@article{ThapaLomholtKrogetal.2018, author = {Thapa, Samudrajit and Lomholt, Michael Andersen and Krog, Jens and Cherstvy, Andrey G. and Metzler, Ralf}, title = {Bayesian analysis of single-particle tracking data using the nested-sampling algorithm: maximum-likelihood model selection applied to stochastic-diffusivity data}, series = {Physical chemistry, chemical physics : PCCP ; a journal of European Chemical Societies}, volume = {20}, journal = {Physical chemistry, chemical physics : PCCP ; a journal of European Chemical Societies}, number = {46}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c8cp04043e}, pages = {29018 -- 29037}, year = {2018}, abstract = {We employ Bayesian statistics using the nested-sampling algorithm to compare and rank multiple models of ergodic diffusion (including anomalous diffusion) as well as to assess their optimal parameters for in silico-generated and real time-series. We focus on the recently-introduced model of Brownian motion with "diffusing diffusivity'-giving rise to widely-observed non-Gaussian displacement statistics-and its comparison to Brownian and fractional Brownian motion, also for the time-series with some measurement noise. We conduct this model-assessment analysis using Bayesian statistics and the nested-sampling algorithm on the level of individual particle trajectories. We evaluate relative model probabilities and compute best-parameter sets for each diffusion model, comparing the estimated parameters to the true ones. We test the performance of the nested-sampling algorithm and its predictive power both for computer-generated (idealised) trajectories as well as for real single-particle-tracking trajectories. Our approach delivers new important insight into the objective selection of the most suitable stochastic model for a given time-series. We also present first model-ranking results in application to experimental data of tracer diffusion in polymer-based hydrogels.}, language = {en} } @article{AbdoulCarimeBaldIllenbergeretal.2018, author = {Abdoul-Carime, Hassan and Bald, Ilko and Illenberger, Eugen and Kopyra, Janina}, title = {Selective Synthesis of Ethylene and Acetylene from Dimethyl Sulfide Cold Films Controlled by Slow Electrons}, series = {The journal of physical chemistry : C, Nanomaterials and interfaces}, volume = {122}, journal = {The journal of physical chemistry : C, Nanomaterials and interfaces}, number = {42}, publisher = {American Chemical Society}, address = {Washington}, issn = {1932-7447}, doi = {10.1021/acs.jpcc.8b07377}, pages = {24137 -- 24142}, year = {2018}, abstract = {One of the major challenges in chemical synthesis is to trigger and control a specific reaction route leading to a specific final product, while side products are avoided. Methodologies based on resonant processes at the molecular level, for example, photochemistry, offer the possibility of inducing selective reactions. Electrons at energies below the molecular ionization potential (<10 eV) are known to dissociate molecules via resonant processes with higher cross sections and specificity than photons. Here we show that even subexcitation electrons with energies as low as 1 eV produce ethylene and acetylene from dimethyl sulfide in competing reactions. However, the production of ethylene can specifically be targeted by controlling the energy of electrons (similar to 3 to 4 eV). Finally, pure ethylene is selectively desorbed by heating the substrate from 90 to 105 K. Beyond the synthesis of these versatile hydrocarbons for various industrial applications from a biogenic sulfur compound, our findings demonstrate the feasibility of electron induced selective chemistry applicable on the nanoscale.}, language = {en} } @article{EvsevleevMishurovaCabezaetal.2018, author = {Evsevleev, Sergei and Mishurova, Tatiana and Cabeza, Sandra and Koos, R. and Sevostianov, Igor and Garc{\´e}s, Gonzales and Requena, Guillermo and Fernandez, R. and Bruno, Giovanni}, title = {The role of intermetallics in stress partitioning and damage evolution of AlSil2CuMgNi alloy}, series = {Materials Science and Engineering: A-Structural materials: properties, microstructure and processing}, volume = {736}, journal = {Materials Science and Engineering: A-Structural materials: properties, microstructure and processing}, publisher = {Elsevier}, address = {Lausanne}, issn = {0921-5093}, doi = {10.1016/j.msea.2018.08.070}, pages = {453 -- 464}, year = {2018}, abstract = {Load partitioning between phases in a cast AlSi12CuMgNi alloy was investigated by in-situ compression test during neutron diffraction experiments. Computed tomography (CT) was used to determine volume fractions of eutectic Si and intermetallic (IM) phases, and to assess internal damage after ex-situ compression tests. The CT reconstructed volumes showed the interconnectivity of IM phases, which build a 3D network together with eutectic Si. Large stresses were found in IMs, revealing their significant role as a reinforcement for the alloy. An existing micromechanical model based on Maxwell scheme was extended to the present case, assuming the alloy as a three-phase composite (Al matrix, eutectic Si, IM phases). The model agrees well with the experimental data. Moreover, it allows predicting the principal stresses in each phase, while experiments can only determine stress differences between the axial and radial sample directions. Finally, we showed that the addition of alloying elements not only allowed developing a 3D interconnected network, but also improved the strength of the Al matrix, and the ability of the alloy constituents to bear mechanical load.}, language = {en} } @article{ThiedeCabezaMishurovaetal.2018, author = {Thiede, Tobias and Cabeza, Sandra and Mishurova, Tatiana and Nadammal, Naresh and Kromm, Arne and Bode, Johannes and Haberland, Christoph and Bruno, Giovanni}, title = {Residual Stress in Selective Laser Melted Inconel 718}, series = {Materials performance and characterization}, volume = {7}, journal = {Materials performance and characterization}, number = {4}, publisher = {American Society for Testing and Materials}, address = {West Conshohocken}, issn = {2379-1365}, doi = {10.1520/MPC20170119}, pages = {717 -- 735}, year = {2018}, abstract = {The residual stress distribution in IN718 elongated prisms produced by selective laser melting was studied by means of neutron (bulk) and laboratory X-ray (surface) diffraction. Two deposition hatch lengths were considered. A horizontal plane near the top surface (perpendicular to the building direction) and a vertical plane near the lateral surface (parallel to the building direction) were investigated. Samples both in as-built (AB) condition and removed from the base plate (RE) were characterized. While surface stress fields seem constant for the AB condition, X-ray diffraction shows stress gradients along the hatch direction in the RE condition. The stress profiles correlate with the distortion maps obtained by tactile probe measurements. Neutron diffraction shows bulk stress gradients for all principal components along the main sample directions. We correlate the observed stress patterns with the hatch length, i.e., with its effect on temperature gradients and heat flow. The bulk stress gradients partially disappear after removal from the base plate.}, language = {en} } @article{MishurovaArtztHaubrichetal.2018, author = {Mishurova, Tatiana and Artzt, Katia and Haubrich, Jan and Requena, Guillermo and Bruno, Giovanni}, title = {New aspects about the search for the most relevant parameters optimizing SLM materials}, series = {Additive manufacturing}, volume = {25}, journal = {Additive manufacturing}, publisher = {Elsevier}, address = {Amsterdam}, issn = {2214-8604}, doi = {10.1016/j.addma.2018.11.023}, pages = {325 -- 334}, year = {2018}, abstract = {While the volumetric energy density is commonly used to qualify a process parameter set, and to quantify its influence on the microstructure and performance of additively manufactured (AM) materials and components, it has been already shown that this description is by no means exhaustive. In this work, new aspects of the optimization of the selective laser melting process are investigated for AM Ti-6Al-4V. We focus on the amount of near-surface residual stress (RS), often blamed for the failure of components, and on the porosity characteristics (amount and spatial distribution). First, using synchrotron x-ray diffraction we show that higher RS in the subsurface region is generated if a lower energy density is used. Second, we show that laser de-focusing and sample positioning inside the build chamber also play an eminent role, and we quantify this influence. In parallel, using X-ray Computed Tomography, we observe that porosity is mainly concentrated in the contour region, except in the case where the laser speed is small. The low values of porosity (less than 1\%) do not influence RS.}, language = {en} } @article{StegemannCabezaPelkneretal.2018, author = {Stegemann, Robert and Cabeza, Sandra and Pelkner, Matthias and Lyamkin, Viktor and Pittner, Andreas and Werner, Daniel and Wimpory, Robert and Boin, Mirko and Kreutzbruck, Marc and Bruno, Giovanni}, title = {Influence of the microstructure on magnetic stray fields of low-carbon steel welds}, series = {Journal of Nondestructive Evaluation}, volume = {37}, journal = {Journal of Nondestructive Evaluation}, number = {3}, publisher = {Springer}, address = {New York}, issn = {0195-9298}, doi = {10.1007/s10921-018-0522-0}, pages = {18}, year = {2018}, abstract = {This study examines the relationship between the magnetic mesostructure with the microstructure of low carbon steel tungsten inert gas welds. Optical microscopy revealed variation in the microstructure of the parent material, in the heat affected and fusion zones, correlating with distinctive changes in the local magnetic stray fields measured with high spatial resolution giant magneto resistance sensors. In the vicinity of the heat affected zone high residual stresses were found using neutron diffraction. Notably, the gradients of von Mises stress and triaxial magnetic stray field modulus follow the same tendency transverse to the weld. In contrast, micro-X-ray fluorescence characterization indicated that local changes in element composition had no independent effect on magnetic stray fields.}, language = {en} } @article{FernandezCabezaMishurovaetal.2018, author = {Fernandez, R. and Cabeza, Sandra and Mishurova, Tatiana and Fernandez-Castrillo, P. and Gonzalez-Doncel, Gaspar and Bruno, Giovanni}, title = {Residual stress and yield strength evolution with annealing treatments in an age-hardenable aluminum alloy matrix composite}, series = {Materials Science and Engineering: A}, volume = {731}, journal = {Materials Science and Engineering: A}, publisher = {Elsevier}, address = {Lausanne}, issn = {0921-5093}, doi = {10.1016/j.msea.2018.06.031}, pages = {344 -- 350}, year = {2018}, abstract = {We investigated the possibility of minimizing tensile matrix residual stresses in age hardenable aluminum alloy metal matrix composites without detrimentally affect their mechanical properties (such as yield strength). Specifically, we performed thermal treatments at different temperatures and times in an age-hardenable aluminum matrix composite 2014Al-15vol\%Al2O3. Using X-ray synchrotron radiation diffraction and mechanical tests, we show that below a certain treatment temperature (250 degrees C) it is possible to identify an appropriate thermal treatment capable of relaxing residual stress in this composite while even increasing its yield strength, with respect to the as processed conditions.}, language = {en} } @article{BuljakBruno2018, author = {Buljak, Vladimir and Bruno, Giovanni}, title = {Numerical modeling of thermally induced microcracking in porous ceramics}, series = {Journal of the European Ceramic Society}, volume = {38}, journal = {Journal of the European Ceramic Society}, number = {11}, publisher = {Elsevier}, address = {Oxford}, issn = {0955-2219}, doi = {10.1016/j.jeurceramsoc.2018.03.041}, pages = {4099 -- 4108}, year = {2018}, abstract = {A numerical framework is developed to study the hysteresis of elastic properties of porous ceramics as a function of temperature. The developed numerical model is capable of employing experimentally measured crystallographic orientation distribution and coefficient of thermal expansion values. For realistic modeling of the microstructure, Voronoi polygons are used to generate polycrystalline grains. Some grains are considered as voids, to simulate the material porosity. To model intercrystalline cracking, cohesive elements are inserted along grain boundaries. Crack healing (recovery of the initial properties) upon closure is taken into account with special cohesive elements implemented in the commercial code ABAQUS. The numerical model can be used to estimate fracture properties governing the cohesive behavior through inverse analysis procedure. The model is applied to a porous cordierite ceramic. The obtained fracture properties are further used to successfully simulate general non-linear macroscopic stress-strain curves of cordierite, thereby validating the model.}, language = {en} } @article{SevostianovBruno2018, author = {Sevostianov, Igor and Bruno, Giovanni}, title = {Maxwell scheme for internal stresses in multiphase composites}, series = {Mechanics of Materials}, volume = {129}, journal = {Mechanics of Materials}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0167-6636}, doi = {10.1016/j.mechmat.2018.12.005}, pages = {320 -- 331}, year = {2018}, abstract = {The paper focuses on the reformulation of classic Maxwell's (1873) homogenization method for calculation of the residual stresses in matrix composites. For this goal, we equate the far fields produced by a set of inhomogeneities subjected to known eigenstrains and by a fictitious domain with unknown eigenstrain. The effect of interaction between the inhomogeneities is reduced to the calculation of the additional field acting on an inhomogeneity due to the eigenstrains in its neighbors. An explicit formula for residual stresses is derived for the general case of a multiphase composite. The method is illustrated by several examples. The results are compared with available experimental data as well as with predictions provided by the non-interaction approximation (Eshelby solution). It is shown that accounting for interaction can explain many experimentally observed phenomena and is required for adequate quantitative analytical modeling of the residual stresses in matrix composites.}, language = {en} } @article{BrunoKachanovSevostianovetal.2018, author = {Bruno, Giovanni and Kachanov, Mark and Sevostianov, Igor and Shyam, Amit}, title = {Micromechanical modeling of non-linear stress-strain behavior of polycrystalline microcracked materials under tension}, series = {Acta materialia}, volume = {164}, journal = {Acta materialia}, publisher = {Elsevier}, address = {Oxford}, issn = {1359-6454}, doi = {10.1016/j.actamat.2018.10.024}, pages = {50 -- 59}, year = {2018}, abstract = {The stress-strain behavior of microcracked polycrystalline materials (such as ceramics or rocks) under conditions of tensile, displacement-controlled, loading is discussed. Micromechanical explanation and modeling of the basic features, such as non-linearity and hysteresis in stress-strain curves, is developed, with stable microcrack propagation and "roughness" of intergranular cracks playing critical roles. Experiments involving complex loading histories were done on large- and medium grain size beta-eucryptite ceramic. The model is shown to reproduce the basic features of the observed stress-strain curves. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.}, language = {en} } @article{NellesenLaquaiMuelleretal.2018, author = {Nellesen, Jens and Laquai, R. and M{\"u}ller, B. R. and Kupsch, Andreas and Hentschel, M. P. and Anar, N. B. and Soppa, E. and Tillmann, W. and Bruno, Giovanni}, title = {In situ analysis of damage evolution in an Al/ Al2O3 MMC under tensile load by synchrotron X-ray refraction imaging}, series = {Journal of materials science}, volume = {53}, journal = {Journal of materials science}, number = {8}, publisher = {Springer}, address = {New York}, issn = {0022-2461}, doi = {10.1007/s10853-017-1957-x}, pages = {6021 -- 6032}, year = {2018}, abstract = {The in situ analysis of the damage evolution in a metal matrix composite (MMC) using synchrotron X-ray refraction radiography (SXRR) is presented. The investigated material is an Al alloy (6061)/10 vol MMC after T6 heat treatment. In an interrupted tensile test the gauge section of dog bone-shaped specimens is imaged in different states of tensile loading. On the basis of the SXRR images, the relative change of the specific surface (proportional to the amount of damage) in the course of tensile loading was analyzed. It could be shown that the damage can be detected by SXRR already at a stage of tensile loading, in which no observation of damage is possible with radiographic absorption-based imaging methods. Moreover, the quantitative analysis of the SXRR images reveals that the amount of damage increases homogeneously by an average of 25\% with respect to the initial state. To corroborate the experimental findings, the damage distribution was imaged in 3D after the final tensile loading by synchrotron X-ray refraction computed tomography (SXRCT) and absorption-based synchrotron X-ray computed tomography (SXCT). It could be evidenced that defects and damages cause pronounced indications in the SXRCT images.}, language = {en} } @article{MishurovaCabezaThiedeetal.2018, author = {Mishurova, Tatiana and Cabeza, Sandra and Thiede, Tobias and Nadammal, Naresh and Kromm, Arne and Klaus, Manuela and Genzel, Christoph and Haberland, Christoph and Bruno, Giovanni}, title = {The Influence of the Support Structure on Residual Stress and Distortion in SLM Inconel 718 Parts}, series = {Metallurgical and Materials Transactions A}, volume = {49A}, journal = {Metallurgical and Materials Transactions A}, number = {7}, publisher = {Springer}, address = {New York}, issn = {1073-5623}, doi = {10.1007/s11661-018-4653-9}, pages = {3038 -- 3046}, year = {2018}, abstract = {The effect of support structure and of removal from the base plate on the residual stress state in selective laser melted IN718 parts was studied by means of synchrotron X-ray diffraction. The residual stresses in subsurface region of two elongated prisms in as-built condition and after removal from the base plate were determined. One sample was directly built on a base plate and another one on a support structure. Also, the distortion on the top surface due to stress release was measured by contact profilometry. High tensile residual stress values were found, with pronounced stress gradient along the hatching direction. In the sample on support, stress redistribution took place after removal from the base plate, as opposed to simple stress relaxation for the sample without support. The sample on support structure showed larger distortion compared to sample without support. We conclude that the use of a support decreases stress values but stress-relieving heat treatments are still needed.}, language = {en} } @article{CabezaMuellerPereyraetal.2018, author = {Cabeza, Sandra and M{\"u}ller, Bernd R. and Pereyra, Ricio and Fernandez, Ricardo and Gonzalez-Doncel, Gaspar and Bruno, Giovanni}, title = {Evidence of damage evolution during creep of Al-Mg alloy using synchrotron X-ray refraction}, series = {Journal of applied crystallography}, volume = {51}, journal = {Journal of applied crystallography}, publisher = {International Union of Crystallography}, address = {Chester}, issn = {1600-5767}, doi = {10.1107/S1600576718001449}, pages = {420 -- 427}, year = {2018}, abstract = {In order to provide further evidence of damage mechanisms predicted by the recent solid-state transformation creep (SSTC) model, direct observation of damage accumulation during creep of Al-3.85Mg was made using synchrotron X-ray refraction. X-ray refraction techniques detect the internal specific surface (i.e. surface per unit volume) on a length scale comparable to the specimen size, but with microscopic sensitivity. A significant rise in the internal specific surface with increasing creep time was observed, providing evidence for the creation of a fine grain substructure, as predicted by the SSTC model. This substructure was also observed by scanning electron microscopy.}, language = {en} } @article{FernandezSerranoBrunoGonzalezDoncel2018, author = {Fernandez Serrano, Ricardo and Bruno, Giovanni and Gonzalez-Doncel, Gaspar}, title = {Fractal nature of aluminum alloys substructures under creep and its implications}, series = {Journal of applied physics}, volume = {123}, journal = {Journal of applied physics}, number = {14}, publisher = {American Institute of Physics}, address = {Melville}, issn = {0021-8979}, doi = {10.1063/1.5012035}, pages = {8}, year = {2018}, abstract = {The present work offers an explanation for the variation of the power-law stress exponent, n, with the stress sigma normalized to the shear modulus G in aluminum alloys. The approach is based on the assumption that the dislocation structure generated with deformation has a fractal nature. It fully explains the evolution of n with sigma/G even beyond the so-called power law breakdown region. Creep data from commercially pure Al99.8\%, Al-3.85\%Mg, and ingot AA6061 alloy tested at different temperatures and stresses are used to validate the proposed ideas. Finally, it is also shown that the fractal description of the dislocation structure agrees well with current knowledge. Published by AIP Publishing.}, language = {en} } @article{ZhangYan2018, author = {Zhang, Heshou and Yan, Huirong}, title = {Polarization of submillimetre lines from interstellar medium}, series = {Monthly notices of the Royal Astronomical Society}, volume = {475}, journal = {Monthly notices of the Royal Astronomical Society}, number = {2}, publisher = {Oxford University Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stx3164}, pages = {2415 -- 2420}, year = {2018}, abstract = {Magnetic fields play important roles in many astrophysical processes. However, there is no universal diagnostic for the magnetic fields in the interstellar medium (ISM) and each magnetic tracer has its limitation. Any new detection method is thus valuable. Theoretical studies have shown that submillimetre fine-structure lines are polarized due to atomic alignment by ultraviolet photon-excitation, which opens up a new avenue to probe interstellar magnetic fields. We will, for the first time, perform synthetic observations on the simulated three-dimensional ISM to demonstrate the measurability of the polarization of submillimetre atomic lines. The maximum polarization for different absorption and emission lines expected from various sources, including star-forming regions are provided. Our results demonstrate that the polarization of submillimetre atomic lines is a powerful magnetic tracer and add great value to the observational studies of the submilimetre astronomy.}, language = {en} } @article{HenkelKlimchitskayaMostepanenko2018, author = {Henkel, Carsten and Klimchitskaya, G. L. and Mostepanenko, V. M.}, title = {Influence of the chemical potential on the Casimir-Polder interaction between an atom and gapped graphene or a graphene-coated substrate}, series = {Physical review : A, Atomic, molecular, and optical physics}, volume = {97}, journal = {Physical review : A, Atomic, molecular, and optical physics}, number = {3}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9926}, doi = {10.1103/PhysRevA.97.032504}, pages = {12}, year = {2018}, abstract = {We present a formalism based on first principles of quantum electrodynamics at nonzero temperature which permits us to calculate the Casimir-Polder interaction between an atom and a graphene sheet with arbitrary mass gap and chemical potential, including graphene-coated substrates. The free energy and force of the Casimir-Polder interaction are expressed via the polarization tensor of graphene in (2 + 1)-dimensional space-time in the framework of the Dirac model. The obtained expressions are used to investigate the influence of the chemical potential of graphene on the Casimir-Polder interaction. Computations are performed for an atom of metastable helium interacting with either a freestanding graphene sheet or a graphene-coated substrate made of amorphous silica. It is shown that the impacts of the nonzero chemical potential and the mass gap on the Casimir-Polder interaction are in opposite directions, by increasing and decreasing the magnitudes of the free energy and force, respectively. It turns out, however, that the temperature-dependent part of the Casimir-Polder interaction is decreased by a nonzero chemical potential, whereas the mass gap increases it compared to the case of undoped, gapless graphene. The physical explanation for these effects is provided. Numerical computations of the Casimir-Polder interaction are performed at various temperatures and atom-graphene separations.