TY - JOUR A1 - Pietsch, Ullrich A1 - Mukhopadhyay, M. K. A1 - Sanyal, M. K. A1 - Datta, A. A1 - Mukherjee, M. A1 - Geue, Thomas A1 - Grenzer, Jörg T1 - Transition from two-dimensional to three-dimensional melting in Langmuir-Blodgett films N2 - Results of energy-dispersive x-ray reflectivity and grazing incidence diffraction studies of Langmuir-Blodgett films exhibited evolution of conventional three-dimensional melting from continuous melting, characteristic of two- dimensional systems, as a function of deposited monolayers. Continuous expansion followed by a sharp phase transition of the in-plane lattice was observed before the melting point and found to be independent of number of deposited layers. Evolution of conventional melting with an increase in the number of monolayers could be quantified by measuring stiffness against tilting of the vertical stack of molecules, which are kept together by an internal field. The internal field as defined in this model reduces as the in-plane lattice expands and the sample temperature approaches melting point. The sharpness of the melting transition, which has been approximated by a Langevin function, increases with the number of deposited monolayers Y1 - 2004 ER - TY - JOUR A1 - Pietsch, Ullrich A1 - Bhattacharya, M. K. A1 - Mukherjee, M. A1 - Sanyal, M. K. A1 - Geue, Thomas A1 - Grenzer, Jörg T1 - Energy dispersive x-ray reflectivity technique to study thermal properties of polymer films Y1 - 2003 ER - TY - JOUR A1 - Mukherjee, M. A1 - Bhattacharya, M. K. A1 - Sanyal, M. K. A1 - Geue, Thomas A1 - Grenzer, Jörg A1 - Pietsch, Ullrich T1 - Temperature dependent thickness and surface tension of polymer films Y1 - 2000 SN - 81-7371295-6 ER -