@article{O'Brien2001, author = {O'Brien, Patrick J.}, title = {Subduction followed by Collision : Alpine and Himalayan examples}, year = {2001}, language = {en} } @article{O'BrienKryza2001, author = {O'Brien, Patrick J. and Kryza, R.}, title = {The Variscan basement of the Polish Sudetes}, year = {2001}, language = {en} } @article{KonradSchmolkeO'BrienZack2011, author = {Konrad-Schmolke, Matthias and O'Brien, Patrick J. and Zack, Thomas}, title = {Fluid Migration above a Subducted Slab-Constraints on Amount, Pathways and Major Element Mobility from Partially Overprinted Eclogite-facies Rocks (Sesia Zone, Western Alps)}, series = {Journal of petrology}, volume = {52}, journal = {Journal of petrology}, number = {3}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0022-3530}, doi = {10.1093/petrology/egq087}, pages = {457 -- 486}, year = {2011}, abstract = {The Western Alpine Sesia-Lanzo Zone (SLZ) is a sliver of eclogite-facies continental crust exhumed from mantle depths in the hanging wall of a subducted oceanic slab. Eclogite-facies felsic and basic rocks sampled across the internal SLZ show different degrees of retrograde metamorphic overprint associated with fluid influx. The weakly deformed samples preserve relict eclogite-facies mineral assemblages that show partial fluid-induced compositional re-equilibration along grain boundaries, brittle fractures and other fluid pathways. Multiple fluid influx stages are indicated by replacement of primary omphacite by phengite, albitic plagioclase and epidote as well as partial re-equilibration and/or overgrowths in phengite and sodic amphibole, producing characteristic step-like compositional zoning patterns. The observed textures, together with the map-scale distribution of the samples, suggest open-system, pervasive and reactive fluid flux across large rock volumes above the subducted slab. Thermodynamic modelling indicates a minimum amount of fluid of 0 center dot 1-0 center dot 5 wt \% interacting with the wall-rocks. Phase relations and reaction textures indicate mobility of K, Ca, Fe and Mg, whereas Al is relatively immobile in these medium-temperature-high-pressure fluids. Furthermore, the thermodynamic models show that recycling of previously fractionated material, such as in the cores of garnet porphyroblasts, largely controls the compositional re-equilibration of the exhumed rock body.}, language = {en} } @article{KonradSchmolkeZackO'Brienetal.2011, author = {Konrad-Schmolke, Matthias and Zack, Thomas and O'Brien, Patrick J. and Barth, Matthias}, title = {Fluid migration above a subducted slab - Thermodynamic and trace element modelling of fluid-rock interaction in partially overprinted eclogite-facies rocks (Sesia Zone, Western Alps)}, series = {Earth \& planetary science letters}, volume = {311}, journal = {Earth \& planetary science letters}, number = {3-4}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0012-821X}, doi = {10.1016/j.epsl.2011.09.025}, pages = {287 -- 298}, year = {2011}, abstract = {The amount and composition of subduction zone fluids and the effect of fluid-rock interaction at a slab-mantle interface have been constrained by thermodynamic and trace element modelling of partially overprinted blueschist-facies rocks from the Sesia Zone (Western Alps). Deformation-induced differences in fluid flux led to a partial preservation of pristine mineral cores in weakly deformed samples that were used to quantify Li, B, Stand Pb distribution during mineral growth, -breakdown and modification induced by fluid-rock interaction. Our results show that Li and 13 budgets are fluid-controlled, thus acting as tracers for fluid-rock interaction processes, whereas Stand Pb budgets are mainly controlled by the fluid-induced formation of epidote. Our calculations show that fluid-rock interaction caused significant Li and B depletion in the affected rocks due to leaching effects, which in turn can lead to a drastic enrichment of these elements in the percolating fluid. Depending on available fluid-mineral trace element distribution coefficients modelled fluid rock ratios were up to 0.06 in weakly deformed samples and at least 0.5 to 4 in shear zone mylonites. These amounts lead to time integrated fluid fluxes of up to 1.4-10(2) m(3) m(-2) in the weakly deformed rocks and 1-8-10(3) m(3) m(-2) in the mylonites. Combined thermodynamic and trace element models can be used to quantify metamorphic fluid fluxes and the associated element transfer in complex, reacting rock systems and help to better understand commonly observed fluid-induced trace element trends in rocks and minerals from different geodynamic environments.}, language = {en} } @article{SchmidtMezgerO'Brien2011, author = {Schmidt, Alexander and Mezger, Klaus and O'Brien, Patrick J.