TY - GEN A1 - Sparkes, Robert B. A1 - Hovius, Niels A1 - Galy, Albert A1 - Liu, James T. T1 - Survival of graphitized petrogenic organic carbon through multiple erosional cycles T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Graphite forms the endpoint for organic carbon metamorphism; it is extremely resilient to physical, biological and chemical degradation. Carbonaceous materials (CM) contained within sediments, collected across Taiwan and from the Gaoping submarine canyon, were analyzed using Raman spectroscopy to determine the crystallinity. This allowed the erosional and orogenic movements of petrogenic organic carbon (OCpetro) during the Taiwanese orogeny to be deduced. After automatically fitting and classifying spectra, the distribution of four groups of CM within the sediments provides evidence that many forms of OCpetro have survived at least one previous cycle of erosion, transport and burial before forming rocks in the Western Foothills of the island. There is extensive detrital graphite present in rocks that have not experienced high-grade metamorphism, and graphite flakes are also found in recently deposited marine sediments off Taiwan. The tectonic and geological history of the island shows that these graphite flakes must have survived at least three episodes of recycling. Therefore, transformation to graphite during burial and orogeny is a mechanism for stabilizing organic carbon over geological time, removing biospheric carbon from the active carbon cycle and protecting it from oxidation during future erosion events. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 1223 KW - graphite KW - organic carbon KW - orogeny KW - recycling KW - Raman spectroscopy KW - erosion Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-533541 SN - 1866-8372 ER - TY - GEN A1 - Emberson, Robert A1 - Hovius, Niels A1 - Galy, Albert A1 - Marc, Odin T1 - Oxidation of sulfides and rapid weathering in recent landslides T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Linking together the processes of rapid physical erosion and the resultant chemical dissolution of rock is a crucial step in building an overall deterministic understanding of weathering in mountain belts. Landslides, which are the most volumetrically important geomorphic process at these high rates of erosion, can generate extremely high rates of very localised weathering. To elucidate how this process works we have taken advantage of uniquely intense landsliding, resulting from Typhoon Morakot, in the T'aimali River and surrounds in southern Taiwan. Combining detailed analysis of landslide seepage chemistry with estimates of catchment-by-catchment landslide volumes, we demonstrate that in this setting the primary role of landslides is to introduce fresh, highly labile mineral phases into the surface weathering environment. There, rapid weathering is driven by the oxidation of pyrite and the resultant sulfuric-acid-driven dissolution of primarily carbonate rock. The total dissolved load correlates well with dissolved sulfate - the chief product of this style of weathering - in both landslides and streams draining the area (R-2 = 0.841 and 0.929 respectively; p < 0.001 in both cases), with solute chemistry in seepage from landslides and catchments affected by significant landsliding governed by the same weathering reactions. The predominance of coupled carbonate-sulfuric-acid-driven weathering is the key difference between these sites and previously studied landslides in New Zealand (Emberson et al., 2016), but in both settings increasing volumes of landslides drive greater overall solute concentrations in streams. Bedrock landslides, by excavating deep below saprolite-rock interfaces, create conditions for weathering in which all mineral phases in a lithology are initially unweathered within landslide deposits. As a result, the most labile phases dominate the weathering immediately after mobilisation and during a transient period of depletion. This mode of dissolution can strongly alter the overall output of solutes from catchments and their contribution to global chemical cycles if landslide-derived material is retained in catchments for extended periods after mass wasting. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 553 KW - physical erosion KW - Mountain Belt KW - Southwestern Taiwan KW - athmospheric CO2 KW - New-Zealand KW - climatic controls KW - Himalayan Rivers KW - Southern Alps KW - carbon-cycle KW - model Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-412326 SN - 1866-8372 IS - 553 ER -