@article{DebPopovaJaffresetal.2022, author = {Deb, Marwan and Popova, Elena and Jaffr{\`e}s, Henri-Yves and Keller, Niels and Bargheer, Matias}, title = {Polarization-dependent subpicosecond demagnetization in iron garnets}, series = {Physical review : B, covering condensed matter and materials physics}, volume = {106}, journal = {Physical review : B, covering condensed matter and materials physics}, number = {18}, publisher = {American Institute of Physics, American Physical Society}, address = {Woodbury, NY}, issn = {2469-9950}, doi = {10.1103/PhysRevB.106.184416}, pages = {7}, year = {2022}, abstract = {Controlling the magnetization dynamics at the fastest speed is a major issue of fundamental condensed matter physics and its applications for data storage and processing technologies. It requires a deep understanding of the interactions between the degrees of freedom in solids, such as spin, electron, and lattice as well as their responses to external stimuli. In this paper, we systematically investigate the fluence dependence of ultrafast magnetization dynamics induced by below-bandgap ultrashort laser pulses in the ferrimagnetic insulators BixY3-xFe5O12 with 1 xBi 3. We demonstrate subpicosecond demagnetization dynamics in this material followed by a very slow remagnetization process. We prove that this demagnetization results from an ultrafast heating of iron garnets by two-photon absorption (TPA), suggesting a phonon-magnon thermalization time of 0.6 ps. We explain the slow remagnetization timescale by the low phonon heat conductivity in garnets. Additionally, we show that the amplitudes of the demagnetization, optical change, and lattice strain can be manipulated by changing the ellipticity of the pump pulses. We explain this phenomenon considering the TPA circular dichroism. These findings open exciting prospects for ultrafast manipulation of spin, charge, and lattice dynamics in magnetic insulators by ultrafast nonlinear optics.}, language = {en} } @article{DebPopovaJaffresetal.2022, author = {Deb, Marwan and Popova, Elena and Jaffr{\`e}s, Henri-Yves and Keller, Niels and Bargheer, Matias}, title = {Controlling high-frequency spin-wave dynamics using double-pulse laser excitation}, series = {Physical review applied}, volume = {18}, journal = {Physical review applied}, number = {4}, publisher = {American Physical Society}, address = {College Park}, issn = {2331-7019}, doi = {10.1103/PhysRevApplied.18.044001}, pages = {7}, year = {2022}, abstract = {Manipulating spin waves is highly required for the development of innovative data transport and processing technologies. Recently, the possibility of triggering high-frequency standing spin waves in magnetic insulators using femtosecond laser pulses was discovered, raising the question about how one can manipulate their dynamics. Here we explore this question by investigating the ultrafast magnetiza-tion and spin-wave dynamics induced by double-pulse laser excitation. We demonstrate a suppression or enhancement of the amplitudes of the standing spin waves by precisely tuning the time delay between the two pulses. The results can be understood as the constructive or destructive interference of the spin waves induced by the first and second laser pulses. Our findings open exciting perspectives towards generating single-mode standing spin waves that combine high frequency with large amplitude and low magnetic damping.}, language = {en} } @article{MarinBeloquiZhangGuoetal.2022, author = {Marin-Beloqui, Jose and Zhang, Guanran and Guo, Junjun and Shaikh, Jordan and Wohrer, Thibaut and Hosseini, Seyed Mehrdad and Sun, Bowen and Shipp, James and Auty, Alexander J. and Chekulaev, Dimitri and Ye, Jun and Chin, Yi-Chun and Sullivan, Michael B. and Mozer, Attila J. and Kim, Ji-Seon and Shoaee, Safa and Clarke, Tracey M.}, title = {Insight into the origin of trapping in polymer/fullerene blends with a systematic alteration of the fullerene to higher adducts}, series = {Journal of physical chemistry C}, volume = {126}, journal = {Journal of physical chemistry C}, number = {5}, publisher = {American Chemical Society}, address = {Washington}, issn = {1932-7447}, doi = {10.1021/acs.jpcc.1c10378}, pages = {2708 -- 2719}, year = {2022}, abstract = {The bimolecular recombination characteristics of conjugated polymer poly[(4,4'-bis(2-ethylhexyl)dithieno[3,2-b:2',3'-d]silole)-2,6-diyl-alt-(2,5-bis 3-tetradecylthiophen-2-y1 thiazolo 5,4-d thiazole)-2,5diy1] (PDTSiTTz) blended with the fullerene series PC60BM, ICMA, ICBA, and ICTA have been investigated using microsecond and femtosecond transient absorption spectroscopy, in conjunction with electroluminescence measurements and ambient photoemission spectroscopy. The non-Langevin polymer PDTSiTTz allows an inspection of intrinsic bimolecular recombination rates uninhibited by diffusion, while the low oscillator strengths of fullerenes allow polymer features to dominate, and we compare our results to those of the well-known polymer Si-PCPDTBT. Using mu s-TAS, we have shown that the trap -limited decay dynamics of the