@article{GiewekemeyerKruegerKalbfleischetal.2011, author = {Giewekemeyer, K. and Krueger, S. P. and Kalbfleisch, S. and Bartels, Meike and Beta, Carsten and Salditt, T.}, title = {X-ray propagation microscopy of biological cells using waveguides as a quasipoint source}, series = {Physical review : A, Atomic, molecular, and optical physics}, volume = {83}, journal = {Physical review : A, Atomic, molecular, and optical physics}, number = {2}, publisher = {American Physical Society}, address = {College Park}, issn = {1050-2947}, doi = {10.1103/PhysRevA.83.023804}, pages = {7}, year = {2011}, abstract = {We have used x-ray waveguides as highly confining optical elements for nanoscale imaging of unstained biological cells using the simple geometry of in-line holography. The well-known twin-image problem is effectively circumvented by a simple and fast iterative reconstruction. The algorithm which combines elements of the classical Gerchberg-Saxton scheme and the hybrid-input-output algorithm is optimized for phase-contrast samples, well-justified for imaging of cells at multi-keV photon energies. The experimental scheme allows for a quantitative phase reconstruction from a single holographic image without detailed knowledge of the complex illumination function incident on the sample, as demonstrated for freeze-dried cells of the eukaryotic amoeba Dictyostelium discoideum. The accessible resolution range is explored by simulations, indicating that resolutions on the order of 20 nm are within reach applying illumination times on the order of minutes at present synchrotron sources.}, language = {en} } @article{GerhardtGroegerMacCarthy2011, author = {Gerhardt, Matthias and Groeger, Gillian and MacCarthy, Niall}, title = {Monopolar vs. bipolar subretinal stimulation-An in vitro study}, series = {Journal of neuroscience methods}, volume = {199}, journal = {Journal of neuroscience methods}, number = {1}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0165-0270}, doi = {10.1016/j.jneumeth.2011.04.017}, pages = {26 -- 34}, year = {2011}, abstract = {This study uses an in vitro rd10 mouse model to quantify and compare the ability of the monopolar and the (concentric) bipolar electrode configurations for subretinal stimulation. To allow for results which can be directly compared an identical region of the retina was stimulated due to the circumstance that the bipolar electrode configuration allows also for monopolar stimulation, if the concentric counter-electrode is set potential-free (floating). A ganglion cell, located centrally over the bipolar electrode configuration was selected to extracellularly record action potentials during stimulation. To analyse the recorded action potentials, we introduce a new method which combines the advantages of (a) singular value decomposition (SVD) for weighting similar modulation patterns with which the recorded action potentials are characterized and (b) multi curve fitting to identify a common threshold level, required to finally assemble a strength-duration relationship (SDR). By directly comparing the obtained SDR curves, we found that the efficiency of stimulation with the monopolar electrode configuration is significantly higher than with the bipolar electrode configuration. All obtained SDR curves were fitted using the Lapicque model to estimate the chronaxie times and the rheobase currents. Liquid inclusions, eventually separating the retina from the electrodes are discussed to be a major cause for low ganglion cell responses during stimulation with the bipolar electrode configuration.}, language = {en} } @misc{Gerhard2011, author = {Gerhard, Reimund}, title = {Honoring Professor Gerhard M. Sessler on his 80th Birthday (15th of February 2011)}, series = {IEEE transactions on dielectrics and electrical insulation}, volume = {18}, journal = {IEEE transactions on dielectrics and electrical insulation}, number = {1}, publisher = {Inst. of Electr. and Electronics Engineers}, address = {Piscataway}, issn = {1070-9878}, doi = {10.1109/TDEI.2011.5704485}, pages = {1 -- 2}, year = {2011}, language = {en} } @article{GagneFehonSavoyetal.2011, author = {Gagne, Marc and Fehon, Garrett and Savoy, Michael R. and Cohen, David H. and Townsley, Leisa K. and Broos, Patrick S. and Povich, Matthew S. and Corcoran, Michael F. and Walborn, Nolan R. and Evans, Nancy Remage and Moffat, Anthony F. J. and Naze, Yael and Oskinova, Lidia M.