TY - JOUR A1 - Kosmella, Sabine A1 - Venus, Jane A1 - Hahn, Jennifer A1 - Prietzel, Claudia Christina A1 - Koetz, Joachim T1 - Low-temperature synthesis of polyethyleneimine-entrapped CdS quantum dots JF - Chemical physics letters N2 - This Letter is focused on the one-pot formation of CdS nanoparticles in aqueous medium in presence of polyethyleneimine (PEI). Quantum dots can be obtained by adding a pre-cooled aqueous Na2S solution to a pre-cooled aqueous CdCl2 solution dropwise in presence of PEI. Field flow fractionation in combination with TEM experiments show a time dependent agglomeration of individual quantum dots from 1.6 nm up to 3.2 nm in size. The hyperbranched PEI of moderate molar mass (>20000 g/mol) is an excellent polymer to prevent a further increase of the particle size. Therefore, stable fluorescent PEI-capped CdS quantum dots are available. Y1 - 2014 U6 - https://doi.org/10.1016/j.cplett.2013.12.019 SN - 0009-2614 SN - 1873-4448 VL - 592 SP - 114 EP - 119 PB - Elsevier CY - Amsterdam ER -