PDTSiTTz polaron becomes progressively slower across the fullerene series, while those of Si-PCPDTBT are invariant. Electroluminescence measurements showed an unusual double peak in pristine PDTSiTTz, attributed to a low energy intragap charge transfer state, likely interchain in nature. Furthermore, while the pristine PDTSiTTz showed a broad, low-intensity density of states, the ICBA and ICTA blends presented a virtually identical DOS to Si-PCPDTBT and its blends. This has been attributed to a shift from a delocalized, interchain highest occupied molecular orbital (HOMO) in the pristine material to a dithienosilole-centered HOMO in the blends, likely a result of the bulky fullerenes increasing interchain separation. This HOMO localization had a side effect of progressively shifting the polymer HOMO to shallower energies, which was correlated with the observed decrease in bimolecular recombination rate and increased "trap" depth. However, since the density of tail states remained the same, this suggests that the traditional viewpoint of "trapping" being dominated by tail states may not encompass the full picture and that the breadth of the DOS may also have a strong influence on bimolecular recombination.}, language = {en} } @article{MayerLeverPicconietal.2022, author = {Mayer, Dennis and Lever, Fabiano and Picconi, David and Metje, Jan and Ališauskas, Skirmantas and Calegari, Francesca and D{\"u}sterer, Stefan and Ehlert, Christopher and Feifel, Raimund and Niebuhr, Mario and Manschwetus, Bastian and Kuhlmann, Marion and Mazza, Tommaso and Robinson, Matthew Scott and Squibb, Richard James and Trabattoni, Andrea and Wallner, M{\aa}ns and Saalfrank, Peter and Wolf, Thomas J. A. and G{\"u}hr, Markus}, title = {Following excited-state chemical shifts in molecular ultrafast x-ray photoelectron spectroscopy}, series = {Nature Communications}, volume = {13}, journal = {Nature Communications}, publisher = {Springer Nature}, address = {Berlin}, issn = {2041-1723}, doi = {10.1038/s41467-021-27908-y}, pages = {9}, year = {2022}, abstract = {The conversion of photon energy into other energetic forms in molecules is accompanied by charge moving on ultrafast timescales. We directly observe the charge motion at a specific site in an electronically excited molecule using time-resolved x-ray photoelectron spectroscopy (TR-XPS). We extend the concept of static chemical shift from conventional XPS by the excited-state chemical shift (ESCS), which is connected to the charge in the framework of a potential model. This allows us to invert TR-XPS spectra to the dynamic charge at a specific atom. We demonstrate the power of TR-XPS by using sulphur 2p-core-electron-emission probing to study the UV-excited dynamics of 2-thiouracil. The method allows us to discover that a major part of the population relaxes to the molecular ground state within 220-250 fs. In addition, a 250-fs oscillation, visible in the kinetic energy of the TR-XPS, reveals a coherent exchange of population among electronic states.}, language = {en} } @article{VilkAghionAvgaretal.2022, author = {Vilk, Ohad and Aghion, Erez and Avgar, Tal and Beta, Carsten and Nagel, Oliver and Sabri, Adal and Sarfati, Raphael and Schwartz, Daniel K. and Weiß, Matthias and Krapf, Diego and Nathan, Ran and Metzler, Ralf and Assaf, Michael}, title = {Unravelling the origins of anomalous diffusion}, series = {Physical review research / American Physical Society}, volume = {4}, journal = {Physical review research / American Physical Society}, number = {3}, publisher = {American Physical Society}, address = {College Park, MD}, issn = {2643-1564}, doi = {10.1103/PhysRevResearch.4.033055}, pages = {16}, year = {2022}, abstract = {Anomalous diffusion or, more generally, anomalous transport, with nonlinear dependence of the mean-squared displacement on the measurement time, is ubiquitous in nature. It has been observed in processes ranging from microscopic movement of molecules to macroscopic, large-scale paths of migrating birds. Using data from multiple empirical systems, spanning 12 orders of magnitude in length and 8 orders of magnitude in time, we employ a method to detect the individual underlying origins of anomalous diffusion and transport in the data. This method decomposes anomalous transport into three primary effects: long-range correlations ("Joseph effect"), fat-tailed probability density of increments ("Noah effect"), and nonstationarity ("Moses effect"). We show that such a decomposition of real-life data allows us to infer nontrivial behavioral predictions and to resolve open questions in the fields of single-particle tracking in living cells and movement ecology.