TY - JOUR A1 - De Andrade, V. A1 - Vidal, O. A1 - Lewin, E. A1 - Agard, P. A1 - O'brien, Patrick T1 - Quantification of electron microprobe compositional maps of rock thin sections: an optimized method and examples JF - Journal of metamorphic geology N2 - Quantification of discrete pressure-temperature domains in deformed chlorite + white mica-bearing metapelites was undertaken on mineral compositions derived by two-dimensional microprobe compositional mapping of selected areas of rock thin sections. In order to achieve compositional information at sufficient analytical precision, spatial resolution and sample coverage within a typical analysis time of 1 day, an optimization of measurement methods was necessary. The method presented here allows collection of raw counts for eight different element concentrations at an analytical precision of similar to 1-2 wt%. X-ray intensity multiplane maps (one map per measured chemical element) are translated into concentration multiplane maps, utilizing selected conventionally measured spot analyses combined with the Castaing approximation for each mineral. As this step requires identification of the different minerals present in the mapped area, a statistical clustering technique to identify different groups of composition was developed, guided by simple petrographic inspection of the thin section, to delineate the important minerals in the mapped area. Finally, the compositions of each pixel are translated into a mineral structural formula thus yielding a new kind of image with a high content of petrological information. The reliability of the mineral composition images was emphasized by carrying out precision tests on the analytical data. The possible use of chemical maps to infer the P-T-deformation history of metamorphic rocks is illustrated with two samples from the Spitzbergen and the Sambagawa blueschist facies belts. In both samples, a strong correlation between structures and chemistry is observed. Qualitative estimates of P-T conditions from the Si-content of mica and chlorite are in good agreement with their location in microstructures that formed at different times. Therefore, the combination of chemical maps with microstructural observations is a very powerful approach to understand both the evolution of complex metamorphic rocks and the control by deformation of mineral reactivity. KW - chlorite KW - compositional map KW - electron microprobe KW - mica KW - Sambagawa KW - Spitzbergen KW - X-ray mapping Y1 - 2006 U6 - https://doi.org/10.1111/j.1525-1314.2006.00660.x SN - 0263-4929 VL - 24 SP - 655 EP - 668 PB - Wiley-Blackwell CY - Oxford ER - TY - JOUR A1 - Pourteau, Amaury A1 - Sudo, Masafumi A1 - Candan, Osman A1 - Lanari, P. A1 - Vidal, O. A1 - Oberhänsli, Roland T1 - Neotethys closure history of Anatolia - insights from Ar-40-Ar-39 geochronology and P-T estimation in high-pressure metasedimentary rocks JF - Journal of metamorphic geology N2 - The multiple high-pressure (HP), low-temperature (LT) metamorphic units of Western and Central Anatolia offer a great opportunity to investigate the subduction-and continental accretion-related evolution of the eastern limb of the long-lived Aegean subduction system. Recent reports of the HP-LT index mineral Fe-Mg-carpholite in three metasedimentary units of the Gondwana-derived Anatolide-Tauride continental block (namely the Afyon Zone, the Oren Unit and the southern Menderes Massif) suggest a more complicated scenario than the single-continental accretion model generally put forward in previous studies. This study presents the first isotopic dates (white mica Ar-40-Ar-39 geochronology), and where possible are combined with P-T estimates (chlorite thermometry, phengite barometry, multi-equilibrium thermobarometry), on carpholite-bearing rocks from these three HP-LT metasedimentary units. It is shown that, in the Afyon Zone, carpholite-bearing assemblages were retrogressed through greenschist-facies conditions at c. 67-62 Ma. Early retrograde stages in the Oren Unit are dated to 63-59 Ma. In the Kurudere-Nebiler Unit (HP Mesozoic cover of the southern Menderes Massif), HP retrograde stages are dated to c. 45 Ma, and post-collisional cooling to c. 26 Ma. These new results support that the Oren Unit represents the westernmost continuation of the Afyon Zone, whereas the Kurudere-Nebiler Unit correlates with the Cycladic Blueschist Unit of the Aegean Domain. In Western Anatolia, three successive HP-LT metamorphic belts thus formed: the northernmost Tavsanli Zone (c. 88-82 Ma), the Oren-Afyon Zone (between 70 and 65 Ma), and the Kurudere-Nebiler Unit (c. 52-45 Ma). The southward younging trend of the HP-LT metamorphism from the upper and internal to the deeper and more external structural units, as in the Aegean Domain, points to the persistence of subduction in Western Anatolia between 93-90 and c. 35 Ma. After the accretion of the Menderes-Tauride terrane, in Eocene times, subduction stopped, leading to continental collision and associated Barrovian-type metamorphism. Because, by contrast, the Aegean subduction did remain active due to slab roll-back and trench migration, the eastern limb (below Southwestern Anatolia) of the Hellenic slab was dramatically curved and consequently teared. It therefore is suggested that the possibility for subduction to continue after the accretion of buoyant (e.g. continental) terranes probably depends much on palaeogeography. KW - Ar-40-Ar-39 geochronology KW - Anatolia KW - chlorite-phengite thermobarometry KW - high-pressure metasedimentary rocks Y1 - 2013 U6 - https://doi.org/10.1111/jmg.12034 SN - 0263-4929 SN - 1525-1314 VL - 31 IS - 6 SP - 585 EP - 606 PB - Wiley-Blackwell CY - Hoboken ER -