TY - JOUR A1 - Bauer, J. A1 - Schulz, Burkhard A1 - Brehmer, Ludwig A1 - Bötcher, M. A1 - Jagdhold, U. A1 - Höppner, K. A1 - Kulesch, A. A1 - Dietzel, Birgit T1 - Anwendung von Langmuir-Blodgett-Schichten als Resist für die Niederspannungs-Elektronenstrahl-Lithografie Y1 - 1995 ER - TY - JOUR A1 - Brehmer, Ludwig A1 - Dietzel, Birgit A1 - Freydank, Anke-Christine A1 - Katholy, Stefan A1 - Knochenhauer, Gerald A1 - Reiche, Jürgen A1 - Schulz, Burkhard A1 - Zetzsche, Thomas T1 - Langmuir- und Langmuir-Blodgett-Filme amphiphiler Oxadiazole Y1 - 1995 ER - TY - JOUR A1 - Dietzel, Birgit A1 - Freydank, A. A1 - Reiche, Jürgen A1 - Brehmer, Ludwig A1 - Knoblauch, H. A1 - Knochenhauer, Gerald A1 - Zetzsche, Thomas T1 - Mono- und Multischichten von neuen aromatischen 1,3,4-Oxadiazolen Y1 - 1995 ER - TY - JOUR A1 - Emmerling, Franziska A1 - Orgzall, Ingo A1 - Dietzel, Birgit A1 - Schulz, Burkhard A1 - Larrucea, Julen T1 - Ordering the amorphous - Structures in PBD LED materials JF - Journal of molecular structure N2 - The class of 2,5 disubstituted-1,3,4-oxadiazoles containing a biphenyl unit on one side is intensively used as electron transport materials to enhance the performance of organic light emitting diodes (OLEDs). In contrast to the ongoing research on these materials insights in their structure-property relationships are still incomplete. To overcome the structural tentativeness and ambiguities the crystal structures of 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole, that of the related compound 2-(4-biphenylyl)-5-phenyl-1,3,4-oxadiazole and of 2-(4-biphenylyl)-5-(2,6-dimethylphenyl)-1,3,4-oxadiazole are determined. A comparison with the results of GAUSSIAN03 calculations and similar compounds in the Cambridge Structural Database leads to a profound characterization. KW - OLED KW - PBD KW - Diphenyl-1,3,4-oxadiazole KW - Crystallization Y1 - 2012 U6 - https://doi.org/10.1016/j.molstruc.2012.04.040 SN - 0022-2860 VL - 1030 IS - 23 SP - 209 EP - 215 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Englisch, Uwe A1 - Barberka, Thomas Andreas A1 - Pietsch, Ullrich A1 - Höhne, U. A1 - Reiche, Jürgen A1 - Dietzel, Birgit T1 - Neutronenreflektivität an Langmuir-Blodgett-Strukturen Y1 - 1995 ER - TY - JOUR A1 - Englisch, Uwe A1 - Pietsch, Ullrich A1 - Reiche, Jürgen A1 - Dietzel, Birgit T1 - Neutronenreflektivität von teildeuterierten LB-Filmen mit verschiedenen Verhältnissen on protonierten zu deuterierten Schichten Y1 - 1995 ER - TY - JOUR A1 - Hoffmann, Katrin A1 - Dietzel, Birgit A1 - Schulz, Burkhard A1 - Reck, Guenter A1 - Hoffmann, Angelika A1 - Orgzall, Ingo A1 - Resch-Genger, Ute A1 - Emmerling, Franziska T1 - Combined structural and fluorescence studies of methyl-substituted 2,5-diphenyl-1,3,4-oxadiazoles - Relation between electronic properties and packing motifs JF - Journal of molecular structure N2 - Prerequisite for the rational design of functional organic materials with tailor-made electronic properties is the knowledge of the structure-property relationship for the specific class of molecules under consideration. This encouraged us to systematically study the influence of the molecular structure and substitution pattern of aromatically substituted 1,3,4-oxadiazoles on the electronic properties and packing motifs of these molecules and on the interplay of these factors. For this purpose, seven diphenyl-oxadiazoles equipped with methyl substituents in the ortho- and meta-position(s) were synthesized and characterized. Absorption and fluorescence spectra in solution served here as tools to monitor substitution-induced changes in the electronic properties of the individual molecules whereas X-ray and optical measurements in the solid state provided information on the interplay of electronic and packing effects. In solution, the spectral position of the absorption maximum, the size of Stokes shift, and the fluorescence quantum yield are considerably affected by ortho-substitution in three or four ortho-positions. This results in blue shifted absorption bands, increased Stokes shifts, and reduced fluorescence quantum yields whereas the spectral position and vibrational structure of the emission bands remain more or less unaffected. In the crystalline state, however, the spectral position and shape of the emission bands display a strong dependence on the molecular structure and/or packing motifs that seem to control the amount of dye-dye-interactions. These observations reveal the limited value of commonly reported absorption and fluorescence measurements in solution for a straightforward comparison of spectroscopic results with single X-ray crystallography. This underlines the importance of solid state spectroscopic studies for a better understanding of the interplay of electronic effects and molecular order. KW - Diphenyl-oxadiazoles KW - X-ray structure KW - Packing motif KW - Optical properties KW - Fluorescence quantum yield Y1 - 2011 U6 - https://doi.org/10.1016/j.molstruc.2010.11.071 SN - 0022-2860 VL - 988 IS - 1-3 SP - 35 EP - 46 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Janietz, Dietmar A1 - Katholy, Stefan A1 - Dietzel, Birgit A1 - Brehmer, Ludwig T1 - Monolayer behaviour of two-fold hydroxy terminated sheet-like Tetrakis(phenylethynyl) benzene derivatives Y1 - 1997 ER - TY - JOUR A1 - Karageorgiev, Peter A1 - Stiller, Burkhard A1 - Prescher, Dietrich A1 - Dietzel, Birgit A1 - Schulz, Burkhard A1 - Brehmer, Ludwig T1 - Modification of the surface potential of azobenzene-containing langmuir-blodgett films in the near field of a scanning kelvin microscope tip by irradiation Y1 - 2000 ER - TY - JOUR A1 - Katholy, Stefan A1 - Reiche, Jürgen A1 - Dietzel, Birgit A1 - Ruhmann, Ralf A1 - Prescher, Dietrich T1 - Copolymerer funktionalisierte Methacrylate Y1 - 1995 ER -