}, language = {en} } @article{BrinkmannBeckerZimmermannetal.2022, author = {Brinkmann, Kai Oliver and Becker, Tim and Zimmermann, Florian and Kreusel, Cedric and Gahlmann, Tobias and Theisen, Manuel and Haeger, Tobias and Olthof, Selina and T{\"u}ckmantel, Christian and G{\"u}nster, M. and Maschwitz, Timo and G{\"o}belsmann, Fabian and Koch, Christine and Hertel, Dirk and Caprioglio, Pietro and Pe{\~n}a-Camargo, Francisco and Perdig{\´o}n-Toro, Lorena and Al-Ashouri, Amran and Merten, Lena and Hinderhofer, Alexander and Gomell, Leonie and Zhang, Siyuan and Schreiber, Frank and Albrecht, Steve and Meerholz, Klaus and Neher, Dieter and Stolterfoht, Martin and Riedl, Thomas}, title = {Perovskite-organic tandem solar cells with indium oxide interconnect}, series = {Nature}, volume = {604}, journal = {Nature}, number = {7905}, publisher = {Nature Research}, address = {Berlin}, issn = {0028-0836}, doi = {10.1038/s41586-022-04455-0}, pages = {280 -- 286}, year = {2022}, abstract = {Multijunction solar cells can overcome the fundamental efficiency limits of single-junction devices. The bandgap tunability of metal halide perovskite solar cells renders them attractive for multijunction architectures(1). Combinations with silicon and copper indium gallium selenide (CIGS), as well as all-perovskite tandem cells, have been reported(2-5). Meanwhile, narrow-gap non-fullerene acceptors have unlocked skyrocketing efficiencies for organic solar cells(6,7). Organic and perovskite semiconductors are an attractive combination, sharing similar processing technologies. Currently, perovskite-organic tandems show subpar efficiencies and are limited by the low open-circuit voltage (V-oc) of wide-gap perovskite cells(8) and losses introduced by the interconnect between the subcells(9,10). Here we demonstrate perovskite-organic tandem cells with an efficiency of 24.0 per cent (certified 23.1 per cent) and a high V-oc of 2.15 volts. Optimized charge extraction layers afford perovskite subcells with an outstanding combination of high V-oc and fill factor. The organic subcells provide a high external quantum efficiency in the near-infrared and, in contrast to paradigmatic concerns about limited photostability of non-fullerene cells(11), show an outstanding operational stability if excitons are predominantly generated on the non-fullerene acceptor, which is the case in our tandems. The subcells are connected by an ultrathin (approximately 1.5 nanometres) metal-like indium oxide layer with unprecedented low optical/electrical losses. This work sets a milestone for perovskite-organic tandems, which outperform the best p-i-n perovskite single junctions(12) and are on a par with perovskite-CIGS and all-perovskite multijunctions(13).}, language = {en} } @article{PenaCamargoThiesbrummelHempeletal.2022, author = {Pena-Camargo, Francisco and Thiesbrummel, Jarla and Hempel, Hannes and Musiienko, Artem and Le Corre, Vincent M. and Diekmann, Jonas and Warby, Jonathan and Unold, Thomas and Lang, Felix and Neher, Dieter and Stolterfoht, Martin}, title = {Revealing the doping density in perovskite solar cells and its impact on device performance}, series = {Applied physics reviews}, volume = {9}, journal = {Applied physics reviews}, number = {2}, publisher = {AIP Publishing}, address = {Melville}, issn = {1931-9401}, doi = {10.1063/5.0085286}, pages = {11}, year = {2022}, abstract = {Traditional inorganic semiconductors can be electronically doped with high precision. Conversely, there is still conjecture regarding the assessment of the electronic doping density in metal-halide perovskites, not to mention of a control thereof. This paper presents a multifaceted approach to determine the electronic doping density for a range of different lead-halide perovskite systems. Optical and electrical characterization techniques, comprising intensity-dependent and transient photoluminescence, AC Hall effect, transfer-length-methods, and charge extraction measurements were instrumental in quantifying an upper limit for the doping density. The obtained values are subsequently compared to the electrode charge per cell volume under short-circuit conditions ( CUbi/eV), which amounts to roughly 10(16) cm(-3). This figure of merit represents the critical limit below which doping-induced charges do not influence the device performance. The experimental results consistently demonstrate that the doping density is below this critical threshold 10(12) cm(-3), which means << CUbi / e V) for all common lead-based metal-halide perovskites. Nevertheless, although the density of doping-induced charges is too low to redistribute the built-in voltage in the perovskite active layer, mobile ions are present in sufficient quantities to create space-charge-regions in the active layer, reminiscent of doped pn-junctions. These results are well supported by drift-diffusion simulations, which confirm that the device performance is not affected by such low doping densities.