}, title = {Carina ob stars: x-ray signatures of wind shocks and magnetic FIELDS}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, volume = {194}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0067-0049}, doi = {10.1088/0067-0049/194/1/5}, pages = {26}, year = {2011}, abstract = {The Chandra Carina Complex contains 200 known O- and B-type stars. The Chandra survey detected 68 of the 70 O stars and 61 of 127 known B0-B3 stars. We have assembled a publicly available optical/X-ray database to identify OB stars that depart from the canonical L-X/L-bol relation or whose average X-ray temperatures exceed 1 keV. Among the single O stars with high kT we identify two candidate magnetically confined wind shock sources: Tr16-22, O8.5 V, and LS 1865, O8.5 V((f)). The O4 III(fc) star HD 93250 exhibits strong, hard, variable X-rays, suggesting that it may be a massive binary with a period of > 30 days. The visual O2 If* binary HD 93129A shows soft 0.6 keV and hard 1.9 keV emission components, suggesting embedded wind shocks close to the O2 If* Aa primary and colliding wind shocks between Aa and Ab. Of the 11 known O-type spectroscopic binaries, the long orbital-period systems HD 93343, HD 93403, and QZ Car have higher shock temperatures than short-period systems such as HD 93205 and FO 15. Although the X-rays from most B stars may be produced in the coronae of unseen, low-mass pre-main-sequence companions, a dozen B stars with high L-X cannot be explained by a distribution of unseen companions. One of these, SS73 24 in the Treasure Chest cluster, is a new candidate Herbig Be star.}, language = {en} } @article{FuhrmannSeehaferValorietal.2011, author = {Fuhrmann, Marcel and Seehafer, Norbert and Valori, Gherardo and Wiegelmann, Thomas}, title = {A comparison of preprocessing methods for solar force-free magnetic field extrapolation}, issn = {0004-6361}, year = {2011}, language = {en} } @article{FuhrmannSeehaferValorietal.2011, author = {Fuhrmann, Marcel and Seehafer, Norbert and Valori, Gherardo and Wiegelmann, T.}, title = {A comparison of preprocessing methods for solar force-free magnetic field extrapolation}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {526}, journal = {Astronomy and astrophysics : an international weekly journal}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/201015453}, pages = {12}, year = {2011}, abstract = {Context. Extrapolations of solar photospheric vector magnetograms into three-dimensional magnetic fields in the chromosphere and corona are usually done under the assumption that the fields are force-free. This condition is violated in the photosphere itself and a thin layer in the lower atmosphere above. The field calculations can be improved by preprocessing the photospheric magnetograms. The intention here is to remove a non-force-free component from the data. Aims. We compare two preprocessing methods presently in use, namely the methods of Wiegelmann et al. (2006, Sol. Phys., 233, 215) and Fuhrmann et al. (2007, A\&A, 476, 349). Methods. The two preprocessing methods were applied to a vector magnetogram of the recently observed active region NOAA AR 10 953. We examine the changes in the magnetogram effected by the two preprocessing algorithms. Furthermore, the original magnetogram and the two preprocessed magnetograms were each used as input data for nonlinear force-free field extrapolations by means of two different methods, and we analyze the resulting fields. Results. Both preprocessing methods managed to significantly decrease the magnetic forces and magnetic torques that act through the magnetogram area and that can cause incompatibilities with the assumption of force-freeness in the solution domain. The force and torque decrease is stronger for the Fuhrmann et al. method. Both methods also reduced the amount of small-scale irregularities in the observed photospheric field, which can sharply worsen the quality of the solutions. For the chosen parameter set, the Wiegelmann et al. method led to greater changes in strong-field areas, leaving weak-field areas mostly unchanged, and thus providing an approximation of the magnetic field vector in the chromosphere, while the Fuhrmann et al. method weakly changed the whole magnetogram, thereby better preserving patterns present in the original magnetogram. Both preprocessing methods raised the magnetic energy content of the extrapolated fields to values above the minimum energy, corresponding to the potential field. Also, the fields calculated from the preprocessed magnetograms fulfill the solenoidal condition better than those calculated without preprocessing.