}, language = {en} } @article{BouchouleSchemmerHenkel2018, author = {Bouchoule, Isabelle and Schemmer, Max and Henkel, Carsten}, title = {Cooling phonon modes of a Bose condensate with uniform few body losses}, series = {Scipost Physics}, volume = {5}, journal = {Scipost Physics}, number = {5}, publisher = {Scipost foundation}, address = {Amsterdam}, issn = {2542-4653}, doi = {10.21468/SciPostPhys.5.5.043}, pages = {18}, year = {2018}, abstract = {We present a general analysis of the cooling produced by losses on condensates or quasi-condensates. We study how the occupations of the collective phonon modes evolve in time, assuming that the loss process is slow enough so that each mode adiabatically follows the decrease of the mean density. The theory is valid for any loss process whose rate is proportional to the jth power of the density, but otherwise spatially uniform. We cover both homogeneous gases and systems confined in a smooth potential. For a low-dimensional gas, we can take into account the modified equation of state due to the broadening of the cloud width along the tightly confined directions, which occurs for large interactions. We find that at large times, the temperature decreases proportionally to the energy scale mc(2), where m is the mass of the particles and c the sound velocity. We compute the asymptotic ratio of these two quantities for different limiting cases: a homogeneous gas in any dimension and a one-dimensional gas in a harmonic trap.}, language = {en} } @article{WeilbacherMonrealIberoVerhammeetal.2018, author = {Weilbacher, Peter Michael and Monreal-Ibero, Ana and Verhamme, Anne and Sandin, Christer and Steinmetz, Matthias and Kollatschny, Wolfram and Krajnovic, Davor and Kamann, Sebastian and Roth, Martin M. and Erroz-Ferrer, Santiago and Marino, Raffaella Anna and Maseda, Michael V. and Wendt, Martin and Bacon, Roland and Dreizler, Stefan and Richard, Johan and Wisotzki, Lutz}, title = {Lyman-continuum leakage as dominant source of diffuse ionized gas in the Antennae galaxy}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {611}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201731669}, pages = {17}, year = {2018}, abstract = {The Antennae galaxy (NGC 4038/39) is the closest major interacting galaxy system and is therefore often studied as a merger prototype. We present the first comprehensive integral field spectroscopic dataset of this system, observed with the MUSE instrument at the ESO VLT. We cover the two regions in this system which exhibit recent star formation: the central galaxy interaction and a region near the tip of the southern tidal tail. In these fields, we detect H II regions and diffuse ionized gas to unprecedented depth. About 15\% of the ionized gas was undetected by previous observing campaigns. This newly detected faint ionized gas is visible everywhere around the central merger, and shows filamentary structure. We estimate diffuse gas fractions of about 60\% in the central field and 10\% in the southern region. We are able to show that the southern region contains a significantly different population of H II regions, showing fainter luminosities. By comparing H II region luminosities with the HST catalog of young star clusters in the central field, we estimate that there is enough Lyman-continuum leakage in the merger to explain the amount of diffuse ionized gas that we detect. We compare the Lyman-continuum escape fraction of each H II region against emission line ratios that are sensitive to the ionization parameter. While we find no systematic trend between these properties, the most extreme line ratios seem to be strong indicators of density bounded ionization. Extrapolating the Lyman-continuum escape fractions to the southern region, we conclude that simply from the comparison of the young stellar populations to the ionized gas there is no need to invoke other ionization mechanisms than Lyman-continuum leaking H II regions for the diffuse ionized gas in the Antennae.}, language = {en} } @article{KretschmerCohenMatthiasetal.2018, author = {Kretschmer, Marlene and Cohen, Judah and Matthias, Vivien and Runge, Jakob and Coumou, Dim}, title = {The different stratospheric influence on cold-extremes in Eurasia and North America}, series = {npj Climate and Atmospheric Science}, volume = {1}, journal = {npj Climate and Atmospheric Science}, publisher = {Nature Publ. Group}, address = {London}, issn = {2397-3722}, doi = {10.1038/s41612-018-0054-4}, pages = {10}, year = {2018}, abstract = {The stratospheric polar vortex can influence the tropospheric circulation and thereby winter weather in the mid-latitudes. Weak vortex states, often associated with sudden stratospheric warmings (SSW), have been shown to increase the risk of cold-spells especially over Eurasia, but its role for North American winters is less clear. Using cluster analysis, we show that there are two dominant patterns of increased polar cap heights in the lower stratosphere. Both patterns represent a weak polar vortex but they are associated with different wave mechanisms and different regional tropospheric impacts. The first pattern is zonally symmetric and associated with absorbed upward-propagating wave activity, leading to a negative phase of the North Atlantic Oscillation (NAO) and cold-air outbreaks over northern Eurasia. This coupling mechanism is well-documented in the literature and is consistent with the downward migration of the northern annular mode (NAM). The second pattern is zonally asymmetric and linked to downward reflected planetary waves over Canada followed by a negative phase of the Western Pacific Oscillation (WPO) and cold-spells in Central Canada and the Great Lakes region. Causal effect network (CEN) analyses confirm the atmospheric pathways associated with this asymmetric pattern. Moreover, our findings suggest the reflective mechanism to be sensitive to the exact region of upward wave-activity fluxes and to be state-dependent on the strength of the vortex. Identifying the causal pathways that operate on weekly to monthly timescales can pave the way for improved sub-seasonal to seasonal forecasting of cold spells in the mid-latitudes.}, language = {en} } @article{SposiniChechkinSenoetal.2018, author = {Sposini, Vittoria and Chechkin, Aleksei V. and Seno, Flavio and Pagnini, Gianni and Metzler, Ralf}, title = {Random diffusivity from stochastic equations}, series = {New Journal of Physics}, journal = {New Journal of Physics}, publisher = {Deutsche Physikalische Gesellschaft / Institute of Physics}, address = {Bad Honnef und London}, issn = {1367-2630}, doi = {10.1088/1367-2630/aab696}, pages = {1 -- 33}, year = {2018}, abstract = {A considerable number of systems have recently been reported in which Brownian yet non-Gaussian dynamics was observed. These are processes characterised by a linear growth in time of the mean squared displacement, yet the probability density function of the particle displacement is distinctly non-Gaussian, and often of exponential(Laplace) shape. This apparently ubiquitous behaviour observed in very different physical systems has been interpreted as resulting from diffusion in inhomogeneous environments and mathematically represented through a variable, stochastic diffusion coefficient. Indeed different models describing a fluctuating diffusivity have been studied. Here we present a new view of the stochastic basis describing time dependent random diffusivities within a broad spectrum of distributions. Concretely, our study is based on the very generic class of the generalised Gamma distribution. Two models for the particle spreading in such random diffusivity settings are studied. The first belongs to the class of generalised grey Brownian motion while the second follows from the idea of diffusing diffusivities. The two processes exhibit significant characteristics which reproduce experimental results from different biological and physical systems. We promote these two physical models for the description of stochastic particle motion in complex environments.}, language = {en} } @article{ŚlęzakMetzlerMagdziarz2018, author = {Ślęzak, Jakub and Metzler, Ralf and Magdziarz, Marcin}, title = {Superstatistical generalised Langevin equation}, series = {New Journal of Physics}, volume = {20}, journal = {New Journal of Physics}, number = {023026}, publisher = {Deutsche Physikalische Gesellschaft / Institute of Physics}, address = {Bad Honnef und London}, issn = {1367-2630}, doi = {10.1088/1367-2630/aaa3d4}, pages = {1 -- 25}, year = {2018}, abstract = {Recent advances in single particle tracking and supercomputing techniques demonstrate the emergence of normal or anomalous, viscoelastic diffusion in conjunction with non-Gaussian distributions in soft, biological, and active matter systems. We here formulate a stochastic model based on a generalised Langevin equation in which non-Gaussian shapes of the probability density function and normal or anomalous diffusion have a common origin, namely a random parametrisation of the stochastic force. We perform a detailed analysis demonstrating how various types of parameter distributions for the memory kernel result in exponential, power law, or power-log law tails of the memory functions. The studied system is also shown to exhibit a further unusual property: the velocity has a Gaussian one point probability density but non-Gaussian joint distributions. This behaviour is reflected in the relaxation from a Gaussian to a non-Gaussian distribution observed for the position variable. We show that our theoretical results are in excellent agreement with stochastic simulations.}, language = {en} } @article{GoldobinTyulkinaKlimenkoetal.2018, author = {Goldobin, Denis S. and Tyulkina, Irina V. and Klimenko, Lyudmila S. and Pikovskij, Arkadij}, title = {Collective mode reductions for populations of coupled noisy oscillators}, series = {Chaos : an interdisciplinary journal of nonlinear science}, volume = {28}, journal = {Chaos : an interdisciplinary journal of nonlinear science}, number = {10}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1054-1500}, doi = {10.1063/1.5053576}, pages = {6}, year = {2018}, abstract = {We analyze the accuracy of different low-dimensional reductions of the collective dynamics in large populations of coupled phase oscillators with intrinsic noise. Three approximations are considered: (i) the Ott-Antonsen ansatz, (ii) the Gaussian ansatz, and (iii) a two-cumulant truncation of the circular cumulant representation of the original system's dynamics. For the latter, we suggest a closure, which makes the truncation, for small noise, a rigorous first-order correction to the Ott-Antonsen ansatz, and simultaneously is a generalization of the Gaussian ansatz. The Kuramoto model with intrinsic noise and the population of identical noisy active rotators in excitable states with the Kuramoto-type coupling are considered as examples to test the validity of these approximations. For all considered cases, the Gaussian ansatz is found to be more accurate than the Ott-Antonsen one for high-synchrony states only. The two-cumulant approximation is always superior to both other approximations. Synchrony of large ensembles of coupled elements can be characterised by the order parameters—the mean fields. Quite often, the evolution of these collective variables is surprisingly simple, which makes a description with only a few order parameters feasible. Thus, one tries to construct accurate closed low-dimensional mathematical models for the dynamics of the first few order parameters. These models represent useful tools for gaining insight into the underlaying mechanisms of some more sophisticated collective phenomena: for example, one describes coupled populations by virtue of coupled equations for the relevant order parameters. A regular approach to the construction of closed low-dimensional systems is also beneficial for dealing with phenomena, which are beyond the applicability scope of these models; for instance, with such an approach, one can determine constraints on clustering in populations. There are two prominent types of situations, where the low-dimensional models can be constructed: (i) for a certain class of ideal paradigmatic systems of coupled phase oscillators, the Ott-Antonsen ansatz yields an exact equation for the main order parameter and (ii) the Gaussian approximation for the probability density of the phases, also yielding a low-dimensional closure, is frequently quite accurate. In this paper, we compare applications of these two model reductions for situations, where neither of them is perfectly accurate. Furthermore, we construct a new reduction approach which practically works as a first-order correction to the best of the two basic approximations.}, language = {en} } @article{RosenblumPikovskij2018, author = {Rosenblum, Michael and Pikovskij, Arkadij}, title = {Efficient determination of synchronization domains from observations of asynchronous dynamics}, series = {Chaos : an interdisciplinary journal of nonlinear science}, volume = {28}, journal = {Chaos : an interdisciplinary journal of nonlinear science}, number = {10}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1054-1500}, doi = {10.1063/1.5037012}, pages = {8}, year = {2018}, abstract = {We develop an approach for a fast experimental inference of synchronization properties of an oscillator. While the standard technique for determination of synchronization domains implies that the oscillator under study is forced with many different frequencies and amplitudes, our approach requires only several observations of a driven system. Reconstructing the phase dynamics from data, we successfully determine synchronization domains of noisy and chaotic oscillators. Our technique is especially important for experiments with living systems where an external action can be harmful and shall be minimized. Published by AIP Publishing.}, language = {en} } @article{ZhengPikovskij2018, author = {Zheng, Chunming and Pikovskij, Arkadij}, title = {Delay-induced stochastic bursting in excitable noisy systems}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {98}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, number = {4}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.98.042148}, pages = {8}, year = {2018}, abstract = {We show that a combined action of noise and delayed feedback on an excitable theta-neuron leads to rather coherent stochastic bursting. An idealized point process, valid if the characteristic timescales in the problem are well separated, is used to describe statistical properties such as the power spectral density and the interspike interval distribution. We show how the main parameters of the point process, the spontaneous excitation rate, and the probability to induce a spike during the delay action can be calculated from the solutions of a stationary and a forced Fokker-Planck equation.}, language = {en} } @article{PeterPikovskij2018, author = {Peter, Franziska and Pikovskij, Arkadij}, title = {Transition to collective oscillations in finite Kuramoto ensembles}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {97}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, number = {3}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.97.032310}, pages = {10}, year = {2018}, abstract = {We present an alternative approach to finite-size effects around the synchronization transition in the standard Kuramoto model. Our main focus lies on the conditions under which a collective oscillatory mode is well defined. For this purpose, the minimal value of the amplitude of the complex Kuramoto order parameter appears as a proper indicator. The dependence of this minimum on coupling strength varies due to sampling variations and correlates with the sample kurtosis of the natural frequency distribution. The skewness of the frequency sample determines the frequency of the resulting collective mode. The effects of kurtosis and skewness hold in the thermodynamic limit of infinite ensembles. We prove this by integrating a self-consistency equation for the complex Kuramoto order parameter for two families of distributions with controlled kurtosis and skewness, respectively.}, language = {en} } @article{Pikovskij2018, author = {Pikovskij, Arkadij}, title = {Reconstruction of a random phase dynamics network from observations}, series = {Physics letters : A}, volume = {382}, journal = {Physics letters : A}, number = {4}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0375-9601}, doi = {10.1016/j.physleta.2017.11.012}, pages = {147 -- 152}, year = {2018}, abstract = {We consider networks of coupled phase oscillators of different complexity: Kuramoto-Daido-type networks, generalized Winfree networks, and hypernetworks with triple interactions. For these setups an inverse problem of reconstruction of the network connections and of the coupling function from the observations of the phase dynamics is addressed. We show how a reconstruction based on the minimization of the squared error can be implemented in all these cases. Examples include random networks with full disorder both in the connections and in the coupling functions, as well as networks where the coupling functions are taken from experimental data of electrochemical oscillators. The method can be directly applied to asynchronous dynamics of units, while in the case of synchrony, additional phase resettings are necessary for reconstruction.}, language = {en} } @article{GrebenkovMetzlerOshanin2018, author = {Grebenkov, Denis S. and Metzler, Ralf and Oshanin, Gleb}, title = {Towards a full quantitative description of single-molecule reaction kinetics in biological cells}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {20}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, number = {24}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c8cp02043d}, pages = {16393 -- 16401}, year = {2018}, abstract = {The first-passage time (FPT), i.e., the moment when a stochastic process reaches a given threshold value for the first time, is a fundamental mathematical concept with immediate applications. In particular, it quantifies the statistics of instances when biomolecules in a biological cell reach their specific binding sites and trigger cellular regulation. Typically, the first-passage properties are given in terms of mean first-passage times. However, modern experiments now monitor single-molecular binding-processes in living cells and thus provide access to the full statistics of the underlying first-passage events, in particular, inherent cell-to-cell fluctuations. We here present a robust explicit approach for obtaining the distribution of FPTs to a small partially reactive target in cylindrical-annulus domains, which represent typical bacterial and neuronal cell shapes. We investigate various asymptotic behaviours of this FPT distribution and show that it is typically very broad in many biological situations, thus, the mean FPT can differ from the most probable FPT by orders of magnitude. The most probable FPT is shown to strongly depend only on the starting position within the geometry and to be almost independent of the target size and reactivity. These findings demonstrate the dramatic relevance of knowing the full distribution of FPTs and thus open new perspectives for a more reliable description of many intracellular processes initiated by the arrival of one or few biomolecules to a small, spatially localised region inside the cell.}, language = {en} } @article{LopezManovaHoppeetal.2018, author = {Lopez, Carlos G. and Manova, Anna and Hoppe, Corinna and Dreja, Michael and Schmiedel, Peter and Job, Mareile and Richtering, Walter and B{\"o}ker, Alexander and Tsarkova, Larisa A.}, title = {Combined UV-Vis-absorbance and reflectance spectroscopy study of dye transfer kinetics in aqueous mixtures of surfactants}, series = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, volume = {550}, journal = {Colloids and surfaces : an international journal devoted to the principles and applications of colloid and interface science ; A, Physicochemical and engineering aspects}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0927-7757}, doi = {10.1016/j.colsurfa.2018.04.024}, pages = {74 -- 81}, year = {2018}, abstract = {We report an analytical approach to study the competitive processes of solubilisation in micelles and of adsorption onto hydrophobic surfaces of poorly soluble hydrophobic dyes. The method is demonstrated on model systems containing two sources of Disperse Red 60: a bulk powder and a donor red textile, with molecularly dissolved dye stabilised in an aqueous environment by mixed micelles of anionic and non-ionic surfactants. The process of dye transfer between a donor textile (red polyester), surfactant micelles and an acceptor textile (white polyamide) was quantified by a combination of colorimetric analyses. UV-Vis absorbance was used to follow the extraction of the dye and to evaluate the solubilisation capacity of the micellar solution. A calibration curve for textile reflectance versus the adsorbed dye was generated to quantify the mass of dye transferred onto the acceptor textile. A combination of both techniques allowed us to compare the amount of dye desorbed from the donor textile and adsorbed onto the acceptor textile as a function of time for systems undergoing exhaustion-solubilisation mechanisms and only solubilisation mechanism. Up to similar or equal to 10 min of the washing process, the released dye is predominantly solubilised in surfactant micelles. At later times, the adsorption of the dye on the hydrophobic surface is energetically favoured. The shift of the desorption equilibrium in the presence of the acceptor textile results in similar or equal to 30\% increase in the release of the dye. The reported methodology provides direct comparative analysis between the solubilisation capacity of amphiphilic stabilisers and the tendency of the dye to adsorb on solid substrates, important for designing novel concepts of disperse dye solubilisation and dye transfer inhibition during textile washing.}, language = {en} } @article{GrunerHainichSanderetal.2018, author = {Gruner, David and Hainich, Rainer and Sander, Andreas Alexander Christoph and Shenar, Tomer and Todt, Helge Tobias and Oskinova, Lida and Ramachandran, Varsha and Ayres, T. and Hamann, Wolf-Rainer}, title = {The extreme O-type spectroscopic binary HD 93129A A quantitative, multiwavelength analysis}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {621}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201833178}, pages = {16}, year = {2018}, abstract = {Context. HD 93129A was classified as the earliest O-type star in the Galaxy (O2 If*) and is considered as the prototype of its spectral class. However, interferometry shows that this object is a binary system, while recent observations even suggest a triple configuration. None of the previous spectral analyses of this object accounted for its multiplicity. With new high-resolution UV and optical spectra, we have the possibility to reanalyze this key object, taking its binary nature into account for the first time. Aims. We aim to derive the fundamental parameters and the evolutionary status of HD 93129A, identifying the contributions of both components to the composite spectrum Results. Despite the similar spectral types of the two components, we are able to find signatures from each of the components in the combined spectrum, which allows us to estimate the parameters of both stars. We derive log(L/L-circle dot) = 6.15, T-eff = 52 kK, and log (M)over dot = -4.7[M-circle dot yr(-1)] for the primary Aa, and log(L/L-circle dot) = 5.58, T-eff = 45 kK, and log (M)over dot = -5.8 [M(circle dot)yr(-1)] for the secondary Ab. Conclusions. Even when accounting for the binary nature, the primary of HD 93129A is found to be one of the hottest and most luminous O stars in our Galaxy. Based on the theoretical decomposition of the spectra, we assign spectral types O2 If* and O3 III(f*) to components Aa and Ab, respectively. While we achieve a good fit for a wide spectral range, specific spectral features are not fully reproduced. The data are not sufficient to identify contributions from a hypothetical third component in the system.