}, language = {en} } @article{MatternReppertZeuschneretal.2022, author = {Mattern, Maximilian and Reppert, Alexander von and Zeuschner, Steffen Peer and Pudell, Jan-Etienne and K{\"u}hne, F. and Diesing, Detlef and Herzog, Marc and Bargheer, Matias}, title = {Electronic energy transport in nanoscale Au/Fe hetero-structures in the perspective of ultrafast lattice dynamics}, series = {Applied physics letters}, volume = {120}, journal = {Applied physics letters}, number = {9}, publisher = {AIP Publishing}, address = {Melville}, issn = {0003-6951}, doi = {10.1063/5.0080378}, pages = {5}, year = {2022}, abstract = {We study the ultrafast electronic transport of energy in a photoexcited nanoscale Au/Fe hetero-structure by modeling the spatiotemporal profile of energy densities that drives transient strain, which we quantify by femtosecond x-ray diffraction. This flow of energy is relevant for intrinsic demagnetization and ultrafast spin transport. We measured lattice strain for different Fe layer thicknesses ranging from few atomic layers to several nanometers and modeled the spatiotemporal flow of energy densities. The combination of a high electron-phonon coupling coefficient and a large Sommerfeld constant in Fe is found to yield electronic transfer of nearly all energy from Au to Fe within the first hundreds of femtoseconds.}, language = {en} } @article{LeCorreDiekmannPenaCamargoetal.2022, author = {Le Corre, Vincent M. and Diekmann, Jonas and Pe{\~n}a-Camargo, Francisco and Thiesbrummel, Jarla and Tokmoldin, Nurlan and Gutierrez-Partida, Emilio and Peters, Karol Pawel and Perdig{\´o}n-Toro, Lorena and Futscher, Moritz H. and Lang, Felix and Warby, Jonathan and Snaith, Henry J. and Neher, Dieter and Stolterfoht, Martin}, title = {Quantification of efficiency losses due to mobile ions in Perovskite solar cells via fast hysteresis measurements}, series = {Solar RRL}, volume = {6}, journal = {Solar RRL}, number = {4}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {2367-198X}, doi = {10.1002/solr.202100772}, pages = {10}, year = {2022}, abstract = {Perovskite semiconductors differ from most inorganic and organic semiconductors due to the presence of mobile ions in the material. Although the phenomenon is intensively investigated, important questions such as the exact impact of the mobile ions on the steady-state power conversion efficiency (PCE) and stability remain. Herein, a simple method is proposed to estimate the efficiency loss due to mobile ions via "fast-hysteresis" measurements by preventing the perturbation of mobile ions out of their equilibrium position at fast scan speeds (approximate to 1000 V s(-1)). The "ion-free" PCE is between 1\% and 3\% higher than the steady-state PCE, demonstrating the importance of ion-induced losses, even in cells with low levels of hysteresis at typical scan speeds (approximate to 100mv s(-1)). The hysteresis over many orders of magnitude in scan speed provides important information on the effective ion diffusion constant from the peak hysteresis position. The fast-hysteresis measurements are corroborated by transient charge extraction and capacitance measurements and numerical simulations, which confirm the experimental findings and provide important insights into the charge carrier dynamics. The proposed method to quantify PCE losses due to field screening induced by mobile ions clarifies several important experimental observations and opens up a large range of future experiments.}, language = {en} } @article{ZeiskeSandbergZarrabietal.2022, author = {Zeiske, Stefan and Sandberg, Oskar J. and Zarrabi, Nasim and Wolff, Christian Michael and Raoufi, Meysam and Pe{\~n}a-Camargo, Francisco and Gutierrez-Partida, Emilio and Meredith, Paul and Stolterfoht, Martin and Armin, Ardalan}, title = {Static disorder in lead halide perovskites}, series = {The journal of physical chemistry letters}, volume = {13}, journal = {The journal of physical chemistry letters}, number = {31}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.2c01652}, pages = {7280 -- 7285}, year = {2022}, abstract = {In crystalline and amorphous semiconductors, the temperature-dependent Urbach energy can be determined from the inverse slope of the logarithm of the absorption spectrum and reflects the static and dynamic energetic disorder. Using recent advances in the sensitivity of photocurrent spectroscopy methods, we elucidate the temperature-dependent Urbach energy in lead halide perovskites containing different numbers of cation components. We find Urbach energies at room temperature to be 13.0 +/- 1.0, 13.2 +/- 1.0, and 13.5 +/- 1.0 meV for single, double, and triple cation perovskite. Static, temperature-independent contributions to the Urbach energy are found to be as low as 5.1 ?+/- 0.5, 4.7 +/- 0.3, and 3.3 +/- 0.9 meV for the same systems. Our results suggest that, at a low temperature, the dominant static disorder in perovskites is derived from zero-point phonon energy rather than structural disorder. This is unusual for solution-processed semiconductors but broadens the potential application of perovskites further to quantum electronics and devices.