@phdthesis{Heinig2003, author = {Heinig, Peter}, title = {The geometry of interacting liquid domains in Langmuir monolayers}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-0000814}, school = {Universit{\"a}t Potsdam}, year = {2003}, abstract = {Es werden die Strukturbildung und Benetzung zweidimensionaler (2D) Phasen von Langmuir-Monolagen im lokalen thermodynamischen Gleichgewicht untersucht. Eine Langmuir-Monolage ist ein isoliertes 2D System von Surfaktanten an der Wasser/Luft-Grenzfl{\"a}che, in dem kristalline, fl{\"u}ssigkristalline, fl{\"u}ssige oder gasf{\"o}rmige Phasen auftreten, die sich in Positionsordnung und/oder Orientierungsordnung unterscheiden. Permanente elektrische Dipolmomente der Surfaktanten f{\"u}hren zu einer langreichweitigen repulsiven Selbstwechselwirkung der Monolage und zur Bildung mesoskopischer Strukturen. Es wird ein Wechselwirkungsmodell verwendet, das die Strukturbildung als Wechselspiel kurzreichweitiger Anziehung (nackte Linienspannung) und langreichweitiger Abstoßung (Oberfl{\"a}chenpotential) auf einer Skala Delta beschreibt. Physikalisch trennt Delta die beiden L{\"a}ngenskalen der lang- und kurzreichweitigen Wechselwirkung. In dieser Arbeit werden die thermodynamischen Stabilit{\"a}tsbedingungen f{\"u}r die Form einer Phasengrenzlinie (Young-Laplace-Gleichung) und Dreiphasenkontaktpunkt (Young-Bedingung) hergeleitet und zur Beschreibung experimenteller Daten genutzt: Die Linienspannung benetzender 2D Tropfen wird mit Hilfe h{\"a}ngender-Tropfen-Tensiometrie gemessen. Die Blasenform und -gr{\"o}ße von 2D Sch{\"a}umen wird theoretisch modelliert und mit experimentellen 2D Sch{\"a}umen verglichen. Kontaktwinkel werden durch die Anpassung von experimentellen Tropfen mit numerischen L{\"o}sungen der Young-Laplace-Gleichung auf Mikrometerskalen gemessen. Das Skalenverhalten des Kontaktwinkels erm{\"o}glicht die Bestimmung einer unteren Schranke von Delta. Weiterhin wird diskutiert, inwieweit das Schalten von 2D Benetzungsmodi in biologischen Membranen zur Steuerung der Reaktionskinetik ein Rolle spielen k{\"o}nnte. Hierzu werden Experimente aus unserer Gruppe, die in einer Langmuir-Monolage durchgef{\"u}hrt wurden, herangezogen. Abschließend wird die scheinbare Verletzung der Gibbs\′schen Phasenregel in Langmuir-Monolagen (nicht-horizontales Plateau der Oberfl{\"a}chendruck-Fl{\"a}che Isotherme, ausgedehntes Dreiphasengebiet in Einkomponentensystemen) quantitativ untersucht. Eine Verschmutzung der verwendeten Substanzen ist demnach die wahscheinlichste Erkl{\"a}rung, w{\"a}hrend Finite-Size-Effekte oder der Einfluss der langreichweitigen Elektrostatik die Gr{\"o}ßenordnung des Effektes nicht beschreiben k{\"o}nnen.}, language = {en} } @phdthesis{Loeffler2005, author = {L{\"o}ffler, Frank}, title = {Numerical simulations of neutron star - black hole mergers}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7743}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {Collisions of black holes and neutron stars, named mixed binaries in the following, are interesting because of at least two reasons. Firstly, it is expected that they emit a large amount of energy as gravitational waves, which could be measured by new detectors. The form of those waves is expected to carry information about the internal structure of such systems. Secondly, collisions of such objects are the prime suspects of short gamma ray bursts. The exact mechanism for the energy emission is unknown so far. In the past, Newtonian theory of gravitation and modifications to it were often used for numerical simulations of collisions of mixed binary systems. However, near to such objects, the gravitational forces are so strong, that the use of General Relativity is necessary for accurate predictions. There are a lot of problems in general relativistic simulations. However, systems of two neutron stars and systems of two black holes have been studies extensively in the past and a lot of those problems have been solved. One of the remaining problems so far has been the use of hydrodynamic on excision boundaries. Inside excision regions, no evolution is carried out. Such regions are often used inside black holes to circumvent instabilities of the numerical methods near the singularity. Methods to handle hydrodynamics at such boundaries have been described and tests are shown in this work. One important test and the first application of those methods has been the simulation of a collapsing neutron star to a black hole. The success of these simulations and in particular the performance of the excision methods was an important step towards simulations of mixed binaries. Initial data are necessary for every numerical simulation. However, the creation of such initial data for general relativistic situations is in general very complicated. In this work it is shown how to obtain initial data for mixed binary systems using an already existing method for initial data of two black holes. These initial data have been used for evolutions of such systems and problems encountered are discussed in this work. One of the problems are instabilities due to different methods, which could be solved by dissipation of appropriate strength. Another problem is the expected drift of the black hole towards the neutron star. It is shown, that this can be solved by using special gauge conditions, which prevent the black hole from moving on the computational grid. The methods and simulations shown in this work are only the starting step for a much more detailed study of mixed binary system. Better methods, models and simulations with higher resolution and even better gauge conditions will be focus of future work. It is expected that such detailed studies can give information about the emitted gravitational waves, which is important in view of the newly built gravitational wave detectors. In addition, these simulations could give insight into the processes responsible for short gamma ray bursts.