@article{GuietGoebelKlinganetal.2015, author = {Guiet, Amandine and Goebel, Caren and Klingan, Katharina and Lublow, Michael and Reier, Tobias and Vainio, Ulla and Kraehnert, Ralph and Schlaad, Helmut and Strasser, Peter and Zaharieva, Ivelina and Dau, Holger and Driess, Matthias and Polte, Joerg and Fischer, Anna}, title = {Hydrophobic Nanoreactor Soft-Templating: A Supramolecular Approach to Yolk@Shell Materials}, series = {Advanced functional materials}, volume = {25}, journal = {Advanced functional materials}, number = {39}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1616-301X}, doi = {10.1002/adfm.201502388}, pages = {6228 -- 6240}, year = {2015}, abstract = {Due to their unique morphology-related properties, yolk@shell materials are promising materials for catalysis, drug delivery, energy conversion, and storage. Despite their proven potential, large-scale applications are however limited due to demanding synthesis protocols. Overcoming these limitations, a simple soft-templated approach for the one-pot synthesis of yolk@shell nanocomposites and in particular of multicore metal nanoparticle@metal oxide nanostructures (M-NP@MOx) is introduced. The approach here, as demonstrated for Au-NP@ITOTR (ITOTR standing for tin-rich ITO), relies on polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) inverse micelles as two compartment nanoreactor templates. While the hydrophilic P4VP core incorporates the hydrophilic metal precursor, the hydrophobic PS corona takes up the hydrophobic metal oxide precursor. As a result, interfacial reactions between the precursors can take place, leading to the formation of yolk@shell structures in solution. Once calcined these micelles yield Au-NP@ITOTR nanostructures, composed of multiple 6 nm sized Au NPs strongly anchored onto the inner surface of porous 35 nm sized ITOTR hollow spheres. Although of multicore nature, only limited sintering of the metal nanoparticles is observed at high temperatures (700 degrees C). In addition, the as-synthesized yolk@shell structures exhibit high and stable activity toward CO electrooxidation, thus demonstrating the applicability of our approach for the design of functional yolk@shell nanocatalysts.}, language = {en} } @article{BommerCoppersmithCoppersmithetal.2015, author = {Bommer, Julian J. and Coppersmith, Kevin J. and Coppersmith, Ryan T. and Hanson, Kathryn L. and Mangongolo, Azangi and Neveling, Johann and Rathje, Ellen M. and Rodriguez-Marek, Adrian and Scherbaum, Frank and Shelembe, Refilwe and Stafford, Peter J. and Strasser, Fleur O.}, title = {A SSHAC Level 3 Probabilistic Seismic Hazard Analysis for a New-Build Nuclear Site in South Africa}, series = {Earthquake spectra : the professional journal of the Earthquake Engineering Research Institute}, volume = {31}, journal = {Earthquake spectra : the professional journal of the Earthquake Engineering Research Institute}, number = {2}, publisher = {Earthquake Engineering Research Institute}, address = {Oakland}, issn = {8755-2930}, doi = {10.1193/060913EQS145M}, pages = {661 -- 698}, year = {2015}, abstract = {A probabilistic seismic hazard analysis has been conducted for a potential nuclear power plant site on the coast of South Africa, a country of low-to-moderate seismicity. The hazard study was conducted as a SSHAC Level 3 process, the first application of this approach outside North America. Extensive geological investigations identified five fault sources with a non-zero probability of being seismogenic. Five area sources were defined for distributed seismicity, the least active being the host zone for which the low recurrence rates for earthquakes were substantiated through investigations of historical seismicity. Empirical ground-motion prediction equations were adjusted to a horizon within the bedrock at the site using kappa values inferred from weak-motion analyses. These adjusted models were then scaled to create new equations capturing the range of epistemic uncertainty in this region with no strong motion recordings. Surface motions were obtained by convolving the bedrock motions with site amplification functions calculated using measured shear-wave velocity profiles.}, language = {en} }