}, language = {en} } @article{HerzogReppertPudelletal.2022, author = {Herzog, Marc and Reppert, Alexander von and Pudell, Jan-Etienne and Henkel, Carsten and Kronseder, Matthias and Back, Christian H. and Maznev, Alexei A. and Bargheer, Matias}, title = {Phonon-dominated energy transport in purely metallic heterostructures}, series = {Advanced functional materials}, volume = {32}, journal = {Advanced functional materials}, number = {41}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1616-301X}, doi = {10.1002/adfm.202206179}, pages = {8}, year = {2022}, abstract = {Ultrafast X-ray diffraction is used to quantify the transport of energy in laser-excited nanoscale gold-nickel (Au-Ni) bilayers. Electron transport and efficient electron-phonon coupling in Ni convert the laser-deposited energy in the conduction electrons within a few picoseconds into a strong non-equilibrium between hot Ni and cold Au phonons at the bilayer interface. Modeling of the subsequent equilibration dynamics within various two-temperature models confirms that for ultrathin Au films, the thermal transport is dominated by phonons instead of conduction electrons because of the weak electron-phonon coupling in Au.}, language = {en} } @article{WarbyZuZeiskeetal.2022, author = {Warby, Jonathan and Zu, Fengshuo and Zeiske, Stefan and Gutierrez-Partida, Emilio and Frohloff, Lennart and Kahmann, Simon and Frohna, Kyle and Mosconi, Edoardo and Radicchi, Eros and Lang, Felix and Shah, Sahil and Pena-Camargo, Francisco and Hempel, Hannes and Unold, Thomas and Koch, Norbert and Armin, Ardalan and De Angelis, Filippo and Stranks, Samuel D. and Neher, Dieter and Stolterfoht, Martin}, title = {Understanding performance limiting interfacial recombination in pin Perovskite solar cells}, series = {Advanced energy materials}, volume = {12}, journal = {Advanced energy materials}, number = {12}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.202103567}, pages = {10}, year = {2022}, abstract = {Perovskite semiconductors are an attractive option to overcome the limitations of established silicon based photovoltaic (PV) technologies due to their exceptional opto-electronic properties and their successful integration into multijunction cells. However, the performance of single- and multijunction cells is largely limited by significant nonradiative recombination at the perovskite/organic electron transport layer junctions. In this work, the cause of interfacial recombination at the perovskite/C-60 interface is revealed via a combination of photoluminescence, photoelectron spectroscopy, and first-principle numerical simulations. It is found that the most significant contribution to the total C-60-induced recombination loss occurs within the first monolayer of C-60, rather than in the bulk of C-60 or at the perovskite surface. The experiments show that the C-60 molecules act as deep trap states when in direct contact with the perovskite. It is further demonstrated that by reducing the surface coverage of C-60, the radiative efficiency of the bare perovskite layer can be retained. The findings of this work pave the way toward overcoming one of the most critical remaining performance losses in perovskite solar cells.}, language = {en} } @article{SchwopePiresKurpasetal.2022, author = {Schwope, Axel and Pires, Adriana M. and Kurpas, Jan and Doroshenko, Victor and Suleimanov, Valery F. and Freyberg, Michael and Becker, Werner and Dennerl, Konrad and Haberl, Frank and Lamer, Georg and Maitra, Chandreyee and Potekhin, Alexander Y. and Ramos-Ceja, Miriam E. and Santangelo, Andrea and Traulsen, Iris and Werner, Klaus}, title = {Phase-resolved X-ray spectroscopy of PSR B0656+14 with SRG/eROSITA and XMM-Newton}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {661}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/202141105}, pages = {21}, year = {2022}, abstract = {We present a detailed spectroscopic and timing analysis of X-ray observations of the bright pulsar PSR B0656+14. The observations were obtained simultaneously with eROSITA and XMM-Newton during the calibration and performance verification phase of the Spektrum-Roentgen-Gamma mission (SRG). The analysis of the 100 ks deep observation of eROSITA is supported by archival observations of the source, including XMM-Newton, NuSTAR, and NICER. Using XMM-Newton and NICER, we first established an X-ray ephemeris for the time interval 2015 to 2020, which connects all X-ray observations in this period without cycle count alias and phase shifts. The mean eROSITA spectrum clearly reveals an absorption feature originating from the star at 570 eV with a Gaussian sigma of about 70 eV that was tentatively identified in a previous long XMM-Newton observation. A second previously discussed absorption feature occurs at 260-265 eV and is described here as an absorption edge. It could be of atmospheric or of instrumental origin. These absorption features are superposed on various emission components that are phenomenologically described here as the sum of hot (120 eV) and cold (65 eV) blackbody components, both of photospheric origin, and a power law with photon index Gamma = 2 from the magnetosphere. We created energy-dependent light curves and phase-resolved spectra with a high signal-to-noise ratio. The phase-resolved spectroscopy reveals that the Gaussian absorption line at 570 eV is clearly present throughout similar to 60\% of the spin cycle, but it is otherwise undetected. Likewise, its parameters were found to be dependent on phase. The visibility of the line strength coincides in phase with the maximum flux of the hot blackbody. If the line originates from the stellar surface, it nevertheless likely originates from a different location than the hot polar cap. We also present three families of model atmospheres: a magnetized atmosphere, a condensed surface, and a mixed model. They were applied to the mean observed spectrum, whose continuum fit the observed data well. The atmosphere model, however, predicts distances that are too short. For the mixed model, the Gaussian absorption may be interpreted as proton cyclotron absorption in a field as high as 10(14) G, which is significantly higher than the field derived from the moderate observed spin-down.