}, language = {en} } @article{FlossKlamrothSaalfrank2011, author = {Floss, Gereon and Klamroth, Tillmann and Saalfrank, Peter}, title = {Laser-controlled switching of molecular arrays in an dissipative environment}, series = {Physical review : B, Condensed matter and materials physics}, volume = {83}, journal = {Physical review : B, Condensed matter and materials physics}, number = {10}, publisher = {American Physical Society}, address = {College Park}, issn = {1098-0121}, doi = {10.1103/PhysRevB.83.104301}, pages = {9}, year = {2011}, abstract = {The optical switching of molecular ensembles in a dissipative environment is a subject of various fields of chemical physics and physical chemistry. Here we try to switch arrays of molecules from a stable collective ground state to a state in which all molecules have been transferred to another stable higher-energy configuration. In our model switching proceeds through electronically excited intermediates which are coherently coupled to each other through dipolar interactions, and which decay incoherently within a finite lifetime by coupling to a dissipative environment. The model is quite general, but parameters are chosen to roughly resemble the all-trans -> all-cis isomerization of an array of azobenzene molecules on a surface. Using analytical and optimal control pulses and the concept of "laser distillation," we demonstrate that for various aggregates (dimers up to hexamers), controlled and complete switching should be possible.}, language = {en} } @phdthesis{FloresSuarez2011, author = {Flores Su{\´a}rez, Rosaura}, title = {Three-dimensional polarization probing in polymer ferroelectrics, polymer-dispersed liquid crystals, and polymer ferroelectrets}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-60173}, school = {Universit{\"a}t Potsdam}, year = {2011}, abstract = {A key non-destructive technique for analysis, optimization and developing of new functional materials such as sensors, transducers, electro-optical and memory devices is presented. The Thermal-Pulse Tomography (TPT) provides high-resolution three-dimensional images of electric field and polarization distribution in a material. This thermal technique use a pulsed heating by means of focused laser light which is absorbed by opaque electrodes. The diffusion of the heat causes changes in the sample geometry, generating a short-circuit current or change in surface potential, which contains information about the spatial distribution of electric dipoles or space charges. Afterwards, a reconstruction of the internal electric field and polarization distribution in the material is possible via Scale Transformation or Regularization methods. In this way, the TPT was used for the first time to image the inhomogeneous ferroelectric switching in polymer ferroelectric films (candidates to memory devices). The results shows the typical pinning of electric dipoles in the ferroelectric polymer under study and support the previous hypotheses of a ferroelectric reversal at a grain level via nucleation and growth. In order to obtain more information about the impact of the lateral and depth resolution of the thermal techniques, the TPT and its counterpart called Focused Laser Intensity Modulation Method (FLIMM) were implemented in ferroelectric films with grid-shaped electrodes. The results from both techniques, after the data analysis with different regularization and scale methods, are in total agreement. It was also revealed a possible overestimated lateral resolution of the FLIMM and highlights the TPT method as the most efficient and reliable thermal technique. After an improvement in the optics, the Thermal-Pulse Tomography method was implemented in polymer-dispersed liquid crystals (PDLCs) films, which are used in electro-optical applications. The results indicated a