@article{MondalKreuzerBehrensetal.2019, author = {Mondal, Suvendu Sekhar and Kreuzer, Alex and Behrens, Karsten and Sch{\"u}tz, Gisela and Holdt, Hans-J{\"u}rgen and Hirscher, Michael}, title = {Systematic experimental study on quantum sieving of hydrogen isotopes in metal-amide-imidazolate frameworks with narrow 1-D channels}, series = {ChemPhysChem : a European journal of chemical physics and physical chemistry}, volume = {20}, journal = {ChemPhysChem : a European journal of chemical physics and physical chemistry}, number = {10}, publisher = {Wiley-VCH}, address = {Weinheim}, issn = {1439-4235}, doi = {10.1002/cphc.201900183}, pages = {1311 -- 1315}, year = {2019}, abstract = {Quantum sieving of hydrogen isotopes is experimentally studied in isostructural hexagonal metal-organic frameworks having 1-D channels, named IFP-1, -3, -4 and -7. Inside the channels, different molecules or atoms restrict the channel diameter periodically with apertures larger (4.2 angstrom for IFP-1, 3.1 angstrom for IFP-3) and smaller (2.1 angstrom for IFP-7, 1.7 angstrom for IFP-4) than the kinetic diameter of hydrogen isotopes. From a geometrical point of view, no gas should penetrate into IFP-7 and IFP-4, but due to the thermally induced flexibility, so-called gate-opening effect of the apertures, penetration becomes possible with increasing temperature. Thermal desorption spectroscopy (TDS) measurements with pure H-2 or D-2 have been applied to study isotope adsorption. Further TDS experiments after exposure to an equimolar H-2/D-2 mixture allow to determine directly the selectivity of isotope separation by quantum sieving. IFP-7 shows a very low selectivity not higher than S=2. The selectivity of the materials with the smallest pore aperture IFP-4 has a constant value of S approximate to 2 for different exposure times and pressures, which can be explained by the 1-D channel structure. Due to the relatively small cavities between the apertures of IFP-4 and IFP-7, molecules in the channels cannot pass each other, which leads to a single-file filling. Therefore, no time dependence is observed, since the quantum sieving effect occurs only at the outermost pore aperture, resulting in a low separation selectivity.}, language = {en} } @book{Behrens2008, author = {Behrens, Michael}, title = {Turnaround Finance : eine Analyse der Kapitalzufuhr im Krisenfall des Mittelstandes}, series = {Schriftenreihe Finanzierung und Banken}, volume = {13}, journal = {Schriftenreihe Finanzierung und Banken}, publisher = {Verl. Wissenschaft \& Praxis}, address = {Sternenfels}, isbn = {978-3-89673-467-9}, pages = {222 S.}, year = {2008}, language = {de} } @article{GrimmBehrensMaerkeretal.2008, author = {Grimm, Rosina and Behrens, T. and M{\"a}rker, Michael and Elsenbeer, Helmut}, title = {Soil organic carbon concentrations and stocks on Barro Colorado Island : digital soil mapping using random forests analysis}, issn = {0016-7061}, doi = {10.1016/j.geoderma.2008.05.008}, year = {2008}, language = {en} } @misc{MondalBehrensMatthesetal.2014, author = {Mondal, Suvendu Sekhar and Behrens, Karsten and Matthes, Philipp R. and Sch{\"o}nfeld, Fabian and Nitsch, J{\"o}rn and Steffen, Andreas and Primus, Philipp-Alexander and Kumke, Michael Uwe and M{\"u}ller-Buschbaum, Klaus and Holdt, Hans-J{\"u}rgen}, title = {White light emission of IFP-1 by in situ co-doping of the MOF pore system with Eu3+ and Tb3+}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:517-opus4-79953}, pages = {4623 -- 4631}, year = {2014}, abstract = {Co-doping of the MOF 3∞[Zn(2-methylimidazolate-4-amide-5-imidate)] (IFP-1 = Imidazolate Framework Potsdam-1) with luminescent Eu3+ and Tb3+ ions presents an approach to utilize the porosity of the MOF for the intercalation of luminescence centers and for tuning of the chromaticity to the emission of white light of the quality of a three color emitter. Organic based fluorescence processes of the MOF backbone as well as metal based luminescence of the dopants are combined to one homogenous single source emitter while retaining the MOF's porosity. The lanthanide ions Eu3+ and Tb3+ were doped in situ into IFP-1 upon formation of the MOF by intercalation into the micropores of the growing framework without a structure directing effect. Furthermore, the color point is temperature sensitive, so that a cold white light with a higher blue content is observed at 77 K and a warmer white light at room temperature (RT) due to the reduction of the organic