}, language = {en} } @article{YeZhangWarbyetal.2022, author = {Ye, Fangyuan and Zhang, Shuo and Warby, Jonathan and Wu, Jiawei and Gutierrez-Partida, Emilio and Lang, Felix and Shah, Sahil and Saglamkaya, Elifnaz and Sun, Bowen and Zu, Fengshuo and Shoai, Safa and Wang, Haifeng and Stiller, Burkhard and Neher, Dieter and Zhu, Wei-Hong and Stolterfoht, Martin and Wu, Yongzhen}, title = {Overcoming C₆₀-induced interfacial recombination in inverted perovskite solar cells by electron-transporting carborane}, series = {Nature Communications}, volume = {13}, journal = {Nature Communications}, number = {1}, publisher = {Springer Nature}, address = {London}, issn = {2041-1723}, doi = {10.1038/s41467-022-34203-x}, pages = {12}, year = {2022}, abstract = {Inverted perovskite solar cells still suffer from significant non-radiative recombination losses at the perovskite surface and across the perovskite/C₆₀ interface, limiting the future development of perovskite-based single- and multi-junction photovoltaics. Therefore, more effective inter- or transport layers are urgently required. To tackle these recombination losses, we introduce ortho-carborane as an interlayer material that has a spherical molecular structure and a three-dimensional aromaticity. Based on a variety of experimental techniques, we show that ortho-carborane decorated with phenylamino groups effectively passivates the perovskite surface and essentially eliminates the non-radiative recombination loss across the perovskite/C₆₀ interface with high thermal stability. We further demonstrate the potential of carborane as an electron transport material, facilitating electron extraction while blocking holes from the interface. The resulting inverted perovskite solar cells deliver a power conversion efficiency of over 23\% with a low non-radiative voltage loss of 110 mV, and retain >97\% of the initial efficiency after 400 h of maximum power point tracking. Overall, the designed carborane based interlayer simultaneously enables passivation, electron-transport and hole-blocking and paves the way toward more efficient and stable perovskite solar cells.}, language = {en} } @article{KunertPangTewsetal.2022, author = {Kunert, Nina and Pang, Peter T. H. and Tews, Ingo and Coughlin, Michael W. and Dietrich, Tim}, title = {Quantifying modeling uncertainties when combining multiple gravitational-wave detections from binary neutron star sources}, series = {Physical review D}, volume = {105}, journal = {Physical review D}, number = {6}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0010}, doi = {10.1103/PhysRevD.105.L061301}, pages = {7}, year = {2022}, abstract = {With the increasing sensitivity of gravitational-wave detectors, we expect to observe multiple binary neutron-star systems through gravitational waves in the near future. The combined analysis of these gravitational-wave signals offers the possibility to constrain the neutron-star radius and the equation of state of dense nuclear matter with unprecedented accuracy. However, it is crucial to ensure that uncertainties inherent in the gravitational-wave models will not lead to systematic biases when information from multiple detections is combined. To quantify waveform systematics, we perform an extensive simulation campaign of binary neutron-star sources and analyze them with a set of four different waveform models. For our analysis with 38 simulations, we find that statistical uncertainties in the neutron-star radius decrease to 1250 m (2\% at 90\% credible interval) but that systematic differences between currently employed waveform models can be twice as large. Hence, it will be essential to ensure that systematic biases will not become dominant in inferences of the neutron-star equation of state when capitalizing on future developments.