possible electrostatic interaction between the COH group in the liquid crystals and the fluorinate atoms of the used ferroelectric matrix. The geometrical parameters of the LC droplets were partially reproduced as they were compared with Scanning Electron Microscopy (SEM) images. For further applications, it is suggested the use of a non-strong-ferroelectric polymer matrix. In an effort to develop new polymerferroelectrets and for optimizing their properties, new multilayer systems were inspected. The results of the TPT method showed the non-uniformity of the internal electric-field distribution in the shaped-macrodipoles and thus suggested the instability of the sample. Further investigation on multilayers ferroelectrets was suggested and the implementation of less conductive polymers layers too.}, language = {en} } @article{FilimonKopfSchmidtetal.2011, author = {Filimon, Marlena and Kopf, Ilona and Schmidt, Dietrich A. and Bruendermann, Erik and R{\"u}he, J{\"u}rgen and Santer, Svetlana and Havenith, Martina}, title = {Local chemical composition of nanophase-separated polymer brushes}, series = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, volume = {13}, journal = {Physical chemistry, chemical physics : a journal of European Chemical Societies}, number = {24}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {1463-9076}, doi = {10.1039/c0cp02756a}, pages = {11620 -- 11626}, year = {2011}, abstract = {Using scattering scanning nearfield infrared microscopy (s-SNIM), we have imaged the nanoscale phase separation of mixed polystyrene-poly(methyl methacrylate) (PS-PMMA) brushes and investigated changes in the top layer as a function of solvent exposure. We deduce that the top-layer of the mixed brushes is composed primarily of PMMA after exposure to acetone, while after exposure to toluene this changes to PS. Access to simultaneously measured topographic and chemical information allows direct correlation of the chemical morphology of the sample with topographic information. Our results demonstrate the potential of s-SNIM for chemical mapping based on distinct infrared absorption properties of polymers with a high spatial resolution of 80 nm x 80 nm.}, language = {en} } @article{FiehlerBannertBischoffetal.2011, author = {Fiehler, Katja and Bannert, Michael M. and Bischoff, Matthias and Blecker, Carlo and Stark, Rudolf and Vaitl, Dieter and Franz, Volker H. and Roesler, Frank}, title = {Working memory maintenance of grasp-target information in the human posterior parietal cortex}, series = {NeuroImage : a journal of brain function}, volume = {54}, journal = {NeuroImage : a journal of brain function}, number = {3}, publisher = {Elsevier}, address = {San Diego}, issn = {1053-8119}, doi = {10.1016/j.neuroimage.2010.09.080}, pages = {2401 -- 2411}, year = {2011}, abstract = {Event-related functional magnetic resonance imaging was applied to identify cortical areas involved in maintaining target information in working memory used for an upcoming grasping action. Participants had to grasp with their thumb and index finger of the dominant right hand three-dimensional objects of different size and orientation. Reaching-to-grasp movements were performed without visual feedback either immediately after object presentation or after a variable delay of 2-12 s. The right inferior parietal cortex demonstrated sustained neural activity throughout the delay, which overlapped with activity observed during encoding of the grasp target. Immediate and delayed grasping activated similar motor-related brain areas and showed no differential activity. The results suggest that the right inferior parietal cortex plays an important functional role in working memory maintenance of grasp-related information. Moreover, our findings confirm the assumption that brain areas engaged in maintaining information are also involved in encoding the same information, and thus extend previous findings on working memory function of the posterior parietal cortex in saccadic behavior to reach-to-grasp movements.