}, language = {en} } @article{LetoTrigilioOskinovaetal.2018, author = {Leto, Paolo and Trigilio, C. and Oskinova, Lida and Ignace, R. and Buemi, C. S. and Umana, G. and Ingallinera, A. and Leone, Francesco and Phillips, N. M. and Agliozzo, Claudia and Todt, Helge Tobias and Cerrigone, L.}, title = {A combined multiwavelength VLA/ALMA/Chandra study unveils the complex magnetosphere of the B-type star HR5907}, series = {Monthly notices of the Royal Astronomical Society}, volume = {476}, journal = {Monthly notices of the Royal Astronomical Society}, number = {1}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/sty244}, pages = {562 -- 579}, year = {2018}, abstract = {We present new radio/millimeter measurements of the hot magnetic star HR5907 obtained with the VLA and ALMA interferometers. We find that HR5907 is the most radio luminous early type star in the cm-mm band among those presently known. Its multi-wavelength radio light curves are strongly variable with an amplitude that increases with radio frequency. The radio emission can be explained by the populations of the non-thermal electrons accelerated in the current sheets on the outer border of the magnetosphere of this fast-rotating magnetic star. We classify HR5907 as another member of the growing class of strongly magnetic fast-rotating hot stars where the gyro-synchrotron emission mechanism efficiently operates in their magnetospheres. The new radio observations of HR5907 are combined with archival X-ray data to study the physical condition of its magnetosphere. The X-ray spectra of HR5907 show tentative evidence for the presence of non-thermal spectral component. We suggest that non-thermal X-rays originate a stellar X-ray aurora due to streams of non-thermal electrons impacting on the stellar surface. Taking advantage of the relation between the spectral indices of the X-ray power-law spectrum and the non-thermal electron energy distributions, we perform 3-D modelling of the radio emission for HR5907. The wavelength-dependent radio light curves probe magnetospheric layers at different heights above the stellar surface. A detailed comparison between simulated and observed radio light curves leads us to conclude that the stellar magnetic field of HR 5907 is likely non-dipolar, providing further indirect evidence of the complex magnetic field topology of HR5907.}, language = {en} } @article{DereudreHoudebert2018, author = {Dereudre, David and Houdebert, Pierre}, title = {Sharp phase transition for the continuum Widom-Rowlinson model}, series = {Annales de l'Institut Henri Poincar{\´e}. B, Probability and statistics}, volume = {57}, journal = {Annales de l'Institut Henri Poincar{\´e}. B, Probability and statistics}, number = {1}, publisher = {Association des Publications de l'Institut Henri Poincar{\´e}}, address = {Bethesda, Md.}, issn = {0246-0203}, doi = {10.1214/20-AIHP1082}, pages = {387 -- 407}, year = {2018}, abstract = {The Widom-Rowlinson model (or the Area-interaction model) is a Gibbs point process in R-d with the formal Hamiltonian defined as the volume of Ux epsilon omega B1(x), where. is a locally finite configuration of points and B-1(x) denotes the unit closed ball centred at x. The model is also tuned by two other parameters: the activity z > 0 related to the intensity of the process and the inverse temperature beta >= 0 related to the strength of the interaction. In the present paper we investigate the phase transition of the model in the point of view of percolation theory and the liquid-gas transition. First, considering the graph connecting points with distance smaller than 2r > 0, we show that for any beta >= 0, there exists 0 <(similar to a)(zc) (beta, r) < +infinity such that an exponential decay of connectivity at distance n occurs in the subcritical phase (i.e. z <(similar to a)(zc) (beta, r)) and a linear lower bound of the connection at infinity holds in the supercritical case (i.e. z >(similar to a)(zc) (beta, r)). These results are in the spirit of recent works using the theory of randomised tree algorithms (Probab. Theory Related Fields 173 (2019) 479-490, Ann. of Math. 189 (2019) 75-99, Duminil-Copin, Raoufi and Tassion (2018)). Secondly we study a standard liquid-gas phase transition related to the uniqueness/non-uniqueness of Gibbs states depending on the parameters z, beta. Old results (Phys. Rev. Lett. 27 (1971) 1040-1041, J. Chem. Phys. 52 (1970) 1670-1684) claim that a non-uniqueness regime occurs for z = beta large enough and it is conjectured that the uniqueness should hold outside such an half line ( z = beta >= beta(c) > 0). We solve partially this conjecture in any dimension by showing that for beta large enough the non-uniqueness holds if and only if z = beta. We show also that this critical value z = beta corresponds to the percolation threshold (similar to a)(zc) (beta, r) = beta for beta large enough, providing a straight connection between these two notions of phase transition.}, language = {en} } @article{ChechkinSokolov2018, author = {Chechkin, Aleksei V. and Sokolov, Igor M.}, title = {Random search with resetting}, series = {Physical review letters}, volume = {121}, journal = {Physical review letters}, number = {5}, publisher = {American Physical Society}, address = {College Park}, issn = {0031-9007}, doi = {10.1103/PhysRevLett.121.050601}, pages = {5}, year = {2018}, abstract = {We provide a unified renewal approach to the problem of random search for several targets under resetting. This framework does not rely on specific properties of the search process and resetting procedure, allows for simpler derivation of known results, and leads to new ones. Concentrating on minimizing the mean hitting time, we show that resetting at a constant pace is the best possible option if resetting helps at all, and derive the equation for the optimal resetting pace. No resetting may be a better strategy if without resetting the probability of not finding a target decays with time to zero exponentially or faster. We also calculate splitting probabilities between the targets, and define the limits in which these can be manipulated by changing the resetting procedure. We moreover show that the number of moments of the hitting time distribution under resetting is not less than the sum of the numbers of moments of the resetting time distribution and the hitting time distribution without resetting.}, language = {en} } @article{ReeseWinkelmannGudmundsson2018, author = {Reese, Ronja and Winkelmann, Ricarda and Gudmundsson, Gudmundur Hilmar}, title = {Grounding-line flux formula applied as a flux condition in numerical simulations fails for buttressed Antarctic ice streams}, series = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, volume = {12}, journal = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, number = {10}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1994-0416}, doi = {10.5194/tc-12-3229-2018}, pages = {3229 -- 3242}, year = {2018}, abstract = {Currently, several large-scale ice-flow models impose a condition on ice flux across grounding lines using an analytically motivated parameterisation of grounding-line flux. It has been suggested that employing this analytical expression alleviates the need for highly resolved computational domains around grounding lines of marine ice sheets. While the analytical flux formula is expected to be accurate in an unbuttressed flow-line setting, its validity has hitherto not been assessed for complex and realistic geometries such as those of the Antarctic Ice Sheet. Here the accuracy of this analytical flux formula is tested against an optimised ice flow model that uses a highly resolved computational mesh around the Antarctic grounding lines. We find that when applied to the Antarctic Ice Sheet the analytical expression provides inaccurate estimates of ice fluxes for almost all grounding lines. Furthermore, in many instances direct application of the analytical formula gives rise to unphysical complex-valued ice fluxes. We conclude that grounding lines of the Antarctic Ice Sheet are, in general, too highly buttressed for the analytical parameterisation to be of practical value for the calculation of grounding-line fluxes.}, language = {en} } @article{ReeseAlbrechtMengeletal.2018, author = {Reese, Ronja and Albrecht, Torsten and Mengel, Matthias and Asay-Davis, Xylar and Winkelmann, Ricarda}, title = {Antarctic sub-shelf melt rates via PICO}, series = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, volume = {12}, journal = {The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union}, number = {6}, publisher = {Copernicus}, address = {G{\"o}ttingen}, issn = {1994-0416}, doi = {10.5194/tc-12-1969-2018}, pages = {1969 -- 1985}, year = {2018}, abstract = {Ocean-induced melting below ice shelves is one of the dominant drivers for mass loss from the Antarctic Ice Sheet at present. An appropriate representation of sub-shelf melt rates is therefore essential for model simulations of marine-based ice sheet evolution. Continental-scale ice sheet models often rely on simple melt-parameterizations, in particular for long-term simulations, when fully coupled ice-ocean interaction becomes computationally too expensive. Such parameterizations can account for the influence of the local depth of the ice-shelf draft or its slope on melting. However, they do not capture the effect of ocean circulation underneath the ice shelf. Here we present the Potsdam Ice-shelf Cavity mOdel (PICO), which simulates the vertical overturning circulation in ice-shelf cavities and thus enables the computation of sub-shelf melt rates consistent with this circulation. PICO is based on an ocean box model that coarsely resolves ice shelf cavities and uses a boundary layer melt formulation. We implement it as a module of the Parallel Ice Sheet Model (PISM) and evaluate its performance under present-day conditions of the Southern Ocean. We identify a set of parameters that yield two-dimensional melt rate fields that qualitatively reproduce the typical pattern of comparably high melting near the grounding line and lower melting or refreezing towards the calving front. PICO captures the wide range of melt rates observed for Antarctic ice shelves, with an average of about 0.1 ma(-1) for cold sub-shelf cavities, for example, underneath Ross or Ronne ice shelves, to 16 ma(-1) for warm cavities such as in the Amundsen Sea region. This makes PICO a computationally feasible and more physical alternative to melt parameterizations purely based on ice draft geometry.}, language = {en} } @article{HeinrichEhlertHatteretal.2018, author = {Heinrich, Benjamin W. and Ehlert, Christopher and Hatter, Nino and Braun, Lukas and Lotze, Christian and Saalfrank, Peter and Franke, Katharina J.}, title = {Control of oxidation and spin state in a single-molecule junction}, series = {ACS nano}, volume = {12}, journal = {ACS nano}, number = {4}, publisher = {American Chemical Society}, address = {Washington}, issn = {1936-0851}, doi = {10.1021/acsnano.8b00312}, pages = {3172 -- 3177}, year = {2018}, abstract = {The oxidation and spin state of a metal-organic molecule determine its chemical reactivity and magnetic properties. Here, we demonstrate the reversible control of the oxidation and spin state in a single Fe porphyrin molecule in the force field of the tip of a scanning electron tunneling microscope. Within the regimes of half-integer and integer spin state, we can further track the evolution of the magnetocrystalline anisotropy. Our experimental results are corroborated by density functional theory and wave function theory. This combined analysis allows us to draw a complete picture of the molecular states over a large range of intramolecular deformations.}, language = {en} } @article{RamanVenkatesanGulyakovaFruebingetal.2018, author = {Raman Venkatesan, Thulasinath and Gulyakova, Anna A. and Fr{\"u}bing, Peter and Gerhard, Reimund}, title = {Relaxation processes and structural transitions in poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) relaxor-ferroelectric terpolymers as seen in dielectric spectroscopy}, series = {IEEE transactions on dielectrics and electrical insulation}, volume = {25}, journal = {IEEE transactions on dielectrics and electrical insulation}, number = {6}, publisher = {Institut of Electrical and Electronics Engineers}, address = {Piscataway}, issn = {1070-9878}, doi = {10.1109/TDEI.2018.007440}, pages = {2229 -- 2235}, year = {2018}, abstract = {Dielectric relaxation processes and structural transitions in Poly(vinylidenefluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) terpolymer films with two different monomer compositions were investigated in comparison with Poly(vinylidenefluoride-trifluoroethylene) (P(VDF-TrFE)) copolymer films as reference material. Differential Scanning Calorimetry was employed to assess annealing effects on phase transitions and crystalline structure, while relaxation processes were investigated by means of Dielectric Relaxation Spectroscopy, the results of which indicate the existence of two separate dispersion regions, denoted as processes A and B, respectively. Process A appears at a certain temperature independent of frequency, but is strongly influenced by the crystallisation temperature and the CFE content, while peak B shows typical features of a relaxation process and is less influenced by crystallisation temperature and CFE content. Furthermore, peak B is related to the glass transition which is more pronounced in the terpolymer than in P(VDF-TrFE). A closer analysis indicates that the addition of CFE and thermal annealing gradually shift the ferro-to-paraelectric transition in P(VDF-TrFE) to lower temperatures, while the phase transition is transformed more and more into a relaxation.}, language = {en} } @article{QiuGrothWirgesetal.2018, author = {Qiu, Xunlin and Groth, Frederick and Wirges, Werner and Gerhard, Reimund}, title = {Cellular polypropylene foam films as DC voltage insulation and as piezoelectrets}, series = {IEEE transactions on dielectrics and electrical insulation}, volume = {25}, journal = {IEEE transactions on dielectrics and electrical insulation}, number = {3}, publisher = {Institut of Electr. and Electronics Engineers}, address = {Piscataway}, issn = {1070-9878}, doi = {10.1109/TDEI.2018.007192}, pages = {829 -- 834}, year = {2018}, abstract = {Polymer foams are in industrial use for several decades. More recently, non-polar polymer foams were found to be piezoelectric (so-called piezoelectrets) after internal electrical charging of the cavities. So far, few studies have been carried out on the electrical-insulation properties of polymer foams. Here, we compare the piezoelectric and the DC-voltage electrical-insulation properties of cellular polypropylene (PP) foams. Their cavity microstructure can be adjusted via inflation in high-pressure nitrogen gas in combination with a subsequent thermal treatment. While inflation is effective for improving the piezoelectricity, it is detrimental for the electrical-insulation properties. The original cellular PP foam shows a breakdown strength of approximately 230 MV/m, within the same range as that of solid PP. The breakdown strength decreases with increasing degree of inflation, and the dependence on the foam thickness follows an inverse power law with an exponent of 1.2. Nevertheless, up to a thickness of 140 mu m (3.5 times the original thickness), the breakdown strength of cellular-foam PP films is at least 7 times that of an air gap with the same thickness. In addition, the influence of high temperatures and high humidities on the piezoelectricity and the breakdown strength of cellular PP was studied. It was found that the piezoelectric d(33) coefficient decays rapidly already at 70 degrees C, while the breakdown strength slightly increases during storage at 70 or 90 degrees C. Under a relative humidity of 95\%, the breakdown strength increases with storage time, while the piezoelectric d(33) coefficient slightly decreases.}, language = {en} } @article{RychkovGerhardKuznetsovetal.2018, author = {Rychkov, Dmitry and Gerhard, Reimund and Kuznetsov, Alexey and Rychkov, Andrey}, title = {Influence of charge density on the trap energy spectrum in fluoroethylenepropylene copolymer films with chemically modified surfaces}, series = {IEEE transactions on dielectrics and electrical insulation}, volume = {25}, journal = {IEEE transactions on dielectrics and electrical insulation}, number = {3}, publisher = {Inst. of Electr. and Electronics Engineers}, address = {Piscataway}, issn = {1070-9878}, doi = {10.1109/TDEI.2018.007437}, pages = {840 -- 844}, year = {2018}, abstract = {Tetrafluoroethylene-hexafluoropropylene copolymer (FEP) films were treated with titanium-tetrachloride vapor by means of molecular-layer deposition. The treatment leads to considerable improvements of the electret-charge stability on positively charged films. A slight improvement is also observed for negatively charged films. In line with our previous findings, we attribute the improvement in electret properties to the formation of deeper traps on the chemically modified polymer surfaces. Here, we investigate the influence of the charge density on electret stability of FEP films with modified surfaces. Trap-energy spectra obtained from thermally-stimulated-discharge measurements indicate that the charge stability on modified FEP films depends on how the surface traps are populated and on the availability of additional deeper traps.}, language = {en} } @article{GidionGerhard2018, author = {Gidion, Gunnar and Gerhard, Reimund}, title = {The Bow on a String}, series = {Acta Acustica united with Acustica}, volume = {104}, journal = {Acta Acustica united with Acustica}, number = {2}, publisher = {Hirzel Verlag}, address = {Stuttgart}, issn = {1610-1928}, doi = {10.3813/AAA.919174}, pages = {315 -- 322}, year = {2018}, abstract = {The interaction between a bowed string instrument and its player is conveyed by the bow, the vibrational properties of which can be measured either separately on the bow or during the bowing procedure. Here, two piezoelectric film sensors, made of a ferroelectret material, are installed on a violin bow, one sensor at the tip and one at the frog. With these sensors, a violin is played under normal conditions, and the signals are analysed. The features in the resulting spectrograms are identified as string harmonics and longitudinal bow-hair resonances. The bow-hair sections on both sides of the bow-string contact exhibit separate resonances which are observed as absorption dips in the spectra. Owing to the sensor positions at the bow-hair terminations, it can be inferred that the two bow-hair sections act as mutual vibration absorbers. From a regression of the observed resonances, the longitudinal bow-hair velocity can be obtained. With additional film sensors under the violin bridge, body vibrations were also detected providing further details of the coupling mechanisms.}, language = {en} } @article{ShenarHainichTodtetal.2018, author = {Shenar, Tomer and Hainich, Rainer and Todt, Helge Tobias and Moffat, Anthony F. J. and Sander, Andreas Alexander Christoph and Oskinova, Lida and Ramachandran, Varsha and Munoz, M. and Pablo, H. and Sana, Hugues and Hamann, Wolf-Rainer}, title = {The shortest-period Wolf-Rayet binary in the small magellanic cloud}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {616}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201833006}, pages = {15}, year = {2018}, abstract = {Context. SMC AB6 is the shortest-period (P = 6.5 d) Wolf-Rayet (WR) binary in the Small Magellanic Cloud. This binary is therefore a key system in the study of binary interaction and formation of WR stars at low metallicity. The WR component in AB6 was previously found to be very luminous (log L = 6.3 [L-circle dot]) compared to its reported orbital mass (approximate to 8 M-circle dot), placing it significantly above the Eddington limit. Aims. Through spectroscopy and orbital analysis of newly acquired optical data taken with the Ultraviolet and Visual Echelle Spectrograph (UVES), we aim to understand the peculiar results reported for this system and explore its evolutionary history. Methods. We measured radial velocities via cross-correlation and performed a spectral analysis using the Potsdam Wolf-Rayet model atmosphere code. The evolution of the system was analyzed using the Binary Population and Spectral Synthesis evolution code. Results. AB6 contains at least four stars. The 6.5 d period WR binary comprises the WR primary (WN3:h, star A) and a rather rapidly rotating (v(eq) = 265 km s(-1)) early O-type companion (O5.5 V, star B). Static N III and N IV emission lines and absorption signatures in He lines suggest the presence of an early-type emission line star (O5.5 I(f), star C). Finally, narrow absorption lines portraying a long-term radial velocity variation show the existence of a fourth star (O7.5 V, star D). Star D appears to form a second 140 d period binary together with a fifth stellar member, which is a B-type dwarf or a black hole. It is not clear that these additional components are bound to the WR binary. We derive a mass ratio of M-O/M-WR = 2.2 +/- 0.1. The WR star is found to be less luminous than previously thought (log L = 5.9 [L-circle dot]) and, adopting M-O = 41 M-circle dot for star B, more massive (M-WR = 18 M-circle dot). Correspondingly, the WR star does not exceed the Eddington limit. We derive the initial masses of M-i,M-WR = 60 M-circle dot and M-i,M-O = 40 M-circle dot and an age of 3.9 Myr for the system. The WR binary likely experienced nonconservative mass transfer in the past supported by the relatively rapid rotation of star B. Conclusions. Our study shows that AB6 is a multiple - probably quintuple - system. This finding resolves the previously reported puzzle of the WR primary exceeding the Eddington limit and suggests that the WR star exchanged mass with its companion in the past.}, language = {en} } @article{HainichOskinovaShenaretal.2018, author = {Hainich, Rainer and Oskinova, Lida and Shenar, Tomer and Marchant Campos, Pablo and Eldridge, J. J. and Sander, Andreas Alexander Christoph and Hamann, Wolf-Rainer and Langer, Norbert and Todt, Helge Tobias}, title = {Observational properties of massive black hole binary progenitors}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {609}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201731449}, pages = {62}, year = {2018}, abstract = {Context: The first directly detected gravitational waves (GW 150914) were emitted by two coalescing black holes (BHs) with masses of ≈ 36 M⊙ and ≈ 29 M⊙. Several scenarios have been proposed to put this detection into an astrophysical context. The evolution of an isolated massive binary system is among commonly considered models. Aims: Various groups have performed detailed binary-evolution calculations that lead to BH merger events. However, the question remains open as to whether binary systems with the predicted properties really exist. The aim of this paper is to help observers to close this gap by providing spectral characteristics of massive binary BH progenitors during a phase where at least one of the companions is still non-degenerate. Methods: Stellar evolution models predict fundamental stellar parameters. Using these as input for our stellar atmosphere code (Potsdam Wolf-Rayet), we compute a set of models for selected evolutionary stages of massive merging BH progenitors at different metallicities. Results: The synthetic spectra obtained from our atmosphere calculations reveal that progenitors of massive BH merger events start their lives as O2-3V stars that evolve to early-type blue supergiants before they undergo core-collapse during the Wolf-Rayet phase. When the primary has collapsed, the remaining system will appear as a wind-fed high-mass X-ray binary. Based on our atmosphere models, we provide feedback parameters, broad band magnitudes, and spectral templates that should help to identify such binaries in the future. Conclusions: While the predicted parameter space for massive BH binary progenitors is partly realized in nature, none of the known massive binaries match our synthetic spectra of massive BH binary progenitors exactly. Comparisons of empirically determined mass-loss rates with those assumed by evolution calculations reveal significant differences. The consideration of the empirical mass-loss rates in evolution calculations will possibly entail a shift of the maximum in the predicted binary-BH merger rate to higher metallicities, that is, more candidates should be expected in our cosmic neighborhood than previously assumed.