}, title = {The time of eclogite formation in the ultrahigh pressure rocks of the Sulu terrane Constraints from Lu-Hf garnet geochronology}, series = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, volume = {125}, journal = {Lithos : an international journal of mineralogy, petrology, and geochemistry}, number = {1-2}, publisher = {Elsevier}, address = {Amsterdam}, issn = {0024-4937}, doi = {10.1016/j.lithos.2011.04.004}, pages = {743 -- 756}, year = {2011}, abstract = {Eclogites from the main borehole of the Chinese Continental Scientific Drilling project yield highly precise Lu-Hf garnet-clinopyroxene ages of 216.9 +/- 1.2 Ma (four samples) and 220.5 +/- 2.7 Ma (one sample). The spatial distribution of the rare earth elements in garnet is consistent with the preservation of primary growth zoning, unmodified by diffusion, which supports the interpretation that the Lu-Hf ages date the time of formation of garnet, the major rock forming mineral in the eclogites. The preservation of primary REE-zoning, despite peak metamorphic temperatures around 800-850 degrees C. indicates that the Lu-Hf chronometer is perfectly suitable to date garnet-forming reactions in high grade rocks. The range of Lu-Hf ages for eclogites in the Dabie-Sulu UHP terrane point to episodic rather than continuous growth of garnets and thus punctuated metamorphism during the collision of the North China Block and the Yangtze Block. The U-Pb ages and Hf-isotope systematics of zircon grains from one eclogite sample imply a protracted geologic history of the eclogite precursors that started around 2 Ga and culminated in the UHP metamorphism around 220 Ma.}, language = {en} } @article{KotkovaO'BrienZiemann2011, author = {Kotkova, Jana and O'Brien, Patrick J. and Ziemann, Martin Andreas}, title = {Diamond and coesite discovered in Saxony-type granulite solution to the Variscan garnet peridotite enigma}, series = {Geology}, volume = {39}, journal = {Geology}, number = {7}, publisher = {American Institute of Physics}, address = {Boulder}, issn = {0091-7613}, doi = {10.1130/G31971.1}, pages = {667 -- 670}, year = {2011}, abstract = {The pressures required for diamond and coesite formation far exceed conditions reached by even the deepest present-day orogenic crustal roots. Therefore the occurrence of metamorphosed continental crust containing these minerals requires processes other than crustal thickening to have operated in the past. Here we report the first in situ finding of diamond and coesite, characterized by micro-Raman spectroscopy, in high-pressure granulites otherwise indistinguishable from granulites found associated with garnet peridotite throughout the European Variscides. Our discovery confirms the provenance of Europe's first reliable diamond, the "Bohemian diamond," found in A.D. 1870, and also represents the first robust evidence for ultrahigh-pressure conditions in a major Variscan crustal rock type. A process of deep continental subduction is required to explain the metamorphic pressures and the granulite-garnet peridotite association, and thus tectonometamorphic models for these rocks involving a deep orogenic crustal root need to be significantly modified.}, language = {en} } @article{SchertlO'Brien2013, author = {Schertl, Hans-Peter and O'Brien, Patrick}, title = {Continental crust at mantle depths - key minerals and microstructures}, series = {Elements : an international magazine of mineralogy, geochemistry, and petrology}, volume = {9}, journal = {Elements : an international magazine of mineralogy, geochemistry, and petrology}, number = {4}, publisher = {Mineralogical Society of America}, address = {Chantilly}, issn = {1811-5209}, doi = {10.2113/gselements.9.4.261}, pages = {261 -- 266}, year = {2013}, abstract = {Finding evidence for ultrahigh-pressure (UHP) metamorphism in crustal rocks is far from straightforward. The index minerals coesite and diamond are incredibly inconspicuous and are therefore difficult to use as UHP prospecting tools. Consequently, petrographers rely on recognizing subtle breakdown microstructures that result from pressure release during the return to the surface of the once deeply buried rock. Similarly, many other UHP minerals are first suspected on the basis of typical reaction or exsolution microstructures. Thus, the painstaking use of microscopic techniques has been fundamental to the tremendous advances in characterizing, quantifying, and understanding macroscopic-scale, deep continental subduction, rapid exhumation, and mountain-building processes.}, language = {en} } @article{DeAndradeVidalLewinetal.2006, author = {De Andrade, V. and Vidal, O. and Lewin, E. and Agard, P. and O'brien, Patrick}, title = {Quantification of electron microprobe compositional maps of rock thin sections: an optimized method and examples}, series = {Journal of metamorphic geology}, volume = {24}, journal = {Journal of metamorphic geology}, publisher = {Wiley-Blackwell}, address = {Oxford}, issn = {0263-4929}, doi = {10.1111/j.1525-1314.2006.00660.x}, pages = {655 -- 668}, year = {2006}, abstract = {Quantification of discrete pressure-temperature domains in deformed chlorite + white mica-bearing metapelites was undertaken on mineral compositions derived by two-dimensional microprobe compositional mapping of selected areas of rock thin sections. In order to achieve compositional information at sufficient analytical precision, spatial resolution and sample coverage within a typical analysis time of 1 day, an optimization of measurement methods was necessary. The method presented here allows collection of raw counts for eight different element concentrations at an analytical precision of similar to 1-2 wt\%. X-ray intensity multiplane maps (one map per measured chemical element) are translated into concentration multiplane maps, utilizing selected conventionally measured spot analyses combined with the Castaing approximation for each mineral. As this step requires identification of the different minerals present in the mapped area, a statistical clustering technique to identify different groups of composition was developed, guided by simple petrographic inspection of the thin section, to delineate the important minerals in the mapped area. Finally, the compositions of each pixel are translated into a mineral structural formula thus yielding