Nd data indicate that exhumation of the high-pressure rocks along the normal fault zone started around 95 Ma ago and continued up to low greenschistibrittle conditions at 76 Ma, as indicated by a Rb-Sr age from a low temperature mylonite. The occurrence of pre-Alpine basement rocks both in the hanging wall and the footwall of eo-Alpine high-pressure rocks suggests exhumation by extrusion processes. Despite the displacement or removal of parts of the lower portion of the high-pressure unit by Tertiary strike-slip faults, eo-Alpine top-to-ESE thrusting, as expected for the structurally lower part of an extruding wedge, was found at and below the base of the eo-Alpine high-pressure rocks. A Rb-Sr age of 77 Ma from a greenschist facies mylonite in this thrust shear zone shows the contemporaneity of deformation at the base and the top of the wedge. The tectonic transport direction within the extruding wedge was E-SE, opposite to the W-NW direction so far reported for the eo-Alpine event in the Eastern Alps. The contemporaneity of opposite tectonic transport directions during continental subduction may be explained by a double-vergent wedge model with a narrow zone of ductile flow, where the high-pressure rocks were exhumed. (c) 2005 Elsevier B.V. All rights reserved Y1 - 2005 SN - 0040-1951 ER - TY - JOUR A1 - O'Brien, Patrick J. A1 - Walte, N. P A1 - Li, J. H. T1 - The petrology of two distinct granulite types in the Hengshan Mts, China, and tectonic implications N2 - The Archean to Proterozoic Hengshan Complex (North China Craton), comprises tonalitic and granodioritic gneisses with subordinate mafic lenses, pegmatites and granites. Amphibolite facies assemblages predominate, although granulite-facies relics are widespread, and greenschist-facies retrogression occurs in km-wide shear zones. Mafic lenses, locally abundant, occur as strongly deformed amphibolite (hornblende + plagioclase) boudins or sheets. In contrast to previously published models we find two series of mafic rocks with distinctly different granulite-facies evolutions. In the north of the complex, relict high-pressure mafic granulites are garnet + clinopyroxene-bearing rocks with a secondary development of orthopyroxene around both garnet (kelyphites) and clinopyroxene (coronas). South of the newly defined central, E-W-trending, Zhujiafang shear zone, numerous mafic boudins and less-deformed dykes exhibit a macroscopically visible magmatic texture with coronitic growth of metamorphic garnet (full of quartz inclusions) between the magmatic plagioclase and pyroxene domains. Additional orthopyroxene (after magmatic augite) and sodic rims to magmatic plagioclase clearly indicate medium-pressure granulite-facies metamorphism. These findings suggest tectonic juxtaposition in this area of three different structural levels of the same Proterozoic-imprinted crust: high-pressure granulite grade in the northern Hengshan, medium-pressure granulite grade in the southern Hengshan and amphibolite- to greenschist-facies grade in the Wutaishan to the SE. (c) 2004 Elsevier Ltd. All rights reserved Y1 - 2005 SN - 1367-9120 ER - TY - JOUR A1 - Botcharnikov, Roman E. A1 - Koepke, J. A1 - Holtz, Francois A1 - McCammon, C. A1 - Wilke, Max T1 - The effect of water activity on the oxidation and structural state of Fe in a ferro-basaltic melt N2 - Experimental investigations have been performed at T = 1200 degrees C, P = 200 MPa and fH(2) corresponding to H2O-MnO-Mn3O4 and H2O-QFM redox buffers to study the effect of H2O activity on the oxidation and structural state of Fe in an iron-rich basaltic melt. The analysis of Mossbauer and Fe K-edge X-ray absorption nearedge structure (XANES) spectra of the quenched hydrous ferrobasaltic glasses shows that the Fe3+/Sigma Fe ratio of the glass is directly related to aH(2)O in a H-2-buffered system and, consequently, to the prevailing oxygen fugacity (through the reaction of water dissociation H2O <-> H-2 + 1/2 O-2). However, water as a chemical component of the silicate melt has an indistinguishable effect on the redox state of iron at studied conditions. The experimentally obtained relationship between fO(2) and Fe3+/Fe2+ in the hydrous ferrobasaltic melt can be adequately predicted in the investigated range by the existing empiric and thermodynamic models. The ratio of ferric and ferrous Fe is proportional to the oxygen fugacity to the power of similar to 0.25 which agrees with the theoretical value from the stoichiometry of the Fe redox reaction (FeO + 1/4 O-2 = FeO1.5). The mean centre shifts for Fe2+ and Fe3+ absorption doublets in Mossbauer spectra show little change with increasing Fe3+/Sigma Fe, suggesting no significant change in the type of iron coordination. Similarly, XANES preedge spectra indicate a mixed (C3h, Td, and Oh, i.e., 5-, 4-, and sixfold) coordination of Fe in hydrous basaltic glasses. Copyright (c) 2005 Elsevier Ltd Y1 - 2005 SN - 0016-7037 ER - TY - JOUR A1 - Wilfried, H T1 - The Bohemians of New Zealand : an ethnic group N2 - The "Bohemians" of New Zealand - an ethnic group? In 1982 a small group of New Zealanders established contacts with the region of origin of their about 200 German-speaking ancestors who had emigrated from Bohemia for economic reasons in the 1860s and 1870s. They had all come from about twenty villages situated west of plzen and founded a rural settlement and participated in the foundation of a second one in New Zealand. Since World War I there had been no further contacts between the emigrants and their descendants on the one hand and their relatives in Bohemia on the other hand. For two reasons new contacts were established after such a long time: (1) the back-to the-roots-movement had spread to New Zealand from the USA, Canada and Australia, and (2) the status of cultural diversity keeps being enhanced in New Zealand since about 1970. These processes also influenced those people in New Zealand who call themselves "Bohemians" because of their ancestors' region of origin. Their total number is estimated at 10, 000 to 15, 000 at present. Up to now hardly any attention was attached to them in New Zealand by academic research and/or the general public. This paper discusses the history and today's situation of the former immigrants' community as well as the New Zealand "Bohemians " in general, raising the questions to what extent they can be defined as an ethnic group now and whether they will retain their status as a specific group in future Y1 - 2005 ER - TY - JOUR A1 - Bousquet, Romain A1 - Goffe, B. A1 - Le Pichon, X. A1 - de Capitani, Christian A1 - Chopin, C. A1 - Henry, P. T1 - Subduction factory : 1. Theoretical mineralogy, densities, seismic wave speeds, and H2O contents Y1 - 2005 ER -