@article{YuQuanMeietal.2019,
  author    = {Yu, Hongtao and Quan, Ting and Mei, Shilin and Kochovski, Zdravko and Huang, Wei and Meng, Hong and Lu, Yan},
  title     = {Prompt Electrodeposition of Ni Nanodots on Ni Foam to Construct a High-Performance Water-Splitting Electrode},
  series = {Nano-Micro Letters},
  volume    = {11},
  journal   = {Nano-Micro Letters},
  number    = {41},
  publisher = {Shanghai JIAO TONG univ press},
  address   = {Shanghai},
  issn      = {2311-6706},
  doi       = {10.1007/s40820-019-0269-x},
  pages     = {13},
  year      = {2019},
  abstract  = {HighlightsFacile electrodeposition for fabricating active Ni nanodots (NiNDs) on Ni foam (NF) is shown.Binder- and heteroatom-free recyclable NiO/NiNDs@NF electrodes are efficiently made.NiO/NiNDs@NF bifunctional catalytic electrodes are used for water splitting. AbstractIn past decades, Ni-based catalytic materials and electrodes have been intensively explored as low-cost hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) catalysts for water splitting. With increasing demands for Ni worldwide, simplifying the fabrication process, increasing Ni recycling, and reducing waste are tangible sustainability goals. Here, binder-free, heteroatom-free, and recyclable Ni-based bifunctional catalytic electrodes were fabricated via a one-step quick electrodeposition method. Typically, active Ni nanodot (NiND) clusters are electrodeposited on Ni foam (NF) in Ni(NO3)(2) acetonitrile solution. After drying in air, NiO/NiND composites are obtained, leading to a binder-free and heteroatom-free NiO/NiNDs@NF catalytic electrode. The electrode shows high efficiency and long-term stability for catalyzing hydrogen and oxygen evolution reactions at low overpotentials ((10)(HER)=119mV and (50)(OER)=360mV) and can promote water catalysis at 1.70V@10mAcm(-2). More importantly, the recovery of raw materials (NF and Ni(NO3)(2)) is quite easy because of the solubility of NiO/NiNDs composites in acid solution for recycling the electrodes. Additionally, a large-sized (S similar to 70cm(2)) NiO/NiNDs@NF catalytic electrode with high durability has also been constructed. This method provides a simple and fast technology to construct high-performance, low-cost, and environmentally friendly Ni-based bifunctional electrocatalytic electrodes for water splitting.},
  language  = {en}
}
@article{WeisHessKircheretal.2019,
  author    = {Weis, Philipp and Hess, Andreas and Kircher, Gunnar and Huang, Shilin and Auernhammer, G{\"u}nter K. and Koynov, Kaloian and Butt, Hans-J{\"u}rgen and Wu, Si},
  title     = {Effects of Spacers on Photoinduced Reversible Solid-to-Liquid Transitions of Azobenzene-Containing Polymers},
  series = {Chemistry - a European journal},
  volume    = {25},
  journal   = {Chemistry - a European journal},
  number    = {46},
  publisher = {Wiley-VCH},
  address   = {Weinheim},
  issn      = {0947-6539},
  doi       = {10.1002/chem.201902273},
  pages     = {10946 -- 10953},
  year      = {2019},
  abstract  = {Photoisomerization in some azobenzene-containing polymers (azopolymers) results in reversible solid-to-liquid transitions because trans- and cis-azopolymers have different glass transition temperatures. This property enables photoinduced healing and processing of azopolymers with high spatiotemporal resolution. However, a general lack of knowledge about the influence of the polymer structure on photoinduced reversible solid-to-liquid transitions hinders the design of such novel polymers. Herein, the synthesis and photoresponsive behavior of new azopolymers with different lengths of spacers between the polymer backbone and the azobenzene group on the side chain are reported. Azopolymers with no and 20 methylene spacers did not show photoinduced solid-to-liquid transitions. Azopolymers with 6 or 12 methylene spacers showed photoinduced solid-to-liquid transitions. This study demonstrates that spacers are essential for azopolymers with photoinduced reversible solid-to-liquid transitions, and thus, gives an insight into how to design azopolymers for photoinduced healing and processing.},
  language  = {en}
}