}, language = {en} } @article{SanderFuerstKretschmaretal.2018, author = {Sander, Andreas Alexander Christoph and F{\"u}rst, F. and Kretschmar, P. and Oskinova, Lida and Todt, Helge Tobias and Hainich, Rainer and Shenar, Tomer and Hamann, Wolf-Rainer}, title = {Coupling hydrodynamics with comoving frame radiative transfer}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {610}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {1432-0746}, doi = {10.1051/0004-6361/201731575}, pages = {19}, year = {2018}, abstract = {Aims. To gain a realistic picture of the donor star in Vela X-1, we constructed a hydrodynamically consistent atmosphere model describing the wind stratification while properly reproducing the observed donor spectrum. To investigate how X-ray illumination affects the stellar wind, we calculated additional models for different X-ray luminosity regimes. Methods. We used the recently updated version of the Potsdam Wolf-Rayet code to consistently solve the hydrodynamic equation together with the statistical equations and the radiative transfer. Results. The wind flow in Vela X-1 is driven by ions from various elements, with Fe III and S III leading in the outer wind. The model-predicted mass-loss rate is in line with earlier empirical studies. The mass-loss rate is almost unaffected by the presence of the accreting NS in the wind. The terminal wind velocity is confirmed at u(infinity) approximate to 600 km s(-1). On the other hand, the wind velocity in the inner region where the NS is located is only approximate to 100 km s(-1), which is not expected on the basis of a standard beta-velocity law. In models with an enhanced level of X-rays, the velocity field in the outer wind can be altered. If the X-ray flux is too high, the acceleration breaks down because the ionization increases. Conclusions. Accounting for radiation hydrodynamics, our Vela X-1 donor atmosphere model reveals a low wind speed at the NS location, and it provides quantitative information on wind driving in this important HMXB.}, language = {en} } @article{OskinovaBulikGomezMoran2018, author = {Oskinova, Lida and Bulik, Tomasz and Gomez-Moran, Ada Nebot}, title = {Infrared outbursts as potential tracers of common-envelope events in high-mass X-ray binary formation}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {613}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/201832925}, pages = {7}, year = {2018}, abstract = {Context. Classic massive binary evolutionary scenarios predict that a transitional common-envelope (CE) phase could be preceded as well as succeeded by the evolutionary stage when a binary consists of a compact object and a massive star, that is, a high-mass X-ray binary (HMXB). The observational manifestations of common envelope are poorly constrained. We speculate that its ejection might be observed in some cases as a transient event at mid-infrared (IR) wavelengths. Aims. We estimate the expected numbers of CE ejection events and HMXBs per star formation unit rate, and compare these theoretical estimates with observations. Methods. We compiled a list of 85 mid-IR transients of uncertain nature detected by the Spitzer Infrared Intensive Transients Survey and searched for their associations with X-ray, optical, and UV sources. Results. Confirming our theoretical estimates, we find that only one potential HMXB may be plausibly associated with an IR-transient and tentatively propose that X-ray source NGC4490-X40 could be a precursor to the SPIRITS 16az event. Among other interesting sources, we suggest that the supernova remnant candidate [BWL2012] 063 might be associated with SPIRITS 16ajc. We also find that two SPIRITS events are likely associated with novae, and seven have potential optical counterparts. Conclusions. The massive binary evolutionary scenarios that involve CE events do not contradict currently available observations of IR transients and HMXBs in star-forming galaxies.}, language = {en} } @article{TorrejonReigFuerstetal.2018, author = {Torrejon, J. M. and Reig, Pablo and F{\"u}rst, F. and Martinez-Chicharro, M. and Postnov, K. and Oskinova, Lida}, title = {NuSTAR rules out a cyclotron line in the accreting magnetar candidate 4U2206+54}, series = {Monthly notices of the Royal Astronomical Society}, volume = {479}, journal = {Monthly notices of the Royal Astronomical Society}, number = {3}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/sty1628}, pages = {3366 -- 3372}, year = {2018}, abstract = {Based on our new NuSTAR X-ray telescope data, we rule out any cyclotron line up to 60 keV in the spectra of the high-mass X-ray binary 4U2206+54. In particular, we do not find any evidence of the previously claimed line around 30 keV, independently of the source flux, along the spin pulse. The spin period has increased significantly, since the last observation, up to 5750 +/- 10 s, confirming the rapid spin-down rate (nu)over dot = -1.8 x 10(-14) Hz s(-1). This behaviour might be explained by the presence of a strongly magnetized neutron star (B-s > several times 10(13) G) accreting from the slow wind of its main-sequence O9.5 companion.}, language = {en} } @article{JayNorellEckertetal.2018, author = {Jay, Raphael M. and Norell, Jesper and Eckert, Sebastian and Hantschmann, Markus and Beye, Martin and Kennedy, Brian and Quevedo, Wilson and Schlotter, William F. and Dakovski, Georgi L. and Minitti, Michael P. and Hoffmann, Matthias C. and Mitra, Ankush and Moeller, Stefan P. and Nordlund, Dennis and Zhang, Wenkai and Liang, Huiyang W. and Kunnus, Kristian and Kubicek, Katharina and Techert, Simone A. and Lundberg, Marcus and Wernet, Philippe and Gaffney, Kelly and Odelius, Michael and F{\"o}hlisch, Alexander}, title = {Disentangling Transient Charge Density and Metal-Ligand Covalency in Photoexcited Ferricyanide with Femtosecond Resonant Inelastic Soft X-ray Scattering}, series = {The journal of physical chemistry letters}, volume = {9}, journal = {The journal of physical chemistry letters}, number = {12}, publisher = {American Chemical Society}, address = {Washington}, issn = {1948-7185}, doi = {10.1021/acs.jpclett.8b01429}, pages = {3538 -- 3543}, year = {2018}, abstract = {Soft X-ray spectroscopies are ideal probes of the local valence electronic structure of photocatalytically active metal sites. Here, we apply the selectivity of time resolved resonant inelastic X-ray scattering at the iron L-edge to the transient charge distribution of an optically excited charge-transfer state in aqueous ferricyanide. Through comparison to steady-state spectra and quantum chemical calculations, the coupled effects of valence-shell closing and ligand-hole creation are experimentally and theoretically disentangled and described in terms of orbital occupancy, metal-ligand covalency, and ligand field splitting, thereby extending established steady-state concepts to the excited-state domain. pi-Back-donation is found to be mainly determined by the metal site occupation, whereas the ligand hole instead influences sigma-donation. Our results demonstrate how ultrafast resonant inelastic X-ray scattering can help characterize local charge distributions around catalytic metal centers in short-lived charge-transfer excited states, as a step toward future rationalization and tailoring of photocatalytic capabilities of transition-metal complexes.}, language = {en} } @article{JayEckertFondelletal.2018, author = {Jay, Raphael Martin and Eckert, Sebastian and Fondell, Mattis and Miedema, Piter S. and Norell, Jesper and Pietzsch, Annette and Quevedo, Wilson and Niskanen, Johannes and Kunnus, Kristjan and F{\"o}hlisch, Alexander}, title = {The nature of frontier orbitals under systematic ligand exchange in (pseudo-)octahedral Fe(II) complexes}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {20}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, number = {44}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c8cp04341h}, pages = {27745 -- 27751}, year = {2018}, abstract = {Understanding and controlling properties of transition metal complexes is a crucial step towards tailoring materials for sustainable energy applications. In a systematic approach, we use resonant inelastic X-ray scattering to study the influence of ligand substitution on the valence electronic structure around an aqueous iron(II) center. Exchanging cyanide with 2-2′-bipyridine ligands reshapes frontier orbitals in a way that reduces metal 3d charge delocalization onto the ligands. This net decrease of metal-ligand covalency results in lower metal-centered excited state energies in agreement with previously reported excited state dynamics. Furthermore, traces of solvent-effects were found indicating a varying interaction strength of the solvent with ligands of different character. Our results demonstrate how ligand exchange can be exploited to shape frontier orbitals of transition metal complexes in solution-phase chemistry; insights upon which future efforts can built when tailoring the functionality of photoactive systems for light-harvesting applications.}, language = {en} } @article{EckertVazdaCruzErtanetal.2018, author = {Eckert, Sebastian and Vaz da Cruz, Vinicius and Ertan, Emelie and Ignatova, Nina and Polyutov, Sergey and Couto, Rafael C. and Fondell, Mattis and Dantz, Marcus and Kennedy, Brian and Schmitt, Thorsten and Pietzsch, Annette and Odelius, Michael and F{\"o}hlisch, Alexander}, title = {One-dimensional cuts through multidimensional potential-energy surfaces by tunable x rays}, series = {Physical review : A, Atomic, molecular, and optical physics}, volume = {97}, journal = {Physical review : A, Atomic, molecular, and optical physics}, number = {5}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9926}, doi = {10.1103/PhysRevA.97.053410}, pages = {7}, year = {2018}, abstract = {The concept of the potential-energy surface (PES) and directional reaction coordinates is the backbone of our description of chemical reaction mechanisms. Although the eigenenergies of the nuclear Hamiltonian uniquely link a PES to its spectrum, this information is in general experimentally inaccessible in large polyatomic systems. This is due to (near) degenerate rovibrational levels across the parameter space of all degrees of freedom, which effectively forms a pseudospectrum given by the centers of gravity of groups of close-lying vibrational levels. We show here that resonant inelastic x-ray scattering (RIXS) constitutes an ideal probe for revealing one-dimensional cuts through the ground-state PES of molecular systems, even far away from the equilibrium geometry, where the independent-mode picture is broken. We strictly link the center of gravity of close-lying vibrational peaks in RIXS to a pseudospectrum which is shown to coincide with the eigenvalues of an effective one-dimensional Hamiltonian along the propagation coordinate of the core-excited wave packet. This concept, combined with directional and site selectivity of the core-excited states, allows us to experimentally extract cuts through the ground-state PES along three complementary directions for the showcase H2O molecule.}, language = {en} } @article{JelkenPandiyarajanGenzeretal.2018, author = {Jelken, Joachim and Pandiyarajan, Chinnayan Kannan and Genzer, Jan and Lomadze, Nino and Santer, Svetlana}, title = {Fabrication of flexible hydrogel sheets featuring periodically spaced circular holes with continuously adjustable size in realtime}, series = {ACS applied materials \& interfaces}, volume = {10}, journal = {ACS applied materials \& interfaces}, number = {36}, publisher = {American Chemical Society}, address = {Washington}, issn = {1944-8244}, doi = {10.1021/acsami.8b09580}, pages = {30844 -- 30851}, year = {2018}, abstract = {We report on the formation of stimuli-responsive structured hydrogel thin films whose pattern geometry can be adjusted on demand and tuned reversibly by varying solvent quality or by changing temperature. The hydrogel films, similar to 100 nm in thickness, were prepared by depositing layers of random copolymers comprising N-isopropylacrylamide and ultraviolet (UV)-active methacryloyloxybenzophenone units onto solid substrates. A two-beam interference pattern technique was used to cross-link the selected areas of the film; any unreacted material was extracted using ethanol after UV light-assisted cross-linking. In this way, we produced nanoholes, perfectly ordered structures with a narrow size distribution, negligible tortuosity, adjustable periodicity, and a high density. The diameter of the circular holes ranged from a few micrometers down to several tens of nanometers; the hole periodicity could be adjusted readily by changing the optical period of the UV interference pattern. The holes were reversibly closed and opened by swelling/deswelling the polymer networks in the presence of ethanol and water, respectively, at various temperatures. The reversible regulation of the hole diameter can be repeated many times within a few seconds. The hydrogel sheet with circular holes periodically arranged may also be transferred onto different substrates and be employed as tunable templates for the deposition of desired substances.}, language = {en} } @article{LoebnerLomadzeKopyshevetal.2018, author = {Loebner, Sarah and Lomadze, Nino and Kopyshev, Alexey and Koch, Markus and Guskova, Olga and Saphiannikova, Marina and Santer, Svetlana}, title = {Light-Induced Deformation of Azobenzene-Containing Colloidal Spheres}, series = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, volume = {122}, journal = {The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces \& biophysical chemistry}, number = {6}, publisher = {American Chemical Society}, address = {Washington}, issn = {1520-6106}, doi = {10.1021/acs.jpcb.7b11644}, pages = {2001 -- 2009}, year = {2018}, abstract = {We report on light-induced deformation of colloidal spheres consisting of azobenzene-containing polymers. The colloids of the size between 60 nm and 2 mu m in diameter were drop casted on a glass surface and irradiated with linearly polarized light. It was found that colloidal particles can be deformed up to ca. 6 times of their initial diameter. The maximum degree of deformation depends on the irradiation wavelength and intensity, as well as on colloidal particles size. On the basis of recently proposed theory by Toshchevikov et al. [J. Phys. Chem. Lett. 2017, 8, 1094], we calculated the optomechanical stresses (ca. 100 MPa) needed for such giant deformations and compared them with the experimental results.}, language = {en} } @article{NiebuurPuchmayrHeroldetal.2018, author = {Niebuur, Bart-Jan and Puchmayr, Jonas and Herold, Christian and Kreuzer, Lucas and Hildebrand, Viet and M{\"u}ller-Buschbaum, Peter and Laschewsky, Andre and Papadakis, Christine M.}, title = {Polysulfobetaines in aqueous solution and in thin film geometry}, series = {Materials}, volume = {11}, journal = {Materials}, number = {5}, publisher = {MDPI}, address = {Basel}, issn = {1996-1944}, doi = {10.3390/ma11050850}, pages = {11}, year = {2018}, abstract = {Polysulfobetaines in aqueous solution show upper critical solution temperature (UCST) behavior. We investigate here the representative of this class of materials, poly (N,N-dimethyl-N-(3-methacrylamidopropyl) ammonio propane sulfonate) (PSPP), with respect to: (i) the dynamics in aqueous solution above the cloud point as function of NaBr concentration; and (ii) the swelling behavior of thin films in water vapor as function of the initial film thickness. For PSPP solutions with a concentration of 5 wt.\%, the temperature dependence of the intensity autocorrelation functions is measured with dynamic light scattering as function of molar mass and NaBr concentration (0-8 mM). We found a scaling of behavior for the scattered intensity and dynamic correlation length. The resulting spinodal temperatures showed a maximum at a certain (small) NaBr concentration, which is similar to the behavior of the cloud points measured previously by turbidimetry. The critical exponent of susceptibility depends on NaBr concentration, with a minimum value where the spinodal temperature is maximum and a trend towards the mean-field value of unity with increasing NaBr concentration. In contrast, the critical exponent of the correlation length does not depend on NaBr concentration and is lower than the value of 0.5 predicted by mean-field theory. For PSPP thin films, the swelling behavior was found to depend on film thickness. A film thickness of about 100 nm turns out to be the optimum thickness needed to obtain fast hydration with H2O.}, language = {en} } @article{WisotzkiBaconBrinchmannetal.2018, author = {Wisotzki, Lutz and Bacon, R. and Brinchmann, J. and Cantalupo, S. and Richter, Philipp and Schaye, J. and Schmidt, Kasper Borello and Urrutia, Tanya and Weilbacher, Peter Michael and Akhlaghi, M. and Bouche, N. and Contini, T. and Guiderdoni, B. and Herenz, E. C. and Inami, H. and Kerutt, Josephine Victoria and Leclercq, F. and Marino, R. A. and Maseda, M. and Monreal-Ibero, A. and Nanayakkara, T. and Richard, J. and Saust, R. and Steinmetz, Matthias and Wendt, Martin}, title = {Nearly all the sky is covered by Lyman-alpha emission around high-redshift galaxies}, series = {Nature : the international weekly journal of science}, volume = {562}, journal = {Nature : the international weekly journal of science}, number = {7726}, publisher = {Nature Publ. Group}, address = {London}, issn = {0028-0836}, doi = {10.1038/s41586-018-0564-6}, pages = {229 -- 232}, year = {2018}, abstract = {Galaxies are surrounded by large reservoirs of gas, mostly hydrogen, that are fed by inflows from the intergalactic medium and by outflows from galactic winds. Absorption-line measurements along the lines of sight to bright and rare background quasars indicate that this circumgalactic medium extends far beyond the starlight seen in galaxies, but very little is known about its spatial distribution. The Lyman-alpha transition of atomic hydrogen at a wavelength of 121.6 nanometres is an important tracer of warm (about 104 kelvin) gas in and around galaxies, especially at cosmological redshifts greater than about 1.6 at which the spectral line becomes observable from the ground. Tracing cosmic hydrogen through its Lyman-a emission has been a long-standing goal of observational astrophysics(1-3), but the extremely low surface brightness of the spatially extended emission is a formidable obstacle. A new window into circumgalactic environments was recently opened by the discovery of ubiquitous extended Lyman-alpha emission from hydrogen around high-redshift galaxies(4,5). Such measurements were previously limited to especially favourable systems(6-8) or to the use of massive statistical averaging(9,10) because of the faintness of this emission. Here we report observations of low-surface-brightness Lyman-alpha emission surrounding faint galaxies at redshifts between 3 and 6. We find that the projected sky coverage approaches 100 per cent. The corresponding rate of incidence (the mean number of Lyman-alpha emitters penetrated by any arbitrary line of sight) is well above unity and similar to the incidence rate of high-column-density absorbers frequently detected in the spectra of distant quasars(11-14). This similarity suggests that most circumgalactic atomic hydrogen at these redshifts has now been detected in emission.}, language = {en} } @article{WillnerOttoLevermann2018, author = {Willner, Sven N. and Otto, Christian and Levermann, Anders}, title = {Global economic response to river floods}, series = {Nature climate change}, volume = {8}, journal = {Nature climate change}, number = {7}, publisher = {Nature Publ. Group}, address = {London}, issn = {1758-678X}, doi = {10.1038/s41558-018-0173-2}, pages = {594 -- 598}, year = {2018}, abstract = {Increasing Earth's surface air temperature yields an intensification of its hydrological cycle. As a consequence, the risk of river floods will increase regionally within the next two decades due to the atmospheric warming caused by past anthropogenic greenhouse gas emissions. The direct economic losses caused by these floods can yield regionally heterogeneous losses and gains by propagation within the global trade and supply network. Here we show that, in the absence of large-scale structural adaptation, the total economic losses due to fluvial floods will increase in the next 20 years globally by 17\% despite partial compensation through market adjustment within the global trade network. China will suffer the strongest direct losses, with an increase of 82\%. The United States is mostly affected indirectly through its trade relations. By contrast to the United States, recent intensification of the trade relations with China leaves the European Union better prepared for the import of production losses in the future.}, language = {en} } @article{WillnerLevermannZhaoetal.2018, author = {Willner, Sven N. and Levermann, Anders and Zhao, Fang and Frieler, Katja}, title = {Adaptation required to preserve future high-end river flood risk at present levels}, series = {Science Advances}, volume = {4}, journal = {Science Advances}, number = {1}, publisher = {American Assoc. for the Advancement of Science}, address = {Washington}, issn = {2375-2548}, doi = {10.1126/sciadv.aao1914}, pages = {8}, year = {2018}, abstract = {Earth's surface temperature will continue to rise for another 20 to 30 years even with the strongest carbon emission reduction currently considered. The associated changes in rainfall patterns can result in an increased flood risk worldwide. We compute the required increase in flood protection to keep high-end fluvial flood risk at present levels. The analysis is carried out worldwide for subnational administrative units. Most of the United States, Central Europe, and Northeast and West Africa, as well as large parts of India and Indonesia, require the strongest adaptation effort. More than half of the United States needs to at least double their protection within the next two decades. Thus, the need for adaptation to increased river flood is a global problem affecting industrialized regions as much as developing countries.}, language = {en} } @article{SeyrichAlirezaeizanjaniBetaetal.2018, author = {Seyrich, Maximilian and Alirezaeizanjani, Zahra and Beta, Carsten and Stark, Holger}, title = {Statistical parameter inference of bacterial swimming strategies}, series = {New journal of physics : the open-access journal for physics}, volume = {20}, journal = {New journal of physics : the open-access journal for physics}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1367-2630}, doi = {10.1088/1367-2630/aae72c}, pages = {20}, year = {2018}, abstract = {We provide a detailed stochastic description of the swimming motion of an E. coli bacterium in two dimension, where we resolve tumble events in time. For this purpose, we set up two Langevin equations for the orientation angle and speed dynamics. Calculating moments, distribution and autocorrelation functions from both Langevin equations and matching them to the same quantities determined from data recorded in experiments, we infer the swimming parameters of E. coli. They are the tumble rate lambda, the tumble time r(-1), the swimming speed v(0), the strength of speed fluctuations sigma, the relative height of speed jumps eta, the thermal value for the rotational diffusion coefficient D-0, and the enhanced rotational diffusivity during tumbling D-T. Conditioning the observables on the swimming direction relative to the gradient of a chemoattractant, we infer the chemotaxis strategies of E. coli. We confirm the classical strategy of a lower tumble rate for swimming up the gradient but also a smaller mean tumble angle (angle bias). The latter is realized by shorter tumbles as well as a slower diffusive reorientation. We also find that speed fluctuations are increased by about 30\% when swimming up the gradient compared to the reversed direction.