}, language = {en} } @article{SchlemmFeldmannWinkelmannetal.2022, author = {Schlemm, Tanja and Feldmann, Johannes and Winkelmann, Ricarda and Levermann, Anders}, title = {Stabilizing effect of melange buttressing on the marine ice-cliff instability of the West Antarctic Ice Sheet}, series = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, volume = {16}, journal = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, number = {5}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1994-0416}, doi = {10.5194/tc-16-1979-2022}, pages = {1979 -- 1996}, year = {2022}, abstract = {Owing to global warming and particularly high regional ocean warming, both Thwaites and Pine Island Glaciers in the Amundsen region of the Antarctic Ice Sheet could lose their buttressing ice shelves over time. We analyse the possible consequences using the parallel ice sheet model (PISM), applying a simple cliff-calving parameterization and an ice melange-buttressing model. We find that the instantaneous loss of ice-shelf buttressing, due to enforced ice-shelf melting, initiates grounding-line retreat and triggers marine ice sheet instability (MISI). As a consequence, the grounding line progresses into the interior of the West Antarctic Ice Sheet and leads to a sea level contribution of 0.6 m within 100 a. By subjecting the exposed ice cliffs to cliff calving using our simplified parameterization, we also analyse marine ice cliff instability (MICI). In our simulations it can double or even triple the sea level contribution depending on the only loosely constrained parameter that determines the maximum cliff-calving rate. The speed of MICI depends on this upper bound of the calving rate, which is given by the ice melange buttressing the glacier. However, stabilization of MICI may occur for geometric reasons. Because the embayment geometry changes as MICI advances into the interior of the ice sheet, the upper bound on calving rates is reduced and the progress of MICI is slowed down. Although we cannot claim that our simulations bear relevant quantitative estimates of the effect of ice-melange buttressing on MICI, the mechanism has the potential to stop the instability. Further research is needed to evaluate its role for the past and future evolution of the Antarctic Ice Sheet.}, language = {en} } @article{FeldmannReeseWinkelmannetal.2022, author = {Feldmann, Johannes and Reese, Ronja and Winkelmann, Ricarda and Levermann, Anders}, title = {Shear-margin melting causes stronger transient ice discharge than ice-stream melting in idealized simulations}, series = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, volume = {16}, journal = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, number = {5}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1994-0416}, doi = {10.5194/tc-16-1927-2022}, pages = {1927 -- 1940}, year = {2022}, abstract = {Basal ice-shelf melting is the key driver of Antarctica's increasing sea-level contribution. In diminishing the buttressing force of the ice shelves that fringe the ice sheet, the melting increases the ice discharge into the ocean. Here we contrast the influence of basal melting in two different ice-shelf regions on the time-dependent response of an isothermal, inherently buttressed ice-sheet-shelf system. In the idealized numerical simulations, the basal-melt perturbations are applied close to the grounding line in the ice-shelf's (1) ice-stream region, where the ice shelf is fed by the fastest ice masses that stream through the upstream bed trough and (2) shear margins, where the ice flow is slower. The results show that melting below one or both of the shear margins can cause a decadal to centennial increase in ice discharge that is more than twice as large compared to a similar perturbation in the ice-stream region. We attribute this to the fact that melt-induced ice-shelf thinning in the central grounding-line region is attenuated very effectively by the fast flow of the central ice stream. In contrast, the much slower ice dynamics in the lateral shear margins of the ice shelf facilitate sustained ice-shelf thinning and thereby foster buttressing reduction. Regardless of the melt location, a higher melt concentration toward the grounding line generally goes along with a stronger response. Our results highlight the vulnerability of outlet glaciers to basal melting in stagnant, buttressing-relevant ice-shelf regions, a mechanism that may gain importance under future global warming.}, language = {en} } @article{Nowak2023, author = {Nowak, Anna}, title = {Untersuchung der Qualit{\"a}t von Selbstreflexionstexten zum Physikunterricht}, series = {Studien zum Physik- und Chemielernen}, volume = {371}, journal = {Studien zum Physik- und Chemielernen}, publisher = {Logos}, address = {Berlin}, isbn = {978-3-8325-5739-3}, issn = {1614-8967}, doi = {10.30819/5739}, pages = {419}, year = {2023}, abstract = {Reflexion wird als notwendig f{\"u}r die professionelle Entwicklung von Lehrer:innen und die Verbesserung von Unterricht angesehen, wenngleich aus theoretischer Sicht große Uneinigkeit {\"u}ber den Begriff selbst, den Reflexionsprozess und die damit verbundenen Kompetenzen herrscht. Ziel dieser Arbeit war die Entwicklung, Untersuchung und Weiterentwicklung eines Reflexionsmodells mit einem theoriebasierten, klaren Konzept des Reflexionsprozesses und einem passenden Anspruch an die Reflexionsleistung der Reflektierenden. Grundlage f{\"u}r die empirische Untersuchung waren N = 132 Selbstreflexionstexte von N = 22 Studierenden aus dem Praxissemester Physik. Zur Codierung der Texte wurden vier mittels qualitativer Inhaltsanalyse