}, language = {en} } @article{FeudelBergemannTuckermanetal.2011, author = {Feudel, Fred and Bergemann, Kay and Tuckerman, Laurette S. and Egbers, C. and Futterer, B. and Gellert, Marcus and Hollerbach, Rainer}, title = {Convection patterns in a spherical fluid shell}, series = {Physical review : E, Statistical, nonlinear and soft matter physics}, volume = {83}, journal = {Physical review : E, Statistical, nonlinear and soft matter physics}, number = {4}, publisher = {American Physical Society}, address = {College Park}, issn = {1539-3755}, doi = {10.1103/PhysRevE.83.046304}, pages = {8}, year = {2011}, abstract = {Symmetry-breaking bifurcations have been studied for convection in a nonrotating spherical shell whose outer radius is twice the inner radius, under the influence of an externally applied central force field with a radial dependence proportional to 1/r(5). This work is motivated by the GeoFlow experiment, which is performed under microgravity condition at the International Space Station where this particular central force can be generated. In order to predict the observable patterns, simulations together with path-following techniques and stability computations have been applied. Branches of axisymmetric, octahedral, and seven-cell solutions have been traced. The bifurcations producing them have been identified and their stability ranges determined. At higher Rayleigh numbers, time-periodic states with a complex spatiotemporal symmetry are found, which we call breathing patterns.}, language = {en} } @misc{FedericiPohlRuppeletal.2011, author = {Federici, S. and Pohl, Martin and Ruppel, J. and Telezhinsky, Igor O. and Hofmann, Werner and Martinez, M. and Knapp, J.}, title = {Design concepts for the Cherenkov Telescope Array CTA}, series = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, volume = {32}, journal = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {1325}, issn = {1866-8372}, doi = {10.25932/publishup-43014}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-430149}, pages = {124}, year = {2011}, abstract = {Ground-based gamma-ray astronomy has had a major breakthrough with the impressive results obtained using systems of imaging atmospheric Cherenkov telescopes. Ground-based gamma-ray astronomy has a huge potential in astrophysics, particle physics and cosmology. CTA is an international initiative to build the next generation instrument, with a factor of 5-10 improvement in sensitivity in the 100 GeV-10 TeV range and the extension to energies well below 100 GeV and above 100 TeV. CTA will consist of two arrays (one in the north, one in the south) for full sky coverage and will be operated as open observatory. The design of CTA is based on currently available technology. This document reports on the status and presents the major design concepts of CTA.}, language = {en} } @article{Fechner2011, author = {Fechner, Cora}, title = {Reconstructing the intergalactic UV background with QSO absorption lines}, series = {Astronomy and astrophysics : an international weekly journal}, volume = {532}, journal = {Astronomy and astrophysics : an international weekly journal}, number = {2}, publisher = {EDP Sciences}, address = {Les Ulis}, issn = {0004-6361}, doi = {10.1051/0004-6361/201117080}, pages = {15}, year = {2011}, abstract = {We present a new approach to observationally constraining the spectral energy distribution of the intergalactic UV background by studying metal absorption systems. We study single-component metal line systems that exhibit various well-measured species. Among the observed transitions, at least two ratios of ionization stages from the same element are required, e. g. C III/C IV and Si III/Si IV. For each system photoionization models are constructed by varying the spectrum of the ionizing radiation. The spectral energy distribution can then be constrained by comparing the models with the observed column density ratios. Extensive tests with artificial absorbers show that the spectrum of the ionizing radiation cannot be reconstructed unambiguously, but it is possible to constrain the main characteristics of the spectrum. Furthermore, the resulting physical parameters of the absorber, such as ionization parameter, metallicity, and relative abundances, may depend strongly on the adopted ionizing spectrum. Even in case of well-fitting models, the uncertainties can be as high as similar to 0.5 dex for the ionization parameter and up to similar to 1.5 dex for the metallicity. Therefore, it is essential to know the hardness of the UV