}, language = {en} } @article{GrinesOsipovPikovskij2018, author = {Grines, Evgeny and Osipov, Grigory V. and Pikovskij, Arkadij}, title = {Describing dynamics of driven multistable oscillators with phase transfer curves}, series = {Chaos : an interdisciplinary journal of nonlinear science}, volume = {28}, journal = {Chaos : an interdisciplinary journal of nonlinear science}, number = {10}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1054-1500}, doi = {10.1063/1.5037290}, pages = {6}, year = {2018}, abstract = {Phase response curve is an important tool in the studies of stable self-sustained oscillations; it describes a phase shift under action of an external perturbation. We consider multistable oscillators with several stable limit cycles. Under a perturbation, transitions from one oscillating mode to another one may occur. We define phase transfer curves to describe the phase shifts at such transitions. This allows for a construction of one-dimensional maps that characterize periodically kicked multistable oscillators. We show that these maps are good approximations of the full dynamics for large periods of forcing. Published by AIP Publishing.}, language = {en} } @article{SmirnovOsipovPikovskij2018, author = {Smirnov, Lev A. and Osipov, Grigory V. and Pikovskij, Arkadij}, title = {Solitary synchronization waves in distributed oscillator populations}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {98}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, number = {6}, publisher = {American Physical Society}, address = {College Park}, issn = {2470-0045}, doi = {10.1103/PhysRevE.98.062222}, pages = {062222-1 -- 062222-7}, year = {2018}, abstract = {We demonstrate the existence of solitary waves of synchrony in one-dimensional arrays of oscillator populations with Laplacian coupling. Characterizing each community with its complex order parameter, we obtain lattice equations similar to those of the discrete nonlinear Schrodinger system. Close to full synchrony, we find solitary waves for the order parameter perturbatively, starting from the known phase compactons and kovatons; these solutions are extended numerically to the full domain of possible synchrony levels. For nonidentical oscillators, the existence of dissipative solitons is shown.}, language = {en} } @article{BolotovSmirnovOsipovetal.2018, author = {Bolotov, Maxim I. and Smirnov, Lev A. and Osipov, Grigory V. and Pikovskij, Arkadij}, title = {Simple and complex chimera states in a nonlinearly coupled oscillatory medium}, series = {Chaos : an interdisciplinary journal of nonlinear science}, volume = {28}, journal = {Chaos : an interdisciplinary journal of nonlinear science}, number = {4}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1054-1500}, doi = {10.1063/1.5011678}, pages = {9}, year = {2018}, abstract = {We consider chimera states in a one-dimensional medium of nonlinear nonlocally coupled phase oscillators. In terms of a local coarse-grained complex order parameter, the problem of finding stationary rotating nonhomogeneous solutions reduces to a third-order ordinary differential equation. This allows finding chimera-type and other inhomogeneous states as periodic orbits of this equation. Stability calculations reveal that only some of these states are stable. We demonstrate that an oscillatory instability leads to a breathing chimera, for which the synchronous domain splits into subdomains with different mean frequencies. Further development of instability leads to turbulent chimeras. Published by AIP Publishing.}, language = {en} } @article{OzturkMarwanKorupetal.2018, author = {Ozturk, Ugur and Marwan, Norbert and Korup, Oliver and Saito, H. and Agarwa, Ankit and Grossman, M. J. and Zaiki, M. and Kurths, J{\"u}rgen}, title = {Complex networks for tracking extreme rainfall during typhoons}, series = {Chaos : an interdisciplinary journal of nonlinear science}, volume = {28}, journal = {Chaos : an interdisciplinary journal of nonlinear science}, number = {7}, publisher = {American Institute of Physics}, address = {Melville}, issn = {1054-1500}, doi = {10.1063/1.5004480}, pages = {8}, year = {2018}, abstract = {Reconciling the paths of extreme rainfall with those of typhoons remains difficult despite advanced forecasting techniques. We use complex networks defined by a nonlinear synchronization measure termed event synchronization to track extreme rainfall over the Japanese islands. Directed networks objectively record patterns of heavy rain brought by frontal storms and typhoons but mask out contributions of local convective storms. We propose a radial rank method to show that paths of extreme rainfall in the typhoon season (August-November, ASON) follow the overall southwest-northeast motion of typhoons and mean rainfall gradient of Japan. The associated eye-of-the-typhoon tracks deviate notably and may thus distort estimates of heavy typhoon rainfall. We mainly found that the lower spread of rainfall tracks in ASON may enable better hindcasting than for westerly-fed frontal storms in June and July.}, language = {en} } @article{AgarwalMaheswaranMarwanetal.2018, author = {Agarwal, Ankit and Maheswaran, Rathinasamy and Marwan, Norbert and Caesar, Levke and Kurths, J{\"u}rgen}, title = {Wavelet-based multiscale similarity measure for complex networks}, series = {The European physical journal : B, Condensed matter and complex systems}, volume = {91}, journal = {The European physical journal : B, Condensed matter and complex systems}, number = {11}, publisher = {Springer}, address = {New York}, issn = {1434-6028}, doi = {10.1140/epjb/e2018-90460-6}, pages = {12}, year = {2018}, abstract = {In recent years, complex network analysis facilitated the identification of universal and unexpected patterns in complex climate systems. However, the analysis and representation of a multiscale complex relationship that exists in the global climate system are limited. A logical first step in addressing this issue is to construct multiple networks over different timescales. Therefore, we propose to apply the wavelet multiscale correlation (WMC) similarity measure, which is a combination of two state-of-the-art methods, viz. wavelet and Pearson's correlation, for investigating multiscale processes through complex networks. Firstly we decompose the data over different timescales using the wavelet approach and subsequently construct a corresponding network by Pearson's correlation. The proposed approach is illustrated and tested on two synthetics and one real-world example. The first synthetic case study shows the efficacy of the proposed approach to unravel scale-specific connections, which are often undiscovered at a single scale. The second synthetic case study illustrates that by dividing and constructing a separate network for each time window we can detect significant changes in the signal structure. The real-world example investigates the behavior of the global sea surface temperature (SST) network at different timescales. Intriguingly, we notice that spatial dependent structure in SST evolves temporally. Overall, the proposed measure has an immense potential to provide essential insights on understanding and extending complex multivariate process studies at multiple scales.}, language = {en} } @article{ArminChenJinetal.2018, author = {Armin, Ardalan and Chen, Zhiming and Jin, Yaocheng and Zhang, Kai and Huang, Fei and Shoaee, Safa}, title = {A Shockley-Type polymer}, series = {Advanced energy materials}, volume = {8}, journal = {Advanced energy materials}, number = {7}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201701450}, pages = {9}, year = {2018}, abstract = {Charge extraction rate in solar cells made of blends of electron donating/accepting organic semiconductors is typically slow due to their low charge carrier mobility. This sets a limit on the active layer thickness and has hindered the industrialization of organic solar cells (OSCs). Herein, charge transport and recombination properties of an efficient polymer (NT812):fullerene blend are investigated. This system delivers power conversion efficiency of >9\% even when the junction thickness is as large as 800 nm. Experimental results indicate that this material system exhibits exceptionally low bimolecular recombination constant, 800 times smaller than the diffusion-controlled electron and hole encounter rate. Comparing theoretical results based on a recently introduced modified Shockley model for fill factor, and experiments, clarifies that charge collection is nearly ideal in these solar cells even when the thickness is several hundreds of nanometer. This is the first realization of high-efficiency Shockley-type organic solar cells with junction thicknesses suitable for scaling up.}, language = {en} } @article{AbeysekaraArcherBenbowetal.2018, author = {Abeysekara, A. U. and Archer, A. and Benbow, Wystan and Bird, Ralph and Brose, Robert and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Chromey, A. J. and Connolly, M. P. and Cui, Wei and Daniel, M. K. and Falcone, A. and Feng, Qi and Finley, John P. and Fortson, L. and Furniss, Amy and Huetten, M. and Hanna, David and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kertzman, M. and Kieda, David and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Lin, T. T. Y. and McArthur, S. and Moriarty, P. and Mukherjee, Reshmi and Ong, R. A. and Otte, Adam Nepomuk and Park, Nahee and Petrashyk, A. and Pohl, Martin and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, Gregory T. and Roache, E. and Rulten, C. and Sadeh, I. and Santander, Marcos and Sembroski, G. H. and Shahinyan, Karlen and Sushch, I. and Tyler, J. and Wakely, S. P. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, D. A. and Williamson, T. J. and Zitzer, B. and Abdollahi, S. and Ajello, Marco and Baldini, Luca and Barbiellini, G. and Bastieri, Denis and Bellazzini, Ronaldo and Berenji, B. and Bissaldi, Elisabetta and Blandford, R. D. and Bonino, R. and Bottacini, E. and Brandt, Terri J. and Bruel, P. and Buehler, R. and Cameron, R. A. and Caputo, R. and Caraveo, P. A. and Castro, D. and Cavazzuti, E. and Charles, Eric and Chiaro, G. and Ciprini, S. and Cohen-Tanugi, Johann and Costantin, D. and Cutini, S. and de Palma, F. and Di Lalla, N. and Di Mauro, M. and Di Venere, L. and Dominguez, A. and Favuzzi, C. and Fegan, S. J. and Franckowiak, Anna and Fukazawa, Yasushi and Funk, Stefan and Fusco, Piergiorgio and Gargano, Fabio and Gasparrini, Dario and Giglietto, Nicola and Giordano, F. and Giroletti, Marcello and Green, D. and Grenier, I. A. and Guillemot, L. and Guiriec, Sylvain and Hays, Elizabeth and Hewitt, John W. and Horan, D. and Johannesson, G. and Kensei, S. and Kuss, M. and Larsson, Stefan and Latronico, L. and Lemoine-Goumard, Marianne and Li, J. and Longo, Francesco and Loparco, Francesco and Lovellette, M. N. and Lubrano, Pasquale and Magill, Jeffrey D. and Maldera, Simone and Mazziotta, Mario Nicola and McEnery, J. E. and Michelson, P. F. and Mitthumsiri, W. and Mizuno, Tsunefumi and Monzani, Maria Elena and Morselli, Aldo and Moskalenko, Igor V. and Negro, M. and Nuss, E. and Ojha, R. and Omodei, Nicola and Orienti, M. and Orlando, E. and Palatiello, M. and Paliya, Vaidehi S. and Paneque, D. and Perkins, Jeremy S. and Persic, M. and Pesce-Rollins, Melissa and Petrosian, Vahe' and Piron, F. and Porter, Troy A. and Principe, G. and Raino, S. and Rando, Riccardo and Rani, B. and Razzano, Massimilano and Razzaque, Soebur and Reimer, A. and Reimer, Olaf and Reposeur, T. and Sgro, C. and Siskind, E. J. and Spandre, Gloria and Spinelli, P. and Suson, D. J. and Tajima, Hiroyasu and Thayer, J. B. and Thompson, David J. and Torres, Diego F. and Tosti, Gino and Troja, Eleonora and Valverde, J. and Vianello, Giacomo and Vogel, M. and Wood, K. and Yassine, M. and Alfaro, R. and Alvarez, C. and Alvarez, J. D. and Arceo, R. and Arteaga-Velazquez, J. C. and Rojas, D. Avila and Ayala Solares, H. A. and Becerril, A. and Belmont-Moreno, E. and BenZvi, S. Y. and Bernal, A. and Braun, J. and Brisbois, C. and Caballero-Mora, K. S. and Capistran, T. and Carraminana, A. and Casanova, Sabrina and Castillo, M. and Cotti, U. and Cotzomi, J. and Coutino de Leon, S. and De Leon, C. and De la Fuente, E. and Dichiara, S. and Dingus, B. L. and DuVernois, M. A. and Diaz-Velez, J. C. and Engel, K. and Enriquez-Rivera, O. and Fiorino, D. W. and Fleischhack, H. and Fraija, N. and Garcia-Gonzalez, J. A. and Garfias, F. and Gonzalez Munoz, A. and Gonzalez, M. M. and Goodman, J. A. and Hampel-Arias, Z. and Harding, J. P. and Hernandez, S. and Hernandez-Almada, A. and Hona, B. and Hueyotl-Zahuantitla, F. and Hui, C. M. and Huntemeyer, P. and Iriarte, A. and Jardin-Blicq, A. and Joshi, V. and Kaufmann, S. and Lara, A. and Lauer, R. J. and Lee, W. H. and Lennarz, D. and Leon Vargas, H. and Linnemann, J. T. and Longinotti, A. L. and Luis-Raya, G. and Luna-Garcia, R. and Lopez-Coto, R. and Malone, K. and Marinelli, S. S. and Martinez, O. and Martinez-Castellanos, I. and Martinez-Castro, J. and Martinez-Huerta, H. and Matthews, J. A. and Miranda-Romagnoli, P. and Moreno, E. and Mostafa, M. and Nayerhoda, A. and Nellen, L. and Newbold, M. and Nisa, M. U. and Noriega-Papaqui, R. and Pelayo, R. and Pretz, J. and Perez-Perez, E. G. and Ren, Z. and Rho, C. D. and Riviere, C. and Rosa-Gonzalez, D. and Rosenberg, M. and Ruiz-Velasco, E. and Salazar, H. and Greus, F. Salesa and Sandoval, A. and Schneider, M. and Arroyo, M. Seglar and Sinnis, G. and Smith, A. J. and Springer, R. W. and Surajbali, P. and Taboada, Ignacio and Tibolla, O. and Tollefson, K. and Torres, I. and Ukwatta, Tilan N. and Villasenor, L. and Weisgarber, T. and Westerhoff, Stefan and Wisher, I. G. and Wood, J. and Yapici, Tolga and Yodh, G. and Zepeda, A. and Zhou, H.}, title = {VERITAS and Fermi-LAT Observations of TeV Gamma-Ray Sources Discovered by HAWC in the 2HWC Catalog}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {866}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration Fermi-LAT Collaboration HAWC Collaboration}, issn = {0004-637X}, doi = {10.3847/1538-4357/aade4e}, pages = {18}, year = {2018}, abstract = {The High Altitude Water Cherenkov (HAWC) collaboration recently published their 2HWC catalog, listing 39 very high energy (VHE; >100 GeV) gamma-ray sources based on 507 days of observation. Among these, 19 sources are not associated with previously known teraelectronvolt (TeV) gamma-ray sources. We have studied 14 of these sources without known counterparts with VERITAS and Fermi-LAT. VERITAS detected weak gamma-ray emission in the 1 TeV-30 TeV band in the region of DA 495, a pulsar wind nebula coinciding with 2HWC J1953+294, confirming the discovery of the source by HAWC. We did not find any counterpart for the selected 14 new HAWC sources from our analysis of Fermi-LAT data for energies higher than 10 GeV. During the search, we detected gigaelectronvolt (GeV) gamma-ray emission coincident with a known TeV pulsar wind nebula, SNR G54.1+0.3 (VER J1930+188), and a 2HWC source, 2HWC J1930+188. The fluxes for isolated, steady sources in the 2HWC catalog are generally in good agreement with those measured by imaging atmospheric Cherenkov telescopes. However, the VERITAS fluxes for SNR G54.1+0.3, DA 495, and TeV J2032+4130 are lower than those measured by HAWC, and several new HAWC sources are not detected by VERITAS. This is likely due to a change in spectral shape, source extension, or the influence of diffuse emission in the source region.}, language = {en} } @article{ArcherBenbowBirdetal.2018, author = {Archer, A. and Benbow, Wystan and Bird, Ralph and Brose, Robert and Buchovecky, M. and Bugaev, V and Cui, Wei and Danie, M. K. and Falcone, A. and Feng, Qi and Finley, John P. and Flinders, A. and Fortson, L. and Furniss, Amy and Gillanders, Gerard H. and Huttens, M. and Hanna, David and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kelley-Hoskins, N. and Kieda, David and Krause, Maria and Krennrich, F. and Kumar, S. and Lang, M. J. and Lin, T. T. Y. and McArthur, S. and Moriarty, P. and Mukherjee, Reshmi and Nieto, Daniel and Ong, R. A. and Otte, A. N. and Park, Nahee and Petrashyk, A. and Pohl, Martin and Popkow, Alexis and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynold, P. T. and Richards, Gregory T. and Roache, E. and Rulten, C. and Sadeh, I and Sembroski, G. H. and Shahinyan, Karlen and Tyler, J. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, David A. and Brisken, W. F. and Pontrelli, P.}, title = {HESS J1943+213}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {862}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration}, issn = {0004-637X}, doi = {10.3847/1538-4357/aacbd0}, pages = {15}, year = {2018}, abstract = {HESS J1943+213 is a very high energy (VHE; > 100 GeV) gamma-ray source in the direction of the Galactic plane. Studies exploring the classification of the source are converging toward its identification as an extreme synchrotron BL Lac object. Here we present 38 hr of VERITAS observations of HESS J1943+213 taken over 2 yr. The source is detected with a significance of similar to 20 standard deviations, showing a remarkably stable flux and spectrum in VHE gamma-rays. Multifrequency Very Long Baseline Array (VLBA) observations of the source confirm the extended, jet-like structure previously found in the 1.6 GHz band with the European VLBI Network and detect this component in the 4.6 and 7.3 GHz bands. The radio spectral indices of the core and the jet and the level of polarization derived from the VLBA observations are in a range typical for blazars. Data from VERITAS, Fermi-LAT, Swift-XRT, the FLWO 48 ' telescope, and archival infrared and hard X-ray observations are used to construct and model the spectral energy distribution (SED) of the source with a synchrotron self-Compton model. The well-measured gamma-ray peak of the SED with VERITAS and Fermi-LAT provides constraining upper limits on the source redshift. Possible contribution of secondary gamma-rays from ultra-high-energy cosmic-ray-initiated electromagnetic cascades to the gamma-ray emission is explored, finding that only a segment of the VHE spectrum can be accommodated with this process. A variability search is performed across X-ray and gamma-ray bands. No statistically significant flux or spectral variability is detected.}, language = {en} } @article{AbeysekaraArcherBenbowetal.2018, author = {Abeysekara, A. U. and Archer, A. and Benbow, Wystan and Bird, Ralph and Brill, A. and Brose, Robert and Buckley, J. H. and Christiansen, Jessie L. and Chromey, A. J. and Daniel, M. K. and Falcone, A. and Feng, Qi and Finley, John P. and Fortson, L. and Furniss, Amy and Gillanders, Gerard H. and Gueta, O. and Hanna, David and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, David and Krause, Maria and Krennrich, F. and Lang, M. J. and Moriarty, P. and Mukherjee, Reshmi and Ong, R. A. and Otte, A. N. and Park, N. and Petrashyk, A. and Pohl, Martin and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, Gregory T. and Roache, E. and Rulten, C. and Sadeh, I. and Santander, Marcos and Scott, S. S. and Sembroski, G. H. and Shahinyan, Karlen and Tyler, J. and Wakely, S. P. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, D. A. and Williamson, T. J. and Zitzer, B. and Kaur, A.}, title = {VERITAS Observations of the BL Lac Object TXS 0506+056}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, volume = {861}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration}, issn = {2041-8205}, doi = {10.3847/2041-8213/aad053}, pages = {6}, year = {2018}, abstract = {On 2017 September 22, the IceCube Neutrino Observatory reported the detection of the high-energy neutrino event IC 170922A, of potential astrophysical origin. It was soon determined that the neutrino direction was consistent with the location of the gamma-ray blazar TXS 0506+056. (3FGL J0509.4+ 0541), which was in an elevated gamma-ray emission state as measured by the Fermi satellite. Very Energetic Radiation Imaging Telescope Array System (VERITAS) observations of the neutrino/blazar region started on 2017 September 23 in response to the neutrino alert and continued through 2018 February 6. While no significant very-high-energy (VHE; E > 100 GeV) emission was observed from the blazar by VERITAS in the two-week period immediately following the IceCube alert, TXS 0506+ 056 was detected by VERITAS with a significance of 5.8 standard deviations (sigma) in the full 35 hr data set. The average photon flux of the source during this period was (8.9 +/- 1.6). x. 10(-12) cm(-2) s(-1), or 1.6\% of the Crab Nebula flux, above an energy threshold of 110 GeV, with a soft spectral index of 4.8. +/-. 1.3.}, language = {en} } @article{AbeysekaraArcherAuneetal.2018, author = {Abeysekara, A. U. and Archer, A. and Aune, Taylor and Benbow, Wystan and Bird, Ralph and Brose, Robert and Buchovecky, M. and Bugaev, V. and Cui, Wei and Daniel, M. K. and Falcone, A. and Feng, Qi and Finley, John P. and Fleischhack, H. and Flinders, A. and Fortson, L. and Furniss, Amy and Gotthelf, Eric V. and Grube, J. and Hanna, David and Hervet, O. and Holder, J. and Huang, K. and Hughes, G. and Humensky, T. B. and Huetten, M. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, David and Krause, Maria and Kumar, S. and Lang, M. J. and Lin, T. T. Y. and Maier, Gernot and McArthur, S. and Moriarty, P. and Mukherjee, Reshmi and Ong, R. A. and Otte, Adam Nepomuk and Pandel, Dirk and Park, Nahee and Petrashyk, A. and Pohl, Martin and Popkow, Alexis and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, Gregory T. and Roache, E. and Rousselle, J. and Rulten, C. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, Karlen and Tyler, J. and Vassiliev, V. V. and Wakely, S. P. and Ward, J. E. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, David A. and Zitzer, B.}, title = {A Very High Energy gamma-Ray Survey toward the Cygnus Region of the Galaxy}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {861}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/aac4a2}, pages = {33}, year = {2018}, abstract = {We present results from deep observations toward the Cygnus region using 300 hr of very high energy (VHE)gamma-ray data taken with the VERITAS Cerenkov telescope array and over 7 yr of high-energy.-ray data taken with the Fermi satellite at an energy above 1 GeV. As the brightest region of diffuse gamma-ray emission in the northern sky, the Cygnus region provides a promising area to probe the origins of cosmic rays. We report the identification of a potential Fermi-LAT counterpart to VER J2031+415 (TeV J2032+4130) and resolve the extended VHE source VER J2019+368 into two source candidates (VER J2018+367* and VER J2020+368*) and characterize their energy spectra. The Fermi-LAT morphology of 3FGL J2021.0+4031e (the Gamma Cygni supernova remnant) was examined, and a region of enhanced emission coincident with VER J2019+407 was identified and jointly fit with the VERITAS data. By modeling 3FGL J2015.6+3709 as two sources, one located at the location of the pulsar wind nebula CTB 87 and one at the quasar QSO J2015+371, a continuous spectrum from 1 GeV to 10 TeV was extracted for VER J2016+371 (CTB 87). An additional 71 locations coincident with Fermi-LAT sources and other potential objects of interest were tested for VHE gamma-ray emission, with no emission detected and upper limits on the differential flux placed at an average of 2.3\% of the Crab Nebula flux. We interpret these observations in a multiwavelength context and present the most detailed gamma-ray view of the region to date.}, language = {en} } @article{AbeysekaraBenbowBirdetal.2018, author = {Abeysekara, A. U. and Benbow, Wystan and Bird, Ralph and Brantseg, T. and Brose, Robert and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Connolly, M. P. and Cui, Wei and Daniel, M. K. and Falcone, A. and Feng, Qi and Finley, John P. and Fortson, L. and Furniss, Amy and Gillanders, Gerard H. and Gunawardhana, Isuru and Huetten, M. and Hanna, David and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kertzman, M. and Krennrich, F. and Lang, M. J. and Lin, T. T. Y. and McArthur, S. and Moriarty, P. and Mukherjee, Reshmi and Ong, R. A. and Otte, Adam Nepomuk and Park, N. and Petrashyk, A. and Pohl, Martin and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, Gregory T. and Roache, E. and Rulten, C. