TY  - JOUR
A1  - Vukicevic, Radovan
A1  - Hierzenberger, Peter
A1  - Hild, Sabine
A1  - Beuermann, Sabine
T1  - Functionalization of carbon black nanoparticles with poly(vinylidene fluoride)
N2  - The surface of carbon black (CB) nanoparticles was functionalized with poly(vinylidene fluoride) (PVDF) either by trapping of macroradicals or by cycloaddition. PVDF with two iodine end groups (I-PVDF-I) obtained from iodine transfer polymerization in supercritical CO2 was heated in the presence of CB and the C-I bond was cleaved resulting in a reaction between the macroradical and the CB surface. To allow for cycloaddition of PVDF to the CB surface for a number of polymers, the iodine end groups were replaced by azide end groups. In addition, microwave irradiation was applied to the functionalization. The influence of temperature, time, polymer concentration, and polymer molar mass on the functionalization reaction was examined.
Y1  - 2010
UR  - http://onlinelibrary.wiley.com/journal/10.1002/%28ISSN%291542-9369
U6  - https://doi.org/10.1002/Pola.24277
SN  - 0887-624X
ER  -