}, subject = {Relativistische Astrophysik}, language = {en} } @phdthesis{Prevot2006, author = {Prevot, Michelle Elizabeth}, title = {Introduction of a thermo-sensitive non-polar species into polyelectrolyte multilayer capsules for drug delivery}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7785}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {The layer-by-layer assembly (LBL) of polyelectrolytes has been extensively studied for the preparation of ultrathin films due to the versatility of the build-up process. The control of the permeability of these layers is particularly important as there are potential drug delivery applications. Multilayered polyelectrolyte microcapsules are also of great interest due to their possible use as microcontainers. This work will present two methods that can be used as employable drug delivery systems, both of which can encapsulate an active molecule and tune the release properties of the active species. Poly-(N-isopropyl acrylamide), (PNIPAM) is known to be a thermo-sensitive polymer that has a Lower Critical Solution Temperature (LCST) around 32oC; above this temperature PNIPAM is insoluble in water and collapses. It is also known that with the addition of salt, the LCST decreases. This work shows Differential Scanning Calorimetry (DSC) and Confocal Laser Scanning Microscopy (CLSM) evidence that the LCST of the PNIPAM can be tuned with salt type and concentration. Microcapsules were used to encapsulate this thermo-sensitive polymer, resulting in a reversible and tunable stimuli- responsive system. The encapsulation of the PNIPAM inside of the capsule was proven with Raman spectroscopy, DSC (bulk LCST measurements), AFM (thickness change), SEM (morphology change) and CLSM (in situ LCST measurement inside of the capsules). The exploitation of the capsules as a microcontainer is advantageous not only because of the protection the capsules give to the active molecules, but also because it facilitates easier transport. The second system investigated demonstrates the ability to reduce the permeability of polyelectrolyte multilayer films by the addition of charged wax particles. The incorporation of this hydrophobic coating leads to a reduced water sensitivity particularly after heating, which melts the wax, forming a barrier layer. This conclusion was proven with Neutron Reflectivity by showing the decreased presence of D2O in planar polyelectrolyte films after annealing creating a barrier layer. The permeability of capsules could also be decreased by the addition of a wax layer. This was proved by the increase in recovery time measured by Florescence Recovery After Photobleaching, (FRAP) measurements. In general two advanced methods, potentially suitable for drug delivery systems, have been proposed. In both cases, if biocompatible elements are used to fabricate the capsule wall, these systems provide a stable method of encapsulating active molecules. Stable encapsulation coupled with the ability to tune the wall thickness gives the ability to control the release profile of the molecule of interest.}, subject = {Mikrokapsel}, language = {en} } @phdthesis{Zoeller2005, author = {Z{\"o}ller, Gert}, title = {Critical states of seismicity : modeling and data analysis}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7427}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {The occurrence of earthquakes is characterized by a high degree of spatiotemporal complexity. Although numerous patterns, e.g. fore- and aftershock sequences, are well-known, the underlying mechanisms are not observable and thus not understood. Because the recurrence times of large earthquakes are usually decades or centuries, the number of such events in corresponding data sets is too small to draw conclusions with reasonable statistical significance. Therefore, the present study combines both, numerical modeling and analysis of real data in order to unveil the relationships between physical mechanisms and observational quantities. The key hypothesis is the validity of the so-called "critical point concept" for earthquakes, which assumes large earthquakes to occur as phase transitions in a spatially extended many-particle system, similar to percolation models. New concepts are developed to detect critical states in simulated and in natural data sets. The results indicate that important features of seismicity like the frequency-size distribution and the temporal clustering of earthquakes depend on frictional and structural fault parameters. In particular, the degree of quenched spatial disorder (the "roughness") of a fault zone determines whether large earthquakes occur quasiperiodically or more clustered. This illustrates the power of numerical models in order to identify regions in parameter space, which are relevant for natural seismicity. The critical point concept is verified for both, synthetic and natural seismicity, in terms of a critical state which precedes a large earthquake: a gradual roughening of the (unobservable) stress field leads to a scale-free (observable) frequency-size distribution. Furthermore, the growth of the spatial correlation length and the acceleration of the seismic energy release prior to large events is found. The predictive power of these precursors is, however, limited. Instead of forecasting time, location, and magnitude of individual events, a contribution to a broad multiparameter approach is encouraging.