TY  - JOUR
A1  - Holländer, Lars
A1  - Kossack, Wilhelm
A1  - Kollosche, Matthias
A1  - Wirges, Werner
A1  - Kremer, Friedrich
A1  - Gerhard, Reimund
T1  - Influence of the remanent polarisation on the liquid crystal alignment in composite films of ferroelectric poly(vinylidene fluoride-trifluoroethylene) and a cyanobiphenyl-based liquid crystal
JF  - Liquid crystals : an international journal of science and technology
N2  - Polymer-dispersed liquid crystals (PDLCs) of ferroelectric poly(vinylidene fluoride-trifluoroethylene) and nematic 4-cyano-4ʹ-n-hexylbiphenyl (6CB) or 4-cyano-4ʹ-n-pentylbiphenyl (5CB) were prepared to study the effect of the remanent polarisation of the polymer on the liquid crystal alignment. We measured the macroscopic alignment of the liquid crystal molecules in the thickness direction by means of Infrared Transition-Moment Orientational Analysis. Electrical poling at 100 V/µm caused an increased order parameter up to 0.15. After subsequent annealing above the nematic-to-isotropic phase-transition temperature, the order parameter was reduced to 0.02. Nevertheless, the order parameter was still higher than for non-poled film indicating a slight orientation in thickness direction. Both values are lower than those expected from model calculations. In agreement with dielectric measurements, we attribute this result to the shielding effect of mobile charge carriers within the liquid crystal inclusions.
KW  - Polymer-dispersed liquid crystal
KW  - ferroelectric polymer
KW  - remanent polarisation
KW  - liquid crystal alignment
Y1  - 2016
U6  - https://doi.org/10.1080/02678292.2016.1185174
SN  - 0267-8292
SN  - 1366-5855
VL  - 43
SP  - 1514
EP  - 1521
PB  - Editions Rodopi BV
CY  - Abingdon
ER  - 
TY  - JOUR
A1  - Anton, Arthur Markus
A1  - Steyrleuthner, Robert
A1  - Kossack, Wilhelm
A1  - Neher, Dieter
A1  - Kremer, Friedrich
T1  - Infrared Transition Moment Orientational Analysis on the Structural Organization of the Distinct Molecular Subunits in Thin Layers of a High Mobility n-Type Copolymer
JF  - Journal of the American Chemical Society
N2  - The IR-based method of infrared transition moment orientational analysis (IR-TMOA) is employed to unravel molecular order in thin layers of the semiconducting polymer poly[N,N'-bis(2-octyldodecyl),-1,4,5,8-naphthalene-diimide-2,6-diyl]-alt-5-5'-(2,2'-bithiophene) (P(NDI2OD-T2)). Structure-specific vibrational bands are analyzed in dependence On polarization and inclination of the sample-With respect to the optical axis. By that the molecular Order parameter tensor for the respective molecular moieties with regard to the sample: coordinate system is deduced. Making use of the specificity of the IR spectral range, we are able to determine separately the orientation of atomistic planes defined through the naphthalenediimide (NDI) and bithiophene (T2) units relative to the substrate, and hence, relative to each other. A pronounced solvent effect is observed While chlorobenzene causes the T2 planes to align preferentially parallel to the substrate at an angle of 29 degrees, using a 1:1 chloronaphthalene:xylene mixture results in a reorientation of the T2 units from a face on into an edge on arrangement. In contrast the NDI unit remains unaffected. Additionally, for both solvents evidence is observed for the aggregation of chains in accord With recently published results obtained by UV-vis absorption spectroscopy.
Y1  - 2015
U6  - https://doi.org/10.1021/jacs.5b01755
SN  - 0002-7863
VL  - 137
IS  - 18
SP  - 6034
EP  - 6043
PB  - American Chemical Society
CY  - Washington
ER  - 
TY  - JOUR
A1  - Meier, Johann Georg
A1  - Stumpe, Joachim
A1  - Fischer, Birgit
A1  - Thieme, Cathrin
A1  - Fischer, Thomas M.
A1  - Kremer, Friedrich
A1  - Öge, Tanja
A1  - Zentel, Rudolf
T1  - Optical suppression of Ferroelectricity in polysiloxane copolymers with chiral an potochromic side groups
Y1  - 1998
ER  -