TY  - JOUR
A1  - Reznichenko, Alexander L.
A1  - Emge, Thomas J.
A1  - Audoersch, Stephan
A1  - Klauber, Eric G.
A1  - Hultzsch, Kai C.
A1  - Schmidt, Bernd
T1  - Group 5 metal binaphtholate complexes for catalytic asymmetric hydroaminoalkylation and hydroamination/cyclization
JF  - Organometallics
N2  - 3,3'-Silylated binaphtholate tantalum and niobium complexes were shown to be efficient catalysts for the asymmetric hydroaminoalkylation of N-methylaniline derivatives and N-benzylmethylamine with simple alkenes in enantioselectivities of up to 80% ee. No hydroaminoalkylation was observed with aminoalkenes; rather, exclusive asymmetric hydroamination/cyclization took place in up to 81% ee.
Y1  - 2011
U6  - https://doi.org/10.1021/om1011006
SN  - 0276-7333
VL  - 30
IS  - 5
SP  - 921
EP  - 924
PB  - American Chemical Society
CY  - Washington
ER  -