}, subject = {Seismizit{\"a}t}, language = {en} } @phdthesis{Jappsen2005, author = {Jappsen, Anne-Katharina}, title = {Present and early star formation : a study on rotational and thermal properties}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7591}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {We investigate the rotational and thermal properties of star-forming molecular clouds using hydrodynamic simulations. Stars form from molecular cloud cores by gravoturbulent fragmentation. Understanding the angular momentum and the thermal evolution of cloud cores thus plays a fundamental role in completing the theoretical picture of star formation. This is true not only for current star formation as observed in regions like the Orion nebula or the ρ-Ophiuchi molecular cloud but also for the formation of stars of the first or second generation in the universe. In this thesis we show how the angular momentum of prestellar and protostellar cores evolves and compare our results with observed quantities. The specific angular momentum of prestellar cores in our models agree remarkably well with observations of cloud cores. Some prestellar cores go into collapse to build up stars and stellar systems. The resulting protostellar objects have specific angular momenta that fall into the range of observed binaries. We find that collapse induced by gravoturbulent fragmentation is accompanied by a substantial loss of specific angular momentum. This eases the "angular momentum problem" in star formation even in the absence of magnetic fields. The distribution of stellar masses at birth (the initial mass function, IMF) is another aspect that any theory of star formation must explain. We focus on the influence of the thermodynamic properties of star-forming gas and address this issue by studying the effects of a piecewise polytropic equation of state on the formation of stellar clusters. We increase the polytropic exponent γ from a value below unity to a value above unity at a certain critical density. The change of the thermodynamic state at the critical density selects a characteristic mass scale for fragmentation, which we relate to the peak of the IMF observed in the solar neighborhood. Our investigation generally supports the idea that the distribution of stellar masses depends mainly on the thermodynamic state of the gas. A common assumption is that the chemical evolution of the star-forming gas can be decoupled from its dynamical evolution, with the former never affecting the latter. Although justified in some circumstances, this assumption is not true in every case. In particular, in low-metallicity gas the timescales for reaching the chemical equilibrium are comparable or larger than the dynamical timescales. In this thesis we take a first approach to combine a chemical network with a hydrodynamical code in order to study the influence of low levels of metal enrichment on the cooling and collapse of ionized gas in small protogalactic halos. Our initial conditions represent protogalaxies forming within a fossil HII region -- a previously ionized HII region which has not yet had time to cool and recombine. We show that in these regions, H2 is the dominant and most effective coolant, and that it is the amount of H2 formed that controls whether or not the gas can collapse and form stars. For metallicities Z <= 10-3 Zsun, metal line cooling alters the density and temperature evolution of the gas by less than 1\% compared to the metal-free case at densities below 1 cm-3 and temperatures above 2000 K. We also find that an external ultraviolet background delays or suppresses the cooling and collapse of the gas regardless of whether it is metal-enriched or not. Finally, we study the dependence of this process on redshift and mass of the dark matter halo.}, subject = {Sternentstehung}, language = {en} } @phdthesis{SchneidervonDeimling2006, author = {Schneider von Deimling, Thomas}, title = {Constraining uncertainty in climate sensitivity : an ensemble simulation approach based on glacial climate}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7778}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Uncertainty about the sensitivity of the climate system to changes in the Earth's radiative balance constitutes a primary source of uncertainty for climate projections. Given the continuous increase in atmospheric greenhouse gas concentrations, constraining the uncertainty range in such type of sensitivity is of vital importance. A common measure for expressing this key characteristic for climate models is the climate sensitivity, defined as the simulated change in global-mean equilibrium temperature resulting from a doubling of atmospheric CO2 concentration. The broad range of climate sensitivity estimates (1.5-4.5°C as given in the last Assessment Report of the Intergovernmental Panel on Climate Change, 2001), inferred from comprehensive climate models, illustrates that the strength of simulated feedback mechanisms varies strongly among different models. The central goal of this thesis is to constrain uncertainty in climate sensitivity. For this objective we first generate a large ensemble of model simulations, covering different feedback strengths, and then request their consistency with present-day observational data and proxy-data from the Last Glacial Maximum (LGM). Our analyses are based on an ensemble of fully-coupled simulations, that were realized with a climate model of intermediate complexity (CLIMBER-2). These model versions cover a broad range of different climate sensitivities, ranging from 1.3 to 5.5°C, and have been generated by simultaneously perturbing a set of 11 model parameters. The analysis of the simulated model feedbacks reveals that the spread in climate sensitivity results from different realizations of the feedback strengths in water vapour, clouds, lapse rate and albedo. The calculated spread in the sum of all feedbacks spans almost the entire