background when estimating the metallicity of the intergalactic medium. Applying the procedure to a small sample of 3 observed single-component metal line systems yields a soft ionizing radiation at z > 2 and a slightly harder spectrum at z < 2. The resulting energy distributions exhibit strong He II Lya re-emission features, suggesting that reprocessing by intergalactic He II is important. Comparing the observed systems to UV background spectra from the literature indicates that a recent model that includes sawtooth modulation due to reprocessing by intergalactic He II with delayed helium reionization fits the investigated systems very well.}, language = {en} } @article{FangWangWirgesetal.2011, author = {Fang, Peng and Wang, Feipeng and Wirges, Werner and Gerhard, Reimund and Basso, Heitor Cury}, title = {Three-layer piezoelectrets from fluorinated ethylene-propylene (FEP) copolymer films}, series = {Applied physics : A, Materials science \& processing}, volume = {103}, journal = {Applied physics : A, Materials science \& processing}, number = {2}, publisher = {Springer}, address = {New York}, issn = {0947-8396}, doi = {10.1007/s00339-010-6008-2}, pages = {455 -- 461}, year = {2011}, abstract = {A process for preparing three-layer piezoelectrets from fluorinated ethylene-propylene (FEP) copolymer films is introduced. Samples are made from commercial FEP films by means of laser cutting, laser bonding, electrode evaporation, and high-field poling. The observed dielectric-resonance spectra demonstrate the piezoelectricity of the FEP sandwiches. Piezoelectric d (33) coefficients up to a few hundred pC/N are achieved. Charging at elevated temperatures can increase the thermal stability of the piezoelectrets. Isothermal experiments for approximately 15 min demonstrate that samples charged at 140A degrees C keep their piezoelectric activity up to at least 120A degrees C and retain 70\% of their initial d (33) even at 130A degrees C. Acoustical measurements show a relatively flat frequency response in the range between 300 Hz and 20 kHz.}, language = {en} } @article{EvansDeGioiaEastwoodGagneetal.2011, author = {Evans, Nancy Remage and DeGioia-Eastwood, Kathleen and Gagne, Marc and Townsley, Leisa and Broos, Patrick S. and Wolk, Scott J. and Naze, Yael and Corcoran, Michael and Oskinova, Lidia M. and Moffat, Anthony F. J. and Wang, Junfeng and Walborn, Nolan R.}, title = {The search for low-mass companions of b stars in the Carina Nebula cluster trumpler 16}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, volume = {194}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series}, number = {1}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {0067-0049}, doi = {10.1088/0067-0049/194/1/13}, pages = {9}, year = {2011}, abstract = {We have developed lists of likely B3-A0 stars (called "late B" stars) in the young cluster Trumpler 16. The following criteria were used: location within 3' of eta Car, an appropriate V and B - V combination, and proper motion (where available). Color and magnitude cuts have been made assuming an E(B - V) = 0.55 mag +/- 0.1, which is a good approximation close to the center of Trumpler 16. These lists have been cross-correlated with X-ray sources found in the Chandra Carina Complex Project. Previous studies have shown that only very rarely (if at all) do late main-sequence B stars produce X-rays. We present evidence that the X-ray-detected sources are binaries with low-mass companions, since stars less massive than 1.4 M-circle dot are strong X-ray sources at the age of the cluster. Both the median X-ray energies and X-ray luminosities of these sources are in good agreement with values for typical low-mass coronal X-ray sources. We find that 39\% of the late B stars based on a list with proper motions have low-mass companions. Similarly, 32\% of a sample without proper motions have low-mass companions. We discuss the X-ray detection completeness. These results on low-mass companions of intermediate-mass stars are complementary to spectroscopic and interferometric results and probe new parameter space of low-mass companions at all separations. They do not support a steeply rising distribution of mass ratios to low masses for intermediate-mass (5 M-circle dot) primaries, such as would be found by random pairing from the initial mass function.