emission at higher temperatures. The study further illustrates the dependence of the amount of luminescent ions on porosity and sorption properties of the MOF and proves the intercalation of luminescence centers into the pore system by low-temperature site selective photoluminescence spectroscopy, SEM and EDX. It also covers an investigation of the border of homogenous uptake within the MOF pores and the formation of secondary phases of lanthanide formates on the surface of the MOF. Crossing the border from a homogenous co-doping to a two-phase composite system can be beneficially used to adjust the character and warmth of the white light. This study also describes two-color emitters of the formula Ln@IFP-1a-d (Ln: Eu, Tb) by doping with just one lanthanide Eu3+ or Tb3+.}, language = {en} } @article{MondalBehrensMatthesetal.2015, author = {Mondal, Suvendu Sekhar and Behrens, Karsten and Matthes, Philipp R. and Sch{\"o}nfeld, Fabian and Nitsch, J{\"o}rn and Steffen, Andreas and Primus, Philipp-Alexander and Kumke, Michael Uwe and M{\"u}ller-Buschbaum, Klaus and Holdt, Hans-J{\"u}rgen}, title = {White light emission of IFP-1 by in situ co-doping of the MOF pore system with Eu3+ and Tb3+}, series = {Journal of materials chemistry : C, Materials for optical and electronic devices}, volume = {18}, journal = {Journal of materials chemistry : C, Materials for optical and electronic devices}, number = {3}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2050-7534}, doi = {10.1039/C4TC02919D}, pages = {4623 -- 4631}, year = {2015}, abstract = {Co-doping of the MOF 3∞[Zn(2-methylimidazolate-4-amide-5-imidate)] (IFP-1 = Imidazolate Framework Potsdam-1) with luminescent Eu3+ and Tb3+ ions presents an approach to utilize the porosity of the MOF for the intercalation of luminescence centers and for tuning of the chromaticity to the emission of white light of the quality of a three color emitter. Organic based fluorescence processes of the MOF backbone as well as metal based luminescence of the dopants are combined to one homogenous single source emitter while retaining the MOF's porosity. The lanthanide ions Eu3+ and Tb3+ were doped in situ into IFP-1 upon formation of the MOF by intercalation into the micropores of the growing framework without a structure directing effect. Furthermore, the color point is temperature sensitive, so that a cold white light with a higher blue content is observed at 77 K and a warmer white light at room temperature (RT) due to the reduction of the organic emission at higher temperatures. The study further illustrates the dependence of the amount of luminescent ions on porosity and sorption properties of the MOF and proves the intercalation of luminescence centers into the pore system by low-temperature site selective photoluminescence spectroscopy, SEM and EDX. It also covers an investigation of the border of homogenous uptake within the MOF pores and the formation of secondary phases of lanthanide formates on the surface of the MOF. Crossing the border from a homogenous co-doping to a two-phase composite system can be beneficially used to adjust the character and warmth of the white light. This study also describes two-color emitters of the formula Ln@IFP-1a-d (Ln: Eu, Tb) by doping with just one lanthanide Eu3+ or Tb3+.}, language = {en} } @article{MondalBehrensMatthesetal.2015, author = {Mondal, Suvendu Sekhar and Behrens, Karsten and Matthes, Philipp R. and Sch{\"o}nfeld, Fabian and Nitsch, J{\"o}rn and Steffen, Andreas and Primus, Philipp-Alexander and Kumke, Michael Uwe and M{\"u}ller-Buschbaum, Klaus and Holdt, Hans-J{\"u}rgen}, title = {White light emission of IFP-1 by in situ co-doping of the MOF pore system with Eu3+ and Tb3+}, series = {Journal of materials chemistry : C, Materials for optical and electronic devices}, volume = {3}, journal = {Journal of materials chemistry : C, Materials for optical and electronic devices}, number = {18}, publisher = {Royal Society of Chemistry}, address = {Cambridge}, issn = {2050-7526}, doi = {10.1039/c4tc02919d}, pages = {4623 -- 4631}, year = {2015}, language = {en} } @article{AlrefaiMondalWrucketal.2019, author = {Alrefai, Anas and Mondal, Suvendu Sekhar and Wruck, Alexander and Kelling, Alexandra and Schilde, Uwe and Brandt, Philipp and Janiak, Christoph and Schoenfeld, Sophie and Weber, Birgit and Rybakowski, Lawrence and Herrman, Carmen and Brennenstuhl, Katlen and Eidner, Sascha and Kumke, Michael Uwe and Behrens, Karsten and G{\"u}nter, Christina