plausible range inferred from a sampling of more complex models. We show that the requirement for consistency between simulated pre-industrial climate and a set of seven global-mean data constraints represents a comparatively weak test for model sensitivity (the data constrain climate sensitivity to 1.3-4.9°C). Analyses of the simulated latitudinal profile and of the seasonal cycle suggest that additional present-day data constraints, based on these characteristics, do not further constrain uncertainty in climate sensitivity. The novel approach presented in this thesis consists in systematically combining a large set of LGM simulations with data information from reconstructed regional glacial cooling. Irrespective of uncertainties in model parameters and feedback strengths, the set of our model versions reveals a close link between the simulated warming due to a doubling of CO2, and the cooling obtained for the LGM. Based on this close relationship between past and future temperature evolution, we define a method (based on linear regression) that allows us to estimate robust 5-95\% quantiles for climate sensitivity. We thus constrain the range of climate sensitivity to 1.3-3.5°C using proxy-data from the LGM at low and high latitudes. Uncertainties in glacial radiative forcing enlarge this estimate to 1.2-4.3°C, whereas the assumption of large structural uncertainties may increase the upper limit by an additional degree. Using proxy-based data constraints for tropical and Antarctic cooling we show that very different absolute temperature changes in high and low latitudes all yield very similar estimates of climate sensitivity. On the whole, this thesis highlights that LGM proxy-data information can offer an effective means of constraining the uncertainty range in climate sensitivity and thus underlines the potential of paleo-climatic data to reduce uncertainty in future climate projections.}, subject = {Dynamische Modellierung}, language = {en} } @phdthesis{Schmeja2006, author = {Schmeja, Stefan}, title = {Properties of turbulent star-forming clusters : models versus observations}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-7364}, school = {Universit{\"a}t Potsdam}, year = {2006}, abstract = {Stars are born in turbulent molecular clouds that fragment and collapse under the influence of their own gravity, forming a cluster of hundred or more stars. The star formation process is controlled by the interplay between supersonic turbulence and gravity. In this work, the properties of stellar clusters created by numerical simulations of gravoturbulent fragmentation are compared to those from observations. This includes the analysis of properties of individual protostars as well as statistical properties of the entire cluster. It is demonstrated that protostellar mass accretion is a highly dynamical and time-variant process. The peak accretion rate is reached shortly after the formation of the protostellar core. It is about one order of magnitude higher than the constant accretion rate predicted by the collapse of a classical singular isothermal sphere, in agreement with the observations. For a more reasonable comparison, the model accretion rates are converted to the observables bolometric temperature, bolometric luminosity, and envelope mass. The accretion rates from the simulations are used as input for an evolutionary scheme. The resulting distribution in the Tbol-Lbol-Menv parameter space is then compared to observational data by means of a 3D Kolmogorov-Smirnov test. The highest probability found that the distributions of model tracks and observational data points are drawn from the same population is 70\%. The ratios of objects belonging to different evolutionary classes in observed star-forming clusters are compared to the temporal evolution of the gravoturbulent models in order to estimate the evolutionary stage of a cluster. While it is difficult to estimate absolute ages, the realtive numbers of young stars reveal the evolutionary status of a cluster with respect to other clusters. The sequence shows Serpens as the youngest and IC 348 as the most evolved of the investigated clusters. Finally the structures of young star clusters are investigated by applying different statistical methods like the normalised mean correlation length and the minimum spanning tree technique and by a newly defined measure for the cluster elongation. The clustering parameters of the model clusters correspond in many cases well to those from observed ones. The temporal evolution of the clustering parameters shows that the star cluster builds up from several subclusters and evolves to a more centrally concentrated cluster, while the cluster expands slower than new stars are formed.}, subject = {Sternentstehung}, language = {en} } @phdthesis{Kleppek2005, author = {Kleppek, Sabine}, title = {Untersuchungen zur dynamischen Kopplung der Troposph{\"a}re und der Stratosph{\"a}re}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-6421}, school = {Universit{\"a}t Potsdam}, year = {2005}, abstract = {Im Rahmen dieser Arbeit wurde ein besseres Verst{\"a}ndnis der Kopplung der Troposph{\"a}re und der Stratosph{\"a}re in den mittleren und polaren Breiten der Nordhemisph{\"a}re (NH) auf Monatszeitskalen erzielt, die auf die Ausbreitung von quasi-station{\"a}ren Wellen zur{\"u}ckzuf{\"u}hren ist. Der Schwerpunkt lag dabei auf den dynamisch aktiven Wintermonaten, welche die gr{\"o}sste Variabilit{\"a}t aufweisen. Die troposph{\"a}rische Variabilit{\"a}t wird zum Grossteil durch bevorzugte Zirkulationsstrukturen, den Telekonnexionsmustern, bestimmt. Mittels einer rotierten EOF-Analyse der geopotenziellen H{\"o}he in 500 hPa wurden die wichtigsten regionalen troposph{\"a}rischen Telekonnexionsmuster der Nordhemisph{\"a}re