TY  - JOUR
A1  - Shainyan, Bagrat A.
A1  - Ushakov, Igor A.
A1  - Koch, Andreas
A1  - Kleinpeter, Erich
T1  - Stereodynamics of 1-(methylsulfonyl)-3,5-bis(trifluoromethylsulfonyl)-1,3,5-triazinane: Experimental and theoretical analysis
N2  - Dynamic NMR of 1-(methylsulfonyl)-3,5-bis(trifluoromethylsulfonyl)-1,3,5-triazinane reveals the existence of three conformers and two dynamic processes: ring inversion and rotation about the N-S bond, both processes having Delta G(double dagger) = 13.5 kcal/mol. An unprecedented large reverse Perlin effect (J(CHax) > J(CHeq)) was found experimentally and calculated theoretically.
Y1  - 2006
UR  - http://pubs.acs.org/doi/full/10.1021/jo061112x
U6  - https://doi.org/10.1021/Jo061112x
ER  -