entwickelte Manuale angewandt. Mit quantitativen Methoden wurden Zusammenh{\"a}nge zwischen strukturellen Elementen, Begr{\"u}ndungen, Inhalten und dem Qualit{\"a}tsmerkmal Reflexionstiefe {\"u}berpr{\"u}ft. Es zeigte sich ein "{\"U}berhang an Negativit{\"a}t": negative Bewertungen, negative Reflexionsausl{\"o}ser und negative Inhalte h{\"a}ngen signifikant positiv mit gr{\"o}ßerer Reflexionstiefe zusammen. Auf Grundlage der empirischen Ergebnisse wurde das Reflexionsmodell mit externaler und internaler Zielorientierung (REIZ) entwickelt. Zudem wurde darauf aufbauend eine Definition f{\"u}r Reflexionstiefe in vier Argumentationsclustern formuliert. F{\"u}r die Lehrkr{\"a}ftebildung wird der in REIZ dargestellte differenzierte Ansatz der Zielorientierung von Reflexion empfohlen.}, language = {de} } @article{ThonigLilliestam2023, author = {Thonig, Richard and Lilliestam, Johan}, title = {Concentrating solar technology policy should encourage high temperatures and modularity to enable spillovers}, series = {AIP conference proceedings}, journal = {AIP conference proceedings}, number = {1}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1551-7616}, doi = {10.1063/5.0149423}, pages = {1 -- 11}, year = {2023}, abstract = {Thermal energy from concentrating solar thermal technologies (CST) may contribute to decarbonizing applications from heating and cooling, desalination, and power generation to commodities such as aluminium, hydrogen, ammonia or sustainable aviation fuels (SAF). So far, successful commercial-scale CST projects are restricted to solar industrial process heat (SIPH) and concentrating solar power (CSP) generation and, at least for the latter, depend on support from public policies that have been stagnating for years. As they are technologically similar, spillovers between SIPH or CSP and other emerging CST could accelerate commercialization across use cases while maximizing the impact of scarce support. Here, we review the technical potential for cross-fertilization between different CST applications and the ability of the current policy regime to enable this potential. Using working temperature as the key variable, we identify different clusters of current and emerging CST technologies. Low-temperature CST (<400℃) applications for heating, cooling and desalination already profit from the significant progress made in line-focussing CSP over the last 15 years. A newly emerging cluster of high temperature CST (>600℃) for solar chemistry and high-grade process heat has significant leverage for spillovers with point-focussing solar tower third-generation CSP currently under development. For these spillovers to happen, however, CSP policy designs would need to prioritize innovation for high working temperature and encourage modular plant design, by adequately remunerating hybridized plants with heat and power in and outputs that include energy sources beyond CST solar fields. This would enable synergies across applications and scales by incentivizing compatibility of modular CST components in multiple sectors and use cases.}, language = {en} } @article{PranavHultzschMusiienkoetal.2023, author = {Pranav, Manasi and Hultzsch, Thomas and Musiienko, Artem and Sun, Bowen and Shukla, Atul and Jaiser, Frank and Shoaee, Safa and Neher, Dieter}, title = {Anticorrelated photoluminescence and free charge generation proves field-assisted exciton dissociation in low-offset PM6:Y5 organic solar cells}, series = {APL materials : high impact open access journal in functional materials science}, volume = {11}, journal = {APL materials : high impact open access journal in functional materials science}, number = {6}, publisher = {AIP Publishing}, address = {Melville}, issn = {2166-532X}, doi = {10.1063/5.0151580}, pages = {8}, year = {2023}, abstract = {Understanding the origin of inefficient photocurrent generation in organic solar cells with low energy offset remains key to realizing high-performance donor-acceptor systems. Here, we probe the origin of field-dependent free-charge generation and photoluminescence in wnon-fullereneacceptor (NFA)-based organic solar cells using the polymer PM6 and the NFA Y5-a non-halogenated sibling to Y6, with a smaller energetic offset to PM6. By performing time-delayed collection field (TDCF) measurements on a variety of samples with different electron transport layers and active layer thickness, we show that the fill factor and photocurrent are limited by field-dependent free charge generation in the bulk of the blend. We also introduce a new method of TDCF called m-TDCF to prove the absence of artifacts from non-geminate recombination of photogenerated and dark charge carriers near the electrodes. We then correlate free charge generation with steady-state photoluminescence intensity and find perfect anticorrelation between these two properties. Through this, we conclude that photocurrent generation in this low-offset system is entirely controlled by the field-dependent dissociation of local excitons into charge-transfer states. (c) 2023 Author(s).}, language = {en} }