berechnet. Diese lassen sich drei grossen geografischen Regionen zuordnen; dem nordatlantisch-europ{\"a}ischen Raum, Eurasien und dem pazifisch-nordamerikanischen Raum. Da es sich um die st{\"a}rksten troposph{\"a}rischen Variabilit{\"a}tsmuster handelt, wurden sie als grundlegende troposph{\"a}rische Gr{\"o}ssen herangezogen, um dynamische Zusammenh{\"a}nge zwischen der troposph{\"a}rischen und der stratosph{\"a}rischen Zirkulation zu untersuchen. Dabei wurde anhand von instantanen und zeitverz{\"o}gerten Korrelationsanalysen der troposph{\"a}rischen Muster mit stratosph{\"a}rischen Variablen erstmalig gezeigt, dass unterschiedliche regionale troposph{\"a}rische Telekonnexionsmuster unterschiedliche Auswirkungen auf die stratosph{\"a}rische Zirkulation haben. Es ergaben sich f{\"u}r die pazifisch-nordamerikanischen Muster signifikante instantane Korrelationen mit quasi-barotropen Musterstrukturen und f{\"u}r die nordatlantisch-europ{\"a}ischen Muster zonalsymmetrische Ringstrukturen ab 1978 mit signifikanten Korrelationswerten {\"u}ber tropischen und subtropischen Breiten und inversen Korrelationswerten {\"u}ber polaren Gebieten. Bei einer Untersuchung des Einflusses der stratosph{\"a}rischen Variabilit{\"a}t wurde gezeigt, dass sich die st{\"a}rkste Kopplung von nordatlantisch-europ{\"a}ischen Telekonnexionsmustern mit der stratosph{\"a}rischen Zirkulation bei einem in Richtung Europa verschobenen Polarwirbel ergibt, wodurch die signifikanten Korrelationen ab 1978 erkl{\"a}rt werden k{\"o}nnen. Eine zonal gemittelte und vor allem lokale Untersuchung der Wellenausbreitungsbedingungen w{\"a}hrend dieser stratosph{\"a}rischen Situation zeigt, dass es zu schw{\"a}cheren Windgeschwindigkeiten in der Stratosph{\"a}re im Bereich von Nordamerika und des westlichen Nordatlantiks kommt und sich dadurch die Wellenausbreitungsbedingungen in diesem geografischen Bereich f{\"u}r planetare Wellen verbessern. Durch die st{\"a}rkere Wellenausbreitung kommt es zu einer st{\"a}rkeren Wechselwirkung mit dem Polarjet, wobei dieser abgebremst wird. Diese Abbremsung f{\"u}hrt zu einer Verst{\"a}rkung der meridionalen Residualzirkulation. D. h., wenn es zu einer verst{\"a}rkten Wellenanregung im Nordatlantik und {\"u}ber Europa kommt, ist die Reaktion der Residualzirkulation bei einem nach Europa verschobenem Polarwirbel besonders stark. Die quasi-barotropen Korrelationsstrukturen, die sich bei den pazifisch-nordamerikanischen Mustern zeigen, weisen aufgrund von abnehmenden St{\"o}rungsamplituden mit zunehmender H{\"o}he, keiner Westw{\"a}rtsneigung und einem negativen Brechungsindex im Pazifik auf verschwindende Wellen hin, die als L{\"o}sung der Wellengleichung bei negativem Brechungsindex auftreten. Dies wird durch den Polarjet, der im Bereich des Pazifiks stets sehr weit in Richtung Norden verlagert ist, verursacht. Abschliessend wurde in dieser Arbeit untersucht, ob die gefundenen Zusammenh{\"a}nge von nordatlantisch-europ{\"a}ischen Telekonnexionsmustern mit der stratosph{\"a}rischen Zirkulation auch von einem Atmosph{\"a}renmodell wiedergegeben werden k{\"o}nnen. Dazu wurde ein transienter 40-Jahre-Klimalauf des ECHAM4.L39(DLR)/CHEM Modells mit m{\"o}glichst realistischen Antrieben erstmalig auf die Kopplung der Troposph{\"a}re und der Stratosph{\"a}re analysiert. Dabei konnten sowohl die troposph{\"a}rischen, als auch die stratosph{\"a}rischen Variabilit{\"a}tsmuster vom Modell simuliert werden. Allerdings zeigen sich in den stratosph{\"a}rischen Mustern Phasenverschiebungen in den Wellenzahl-1-Strukturen und ihre Zeitreihen weisen keinen signifikanten Trend ab 1978 auf. Die Kopplung der nordatlantisch-europ{\"a}ischen Telekonnexionsmuster mit der stratosph{\"a}rischen Zirkulation zeigt eine wesentlich schw{\"a}chere Reaktion der meridionalen Residualzirkulation. Somit stellte sich heraus, dass insbesondere die stratosph{\"a}rische Zirkulation im Modell starke Diskrepanzen zu den Beobachtungen zeigt, die wiederum Einfluss auf die Wellenausbreitungsbedingungen haben. Es wird damit deutlich, dass f{\"u}r eine richtige Wiedergabe der Wellenausbreitung und somit der Kopplung der Troposph{\"a}re und Stratosph{\"a}re die stratosph{\"a}rische Zirkulation eine wichtige Rolle spielt.}, subject = {Wellenausbreitung}, language = {de} } @unpublished{Feudel1996, author = {Feudel, Ulrike}, title = {Komplexes Verhalten in multistabilen, schwach dissipativen Systemen}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-14412}, year = {1996}, abstract = {Anhand eines paradigmatischen Modellbeispiels werden die Konsequenzen der Koexistenz vieler Attraktoren auf die globale Dynamik schwach dissipativer Systeme studiert. Es wird gezeigt, dass diese Systeme eine sehr reichhaltige Dynamik besitzen und extrem sensitiv gegen{\"u}ber St{\"o}rungen in den Anfangsbedingungen sind. Diese Systeme zeichnen sich durch eine extrem hohe Flexibilit{\"a}t ihres Verhaltens aus.}, language = {de} } @unpublished{ZakharovMeister2000, author = {Zakharov, Venjamin E. and Meister, Claudia-Veronika}, title = {Acceleration and heating in the auroral magnetosphere by current driven electrostatic ion cyclotron turbulence}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-14959}, year = {2000}, abstract = {A numerical MHD model is developed to investigate acceleration and heating of both thermal and auroral plasma. This is done for magnetospheric flux tubes in which intensive field aligned currents flow. To give each of these tubes, the empirical Tsyganenko model of the magnetospheric field is used. The parameters of the background plasma outside the flux tube as well as the strength of the electric field of magnetospheric convection are given. Performing the numerical calculations, the distributions of the plasma densities, velocities, temperatures, parallel electric field and current, and of the coefficients of thermal conductivity are obtained in a self-consistent way. It is found that EIC turbulence develops effectively in the thermal plasma. The parallel electric field develops under the action of the anomalous resistivity. This electric field accelerates both the thermal and the auroral plasma. The thermal turbulent plasma is also subjected to an intensive heating. The increase of the plasma of the Earth's ionosphere. Besides, studying the growth and dispersion properties of oblique ion cyclotron waves excited in a drifting magnetized plasma, it is shown that under non-stationary conditions such waves may reveal the properties of bursts of polarized transverse electromagnetic waves at frequencies near the patron gyrofrequency.