@misc{MayerLeverPicconietal.2022, author = {Mayer, Dennis and Lever, Fabiano and Picconi, David and Metje, Jan and Ališauskas, Skirmantas and Calegari, Francesca and D{\"u}sterer, Stefan and Ehlert, Christopher and Feifel, Raimund and Niebuhr, Mario and Manschwetus, Bastian and Kuhlmann, Marion and Mazza, Tommaso and Robinson, Matthew Scott and Squibb, Richard James and Trabattoni, Andrea and Wallner, M{\aa}ns and Saalfrank, Peter and Wolf, Thomas J. A. and G{\"u}hr, Markus}, title = {Following excited-state chemical shifts in molecular ultrafast x-ray photoelectron spectroscopy}, series = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, journal = {Zweitver{\"o}ffentlichungen der Universit{\"a}t Potsdam : Mathematisch-Naturwissenschaftliche Reihe}, number = {1301}, issn = {1866-8372}, doi = {10.25932/publishup-57744}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-577442}, pages = {9}, year = {2022}, abstract = {The conversion of photon energy into other energetic forms in molecules is accompanied by charge moving on ultrafast timescales. We directly observe the charge motion at a specific site in an electronically excited molecule using time-resolved x-ray photoelectron spectroscopy (TR-XPS). We extend the concept of static chemical shift from conventional XPS by the excited-state chemical shift (ESCS), which is connected to the charge in the framework of a potential model. This allows us to invert TR-XPS spectra to the dynamic charge at a specific atom. We demonstrate the power of TR-XPS by using sulphur 2p-core-electron-emission probing to study the UV-excited dynamics of 2-thiouracil. The method allows us to discover that a major part of the population relaxes to the molecular ground state within 220-250 fs. In addition, a 250-fs oscillation, visible in the kinetic energy of the TR-XPS, reveals a coherent exchange of population among electronic states.}, language = {en} } @article{MayerLeverPicconietal.2022, author = {Mayer, Dennis and Lever, Fabiano and Picconi, David and Metje, Jan and Ališauskas, Skirmantas and Calegari, Francesca and D{\"u}sterer, Stefan and Ehlert, Christopher and Feifel, Raimund and Niebuhr, Mario and Manschwetus, Bastian and Kuhlmann, Marion and Mazza, Tommaso and Robinson, Matthew Scott and Squibb, Richard James and Trabattoni, Andrea and Wallner, M{\aa}ns and Saalfrank, Peter and Wolf, Thomas J. A. and G{\"u}hr, Markus}, title = {Following excited-state chemical shifts in molecular ultrafast x-ray photoelectron spectroscopy}, series = {Nature Communications}, volume = {13}, journal = {Nature Communications}, publisher = {Springer Nature}, address = {Berlin}, issn = {2041-1723}, doi = {10.1038/s41467-021-27908-y}, pages = {9}, year = {2022}, abstract = {The conversion of photon energy into other energetic forms in molecules is accompanied by charge moving on ultrafast timescales. We directly observe the charge motion at a specific site in an electronically excited molecule using time-resolved x-ray photoelectron spectroscopy (TR-XPS). We extend the concept of static chemical shift from conventional XPS by the excited-state chemical shift (ESCS), which is connected to the charge in the framework of a potential model. This allows us to invert TR-XPS spectra to the dynamic charge at a specific atom. We demonstrate the power of TR-XPS by using sulphur 2p-core-electron-emission probing to study the UV-excited dynamics of 2-thiouracil. The method allows us to discover that a major part of the population relaxes to the molecular ground state within 220-250 fs. In addition, a 250-fs oscillation, visible in the kinetic energy of the TR-XPS, reveals a coherent exchange of population among electronic states.}, language = {en} } @article{HegerBernardVerdierGessleretal.2019, author = {Heger, Tina and Bernard-Verdier, Maud and Gessler, Arthur and Greenwood, Alex D. and Grossart, Hans-Peter and Hilker, Monika and Keinath, Silvia and Kowarik, Ingo and K{\"u}ffer, Christoph and Marquard, Elisabeth and Mueller, Johannes and Niemeier, Stephanie and Onandia, Gabriela and Petermann, Jana S. and Rillig, Matthias C. and Rodel, Mark-Oliver and Saul, Wolf-Christian and Schittko, Conrad and Tockner, Klement and Joshi, Jasmin Radha and Jeschke, Jonathan M.}, title = {Towards an Integrative, Eco-Evolutionary Understanding of Ecological Novelty: Studying and Communicating Interlinked Effects of Global Change}, series = {Bioscience}, volume = {69}, journal = {Bioscience}, number = {11}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0006-3568}, doi = {10.1093/biosci/biz095}, pages = {888 -- 899}, year = {2019}, abstract = {Global change has complex eco-evolutionary consequences for organisms and ecosystems, but related concepts (e.g., novel ecosystems) do not cover their full range. Here we propose an umbrella concept of "ecological novelty" comprising (1) a site-specific and (2) an organism-centered, eco-evolutionary perspective. Under this umbrella, complementary options for studying and communicating effects of global change on organisms, ecosystems, and landscapes can be included in a toolbox. This allows researchers to address ecological novelty from different perspectives, e.g., by defining it based on (a) categorical or continuous measures, (b) reference conditions related to sites or organisms, and (c) types of human activities. We suggest striving for a descriptive, non-normative usage of the term "ecological novelty" in science. Normative evaluations and decisions about conservation policies or management are important, but require additional societal processes and engagement with multiple stakeholders.}, language = {en} } @misc{KalinkatCabralDarwalletal.2017, author = {Kalinkat, Gregor and Cabral, Juliano Sarmento and Darwall, William and Ficetola, G. Francesco and Fisher, Judith L. and Giling, Darren P. and Gosselin, Marie-Pierre and Grossart, Hans-Peter and Jaehnig, Sonja C. and Jeschke, Jonathan M. and Knopf, Klaus and Larsen, Stefano and Onandia, Gabriela and Paetzig, Marlene and Saul, Wolf-Christian and Singer, Gabriel and Sperfeld, Erik and Jaric, Ivan}, title = {Flagship umbrella species needed for the conservation of overlooked aquatic biodiversity}, series = {Conservation biology : the journal of the Society for Conservation Biology}, volume = {31}, journal = {Conservation biology : the journal of the Society for Conservation Biology}, publisher = {Wiley}, address = {Hoboken}, issn = {0888-8892}, doi = {10.1111/cobi.12813}, pages = {481 -- 485}, year = {2017}, language = {en} }