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, Karlen and Wakely, S. P. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Williams, D. A. and Zitzer, B. and Jorstad, Svetlana G. and Marscher, Alan P. and Lister, Matthew L. and Kovalev, Yuri Y. and Pushkarev, A. B. and Savolainen, Tuomas and Agudo, I. and Molina, S. N. and Gomez, J. L. and Larionov, Valeri M. and Borman, G. A. and Mokrushina, A. A. and Tornikoski, Merja and Lahteenmaki, A. and Chamani, W. and Enestam, S. and Kiehlmann, S. and Hovatta, Talvikki and Smith, P. S. and Pontrelli, P.}, title = {Multiwavelength Observations of the Blazar BL Lacertae}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {856}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration}, issn = {0004-637X}, doi = {10.3847/1538-4357/aab35c}, pages = {14}, year = {2018}, abstract = {Combined with measurements made by very-long-baseline interferometry, the observations of fast TeV gamma-ray flares probe the structure and emission mechanism of blazar jets. However, only a handful of such flares have been detected to date, and only within the last few years have these flares been observed from lower-frequency-peaked BL. Lac objects and flat-spectrum radio quasars. We report on a fast TeV gamma-ray flare from the blazar BL. Lacertae observed by the Very Energetic Radiation Imaging Telescope Array System (VERITAS). with a rise time of similar to 2.3 hr and a decay time of similar to 36 min. The peak flux above 200 GeV is (4.2 +/- 0.6) x 10(-6) photon m(-2) s(-1) measured with a 4-minute-binned light curve, corresponding to similar to 180\% of the flux that is observed from the Crab Nebula above the same energy threshold. Variability contemporaneous with the TeV gamma-ray flare was observed in GeV gamma-ray, X-ray, and optical flux, as well as in optical and radio polarization. Additionally, a possible moving emission feature with superluminal apparent velocity was identified in Very Long Baseline Array observations at 43 GHz, potentially passing the radio core of the jet around the time of the gamma-ray flare. We discuss the constraints on the size, Lorentz factor, and location of the emitting region of the flare, and the interpretations with several theoretical models that invoke relativistic plasma passing stationary shocks.}, language = {en} } @article{AbeysekaraArcherBenbowetal.2018, author = {Abeysekara, A. U. and Archer, A. and Benbow, Wystan and Bird, Ralph and Brose, Robert and Buchovecky, M. and Bugaev, V. and Connolly, M. P. and Cui, Wei and Errando, Manel and Falcone, A. and Feng, Qi and Finley, John P. and Flinders, A. and Fortson, L. and Furniss, Amy and Gillanders, Gerard H. and Huetten, M. and Hanna, David and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, Caitlin A. and Kaaret, Philip and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, David and Krause, Maria and Krennrich, F. and Lang, M. J. and Lin, T. T. Y. and Maier, Gernot and McArthur, S. and Moriarty, P. and Mukherjee, Reshmi and Ong, R. A. and Park, N. and Perkins, Jeremy S. and Petrashyk, A. and Pohl, Martin and Popkow, Alexis and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, Gregory T. and Roache, E. and Rulten, C. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Shahinyan, Karlen and Tyler, J. and Wakely, S. P. and Weiner, O. M. and Weinstein, A. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, David A. and Zitzer, B. and Vurm, Indrek and Beloborodov, Andrei}, title = {A Strong Limit on the Very-high-energy Emission from GRB 150323A}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {857}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, organization = {VERITAS Collaboration}, issn = {0004-637X}, doi = {10.3847/1538-4357/aab371}, pages = {6}, year = {2018}, abstract = {On 2015 March 23, the Very Energetic Radiation Imaging Telescope Array System (VERITAS) responded to a Swift-Burst Alert Telescope (BAT) detection of a gamma-ray burst, with observations beginning 270 s after the onset of BAT emission, and only 135 s after the main BAT emission peak. No statistically significant signal is detected above 140 GeV. The VERITAS upper limit on the fluence in a 40-minute integration corresponds to about 1\% of the prompt fluence. Our limit is particularly significant because the very-high-energy (VHE) observation started only similar to 2 minutes after the prompt emission peaked, and Fermi-Large Area Telescope observations of numerous other bursts have revealed that the high-energy emission is typically delayed relative to the prompt radiation and lasts significantly longer. Also, the proximity of GRB 150323A (z = 0.593) limits the attenuation by the extragalactic background light to similar to 50\% at 100-200 GeV. We conclude that GRB 150323A had an intrinsically very weak high-energy afterglow, or that the GeV spectrum had a turnover below similar to 100 GeV. If the GRB exploded into the stellar wind of a massive progenitor, the VHE non-detection constrains the wind density parameter to be A greater than or similar to 3 x 10(11) g . cm(-1), consistent with a standard Wolf-Rayet progenitor. Alternatively, the VHE emission from the blast wave would be weak in a very tenuous medium such as the interstellar medium, which therefore cannot be ruled out as the environment of GRB 150323A.}, language = {en} } @article{PetrukKuzyoOrlandoetal.2018, author = {Petruk, Oleh and Kuzyo, T. and Orlando, S. and Pohl, Martin and Miceli, M. and Bocchino, F. and Beshley, V. and Brose, Robert}, title = {Post-adiabatic supernova remnants in an interstellar magnetic field}, series = {Monthly notices of the Royal Astronomical Society}, volume = {479}, journal = {Monthly notices of the Royal Astronomical Society}, number = {3}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/sty1750}, pages = {4253 -- 4270}, year = {2018}, abstract = {We present very-high-resolution 1D MHD simulations of the late-stage supernova remnants (SNRs). In the post-adiabatic stage, the magnetic field has an important and significant dynamical effect on the shock dynamics, the flow structure, and hence the acceleration and emission of cosmic rays. We find that the tangential component of the magnetic field provides pressure support that to a fair degree prevents the collapse of the radiative shell and thus limits the total compression ratio of the partially or fully radiative forward shock. A consequence is that the spectra of cosmic rays would not be as hard as in hydrodynamic simulations. We also investigated the effect on the flow profiles of the magnetic-field inclination and a large-scale gradient in the gas density and/or the magnetic field. A positive density gradient shortens the evolutionary stages, whereas a shock obliquity lowers the shock compression. The compression of the tangential component of the magnetic field leads to its dominance in the downstream region of post-adiabatic shocks for a wide range of orientation of the upstream field, which may explain why one preferentially observes tangential radio polarization in old SNRs. As most cosmic rays are produced at late stages of SNR evolution, the post-adiabatic phase and the influence of the magnetic field during it are most important for modeling the cosmic-ray acceleration at old SNRs and the gamma-ray emission from late-stage SNRs interacting with clouds.}, language = {en} } @article{MaciasGordonCrockeretal.2018, author = {Macias, Oscar and Gordon, Chris and Crocker, Roland M. and Coleman, Brendan and Paterson, Dylan and Horiuchi, Shunsaku and Pohl, Martin}, title = {Galactic bulge preferred over dark matter for the Galactic centre gamma-ray excess}, series = {Nature Astronomy}, volume = {2}, journal = {Nature Astronomy}, number = {5}, publisher = {Nature Publ. Group}, address = {London}, issn = {2397-3366}, doi = {10.1038/s41550-018-0414-3}, pages = {387 -- 392}, year = {2018}, abstract = {An anomalous gamma-ray excess emission has been found in the Fermi Large Area Telescope data1 covering the centre of the Galaxy2,3. Several theories have been proposed for this 'Galactic centre excess'. They include self-annihilation of dark-matter particles4, an unresolved population of millisecond pulsars5, an unresolved population of young pulsars6, or a series of burst events7. Here, we report on an analysis that exploits hydrodynamical modelling to register the position of interstellar gas associated with diffuse Galactic gamma-ray emission. We find evidence that the Galactic centre excess gamma rays are statistically better described by the stellar over-density in the Galactic bulge and the nuclear stellar bulge, rather than a spherical excess. Given its non-spherical nature, we argue that the Galactic centre excess is not a dark-matter phenomenon but rather associated with the stellar population of the Galactic bulge and the nuclear bulge.}, language = {en} } @article{DenkerKuckeinVermaetal.2018, author = {Denker, Carsten and Kuckein, Christoph and Verma, Meetu and Manrique Gonzalez, Sergio Javier Gonzalez and Diercke, Andrea and Enke, Harry and Klar, Jochen and Balthasar, Horst and Louis, Rohan E. and Dineva, Ekaterina Ivanova}, title = {High-cadence Imaging and Imaging Spectroscopy at the GREGOR Solar Telescope-A Collaborative Research Environment for High-resolution Solar Physics}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, volume = {236}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0067-0049}, doi = {10.3847/1538-4365/aab773}, pages = {12}, year = {2018}, abstract = {In high-resolution solar physics, the volume and complexity of photometric, spectroscopic, and polarimetric ground-based data significantly increased in the last decade, reaching data acquisition rates of terabytes per hour. This is driven by the desire to capture fast processes on the Sun and the necessity for short exposure times "freezing" the atmospheric seeing, thus enabling ex post facto image restoration. Consequently, large-format and high-cadence detectors are nowadays used in solar observations to facilitate image restoration. Based on our experience during the "early science" phase with the 1.5 m GREGOR solar telescope (2014-2015) and the subsequent transition to routine observations in 2016, we describe data collection and data management tailored toward image restoration and imaging spectroscopy. We outline our approaches regarding data processing, analysis, and archiving for two of GREGOR's post-focus instruments (see http://gregor.aip.de), i.e., the GREGOR Fabry-P{\´e}rot Interferometer (GFPI) and the newly installed High-Resolution Fast Imager (HiFI). The heterogeneous and complex nature of multidimensional data arising from high-resolution solar observations provides an intriguing but also a challenging example for "big data" in astronomy. The big data challenge has two aspects: (1) establishing a workflow for publishing the data for the whole community and beyond and (2) creating a collaborative research environment (CRE), where computationally intense data and postprocessing tools are colocated and collaborative work is enabled for scientists of multiple institutes. This requires either collaboration with a data center or frameworks and databases capable of dealing with huge data sets based on virtual observatory (VO) and other community standards and procedures.}, language = {en} } @article{VafinRafighiPohletal.2018, author = {Vafin, Sergei and Rafighi, Iman and Pohl, Martin and Niemiec, Jacek}, title = {The Electrostatic Instability for Realistic Pair Distributions in Blazar/EBL Cascades}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {857}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/aab552}, pages = {12}, year = {2018}, abstract = {This work revisits the electrostatic instability for blazar-induced pair beams propagating through the intergalactic medium (IGM) using linear analysis and PIC simulations. We study the impact of the realistic distribution function of pairs resulting from the interaction of high-energy gamma-rays with the extragalactic background light. We present analytical and numerical calculations of the linear growth rate of the instability for the arbitrary orientation of wave vectors. Our results explicitly demonstrate that the finite angular spread of the beam dramatically affects the growth rate of the waves, leading to the fastest growth for wave vectors quasi-parallel to the beam direction and a growth rate at oblique directions that is only a factor of 2-4 smaller compared to the maximum. To study the nonlinear beam relaxation, we performed PIC simulations that take into account a realistic wide-energy distribution of beam particles. The parameters of the simulated beam-plasma system provide an adequate physical picture that can be extrapolated to realistic blazar-induced pairs. In our simulations, the beam looses only 1\% of its energy, and we analytically estimate that the beam would lose its total energy over about 100 simulation times. An analytical scaling is then used to extrapolate the parameters of realistic blazar-induced pair beams. We find that they can dissipate their energy slightly faster by the electrostatic instability than through inverse-Compton scattering. The uncertainties arising from, e.g., details of the primary gamma-ray spectrum are too large to make firm statements for individual blazars, and an analysis based on their specific properties is required.}, language = {en} } @article{ArcherBenbowBirdetal.2018, author = {Archer, A. and Benbow, W. and Bird, R. and Brose, Robert and Buchovecky, M. and Buckley, J. H. and Bugaev, V. and Connolly, M. P. and Cui, W. and Daniel, M. K. and Feng, Q. and Finley, J. P. and Fortson, L. and Furniss, A. and Gillanders, G. and Huetten, M. and Hanna, D. and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Johnson, C. A. and Kaaret, P. and Kar, P. and Kelley-Hoskins, N. and Kertzman, M. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Lin, T. T. Y. and Maier, G. and McArthur, S. and Moriarty, P. and Mukherjee, R. and Ong, R. A. and Otte, A. N. and Petrashyk, A. and Pohl, M. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Sadeh, I. and Santander, M. and Sembroski, G. H. and Staszak, D. and Sushch, I. and Wakely, S. P. and Wells, R. M. and Wilcox, P. and Wilhelm, Alina and Williams, D. A. and Williamson, T. J. and Zitzer, B.}, title = {Measurement of cosmic-ray electrons at TeV energies by VERITAS}, series = {Physical review : D, Particles, fields, gravitation, and cosmology}, volume = {98}, journal = {Physical review : D, Particles, fields, gravitation, and cosmology}, number = {6}, publisher = {American Physical Society}, address = {College Park}, organization = {VERITAS Collaboration}, issn = {2470-0010}, doi = {10.1103/PhysRevD.98.062004}, pages = {7}, year = {2018}, abstract = {Cosmic-ray electrons and positrons (CREs) at GeV-TeV energies are a unique probe of our local Galactic neighborhood. CREs lose energy rapidly via synchrotron radiation and inverse-Compton scattering processes while propagating within the Galaxy, and these losses limit their propagation distance. For electrons with TeV energies, the limit is on the order of a kiloparsec. Within that distance, there are only a few known astrophysical objects capable of accelerating electrons to such high energies. It is also possible that the CREs are the products of the annihilation or decay of heavy dark matter (DM) particles. VERITAS, an array of imaging air Cherenkov telescopes in southern Arizona, is primarily utilized for gamma-ray astronomy but also simultaneously collects CREs during all observations. We describe our methods of identifying CREs in VERITAS data and present an energy spectrum, extending from 300 GeV to 5 TeV, obtained from approximately 300 hours of observations. A single power-law fit is ruled out in VERITAS data. We find that the spectrum of CREs is consistent with a broken power law, with a break energy at 710 +/- 40(stat) +/- 140(syst) GeV.}, language = {en} } @article{ArcherBenbowBirdetal.2018, author = {Archer, A. and Benbow, W. and Bird, R. and Brose, Robert and Buchovecky, M. and Bugaev, V. and Connolly, M. P. and Cui, W. and Daniel, M. K. and Falcone, A. and Feng, Q. and Finley, J. P. and Fleischhack, H. and Fortson, L. and Furniss, A. and Hanna, D. and Hervet, O. and Holder, J. and Hughes, G. and Humensky, T. B. and Hutten, M. and Johnson, C. A. and Kaaret, P. and Kelley-Hoskins, N. and Kieda, D. and Krause, M. and Krennrich, F. and Kumar, S. and Lang, M. J. and Maier, G. and McArthur, S. and Moriarty, P. and Mukherjee, R. and Nieto, D. and Ong, R. A. and Otte, A. N. and Park, N. and Petrashyk, A. and Pohl, Martin and Popkow, A. and Pueschel, Elisa and Quinn, J. and Ragan, K. and Reynolds, P. T. and Richards, G. T. and Roache, E. and Rulten, C. and Sadeh, I. and Tyler, J. and Wakely, S. P. and Weiner, O. M. and Wilcox, P. and Wilhelm, Alina and Williams, D. A. and Wissel, S. A. and Zitzer, B.}, title = {Measurement of the iron spectrum in cosmic rays by VERITAS}, series = {Physical review : D, Particles, fields, gravitation, and cosmology}, volume = {98}, journal = {Physical review : D, Particles, fields, gravitation, and cosmology}, number = {2}, publisher = {American Physical Society}, address = {College Park}, organization = {VERITAS Collaboration}, issn = {2470-0010}, doi = {10.1103/PhysRevD.98.022009}, pages = {15}, year = {2018}, abstract = {We present a new measurement of the energy spectrum of iron nuclei in cosmic rays from 20 TeV to 500 TeV; The measurement makes use of a template-based analysis method, which, for the first time, is applied to the energy reconstruction of iron-induced air showers recorded by the VERITAS array of imaging atmospheric Cherenkov telescopes. The event selection makes use of the direct Cherenkov light which is emitted by charged particles before the first interaction, as well as other parameters related to the shape of the recorded air shower images. The measured spectrum is well described by a power law dF/dE = f(0) center dot (E/E-0)(-gamma) over the full energy range, with gamma = 2.82 +/- 0.30(stat)(-0.27)(+0.24)(syst) and f(0) = (4.82 +/- 0.98(stat)(-2.70)(+2.12)(syst)) x 10(-7) m(-2) s(-1) TeV-1 sr(-1) at E-0 = 50 TeV, with no indication of a cutoff or spectral break. The measured differential flux is compatible with previous results, with improved statistical uncertainty at the highest energies.}, language = {en} } @article{ChenLoischGrossetal.2018, author = {Chen, Ye and Loisch, Gregor and Gross, Matthias and Jao, Chun-Sung and Krasilnikov, Mikhail and Oppelt, Anne and Osterhoff, Jens and Pohl, Martin and Qian, Houjun and Stephan, Frank and Vafin, Sergei}, title = {Generation of quasi continuous-wave electron beams in an L-band normal conducting pulsed RF injector for laboratory astrophysics experiments}, series = {Nuclear instruments \& methods in physics research : a journal on accelerators, instrumentation and techniques applied to research in nuclear and atomic physics, materials science and related fields in physics ; A, Accelerators, spectrometers, detectors and associated equipment}, volume = {903}, journal = {Nuclear instruments \& methods in physics research : a journal on accelerators, instrumentation and techniques applied to research in nuclear and atomic physics, materials science and related fields in physics ; A, Accelerators, spectrometers, detectors and associated equipment}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0168-9002}, doi = {10.1016/j.nima.2018.06.063}, pages = {119 -- 125}, year = {2018}, abstract = {We report on an approach to produce quasi continuous-wave (cw) electron beams with an average beam current of milliamperes and a mean beam energy of a few MeV in a pulsed RF injector. Potential applications are in the planned laboratory astrophysics programs at DESY. The beam generation is based on field emission from a specially designed metallic field emitter. A quasi cw beam profile is formed over subsequent RF cycles at the resonance frequency of the gun cavity. This is realized by debunching in a cut disk structure accelerating cavity (booster) downstream of the gun. The peak and average beam currents can be tuned in beam dynamics simulations by adjusting operation conditions of the booster cavity. Optimization of the transverse beam size at specific positions (e.g., entrance of the plasma experiment) is performed by applying magnetic focusing fields provided by solenoids along the beam line. In this paper, the design of a microtip field emitter is introduced and characterized in electromagnetic field simulations in the gun cavity. A series of particle tracking simulations are conducted for multi-parametric optimization of the parameters of the produced quasi cw electron beams. The obtained results will be presented and discussed. In addition, measurements of the parasitic field emission (PFE) current (dark current) in the PITZ gun will be exemplarily shown to distinguish its order of magnitude from the produced beam current by the designed field emitter.}, language = {en} } @article{SteffenRoeckstromRichardsonetal.2018, author = {Steffen, Will and R{\"o}ckstrom, Johan and Richardson, Katherine and Lenton, Timothy M. and Folke, Carl and Liverman, Diana and Summerhayes, Colin P. and Barnosky, Anthony D. and Cornell, Sarah E. and Crucifix, Michel and Donges, Jonathan and Fetzer, Ingo and Lade, Steven J. and Scheffer, Marten and Winkelmann, Ricarda and Schellnhuber, Hans Joachim}, title = {Trajectories of the Earth System in the Anthropocene}, series = {Proceedings of the National Academy of Sciences of the United States of America}, volume = {115}, journal = {Proceedings of the National Academy of Sciences of the United States of America}, number = {33}, publisher = {National Acad. of Sciences}, address = {Washington}, issn = {0027-8424}, doi = {10.1073/pnas.1810141115}, pages = {8252 -- 8259}, year = {2018}, abstract = {We explore the risk that self-reinforcing feedbacks could push the Earth System toward a planetary threshold that, if crossed, could prevent stabilization of the climate at intermediate temperature rises and cause continued warming on a "Hothouse Earth" pathway even as human emissions are reduced. Crossing the threshold would lead to a much higher global average temperature than any interglacial in the past 1.2 million years and to sea levels significantly higher than at any time in the Holocene. We examine the evidence that such a threshold might exist and where it might be. If the threshold is crossed, the resulting trajectory would likely cause serious disruptions to ecosystems, society, and economies. Collective human action is required to steer the Earth System away from a potential threshold and stabilize it in a habitable interglacial-like state. Such action entails stewardship of the entire Earth System-biosphere, climate, and societies-and could include decarbonization of the global economy, enhancement of biosphere carbon sinks, behavioral changes, technological innovations, new governance arrangements, and transformed social values.}, language = {en} } @article{GorenflotPaulkePiersimonietal.2018, author = {Gorenflot, Julien and Paulke, Andreas and Piersimoni, Fortunato and Wolf, Jannic and Kan, Zhipeng and Cruciani, Federico and El Labban, Abdulrahman and Neher, Dieter and Beaujuge, Pierre M. and Laquai, Frederic}, title = {From recombination dynamics to device performance}, series = {dvanced energy materials}, volume = {8}, journal = {dvanced energy materials}, number = {4}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201701678}, pages = {12}, year = {2018}, abstract = {An original set of experimental and modeling tools is used to quantify the yield of each of the physical processes leading to photocurrent generation in organic bulk heterojunction solar cells, enabling evaluation of materials and processing condition beyond the trivial comparison of device performances. Transient absorption spectroscopy, "the" technique to monitor all intermediate states over the entire relevant timescale, is combined with time-delayed collection field experiments, transfer matrix simulations, spectral deconvolution, and parametrization of the charge carrier recombination by a two-pool model, allowing quantification of densities of excitons and charges and extrapolation of their kinetics to device-relevant conditions. Photon absorption, charge transfer, charge separation, and charge extraction are all quantified for two recently developed wide-bandgap donor polymers: poly(4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-3,4-difluorothiophene) (PBDT[2F]T) and its nonfluorinated counterpart poly(4,8-bis((2-ethylhexyl)oxy)benzo[1,2-b:4,5-b′]dithiophene-3,4-thiophene) (PBDT[2H]T) combined with PC71BM in bulk heterojunctions. The product of these yields is shown to agree well with the devices' external quantum efficiency. This methodology elucidates in the specific case studied here the origin of improved photocurrents obtained when using PBDT[2F]T instead of PBDT[2H]T as well as upon using solvent additives. Furthermore, a higher charge transfer (CT)-state energy is shown to lead to significantly lower energy losses (resulting in higher VOC) during charge generation compared to P3HT:PCBM.