}, language = {en} } @unpublished{VolosevichMeister2000, author = {Volosevich, Alexandra and Meister, Claudia-Veronika}, title = {Nonlinear electrostatic ion-acoustic waves in the solar atmosphere}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-14968}, year = {2000}, abstract = {Basing on recent solar models, the excitation of ion-acoustic turbulence in the weaklycollisional, fully and partially-ionized regions of the solar atmosphere is investigated. Within the frame of hydrodynamics, conditions are found under which the heating of the plasma by ion-acoustic type waves is more effective than the Joule heating. Taking into account wave and Joule heating effects, a nonlinear differential equation is derived, which describes the evolution of nonlinear ion-acoustic waves in the collisional plasma.}, language = {en} } @unpublished{MeisterDziourkevich2000, author = {Meister, Claudia-Veronika and Dziourkevich, Natalia S.}, title = {Temperature-anisotropy driven mirror waves in space plasma}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-14977}, year = {2000}, abstract = {In this paper an analysis of the excitation conditions of mirror waves is done, which propagate parallel to an external magnetic field. There are found analytical expressions for the dispersion relations of the waves in case of different plasma conditions. These relations may be used in future to develop the nonlinear theory of mirror waves. In comparison with former analytical works, in the study the inuence of the magnetic field and nite temperatures of the ions parallel to the magnetic field are taken into account. Application is done for the earth's magnetosheath.}, language = {en} } @unpublished{LiperovskyMeisterDodaetal.2005, author = {Liperovsky, V. A. and Meister, Claudia-Veronika and Doda, L. N. and Liperovskaya, E. V. and Davidov, V. F. and Bogdanov, V. V.}, title = {On the possible influence of radon and aerosol injection on the atmosphere and ionosphere before earthquakes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-14995}, year = {2005}, abstract = {A model of the generation of pulses of local electric fields with characteristic time scales of 1-10 minutes is considered for atmospheric conditions above fracture regions of earthquakes. In the model, it is proposed that aerosols, increased ionization velocity and upstreaming air flows occur at night-time conditions. The pulses of local electric fields cause respective pulses of infrared emissions. But infrared emissions with time scales of 1-10 minutes were not observed up to now experimentally. The authors think, that the considered non-stationary field and radiation effects might be a new-type of applicable earthquake indicators and ask to perform special earth-based and satellite observations of the night-time atmosphere in seismoactive fracture regions.}, language = {en} } @unpublished{LiperovskayaMeisterParrotetal.2006, author = {Liperovskaya, E. V. and Meister, Claudia-Veronika and Parrot, M. and Bogdanov, V. V. and Vasil'eva, N. E.}, title = {On Es-spread effects in the ionosphere connected to earthquakes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-15003}, year = {2006}, abstract = {In the present work, phenomena in the ionosphere are studied, which are connected with earthquakes (16 events) having a depth of less than 50 km and a magnitude M larger than 4. Analysed are night-time Es-spread effects using data of the vertical sounding station Petropavlovsk- Kanchatsky (φ=53.0°, λ=158.7°) from May 2004 until August 2004 registered every 15 minutes. It is found that the maximum distance of the earthquake from the sounding station, where pre-seismic phenomena are yet observable, depends on the magnitude of the earthquake. Further it is shown that 1-2 days before the earthquakes, in the premidnight hours, the appearance of Es-spread increases. The reliability of this increase amounts to 0.95.}, language = {en} } @unpublished{LiperovskayaParrotBogdanovetal.2006, author = {Liperovskaya, E. V. and Parrot, M. and Bogdanov, V. V. and Meister, Claudia-Veronika and Rodkin, M. V. and Liperovsky, V. A.}, title = {On long-term variations of foF2 in the mid-latitude ionosphere before strong earthquakes}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-15017}, year = {2006}, abstract = {The statistical analysis of the variations of the dayly-mean frequency of the maximum ionospheric electron density foF2 is performed in connection with the occurrence of (more than 60) earthquakes with magnitudes M > 6.0, depths h < 80 km and distances from the vertical sounding station R < 1000 km. For the study, data of the Tokyo sounding station are used, which were registered every hour in the years 1957-1990. It is shown that, on the average, foF2 decreases before the earthquakes. One day before the shock the decrease amounts to about 5 \%. The statistical reliability of this phenomenon is obtained to be better than 0.95. Further, the variations of the occurrence probability of the turbulization of the F-layer (F spread) are investigated for (more than 260) earthquakes with M > 5.5, h < 80 km, R < 1000 km. For the analysis, data of the Japanese station Akita from 1969-1990 are used, which were obtained every hour. It is found that before the earthquakes the occurrence probability of F spread decreases. In the week before the event, the decrease has values of more than 10 \%. The statistical reliability of this phenomenon is also larger than 0.95. Examining the seismo-ionospheric effects, here periods of time with weak heliogeomagnetic disturbances are considered, the Wolf number is less than 100 and the index ∑ Kp is smaller than 30.