a new kind of image with a high content of petrological information. The reliability of the mineral composition images was emphasized by carrying out precision tests on the analytical data. The possible use of chemical maps to infer the P-T-deformation history of metamorphic rocks is illustrated with two samples from the Spitzbergen and the Sambagawa blueschist facies belts. In both samples, a strong correlation between structures and chemistry is observed. Qualitative estimates of P-T conditions from the Si-content of mica and chlorite are in good agreement with their location in microstructures that formed at different times. Therefore, the combination of chemical maps with microstructural observations is a very powerful approach to understand both the evolution of complex metamorphic rocks and the control by deformation of mineral reactivity.}, language = {en} } @article{KonradSchmolkeBabistHandyetal.2006, author = {Konrad-Schmolke, Matthias and Babist, Jochen and Handy, Mark R. and O'brien, Patrick J.}, title = {The physico-chemical properties of a subducted slab from garnet zonation patterns (Sesia Zone, Western Alps)}, series = {Journal of petrology}, volume = {47}, journal = {Journal of petrology}, number = {11}, publisher = {Oxford Univ. Press}, address = {Oxford}, issn = {0022-3530}, doi = {10.1093/petrology/egl039}, pages = {2123 -- 2148}, year = {2006}, abstract = {Garnets in continentally derived high-pressure (HP) rocks of the Sesia Zone (Western Alps) exhibit three different chemical zonation patterns, depending on sample locality. Comparison of observed garnet zonation patterns with thermodynamically modelled patterns shows that the different patterns are caused by differences in the water content of the subducted protoliths during prograde metamorphism. Zonation patterns of garnets in water-saturated host rocks show typical prograde chemical zonations with steadily increasing pyrope content and increasing XMg, together with bell-shaped spessartine patterns. In contrast, garnets in water-undersaturated rocks have more complex zonation patterns with a characteristic decrease in pyrope and XMg between core and inner rim. In some cases, garnets show an abrupt compositional change in core-to-rim profiles, possibly due to water-undersaturation prior to HP metamorphism. Garnets from both water-saturated and water-undersaturated rocks show signs of intervening growth interruptions and core resorption. This growth interruption results from bulk-rock depletion caused by fractional garnet crystallization. The water content during burial influences significantly the physical properties of the subducted rocks. Due to enhanced garnet crystallization, water-undersaturated rocks, i.e. those lacking a free fluid phase, become denser than their water-saturated equivalents, facilitating the subduction of continental material. Although water-bearing phases such as phengite and epidote are stable up to eclogite-facies conditions in these rocks, dehydration reactions during subduction are lacking in water-undersaturated rocks up to the transition to the eclogite facies, due to the thermodynamic stability of such hydrous phases at high P-T conditions. Our calculations show that garnet zonation patterns strongly depend on the mineral parageneses stable during garnet growth and that certain co-genetic mineral assemblages cause distinct garnet zonation patterns. This observation enables interpretation of complex garnet growth zonation patterns in terms of garnet-forming reactions and water content during HP metamorphism, as well determination of detailed P-T paths.}, language = {en} } @article{WilkeO'BrienAltenbergeretal.2010, author = {Wilke, Franziska Daniela Helena and O'Brien, Patrick J. and Altenberger, Uwe and Konrad-Schmolke, Matthias and Khan, M. Ahmed}, title = {Multi-stage reaction history in different eclogite types from the Pakistan Himalaya and implications for exhumation processes}, issn = {0024-4937}, doi = {10.1016/j.lithos.2009.07.015}, year = {2010}, abstract = {Metabasites were sampled from rock series of the subducted margin of the Indian Plate, the so-called Higher Himalayan Crystalline, in the Upper Kaghan Valley, Pakistan. These vary from corona dolerites, cropping out around Saif- ul-Muluk in the south, to coesite-eclogite close to the suture zone against rocks of the Kohistan arc in the north. Bulk rock major- and trace-element chemistry reveals essentially a single protolith as the source for five different eclogite types, which differ in fabric, modal mineralogy as well as in mineral chemistry. The study of newly-collected samples reveals coesite (confirmed by in situ Raman spectroscopy) in both garnet and omphacite. All eclogites show growth of amphiboles during exhumation. Within some coesite-bearing eclogites the presence of glaucophane cores to barroisite is noted whereas in most samples porphyroblastic sodic-calcic amphiboles are rimmed by more aluminous calcic amphibole (pargasite, tschermakite, and edenite). Eclogite facies rutile is replaced by ilmenite which itself is commonly surrounded by titanite. In addition, some eclogite bodies show leucocratic segregations containing phengite, quartz, zoisite and/or kyanite. The important implication is that the complex exhumation path shows stages of initial cooling during decompression (formation of glaucophane) followed by reheating: a very similar situation to that reported for the coesite-bearing eclogite series of the Tso Morari massif, India, 450 km to the south-east.}, language = {en} }