TY  - JOUR
A1  - Shainyan, Bagrat A.
A1  - Moskalik, Mikail Yu
A1  - Starke, Ines
A1  - Schilde, Uwe
T1  - Formation of unexpected products in the attempted aziridination of styrene with trifluoromethanesulfonyl nitrene
N2  - The reaction of styrene with trifluoromethanesulfonyl nitrene generated from trifluoromethanesulfonamide in the system (t-BuOCl+NaI) results in the formation of trifluoro-N-[2-phenyl-2-(trifluoromethylsulfonyl) aminoethyl]methanesulfonamide, 1-pheny1-2-iodo-ethanol, and 2,5-diphenyl-1,4-bis(trifluoromethyl sulfonyl)piperazine rather than the expected product of aziridination, 2-phenyl-1-(trifluoromethylsulfonyl) aziridine. The mechanism of the reaction is discussed.
Y1  - 2010
UR  - http://www.sciencedirect.com/science/journal/00404020
U6  - https://doi.org/10.1016/j.tet.2010.08.070
SN  - 0040-4020
ER  -