}, language = {en} } @phdthesis{Zou2007, author = {Zou, Yong}, title = {Exploring recurrences in quasiperiodic systems}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16497}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {In this work, some new results to exploit the recurrence properties of quasiperiodic dynamical systems are presented by means of a two dimensional visualization technique, Recurrence Plots(RPs). Quasiperiodicity is the simplest form of dynamics exhibiting nontrivial recurrences, which are common in many nonlinear systems. The concept of recurrence was introduced to study the restricted three body problem and it is very useful for the characterization of nonlinear systems. I have analyzed in detail the recurrence patterns of systems with quasiperiodic dynamics both analytically and numerically. Based on a theoretical analysis, I have proposed a new procedure to distinguish quasiperiodic dynamics from chaos. This algorithm is particular useful in the analysis of short time series. Furthermore, this approach demonstrates to be efficient in recognizing regular and chaotic trajectories of dynamical systems with mixed phase space. Regarding the application to real situations, I have shown the capability and validity of this method by analyzing time series from fluid experiments.}, language = {en} } @book{Gutlederer2007, author = {Gutlederer, Erwin Johann}, title = {On the morphology of vesicles. - [{\"u}berarb. Diss.]}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-15065}, publisher = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {This dissertation contains theoretical investigations on the morphology and statistical mechanics of vesicles. The shapes of homogeneous fluid vesicles and inhomogeneous vesicles with fluid and solid membrane domains are calculated. The influence of thermal fluctuations is investigated. The obtained results are valid on mesoscopic length scales and are based on a geometrical membrane model, where the vesicle membrane is described as either a static or a thermal fluctuating surface. The thesis consists of three parts. In the first part, homogeneous vesicles are considered. The focus in this part is on the thermally induced morphological transition between vesicles with prolate and oblate shape. With the help of Monte Carlo simulations, the free energy profile of these vesicles is determined. It can be shown that the shape transformation between prolate and oblate vesicles proceeds continuously and is not hampered by a free energy barrier. The second and third part deal with inhomogeneous vesicles which contain intramembrane domains. These investigations are motivated by experimental results on domain formation in single or multicomponent vesicles, where phase separation occurs and different membrane phases coexist. The resulting domains differ with regard to their membrane structure (solid, fluid). The membrane structure has a distinct effect on the form of the domain and the morphology of the vesicle. In the second part, vesicles with coexisting solid and fluid membrane domains are studied, while the third part addresses vesicles with coexisting fluid domains. The equilibrium morphology of vesicles with simple and complex domain forms, derived through minimisation of the membrane energy, is determined as a function of material parameters. The results are summarised in morphology diagrams. These diagrams show previously unknown morphological transitions between vesicles with different domain shapes. The impact of thermal fluctuations on the vesicle and the form of the domains is investigated by means of Monte Carlo simulations.}, language = {en} } @phdthesis{Brand2007, author = {Brand, Sascha}, title = {Klimavariabilit{\"a}t der Tropo- und Stratosph{\"a}re in einem globalen gekoppelten Atmosph{\"a}re-Ozean-Modell mit vereinfachter stratosph{\"a}rischer Chemie}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16602}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {In dieser Arbeit wurde die Variabilit{\"a}t der Atmosph{\"a}re in einem neuen gekoppelten Klimamodell (ECHO-GiSP) untersucht, welches eine vereinfachte Stratosph{\"a}renchemie (bis 80 km H{\"o}he) enth{\"a}lt. Es wurden 2 Simulationen {\"u}ber 150 Jahre durchgef{\"u}hrt. In einer der Simulationen wurde die atmosph{\"a}rische Chemie modelliert, hatte aber keinen Einfluß auf die Dynamik des Klimamodelles. In der zweiten Simulation wurde hingegen die Wirkung der Chemie auf die Klimadynamik explizit ber{\"u}cksichtigt, die {\"u}ber die Strahlungsbilanz des Modelles erfolgt. Dies ist die erste Langzeitsimulation mit einem voll gekoppelten globalen Klimamodell mit interaktiver Chemie. Die Simulation mit r{\"u}ckgekoppelter Chemie zeigt eine Abschw{\"a}chung des atmosph{\"a}rischen Variabilit{\"a}tsmusters der Arktischen Oszillation (AO). Zudem kommt es in der Troposph{\"a}re zu einer Reduzierung der mittleren Windgeschwindigkeiten der gem{\"a}ßigten Breiten aufgrund verringerter Temperaturgegens{\"a}tze zwischen den Tropen und den Polargebieten. Auch in der Stratosph{\"a}re ergibt sich eine Abschw{\"a}chung und