TY  - JOUR
A1  - Abouserie, Ahed
A1  - Zehbe, Kerstin
A1  - Metzner, Philipp
A1  - Kelling, Alexandra
A1  - Günter, Christina
A1  - Schilde, Uwe
A1  - Strauch, Peter
A1  - Körzdörfer, Thomas
A1  - Taubert, Andreas
T1  - Alkylpyridinium Tetrahalidometallate Ionic Liquids and Ionic Liquid Crystals: Insights into the Origin of Their Phase Behavior
JF  - European journal of inorganic chemistry : a journal of ChemPubSoc Europe
N2  - Six N-alkylpyridinium salts [CnPy](2)[MCl4] (n = 4 or 12 and M = Co, Cu, Zn) were synthesized, and their structure and thermal properties were studied. The [C4Py](2)[MCl4] compounds are monoclinic and crystallize in the space group P2(1)/n. The crystals of the longer chain analogues [C12Py](2)[MCl4] are triclinic and crystallize in the space group P (1) over bar. Above the melting temperature, all compounds are ionic liquids (ILs). The derivatives with the longer C12 chain exhibit liquid crystallinity and the shorter chain compounds only show a melting transition. Consistent with single-crystal analysis, electron paramagnetic resonance spectroscopy suggests that the [CuCl4](2-) ions in the Cu-based ILs have a distorted tetrahedral geometry.
KW  - Ionic liquids
KW  - Alkylpyridinium salts
KW  - Structure elucidation
KW  - Phase transitions
Y1  - 2017
U6  - https://doi.org/10.1002/ejic.201700826
SN  - 1434-1948
SN  - 1099-0682
SP  - 5640
EP  - 5649
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Abouserie, Ahed
A1  - Zehbe, Kerstin
A1  - Metzner, Philipp
A1  - Kelling, Alexandra
A1  - Günter, Christina
A1  - Schilde, Uwe
A1  - Strauch, Peter
A1  - Körzdörfer, Thomas
A1  - Taubert, Andreas
T1  - Alkylpyridinium Tetrahalidometallate Ionic Liquids and Ionic Liquid Crystals: Insights into the Origin of Their Phase Behavior
JF  - European journal of inorganic chemistry : a journal of ChemPubSoc Europe
N2  - Six N-alkylpyridinium salts [CnPy](2)[MCl4] (n = 4 or 12 and M = Co, Cu, Zn) were synthesized, and their structure and thermal properties were studied. The [C4Py](2)[MCl4] compounds are monoclinic and crystallize in the space group P2(1)/n. The crystals of the longer chain analogues [C12Py](2)[MCl4] are triclinic and crystallize in the space group P (1) over bar. Above the melting temperature, all compounds are ionic liquids (ILs). The derivatives with the longer C12 chain exhibit liquid crystallinity and the shorter chain compounds only show a melting transition. Consistent with single-crystal analysis, electron paramagnetic resonance spectroscopy suggests that the [CuCl4](2-) ions in the Cu-based ILs have a distorted tetrahedral geometry.
KW  - Ionic liquids
KW  - Alkylpyridinium salts
KW  - Structure elucidation
KW  - Phase transitions
Y1  - 2017
U6  - https://doi.org/10.1002/ejic.201700826
SN  - 1434-1948
SN  - 1099-0682
SP  - 5640
EP  - 5649
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Strehmel, Veronika
A1  - Rexhausen, Hans
A1  - Strauch, Peter
T1  - New spin probes starting from 4-amino-2,2,6,6-tetramethylpiperidine-1-yloxyl
JF  - Tetrahedron letters
N2  - This Letter describes four new 4-trimethylammonio-2,2,6,6-tetramethylpiperidine-1-yloxyls bearing camphorsulfonate, triflate, tosylate, or lactate as counter ions. These spin probes were made by anion metathesis of 4-trimethylammonio-2,2,6,6-tetramethylpiperidine-1-yloxyl iodide using the corresponding silver salts. The latter is made by the alkylation of 4-amino-2,2,6,6-tetramethylpiperidine-1-yloxyl. Furthermore, the Letter gives an improved synthetic way to 4-sulfonamido-2,2,6,6-tetramethylpiperidine-1-yloxyl using chlorosulfuric acid trimethylsilylester and 4-amino-2,2,6,6-tetramethylpiperidine-1-yloxyl. All the spin probes are highly interesting for the investigation of ionic liquids.
KW  - Nitroxides
KW  - Spin probes
KW  - ESR spectroscopy
KW  - Ionic liquids
Y1  - 2012
U6  - https://doi.org/10.1016/j.tetlet.2012.01.063
SN  - 0040-4039
VL  - 53
IS  - 13
SP  - 1587
EP  - 1591
PB  - Elsevier
CY  - Oxford
ER  -