}, language = {en} } @article{ShivhareErdmannHoermannetal.2018, author = {Shivhare, Rishi and Erdmann, Tim and Hoermann, Ulrich and Collado-Fregoso, Elisa and Zeiske, Stefan and Benduhn, Johannes and Ullbrich, Sascha and Huebner, Rene and Hambsch, Mike and Kiriy, Anton and Voit, Brigitte and Neher, Dieter and Vandewal, Koen and Mannsfeld, Stefan C. B.}, title = {Alkyl Branching Position in Diketopyrrolopyrrole Polymers}, series = {Chemistry of materials : a publication of the American Chemical Society}, volume = {30}, journal = {Chemistry of materials : a publication of the American Chemical Society}, number = {19}, publisher = {American Chemical Society}, address = {Washington}, issn = {0897-4756}, doi = {10.1021/acs.chemmater.8b02739}, pages = {6801 -- 6809}, year = {2018}, abstract = {Diketopyrrolopyrrole (DPP)-based donor acceptor copolymers have gained a significant amount of research interest in the organic electronics community because of their high charge carrier mobilities in organic field-effect transistors (OFETs) and their ability to harvest near-infrared (NIR) photons in solar cells. In this study, we have synthesized four DPP based donor-acceptor copolymers with variations in the donor unit and the branching point of the solubilizing alkyl chains (at the second or sixth carbon position). Grazing incidence wide-angle X-ray scattering (GIWAXS) results suggest that moving the branching point further away from the polymer backbone increases the tendency for aggregation and yields polymer phases with a higher degree of crystallinity (DoC). The polymers were blended with PC70BM and used as active layers in solar cells. A careful analysis of the energetics of the neat polymer and blend films reveals that the charge-transfer state energy (E-CT) of the blend films lies exceptionally close to the singlet energy of the donor (E-D*), indicating near zero electron transfer losses. The difference between the optical gap and open-circuit voltage (V-OC) is therefore determined to be due to rather high nonradiative 418 +/- 13 mV) and unavoidable radiative voltage losses (approximate to 255 +/- 8 mV). Even though the four materials have similar optical gaps, the short-circuit current density (J(SC)) covers a vast span from 7 to 18 mA cm(-2) for the best performing system. Using photoluminescence (PL) quenching and transient charge extraction techniques, we quantify geminate and nongeminate losses and find that fewer excitons reach the donor-acceptor interface in polymers with further away branching points due to larger aggregate sizes. In these material systems, the photogeneration is therefore mainly limited by exciton harvesting efficiency.}, language = {en} } @article{BraungerMundtWolffetal.2018, author = {Braunger, Steffen and Mundt, Laura E. and Wolff, Christian Michael and Mews, Mathias and Rehermann, Carolin and Jost, Marko and Tejada, Alvaro and Eisenhauer, David and Becker, Christiane and Andres Guerra, Jorge and Unger, Eva and Korte, Lars and Neher, Dieter and Schubert, Martin C. and Rech, Bernd and Albrecht, Steve}, title = {Cs(x)FA(1-x)Pb(l(1-y)Br(y))(3) Perovskite Compositions}, series = {The journal of physical chemistry : C, Nanomaterials and interfaces}, volume = {122}, journal = {The journal of physical chemistry : C, Nanomaterials and interfaces}, number = {30}, publisher = {American Chemical Society}, address = {Washington}, issn = {1932-7447}, doi = {10.1021/acs.jpcc.8b06459}, pages = {17123 -- 17135}, year = {2018}, abstract = {We report on the formation of wrinkle-patterned surface morphologies in cesium formamidinium-based Cs(x)FA(1-y)Pb(I1-yBry)(3) perovskite compositions with x = 0-0.3 and y = 0-0.3 under various spin-coating conditions. By varying the Cs and Br contents, the perovskite precursor solution concentration and the spin-coating procedure, the occurrence and characteristics of the wrinkle-shaped morphology can be tailored systematically. Cs(0.17)FA(0.83)Pb(I0.83Br0.17)(3) perovskite layers were analyzed regarding their surface roughness, microscopic structure, local and overall composition, and optoelectronic properties. Application of these films in p-i-n perovskite solar cells (PSCs) with indium-doped tin oxide/NiOx/perovskite/C-60/bathocuproine/Cu architecture resulted in up to 15.3 and 17.0\% power conversion efficiency for the flat and wrinkled morphology, respectively. Interestingly, we find slightly red-shifted photoluminescence (PL) peaks for wrinkled areas and we are able to directly correlate surface topography with PL peak mapping. This is attributed to differences in the local grain size, whereas there is no indication for compositional demixing in the films. We show that the perovskite composition, crystallization kinetics, and layer thickness strongly influence the formation of wrinkles which is proposed to be related to the release of compressive strain during perovskite crystallization. Our work helps us to better understand film formation and to further improve the efficiency of PSCs with widely used mixed-perovskite compositions.}, language = {en} } @article{GonzalezGalanOskinovaPopovetal.2018, author = {Gonz{\´a}lez-Gal{\´a}n, Ana and Oskinova, Lida and Popov, Sergei B. and Haberl, F. and K{\"u}hnel, M. and Gallagher, John S. and Schurch, Matthew and Guerrero, Mart{\´i}n A.}, title = {A multiwavelength study of SXP 1062, the long-period X-ray pulsar associated with a supernova remnant}, series = {Monthly notices of the Royal Astronomical Society}, volume = {475}, journal = {Monthly notices of the Royal Astronomical Society}, number = {2}, publisher = {Oxford University Press}, address = {Oxford}, issn = {0035-8711}, doi = {10.1093/mnras/stx3127}, pages = {2809 -- 2821}, year = {2018}, abstract = {SXP 1062 is a Be X-ray binary (BeXB) located in the Small Magellanic Cloud. It hosts a long-period X-ray pulsar and is likely associated with the supernova remnant MCSNR J0127-7332. In this work we present a multiwavelength view on SXP 1062 in different luminosity regimes. We consider monitoring campaigns in optical (OGLE survey) and X-ray (Swift telescope). During these campaigns a tight coincidence of X-ray and optical outbursts is observed. We interpret this as typical Type I outbursts as often detected in BeXBs at periastron passage of the neutron star (NS). To study different X-ray luminosity regimes in depth, during the source quiescence we observed it with XMM-Newton while Chandra observations followed an X-ray outburst. Nearly simultaneously with Chandra observations in X-rays, in optical the RSS/SALT telescope obtained spectra of SXP 1062. On the basis of our multiwavelength campaign we propose a simple scenario where the disc of the Be star is observed face-on, while the orbit of the NS is inclined with respect to the disc. According to the model of quasi-spherical settling accretion our estimation of the magnetic field of the pulsar in SXP 1062 does not require an extremely strong magnetic field at the present time.}, language = {en} } @article{MolinaGarciaSandevSafdarietal.2018, author = {Molina-Garcia, Daniel and Sandev, Trifce and Safdari, Hadiseh and Pagnini, Gianni and Chechkin, Aleksei V. and Metzler, Ralf}, title = {Crossover from anomalous to normal diffusion}, series = {New Journal of Physics}, volume = {20}, journal = {New Journal of Physics}, publisher = {IOP Publishing Ltd}, address = {London und Bad Honnef}, issn = {1367-2630}, doi = {10.1088/1367-2630/aae4b2}, pages = {28}, year = {2018}, abstract = {Abstract The emerging diffusive dynamics in many complex systems show a characteristic crossover behaviour from anomalous to normal diffusion which is otherwise fitted by two independent power-laws. A prominent example for a subdiffusive-diffusive crossover are viscoelastic systems such as lipid bilayer membranes, while superdiffusive-diffusive crossovers occur in systems of actively moving biological cells. We here consider the general dynamics of a stochastic particle driven by so-called tempered fractional Gaussian noise, that is noise with Gaussian amplitude and power-law correlations, which are cut off at some mesoscopic time scale. Concretely we consider such noise with built-in exponential or power-law tempering, driving an overdamped Langevin equation (fractional Brownian motion) and fractional Langevin equation motion. We derive explicit expressions for the mean squared displacement and correlation functions, including different shapes of the crossover behaviour depending on the concrete tempering, and discuss the physical meaning of the tempering. In the case of power-law tempering we also find a crossover behaviour from faster to slower superdiffusion and slower to faster subdiffusion. As a direct application of our model we demonstrate that the obtained dynamics quantitatively describes the subdiffusion-diffusion and subdiffusion-subdiffusion crossover in lipid bilayer systems. We also show that a model of tempered fractional Brownian motion recently proposed by Sabzikar and Meerschaert leads to physically very different behaviour with a seemingly paradoxical ballistic long time scaling.}, language = {en} } @article{SandevTomovskiDubbeldametal.2018, author = {Sandev, Trifce and Tomovski, Zivorad and Dubbeldam, Johan L. A. and Chechkin, Aleksei V.}, title = {Generalized diffusion-wave equation with memory kernel}, series = {Journal of physics : A, Mathematical and theoretical}, volume = {52}, journal = {Journal of physics : A, Mathematical and theoretical}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {1751-8113}, doi = {10.1088/1751-8121/aaefa3}, pages = {22}, year = {2018}, abstract = {We study generalized diffusion-wave equation in which the second order time derivative is replaced by an integro-differential operator. It yields time fractional and distributed order time fractional diffusion-wave equations as particular cases. We consider different memory kernels of the integro-differential operator, derive corresponding fundamental solutions, specify the conditions of their non-negativity and calculate the mean squared displacement for all cases. In particular, we introduce and study generalized diffusion-wave equations with a regularized Prabhakar derivative of single and distributed orders. The equations considered can be used for modeling the broad spectrum of anomalous diffusion processes and various transitions between different diffusion regimes.}, language = {en} } @article{SandevMetzlerChechkin2018, author = {Sandev, Trifce and Metzler, Ralf and Chechkin, Aleksei V.}, title = {From continuous time random walks to the generalized diffusion equation}, series = {Fractional calculus and applied analysis : an international journal for theory and applications}, volume = {21}, journal = {Fractional calculus and applied analysis : an international journal for theory and applications}, number = {1}, publisher = {De Gruyter}, address = {Berlin}, issn = {1311-0454}, doi = {10.1515/fca-2018-0002}, pages = {10 -- 28}, year = {2018}, abstract = {We obtain a generalized diffusion equation in modified or Riemann-Liouville form from continuous time random walk theory. The waiting time probability density function and mean squared displacement for different forms of the equation are explicitly calculated. We show examples of generalized diffusion equations in normal or Caputo form that encode the same probability distribution functions as those obtained from the generalized diffusion equation in modified form. The obtained equations are general and many known fractional diffusion equations are included as special cases.}, language = {en} } @article{JanowskiZoschkeScharffetal.2018, author = {Janowski, Marcin Andrzej and Zoschke, Reimo and Scharff, Lars B. and Jaime, Silvia Martinez and Ferrari, Camilla and Proost, Sebastian and Xiong, Jonathan Ng Wei and Omranian, Nooshin and Musialak-Lange, Magdalena and Nikoloski, Zoran and Graf, Alexander and Schoettler, Mark Aurel and Sampathkumar, Arun and Vaid, Neha and Mutwil, Marek}, title = {AtRsgA from Arabidopsis thaliana is important for maturation of the small subunit of the chloroplast ribosome}, series = {The plant journal}, volume = {96}, journal = {The plant journal}, number = {2}, publisher = {Wiley}, address = {Hoboken}, issn = {0960-7412}, doi = {10.1111/tpj.14040}, pages = {404 -- 420}, year = {2018}, abstract = {Plastid ribosomes are very similar in structure and function to the ribosomes of their bacterial ancestors. Since ribosome biogenesis is not thermodynamically favorable under biological conditions it requires the activity of many assembly factors. Here we have characterized a homolog of bacterial RsgA in Arabidopsis thaliana and show that it can complement the bacterial homolog. Functional characterization of a strong mutant in Arabidopsis revealed that the protein is essential for plant viability, while a weak mutant produced dwarf, chlorotic plants that incorporated immature pre-16S ribosomal RNA into translating ribosomes. Physiological analysis of the mutant plants revealed smaller, but more numerous, chloroplasts in the mesophyll cells, reduction of chlorophyll a and b, depletion of proplastids from the rib meristem and decreased photosynthetic electron transport rate and efficiency. Comparative RNA sequencing and proteomic analysis of the weak mutant and wild-type plants revealed that various biotic stress-related, transcriptional regulation and post-transcriptional modification pathways were repressed in the mutant. Intriguingly, while nuclear- and chloroplast-encoded photosynthesis-related proteins were less abundant in the mutant, the corresponding transcripts were increased, suggesting an elaborate compensatory mechanism, potentially via differentially active retrograde signaling pathways. To conclude, this study reveals a chloroplast ribosome assembly factor and outlines the transcriptomic and proteomic responses of the compensatory mechanism activated during decreased chloroplast function. Significance Statement AtRsgA is an assembly factor necessary for maturation of the small subunit of the chloroplast ribosome. Depletion of AtRsgA leads to dwarfed, chlorotic plants, a decrease of mature 16S rRNA and smaller, but more numerous, chloroplasts. Large-scale transcriptomic and proteomic analysis revealed that chloroplast-encoded and -targeted proteins were less abundant, while the corresponding transcripts were increased in the mutant. We analyze the transcriptional responses of several retrograde signaling pathways to suggest the mechanism underlying this compensatory response.}, language = {en} } @article{ShpritsMeniettiDrozdovetal.2018, author = {Shprits, Yuri Y. and Menietti, J. D. and Drozdov, Alexander and Horne, Richard B. and Woodfield, Emma E. and Groene, J. B. and de Soria-Santacruz, M. and Averkamp, T. F. and Garrett, H. and Paranicas, C. and Gurnett, Don A.}, title = {Strong whistler mode waves observed in the vicinity of Jupiter's moons}, series = {Nature Communications}, volume = {9}, journal = {Nature Communications}, publisher = {Nature Publ. Group}, address = {London}, issn = {2041-1723}, doi = {10.1038/s41467-018-05431-x}, pages = {6}, year = {2018}, abstract = {Understanding of wave environments is critical for the understanding of how particles are accelerated and lost in space. This study shows that in the vicinity of Europa and Ganymede, that respectively have induced and internal magnetic fields, chorus wave power is significantly increased. The observed enhancements are persistent and exceed median values of wave activity by up to 6 orders of magnitude for Ganymede. Produced waves may have a pronounced effect on the acceleration and loss of particles in the Jovian magnetosphere and other astrophysical objects. The generated waves are capable of significantly modifying the energetic particle environment, accelerating particles to very high energies, or producing depletions in phase space density. Observations of Jupiter's magnetosphere provide a unique opportunity to observe how objects with an internal magnetic field can interact with particles trapped in magnetic fields of larger scale objects.}, language = {en} } @article{HoermannZeiskePiersimonietal.2018, author = {H{\"o}rmann, Ulrich and Zeiske, Stefan and Piersimoni, Fortunato and Hoffmann, Lukas and Schlesinger, Raphael and Koch, Norbert and Riedl, Thomas and Andrienko, Denis and Neher, Dieter}, title = {Stark effect of hybrid charge transfer states at planar ZnO/organic interfaces}, series = {Physical review : B, Condensed matter and materials physics}, volume = {98}, journal = {Physical review : B, Condensed matter and materials physics}, number = {15}, publisher = {American Physical Society}, address = {College Park}, issn = {2469-9950}, doi = {10.1103/PhysRevB.98.155312}, pages = {9}, year = {2018}, abstract = {We investigate the bias dependence of the hybrid charge transfer state emission at planar heterojunctions between the metal oxide acceptor ZnO and three donor molecules. The electroluminescence peak energy linearly increases with the applied bias, saturating at high fields. Variation of the organic layer thickness and deliberate change of the ZnO conductivity through controlled photodoping allow us to confirm that this bias-induced spectral shift relates to the internal electric field in the organic layer rather than the filling of states at the hybrid interface. We show that existing continuum models overestimate the hole delocalization and propose a simple electrostatic model in which the linear and quadratic Stark effects are explained by the electrostatic interaction of a strongly polarizable molecular cation with its mirror image.}, language = {en} } @article{NiCaoShpritsetal.2018, author = {Ni, Binbin and Cao, Xing and Shprits, Yuri Y. and Summers, Danny and Gu, Xudong and Fu, Song and Lou, Yuequn}, title = {Hot Plasma Effects on the Cyclotron-Resonant Pitch-Angle Scattering Rates of Radiation Belt Electrons Due to EMIC Waves}, series = {Geophysical research letters}, volume = {45}, journal = {Geophysical research letters}, number = {1}, publisher = {American Geophysical Union}, address = {Washington}, issn = {0094-8276}, doi = {10.1002/2017GL076028}, pages = {21 -- 30}, year = {2018}, abstract = {To investigate the hot plasma effects on the cyclotron-resonant interactions between electromagnetic ion cyclotron (EMIC) waves and radiation belt electrons in a realistic magnetospheric environment, calculations of the wave-induced bounce-averaged pitch angle diffusion coefficients are performed using both the cold and hot plasma dispersion relations. The results demonstrate that the hot plasma effects have a pronounced influence on the electron pitch angle scattering rates due to all three EMIC emission bands (H+, He+, and O+) when the hot plasma dispersion relation deviates significantly from the cold plasma approximation. For a given wave spectrum, the modification of the dispersion relation by hot anisotropic protons can strongly increase the minimum resonant energy for electrons interacting with O+ band EMIC waves, while the minimum resonant energies for H+ and He+ bands are not greatly affected. For H+ band EMIC waves, inclusion of hot protons tends to weaken the pitch angle scattering efficiency of >5MeV electrons. The most crucial differences introduced by the hot plasma effects occur for >3MeV electron scattering rates by He+ band EMIC waves. Mainly due to the changes of resonant frequency and wave group velocity when the hot protons are included, the difference in scattering rates can be up to an order of magnitude, showing a strong dependence on both electron energy and equatorial pitch angle. Our study confirms the importance of including hot plasma effects in modeling the scattering of ultra-relativistic radiation belt electrons by EMIC waves.}, language = {en} } @article{KaramzadehToularoudHeimannDahmetal.2018, author = {Karamzadeh Toularoud, Nasim and Heimann, Sebastian and Dahm, Torsten and Kr{\"u}ger, Frank}, title = {Application based seismological array design by seismicity scenario modelling}, series = {Geophysical journal international}, volume = {216}, journal = {Geophysical journal international}, number = {3}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0956-540X}, pages = {1711 -- 1727}, year = {2018}, abstract = {The design of an array configuration is an important task in array seismology during experiment planning. Often the array response function (ARF), which depends on the relative position of array stations and frequency content of the incoming signals, is used as the array design criterion. In practice, additional constraints and parameters have to be taken into account, for example, land ownership, site-specific noise levels or characteristics of the seismic sources under investigation. In this study, a flexible array design framework is introduced that implements a customizable scenario modelling and optimization scheme by making use of synthetic seismograms. Using synthetic seismograms to evaluate array performance makes it possible to consider additional constraints. We suggest to use synthetic array beamforming as an array design criterion instead of the ARF. The objective function of the optimization scheme is defined according to the monitoring goals, and may consist of a number of subfunctions. The array design framework is exemplified by designing a seven-station small-scale array to monitor earthquake swarm activity in Northwest Bohemia/Vogtland in central Europe. Two subfunctions are introduced to verify the accuracy of horizontal slowness estimation; one to suppress aliasing effects due to possible secondary lobes of synthetic array beamforming calculated in horizontal slowness space and the other to reduce the event's mislocation caused by miscalculation of the horizontal slowness vector. Subsequently, a weighting technique is applied to combine the subfunctions into one single scalar objective function to use in the optimization process.}, language = {en} } @article{KurpiersFerronRolandetal.2018, author = {Kurpiers, Jona and Ferron, Thomas and Roland, Steffen and Jakoby, Marius and Thiede, Tobias and Jaiser, Frank and Albrecht, Steve and Janietz, Silvia and Collins, Brian A. and Howard, Ian A. and Neher, Dieter}, title = {Probing the pathways of free charge generation in organic bulk heterojunction solar cells}, series = {Nature Communications}, volume = {9}, journal = {Nature Communications}, publisher = {Nature Publ. Group}, address = {London}, issn = {2041-1723}, doi = {10.1038/s41467-018-04386-3}, pages = {11}, year = {2018}, abstract = {The fact that organic solar cells perform efficiently despite the low dielectric constant of most photoactive blends initiated a long-standing debate regarding the dominant pathways of free charge formation. Here, we address this issue through the accurate measurement of the activation energy for free charge photogeneration over a wide range of photon energy, using the method of time-delayed collection field. For our prototypical low bandgap polymer:fullerene blends, we find that neither the temperature nor the field dependence of free charge generation depend on the excitation energy, ruling out an appreciable contribution to free charge generation though hot carrier pathways. On the other hand, activation energies are on the order of the room temperature thermal energy for all studied blends. We conclude that charge generation in such devices proceeds through thermalized charge transfer states, and that thermal energy is sufficient to separate most of these states into free charges.