Erw{\"a}rmung des Polarwirbels. Diese Auswirkungen der Kopplung zwischen der atmosph{\"a}rischen Chemie und der Dynamik des Klimamodelles sind eine wichtige Erkenntnis, da in fr{\"u}heren Klimasimulationen die Variabilit{\"a}t der AO oft zu stark ausgepr{\"a}gt war. In der Stratosph{\"a}re reduziert sich infolge des abgeschw{\"a}chten Polarwirbels auch die großr{\"a}umige Zirkulation zwischen den beiden Hemisph{\"a}ren der Erde. In der Troposph{\"a}re werden hingegen die allgemeine Zirkulation, und damit auch die subtropischen Strahlstr{\"o}me des Windes verst{\"a}rkt. Zudem kommt es in den Tropen zu Temperatur{\"a}nderungen durch stratosph{\"a}rische Ozonschwankungen in Abh{\"a}ngigkeit von der AO. Allgemein ver{\"a}ndert sich die Kopplung zwischen Troposph{\"a}re und Stratosph{\"a}re, einschließlich des durch die Anregung von langen atmosph{\"a}rischen Wellen erfolgenden vertikalen Energie{\"u}bertrages aus der Troposph{\"a}re in die Stratosph{\"a}re.}, language = {de} } @phdthesis{Seefeldt2008, author = {Seefeldt, Michael}, title = {Pikosekunden-Weißlichterzeugung in mikrostrukturierten Fasern unter Ausnutzung nichtlinear optischer Effekte}, publisher = {Universit{\"a}tsverlag Potsdam}, address = {Potsdam}, isbn = {978-3-940793-20-1}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-16461}, school = {Universit{\"a}t Potsdam}, pages = {x, 133}, year = {2008}, abstract = {Im Rahmen der vorliegenden Arbeit ist es erstmals gelungen, mit einem ps-Pumplaser (10 ps) Weißlicht mit einer spektralen Breite von mehr als einer optischen Oktave in einer mikrostrukturierten Faser (MSF) bei einer Pumpwellenl{\"a}nge von 1064 nm zu generieren. Es ließ sich, abgesehen von nichtkonvertierten Resten der Pumpstrahlung, ein unstrukturiertes und zeitlich stabiles Weißlichtspektrum von 700 nm bis 1650 nm generieren. Die maximale Ausgangsleistung dieser Weißlichtstrahlung betrug 3,1 W. Es konnten sehr gute Einkoppeleffizienzen von maximal 62 \% erzielt werden. Die an der Weißlichterzeugung beteiligten dispersiven und nichtlinear optischen Effekte, wie z.B. Selbstphasenmodulation, Vierwellenmischung, Modulationsinstabilit{\"a}ten oder Solitoneneffekte, werden detailliert theoretisch untersucht und erl{\"a}utert. Die Arbeit beinhaltet ebenfalls eine umfangreiche Beschreibung der Wirkungsweise und Eigenschaften von mikrostrukturierten Fasern mit einem festen Faserkern. Aufgrund der großen Variationsvielfalt des mikrostrukturierten Fasermantels und der damit verbundenen Wellenleitereigenschaften ergeben sich, insbesondere f{\"u}r die Anwendung in der nichtlinearen Optik, eine Reihe von interessanten Eigenschaften. Es wurden insgesamt vier verschiedene mikrostrukturierte Fasern experimentell untersucht. F{\"u}r die Interpretation der experimentellen Ergebnisse ist die Pulsausbreitung der ps-Pumppulse in einer dispersiven, nichtlinear optischen Faser anhand der verallgemeinerten nichtlinearen Schr{\"o}dinger-Gleichung berechnet worden. Durch einen Vergleich der Berechnungen mit den Messdaten ließen sich verst{\"a}rkte Modulationsinstabilit{\"a}ten und verschiedene Solitoneneffekte als haupts{\"a}chlich f{\"u}r die Weißlichterzeugung bei ps-Anregungspulsen verantwortlich identifizieren. Auf der Basis der durchgef{\"u}hrten Untersuchungen wurde in Kooperation mit der Fa. Jenoptik Laser, Optik, Systeme GmbH eine kompakte und leistungsstarke Weißlichtquelle entwickelt. Diese wurde erfolgreich in einer Koh{\"a}renztomographiemessung (Optical Coherence Tomography - OCT) getestet: Es konnte in ex vivo-Untersuchungen gezeigt werden, dass sich mit dieser ps-Weißlichtquelle eine hohe Eindringtiefe von ca. 400 µm in die Netzhaut eines Affen erreichen l{\"a}sst.}, language = {de} } @phdthesis{Weikl2007, author = {Weikl, Thomas R.}, title = {Transition states and loop-closure principles in protein folding}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-26975}, school = {Universit{\"a}t Potsdam}, year = {2007}, abstract = {Proteins are chain molecules built from amino acids. The precise sequence of the 20 different types of amino acids in a protein chain defines into which structure a protein folds, and the three-dimensional structure in turn specifies the biological function of the protein. The reliable folding of proteins is a prerequisite for their robust function. Misfolding can lead to protein aggregates that cause severe diseases, such as Alzheimer's, Parkinson's, or the variant Creutzfeldt-Jakob disease. Small single-domain proteins often fold without experimentally detectable metastable intermediate states. The folding dynamics of these proteins is thought to be governed by a single transition-state barrier between the unfolded and the folded state. The transition state is highly instable and cannot be observed directly. However, mutations in which a single amino acid of the protein is substituted by another one can provide indirect access. The mutations slightly change the transition-state barrier and, thus, the folding and unfolding times of the protein. The central question is how to reconstruct the transition state from the observed changes in folding times. In this habilitation thesis, a novel method to extract structural information on transition states from mutational data is presented. The method is based on (i) the cooperativity of structural elements such as alpha-helices and beta-hairpins, and (ii) on splitting up mutation-induced free-energy changes into components for these elements. By fitting few parameters, the method reveals the degree of structure formation of alpha-helices and beta-hairpins in the transition state. In addition, it is shown in this thesis that the folding routes of small single-domain proteins are dominated by loop-closure dependencies between the structural elements.}, language = {en} }