}, language = {en} } @article{EichlerPohl2011, author = {Eichler, David and Pohl, Martin}, title = {Can ultrahigh-energy cosmic rays come from Gamma-ray bursts? - cosmic rays below the ankle and galactic gamma-ray bursts}, series = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, volume = {738}, journal = {The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters}, number = {2}, publisher = {IOP Publ. Ltd.}, address = {Bristol}, issn = {2041-8205}, doi = {10.1088/2041-8205/738/2/L21}, pages = {4}, year = {2011}, abstract = {The maximum cosmic-ray energy achievable by acceleration by a relativistic blast wave is derived. It is shown that forward shocks from long gamma-ray bursts (GRBs) in the interstellar medium accelerate protons to large enough energies, and have a sufficient energy budget, to produce the Galactic cosmic-ray component just below the ankle at 4 x 10(18) eV, as per an earlier suggestion. It is further argued that, were extragalactic long GRBs responsible for the component above the ankle as well, the occasional Galactic GRB within the solar circle would contribute more than the observational limits on the outward flux from the solar circle, unless an avoidance scenario, such as intermittency and/or beaming, allows the present-day local flux to be less than 10(-3) of the average. Difficulties with these avoidance scenarios are noted.}, language = {en} } @article{DoeringKolloscheRabeetal.2011, author = {D{\"o}ring, Sebastian and Kollosche, Matthias and Rabe, Torsten and Stumpe, Joachim and Kofod, Guggi}, title = {Electrically tunable polymer DFB laser}, series = {Advanced materials}, volume = {23}, journal = {Advanced materials}, number = {37}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {0935-9648}, doi = {10.1002/adma.201102465}, pages = {4265 -- 4269}, year = {2011}, language = {en} } @phdthesis{Doering2011, author = {D{\"o}ring, Sebastian}, title = {Oberfl{\"a}chengitter in azobenzenhaltigen Schichten f{\"u}r organische DFB-Laser}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus-59211}, school = {Universit{\"a}t Potsdam}, year = {2011}, abstract = {Ein neuentwickeltes azobenzenhaltiges Material, das auf einem supramolekularen Konzept basiert, wird bez{\"u}glich seiner Strukturbildung w{\"a}hrend einer holografischen Belichtung bei 488 nm untersucht. Im Mittelpunkt stehen dabei eindimensionale, sinusf{\"o}rmige Reliefs mit Periodizit{\"a}ten kleiner 500 nm. Es wird gezeigt, wie der Grad der Vernetzung der photosensitiven Schicht die Strukturbildung in diesem Gr{\"o}ßenbereich beeinflusst. Zur Maximierung der Strukturtiefe werden gezielt Prozessparameter der Belichtung sowie Materialparameter variiert. Unter Standardbedingungen und moderaten Belichtungsintensit{\"a}ten von ca. 200 mW/cm² bilden sich innerhalb weniger Minuten bei einer Periode von 400 nm Strukturtiefen von bis zu 80nm aus. Durch die Beeinflussung von Materialparametern, wie Oberfl{\"a}chenspannung und Viskosit{\"a}t, wird die maximale Strukturtiefe auf 160nm verdoppelt. Durch Mehrfachbelichtungen wird auch die Bildung von zweidimensionalen Gittern untersucht. Die Originalstrukturen werden in einem Abformverfahren kopiert und in Schichten von unter UV-Licht aush{\"a}rtenden Polymeren {\"u}bertragen. Durch das Abformen kommt es zu einer geringf{\"u}gigen Verschlechterung der Oberfl{\"a}chenqualit{\"a}t sowie Abnahme der Strukturtiefe. Dieser Verlust wird durch eine Verringerung der Prozesstemperatur verringert. Mithilfe kopierter Oberfl{\"a}chengitter werden organische Distributed Feedback-(DFB)-Laser zweiter Ordnung hergestellt, um den Einfluss von Gitterparametern auf die Emissionseigenschaften dieser Laser zu untersuchen. Dazu erfolgt zun{\"a}chst die Charakterisierung der optischen Verst{\"a}rkungseigenschaften ausgew{\"a}hlter organischer Emittermaterialien mittels der Variablen Strichl{\"a}ngenmethode. Das mit dem Laserfarbstoff Pyrromthen567 (PM567) dotierte Polystyrol (PS) zeigt dabei trotz konzentrationsbedingter geringer Absorption eine vergleichsweise geringe Gewinnschwelle von 50µJ/cm² bei ca. 575 nm. Das aktive Gast-Wirt-System der konjugierten Polymere MEH-PPV und F8BT* weist eine hohe Absorption und eine kleine Gewinnschwelle von 2,5 µJ/cm² bei 630 nm auf. Dieses