TY  - THES
A1  - Pape, Simon
T1  - Entwicklung und Evaluierung von Methoden zur Synthese neuartiger Additive für die außenstromlose Nickel-Phosphor-Abscheidung
Y1  - 2016
ER  - 
TY  - JOUR
A1  - Pape, Simon
A1  - Wessig, Pablo
A1  - Brunner, Heiko
T1  - Iron Trichloride and Air Mediated Guanylation of Acylthioureas. An Ecological Route to Acylguanidines: Scope and Mechanistic Insights
JF  - The journal of organic chemistry
N2  - Recently we introduced iron trichloride as an environmentally benign and cost-efficient reagent for the synthesis of N-benzoylguanidines. This highly attractive synthetic approach grants access to a broad spectrum of N-benzoylguanidines under mild conditions in short reaction times. In this work we present an extended scope of Our methodology along with the results obtained from mechanistic studies via in situ IR spectroscopy in combination with LC (liquid chromatography)-MS analyses. On the basis of these new mechanistic insights we were able to optimize the synthetic protocol and to develop an alternative mechanistic proposal. In this context the symbiotic roles of iron trithloride and oxygen in the guanylation process are highlighted.
Y1  - 2016
U6  - https://doi.org/10.1021/acs.joc.6b00600
SN  - 0022-3263
VL  - 81
SP  - 4701
EP  - 4712
PB  - American Chemical Society
CY  - Washington
ER  -