and M{\"u}ller, Holger and Holdt, Hans-J{\"u}rgen}, title = {Hydrogen-bonded supramolecular metal-imidazolate frameworks: gas sorption, magnetic and UV/Vis spectroscopic properties}, series = {Journal of Inclusion Phenomena and Macrocyclic Chemistry}, volume = {94}, journal = {Journal of Inclusion Phenomena and Macrocyclic Chemistry}, number = {3-4}, publisher = {Springer}, address = {Dordrecht}, issn = {1388-3127}, doi = {10.1007/s10847-019-00926-6}, pages = {155 -- 165}, year = {2019}, abstract = {By varying reaction parameters for the syntheses of the hydrogen-bonded metal-imidazolate frameworks (HIF) HIF-1 and HIF-2 (featuring 14 Zn and 14 Co atoms, respectively) to increase their yields and crystallinity, we found that HIF-1 is generated in two different frameworks, named as HIF-1a and HIF-1b. HIF-1b is isostructural to HIF-2. We determined the gas sorption and magnetic properties of HIF-2. In comparison to HIF-1a (Brunauer-Emmett-Teller (BET) surface area of 471m(2) g(-1)), HIF-2 possesses overall very low gas sorption uptake capacities [BET(CO2) surface area=85m(2) g(-1)]. Variable temperature magnetic susceptibility measurement of HIF-2 showed antiferromagnetic exchange interactions between the cobalt(II) high-spin centres at lower temperature. Theoretical analysis by density functional theory confirmed this finding. The UV/Vis-reflection spectra of HIF-1 (mixture of HIF-1a and b), HIF-2 and HIF-3 (with 14 Cd atoms) were measured and showed a characteristic absorption band centered at 340nm, which was indicative for differences in the imidazolate framework.}, language = {en} } @article{NienaberHeinzRappetal.2018, author = {Nienaber, Andr{\´e} and Heinz, Andreas and Rapp, Michael A. and Bermpohl, F. and Schulz, M. and Behrens, J. and L{\"o}hr, M.}, title = {Einfluss der Personalbesetzung auf Konflikte auf psychiatrischen Stationen}, series = {Der Nervenarzt : Organ der Deutschen Gesellschaft f{\"u}r Psychiatrie, Psychotherapie und Nervenheilkunde ; Mitteilungsblatt der Deutschen Gesellschaft f{\"u}r Neurologie}, volume = {89}, journal = {Der Nervenarzt : Organ der Deutschen Gesellschaft f{\"u}r Psychiatrie, Psychotherapie und Nervenheilkunde ; Mitteilungsblatt der Deutschen Gesellschaft f{\"u}r Neurologie}, number = {7}, publisher = {Springer}, address = {New York}, issn = {0028-2804}, doi = {10.1007/s00115-018-0521-5}, pages = {821 -- 827}, year = {2018}, abstract = {Psychiatrische Stationen sind ein wichtiges Element in der psychiatrischen Versorgung von Menschen mit akuter Eigen- oder Fremdgef{\"a}hrdung. Leider kommt es in diesem Rahmen immer wieder auch zu Aggression, Gewalt (Konflikten) sowie zur Anwendung von Zwang (Eind{\"a}mmung). Als entscheidender Faktor f{\"u}r den sachgem{\"a}ßen Umgang mit diesen Situationen wird sowohl die Quantit{\"a}t als auch die Qualit{\"a}t der Mitarbeitenden angesehen. Vor diesem Hintergrund besch{\"a}ftigt sich die vorliegende Untersuchung mit der Versorgungssituation auf akutpsychiatrischen Stationen. Die Hypothese lautet, dass sowohl die Gr{\"o}ße der akutpsychiatrischen Station als auch die Anzahl der Pflegenden einen Einfluss auf das Vorkommen konflikthafter Situationen haben. Hierf{\"u}r sind Daten in 6 Kliniken auf insgesamt 12 psychiatrischen Stationen erfasst worden. Als Erfassungsinstrument diente die Patient Staff Conflict Checklist - Shift Report (PCC-SR). Insgesamt konnten 2026 Schichten (Fr{\"u}h‑, Sp{\"a}t- und Nachtschicht) erfasst und ausgewertet werden. Die personelle Besetzung der Stationen mit Pflegepersonal variierte erheblich. Die Ergebnisse zeigen, dass sowohl die Stationsgr{\"o}ße als auch die Anzahl der Pflegepersonen auf akutpsychiatrischen Stationen einen signifikanten Einfluss auf das Vorkommen von Konflikten haben. In den Ergebnissen zeigt sich weiterhin, dass sich die Inzidenz des konflikthaften Verhaltens von Patienten sowohl im Hinblick auf die untersuchten Stationen der beteiligten Krankenh{\"a}user als auch im Hinblick auf die betrachteten Dienstzeittypen unterscheiden. Dar{\"u}ber hinaus zeigt sich, dass das Ausmaß der Schließung einer Akutstation und die Gr{\"o}ße einer Station einen negativen Einfluss auf die Inzidenz von Konflikten im station{\"a}r akutpsychiatrischen Kontext haben. Das Auftreten konflikthaften Verhaltens kann zur Fremd- oder Selbstgef{\"a}hrdung und zu einer Vielzahl deeskalierender und eind{\"a}mmender Maßnahmen f{\"u}hren. Hierf{\"u}r sind entsprechende personelle Ressourcen erforderlich.}, language = {de} }