TY - JOUR A1 - Bruma, Maria A1 - Schulz, Burkhard A1 - Mercer, Frank W. T1 - Synthesis and characterization of fluorinated poly(imide-pyridazine- amide)s Y1 - 1994 ER - TY - JOUR A1 - Sava, Ion A1 - Schulz, Burkhard A1 - Zhu, Shigen A1 - Bruma, Maria T1 - Synthesis and characterization of new silicon-containing poly(arylene-1,3,4-oxadiazole)s Y1 - 1995 UR - http://hip.sagepub.com/ U6 - https://doi.org/10.1088/0954-0083/7/4/011 SN - 0954-0083 ER - TY - JOUR A1 - Mercer, Frank W. A1 - McKenzie, M. A1 - Bruma, Maria A1 - Schulz, Burkhard T1 - Synthesis and properties of fluorinated polyimides and fluorinated poly(imide-amide)s containing pendent cyano groups Y1 - 1994 ER - TY - JOUR A1 - Hamaciuc, E. A1 - Bruma, Maria A1 - Köpnick, Thomas A1 - Kaminorz, Yvette A1 - Schulz, Burkhard T1 - Synthesis and Study of New Silicon-containing Polyoxadiazoles N2 - A series of new poly-1,3,4-oxadiazoles has been synthesized by polycondensation reaction of hydrazine sulfate with a mixture of a dicarboxylic acid containing unsaturated bonds and a dicarboxylic acid containing silicon, by using methanesulfonic acid/phosphorus pentoxide as a reaction medium. These polymers were highly thermostable but they were only soluble in strong inorganic acids such as sulfuric or methanesulfonic ones. An alternative way was followed by using the corresponding dihydrazides containing unsaturated bonds and the corresponding diacid chloride containing silicon that reacted in N-methylpyrrolidinone (NMP) to give soluble silicon-containing unsaturated polyhydrazides, which were cyclodehydrated either by thermal or chemical treatment to give the corresponding polyoxadiazoles. Very thin coatings of polyhydrazides and polyoxadiazoles were deposited onto silicon wafers and they showed a very smooth surface, free of pinholes, when studied by atomic force microscopy (AFM). Some polyoxadiazole films showed strong blue photoluminescence. Y1 - 2001 ER -