Verhalten spiegelt sich auch in den Emissionseigenschaften der damit hergestellten DFB-Laser wieder. Die Dicke der aktiven Schichten liegen im Bereich hunderter Nanometer und wird so eingestellt, dass sich nur die transversalen Grundmoden im Wellenleiter ausbreiten k{\"o}nnen. Die Gitterperiode sind so gew{\"a}hlt, dass ein Lichtmode im Verst{\"a}rkungsbereich des Emittermaterials liegt. Die Emissionslinien der Laser sind mit FWHM-Werten von bis zu 0,3 nm spektral sehr schmalbandig und weisen auf eine sehr gute Gitterqualit{\"a}t hin. Die Untersuchungen liefern minimale Laserschwellen und maximale differentielle Effizienzen von 4,0µJ/cm² und 8,4\% f{\"u}r MEH-PPV in F8BT* (bei ca. 640nm) sowie 80 µJ/cm² und 0,9\% f{\"u}r PM567 in PS (bei ca. 575 nm). Die Vergr{\"o}ßerung der Strukturtiefe von 40nm auf 80nm in mit MEH-PPV dotierten F8BT*-Lasern zu einem deutlichen Anstieg der ausgekoppelten Energie sowie der differentiellen Effizienz und einem geringen Absinken der Laserschwelle. Dies ist ein Resultat der erh{\"o}hten Kopplung von Lasermode und Gitter. Die Emission von DFB-Lasern mit zweidimensionalen Oberfl{\"a}chengittern zeigen eine Verringerung der Divergenz aber kein Einfluss auf die Laserschwelle. Abschließend erfolgt eine Vermessung der Photostabilit{\"a}t von DFB-Lasern unter verschiedenen Bedingungen. Das Einbringen eines konjugierten Polymers in eine aktive Matrix sowie der Betrieb in einer Stickstoffatmosph{\"a}re f{\"u}hren dabei zu einer Erh{\"o}hung der Lebensdauer auf {\"u}ber eine Million Pulse. Durch die Kombination von Oberfl{\"a}chengittern in PDMS-Filmen mit elektroaktiven Substraten wird eine elektrisch steuerbare Deformation des Beugungsgitters erreicht und auf einen DFB-Laser {\"u}bertragen. Die spannungsinduzierte Verformung wird zun{\"a}chst in Beugungsexperimenten charakterisiert und ein optimaler Arbeitspunkt bestimmt. Mit den beiden Elastomeren SEBS12 und VHB4910 werden in den Gittern maximale Perioden{\"a}nderungen von 1,3\% bzw. 3,4\% bei einer Steuerspannung von 2 kV erreicht. Der Unterschied resultiert aus den verschiedenen Elastizit{\"a}tsmoduln der Materialien. {\"U}bertragen auf DFB-Laser resultiert eine Variation der Gitterperiode senkrecht zu den Gitterlinien in einer kontinuierlichen Verschiebung der Emissionswellenl{\"a}nge. Mit einem Spannungssignal von 3,25 kV wird die schmalbandige Emission eines elastischen DFB-Lasers kontinuierlich um fast 50nm von 604 nm zu 557 nm hin verschoben. Aus dem Deformationsverhalten sowohl der reinen Beugungsgitter als auch der Laser werden R{\"u}ckschl{\"u}sse auf die Elastizit{\"a}t der verwendeten Materialien gezogen und erlauben Verbesserungen der Bauteile.}, language = {de} } @article{DouceSuisseGuillonetal.2011, author = {Douce, Laurent and Suisse, Jean-Moise and Guillon, Daniel and Taubert, Andreas}, title = {Imidazolium-based liquid crystals a modular platform for versatile new materials with finely tuneable properties and behaviour}, series = {Liquid crystals : an international journal of science and technology}, volume = {38}, journal = {Liquid crystals : an international journal of science and technology}, number = {11-12}, publisher = {Routledge, Taylor \& Francis Group}, address = {Abingdon}, issn = {0267-8292}, doi = {10.1080/02678292.2011.610474}, pages = {1653 -- 1661}, year = {2011}, abstract = {Ionic liquid Crystals constitute highly versatile materials that have drawn much interest these past few years in the fields of academic research and industrial development. In this respect, the present article is intended as an update of K. Binnemans review published in 2005, but focusing exclusively on the imidazolium cation - the most widely studied. Herein, imidazolium-containing thermotropic liquid crystalline materials will be sorted by molecular structure (mono-, bis-, poly-imidazolium compounds, with symmetrical and non-symmetrical structures) and discussed. Their physico-chemical properties will be exposed in order to adduce the relevancy and potential of the imidazolium platform in various fields of research.}, language = {en} } @phdthesis{Dosche2011, author = {Dosche, Carsten}, title = {Funktionale Farbstoffe und ihre Photophysik und Anwendung in komplexen Matrizes}, address = {Potsdam}, pages = {151 S.}, year = {2011}, language = {de} }