}, language = {en} } @article{SiniSchubertRiskoetal.2018, author = {Sini, Gjergji and Schubert, Marcel and Risko, Chad and Roland, Steffen and Lee, Olivia P. and Chen, Zhihua and Richter, Thomas V. and Dolfen, Daniel and Coropceanu, Veaceslav and Ludwigs, Sabine and Scherf, Ullrich and Facchetti, Antonio and Frechet, Jean M. J. and Neher, Dieter}, title = {On the Molecular Origin of Charge Separation at the Donor-Acceptor Interface}, series = {Advanced energy materials}, volume = {8}, journal = {Advanced energy materials}, number = {12}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201702232}, pages = {15}, year = {2018}, abstract = {Fullerene-based acceptors have dominated organic solar cells for almost two decades. It is only within the last few years that alternative acceptors rival their dominance, introducing much more flexibility in the optoelectronic properties of these material blends. However, a fundamental physical understanding of the processes that drive charge separation at organic heterojunctions is still missing, but urgently needed to direct further material improvements. Here a combined experimental and theoretical approach is used to understand the intimate mechanisms by which molecular structure contributes to exciton dissociation, charge separation, and charge recombination at the donor-acceptor (D-A) interface. Model systems comprised of polythiophene-based donor and rylene diimide-based acceptor polymers are used and a detailed density functional theory (DFT) investigation is performed. The results point to the roles that geometric deformations and direct-contact intermolecular polarization play in establishing a driving force ( energy gradient) for the optoelectronic processes taking place at the interface. A substantial impact for this driving force is found to stem from polymer deformations at the interface, a finding that can clearly lead to new design approaches in the development of the next generation of conjugated polymers and small molecules.}, language = {en} } @article{RanLoveHeiberetal.2018, author = {Ran, Niva A. and Love, John A. and Heiber, Michael C. and Jiao, Xuechen and Hughes, Michael P. and Karki, Akchheta and Wang, Ming and Brus, Viktor V. and Wang, Hengbin and Neher, Dieter and Ade, Harald and Bazan, Guillermo C. and Thuc-Quyen Nguyen,}, title = {Charge generation and recombination in an organic solar cell with low energetic offsets}, series = {dvanced energy materials}, volume = {8}, journal = {dvanced energy materials}, number = {5}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201701073}, pages = {12}, year = {2018}, abstract = {Organic bulk heterojunction (BHJ) solar cells require energetic offsets between the donor and acceptor to obtain high short-circuit currents (J(SC)) and fill factors (FF). However, it is necessary to reduce the energetic offsets to achieve high open-circuit voltages (V-OC). Recently, reports have highlighted BHJ blends that are pushing at the accepted limits of energetic offsets necessary for high efficiency. Unfortunately, most of these BHJs have modest FF values. How the energetic offset impacts the solar cell characteristics thus remains poorly understood. Here, a comprehensive characterization of the losses in a polymer:fullerene BHJ blend, PIPCP:phenyl-C61-butyric acid methyl ester (PC61BM), that achieves a high V-OC (0.9 V) with very low energy losses (E-loss = 0.52 eV) from the energy of absorbed photons, a respectable J(SC) (13 mA cm(-2)), but a limited FF (54\%) is reported. Despite the low energetic offset, the system does not suffer from field-dependent generation and instead it is characterized by very fast nongeminate recombination and the presence of shallow traps. The charge-carrier losses are attributed to suboptimal morphology due to high miscibility between PIPCP and PC61BM. These results hold promise that given the appropriate morphology, the J(SC), V-OC, and FF can all be improved, even with very low energetic offsets.}, language = {en} } @article{AlqahtaniBabicsGorenflotetal.2018, author = {Alqahtani, Obaid and Babics, Maxime and Gorenflot, Julien and Savikhin, Victoria and Ferron, Thomas and Balawi, Ahmed H. and Paulke, Andreas and Kan, Zhipeng and Pope, Michael and Clulow, Andrew J. and Wolf, Jannic and Burn, Paul L. and Gentle, Ian R. and Neher, Dieter and Toney, Michael F. and Laquai, Frederic and Beaujuge, Pierre M. and Collins, Brian A.}, title = {Mixed Domains Enhance Charge Generation and Extraction in Bulk-Heterojunction Solar Cells with Small-Molecule Donors}, series = {Advanced energy materials}, volume = {8}, journal = {Advanced energy materials}, number = {19}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201702941}, pages = {16}, year = {2018}, abstract = {The interplay between nanomorphology and efficiency of polymer-fullerene bulk-heterojunction (BHJ) solar cells has been the subject of intense research, but the generality of these concepts for small-molecule (SM) BHJs remains unclear. Here, the relation between performance; charge generation, recombination, and extraction dynamics; and nanomorphology achievable with two SM donors benzo[1,2-b:4,5-b]dithiophene-pyrido[3,4-b]-pyrazine BDT(PPTh2)(2), namely SM1 and SM2, differing by their side-chains, are examined as a function of solution additive composition. The results show that the additive 1,8-diiodooctane acts as a plasticizer in the blends, increases domain size, and promotes ordering/crystallinity. Surprisingly, the system with high domain purity (SM1) exhibits both poor exciton harvesting and severe charge trapping, alleviated only slightly with increased crystallinity. In contrast, the system consisting of mixed domains and lower crystallinity (SM2) shows both excellent exciton harvesting and low charge recombination losses. Importantly, the onset of large, pure crystallites in the latter (SM2) system reduces efficiency, pointing to possible differences in the ideal morphologies for SM-based BHJ solar cells compared with polymer-fullerene devices. In polymer-based systems, tie chains between pure polymer crystals establish a continuous charge transport network, whereas SM-based active layers may in some cases require mixed domains that enable both aggregation and charge percolation to the electrodes.}, language = {en} } @article{WoodfieldHorneGlauertetal.2018, author = {Woodfield, Emma E. and Horne, Richard B. and Glauert, S. A. and Menietti, J. D. and Shprits, Yuri Y. and Kurth, William S.}, title = {Formation of electron radiation belts at Saturn by Z-mode wave acceleration}, series = {Nature Communications}, volume = {9}, journal = {Nature Communications}, publisher = {Nature Publ. Group}, address = {London}, issn = {2041-1723}, doi = {10.1038/s41467-018-07549-4}, pages = {7}, year = {2018}, abstract = {At Saturn electrons are trapped in the planet's magnetic field and accelerated to relativistic energies to form the radiation belts, but how this dramatic increase in electron energy occurs is still unknown. Until now the mechanism of radial diffusion has been assumed but we show here that in-situ acceleration through wave particle interactions, which initial studies dismissed as ineffectual at Saturn, is in fact a vital part of the energetic particle dynamics there. We present evidence from numerical simulations based on Cassini spacecraft data that a particular plasma wave, known as Z-mode, accelerates electrons to MeV energies inside 4 RS (1 RS = 60,330 km) through a Doppler shifted cyclotron resonant interaction. Our results show that the Z-mode waves observed are not oblique as previously assumed and are much better accelerators than O-mode waves, resulting in an electron energy spectrum that closely approaches observed values without any transport effects included.}, language = {en} } @article{GiangrisostomiOvsyannikovSorgenfreietal.2018, author = {Giangrisostomi, Erika and Ovsyannikov, Ruslan and Sorgenfrei, Nomi and Zhang, Teng and Lindblad, Andreas and Sassa, Yasmine and Cappel, Ute B. and Leitner, Torsten and Mitzner, Rolf and Svensson, Svante and Martensson, Nils and F{\"o}hlisch, Alexander}, title = {Low Dose Photoelectron Spectroscopy at BESSY II}, series = {Journal of electron spectroscopy and related phenomena : the international journal on theoretical and experimental aspects of electron spectroscopy}, volume = {224}, journal = {Journal of electron spectroscopy and related phenomena : the international journal on theoretical and experimental aspects of electron spectroscopy}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0368-2048}, doi = {10.1016/j.elspec.2017.05.011}, pages = {68 -- 78}, year = {2018}, abstract = {The implementation of a high-transmission, angular-resolved time-of-Right electron spectrometer with a 1.25 MHz pulse selector at the PM4 soft X-ray dipole beamline of the synchrotron BESSY II creates unique capabilities to inquire electronic structure via photoelectron spectroscopy with a minimum of radiation dose. Solid-state samples can be prepared and characterized with standard UHV techniques and rapidly transferred from various preparation chambers to a 4-axis temperature-controlled measurement stage. A synchronized MHz laser system enables excited-state characterization and dynamical studies starting from the picosecond timescale. This article introduces the principal characteristics of the PM4 beamline and LowDosePES end-station. Recent results from graphene, an organic hole transport material for solar cells and the transition metal dichalcogenide MoS2 are presented to demonstrate the instrument performances.}, language = {en} } @article{PontiusBeyeTrabantetal.2018, author = {Pontius, Niko and Beye, Martin and Trabant, Christoph and Mitzner, Rolf and Sorgenfrei, Nomi and Kachel, Torsten and Woestmann, Michael and Roling, Sebastian and Zacharias, Helmut and Ivanov, Rosen and Treusch, Rolf and Buchholz, Marcel and Metcalf, Pete and Schuessler-Langeheine, Christian and F{\"o}hlisch, Alexander}, title = {Probing the non-equilibrium transient state in magnetite by a jitter-free two-color X-ray pump and X-ray probe experiment}, series = {Structural dynamics}, volume = {5}, journal = {Structural dynamics}, number = {5}, publisher = {American Institute of Physics}, address = {Melville}, issn = {2329-7778}, doi = {10.1063/1.5042847}, pages = {8}, year = {2018}, abstract = {We present a general experimental concept for jitter-free pump and probe experiments at free electron lasers. By generating pump and probe pulse from one and the same X-ray pulse using an optical split-and-delay unit, we obtain a temporal resolution that is limited only by the X-ray pulse lengths. In a two-color X-ray pump and X-ray probe experiment with sub 70 fs temporal resolution, we selectively probe the response of orbital and charge degree of freedom in the prototypical functional oxide magnetite after photoexcitation. We find electronic order to be quenched on a time scale of (30 +/- 30) fs and hence most likely faster than what is to be expected for any lattice dynamics. Our experimental result hints to the formation of a short lived transient state with decoupled electronic and lattice degree of freedom in magnetite. The excitation and relaxation mechanism for X-ray pumping is discussed within a simple model leading to the conclusion that within the first 10 fs the original photoexcitation decays into low-energy electronic excitations comparable to what is achieved by optical pump pulse excitation. Our findings show on which time scales dynamical decoupling of degrees of freedom in functional oxides can be expected and how to probe this selectively with soft X-ray pulses. Results can be expected to provide crucial information for theories for ultrafast behavior of materials and help to develop concepts for novel switching devices. (C) 2018 Author(s).}, language = {en} } @article{KimShprits2018, author = {Kim, Kyung-Chan and Shprits, Yuri Y.}, title = {Survey of the Favorable Conditions for Magnetosonic Wave Excitation}, series = {Journal of geophysical research : Space physics}, volume = {123}, journal = {Journal of geophysical research : Space physics}, number = {1}, publisher = {American Geophysical Union}, address = {Washington}, issn = {2169-9380}, doi = {10.1002/2017JA024865}, pages = {400 -- 413}, year = {2018}, abstract = {The ratio of the proton ring velocity (VR) to the local Alfven speed (VA), in addition to proton ring distributions, plays a key factor in the excitation of magnetosonic waves at frequencies between the proton cyclotron frequency fcp and the lower hybrid resonance frequency fLHR in the Earth's magnetosphere. Here we investigate whether there is a statistically significant relationship between occurrences of proton rings and magnetosonic waves both outside and inside the plasmapause using particle and wave data from Van Allen Probe-A during the time period of October 2012 to December 2015. We also perform a statistical survey of the ratio of the ring energy (ER, corresponding to VR) to the Alfven energy (EA, corresponding to VA) to determine the favorable conditions under which magnetosonic waves in each of two frequency bands (fcp < f ≤ 0.5 fLHR and 0.5 fLHR < f < fLHR) can be excited. The results show that the magnetosonic waves in both frequency bands occur around the postnoon (12-18 magnetic local time, MLT) sector outside the plasmapause when ER is comparable to or lower than EA, and those in lower-frequency bands (fcp < f ≤ 0.5 fLHR) occur around the postnoon sector inside the plasmapause when ER/EA > ~9. However, there is one discrepancy between occurrences of proton rings and magnetosonic waves in low-frequency bands around the prenoon sector (6-12 MLT) outside the plasmapause, which suggests either that the waves may have propagated during active time from the postnoon sector after being excited during quiet time, or they may have locally excited in the prenoon sector during active time.}, language = {en} } @article{LiBenduhnLietal.2018, author = {Li, Tian-yi and Benduhn, Johannes and Li, Yue and Jaiser, Frank and Spoltore, Donato and Zeika, Olaf and Ma, Zaifei and Neher, Dieter and Vandewal, Koen and Leo, Karl}, title = {Boron dipyrromethene (BODIPY) with meso-perfluorinated alkyl substituents as near infrared donors in organic solar cells}, series = {Journal of materials chemistry : A, Materials for energy and sustainability}, volume = {6}, journal = {Journal of materials chemistry : A, Materials for energy and sustainability}, number = {38}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2050-7488}, doi = {10.1039/c8ta06261g}, pages = {18583 -- 18591}, year = {2018}, abstract = {Three furan-fused BODIPYs were synthesized with perfluorinated methyl, ethyl and n-propyl groups on the meso-carbon. They were obtained with high yields by reacting the furan-fused 2-carboxylpyrrole in corresponding perfluorinated acid and anhydride. With the increase in perfluorinated alkyl chain length, the molecular packing in the single crystal is influenced, showing increasing stacking distance and decreasing slope angle. All the BODIPYs were characterized as intense absorbers in near infrared region in solid state, peaking at similar to 800 nm with absorption coefficient of over 280 000 cm(-1). Facilitated by high thermal stability, the furan-fused BODIPYs were employed in vacuum-deposited organic solar cells as electron donors. All devices exhibit PCE over 6.0\% with the EQE maximum reaching 70\% at similar to 790 nm. The chemical modification of the BODIPY donors have certain influence on the active layer morphology, and the highest PCE of 6.4\% was obtained with a notably high jsc of 13.6 mA cm(-2). Sensitive EQE and electroluminance studies indicated that the energy losses generated by the formation of a charge transfer state and the radiative recombination at the donor-acceptor interface were comparable in the range of 0.14-0.19 V, while non-radiative recombination energy loss of 0.38 V was the main energy loss route resulting in the moderate V-oc of 0.76 V.}, language = {en} } @article{LiebigSarhanPrietzeletal.2018, author = {Liebig, Ferenc and Sarhan, Radwan Mohamed and Prietzel, Claudia Christina and Th{\"u}nemann, Andreas F. and Bargheer, Matias and Koetz, Joachim}, title = {Undulated Gold Nanoplatelet Superstructures}, series = {Langmuir}, volume = {34}, journal = {Langmuir}, number = {15}, publisher = {American Chemical Society}, address = {Washington}, issn = {0743-7463}, doi = {10.1021/acs.langmuir.7b02898}, pages = {4584 -- 4594}, year = {2018}, abstract = {Negatively charged flat gold nanotriangles, formed in a vesicular template phase and separated by an AOT-micelle-based depletion flocculation, were reloaded by adding a cationic polyelectrolyte, that is, a hyperbranched polyethylenimine (PEI). Heating the system to 100 degrees C in the presence of a gold chloride solution, the reduction process leads to the formation of gold nanoparticles inside the polymer shell surrounding the nanoplatelets. The gold nanoparticle formation is investigated by UV-vis spectroscopy, small-angle X-ray scattering, and dynamic light scattering measurements in combination with transmission electron microscopy. Spontaneously formed gold clusters in the hyperbranched PEI shell with an absorption maximum at 350 nm grow on the surface of the nanotriangles as hemispherical particles with diameters of similar to 6 nm. High-resolution micrographs show that the hemispherical gold particles are crystallized onto the {111} facets on the bottom and top of the platelet as well as on the edges without a grain boundary. Undulated gold nanoplatelet superstructures with special properties become available, which show a significantly modified performance in SERS-detected photocatalysis regarding both reactivity and enhancement factor.}, language = {en} } @article{LiebigHenningSarhanetal.2018, author = {Liebig, Ferenc and Henning, Ricky and Sarhan, Radwan Mohamed and Prietzel, Claudia Christina and Bargheer, Matias and Koetz, Joachim}, title = {A new route to gold nanoflowers}, series = {Nanotechnology}, volume = {29}, journal = {Nanotechnology}, number = {18}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0957-4484}, doi = {10.1088/1361-6528/aaaffd}, pages = {8}, year = {2018}, abstract = {Catanionic vesicles spontaneously formed by mixing the anionic surfactant bis(2-ethylhexyl)sulfosuccinate sodium salt with the cationic surfactant cetyltrimethylammonium bromide were used as a reducing medium to produce gold clusters, which are embedded and well-ordered into the template phase. The gold clusters can be used as seeds in the growth process that follows by adding ascorbic acid as a mild reducing component. When the ascorbic acid was added very slowly in an ice bath round-edged gold nanoflowers were produced. When the same experiments were performed at room temperature in the presence of Ag+ ions, sharp-edged nanoflowers could be synthesized. The mechanism of nanoparticle formation can be understood to be a non-diffusion-limited Ostwald ripening process of preordered gold nanoparticles embedded in catanionic vesicle fragments. Surface-enhanced Raman scattering experiments show an excellent enhancement factor of 1.7 . 10(5) for the nanoflowers deposited on a silicon wafer.}, language = {en} } @article{SteteSchossauBargheeretal.2018, author = {Stete, Felix and Schossau, Phillip and Bargheer, Matias and Koopman, Wouter-Willem Adriaan}, title = {Size-Dependent coupling of Hybrid Core-Shell Nanorods}, series = {The journal of physical chemistry : C, Nanomaterials and interfaces}, volume = {122}, journal = {The journal of physical chemistry : C, Nanomaterials and interfaces}, number = {31}, publisher = {American Chemical Society}, address = {Washington}, issn = {1932-7447}, doi = {10.1021/acs.jpcc.8b04204}, pages = {17976 -- 17982}, year = {2018}, abstract = {Owing to their ability of concentrating electromagnetic fields to subwavelength mode volumes, plasmonic nanoparticles foster extremely high light-matter coupling strengths reaching far into the strong-coupling regime of light matter interaction. In this article, we present an experimental investigation on the dependence of coupling strength on the geometrical size of the nanoparticle. The coupling strength for differently sized hybrid plasmon-core exciton-shell nanorods was extracted from the typical resonance anticrossing of these systems, obtained by controlled modification of the environment permittivity using layer-by-layer deposition of polyelectrolytes. The observed size dependence of the coupling strength can be explained by a simple model approximating the electromagnetic mode volume by the geometrical volume of the particle. On the basis of this model, the coupling strength for particles of arbitrary size can be predicted, including the particle size necessary to support single-emitter strong coupling.}, language = {en} } @article{DavidzonIlbertFaisstetal.2018, author = {Davidzon, Iary and Ilbert, Olivier and Faisst, Andreas L. and Sparre, Martin and Capak, Peter L.}, title = {An Alternate Approach to Measure Specific Star Formation Rates at 2 < z < 7}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, volume = {852}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0004-637X}, doi = {10.3847/1538-4357/aaa19e}, pages = {11}, year = {2018}, abstract = {We trace the specific star formation rate (sSFR) of massive star-forming galaxies (greater than or similar to 10(10)M(circle dot)) from z similar to 2 to 7. Our method is substantially different from previous analyses, as it does not rely on direct estimates of star formation rate, but on the differential evolution of the galaxy stellar mass function (SMF). We show the reliability of this approach by means of semianalytical and hydrodynamical cosmological simulations. We then apply it to real data, using the SMFs derived in the COSMOS and CANDELS fields. We find that the sSFR is proportional to (1 + z)(1.1) (+/-) (0.2) at z > 2, in agreement with other observations but in tension with the steeper evolution predicted by simulations from z similar to 4 to 2. We investigate the impact of several sources of observational bias, which, however, cannot account for this discrepancy. Although the SMF of high-redshift galaxies is still affected by significant errors, we show that future large-area surveys will substantially reduce them, making our method an effective tool to probe the massive end of the main sequence of star-forming galaxies.}, language = {en} } @article{YazmaciyanStolterfohtBurnetal.2018, author = {Yazmaciyan, Aren and Stolterfoht, Martin and Burn, Paul L. and Lin, Qianqian and Meredith, Paul and Armin, Ardalan}, title = {Recombination losses above and below the transport percolation threshold in bulk heterojunction organic solar cells}, series = {Advanced energy materials}, volume = {8}, journal = {Advanced energy materials}, number = {18}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1614-6832}, doi = {10.1002/aenm.201703339}, pages = {8}, year = {2018}, abstract = {Achieving the highest power conversion efficiencies in bulk heterojunction organic solar cells requires a morphology that delivers electron and hole percolation pathways for optimized transport, plus sufficient donor:acceptor contact area for near unity charge transfer state formation. This is a significant structural challenge, particularly in semiconducting polymer:fullerene systems. This balancing act in the model high efficiency PTB7:PC70BM blend is studied by tuning the donor:acceptor ratio, with a view to understanding the recombination loss mechanisms above and below the fullerene transport percolation threshold. The internal quantum efficiency is found to be strongly correlated to the slower carrier mobility in agreement with other recent studies. Furthermore, second-order recombination losses dominate the shape of the current density-voltage curve in efficient blend combinations, where the fullerene phase is percolated. However, below the charge transport percolation threshold, there is an electric-field dependence of first-order losses, which includes electric-field-dependent photogeneration. In the intermediate regime, the fill factor appears to be limited by both first- and second-order losses. These findings provide additional basic understanding of the interplay between the bulk heterojunction morphology and the order of recombination in organic solar cells. They also shed light on the limitations of widely used transport models below the percolation threshold.}, language = {en} }